Energy Storage Materials最新文献

{"title":"Thermal decomposition pathways of bulk electrolytes on vanadium oxide nanocrystals","authors":"Jian Zhi Hu, Wenda Hu, Heonjae Jeong, Grant Alexander, Nguyen Dan Thien, Venkateshkumar Prabhakaran, Kee Sung Han, Ying Chen, Jordi Cabana-Jimenez, Justin Connell, Lei Cheng, Vijayakumar Murugesan, Kevin R. Zavadil, Karl T. Mueller","doi":"10.1016/j.ensm.2025.104315","DOIUrl":"https://doi.org/10.1016/j.ensm.2025.104315","url":null,"abstract":"The thermal stability of electrolytes at an elevated temperature induced by battery charge-discharge cycling is critical for the long cycling performance of a rechargeable battery. For many multivalent systems, such as rechargeable magnesium batteries, which offer great potential for high energy density and utilize earth-abundant resources, electrolyte instability and electrode surface passivation, arising from electrolyte decomposition, remain as major roadblocks. Understanding the electrolyte decomposition pathways at the electrode-electrolyte interface is essential to provide guidance in overcoming this challenge. In this work, in situ ¹³C magic angle spinning nuclear magnetic resonance (MAS NMR) and first-principles calculations were used to investigate the thermal decomposition of the electrolyte in a system consisting of MgV₂O₄, a novel cathode for magnesium batteries, mixed with a bulk electrolyte consisting of magnesium bis(trifluoromethanesulfonyl)imide (Mg(TFSI)₂) in diglyme (G2). We show that significant electrolyte decomposition is observed in bulk 1.0 M Mg(TFSI)₂ in G2 mixed with nanometer sized MgV₂O₄ powder at elevated temperature. This observation is to mimic the possible thermal decomposition that might happen during battery cycling. We demonstrate that the MgV₂O₄ surface is covered by a layer of decomposed G2 products. We conclude that the dominant reaction pathway for electrolyte decomposition is the thermal decomposition of the pure electrolytes at elevated temperatures, followed by adsorption of G2 decomposition products to the MgV₂O₄ surface. The activation energy for the major decomposition pathway is obtained. This work highlights the importance of studying thermal decomposition of electrolytes for overall system stability and explores electrolyte stability at significantly elevated temperatures.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"229 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143926889","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A dynamic organic-inorganic bilayer solid/electrolyte interphase employed L-carnosine additive for highly stable zinc metal anode","authors":"Rongkun Sun,&nbsp;Jiushi Ma,&nbsp;Yizhan Gao,&nbsp;Jiale Peng,&nbsp;Wenyao Ma,&nbsp;Jincheng Yu,&nbsp;Da Wang,&nbsp;Zhi Li,&nbsp;Xiaohong Kang","doi":"10.1016/j.ensm.2025.104293","DOIUrl":"10.1016/j.ensm.2025.104293","url":null,"abstract":"<div><div>The construction of a solid/electrolyte interphase (SEI) is a critical aspect to control the highly stable plating/stripping of Zn metal anode and side reactions for aqueous zinc-ion batteries (AZIBs). Here, we employ l-carnosine (HL), a dipeptide regulating pH in human cells, as an electrolyte additive to construct a dynamic organic-inorganic bilayer SEI to stabilize the Zn anode. The bilayer SEI consists of an amorphous organic inner layer and a ZnCO₃-rich crystalline outer layer. The dynamic organic inner layer reduces Zn²⁺ deposition resistance and promotes uniform Zn²⁺ flux, thereby mitigating dendrite formation. While the ordered crystalline outer layer effectively isolates water molecules, thereby enhancing the overall mechanical strength and stability of the SEI. As a result, the cycle life of the Zn||Zn symmetric cell exceeds 5500 h at 1 mA cm⁻², 1 mAh cm⁻², and 1450 h at a high current density of 10 mA cm⁻², 10 mAh cm⁻². The Zn||NVO full cell also presents a discharge specific capacity of more than 180 mAh g⁻¹ and close to 100% coulomb efficiency (CE) after a stable cycling of 2000 cycles.