Glass and Ceramics最新文献

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Effect of Alkaline Components on Dental Filling Glass 碱性成分对牙科填充玻璃的影响
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-04-29 DOI: 10.1007/s10717-024-00643-8
E. M. Zinina, V. I. Savinkov, F. Posokhova, A. A. Buzov, V. P. Chuev, V. N. Sigaev
{"title":"Effect of Alkaline Components on Dental Filling Glass","authors":"E. M. Zinina,&nbsp;V. I. Savinkov,&nbsp;F. Posokhova,&nbsp;A. A. Buzov,&nbsp;V. P. Chuev,&nbsp;V. N. Sigaev","doi":"10.1007/s10717-024-00643-8","DOIUrl":"10.1007/s10717-024-00643-8","url":null,"abstract":"<p>The influence of the modification of glass in the strontium-aluminum-boron-silicate system (SABS) on technological and physicochemical properties was investigated. Introducing two alkalis into the glass makeup significantly lowered the melting temperature, from 1500 to 1450°C, which effected changes in the properties of the glass. On introducing alkalis in amounts up to 5 mol.% the thermal linear expansion coefficient (LTEC) decreased from 58 to 50 (α × 10 <sup>– 7</sup> K<sup>– 1</sup>) and the refractive index <i>n</i><sub><i>D</i></sub> from 1.551 to 1.528. However, alkaline components adversely affect the hydrolytic resistance of the glass, transferring it from hydrolytic class I to II. The solution to this problem was to: (1) employ the polyalkaline effect, (2) maintain high radiopacity of the glass by introducing a small amount of highly effective radiopaque barium oxide into the makeup and significant strontium oxide reduction, and (3) increase the aluminum oxide content, which ordinarily increases the chemical resistance of the glass. The result was improved melting properties on lower melting temperatures and glass with high values of x-ray contrast (about 550%), light transmission (<i>T</i> = 90%), refractive index values <i>n</i><sub><i>D</i></sub> = 1.530 and LTEC = 56 (α × 10 <sup>– 7</sup> K<sup>– 1</sup>) were obtained while maintaining chemical stability with respect to water the corresponding hydrolytic class I.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 11-12","pages":"513 - 516"},"PeriodicalIF":0.6,"publicationDate":"2024-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140810330","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sintering of Amorphous Al(OH)3 Using Cold Isostatic Pressing 利用冷等静压烧结无定形 Al(OH)3
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-04-29 DOI: 10.1007/s10717-024-00645-6
S. Yu. Prilipko, G. K. Volkova, L. V. Loladze, I. I. Bryukhanova, G. N. Golovan, V. A. Glazunova
{"title":"Sintering of Amorphous Al(OH)3 Using Cold Isostatic Pressing","authors":"S. Yu. Prilipko,&nbsp;G. K. Volkova,&nbsp;L. V. Loladze,&nbsp;I. I. Bryukhanova,&nbsp;G. N. Golovan,&nbsp;V. A. Glazunova","doi":"10.1007/s10717-024-00645-6","DOIUrl":"10.1007/s10717-024-00645-6","url":null,"abstract":"<p>It was found that the high decomposition temperature of amorphous Al(OH)<sub>3</sub> makes it possible to sinter corundum ceramics directly from aluminum hydroxide, bypassing the stage of its preliminary thermal dehydration. Using the cold isostatic pressing method at 200, 600, and 1000 MPa, compacts with densities of 62, 69, and 79% of the theoretical value were obtained. The temperature dependence of the shrinkage of amorphous Al(OH)<sub>3</sub> compacts was studied as a function of the cold isostatic pressing pressure. An area of intense shrinkage was discovered in the range 1050 – 1150°C, which coincides with both the temperature of complete decomposition of amorphous Al(OH)<sub>3</sub> and the transition γ → α-Al<sub>2</sub>O<sub>3</sub>.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 11-12","pages":"521 - 523"},"PeriodicalIF":0.6,"publicationDate":"2024-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140810335","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Local Analysis of Birefringence in Ion-Exchange Strengthened Glass 离子交换强化玻璃中双折射的局部分析
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-04-29 DOI: 10.1007/s10717-024-00634-9
S. S. Fedotov, V. I. Savinkov, Yu. I. Mashir, A. I. Ozerova, A. S. Naumov, I. A. Veselov, E. H. Mamadzhanova, M. Z. Ziyatdinova, V. N. Sigaev
