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Linking microscopic network structure to macroscopic rheological properties in polydimethylsiloxane composite fluids 聚二甲基硅氧烷复合流体微观网络结构与宏观流变性能的联系
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-28 DOI: 10.1016/j.compscitech.2025.111193
Siyuan Cheng , Yimin Wei , Gaohong Lv , Xiangchao Xie , Jiahui Wang , Shujun Cai , Yabiao Ma , Jian-Bin Xu , Xiaoliang Zeng , Rong Sun
{"title":"Linking microscopic network structure to macroscopic rheological properties in polydimethylsiloxane composite fluids","authors":"Siyuan Cheng ,&nbsp;Yimin Wei ,&nbsp;Gaohong Lv ,&nbsp;Xiangchao Xie ,&nbsp;Jiahui Wang ,&nbsp;Shujun Cai ,&nbsp;Yabiao Ma ,&nbsp;Jian-Bin Xu ,&nbsp;Xiaoliang Zeng ,&nbsp;Rong Sun","doi":"10.1016/j.compscitech.2025.111193","DOIUrl":"10.1016/j.compscitech.2025.111193","url":null,"abstract":"<div><div>Polydimethylsiloxane-based composite fluids are extensively utilized as thermal interface materials for heat dissipation of chips, due to their high thermal conductivity and distinctive rheological behaviors. However, establishing direct correlations between macroscopic rheological properties and microscopic structures has proven challenging. Here, using micron sized platelet boron nitride (BN) and spherical aluminum oxide (Al<sub>2</sub>O<sub>3</sub>) as model fillers, we elucidate the relationship between the microscopic network structure and the macroscopic rheological properties of polydimethylsiloxane (PDMS) based composite fluids by analyzing the particle networks in conjunction with scaling theory. We find that the rheology properties of the Al<sub>2</sub>O<sub>3</sub>/PDMS composite fluids are different from those of the BN/PDMS composite fluids, where the Al<sub>2</sub>O<sub>3</sub>/PDMS composite fluids increase hyper exponentially with filling volume fraction, but the BN/PDMS composite fluids increases exponentially. The thixotropic properties reveal that the spherical Al<sub>2</sub>O<sub>3</sub> particles have high recovery rate, but the platelet BN contributes to a low recovery rate. The difference in rheological performance between BN and Al<sub>2</sub>O<sub>3</sub> stems from the interparticle forces and particle networks: BN particles surprisingly form colloidal-style clusters and particle networks, whereas Al<sub>2</sub>O<sub>3</sub> particles create a volume-repulsion-dominated jamming structure. Using these two composite fluids as thermal interface materials, we demonstrate that the BN/PDMS composite fluids capable with better dispensing operation performance and better ability of heat dissipation for chip than the Al<sub>2</sub>O<sub>3</sub>/PDMS composite fluids.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"267 ","pages":"Article 111193"},"PeriodicalIF":8.3,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143892164","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultralight, flexible, and breathable Bi-modified W18O49/MWCNTs/PAN hybrid nanofiber membrane for NIR/VIS/UV/X-ray broadband electromagnetic shielding 用于近红外/可见/紫外/ x射线宽带电磁屏蔽的bi改性W18O49/MWCNTs/PAN杂化纳米纤维膜
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-28 DOI: 10.1016/j.compscitech.2025.111211
Xin Qu , Ce Wang , Yuanyu Zhao , Jinqiu Ye , Ping Hu , Rui Zhao , Yong Liu
{"title":"Ultralight, flexible, and breathable Bi-modified W18O49/MWCNTs/PAN hybrid nanofiber membrane for NIR/VIS/UV/X-ray broadband electromagnetic shielding","authors":"Xin Qu ,&nbsp;Ce Wang ,&nbsp;Yuanyu Zhao ,&nbsp;Jinqiu Ye ,&nbsp;Ping Hu ,&nbsp;Rui Zhao ,&nbsp;Yong Liu","doi":"10.1016/j.compscitech.2025.111211","DOIUrl":"10.1016/j.compscitech.2025.111211","url":null,"abstract":"<div><div>Human activities, ranging from medical applications to space exploration, face significant threats from multiband electromagnetic radiation. This challenge is particularly pronounced in the complex