Energy Storage Materials最新文献

{"title":"The rise of an intelligent partner: How machine learning is reshaping electrolyte research and development","authors":"Yifan Hao ,&nbsp;Yun Su ,&nbsp;Zhenwei Zhu ,&nbsp;Weijie Sun ,&nbsp;Lujia Zhou ,&nbsp;Jingyi Qiu ,&nbsp;Xiaoxu Wang ,&nbsp;Bin Deng ,&nbsp;Haiming Hua ,&nbsp;Jun Ming ,&nbsp;Xiangming He ,&nbsp;Hao Zhang","doi":"10.1016/j.ensm.2026.105134","DOIUrl":"10.1016/j.ensm.2026.105134","url":null,"abstract":"<div><div>The development of high-performance electrolytes for advanced lithium batteries is pivotal for the energy transition but remains hindered by the inefficiencies of traditional trial-and-error approaches. The intricate balance among energy density, safety, and cycle life constitutes a complex multi-objective optimization problem that challenges conventional methods. Recently, machine learning (ML) has emerged as a transformative tool, shifting the electrolyte research paradigm from experience-driven to data-model-driven design. This review systematically outlines the progression of ML in electrolyte research, commencing with its role in high-throughput screening and performance prediction. We highlight the recent advent of generative models for de novo molecular design and the establishment of closed-loop \"dry-wet\" experimental systems, which achieve weekly iterative optimization. These advancements are poised to accelerate the discovery of electrolytes tailored for next-generation batteries. Finally, we critically discuss the persisting challenges, such as data standardization, multi-scale modeling, and human-machine collaboration, and propose feasible solutions to pave the way for an intelligent and autonomous future in electrolyte innovation.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"88 ","pages":"Article 105134"},"PeriodicalIF":20.2,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147719725","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Multiscale insights into intragranular cracking mechanisms in Ni-rich single-crystal layered oxide cathodes","authors":"Huazhang Zhou ,&nbsp;Zenghua Tian ,&nbsp;Peng Gao ,&nbsp;Yongming Zhu ,&nbsp;Xudong Li ,&nbsp;Liguang Wang","doi":"10.1016/j.ensm.2026.105175","DOIUrl":"10.1016/j.ensm.2026.105175","url":null,"abstract":"<div><div>Intragranular cracking has emerged as a dominant degradation pathway in Ni-rich single-crystal LiNi_xCo_yMn_1-x-yO₂ (SC-NCM) cathodes, driving structural fragmentation and irreversible capacity fading. Despite its critical impact on long-term performance, the mechanistic origins of crack nucleation and growth—and their interplay with existing mitigation strategies—remain insufficiently understood, constituting a major barrier to further materials optimization. In this review, we provide a comprehensive analysis of the chemical, mechanical, and electro-chemo-mechanical factors that govern intragranular crack formation and propagation in Ni-rich SC-NCM. We critically examine current crack-suppression strategies and elucidate the mechanistic principles underlying their effectiveness. Remaining challenges are highlighted, and we outline opportunities for integrating advanced in situ/operando characterization with multiscale, non-destructive imaging, and artificial intelligence-enabled predictive modeling. Together, these approaches offer a promising pathway toward resolving intragranular cracking and accelerating the commercial realization of next-generation, high-energy-density lithium-ion batteries.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"88 ","pages":"Article 105175"},"PeriodicalIF":20.2,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147850384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Precision functional group engineering in solid-state polymer electrolytes for lithium-metal batteries","authors":"Tianyou Lan ,&nbsp;Yupeng Feng ,&nbsp;Miao He ,&nbsp;Wang Xu ,&nbsp;Yang Yin ,&nbsp;Yuhan Li ,&nbsp;Fei Li ,&nbsp;Wei Xiang ,&nbsp;Jianping Long ,&nbsp;Anjun Hu","doi":"10.1016/j.ensm.2026.105153","DOIUrl":"10.1016/j.ensm.2026.105153","url":null,"abstract":"<div><div>Lithium metal batteries (LMBs) promise exceptionally high energy density, but their practical deployment is constrained by the safety issues and instability of liquid electrolytes. Solid-state polymer electrolytes (SSPEs) improve safety and manufacturability, yet remain bottlenecked by coupled trade-offs among room-temperature ionic conductivity, Li⁺ transference number, and interfacial-mechanical integrity. This review provides a functional-group-centric framework that links molecular chemistry (e.g., polarity, electronic inductive effects, and sterics) to salt dissociation, solvation structures, ion-transport pathways, and interphase chemistry, thereby enabling rational “bottom-up” SSPE design. We systematically classify functional motifs by their dominant roles in: (i) promoting ion dissociation and conduction, (ii) immobilizing anions to increase the Li⁺ transference number, (iii) enhancing mechanical robustness, (iv) regulating electrode-electrolyte interfaces and electrochemical stability, and (v) improving thermal safety. Beyond single-function optimization, we distill synergistic design rules that overcome conflicting properties, and highlight how advanced polymer topologies and architectures (e.g., crosslinked/interpenetrating networks and brush/star/hyperbranched systems) amplify functionality through spatial partitioning and emergent transport-mechanical coupling. By bridging molecular design principles with macroscopic performance, this review demonstrates how rational functional group engineering can accelerate the transition of SSPEs from laboratory research to commercially viable solutions for next-generation LMBs.