Energy Storage Materials最新文献_第2页

Wide-Temperature Solid-State Sodium Metal Batteries Using Na+ Superionic Conductor-Type Solid Electrolytes

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2024-12-18 DOI: 10.1016/j.ensm.2024.103973

Debao Fang, Yali Li, Chengzhi Wang, Runqing Miao, Shuaishuai Yang, Yu Zhao, Yu Ding, Jingxin He, Lai Chen, Ning Li, Jingbo Li, Yuefeng Su, Haibo Jin

{"title":"Wide-Temperature Solid-State Sodium Metal Batteries Using Na+ Superionic Conductor-Type Solid Electrolytes","authors":"Debao Fang, Yali Li, Chengzhi Wang, Runqing Miao, Shuaishuai Yang, Yu Zhao, Yu Ding, Jingxin He, Lai Chen, Ning Li, Jingbo Li, Yuefeng Su, Haibo Jin","doi":"10.1016/j.ensm.2024.103973","DOIUrl":"https://doi.org/10.1016/j.ensm.2024.103973","url":null,"abstract":"Solid-state sodium metal batteries (SSMBs) are considered as one of the critical technologies for safe and high-energy-density batteries. However, most SSMBs encounter poor cycling performance due to the sluggish charge transfer processes across the solid-solid interfaces. Based on a cation doping strategy, Al3+ and Zn2+ doped Na3Zr2Si2PO12 solid electrolytes (SEs) are comprehensively examined to decouple their ionic conductivities and interfacial resistances with sodium metal in a wide temperature range of -20-80 °C. The Zn2+ doping signifies more favorable effect than the Al3+ doping on improving the conductivity and reducing the interfacial resistance. The Na3.20Zr1.90Zn0.10Si2PO12 SE shows an optimal conductivity of 1.58 mS cm-1 at 30 °C, which is over 4 times higher than that of Na3Zr2Si2PO12, and possesses intrinsically small interfacial resistances of 229.80, 24.72, and 2.96 ohm cm⁻² at -20, 30, and 60 °C, respectively. Stable sodium plating/stripping cycles over long terms are achieved, specifically demonstrating accumulated capacities of 90, 300, and 582 mAh cm-2 at 0, 30, and 60 °C, respectively. Moreover, full cells using a Na3V2(PO4)3 cathode exhibit notable cycling stability at 0 °C with a high retention of 90.4% over 1800 cycles, providing insights into the practical SSMBs operating in diverse temperature conditions.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"271 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142849737","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Trace high-valence ions induced surface coherent phase stabilized high voltage LiCoO2

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2024-12-16 DOI: 10.1016/j.ensm.2024.103950

Muhammad Imran, Zhongsheng Dai, Fiaz Hussain, Wei Xia, Renjie Chen, Feng Wu, Li Li

{"title":"Trace high-valence ions induced surface coherent phase stabilized high voltage LiCoO2","authors":"Muhammad Imran, Zhongsheng Dai, Fiaz Hussain, Wei Xia, Renjie Chen, Feng Wu, Li Li","doi":"10.1016/j.ensm.2024.103950","DOIUrl":"https://doi.org/10.1016/j.ensm.2024.103950","url":null,"abstract":"Employing higher voltage (≥4.6 V) is an effective strategy to achieve higher energy densities in LiCoO2 based lithium-ion batteries. However, higher-voltage operation was generally followed by more severely surface to bulk structure deterioration, leading to rapid battery performance decay. Herein, a co-doping strategy involving in trace high-valence tantalum and niobium doping in LiCoO2 material was proposed. Owing to the charge neutralization effect, the incorporated Ta and Nb ions induced the Co to lower valence state, which could further migrate to the Li layer for the similar ionic radius, and thus a nanoscale disordered layer on LiCoO2 surface was successfully constructed. The stable disordered layer with tiny lattice mismatch to inner layered structure (coherent phase) could serve as an “armor” to restrain surface side reactions with electrolyte. Furthermore, the strong Ta-O and Nb-O bonding could act as an “oxygen anchor” to inhibit excessive oxygen oxidation under high-voltage operation. This helped the modified cathode showed 82.1% capacity retention after 100 cycles (4.6 V). Furthermore, the full cell composed of modified cathode and graphite anode revealed a remarkable capacity retention of 98% after 400 cycles. This study provides deep insights into the different phenomena associated with interfacial and structural parameters that need to be tuned to enhance the electrochemical performance at elevated voltages.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"23 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142825725","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Suppressing Organic Cation Reactivity in Locally Concentrated Ionic Liquid Electrolytes for Lithium Metal Batteries