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"79 ","pages":"Article 104293"},"PeriodicalIF":18.9,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143926890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Machine learning accelerates high-voltage electrolyte discovery for lithium metal batteries","authors":"Yizhe Yan ,&nbsp;Feng Hai ,&nbsp;Bin Wang ,&nbsp;Wenrui Cao ,&nbsp;Mingtao Li ,&nbsp;Chaohui Wang ,&nbsp;Naipeng Li ,&nbsp;Dan Zhao","doi":"10.1016/j.ensm.2025.104312","DOIUrl":"10.1016/j.ensm.2025.104312","url":null,"abstract":"<div><div>Appropriate electrolytes are essential for ensuring the performance stability of high-voltage lithium metal batteries. However, the complexity arising from multiple solvents and their relative ratios leads to significant challenges for the design of electrolytes. Herein, we propose a machine learning (ML) approach that links the microscopic properties of electrolytes with their macroscopic battery performance, thus enabling the discovery of high-performance electrolyte formulations to be accelerated. By designing chemical groups of electrolyte solvents as features and establishing a cycling stability evaluation metric for batteries, an ML model is created to predict the capacity retention of high-voltage lithium metal batteries. Through integrating this ML model with a heuristic optimization algorithm, a series of superior electrolytes are identified within a ternary solvent design space (over 29,000 possible electrolytes). Our model reveals that a specific proportion of the fluorinated ether diluent is critical for achieving superior capacity retention in fluorinated electrolytes. To validate the cycling stability of these electrolytes, we experimentally tested them in a Li||LiNi_0.5Mn_1.5O₄ coin cell configuration. All the cells containing the discovered electrolytes demonstrate outstanding capacity retention, consistent with our model’s prediction trend. This work highlights the potential of ML approaches for the design and optimization of stable, high-performance battery electrolytes.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"79 ","pages":"Article 104312"},"PeriodicalIF":18.9,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143915891","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unlocking the value of copper and aluminum foils from spent lithium-ion batteries","authors":"Xufeng Qian ,&nbsp;Jingqin Ji ,&nbsp;Yanlan Zhao ,&nbsp;Shaoqi Zhou ,&nbsp;Shengming Xu","doi":"10.1016/j.ensm.2025.104309","DOIUrl":"10.1016/j.ensm.2025.104309","url":null,"abstract":"<div><div>Recovering copper (Cu) and aluminum (Al) foils from spent lithium-ion batteries (LIBs) is a critical step in enhancing the sustainability of battery recycling and addressing the growing demand for these metals. However, the strong adhesion between the foils and active materials poses significant technical challenges, mainly due to the presence of polymeric binders such as polyvinylidene fluoride (PVDF). This review focuses on the separation mechanisms of Cu and Al foils, with special emphasis on the physical, chemical, and electrochemical processes that facilitate the separation of active materials from the collector. The existing methods and advances in the recovery and utilization of Cu/Al current collectors from spent LIBs are highlighted, including chemical dissolution, mechano-chemistry, thermal treatment, and electrochemical separation. The potential for reusing recovered Cu/Al in new LIBs or other industrial applications is also evaluated, emphasizing the importance of material purity and quality. Future directions for improving the recycling process are explored, focusing on innovative separation technologies and sustainable resource utilization strategies. This review seeks to provide a comprehensive understanding of the current state of Cu/Al foil recovery in LIBs recycling while offering insights into potential advances in this field.