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Dynamic behavior on multi-stage sodium storage in disordered carbon 无序碳中钠的多级贮存动力学行为
IF 20.2 1区 材料科学
Energy Storage Materials Pub Date : 2025-09-16 DOI: 10.1016/j.ensm.2025.104607
Liang Yue , Yuhao Lu , Yi Zhang , ZhiYong Xiong , LiXin Bai , Zheng Yi , Yuansen Xie , MaoWen Xu , YuRuo Qi
{"title":"Dynamic behavior on multi-stage sodium storage in disordered carbon","authors":"Liang Yue ,&nbsp;Yuhao Lu ,&nbsp;Yi Zhang ,&nbsp;ZhiYong Xiong ,&nbsp;LiXin Bai ,&nbsp;Zheng Yi ,&nbsp;Yuansen Xie ,&nbsp;MaoWen Xu ,&nbsp;YuRuo Qi","doi":"10.1016/j.ensm.2025.104607","DOIUrl":"10.1016/j.ensm.2025.104607","url":null,"abstract":"<div><div>The structural complexity and heterogeneity of disordered carbons give rise to significant challenges in elucidating the sodiation mechanism in them. Herein, by means of a precisely controlled gaseous corrosion strategy, disordered carbon samples with tailored local structures are prepared elaborately so that we are able to unravel the sodium storage explicitly in such materials. In terms of results, a multi-stage sodium storage model comprising “physical adsorption - chemical interaction –(solid phase diffusion) - sodium cluster filling” is proposed. This work is the first to highlight the critical role of “solid phase diffusion” as an essential kinetic bridge, which is activated upon the saturation of defect sites and functional groups and governs the initial stage of sodium cluster formation within closed pores. Furthermore, our study reveals that sodium storage mechanisms are related to structures of disorder carbon materials, dictated by their defect concentrations, types and spatial distributions. It is demonstrated that a superior disordered carbon anode for a sodium ion battery necessitates an elaborate balance between abundant closed pores and moderate monovacancy-type defects so as to possess good capacity, rate performance and initial coulombic efficiency. With balanced features, the disordered carbon sample delivers a high reversible capacity of 367.1 mA h g<sup>-1</sup>, and the full cell achieves an energy density of 307.7 Wh kg⁻¹ while maintains 95.1 % capacity retention after 160 cycles. This research advances the understanding of sodium storage and provides new insights for engineering next-generation high-performance carbon anodes for sodium ion batteries.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"82 ","pages":"Article 104607"},"PeriodicalIF":20.2,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145072083","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrigendum to “Tuning Microstructures of Hard Carbon Anode by Rapid Pre-foaming Strategy for Superhigh-Rate Sodium-ion Storage Performance in Low-plateau Region” [Energy Storage Materials, Volume 78, May 2025, 104283] “通过快速预发泡策略调整硬碳阳极的微观结构以提高低高原地区的超高速率钠离子存储性能”[储能材料,vol . 78, May 2025, 104283]
IF 20.4 1区 材料科学
Energy Storage Materials Pub Date : 2025-09-16 DOI: 10.1016/j.ensm.2025.104616
Zhihua Xiao, Zechen Li, Yankun Sun, Fangzhi Zheng, Chong Xu, Dong Sun, Shuang Liu, Bo Sun, Ziang Wang, Sijia Liao, Taoyuan Pan, Qiang Ye, Tao Li, Chunming Xu, Yongfeng Li
{"title":"Corrigendum to “Tuning Microstructures of Hard Carbon Anode by Rapid Pre-foaming Strategy for Superhigh-Rate Sodium-ion Storage Performance in Low-plateau Region” [Energy Storage Materials, Volume 78, May 2025, 104283]","authors":"Zhihua Xiao, Zechen Li, Yankun Sun, Fangzhi Zheng, Chong Xu, Dong Sun, Shuang Liu, Bo Sun, Ziang Wang, Sijia Liao, Taoyuan Pan, Qiang Ye, Tao Li, Chunming Xu, Yongfeng Li","doi":"10.1016/j.ensm.2025.104616","DOIUrl":"https://doi.org/10.1016/j.ensm.2025.104616","url":null,"abstract":"The authors regret there were errors in Section 4.4. We should revise the title of Section 4.4 of the article from \"DFT\" to \"Molecular Dynamics Simulation\", and the content on Page 11 from \"For further understanding the optimization mechanism of various closed pore sizes and carbon interlayer spacings on the Na<sup>+</sup> storage capability, the density functional theory (DFT) calculations have been performed.