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2024-12-16 DOI: 10.1016/j.ensm.2024.103966

Sewon Eom, Minhee Park, Bonhyeop Koo, Chang-eui Yang, Junsik kang, Hongkyung Lee, Won Bo Lee, Hochun Lee

{"title":"Suppressing Organic Cation Reactivity in Locally Concentrated Ionic Liquid Electrolytes for Lithium Metal Batteries","authors":"Sewon Eom, Minhee Park, Bonhyeop Koo, Chang-eui Yang, Junsik kang, Hongkyung Lee, Won Bo Lee, Hochun Lee","doi":"10.1016/j.ensm.2024.103966","DOIUrl":"https://doi.org/10.1016/j.ensm.2024.103966","url":null,"abstract":"The quest for highly stable ionic liquid electrolytes is vital for longer, safer cycling of Li-metal batteries (LMBs), given their nonflammable nature and broad electrochemical window. Locally concentrated ionic liquid electrolytes (LCILEs) have emerged by incorporating anti-solvating co-solvents to address the high viscosity and poor conductivity of Li+-concentrated ionic liquids. Although solvation and interface chemistry are crucial in determining cell performance, the impacts of organic cations in LCILEs remain overlooked. This work unravels the co-solvent-guided mediation of organic cation reactivity toward Li metal anodes. The donor number (DN) of co-solvents is found to significantly influence their local distribution within LCILEs, modulating Coulombic interactions between Li+–anion complexes and organic cations. Low DN co-solvents, such as hydrofluoroethers, hardly interact with Li+–anion complexes but dissociate and destabilize organic cations, adversely promoting organic cation decomposition at Li metal anodes. Conversely, high DN co-solvents prefer to occupy the Li+ solvation sheath, promoting organic cation–anion association and mitigating the cathodic decomposition. Suppressing the reactivity of organic cations in LCILEs is essential for proper anion-derived solid-electrolyte interphase formation and stable cycling of LMBs. The controlled reactivity of organic cations in concentrated ionic liquid electrolytes incorporating high DN co-solvent enables stable cycling of LMBs under stringent conditions, achieving 95% capacity retention over 200 cycles.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"11 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142832884","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Boosted Capacity and Stability of Aqueous Iron-Sulfur Battery using DMSO as an Electrolyte Additive 使用二甲基亚砜作为电解质添加剂提高铁硫水溶液电池的容量和稳定性

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2024-12-15 DOI: 10.1016/j.ensm.2024.103965

Man Singh, Sukhjot Kaur, Shivangi Mehta, Mukesh Kumar, Kush Kumar, Santosh Kumar Meena, Tharamani C. Nagaiah

{"title":"Boosted Capacity and Stability of Aqueous Iron-Sulfur Battery using DMSO as an Electrolyte Additive","authors":"Man Singh, Sukhjot Kaur, Shivangi Mehta, Mukesh Kumar, Kush Kumar, Santosh Kumar Meena, Tharamani C. Nagaiah","doi":"10.1016/j.ensm.2024.103965","DOIUrl":"https://doi.org/10.1016/j.ensm.2024.103965","url":null,"abstract":"Exploring metal-sulfur batteries with low cost, high safety, and capacity is the need of the hour for large storage applications. Iron (Fe) being a highly abundant and cost-effective element, provides an excellent option as an anode material which on coupling with abundant sulfur (S) in an aqueous electrolyte will be a game-changing approach. Despite a promising outlook, the stability of Fe anode due to side reactions in aqueous electrolytes and inherent corrosion tendencies limit their performance. Herein, we have explored dimethyl sulfoxide (DMSO) as an electrolyte additive in iron percholorate (Fe(ClO4)2 for aqueous Fe-S battery, which exhibited high specific capacity of 1145 mAh g-1 at 50 mA g-1 with remarkable cycling stability for 400 continuous cycles at 2.0 and 0.5 A g-1 current densities with 72% and 98% capacity retention respectively without replacing the Fe-anode. The addition of DMSO, suppressed parasitic hydrogen evolution reaction (HER) by 6.7 times and mitigated the corrosion rate of iron electrodes by 2.2 times as evidenced by the spectroscopic and gas chromatography techniques. The molecular dynamics (MD) simulations revealed that DMSO engages the water molecules through hydrogen bonding which reduced the fraction of free water molecules available for HER and corrosion of iron electrodes.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"44 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2024-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142823357","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electrothermally tailored lithiophilic Co/CoxOy@porous graphite composites for high-performance Li-ion/metal hybrid batteries

