Energy Storage Materials最新文献

Phase engineering enables ultrahigh-capacity 1T/2H-MoS2 for advanced ammonium-ion storage

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2025-01-25 DOI: 10.1016/j.ensm.2025.104063

Xinyu Qi, Yirong Zhu, Yuting Xu, Wenhao Chen, Zhongliang Hu, Liujiang Xi, Yujia Xie, Hongshuai Hou, Guoqiang Zou, Xiaobo Ji

{"title":"Phase engineering enables ultrahigh-capacity 1T/2H-MoS2 for advanced ammonium-ion storage","authors":"Xinyu Qi, Yirong Zhu, Yuting Xu, Wenhao Chen, Zhongliang Hu, Liujiang Xi, Yujia Xie, Hongshuai Hou, Guoqiang Zou, Xiaobo Ji","doi":"10.1016/j.ensm.2025.104063","DOIUrl":"https://doi.org/10.1016/j.ensm.2025.104063","url":null,"abstract":"The aqueous ammonium ion batteries (AIBs) have recently drawn increasing concern due to their many advantages. However, the low capacity, poor rate performance and unstable structure of anode materials largely affect the overall performance of AIBs, thereby impeding their further development. Herein, inspired by DFT calculations, the MoS2 nanoflowers with 1T/2H hybrid crystal phase are designed by phase engineering strategy, and utilized as anode materials for aqueous AIBs for the first time. DFT calculations and experiments reveal that 1T/2H-MoS2 possesses an enlarged interlayer spacing, better electronic conductivity, and smaller diffusion energy barrier than 2H-MoS2 after the introduction of 1T phase, thus achieving an ultrahigh specific capacity (225.7 mAh g−1 at 0.1 A g−1) and splendid rate capability (100.0 mAh g−1 at 2.0 A g−1), which surpass the most metal-based anode materials in aqueous AIBs. Additionally, systematical ex-situ characterizations are utilized to illustrate the energy storage mechanism of NH4+ insertion/extraction in 1T/2H-MoS2 accompanied by H-bond formation/breaking and reversible transition of 1T/2H. This research not only offers a good strategy for designing and developing high-performance AIBs anode materials, but also provides valuable theoretical guidance for future exploration of their energy storage mechanism.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"29 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143031172","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Unveiling the potential of high-entropy materials toward high-energy metal batteries based on conversion reactions: synthesis, structure, properties, and beyond 揭示了基于转化反应的高能金属电池的高熵材料的潜力：合成、结构、性质等

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2025-01-23 DOI: 10.1016/j.ensm.2025.104054

Mingyu Lian, Weihao Gong, Shaofei Guo, Ying Jiang, Zhengqing Ye

{"title":"Unveiling the potential of high-entropy materials toward high-energy metal batteries based on conversion reactions: synthesis, structure, properties, and beyond","authors":"Mingyu Lian, Weihao Gong, Shaofei Guo, Ying Jiang, Zhengqing Ye","doi":"10.1016/j.ensm.2025.104054","DOIUrl":"https://doi.org/10.1016/j.ensm.2025.104054","url":null,"abstract":"The sluggish conversion reaction and uncontrolled dendrite growth inhibit the development of rechargeable metal batteries with high energy density and environmental friendliness. Thanks to the four core effects, high entropy (HE) materials have gained tremendous attention in rechargeable metal batteries based on conversion reactions toward resolving the above issues. Although the brilliance of HE materials in conversion reaction metal batteries, there is still lacking a comprehensive review to discuss the present status and challenges inherent to HE materials in rechargeable metal batteries based on conversion reactions. Herein, this review provides a comprehensive overview of structural characteristics, intrinsic properties, prevalent synthetic methodologies, characterization techniques, computational modeling, and diversified applications of HE materials in the realm of rechargeable metal batteries based on conversion reactions. In particular, we comprehensively summarize state-of-the-art research progress and highlight critical strategies in the rational design of advanced HE materials toward rechargeable metal batteries based on conversion reactions (Li-S, Li-air, Li-CO2, and Zn-air batteries) including metal anode, cathode materials, and electrocatalysts from both experimental and calculational aspects. Finally, we outline the remaining challenges and future perspectives in the synthesis, characterization, and theoretical simulations of high-entropy metal battery materials based on conversion reactions.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"50 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143020880","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Unveiling the Mysteries of Anode-Free Zn Metal Batteries: From key challenges to viable solutions 揭开无阳极锌金属电池的奥秘：从关键挑战到可行的解决方案

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2025-01-23 DOI: 10.1016/j.ensm.2025.104056

Ying Li, Jing-Yu Wang, Jun-Wei Yin, Peng-Fei Wang, Zong-Lin Liu, Jie Shu, Ting-Feng Yi