\" to \"For further understanding the optimization mechanism of various closed pore sizes and carbon interlayer spacings on the Na<sup>+</sup> storage capability, the molecular dynamics simulations have been performed.\" In addition, the authors information about “Prof. Zhihua Xiao, Prof. Chunming Xu and Prof. Yongfeng Li” should be replaced by “Zhihua Xiao, Chunming Xu, Yongfeng Li”.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"52 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145072429","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sculpturing Cu current collector to enhance lithium metal electrochemistry 雕刻铜集热器,提高锂金属电化学性能
IF 20.2 1区 材料科学
Energy Storage Materials Pub Date : 2025-09-16 DOI: 10.1016/j.ensm.2025.104602
Enlan Deng, Xueyi Lu, Yang Sun, Xia Lu
{"title":"Sculpturing Cu current collector to enhance lithium metal electrochemistry","authors":"Enlan Deng,&nbsp;Xueyi Lu,&nbsp;Yang Sun,&nbsp;Xia Lu","doi":"10.1016/j.ensm.2025.104602","DOIUrl":"10.1016/j.ensm.2025.104602","url":null,"abstract":"<div><div>The relentless pursuit of high energy density has driven significant interest in lithium metal batteries with anode-free configuration. Despite the ultra-high theoretical capacity, the inherent electrochemical instability of lithium metal-based anode remains a critical obstacle to the commercialization. In this context, rational design of Cu current collectors with optimized architectures and interfacial properties emerges as a pivotal strategy to make full advantage of Li metal anode. Based on state-of-the-art current collector modification strategies, this review highlights three promising strategies, namely structural design of 3D frameworks to regulate lithium deposition, lithiophilic modification to homogenize nucleation behavior, and interfacial protection layers to stabilize electrode/electrolyte interfaces, all of which are critically analyzed regarding its mechanistic advantages, implementation complexity, and limitations in practical applications to enhance the electrochemical performance of lithium metal batteries. The future developments are then provided, including dynamically integrating to create multi-level synergistic mechanisms, conducting in-depth investigations into the lithium deposition and solid electrolyte interphase formation, and constructing safe, high-energy-density battery systems suitable for commercialization of high energy density lithium metal batteries.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"82 ","pages":"Article 104602"},"PeriodicalIF":20.2,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145067912","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Inside lithium–sulfur batteries: Real-time multimodal insights into structure and polysulfide dynamics 锂硫电池内部:实时多模态洞察结构和多硫化物动力学
IF 20.2 1区 材料科学
Energy Storage Materials Pub Date : 2025-09-16 DOI: 10.1016/j.ensm.2025.104617
Mustafa Khan , Liyuan Qian , Zhiqian Lin , Yun Wang , Haibin Lin , Xiaofei Wang , Songbai Han , Jinlong Zhu
{"title":"Inside lithium–sulfur batteries: Real-time multimodal insights into structure and polysulfide dynamics","authors":"Mustafa Khan ,&nbsp;Liyuan Qian ,&nbsp;Zhiqian Lin ,&nbsp;Yun Wang ,&nbsp;Haibin Lin ,&nbsp;Xiaofei Wang ,&nbsp;Songbai Han ,&nbsp;Jinlong Zhu","doi":"10.1016/j.ensm.2025.104617","DOIUrl":"10.1016/j.ensm.2025.104617","url":null,"abstract":"<div><div>Lithium–sulfur (Li–S) batteries are increasingly designated as a viable choice for future energy storage systems, owing to their substantial theoretical energy density, economic viability, and the abundant availability of sulfur. However, despite their significant potential, widespread commercialization has been limited by major obstacles, encompassing the polysulfide shuttle effect, slow sulfur redox reaction dynamics, and substantial structural degradation during cycling. To overcome these limitations and fully realize the optimal strength of Li–S batteries, a comprehensive comprehension of the fundamental electrochemical processes and real-time morphological changes