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2024-12-14 DOI: 10.1016/j.ensm.2024.103961

Byungseok Seo, Daehyun Kim, Seonghyun Park, Dongjoon Shin, Kyungmin Kim, Wonjoon Choi

{"title":"Electrothermally tailored lithiophilic Co/CoxOy@porous graphite composites for high-performance Li-ion/metal hybrid batteries","authors":"Byungseok Seo, Daehyun Kim, Seonghyun Park, Dongjoon Shin, Kyungmin Kim, Wonjoon Choi","doi":"10.1016/j.ensm.2024.103961","DOIUrl":"https://doi.org/10.1016/j.ensm.2024.103961","url":null,"abstract":"Li-based batteries with high energy density and cyclic stability are essential for sustainable energy systems, whereas conventional design strategies are limited in restricted capacity and dendrite formation. Herein, we report precisely tunable Co/CoxOy@porous graphite (p-G) composites fabricated by the scalable electrothermal wave (ETW) process, enabling exceptional lithiophilic properties, increased surface area, and high porosity. The optimal heating-cooling rates adjusted by the ETW parameters could surpass the decomposition temperature of precursors yet suppress the excess thermal energy density inducing the aggregation of the resulting Co/CoxOy@p-G composite, thereby offering the rapid screening of their physicochemical characteristics. The screened Co/CoxOy@p-G composites as anodes in Li-ion/metal hybrid batteries, exhibit outstanding lithiation, Li plating at high capacities, and dendrite resistance. Compared to bare p-G anodes, they enhance Coulombic efficiency and cyclic stability by 600 % in half-cell tests, while maintaining an energy density ranging from 272.59 to 240.25 Wh∙kg-1 over 110 cycles in full-cell tests, representing a 153.14 % improvement. The outcomes will inspire ultrafast yet effective fabrication strategies for high-performance electrochemical cells.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"41 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2024-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142820973","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Activating reversible multi-electron reaction of Na3(VO)2(PO4)2F cathode via Fe/F dual-doping for high-energy and stable sodium storage

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2024-12-14 DOI: 10.1016/j.ensm.2024.103960

Qiang Fu, Fangxiang Song, Changhui Mu, Qingqing Wu, Keliang Wang, Song Li, Xianquan Ao

{"title":"Activating reversible multi-electron reaction of Na3(VO)2(PO4)2F cathode via Fe/F dual-doping for high-energy and stable sodium storage","authors":"Qiang Fu, Fangxiang Song, Changhui Mu, Qingqing Wu, Keliang Wang, Song Li, Xianquan Ao","doi":"10.1016/j.ensm.2024.103960","DOIUrl":"https://doi.org/10.1016/j.ensm.2024.103960","url":null,"abstract":"Na3(VO)2(PO4)2F cathode has garnered extensive interest for its stable structure, abundant Na+ migration channels, and high working voltage, though higher energy densities are sought for commercial applications. This study enhances energy density by activating multi-electron reactions through the partial substitution of V4+ and dangling O2− with Fe3+ and F⁻, respectively, using a straightforward hydrothermal method. This substitution successfully activates the V3+/V4+ redox couple, facilitating multi-electron reactions. The modified cathode, Na₃(VO)1.8Fe0.2(PO4)2F1.2 (N(VO)1.8Fe0.2PF1.2), exhibits a reversible specific capacity of 213.3 mAh g−1 at 50 mA g−1. Characterization techniques, including in situ X-ray diffraction and ex-situ X-ray photoelectron spectroscopy, confirm that the activated V3+/V4+ redox reaction proceeds via a solid-solution mechanism. Density functional theory analysis suggests that Na3(VO)1.8Fe0.2(PO4)2F1.2 offers improved electronic conductivity and structural stability, elucidating the origins of low Na+ migration energy barriers and ideal diffusion kinetics. When paired with a hard carbon (HC) anode, the full cell (HC//N(VO)1.8Fe0.2PF1.2) achieves a reversible capacity of 196.6 mAh g−1 and an energy density of 287.0 Wh kg−1 at 50 mA g−1, demonstrating exceptional long-term cyclic stability with a capacity retention of 94.7% after 200 cycles at 500 mA g−1. This study opens new avenues for the commercial application of sodium-ion batteries (SIBs) cathodes.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"19 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2024-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142820974","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advanced Direct Recycling Technology Enables a Second Life of Spent Lithium-ion Battery