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"88 ","pages":"Article 105153"},"PeriodicalIF":20.2,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147798647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Realizing anion/ cation co-storage via forming -C-S-C- bonds in sulfur-doped graphitized carbon for high capacity cathode of dual-ion battery","authors":"Yuecong Chen ,&nbsp;Shiyin Xie ,&nbsp;Yining Lao ,&nbsp;Pengwei Jing ,&nbsp;Pengyu Liu ,&nbsp;Pei Tang ,&nbsp;Zhancai Qiu ,&nbsp;Shaofeng Chen ,&nbsp;Dongcheng Chen ,&nbsp;Cuiying Lu ,&nbsp;Bingjun Yang ,&nbsp;Jian Zhu ,&nbsp;Qingyun Dou ,&nbsp;Xingbin Yan","doi":"10.1016/j.ensm.2026.105156","DOIUrl":"10.1016/j.ensm.2026.105156","url":null,"abstract":"<div><div>Dual-ion batteries represent a promising energy storage technology, but suffer from low specific capacity of conventional graphite cathode -due to their single anion storage capability. Here, to break the capacity limit coming from anion storage, we propose a structural design strategy involving sulfur doping within the carbon lattice (forming -C-S-C- bonds) to enable the co-storage of both anions and cations. The introduction of sulfur atoms expands the interlayer spacing of the graphitized carbon cathode and enhances its electrical conductivity, thereby improving anion storage. More importantly, -C-S-C- bonds can reversibly react with Li⁺ to form Li₂S during discharging, and release Li⁺ to reestablish the -C-S-C- bonds during charging, thereby enabling the storage of lithium ions in the cathode. Leveraging this unique energy storage mechanism, the built dual-ion battery demonstrates an unprecedented high specific capacity (280 mAh g⁻¹ at 50 mA g⁻¹), excellent rate capability (125 mAh g⁻¹ at 500 mA g⁻¹), and outstanding cycling stability (no significant degradation after over 2700 cycles). This work provides a simple and reliable strategy for designing high-capacity cathodes for dual-ion batteries.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"88 ","pages":"Article 105156"},"PeriodicalIF":20.2,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147798648","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Architecting catalytic negative electrodes for practical vanadium flow batteries: From preloading to in-situ construction","authors":"Yizhe Nie ,&nbsp;Lihong Yu ,&nbsp;Zuo Wang ,&nbsp;Annan Gao ,&nbsp;Le Liu ,&nbsp;Jingyu Xi","doi":"10.1016/j.ensm.2026.105176","DOIUrl":"10.1016/j.ensm.2026.105176","url":null,"abstract":"<div><div>Vanadium flow battery (VFB) is promising for grid-scale energy storage, yet the negative electrode remains a major bottleneck because sluggish V³⁺/V²⁺ kinetics and the hydrogen evolution reaction (HER) jointly limit efficiency, usable capacity, and cycling stability. Existing reviews mainly compare catalyst identities and electrochemical metrics, whereas the catalyst-loading route itself governs catalyst distribution in three-dimensional felts, manufacturability, maintenance mode, and cost-scaling from laboratory cells to commercial stacks. This Review uses metal-based multifunctional catalytic layers as a representative platform to compare two routes for catalytic negative electrodes: preloading before cell assembly and in-situ construction from electrolyte-borne metal ions during operation. We first organize an evidence framework for electrode evaluation, highlighting operando and spatially resolved diagnostics that distinguish catalyst-related improvements from changes in wetting and mass transport and directly detect HER in porous felts. We then analyze representative preloaded and in-situ-constructed metal systems and show that the two routes follow fundamentally different techno-economic logics: preloading is constrained by area-dependent fabrication, uniformity control, and refurbishment burdens, whereas in-situ construction shifts the intervention toward low-dose electrolyte additives, electrochemical conditioning, and operation-integrated maintenance. On this basis, we propose an application-oriented framework spanning activity, HER suppression, stability, cost-effectiveness, and scalability, and argue that in-situ construction is currently the more deployment-oriented pathway, while preloading remains indispensable for catalyst discovery and mechanistic validation.