during operation is crucial. This study offers a wide-ranging evaluation of recent progress in in situ and operando methods that enable direct observations of the dynamic behavior of Li–S systems under real-world conditions. Techniques including neutron scattering, X-ray tomography, X-ray reflectometry (XRR), Raman spectroscopy, small-angle neutron scattering (SANS), transmission electron microscopy (TEM), and atomic force microscopy (AFM) are examined in detail for their ability to monitor key processes like polysulfide dissolution, phase transitions, and electrochemical reactions. This review emphasizes a comparative and integrative perspective, highlighting how different diagnostic techniques collectively address critical challenges such as polysulfide migration, sluggish Li<sub>2</sub>S conversion, and electrode degradation. Furthermore, the review highlights future research avenues aimed at enhancing these experimental techniques and integrating computational models to deepen our understanding of battery degradation mechanisms. The role of machine learning in predicting battery behavior and optimizing performance is also discussed as a key area for future exploration. This review emphasizes the transformative potential of real-time monitoring in overcoming the challenges encountered by Li–S batteries, accelerating their development toward widespread adoption and large-scale application.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"82 ","pages":"Article 104617"},"PeriodicalIF":20.2,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145068034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nucleation-Driven Volcano Effect via Interface Synergy for Stable Zn-Ion Batteries 稳定锌离子电池的界面协同成核驱动火山效应
IF 20.4 1区 材料科学
Energy Storage Materials Pub Date : 2025-09-16 DOI: 10.1016/j.ensm.2025.104619
Guosheng Duan, Kun Zhang, Yang Wang, Leilei Sun, Bin Luo, Sinan Zheng, Zhean Bao, Maojun Zhou, Hanwei Hu, Dinghao Chen, Li Gong, Zhizhen Ye, Jingyun Huang
{"title":"Nucleation-Driven Volcano Effect via Interface Synergy for Stable Zn-Ion Batteries","authors":"Guosheng Duan, Kun Zhang, Yang Wang, Leilei Sun, Bin Luo, Sinan Zheng, Zhean Bao, Maojun Zhou, Hanwei Hu, Dinghao Chen, Li Gong, Zhizhen Ye, Jingyun Huang","doi":"10.1016/j.ensm.2025.104619","DOIUrl":"https://doi.org/10.1016/j.ensm.2025.104619","url":null,"abstract":"The commercial viability of aqueous Zn-ion batteries is hindered by dendrite growth and parasitic side reactions. Natural amino acid-inspired additives with tailored adsorption-coordination synergy present a promising strategy to regulate Zn electrodeposition. Herein, we systematically investigated six C4-chain molecules with distinct functional groups and established a volcano-shaped relationship between adsorption-coordination interactions and electrochemical performance. Succinamic acid (SuaA), which has balanced adsorption and coordination strengths, induces 3D-progressive nucleation and (002)-textured growth via a nucleation-driven volcano mechanism that minimizes interfacial charge transfer resistance. The optimized Zn||Zn symmetric cell achieves an ultra-long cycle stability of 7500 hours, and can operate stably for 500 hours even at a discharge depth of about 85.5%. The Zn||Cu asymmetric cell demonstrates a Coulombic efficiency of 99.75%, and Zn||NaV3O8·1.5H₂O full cell retains &gt;80% capacity after 400 cycles at an actual N/P ratio of 3.66. This work establishes a universal design principle balancing adsorption-coordination interplay for dendrite-free AZIBs.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"15 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145067900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic regulation of closed pore architecture and interface engineering in hard carbon for high energy density sodium-ion batteries 高能量密度钠离子电池用硬炭闭孔结构与界面工程的协同调控
IF 20.2 1区 材料科学
Energy Storage Materials Pub Date : 2025-09-15 DOI: 10.1016/j.ensm.2025.104612
Zhaoxin Yu , Xue Li , Ning Sun , He Chen , Razium Ali Soomro , Bin Xu
