{"title":"氧化钛改性碳化硅","authors":"I. S. Grishin, N. N. Smirnov, D. N. Iashkova","doi":"10.1007/s10717-025-00730-4","DOIUrl":null,"url":null,"abstract":"<p>In this work, a titanium oxide-modified silicon oxycarbide composite was synthesized. A combined mechanical treatment by deposition of TiO<sub>2</sub> on the surface of white soot and activated carbon was used. The fixation of titanium oxide was confirmed by elemental analysis data. Scanning electron microscopy (SEM) showed that the size of the deposited particles did not exceed 100 nm. The structure of the obtained materials was studied by x-ray diffraction and IR spectroscopy. It was shown that the silicon oxycarbide composite has a high degree of amorphism; the diffraction pattern contains peaks characteristic of reflections from anatase planes. The IR spectra contain bands corresponding to vibrations of the Ti–O–Ti and Ti–O–C bonds. The porosity of the synthesized samples was investigated by low temperature nitrogen adsorption/desorption. It was found that the composite has a sufficiently developed porous structure with a predominance of meso- and macro pores. The material is proposed to be used as a photocatalyst for the degradation of organic compounds in cleaning processes.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"81 11-12","pages":"482 - 486"},"PeriodicalIF":0.6000,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Titanium Oxide Modification of Silicon Oxycarbide\",\"authors\":\"I. S. Grishin, N. N. Smirnov, D. N. Iashkova\",\"doi\":\"10.1007/s10717-025-00730-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In this work, a titanium oxide-modified silicon oxycarbide composite was synthesized. A combined mechanical treatment by deposition of TiO<sub>2</sub> on the surface of white soot and activated carbon was used. The fixation of titanium oxide was confirmed by elemental analysis data. Scanning electron microscopy (SEM) showed that the size of the deposited particles did not exceed 100 nm. The structure of the obtained materials was studied by x-ray diffraction and IR spectroscopy. It was shown that the silicon oxycarbide composite has a high degree of amorphism; the diffraction pattern contains peaks characteristic of reflections from anatase planes. The IR spectra contain bands corresponding to vibrations of the Ti–O–Ti and Ti–O–C bonds. The porosity of the synthesized samples was investigated by low temperature nitrogen adsorption/desorption. It was found that the composite has a sufficiently developed porous structure with a predominance of meso- and macro pores. The material is proposed to be used as a photocatalyst for the degradation of organic compounds in cleaning processes.</p>\",\"PeriodicalId\":579,\"journal\":{\"name\":\"Glass and Ceramics\",\"volume\":\"81 11-12\",\"pages\":\"482 - 486\"},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2025-03-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Glass and Ceramics\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10717-025-00730-4\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Glass and Ceramics","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s10717-025-00730-4","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0
摘要
这项研究合成了一种氧化钛改性碳化硅复合材料。通过在白烟灰和活性炭表面沉积二氧化钛,采用了一种综合机械处理方法。元素分析数据证实了氧化钛的固定。扫描电子显微镜(SEM)显示,沉积颗粒的大小不超过 100 纳米。通过 X 射线衍射和红外光谱对所获材料的结构进行了研究。结果表明,氧碳化硅复合材料具有高度的非晶性;衍射图样包含锐钛矿平面反射的特征峰。红外光谱包含与 Ti-O-Ti 和 Ti-O-C 键振动相对应的波段。通过低温氮吸附/解吸法研究了合成样品的孔隙率。结果发现,该复合材料具有充分发达的多孔结构,中孔和大孔居多。建议将这种材料用作光催化剂,在清洁过程中降解有机化合物。
In this work, a titanium oxide-modified silicon oxycarbide composite was synthesized. A combined mechanical treatment by deposition of TiO2 on the surface of white soot and activated carbon was used. The fixation of titanium oxide was confirmed by elemental analysis data. Scanning electron microscopy (SEM) showed that the size of the deposited particles did not exceed 100 nm. The structure of the obtained materials was studied by x-ray diffraction and IR spectroscopy. It was shown that the silicon oxycarbide composite has a high degree of amorphism; the diffraction pattern contains peaks characteristic of reflections from anatase planes. The IR spectra contain bands corresponding to vibrations of the Ti–O–Ti and Ti–O–C bonds. The porosity of the synthesized samples was investigated by low temperature nitrogen adsorption/desorption. It was found that the composite has a sufficiently developed porous structure with a predominance of meso- and macro pores. The material is proposed to be used as a photocatalyst for the degradation of organic compounds in cleaning processes.
期刊介绍:
Glass and Ceramics reports on advances in basic and applied research and plant production techniques in glass and ceramics. The journal''s broad coverage includes developments in the areas of silicate chemistry, mineralogy and metallurgy, crystal chemistry, solid state reactions, raw materials, phase equilibria, reaction kinetics, physicochemical analysis, physics of dielectrics, and refractories, among others.