Energy Storage Materials最新文献

{"title":"Spinel-Structured Tetragonal Mn3O4 Nanocrystals as Promising Electrode for Aqueous Ammonium-Ion Storage","authors":"Abhishek Kulkarni, Ankit Dandriyal, Shubham Patil, Niroshan Manoharan, Digambar Sawant, Mahesh Chougale, Gaurav Lohar, Jennifer MacLeod, Prashant Sonar, Deepak Dubal","doi":"10.1016/j.ensm.2026.105029","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.105029","url":null,"abstract":"The development of sustainable and efficient energy storage systems based on abundant and environmentally friendly charge carriers is paramount to achieving global net-zero goals. Ammonium (NH<ce:inf loc=\"post\">4</ce:inf><ce:sup loc=\"post\">+</ce:sup>)-ion-based systems present a promising non-metallic alternative owing to their atomic structure that enhances the kinetics, assisting charge storage. However, the identification of suitable host materials for reversible NH<ce:inf loc=\"post\">4</ce:inf>⁺ storage remains a significant challenge. Herein, we report the use of manganese oxide (Mn<ce:inf loc=\"post\">3</ce:inf>O<ce:inf loc=\"post\">4</ce:inf>) as a novel electrode material for aqueous ammonium-ion storage. Tetragonal-shaped Mn<ce:inf loc=\"post\">3</ce:inf>O<ce:inf loc=\"post\">4</ce:inf> nanoparticles were synthesised directly on carbon cloth (Mn<ce:inf loc=\"post\">3</ce:inf>O<ce:inf loc=\"post\">4</ce:inf>@CC) using a controlled layer-by-layer assembly method. These electrodes exhibit an excellent specific capacity of 322.8 mAh/g at a current density of 0.5 A/g, with impressive rate capability and 77.7 mAh/g capacity retention over 3000 cycles. The charge storage kinetics analysed using ex-situ characterisations confirm the reversible insertion and extraction mechanism of the NH<ce:inf loc=\"post\">4</ce:inf><ce:sup loc=\"post\">+</ce:sup>-ion in the Mn<ce:inf loc=\"post\">3</ce:inf>O<ce:inf loc=\"post\">4</ce:inf> structure. DFT calculations reveal the superior electronic conductivity and the interaction of the NH<ce:inf loc=\"post\">4</ce:inf><ce:sup loc=\"post\">+</ce:sup> ion with Mn<ce:inf loc=\"post\">3</ce:inf>O<ce:inf loc=\"post\">4</ce:inf>, by which the material could achieve a high capacity. Furthermore, an ammonium-ion supercapacitor (AISC) was constructed using the Mn<ce:inf loc=\"post\">3</ce:inf>O<ce:inf loc=\"post\">4</ce:inf>@CC as the positive and activated carbon (AC) as the negative electrode material. The device delivered a maximum specific energy of 47.9 Wh/kg and a specific power of 8000 W/kg, with excellent cycling stability. This investigation highlights Mn<ce:inf loc=\"post\">3</ce:inf>O<ce:inf loc=\"post\">4</ce:inf> as a promising material for NH<ce:inf loc=\"post\">4</ce:inf>⁺ ion storage and paves the way for the exploration of other electrode materials synthesised using the layer-by-layer method for next-generation, environmentally friendly energy storage systems.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"80 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147393164","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Dual P=O Molecule Engineering for All-Climate Aqueous Zinc-Ion Batteries","authors":"Jiali Wang, Helong Jiang, Jiawei Mu, Xuri Wang, Miao Yu, Xiangcun Li, Gaohong He","doi":"10.1016/j.ensm.2026.105028","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.105028","url":null,"abstract":"The practical deployment of aqueous zinc-ion batteries (AZIBs) faces fundamental constraints from irreversible degradation and catastrophic extreme-temperature failure. Herein, tetramethyl methylene-diphosphonate (TEMDP) is introduced by a molecular engineering-designing synergistic strategy involving double P=O group (zinc-affinity and hydrophilic) and -O- group (hydrogen bond receptor). Orchestrating dual mechanisms: reconstruction of solvation sheath through preferential Zn<ce:sup loc=\"post\">2+</ce:sup>-P=O coordination, which reduces de-solvation barriers and directs in-situ formation of the hybrid SEI with an organic C-F/C-O-rich outer layer (ensuring flexibility) and high ion-conductive Zn<ce:inf loc=\"post\">3</ce:inf>(PO<ce:inf loc=\"post\">4</ce:inf>)<ce:inf loc=\"post\">2</ce:inf>-ZnF<ce:inf loc=\"post\">2</ce:inf>-ZnS-ZnO inner layers (12.65 mS cm<ce:sup loc=\"post\">-1</ce:sup> under -30°C); Reprogramming of hydrogen-bond networks via competitive TEMDP-H<ce:inf loc=\"post\">2</ce:inf>O bonding benefiting from the hydrophilicity and high-electronegativity of P=O and -O- groups, enabling operation at -30°C while reducing hydrogen evolution at 60°C. This molecular synergy delivers excellent electrochemical resilience across an extreme temperature, including symmetric cell for 1960 h at 30°C and 1200 h at -20°C, alongside Zn||CaV<ce:inf loc=\"post\">6</ce:inf>O<ce:inf loc=\"post\">16</ce:inf>·3H<ce:inf loc=\"post\">2</ce:inf>O full cells maintaining 85.7% capacity after 7000 cycles at -20°C and no degradation through 1500 cycles at -30°C. Significantly, it demonstrates 80.3% capacity retention over 800 cycles at 60°C. This work establishes multifunctional synergistic molecular to unlock all-climate AZIBs for applications from North to desert energy storage.