{"title":"Synergistic regulation of closed pore architecture and interface engineering in hard carbon for high energy density sodium-ion batteries","authors":"Zhaoxin Yu ,&nbsp;Xue Li ,&nbsp;Ning Sun ,&nbsp;He Chen ,&nbsp;Razium Ali Soomro ,&nbsp;Bin Xu","doi":"10.1016/j.ensm.2025.104612","DOIUrl":"10.1016/j.ensm.2025.104612","url":null,"abstract":"<div><div>Hard carbon with extended low-potential plateau capacity holds promise for commercial sodium-ion batteries (SIBs). However, the complicated microstructure of hard carbon poses significant challenges in rationally designing active sites to improve reversible Na-storage capacity without compromising initial Coulombic efficiency (ICE). Herein, hard carbons with elaborate closed pore structures and tunable pore entrances were successfully fabricated using waste polyolefins-derived activated carbon (PC) as the precursor. The regulation of porosity architecture was realized by adjusting the deposited carbon layer derived from the polypropylene (PP)-based light aromatic compounds. The optimal PP/PC-3 electrode exhibited an ultra-high reversible capacity of 393.5 mAh g<sup>−1</sup> and an ICE of up to 88.5% in the ester-based electrolytes. While in the ether-based systems, the Na-storage capacity reached 477.3 mAh g<sup>−1</sup>, with a capacity of 340.3 mAh g<sup>−1</sup> stemming from the low-voltage plateau region. The anode also demonstrates excellent low-temperature compatibility as well as exceptional cycling stability. Additionally, the assembled sodium-ion full battery achieved an energy density as high as 307.3 Wh kg<sup>−1</sup>, suggesting its prospective application in high-energy-density SIBs. Furthermore, the differences in the Li/Na/K ion storage process within closed pores were elucidated, providing a deep insight into the structure engineering of carbon anode for advanced energy storage devices.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"82 ","pages":"Article 104612"},"PeriodicalIF":20.2,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145059713","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A binary contact-curved nano-shield design for separators to suppress dendrite formation for stable lithium-metal batteries 一种用于抑制稳定锂金属电池枝晶形成的二元接触弯曲纳米屏蔽隔膜设计
IF 20.2 1区 材料科学
Energy Storage Materials Pub Date : 2025-09-15 DOI: 10.1016/j.ensm.2025.104613
Manxian Li , Ziwei Yuan , Xiaochuan Chen , Junxiong Wu , So Yeon Kim , Xiaoyan Li , Jingyue Zhao , Zulin Li , Xuan Li , Lijuan Tong , Chuanping Li , Yiu-Wing Mai , Yuming Chen
{"title":"A binary contact-curved nano-shield design for separators to suppress dendrite formation for stable lithium-metal batteries","authors":"Manxian Li ,&nbsp;Ziwei Yuan ,&nbsp;Xiaochuan Chen ,&nbsp;Junxiong Wu ,&nbsp;So Yeon Kim ,&nbsp;Xiaoyan Li ,&nbsp;Jingyue Zhao ,&nbsp;Zulin Li ,&nbsp;Xuan Li ,&nbsp;Lijuan Tong ,&nbsp;Chuanping Li ,&nbsp;Yiu-Wing Mai ,&nbsp;Yuming Chen","doi":"10.1016/j.ensm.2025.104613","DOIUrl":"10.1016/j.ensm.2025.104613","url":null,"abstract":"<div><div>The development of mechanically robust interfacial barriers is critical to address lithium (Li) dendrite penetration through separators in Li-metal batteries (LMBs) during prolonged cycling. Herein, we propose a novel binary contact-curved (BC) nano-shield separator architecture, characterized by two fibers positioned side-by-side in close contact, forming a unique curved interface. Mechanical analysis and multiphysics simulations demonstrate that the geometry of the BC separator effectively mitigates localized stress, while its enhanced effective Young's modulus compared to the single-curved (SC) counterpart significantly suppresses Li dendrite growth. Besides, the unique structure of the BC separator endows it with superior electrolyte affinity, achieving exceptional wettability and enhanced ionic conductivity. As a proof of concept, Li||LiFePO<sub>4</sub> (LFP) and Li||sulfurized polyacrylonitrile (SPAN) full cells using this BC separator demonstrate outstanding electrochemical performance, including extended cycle life and distinguished rate capability. Furthermore, the BC separator also shows outstanding compatibility with a range of alkali metal batteries across diverse electrolyte systems, consistently delivering significant performance improvements. This work establishes a universal design paradigm for next-generation separators, advancing the development of safe, high-performance alkali metal anode batteries for energy storage applications.