{"title":"Unveiling the Mysteries of Anode-Free Zn Metal Batteries: From key challenges to viable solutions","authors":"Ying Li, Jing-Yu Wang, Jun-Wei Yin, Peng-Fei Wang, Zong-Lin Liu, Jie Shu, Ting-Feng Yi","doi":"10.1016/j.ensm.2025.104056","DOIUrl":"https://doi.org/10.1016/j.ensm.2025.104056","url":null,"abstract":"The anode-free battery has garnered wide attention because of its high theoretical energy density, simplified structure, and minimal costs. Over the past few decades, the successful commercialization of lithium-ion batteries featuring lithium-free anodes—often referred to as “rocking-chair” lithium-ion batteries—has been prominently witnessed worldwide. Aqueous zinc-ion batteries (ZIBs) have attracted extensive interest among researchers for their safety, cost-effectiveness, environmental friendliness, and high ionic conductivity of the electrolyte. Nevertheless, the practical application of ZIBs is predominantly hindered by the dendritic growth of Zn metal anodes, leading to poor cycling stability and potential safety concerns. Therefore, the development of aqueous ZIBs anodes utilizing zinc-free metal materials to replace traditional zinc metal anodes represents a significant advancement. Moreover, comprehensive reviews on this topic are scarce. In this context, we systematically review the emerging Zn-free “rocking-chair” ZIBs (ZFIBs) that employ zinc-based alloy anodes as substitutes for zinc metal anodes. Initially, we introduce the fundamental principles, advantages, and challenges associated with ZFIBs. Subsequently, we provide an overview of the design principles and recent advancements in ZFIBs featuring zinc-free anodes. The review encompasses the progress made in various types of zinc-free anode materials within aqueous ZFIBs, including metals/alloys, metal oxides, metal chalcogenides, MXene materials, organic compounds, in situ solid-electrolyte interphase film stable zinc-free anodes, and other zinc-free anodes. Finally, we offer insights on the future perspectives of “rocking-chair” ZIBs. It is our hope that this paper provides novel strategies for the design and development of zinc-free anodes.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"33 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143020885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The origin of the superior fast-charging performance of hybrid graphite/hard carbon anodes for Li-ion batteries 锂离子电池石墨/硬碳混合阳极优越快速充电性能的来源

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2025-01-22 DOI: 10.1016/j.ensm.2025.104053

Vishwas Goel, Kevin Masel, Kuan-Hung Cheng, Ammar Safdari, Neil P. Dasgupta, Katsuyo Thornton

引用次数: 0

An Ultra-stable Sodium Dual-ion Battery Based on S/Se Co-doped Covalent Organic Framework Anode with 12,000 Cycles Under Lean Electrolyte 贫电解质下基于S/Se共掺杂共价有机骨架阳极12000次循环的超稳定钠双离子电池

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2025-01-20 DOI: 10.1016/j.ensm.2025.104052

Hongzheng Wu, Shenghao Luo, Hubing Wang, Li Li, Xuenong Gao, Zhengguo Zhang, Wenhui Yuan

{"title":"An Ultra-stable Sodium Dual-ion Battery Based on S/Se Co-doped Covalent Organic Framework Anode with 12,000 Cycles Under Lean Electrolyte","authors":"Hongzheng Wu, Shenghao Luo, Hubing Wang, Li Li, Xuenong Gao, Zhengguo Zhang, Wenhui Yuan","doi":"10.1016/j.ensm.2025.104052","DOIUrl":"https://doi.org/10.1016/j.ensm.2025.104052","url":null,"abstract":"Sodium dual-ion batteries (SDIBs) employing covalent organic frameworks (COFs) as anode exhibit enormous application prospect and attract widespread attention for large-scale energy storage and conversion owing to the advantages of environment-friendly, cost-effective, and high-safety. However, achieving long-term cyclic stability and capacity retention at high current densities remains a huge challenge due to inherent low conductivity and kinetic limitations as well as severe solubility in electrolytes. Rational design of COFs with high conductivity, rapid redox kinetics, and structural stability is the key to improving their performance in SDIBs. Herein, a kind of S/Se co-doped COF is successfully designed and synthesized in which the co-doping effect significantly enhances stability and conductivity, improves the compatibility with electrolyte, facilitates the fast ion and electron transfer, and strengthens the adsorption capability for Na+. As anticipated, the constructed SDIBs not only deliver a high discharge capacity of up to 167.2 mAh g−1 and can cycle stably for 700 cycles at 2 C without degradation, but also achieve an ultra-long cycle life of 15,000 cycles at 20 C, with a capacity decay rate as low as 0.00045% per cycle. Moreover, a capacity retention of 89.2% corresponding to the normal electrolyte dosage and 12,000 ultra-stable cycles are realized even under lean electrolyte and demonstrate excellent fast-charging performance with extremely low self-discharge rate. The structural evolution of electrodes and the energy storage mechanism of DIBs are further revealed by in-situ characterization and theoretical calculations. This work expands the versatility of designing COFs with high redox activity, emphasizes the importance of heterogeneous element doping, and sheds novel insights on the construction of COFs-based materials for efficient Na+ storage.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"37 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142991422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Direct Observation of Li6PS5Cl–NMC Electrochemical Reactivity in All-Solid-State Cells 直接观察全固态电池中 Li6PS5Cl-NMC 的电化学反应活性