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"33 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147393166","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Orbital Regulation–Enabled Suppression of Jahn–Teller Distortion for Structurally Robust LiMnFePO4 Cathodes","authors":"Chao Ye, Wenqin Ling, Xiao Huang, Shan Fang, Xiaowei Huang, Naigen Zhou","doi":"10.1016/j.ensm.2026.105030","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.105030","url":null,"abstract":"Olivine-type LiMn<ce:inf loc=\"post\">x</ce:inf>Fe<ce:inf loc=\"post\">1-x</ce:inf>PO<ce:inf loc=\"post\">4</ce:inf> (LMFP) cathodes are attractive for lithium-ion batteries (LIBs) because of their intrinsic safety and low cost, yet their practical performance is limited by poor electronic conductivity and structural instability associated with Mn-induced Jahn–Teller (J–T) distortion. In this work, Al incorporation is shown to simultaneously improve charge transport and structural reversibility in LMFP. Density functional theory calculations combined with advanced structural characterizations indicate that Al<ce:sup loc=\"post\">3+</ce:sup> reduces the bandgap of LMFP and, more importantly, modifies the Mn 3d electronic configuration by lowering dz<ce:sup loc=\"post\">2</ce:sup> orbital occupancy and weakening eg orbital splitting. Such orbital-level modulation alleviates J–T distortion and reduces Mn–O bond-length variation during repeated lithiation and delithiation, leading to mitigated local lattice strain and suppressed Mn dissolution. As a result, the optimized LMFP/C-1Al cathode delivers a high specific capacity of 164.5 mAh g⁻<ce:sup loc=\"post\">1</ce:sup> at 0.1 C, a rate capability of 101.5 mAh g⁻<ce:sup loc=\"post\">1</ce:sup> at 10 C, and retains 98.7% of its capacity after 1000 cycles at 1 C. These results highlight orbital regulation as an effective route to stabilizing Mn-based olivine cathodes and provide mechanistic guidance for the design of durable phosphate cathode materials.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"14 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147393163","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Minimum Effective Thickness of Cathode Protective Layers for Sulfide-Based All-Solid-State Batteries via Powder-Atomic Layer Deposition","authors":"Kyu Moon Kwon, Minji Lee, Dae Ho Kim, Hyo Rang Kang, Tae Joo Park","doi":"10.1016/j.ensm.2026.105027","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.105027","url":null,"abstract":"Ultra-thin lithium niobium oxide (LNO) protective layers were conformally deposited onto LiNi_0.8Co_0.1Mn_0.1O₂ via a powder-atomic layer deposition process, and their thickness-dependent effects on sulfide-based all-solid-state batteries (ASSBs) performance are systematically examined under a 4.5 V vs Li/Li⁺ cut-off condition. The cells with 2.5 and 5 nm-thick LNO protective layers exhibit comparable cycling stability. In contrast, the cell with a 1 nm-thick LNO layer shows approximately 28% shorter cycle life and ∼59% higher interfacial resistance after 80 cycles compared to the cell with a 2.5 nm-thick LNO layer. The uncoated cell exhibits more severe degradation, with a 43% shorter cycle life and ∼145% higher interfacial resistance relative to the same reference. These results indicate that a 2.5 nm-thick LNO layer represents the minimum effective thickness required to mitigate interfacial degradation, thereby establishing a quantitative thickness criterion for cathode active materials protection in sulfide-based ASSBs.