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"82 ","pages":"Article 104613"},"PeriodicalIF":20.2,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145059710","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dynamics-enhanced sandwich solid-state electrolyte separator for wide-temperature operation of lithium metal batteries 用于锂金属电池宽温运行的动态增强夹层固态电解质分离器
IF 20.2 1区 材料科学
Energy Storage Materials Pub Date : 2025-09-15 DOI: 10.1016/j.ensm.2025.104614
Huipeng Zeng , Qingrong Wang , Chunyu Liu , Kai Yu , Ruilin He , Xiaoqi Wu , Xu Yan , Guangzhao Zhang , Hongli Xu , Jun Wang , Chaoyang Wang , Jijian Xu , Yonghong Deng , Xiaoxiong Xu , Shang-Sen Chi
{"title":"Dynamics-enhanced sandwich solid-state electrolyte separator for wide-temperature operation of lithium metal batteries","authors":"Huipeng Zeng ,&nbsp;Qingrong Wang ,&nbsp;Chunyu Liu ,&nbsp;Kai Yu ,&nbsp;Ruilin He ,&nbsp;Xiaoqi Wu ,&nbsp;Xu Yan ,&nbsp;Guangzhao Zhang ,&nbsp;Hongli Xu ,&nbsp;Jun Wang ,&nbsp;Chaoyang Wang ,&nbsp;Jijian Xu ,&nbsp;Yonghong Deng ,&nbsp;Xiaoxiong Xu ,&nbsp;Shang-Sen Chi","doi":"10.1016/j.ensm.2025.104614","DOIUrl":"10.1016/j.ensm.2025.104614","url":null,"abstract":"<div><div>The separator is an essential component of the battery, and its performance can be significantly enhanced through modifications. Some studies have attempted to use solid-state electrolytes as coating materials to replace inert materials that do not participate in ion transport. However, the mechanism of the solid-state electrolyte coatings remains elusive and lacks in-depth investigation. Herein, a dynamics-enhanced separator (SWS@PE) is designed by using LLZTO and LATP as asymmetric coating materials. The solid-state electrolyte coatings not only participate in Li<sup>+</sup> transport, but the LLZTO layer also absorbs FSI<sup>−</sup> to help Li<sup>+</sup> desolvation, which enhances Li<sup>+</sup> transport dynamics and enables excellent capacity release at low temperatures. Additionally, the LATP layer can absorb dissolved transition metal ions and inhibit the formation of the rock salt phase, further extending the stable cycling of the high-nickel cathode at elevated temperatures. Ultimately, Li||NCM811 cell using SWS@PE with excellent physical and electrochemical properties achieves better capacity release and retention across a wider temperature range. Notably, the 355 mAh Li||NCM83 pouch cell achieves excellent capacity retention of 95.89 % after 150 cycles. This work provides insight into the interfacial mechanism of solid-state electrolyte coatings and offers a new perspective on separator modification.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"82 ","pages":"Article 104614"},"PeriodicalIF":20.2,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145059709","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dual-halide engineered interphases for combustion-resistant and high-performance sodium-based batteries 用于耐燃和高性能钠基电池的双卤化物工程界面
IF 20.2 1区 材料科学
Energy Storage Materials Pub Date : 2025-09-15 DOI: 10.1016/j.ensm.2025.104615
Xinru Zhang , Longfei Han , Yukun Cao , Liying Cheng , Xiangfei Ren , Yongchun Kan , Jixin Zhu , Yuan Hu