radiation environments of space. There is an urgent need for high-efficiency, stable broadband electromagnetic shielding materials to safeguard human health and equipment safety. Herein, a Bi-modified W<sub>18</sub>O<sub>49</sub>/MWCNTs/PAN hybrid nanofiber membrane is successfully prepared by electrospinning and post-treatment. Relying on the synergistic effect of Bi, W<sub>18</sub>O<sub>49</sub>, MWCNTs, and porous structures, excellent broadband radiation protection capability is achieved: (i) Low near-infrared-visible-light (NIR-VIS) transmittance (0.62 %); (ii) Ultraviolet (UV) transmittance of only 0.012 % and UPF value as high as 2000; (iii) Mass attenuation coefficient up to 16.18 cm<sup>2</sup> g<sup>−1</sup> and attenuation ratio of 85.74 % (thickness: 4 mm) at 33 keV X-ray energy. Furthermore, porous structure and high specific surface area give the membrane ultralight density (0.36 g cm<sup>−3</sup>), flexibility, and outstanding air permeability (8.5 kg m<sup>−2</sup> d<sup>−1</sup>). Even after 2000 bends, it still maintains stable structure and performance. Meanwhile, low thermal conductivity (42.2 mW m<sup>−1</sup> K<sup>−1</sup>) and superior temperature resistance (300 °C) enable it to adapt to complex and changing environments. These advantages make the membrane highly promising for radiation protection in medical, industrial, and aerospace applications.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"267 ","pages":"Article 111211"},"PeriodicalIF":8.3,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143882992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cartilage-inspiration for constructing photothermal-driven, weather-resistant, self-healing and long-term anti-corrosion dual-layer coating 软骨-灵感用于构建光热驱动,耐候性,自修复和长期防腐的双层涂层
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-25 DOI: 10.1016/j.compscitech.2025.111207
Weixiang Xu , Hao Liu , Aihua Tang , Jia Jiang , Zewen Wu , Hanzhong Ren , Rong Jia , Yiting Xu , Birong Zeng , Conghui Yuan , Lizong Dai
{"title":"Cartilage-inspiration for constructing photothermal-driven, weather-resistant, self-healing and long-term anti-corrosion dual-layer coating","authors":"Weixiang Xu ,&nbsp;Hao Liu ,&nbsp;Aihua Tang ,&nbsp;Jia Jiang ,&nbsp;Zewen Wu ,&nbsp;Hanzhong Ren ,&nbsp;Rong Jia ,&nbsp;Yiting Xu ,&nbsp;Birong Zeng ,&nbsp;Conghui Yuan ,&nbsp;Lizong Dai","doi":"10.1016/j.compscitech.2025.111207","DOIUrl":"10.1016/j.compscitech.2025.111207","url":null,"abstract":"<div><div>The economic and social damages caused by steel corrosion are enormous, and the development of efficient and long-term anti-corrosion coatings has become a key challenge. The aim of this study was to develop a novel, photothermal self-repairing, intelligent, weather resistance, and anti-corrosion composite coating. In this study, cartilage-inspired tannic acid (TA)-modified MXene multifunctional filler (MT) was prepared by a hydrothermal method and combined with self-healing polyurethane (PU-SS-Salen-Ni) to form a topcoat, while epoxy resin (901) was selected as the primer. The network structure of MT endowed the polyurethane with highly efficient photo-thermal conversion ability, which could increase the local temperature of the material to more than 80 °C within 60s. It also gives the coating excellent weathering resistance. Thanks to the synergistic effect of the active anticorrosive properties of MXene, the passive anticorrosive effect of tannic acid, and the self-healing polyurethane epoxy double-layer coating on the substrate, the composites exhibited excellent anticorrosive properties (|Z|<sub>f = 0.01Hz</sub> &gt; 1 × 10<sup>11</sup> Ω cm<sup>2</sup>) after 180 days of immersion in 3.5 % NaCl solution. Therefore, the present work successfully realized polyurethane materials with active/passive corrosion protection and self-healing functions through MT networks, and innovatively introduced and studied the organic double-layer coating structure, which provides a new solution in the field of corrosion prevention, weathering, and photo-thermal conversion self-healing.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"267 ","pages":"Article 111207"},"PeriodicalIF":8.3,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143882991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-functional MOF-CNT polymer aerogels: A novel design for low-frequency sound-absorbing and thermal insulation 多功能MOF-CNT聚合物气凝胶:一种低频吸声和隔热的新设计