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"88 ","pages":"Article 105176"},"PeriodicalIF":20.2,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147850383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advanced solid-state NMR for cathode materials: Insights into local structure and ionic dynamics mechanisms in lithium- and sodium-ion batteries","authors":"Lina Gao ,&nbsp;Yaqin Liu ,&nbsp;Xueqian Kong","doi":"10.1016/j.ensm.2026.105163","DOIUrl":"10.1016/j.ensm.2026.105163","url":null,"abstract":"<div><div>This review synthesizes the pivotal role of advanced solid-state nuclear magnetic resonance (SSNMR) in characterizing high-performance lithium- and sodium-ion battery cathodes. While diffraction-based techniques are often constrained by long-range order requirements, SSNMR leverages the unique chemical shift and hyperfine interactions to resolve the local atomic and electronic landscapes of paramagnetic cathode materials. We examine critical methodological innovations, such as ultrafast magic angle spinning and multi-dimensional experiments, which are essential for mitigating paramagnetic broadening and achieving high-resolution spectra. Furthermore, we discuss the integration of operando SSNMR as a powerful tool for the real-time observation of electrochemical pathways and structural evolution under realistic cycling conditions. The review systematically explores applications across layered oxides (oxygen redox and structural evolution), disordered rock-salts (lattice fluorination), and polyanionic frameworks (multi-electron transfer and ion dynamics). Finally, we outlook the future potential of dynamic nuclear polarization and DFT-integrated machine learning in decoding complex interfacial phenomena and structural heterogeneities.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"88 ","pages":"Article 105163"},"PeriodicalIF":20.2,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147798036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Achieving highly reversible and energy-intensive cathodes in aqueous zinc-iodine batteries: The electrolyte pathway","authors":"Xincheng Liang,&nbsp;Qian Liu,&nbsp;Mengke Hou,&nbsp;Yupu Wei,&nbsp;Yifan Du,&nbsp;Yuquan Gou,&nbsp;Huan Wen,&nbsp;Shibin Yin","doi":"10.1016/j.ensm.2026.105158","DOIUrl":"10.1016/j.ensm.2026.105158","url":null,"abstract":"<div><div>Aqueous zinc-iodine batteries (AZIBs) exhibit intrinsic safety, cost-effectiveness, extended service life, and environmental sustainability, demonstrating promising application prospects. Nevertheless, the sluggish kinetics of iodine conversion reactions, the “shuttle effect” of polyiodides, and the instability of high-valence iodine species in aqueous electrolytes limit their reversibility and energy density. By summarizing the recent advances in electrolytes for AZIBs, including material design and mechanistic investigations, this review provides a comprehensive overview of energy storage mechanisms based on iodine conversion chemistry, emphatically analyzes the underlying roots of the above challenges, and highlights the critical role of electrolyte optimization in enhancing the reversibility and energy density of AZIBs. Building on these insights, guidelines and future research directions for AZIBs are proposed. This review aims to provide a valuable reference for developing AZIBs and facilitating their commercial applications.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"88 ","pages":"Article 105158"},"PeriodicalIF":20.2,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147850382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Emerging polymer-based electrolytes for coordination-mediated ion transport and interface stabilization in solid-state lithium batteries","authors":"Fangqi Zhan ,&nbsp;Tong Wu ,&nbsp;Yingjie Wang ,&nbsp;Wenqing Sun ,&nbsp;Yuxiang Bai ,&nbsp;Kaiyang Zhang ,&nbsp;Pengfei Huo ,&nbsp;Jitao Huang ,&nbsp;Zhong Jin ,&nbsp;Wen-Yong Lai ,&nbsp;Qian Wang ,&nbsp;Shi Wang","doi":"10.1016/j.ensm.2026.105180","DOIUrl":"10.1016/j.ensm.2026.105180","url":null,"abstract":"<div><div>All-solid-state lithium batteries are pivotal for next-generation energy storage, yet their development is hampered by the intrinsic limitations of polymer-based electrolytes, such as low ionic conductivity and interfacial instability. The coordination chemistry of ions—particularly lithium ion and the corresponding anions—with functional groups governs ion transport and interface regulation in polymer electrolytes. Despite considerable advances in this field, systematic analysis from a coordination chemistry perspective remains notably scarce. This review aims to establish a coherent framework that connects molecular-level design to macroscopic electrolyte properties via coordination chemistry. Specifically, it outlines the ion-coordination mechanisms in conventional polyether-based electrolytes and advances to discuss modern polymer design strategies that modulate ion transport through alternative coordination chemistries, including the use of competitive units (e.g., heterometallic ions, organic cations), polymer functionalization with charged/zwitterionic groups, and solvation structure engineering derived from high-concentration electrolytes. Furthermore, the latest and most representative polymer-based electrolyte systems from the perspective of their coordination structure and interface behavior are organized and presented, highlighting their unique merits and underlying principles. Finally, a forward-looking perspective is articulated, exploring promising directions such as precise electrolyte customization for specific battery configurations, on-demand synthesis of functional polymers, and the development of new coordination-assisted interfacial layers. Serving as a bridge between theory and practice, this review consolidates key insights to guide the development of next-generation polymer-based electrolytes for solid-state batteries.