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"79 ","pages":"Article 104309"},"PeriodicalIF":18.9,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143915890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Anionic flip induced gating effect enables high stability of zinc metal anode","authors":"Qiwen Zhao ,&nbsp;Yesong Chen ,&nbsp;Wen Liu ,&nbsp;Changding Wang ,&nbsp;Hanwei He ,&nbsp;Bingang Xu ,&nbsp;Gang Zhou ,&nbsp;Yuejiao Chen ,&nbsp;Libao Chen","doi":"10.1016/j.ensm.2025.104305","DOIUrl":"10.1016/j.ensm.2025.104305","url":null,"abstract":"<div><div>The persistent issues of zinc dendrite and water-induced side reactions continue to compromise the stability of the anode/electrolyte interface. Herein, the gating mechanism based on interfacial ion flipping is proposed to stabilize the anode interface, suppress side reactions and facilitate dendrite-free Zn deposition. Under the specific adsorption of anions, water molecules are effectively expelled by hydrophobic cyclohexyl, thereby mitigating corrosion. Moreover, under the influence of electric field, negatively charged anions undergo flipping, enhancing cation transfer. Sodium ions preferentially adsorb at the electrode protrusions, creating an electrostatic shielding effect. Simultaneously, Zn ions redistribute spatially, thereby achieving uniform Zn deposition. Through the synergistic effect of anion flipping, a distinctive gating mechanism is established within the electric double layer, which precisely modulates the distribution and behavior of cations, water molecules, and anions at the interface. This dynamic regulation mechanism provides continuous protection for the Zn metal anode, ensuring its electrochemical stability. Accordingly, a high average coulombic efficiency of 99.79 % is obtained during 2250 cycles, demonstrating outstanding plating/stripping reversibility. Moreover, Zn//NVO full cell exhibits well-improved capacity retention with long cycling lifespan of 5000 cycles at 5 A g^-1. The successful application of the anion flipping effectively presents a novel paradigm for stabilizing Zn anodes.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"79 ","pages":"Article 104305"},"PeriodicalIF":18.9,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143915889","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Methyl exchange facilitates the collective dissolution of electrolyte additives for better lithium metal batteries","authors":"Yuanhang Gao,&nbsp;Zuxin Wen,&nbsp;Tao Zhang,&nbsp;Wenjie Yan,&nbsp;Zuosu Qin,&nbsp;Anqiang Pan,&nbsp;Ning Zhang,&nbsp;Xiaohe Liu,&nbsp;Gen Chen","doi":"10.1016/j.ensm.2025.104310","DOIUrl":"10.1016/j.ensm.2025.104310","url":null,"abstract":"<div><div>The development of advanced lithium metal batteries (LMBs) is strongly dependent on the progress of electrolyte chemistry. Herein, we investigate the molecular-level interactions of 1-ethyl-3-methylimidazole dimethyl phosphate (EMDP) and methyltrifluoromethane-sulfonic acid (MeOTf) within carbonate electrolytes to enhance the electrochemical performances of LMBs. The electron-rich dimethyl phosphate anion displays a significant proclivity to react with the electron-deficient methyl group in MeOTf, thereby leading to rapid methyl exchange reaction (MER). This enables the collective dissolution of EMDP and MeOTf in the carbonate solvents. The <em>in situ</em> generated products not only function as film-forming additives, but also facilitate the dissolution of LiNO₃ due to the highly electronegative trifluoromethanesulfonate anion and the high donor number of trimethyl phosphate. Consequently, the trace addition-optimized electrolyte promotes the formation of a gradient heterogeneous electrode-electrolyte interphase (EEI), comprising an inner layer rich in inorganic compounds (such as Li₃N, Li₃P, Li₂S). The nitrogen/phosphorus-rich EEI not only renders the formation of a dendrite-free lithium anode with a high Coulombic efficiency of 99.19 %, but also improves the voltage tolerance of the carbonate electrolyte to 4.4 V with a capacity retention of 82.5 % after 250 cycles. The proposed MER represents a novel and practical strategy to diversify the electrolyte chemistry for LMBs.