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"27 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147383893","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Single-Crystal Copper Foils with Exposed (100) Facet for Dendrite-Free Sodium Deposition Enables Ah-Level Anode-Free Sodium Batteries","authors":"Wen-Jie Shi, Xiao-Rui Wang, Min-Peng Li, Hong-Yan Li, Ming-Hui Yang, Hong-Tao Xue, Mao-Cheng Liu, Yu-Xia Hu, Bao Liu","doi":"10.1016/j.ensm.2026.105026","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.105026","url":null,"abstract":"Anode-free sodium batteries (AFSBs) are promising candidates for next-generation high energy density and superior cost-effectiveness energy storage systems. However, their cycle stability is hindered by the uncontrolled Na dendrite formation and consequent electrolyte depletion induced by exacerbated side reactions. Herein, dendrite-free Na deposition is realized on a single-crystal Cu substrate characterized by the preferential growth of (100) facet grains (denoted as Cu(100)) with high surface energy and the extensive elimination of grain boundary. Single-crystal Cu(100) substrate reduced heterogeneous Na nucleation Gibbs free energy and homogenized Na⁺ flux, achieving stable cycling by inducing a Frank-van der Merwe Na deposition mode. As a result, the Na||Cu(100) asymmetric battery shows a Coulombic efficiency (CE) of 99.82% and the Cu(100)@Na||Cu(100)@Na symmetric battery maintains stable cycling for over 1200 h at 0.5 mA cm⁻²/0.5 mAh cm⁻². The Cu(100)||Na₃V₂(PO₄)₃ anode-free battery achieves stable cycling performance for over 200 cycles with a capacity retention of 91.8%, delivering a high energy density of 302.5 Wh kg⁻¹. Remarkably, an Ah-level AFSB delivers stable cycling and achieves an high energy density of 163.5 Wh kg⁻¹ based on the total mass of battery. This work regulated the thermodynamic and kinetic behaviors of Na deposition through substrate facet engineering, providing novel insights into achieving dendrite-free deposition to enhance cycle stability and facilitate the practical deployment of high energy density AFSBs.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"81 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147371270","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Whole Greater Than the Sum of Its Parts: Composite-Electrolyte-Induced Rigid-Adaptive Interphase for Stabilizing a Lithium-Rich Cathode","authors":"Huiquan Che, Yuefeng Su, Jinyang Dong, Yun Lu, Jianan Hao, Yiya Wang, Teng Yang, Xinbai He, Yujia Wu, Ning Li, Xulai Yang, Tinglu Song, Lai Chen, Feng Wu","doi":"10.1016/j.ensm.2026.105020","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.105020","url":null,"abstract":"Stabilizing lithium-rich manganese-based layered oxides (LRMOs) during high-voltage cycling remains difficult for high-energy lithium-ion batteries because oxygen-redox reactions trigger severe surface reconstruction, dissolution of transition-metal ions, electrolyte breakdown, and the development of an unstable cathode-electrolyte interphase (CEI). These degradation routes become even more pronounced at elevated temperatures, where reactive oxygen species and electrolyte-generated fragments accelerate structural deterioration and promote rapid voltage fading. Achieving long-term LRMO stability, therefore, requires an interphase that provides both mechanical strength and chemical tolerance. Here, we propose a composite‑electrolyte strategy that integrates a mechanically robust inorganic framework (Al₂O₃) with a reactive film‑forming agent (lithium tri(tert‑butoxy)hydroaluminate, LTBA) to construct a rigid‑adaptive CEI on LRMO cathodes. This hybrid interphase synergistically combines the structural durability of Al₂O₃ with the chemical flexibility of LTBA, resulting in a uniform, continuous, and aluminum‑rich CEI that effectively suppresses oxygen‑driven side reactions, mitigates transition‑metal dissolution, and inhibits lattice distortion. Electrochemical evaluations demonstrate that the composite electrolyte significantly enhances the initial Coulombic efficiency, improves capacity retention, and reduces the average voltage decay rate by approximately 50%. Multiscale post‑cycling characterizations confirm attenuated surface reconstruction, preserved lattice ordering, and a more stable interfacial chemical environment. These findings establish an interphase design paradigm that integrates structural resilience with chemical responsiveness and highlights its potential for enabling stable operation of high-voltage, high-energy lithium-ion batteries.