{"title":"Local Analysis of Birefringence in Ion-Exchange Strengthened Glass","authors":"S. S. Fedotov,&nbsp;V. I. Savinkov,&nbsp;Yu. I. Mashir,&nbsp;A. I. Ozerova,&nbsp;A. S. Naumov,&nbsp;I. A. Veselov,&nbsp;E. H. Mamadzhanova,&nbsp;M. Z. Ziyatdinova,&nbsp;V. N. Sigaev","doi":"10.1007/s10717-024-00634-9","DOIUrl":"10.1007/s10717-024-00634-9","url":null,"abstract":"<p>The local Abrio method of birefringence assessment was applied for the first time to strengthened glasses, and it was used to investigate the micro-stress distribution in float glass subjected to ion-exchange strengthening. It is demonstrated that the thickness of the stressed layer can be determined with great precision, and a correlation is found between the depth of the stressed layer and the penetration depth of potassium cations in the course of ion exchange.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 11-12","pages":"460 - 463"},"PeriodicalIF":0.6,"publicationDate":"2024-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140810292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Eutectic Additive Influence in the Li2O–B2O3 System on the Sintering Process and Properties of Li2MgTi3O8 Ceramics Li2O-B2O3 体系中的共晶添加剂对 Li2MgTi3O8 陶瓷烧结工艺和性能的影响
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-04-29 DOI: 10.1007/s10717-024-00633-w
V. D. Stolyarov, O. E. Shubabko, D. I. Vershinin
{"title":"Eutectic Additive Influence in the Li2O–B2O3 System on the Sintering Process and Properties of Li2MgTi3O8 Ceramics","authors":"V. D. Stolyarov,&nbsp;O. E. Shubabko,&nbsp;D. I. Vershinin","doi":"10.1007/s10717-024-00633-w","DOIUrl":"10.1007/s10717-024-00633-w","url":null,"abstract":"<p>The effect of the eutectic additive of the system Li<sub>2</sub>O–B<sub>2</sub>O<sub>3</sub> on the sintering process and the dielectric properties of Li<sub>2</sub>MgTi<sub>3</sub>O<sub>8</sub>-based ceramics was studied. It was found that the introduction of an additive in amounts 10.0 – 15.0% promotes sintering of ceramics by means of a liquid-phase mechanism. Li<sub>2</sub>MgTi<sub>3</sub>O<sub>8</sub>-based ceramic, containing a sintering additive in the amount 15.0% and fired at 900°C, demonstrates the following property levels: average density ρ<sub>av</sub> = 3.04 g/cm<sup>3</sup>, open porosity P<sub>o</sub> = 5.7%, relative dielectric constant ε<sub><i>r</i></sub> = 19.0, and dielectric loss tangent tan δ = 0.028. The lowered sintering temperature of the ceramic will allow the manufacture of different electronic components based on it, using low-temperature co-firing ceramic (LTCC) technology, and the a specified level of dielectric properties will allow the miniaturization of devices.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 11-12","pages":"455 - 459"},"PeriodicalIF":0.6,"publicationDate":"2024-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140810289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of a Method for Manufacturing Easily Removable Ceramic Rods for Lost Waste Casting 开发一种用于废料铸造的易脱陶瓷棒的制造方法
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-04-29 DOI: 10.1007/s10717-024-00644-7
V. V. Punkaev, A. A. Yukseeva, N. P. Ouglev
{"title":"Development of a Method for Manufacturing Easily Removable Ceramic Rods for Lost Waste Casting","authors":"V. V. Punkaev,&nbsp;A. A. Yukseeva,&nbsp;N. P. Ouglev","doi":"10.1007/s10717-024-00644-7","DOIUrl":"10.1007/s10717-024-00644-7","url":null,"abstract":"<p>The main commercial method of preparing precision metal parts with a high surface finish, for example, the blades of a turbo-ram jet engine, is lost waste casting. On preparing a wax model, a ceramic immuring element (rod) is placed in side the model in order to form cavities of complex shape, intended to reduce the mass of the casting and for forming channel of the cooling system of the blades cooled by the secondary air flow after a rod is removed. The main technological problems on removal of the inner rods are their strength and high chemical inertness, as a result of which their removal time and labor costs are quite large. This article investigates a method of preparing ceramic rods whose strength is not uniform along depth, which makes it possible, first of all, to remove (quite easily) the soft center and then to dissolve the stronger periphery.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 11-12","pages":"517 - 520"},"PeriodicalIF":0.6,"publicationDate":"2024-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140810290","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