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"79 ","pages":"Article 104310"},"PeriodicalIF":18.9,"publicationDate":"2025-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143915894","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ultra-high energy storage performance of field-induced ferroelectric Al2O3-inserted Hf0.5Zr0.5O2 thin films for electrostatic supercapacitors","authors":"Jonghoon Shin,&nbsp;Dong Hoon Shin,&nbsp;Haengha Seo,&nbsp;Kyung Do Kim,&nbsp;Seungheon Choi,&nbsp;Tae Kyun Kim,&nbsp;Heewon Paik,&nbsp;Haewon Song,&nbsp;Seungyong Byun,&nbsp;In Soo Lee,&nbsp;Cheol Seong Hwang","doi":"10.1016/j.ensm.2025.104306","DOIUrl":"10.1016/j.ensm.2025.104306","url":null,"abstract":"<div><div>This study investigates the impact of Al₂O₃​ doping on the structural and chemical characteristics and the energy storage performance of atomic layer deposited Hf_0.5Zr_0.5O₂ (HZO) thin films. By adjusting the number of Al₂O₃​ dopant cycles and layer insertion positions, optimized Al₂O₃-inserted HZO films achieve a record-high energy storage density (ESD) of ∼138 J cm^-3 among planar-structured (Hf,Zr)O₂-based thin films, with a high efficiency of ∼80 %. The films maintain stable energy storage performance over 10⁹ cycles at 6.0 MV cm^-1 without electrical breakdown. A single Al₂O₃​ cycle (∼0.12 nm), uniformly diffused at multiple locations within the HZO matrix, suppresses the monoclinic phase and stabilizes the tetragonal phase. This structure enhances the field-induced ferroelectric (FFE) switching, decreases the hysteresis loop area, and increases the breakdown field (above ∼8.0 MV cm^-1). In contrast, thicker Al₂O₃​ layers (∼0.24–0.36 nm) form continuous, non-diffusive layers that hinder FFE tetragonal phase stabilization. These findings highlight the critical role of precise Al₂O₃​ insertion in maximizing the energy storage capabilities of (Hf,Zr)O₂ thin films. High ESD was maintained at fast discharge times below 1 μs. The effective discharge time is proposed as an efficient metric for future evaluations.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"79 ","pages":"Article 104306"},"PeriodicalIF":18.9,"publicationDate":"2025-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143910683","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Boosting anionic-cationic redox chemistry in anion-rich CuSe2 cathode toward high-energy magnesium batteries","authors":"Changliang Du ,&nbsp;Youqi Zhu ,&nbsp;Lifen Yang ,&nbsp;Rong Jiang ,&nbsp;Mingwei Jin ,&nbsp;Qianwei Zhang ,&nbsp;Siru He ,&nbsp;Tinglu Song ,&nbsp;Xilan Ma ,&nbsp;Chuanbao Cao ,&nbsp;Meishuai Zou","doi":"10.1016/j.ensm.2025.104304","DOIUrl":"10.1016/j.ensm.2025.104304","url":null,"abstract":"<div><div>Electrochemical Mg-Cu displacement is recognized as the prominent capacity-contribution reaction in copper-based chalcogenide cathodes. However, such one-sided mechanism experiences low discharge voltage plateau and thus restricts the exploitation of high-energy magnesium batteries. Herein, a synergetic cationic-anionic redox chemistry mechanism is revealed in anion-rich copper selenide (CuSe₂) cathode for high-energy magnesium batteries. <em>Ex-situ</em> spectroscopic characterization and DFT calculations demonstrate the mechanism with high-voltage Se-Cl anionic redox chemistry and low-voltage cationic Mg-Cu replacement reaction. A series of copper selenides with controllable anion content are fabricated by phase engineering strategy via regulating the Se source concentration during selenization. The anion-rich CuSe₂ cathode shows both superior anionic and cationic redox reactions for Mg²⁺ storage kinetics with considerable capacity of 440.6 mAh g^–1 and high energy density of 439.4 Wh kg^–1. Based on the outstanding reaction kinetics, the CuSe₂ cathode also delivers remarkable rate capability with 169 mAh g^–1 at 2.0 A g^–1 and cycling life for 1500 cycles. Theoretical investigation suggests that the anion-rich phase can show the most effective adsorption of Mg²⁺ and Cl^– and the highest conductivity. This work unveils a brand-new anionic-cationic redox chemistry mechanism and provides a high-efficiency strategy for fabricating anion-rich copper selenides toward high-energy rechargeable magnesium batteries.