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2025-01-20 DOI: 10.1016/j.ensm.2025.104050

Paul Naillou, Adrien Boulineau, Eric De Vito, Enora Lavanant, Philippe Azaïs

{"title":"Direct Observation of Li6PS5Cl–NMC Electrochemical Reactivity in All-Solid-State Cells","authors":"Paul Naillou, Adrien Boulineau, Eric De Vito, Enora Lavanant, Philippe Azaïs","doi":"10.1016/j.ensm.2025.104050","DOIUrl":"https://doi.org/10.1016/j.ensm.2025.104050","url":null,"abstract":"Sulfide solid electrolytes have demonstrated some of the highest known lithium ion conductivities and are expected to participate in the incoming generation of all-solid-state lithium-ion batteries (ASSLIB). Amongst the best promising electrolytes, several lithium thiophosphates have been extensively studied for their outstanding performances. However, they also suffer from their narrow electrochemical stability window, leading to a range of various redox reactions during cycling when used in electrochemical cells. As a result, losses of capacity and increases of cell impedance are systematically observed. As already pointed out, Li6PS5Cl argyrodite-type electrolyte undergoes a series of decomposition reactions during cycling, previously investigated by several spectroscopic, electrochemical and DFT studies. However, this work provides a direct high resolution observation of the decomposition products of Li6PS5Cl and their spatial distribution in a composite cathode based on Ni-rich NMC compound (LiNixMnyCo1–x–yO2, x > 0.8) through scanning/ transmission electron microscopy (S/TEM). This study focuses on the understanding of the oxidative mechanisms and reports the detailed observations of LiCl, Li3PS4, P2S5, P2O5, NiSx and Li2O compounds.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"100 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142990300","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Polyanion-type iron-based sulfate cathode materials: from fundamental research to industrialization 多阴离子型铁基硫酸盐阴极材料：从基础研究到产业化

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2025-01-20 DOI: 10.1016/j.ensm.2025.104049

Xiaoyan Shi, Yun Wan, Zhiming Zhou, Wenxi Kuang, Xiaomin Chen, Jian Chen, Xunzhu Zhou, Junxiang Liu, Shulei Chou, Lin Li

引用次数: 0

Crossing the capacity threshold in Si-S batteries through mud-crack electrodes 通过泥裂电极跨越硅-硅电池的容量阈值

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2025-01-20 DOI: 10.1016/j.ensm.2025.104046

Zhaotian Xie, Wentao Zhang, Xin He, Ziyao Gao, Zhicheng Du, Hongkai Yang, Xinming Zhang, Rui li, Yanbing He, Lele Peng, Feiyu Kang

{"title":"Crossing the capacity threshold in Si-S batteries through mud-crack electrodes","authors":"Zhaotian Xie, Wentao Zhang, Xin He, Ziyao Gao, Zhicheng Du, Hongkai Yang, Xinming Zhang, Rui li, Yanbing He, Lele Peng, Feiyu Kang","doi":"10.1016/j.ensm.2025.104046","DOIUrl":"https://doi.org/10.1016/j.ensm.2025.104046","url":null,"abstract":"Silicon-Sulfur (Si-S) battery may promise high energy density and stability thanks to the high-capacity and less-dendrite-formation features of Si anode. However, current design principle for Si-S battery relies on a lab-scale, trial-and-error approach to designing and pairing sophisticated sulfur cathodes and Si/C anodes, lacking a feasible protocol to achieve practical application. Herein, we reveal that the Si-S battery made with commercially available Si/C and sulfur will reach a capacity (discharge) threshold that is independent of the mass of sulfur. This phenomenon is caused by the extremely sluggish Li+ diffusion at the charging plateaus (∼0.43 V) of silicon. In response to this challenge, we propose a dry-slurry process to fabricate a mud- crack structured Si electrode with significantly improved Li+ diffusion behavior, which could fully release the capacity of the full cell at low NP ratio by surpassing the capacity threshold. The resulting Si-S battery delivers a specific capacity of 1086 mAh g-1 and 9.7 mAh cm-2 with a sulfur loading of 8.9 mg cm-2, which is much higher than the device based on the conventionally made Si/C electrode. Furthermore, the corresponding Si-S pouch cell achieves ∼600 mAh g-1 after 200 cycles, showing a better stability compared to Li-S battery at a practical level. These findings suggest that charge transfer in the anode plays a decisive role in the overall performance and provides an overarching design protocol for fabricating practical Si-S full batteries.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"74 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142990308","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhancing Lithium Metal Battery Performance with a Perfluorinated Bisalt Electrolyte Achieving High-Voltage Stability up to 4.8 V 利用全氟化铋电解质提高锂金属电池性能，实现高达4.8 V的高压稳定性