YAG-Ceramic Powders — Size-Reduction Influence on Optical Ceramic Properties YAG 陶瓷粉末--尺寸缩小对光学陶瓷特性的影响
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-04-29 DOI: 10.1007/s10717-024-00637-6
V. E. Suprunchuk, A. A. Kravtsov, V. A. Lapin, V. A. Tarala, L. V. Tarala, E. V. Medyanik, F. F. Malyavin
{"title":"YAG-Ceramic Powders — Size-Reduction Influence on Optical Ceramic Properties","authors":"V. E. Suprunchuk,&nbsp;A. A. Kravtsov,&nbsp;V. A. Lapin,&nbsp;V. A. Tarala,&nbsp;L. V. Tarala,&nbsp;E. V. Medyanik,&nbsp;F. F. Malyavin","doi":"10.1007/s10717-024-00637-6","DOIUrl":"10.1007/s10717-024-00637-6","url":null,"abstract":"<p>The morphology and degree of agglomeration of the precursor and YAG-ceramic powders were investigated as functions of the grinding conditions, followed by an assessment of the influence of these parameters on the optical properties and structure of the ceramic. YAG-precursor powders were obtained by chemical coprecipitation. The morphology and size of the agglomerates and crystallites were assessed by means of scanning electron microscopy, laser diffraction analysis, x-ray diffraction analysis, and Brunauer–Emmett–Teller gas adsorption. It was discovered that grinding of the YAG precursor powders can decrease the degree of agglomeration of the ceramic powder. It was found that with a mass ratio of grinding balls to precursor powder of 6.75/1 and a mass ratio of the grinding medium to the mass of the precursor powder of 4.5/1, optimal conditions obtain for providing the necessary granulometric characteristics and the highest mono-dispersity. In summary, by such means the properties of YAG optical ceramic can be improved by using of an additional grinding stage for the powders synthesized by chemical deposition and by selecting suitable grinding modes.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 11-12","pages":"479 - 486"},"PeriodicalIF":0.6,"publicationDate":"2024-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140810331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of the Vacuum Sintering Kinetics of the Optical Luminescent Ceramic Y3–xScxAl5O12:Cr 光学发光陶瓷 Y3-xScxAl5O12:Cr 的真空烧结动力学研究
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-04-27 DOI: 10.1007/s10717-024-00635-8
V. A. Lapin, V. E. Suprunchuk, V. A. Tarala, D. S. Vakalov, A. A. Kravtsov, F. F. Malyavin, L. V. Tarala, E. V. Medyanik, L. V. Kozhitov
{"title":"Investigation of the Vacuum Sintering Kinetics of the Optical Luminescent Ceramic Y3–xScxAl5O12:Cr","authors":"V. A. Lapin,&nbsp;V. E. Suprunchuk,&nbsp;V. A. Tarala,&nbsp;D. S. Vakalov,&nbsp;A. A. Kravtsov,&nbsp;F. F. Malyavin,&nbsp;L. V. Tarala,&nbsp;E. V. Medyanik,&nbsp;L. V. Kozhitov","doi":"10.1007/s10717-024-00635-8","DOIUrl":"10.1007/s10717-024-00635-8","url":null,"abstract":"<p>The intent of this work is to investigate the influence of scandium occupying dodecahedral and octahedral positions of the garnet crystal lattice on the aspects of vacuum sintering of the optical ceramic Y<sub>3–<i>x</i></sub>Sc<sub><i>x</i></sub>Al<sub>2–<i>y</i></sub>Sc<sub><i>y</i></sub>Al<sub>3</sub>O<sub>12</sub>:Cr as well as on its optical and luminescent properties. As part of this investigation, YSAG:Cr optical luminescent ceramic was produced for the first time from ceramic powders of metastable compositions with a high content of scandium in the dodecahedral position. The compositions considered were described by the general formula Y<sub>3</sub><sub>–<i>x</i></sub>Sc<sub><i>x</i></sub>Al<sub>2–<i>y</i></sub>Sc<sub><i>y</i></sub>Al<sub>3</sub>O<sub>12</sub>, where 0.12 ≤ <i>x</i> ≤ 1.50 and 0.08 ≤ <i>y</i> ≤ 1.00 p.u. [physical units] with total scandium content 0.12 – 1.70 p.u. The following investigations of YSAG:Cr ceramic samples were conducted: x-ray diffractometry, measurement of the shrinkage kinetics of ceramic compacts using dilatometry, and investigation of the morphology and elemental composition of the ceramic surface by means of scanning electron microscopy. The spectra of light transmission and luminescence were measured. It was shown that ceramic made from compositions with scandium content predominating in the dodecahedral positions reach maximum density at lower temperatures compared to compositions containing a larger amount of scandium in the octahedral positions. It was found that as the sintering temperature of YSAG:Cr ceramic increases, compositions with a high content of scandium in the dodecahedral position become unstable.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 11-12","pages":"464 - 471"},"PeriodicalIF":0.6,"publicationDate":"2024-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140810326","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A New Alternative Source of Clay Raw Materials for Ceramic Materials Based on the Muddy Deposits in Water-Reservoirs 基于水库泥质矿床的陶瓷材料粘土原料新替代来源