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-25 DOI: 10.1016/j.compscitech.2025.111208
Shu-Ting Fan , Dong-Lin Guo , Jing-Li , Ye-Tao Zhang , Bang-Jing Li , Sheng Zhang
{"title":"Multi-functional MOF-CNT polymer aerogels: A novel design for low-frequency sound-absorbing and thermal insulation","authors":"Shu-Ting Fan ,&nbsp;Dong-Lin Guo ,&nbsp;Jing-Li ,&nbsp;Ye-Tao Zhang ,&nbsp;Bang-Jing Li ,&nbsp;Sheng Zhang","doi":"10.1016/j.compscitech.2025.111208","DOIUrl":"10.1016/j.compscitech.2025.111208","url":null,"abstract":"<div><div>Absorbing low frequency sound below 500 Hz with ultra-lightweight materials is a key challenge due to the structural homogeneity of existing sound absorbing materials. In order to address the challenge of combining enhanced low frequency sound absorption, mechanical robustness, moisture resistance and thermal insulation, this study proposes a new multiple acoustic material design. Coaxial electrostatic spinning was used to introduce MOF and CNT acoustic additives into the polymer matrix in a single step. The addition of PI and directional freezing then led to the formation of radially aligned lamellar structures within the electrospun fibers and PI polymer aerogel. It was found that PI/CZ-X aerogels with a radical porous structure, nanofibres and acoustic absorbing additives with high MOF-CNT content show excellent low frequency sound absorption properties (up to 0.99 at low frequencies of 500 Hz, 0.5 at low frequencies of 200 Hz and an NRC coefficient of 0.70), excellent thermal insulation properties (thermal conductivity of approximately 24.03 mW/mK), super elasticity (deformation returns to 90 % of its original value after 1000 cycles of compression) and hydrophobic properties (water contact angle of 140°). This work provides an effective strategy to design low-frequency broadband acoustic absorption materials.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"267 ","pages":"Article 111208"},"PeriodicalIF":8.3,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143887315","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Process modeling and deformation prediction of 3D printed continuous fiber-reinforced composites based on in-situ micro-scale measuring 基于原位微尺度测量的3D打印连续纤维增强复合材料过程建模与变形预测
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-24 DOI: 10.1016/j.compscitech.2025.111209
Shiping Ouyang, Dongsheng Li, Weijun Zhu, Long Fu, Zhikun Zhang, Ning Wang, Quan Zhi
{"title":"Process modeling and deformation prediction of 3D printed continuous fiber-reinforced composites based on in-situ micro-scale measuring","authors":"Shiping Ouyang,&nbsp;Dongsheng Li,&nbsp;Weijun Zhu,&nbsp;Long Fu,&nbsp;Zhikun Zhang,&nbsp;Ning Wang,&nbsp;Quan Zhi","doi":"10.1016/j.compscitech.2025.111209","DOIUrl":"10.1016/j.compscitech.2025.111209","url":null,"abstract":"<div><div>3D printing of continuous fiber-reinforced thermoplastic composites (CFRTPCs) is a promising manufacturing technology. However, deformation caused by the release of residual stresses in printed parts remains unavoidable, and there is a lack of accurate and comprehensive measurements or models addressing the microscopic factors behind their formation. This paper presents in-situ measurements of process parameters related to residual stress formation, including