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2025-01-20 DOI: 10.1016/j.ensm.2025.104048

Xue Li, Fei Luo, Miaomiao Yu, Runze Liu, Shangquan Zhao, Shan Fang

{"title":"Enhancing Lithium Metal Battery Performance with a Perfluorinated Bisalt Electrolyte Achieving High-Voltage Stability up to 4.8 V","authors":"Xue Li, Fei Luo, Miaomiao Yu, Runze Liu, Shangquan Zhao, Shan Fang","doi":"10.1016/j.ensm.2025.104048","DOIUrl":"https://doi.org/10.1016/j.ensm.2025.104048","url":null,"abstract":"The electrolyte holds a pivotal function in modulating and stabilizing the interphase of lithium metal anodes in lithium metal batteries. This study investigates the molecules composition of solvents and their interactions with lithium salts to the develop a perfluorinated bisalt electrolyte. This innovative electrolyte employs ethyl 2-fluoropropionate (EFP) in conjunction with fluoroethylene carbonate (FEC) to modulate the solvent shell structure, enhancing the cooperative effects of the dual lithium salts, lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) and lithium hexafluorophosphate (LiPF6) (referred to as 15TP). This approach promotes anions aggregation and the development of a robust inorganic-rich electrode/electrolyte interphase layer, efficiently suppressing lithium dendrite growth and stabilizing the ultra-high-nickel LiNi0.91Co0.06Mn0.03O2 (NCM91) cathode. Compared to commercial electrolytes, the 15TP significantly reduces undesirable side reactions at high-voltages. Its non-flammability, excellent wettability, and broad electrochemical window enable the Li||NCM91 cell to achieve a discharge capacity of 150 mAh g-1 after 500 cycles at a 4.5 V and a 1 C rate, with a super high average Coulombic efficiency of 99.74%. It retains 85.57% capacity after 100 cycles at 4.7 V and exceeds 80% retention at 4.8 V. The findings provide a novel approach for designing high-voltage electrolytes for lithium metal batteries.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"78 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142990304","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Progress and challenges of transition metal-based catalysts regulation for Li-CO2 batteries 锂-CO2 电池过渡金属催化剂调控的进展与挑战

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2025-01-20 DOI: 10.1016/j.ensm.2025.104047

Shasha Xiao, Ying Xiao, Shilin Hu, Tonghui Zhang, Gang He, Jihui Jing, Shimou Chen

{"title":"Progress and challenges of transition metal-based catalysts regulation for Li-CO2 batteries","authors":"Shasha Xiao, Ying Xiao, Shilin Hu, Tonghui Zhang, Gang He, Jihui Jing, Shimou Chen","doi":"10.1016/j.ensm.2025.104047","DOIUrl":"https://doi.org/10.1016/j.ensm.2025.104047","url":null,"abstract":"Lithium-carbon dioxide (Li−CO2) batteries have gained wide attention in recent years due to their high energy density and effective CO2 fixation and conversion. However, the sluggish CO2 transformation kinetics always result in high polarization voltage and poor cycling stability, seriously impeding their development. Electrochemical catalysts especially transition metal (TM)-based ones with modulated micro- and electronic-structure have attracted significant interest and exhibited great promising in promoting the CO2 reduction and evolution reactions owing to their unique d orbital. In this review, we summarize the hot modifying strategies and the related mechanism of TM-based catalysts including Ru, Ir, Pt and non-nobel transition metals such as Mo, Co, Cu, Mn, Fe, Ni, Cr, Cd, V, In, W and Re etc. applied in Li−CO2 batteries. The latest research progress along with some remaining issues is discussed in detail. Finally, the perspectives and challenges of TMs-based catalysts for Li−CO2 battery are presented, aiming to provide valuable guidance for the design and optimization of advanced cathodic catalysts in high-efficiency Li−CO2 batteries.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"8 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142990302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0