{"title":"Dual-halide engineered interphases for combustion-resistant and high-performance sodium-based batteries","authors":"Xinru Zhang ,&nbsp;Longfei Han ,&nbsp;Yukun Cao ,&nbsp;Liying Cheng ,&nbsp;Xiangfei Ren ,&nbsp;Yongchun Kan ,&nbsp;Jixin Zhu ,&nbsp;Yuan Hu","doi":"10.1016/j.ensm.2025.104615","DOIUrl":"10.1016/j.ensm.2025.104615","url":null,"abstract":"<div><div>Unstable electrode-electrolyte interfaces in high-voltage sodium-ion batteries (SIBs) significantly hinder Na<sup>+</sup> transport and pose severe safety risks. Herein, we propose a cost-effective strategy by introducing trichloromethane (TCM) as an additive into conventional carbonate-based electrolytes. This approach enables the in situ formation of a robust chlorine/fluorine-rich interphase that enhances Na<sup>+</sup> transport kinetics and provides intrinsic flame retardancy. The interphase suppresses flammability through the release of chlorine radicals, effectively mitigating combustion in 1 Ah pouch cells. As a result, the modified electrolyte enables Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub>/Na cells to retain 80.6% of their capacity over 800 cycles at 1 C and 4.3 V at room temperature, and 92.1% after 150 cycles at 4.5 V. Furthermore, under wide voltage windows and harsh thermal conditions, the cells maintain 87.8% and 98.0% capacity retention after 440 and 200 cycles at 55 °C and -24 °C, respectively, Fast-charging capability is also retained. This work demonstrates a feasible and scalable electrolyte design that simultaneously improves interfacial stability, thermal safety, and high-voltage operation. It also offers mechanistic insights into designing safer, high-performance sodium-based batteries.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"82 ","pages":"Article 104615"},"PeriodicalIF":20.2,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145059711","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The high-temperature adaptive interfacial chemistry engineering of sulfolane-based electrolytes enables long-cycle lithium-ion batteries under extreme temperatures (≥80 °C) 磺胺基电解质的高温自适应界面化学工程使锂离子电池在极端温度(≥80 °C)下实现长循环。
IF 20.2 1区 材料科学
Energy Storage Materials Pub Date : 2025-09-14 DOI: 10.1016/j.ensm.2025.104610
Xianhui Zhao , Sai Li , Yan Zhou , Zheng Liu , Rang Xiao , Fangmin Wu , Geping Yin , Pengjian Zuo , Yulin Ma , Guokang Han , Chunyu Du
{"title":"The high-temperature adaptive interfacial chemistry engineering of sulfolane-based electrolytes enables long-cycle lithium-ion batteries under extreme temperatures (≥80 °C)","authors":"Xianhui Zhao ,&nbsp;Sai Li ,&nbsp;Yan Zhou ,&nbsp;Zheng Liu ,&nbsp;Rang Xiao ,&nbsp;Fangmin Wu ,&nbsp;Geping Yin ,&nbsp;Pengjian Zuo ,&nbsp;Yulin Ma ,&nbsp;Guokang Han ,&nbsp;Chunyu Du","doi":"10.1016/j.ensm.2025.104610","DOIUrl":"10.1016/j.ensm.2025.104610","url":null,"abstract":"<div><div>With the growing demand for lithium-ion batteries (LIBs) capable of reliable operation under extreme high-temperature conditions (≥60 °C), conventional carbonate-based electrolytes face critical limitations due to thermal instability and interfacial degradation. In this study, we develop a sulfolane (SL)-based electrolyte incorporating fluorine-free vinylene carbonate (VC) as a functional additive to construct a high-temperature adaptive interfacial chemistry strategy. VC, featuring moderate coordination ability and interfacial passivation capability, enables controllable formation of thermally stable solid electrolyte interphases (SEIs). Systematic analysis reveals that increasing temperature induces a transition from solvent-separated ion pairs (SSIPs) to contact ion pairs (CIPs) and aggregated ion clusters (AGGs), which promotes the formation of a composite SEI comprising LiF-rich inorganic phases and poly(VC) networks. The interwoven SEI exhibits excellent mechanical integrity, thermal robustness, and facilitates efficient Li⁺ transport. Electrochemical evaluations demonstrate that the SL-based electrolyte enables graphite half-cells to retain 95.89 % of capacity after 200 cycles at 60 °C, and pouch cells (NCM523||graphite) maintain 89.55 % of capacity after 1000 cycles at 60 °C, outperforming conventional systems. These results highlight the potential of SL-based electrolytes for safe and long-lasting high-temperature LIB applications.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"82 ","pages":"Article 104610"},"PeriodicalIF":20.2,"publicationDate":"2025-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145056978","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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