temperature gradients, printing force fields, and deformation of printed samples. As temperature is a key factor contributing to residual stresses, this study introduces an in-situ micro-scale characterization method for the printing temperature field using temperature-sensitive prepreg filaments. The method enables accurate measurement of the full life cycle temperature data across different microscopic regions of the prepreg filament during printing. Using the measured data, including temperature, printing pressure, and tension force, this paper proposes a multi-scale process modeling method referred to as the “extrusion process-printing process combination”. This model simulates the temperature field distribution during the extrusion process, as well as the residual stress and deformation during the printing process. Simulation results were validated by experiments, with an error margin of less than 5 %. Using this model, the preliminary process optimization for reducing the residual stress was carried out. In addition, the effects of various process parameters on the temperature gradient during printing and the deformation of printed samples were analyzed. The results show that by optimizing the printing process, it is expected to reduce the generation of residual stresses in composite printed products.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"267 ","pages":"Article 111209"},"PeriodicalIF":8.3,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143879137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MXene triggered double conductive mechanism hydrogels for strain sensing with electromagnetic interference shielding performance 具有电磁干扰屏蔽性能的MXene触发双导电机制应变传感水凝胶
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-24 DOI: 10.1016/j.compscitech.2025.111210
Haofei Sima , Bo Liu , Jingshi Liang , Xiaolin Shi , Chunling Zhang
{"title":"MXene triggered double conductive mechanism hydrogels for strain sensing with electromagnetic interference shielding performance","authors":"Haofei Sima ,&nbsp;Bo Liu ,&nbsp;Jingshi Liang ,&nbsp;Xiaolin Shi ,&nbsp;Chunling Zhang","doi":"10.1016/j.compscitech.2025.111210","DOIUrl":"10.1016/j.compscitech.2025.111210","url":null,"abstract":"<div><div>Highly conductive and super-tough acrylamide hydrogels are essential for the development of flexible electronics. However, the inherent electrical and mechanical deficiencies of polyacrylamide (PAM) impede their utilization in flexible electronics. To address this challenge, a novel double-crosslinking method for rapid gelation based on an MXene-initiated poly (acrylamide/vinylimidazole) (MPAV) system is presented in this paper. MXene rapidly initiated the copolymerization of acrylamide with ionic liquids and acted as a physical cross-linking point for dynamic and reversible physical interactions with the polymer chains. The copolymerization of ionic liquids solved the problem of MXene aggregation in the medium and enabled the ionic conductivity mechanism of directional movement of free ions inside the MPAV hydrogel. MPAV hydrogels exhibited high electrical conductivity (2.28 S/m), excellent electromagnetic interference shielding efficiency (SE<sub>t</sub> &gt; 35 dB), and sensitive strain sensing properties (maximum gauge factor: 14.69 and maximum sensitivity: 0.124 kPa<sup>−1</sup>). The well-designed MPAV double crosslinked hydrogel also displays remarkable mechanical properties (elongation: 457 % and compressibility: 80 %) and self-healing capabilities.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"267 ","pages":"Article 111210"},"PeriodicalIF":8.3,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143882989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unidirectional porous Si3N4 reinforced epoxy composites with high thermal conductivity and low thermal expansion 具有高导热、低热膨胀的单向多孔Si3N4增强环氧复合材料