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"88 ","pages":"Article 105180"},"PeriodicalIF":20.2,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147850309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Oxygen-site engineering guided bonding coupling and intrinsic distortion: Enabling high-rate long-lasting Zn-MnO2 batteries","authors":"Ningkang Zhang ,&nbsp;Zhiyuan Jiang ,&nbsp;Zizheng Ai ,&nbsp;Xiaolong Xu ,&nbsp;Enyan Guo ,&nbsp;Qifang Lu ,&nbsp;Dong Shi ,&nbsp;Meiling Huang ,&nbsp;Zhiliang Xiu ,&nbsp;Yongzhong Wu ,&nbsp;Weidong He ,&nbsp;Xiaopeng Hao","doi":"10.1016/j.ensm.2026.105155","DOIUrl":"10.1016/j.ensm.2026.105155","url":null,"abstract":"<div><div>Manganese oxides are widely recognized as promising cathodes for grid-scale aqueous zinc-ion batteries (AZIBs) owing to their cost benefit and excellent capacity, but the notorious Jahn-Teller effect and sluggish diffusion kinetics, especially at high current-density, inducing severe structural collapse, poor cycleability and limited rate during repeated switching between active Mn³⁺ and non-active Mn⁴⁺. Herein, we introduce intrinsic distortion and new bonding structure (P-O-Mn bridging linkages and Mn-S bonds) into δ-MnO₂ via oxygen-site engineering based on P and S heteroatom collaborative modification for constructing MnO₂ cathode with high reactivity, rich defects and low-valence Mn. The intrinsic distortion in MnO₂ matrix and electrochemical heterointerface caused by bonding structure coupling suppress J-T distortion and interface side reactions during cycling, enhancing recyclability and structural stability. Furthermore, tailored MnO₂ cathode selectively accelerates Zn²⁺ (Mn-S bond as main function) and H⁺ (bridging linkage as main function) transport kinetics while enhancing electron transport capability, leading to better rate performance. As a result, tailored Zn-MnO₂ cell delivers high-rate endurance (192.5 mAh g^-1 at 10 A g^-1) and long-lasting stability (96% capacity retention over 4500 cycles at 10 A g^-1). Our work highlights the significant promise of distortion engineering and bonding chemistry for optimizing cathode in practical Zn batteries.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"88 ","pages":"Article 105155"},"PeriodicalIF":20.2,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147736183","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Engineering Disorder: Entropy as a Design Lever for Stable Interfaces in Solid-state Sodium-metal Batteries","authors":"Arindam Chatterjee ,&nbsp;Dipsikha Ganguly ,&nbsp;Seeram Ramakrishna ,&nbsp;Subramshu S. Bhattacharya ,&nbsp;Kingshuk Roy","doi":"10.1016/j.ensm.2026.105168","DOIUrl":"10.1016/j.ensm.2026.105168","url":null,"abstract":"<div><div>Solid-state sodium-metal batteries (SSSMBs) promise a rare combination of high energy density, enhanced safety, and elemental abundance. Yet, their progress is repeatedly stalled not by bulk properties, but by a far more elusive barrier: the interface. Across oxide, sulfide, and halide electrolytes, electrochemical degradation, space-charge polarization, and contact failure continue to limit performance; often irreversibly. This review reframes the interface not as a passive boundary to be tolerated, but as an active, designable medium that dictates long-term stability. We critically dissect how ion transport, chemical reactivity, and interphase mechanics evolve under realistic cycling conditions, and show that conventional fixes, such as thin film coatings, wetting agents, and buffer layers, offer only fragmented relief. In contrast, we spotlight configurational entropy as a powerful, underexploited tool to systematically modulate interfacial behaviour. Through compositional complexity, entropy rich architectures can flatten potential gradients, localize electron exclusion, and foster self-limiting passivation, while preserving Na⁺ mobility. We unify these insights across electrolyte chemistries, benchmark interfacial performance under practical constraints, and offer a roadmap for building reproducible, scalable, and high rate SSSMBs. This review does not merely summarize a field; it sharpens its focus and proposes a new scientific language for tackling one of energy storage’s most persistent bottlenecks.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"89 ","pages":"Article 105168"},"PeriodicalIF":20.2,"publicationDate":"2026-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147827437","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}