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2024-12-13 DOI: 10.1016/j.ensm.2024.103964

Ji Shen, Miaomiao Zhou, Wei Liu, Yiliang Shi, Wenhao Tang, Yirui Deng, Ruiping Liu, Yinze Zuo, Jiujun Zhang

{"title":"Advanced Direct Recycling Technology Enables a Second Life of Spent Lithium-ion Battery","authors":"Ji Shen, Miaomiao Zhou, Wei Liu, Yiliang Shi, Wenhao Tang, Yirui Deng, Ruiping Liu, Yinze Zuo, Jiujun Zhang","doi":"10.1016/j.ensm.2024.103964","DOIUrl":"https://doi.org/10.1016/j.ensm.2024.103964","url":null,"abstract":"With the emergence of the energy crisis and the rise of human environmental awareness, lithium-ion batteries (LIBs), as a new type of energy storage device, are widely used in electric vehicles (EVs), mobile electronic products and stationary energy storage devices. The demand for LIBs has dramatically increased in recent years, leading to a shortage of raw materials for LIBs and a large number of retired LIBs. Therefore, it is particularly important to recycle spent LIBs. Compared with pyrometallurgy and hydrometallurgy, direct recycling, as a more advanced technology, focuses on repairing of the electrodes of spent LIBs. However, direct recycling technology is still in the laboratory operation stage, and there are still many difficulties and challenges to overcome. Herein, we firstly highlight the importance of recycling spent LIBs from LIB market development, raw material supply, environmental impact, and economic benefits. Subsequently, starting from the failure forms and mechanisms of electrode materials, we provide a detailed summary of various direct recycling and upcycling processes, reaction principles, as well as advantages and disadvantages. Additionally, the technology for converting waste cathodes and graphite into new functional materials, a topic rarely addressed in previous reviews, is comprehensively detailed in this review. Lastly, we provide a summary of the current status of LIB recycling and present future challenges. This review may serve as a source of inspiration for researchers and enterprises to develop more advanced recycling methodologies.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"46 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2024-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142816478","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Quantification of activated carbon functional groups and active surface area by TPD-MS and their impact on supercapacitor performance

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2024-12-12 DOI: 10.1016/j.ensm.2024.103963

Bénédicte Réty, Hui-Yi Yiin, Camélia Matei Ghimbeu

{"title":"Quantification of activated carbon functional groups and active surface area by TPD-MS and their impact on supercapacitor performance","authors":"Bénédicte Réty, Hui-Yi Yiin, Camélia Matei Ghimbeu","doi":"10.1016/j.ensm.2024.103963","DOIUrl":"https://doi.org/10.1016/j.ensm.2024.103963","url":null,"abstract":"Carbon oxygenated functional groups and active sites play an important role in the interactions with the electrolytes in aqueous supercapacitors. For the first time, correlations between each type of O-surface groups and electrochemical performance are established by means of thermodesorption coupled with mass spectrometry (TPD-MS). A set of five activated carbons and one soft-salt templated carbon, were studied in three different pH electrolytes, 1M H2SO4, 1M KOH and 1M Na2SO4. Linear correlations between surface groups and capacitance were found: acidic groups such as carboxylic acid and phenol-ether groups improve capacitance, whereas carbonyl-quinone groups are detrimental. Moreover, active surface area (ASA) is for the first time measured for activated carbons thanks to a new protocol, which minimises material burn-off during oxygen chemisorption. In addition, a new approach consisting in the quantification of the ASA is proposed. It has been highlighted that certain active sites are linearly correlated to an improvement of capacitance. Although the oxygen surface groups and ASA improve the capacitance via pseudo-capacitance phenomena, the capacitive mechanisms, governed by the porosity of the activated carbons, are shown to be predominant. Among all materials, the soft-salt templated carbon gives the best electrochemical performance. Indeed, it combines a large quantity of carboxylic acid and phenol-ether surface groups as well as appropriate ASA. Moreover, it has a high specific surface area (2556 m²·g-1) and optimal pore size (0.88 nm). All these characteristics, provide a high capacitance, a high rate capability and a high capacitance retention after 10,000 cycles.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"40 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142815981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effective Control of the Solution Environment in Aqueous Zinc-ion Batteries for Promoting (002)-Textured Zinc Growth by a Bio-Electrolyte Additive

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2024-12-12 DOI: 10.1016/j.ensm.2024.103959