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-04-27 DOI: 10.1007/s10717-024-00646-5
Z. M. Kuryazov, Z. R. Kadyrova, A. M. Eminov
{"title":"A New Alternative Source of Clay Raw Materials for Ceramic Materials Based on the Muddy Deposits in Water-Reservoirs","authors":"Z. M. Kuryazov,&nbsp;Z. R. Kadyrova,&nbsp;A. M. Eminov","doi":"10.1007/s10717-024-00646-5","DOIUrl":"10.1007/s10717-024-00646-5","url":null,"abstract":"<p>The possibility of obtaining a new alternative source of clay raw materials for making ceramic materials based on muddy deposits, possessing functional properties, from reservoirs is considered. The physicochemical properties of sediments from the muddy bottom of the Tuyamuyun reservoir in Uzbekistan were studied. It was found that the ceramic bodies developed based on the dual muddy-kaolin composition can be used to produce ceramic materials intended for construction.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 11-12","pages":"524 - 528"},"PeriodicalIF":0.6,"publicationDate":"2024-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140810333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Transparent Lithium-Aluminum-Silicate Glass-Ceramics (Overview) 透明锂铝硅酸盐玻璃陶瓷(概述)
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-04-27 DOI: 10.1007/s10717-024-00639-4
A. S. Naumov, V. N. Sigaev
{"title":"Transparent Lithium-Aluminum-Silicate Glass-Ceramics (Overview)","authors":"A. S. Naumov,&nbsp;V. N. Sigaev","doi":"10.1007/s10717-024-00639-4","DOIUrl":"10.1007/s10717-024-00639-4","url":null,"abstract":"<p>Methods of laser micro- and nano-modification of the structure of transparent dielectrics offer much for the creation of a new type of glass-crystalline materials and new applications. In the present work, after a brief excursion into the history of glass-ceramics, transparent aluminosilicate sitalls [glass-ceramics] are discussed, mainly for the example of the Li<sub>2</sub>O–Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub> system, and the areas of their new applications. The recently discovered possibilities of laser micro-modification of the structure of sitalls and the writing of elements of photonics and integrated optics in their interior volume are considered. Special attention is given to transparent glass-ceramics with thermal expansion coefficient close to zero.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 11-12","pages":"491 - 499"},"PeriodicalIF":0.6,"publicationDate":"2024-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140810396","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ceramic and Refractory Materials Based on it — a Review. Part 1: Methods of the Synthesis of Calcium Zirconate 陶瓷及其耐火材料 - 综述。第 1 部分:锆酸钙的合成方法
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-04-27 DOI: 10.1007/s10717-024-00648-3
B. L. Krasnyi, N. A. Makarov, K. I. Ikonnikov, D. O. Lemeshev, D. D. Bernt, A. L. Galganova, A. S. Cizova, O. I. Rodimov
{"title":"Ceramic and Refractory Materials Based on it — a Review. Part 1: Methods of the Synthesis of Calcium Zirconate","authors":"B. L. Krasnyi,&nbsp;N. A. Makarov,&nbsp;K. I. Ikonnikov,&nbsp;D. O. Lemeshev,&nbsp;D. D. Bernt,&nbsp;A. L. Galganova,&nbsp;A. S. Cizova,&nbsp;O. I. Rodimov","doi":"10.1007/s10717-024-00648-3","DOIUrl":"10.1007/s10717-024-00648-3","url":null,"abstract":"<p>The publication presents general information on calcium zirconate and the physical/chemical properties of products based on it. Methods for CaZrO<sub>3</sub> production, such as solid phase synthesis, electric arc fusion, codeposition, hydrothermal synthesis, etc. are studied.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 11-12","pages":"535 - 541"},"PeriodicalIF":0.6,"publicationDate":"2024-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140812874","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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