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"4 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147359738","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Heterointerface charge reorganization enables high-voltage sodium storage in NASICON-type cathodes","authors":"Shuoshuo Cheng, Chenchen Song, Miaorui Yang, Fan Li, Zhiyu Song, Shiyu Li, Peng Lv, Ying Bai","doi":"10.1016/j.ensm.2026.105024","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.105024","url":null,"abstract":"NASICON-type fluorophosphates are attractive cathode candidates for sodium-ion batteries due to their rigid frameworks and accessible multi-electron transition metal redox chemistry. Nevertheless, reconciling high operating voltage with long-term structural durability remains challenging. Here, a Na₃V₂(PO₄)₂F₃/Na₂MnPO₄F (NVPF/NMPF) heterostructure is constructed to modulate interfacial electronic states and promote stable high-voltage operation. Density functional theory calculations reveal pronounced interfacial charge redistribution, in which electron transfer from NMPF to NVPF strengthens the interfacial Mn-O-V covalency and stabilizes the high-potential V³⁺/V⁴⁺ redox transitions (∼3.7 and 4.2 V). This electronically coupled interface enhances structural robustness while accelerating both electronic conduction and Na⁺ transport. Benefiting from these synergistic effects, the NVPF/NMPF heterostructure delivers outstanding durability, retaining 82.7% of its capacity after 1000 cycles at 1 C and sustaining highly stable operation for over 10000 cycles at 50 C. These findings highlight the effectiveness of interfacial electronic engineering in designing heterostructure fluorophosphate cathodes with elevated energy output and extended cycling life.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"9 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147359739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Amide-Mediated Solvation Remodeling Enables Cryogenic High-Voltage Lithium Metal Batteries","authors":"Xuehui Shangguan, Rongmin Lu, Lina Liu, Siqi wang, Qinglei Wang, Qiuying Xu, Zunxiang Hu, Ping Li, Li Su, Huanqi Yao, Haixin Zhang, Jing Zhou, Faqiang Li","doi":"10.1016/j.ensm.2026.105021","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.105021","url":null,"abstract":"","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"48 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147359772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Highly Stable Composite Polymer Electrolyte with Covalent/Non-Covalent Network for Solid-State Zinc-Iodine Battery","authors":"Yang Su, Jingyuan Zhao, Dan Liu, Xinlu Wang, Jinxian Wang, Wensheng Yu, Xiangting Dong, Dongtao Liu","doi":"10.1016/j.ensm.2026.105023","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.105023","url":null,"abstract":"Zinc-iodine (Zn-I₂) batteries have emerged as promising candidates for next-generation energy storage systems due to their low cost, environmental friendliness, and inherent safety. However, challenges such as Zn dendrite growth, hydrogen evolution, and the shuttle effect of polyiodides in liquid electrolytes significantly hinder their practical applications. To address these issues, we propose a novel composite polymer electrolyte (CPE) with a dual-network design, integrating a 3D porous <em>β</em>-cyclodextrin polymer (CDP) framework and hollow spherical TiO₂ (H-TiO₂) nanoparticles through synergistic covalent/non-covalent interactions. The CDP is constructed by cross-linking flexible <em>β</em>-cyclodextrin (<em>β</em>-CD) units with rigid aryl-rich polymers of intrinsic microporosity (PIM-1), forming a mechanically robust and highly porous architecture. Within this network, H-TiO₂ nanoparticles are uniformly dispersed via hydrogen bonding with PEO chains and CDP functional groups, enhancing interfacial compatibility and ion transport pathways. The resulting electrolyte (PCPE-CDP-TiO₂) achieves an exceptional ionic conductivity of 9.4 × 10^-4 S cm^-1 at room temperature, and effectively suppresses Zn dendrite growth and polyiodide shuttling. Symmetrical Zn//Zn batteries with PCPE-CDP-TiO₂ exhibit reversible Zn plating/stripping for over 11000 hours at 5 mA cm^-2. Solid-state Zn-I₂ full batteries enables an ultra-long cycle life of 10000 cycles at 5 C. This work presents a molecular engineering strategy for designing high-performance CPEs.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"31 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147359773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Electrochemo-Mechanical-Thermal Dynamics of Internal Short Circuits in Batteries","authors":"Shuguo Sun, Bo Rui, Saurabh Bahuguna, Jun Zhou, Faisal Sayeed, Jun Xu","doi":"10.1016/j.ensm.2026.105022","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.105022","url":null,"abstract":"","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"5 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147360245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}