Yarui Xiong, Weiyu Teng, Zhiwei Zhao, Shiling Xu, Yingyuan Ma, Yingzhen Gong, Dehua Li, Xun Wang, Yaoxi Shen, Zhen Shen, Yi Hu

{"title":"Effective Control of the Solution Environment in Aqueous Zinc-ion Batteries for Promoting (002)-Textured Zinc Growth by a Bio-Electrolyte Additive","authors":"Yarui Xiong, Weiyu Teng, Zhiwei Zhao, Shiling Xu, Yingyuan Ma, Yingzhen Gong, Dehua Li, Xun Wang, Yaoxi Shen, Zhen Shen, Yi Hu","doi":"10.1016/j.ensm.2024.103959","DOIUrl":"https://doi.org/10.1016/j.ensm.2024.103959","url":null,"abstract":"Aqueous zinc-ion batteries (AZIBs) have garnered considerable interest due to their intrinsic safety features and high energy density. However, challenges such as the growth of Zn dendrites and the prevalence of parasitic reactions during cycling have impeded their broader application. This study introduces Silk Sericin (SS), a multifunctional natural protein, as an electrolyte additive designed to overcome these obstacles. Through a series of detailed experimental validations and theoretical analyses, it is demonstrated that SS molecules, rich in polar functional groups, effectively anchor onto the anode-electrolyte interphase. This anchoring leads to the formation of a stable solid electrolyte interface (SEI) layer while simultaneously modulating the coordination environment of zinc ions through strong interactions with water molecules. The adsorption energies and substantial binding affinity of SS induce a synergistic effect, preferentially orienting zinc ions deposition on the (002) plane, thereby promoting the formation of a flat and compact deposition layer. The modified Zn || Zn cells containing 1% SS exhibit exceptional durability, surpassing 5200 h of operation at 1 mA cm−2/1 mAh cm−2 with highly reversible Zn plating/stripping behavior. Moreover, Zn || VO2 full cells deliver a high specific capacity of 213 mAh g−1 at 4 A g−1, maintaining robust performances over 3800 cycles. Additionally, Aqueous zinc-ion micro-batteries (AZMBs) based on SS demonstrate superior capacity retention, underscoring their potential for advanced energy storage applications. This research presents a novel electrolyte engineering approach that combines interface control with solution environment optimization, offering an effective strategy to enhance both the reversibility and stability of Zn anodes.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"73 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142816404","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Preparation, Design and Interfacial Modification of Sulfide Solid Electrolytes for All-Solid-State Lithium Metal Batteries

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2024-12-12 DOI: 10.1016/j.ensm.2024.103962

Jianwei Li, Yuanyuan Li, Yuxiao Wang, Xiaojun Wang, Peng Wang, Lijie Ci, Zhiming Liu

{"title":"Preparation, Design and Interfacial Modification of Sulfide Solid Electrolytes for All-Solid-State Lithium Metal Batteries","authors":"Jianwei Li, Yuanyuan Li, Yuxiao Wang, Xiaojun Wang, Peng Wang, Lijie Ci, Zhiming Liu","doi":"10.1016/j.ensm.2024.103962","DOIUrl":"https://doi.org/10.1016/j.ensm.2024.103962","url":null,"abstract":"All-solid-state batteries (ASSBs) have garnered significant interest as a potential energy storage solution, primarily because of their enhanced safety features and high energy density. Sulfide solid electrolytes have emerged as a focal point in solid-state battery research, attributed to their exceptional ionic conductivity, wide electrochemical stability range, and robust mechanical properties. However, their practical performance is frequently limited by interfacial compatibility issues with lithium-metal anodes and challenges associated with the high-cost of sulfide solid electrolyte. Therefore, the design and optimization of low-cost sulfide solid electrolytes, as well as compatibility strategies for lithium metal anodes, are vital for broadening the application prospects of sulfide solid electrolytes. This review systematically analyses the classification and synthesis methods of sulfide solid electrolytes, focusing on low-cost synthesis approaches. Furthermore, this review examines recent advancements in optimizing the interface between sulfide solid electrolytes and lithium-metal anodes, and provides strategic insights into the optimal selection and engineering of materials for the interfacial layer of lithium-metal anodes by synthesizing the latest experimental and theoretical findings. Finally, this review provides insights into the developmental trends and future prospects of sulfide all-solid-state lithium-metal batteries (ASSLMBs), offering valuable guidance for the practical application of high-performance ASSLMBs.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"29 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142810008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0