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"79 ","pages":"Article 104304"},"PeriodicalIF":18.9,"publicationDate":"2025-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143905448","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Surface defects induced by acid etching for promoting Ni-rich cathode regeneration","authors":"Meng Xiao,&nbsp;Xiaopeng Fu,&nbsp;Zhian Zhang,&nbsp;Meng Ye,&nbsp;Lang Qiu,&nbsp;Zhenguo Wu,&nbsp;Fang Wan,&nbsp;Xiaodong Guo","doi":"10.1016/j.ensm.2025.104307","DOIUrl":"10.1016/j.ensm.2025.104307","url":null,"abstract":"<div><div>Direct regeneration has been considered as the promising strategy for the recycling of spent LiNi_xCo_yMn_zO₂ (NCM) cathode materials. The spent NCM suffers from the lithium deficiency in the interior and the phase transition on the surface. The phase transition on the surface suppresses the Li⁺ diffusion during the direct regeneration process. Surface acid etching is employed to eliminate by-products and degraded phases from spent NCM, aiming to mitigate the Li⁺ diffusion barrier during regeneration. However, the underlying mechanism of this surface engineering on defect formation and material regeneration remains unclear. Here, we systematically investigated the surface acid etching process and regeneration mechanism of spent NCM. We reveal that controlled surface dissolution of metal ions induces the formation of oxygen vacancies. This enhances Li⁺ adsorption on the spent NCM surface and facilitates Li⁺ transport during regeneration process, thus effectively restoring the layered structure and lithium deficiency. Consequently, the regenerated NCM exhibits a discharge capacity of 192.9 mA h g^-1 at 0.1 C, surpassing that of the regenerated NCM without etching (188.1 mA h g^-1). In addition, the regenerated NCM delivers a high-capacity retention of 92.6% after 100 cycles at 1 C, while that of the regenerated NCM without etching is only 68.8%. This finding provides mechanistic insight into the role of surface oxygen vacancies for promoting NCM regeneration.</div><div>Keywords</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"79 ","pages":"Article 104307"},"PeriodicalIF":18.9,"publicationDate":"2025-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143910744","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Structural stability of layered oxides for sodium-ion batteries: Insights and strategies","authors":"Xingyu Li ,&nbsp;Songlin Yu ,&nbsp;Xiaolin Zhao ,&nbsp;Jianjun Liu","doi":"10.1016/j.ensm.2025.104303","DOIUrl":"10.1016/j.ensm.2025.104303","url":null,"abstract":"<div><div>Sodium-ion batteries have garnered significant attention due to the notable advantages in resource availability and cost-effectiveness, offering an alternative solution to lithium-ion batteries. Layered oxide cathodes (LOCs), a key component of SIBs, are among the most commercially viable materials due to their low cost, ease of synthesis, and high theoretical capacity. However, challenges such as lattice defects and particle cracking caused by air exposure and electrochemical cycling lead to structural instability, resulting in capacity degradation and reduced cycle life. Addressing these issues requires multi-scale investigations, from atomic to macroscopic levels, to fully understand structural evolution. This review investigates the intrinsic mechanisms governing the structural stability of LOCs and discusses strategies for integrating multi-scale information, from atomic structure and material properties to electrochemical performance, to bridge theoretical and experimental research. Furthermore, we discuss effective approaches to enhance structural stability and outline future research directions to accelerate SIB commercialization and advance their role in energy storage.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"79 ","pages":"Article 104303"},"PeriodicalIF":18.9,"publicationDate":"2025-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143905447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}