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-24 DOI: 10.1016/j.compscitech.2025.111199
Zhilei Wei , Wenqi Xie , Biao Zhang , Xiaonan Zhou , Yinuo Ma , Lei Zhao , Bo Wang , Zhongqi Shi
{"title":"Unidirectional porous Si3N4 reinforced epoxy composites with high thermal conductivity and low thermal expansion","authors":"Zhilei Wei ,&nbsp;Wenqi Xie ,&nbsp;Biao Zhang ,&nbsp;Xiaonan Zhou ,&nbsp;Yinuo Ma ,&nbsp;Lei Zhao ,&nbsp;Bo Wang ,&nbsp;Zhongqi Shi","doi":"10.1016/j.compscitech.2025.111199","DOIUrl":"10.1016/j.compscitech.2025.111199","url":null,"abstract":"<div><div>Efficient heat dissipation via anisotropic thermal management materials (TMMs) has become increasingly urgent as the microelectronic devices develops towards miniaturization and high integration. However, traditional polymer/ceramic composites suffered from the drawbacks of limited thermal conductivities (TCs) and high coefficients of thermal expansion (CTEs) due to the random dispersion of ceramic grains in the polymer matrices, which resulted in the deteriorated life span of devices. Although recent works successfully constructed anisotropic thermal networks in the polymer-based composites, the connectivity of the ceramic grains was inferior, leading to the high contact thermal resistance (<em>R</em><sub>cf</sub>) and less constraint of the thermal expansion of polymer matrices. Therefore, achieving high TC while decreasing the CTE of the polymer-based TMMs was still a great challenge. In this work, a novel technique of freeze casting combined with combustion synthesis was employed to fabricate unidirectional porous (UP) Si<sub>3</sub>N<sub>4</sub> ceramics, which were then utilized as the reinforcements for epoxy (EP). The rigid and anisotropic UP Si<sub>3</sub>N<sub>4</sub> skeletons were successfully constructed in the obtained composites, leading to the decreased <em>R</em><sub>cf</sub> and enhanced constraint of the thermal expansion of EP. As a consequence, the TCs in the directions parallel and perpendicular to the channels achieved 20.54 W m<sup>−1</sup> K<sup>−1</sup> and 12.68 W m<sup>−1</sup> K<sup>−1</sup>, respectively, at a Si<sub>3</sub>N<sub>4</sub> loading of 53.8 vol%. The corresponding CTEs in the above two principal directions were only 11.53 × 10<sup>−6</sup> K<sup>−1</sup> and 4.98 × 10<sup>−6</sup> K<sup>−1</sup>, respectively. The composites displayed excellent heat dissipation performance in both experimental and simulation results, indicating promising application prospect as TMMs for microelectronic devices.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"267 ","pages":"Article 111199"},"PeriodicalIF":8.3,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877315","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interlaminar toughness of carbon fiber/epoxy laminates interleaved by nanofibrous veils: from molecular structure to macroscopic properties 纳米纤维膜交织碳纤维/环氧层压板的层间韧性:从分子结构到宏观性能
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-22 DOI: 10.1016/j.compscitech.2025.111205
Weiwei Jiao , Guoxiong Niu , Dingding Bai , Yuanpeng Zheng , Haidong Wang , Yaqing Liu
{"title":"Interlaminar toughness of carbon fiber/epoxy laminates interleaved by nanofibrous veils: from molecular structure to macroscopic properties","authors":"Weiwei Jiao ,&nbsp;Guoxiong Niu ,&nbsp;Dingding Bai ,&nbsp;Yuanpeng Zheng ,&nbsp;Haidong Wang ,&nbsp;Yaqing Liu","doi":"10.1016/j.compscitech.2025.111205","DOIUrl":"10.1016/j.compscitech.2025.111205","url":null,"abstract":"<div><div>Nanofibrous veils with nanometer-scale diameters and continuous lengths are considered promising interlayers for enhancing the interlaminar toughness of continuous fiber-reinforced polymer matrix laminates (CFRPs). The molecular structure of nanofibers is a crucial factor influencing their toughening performance, but the underlying <em>trans</em>-dimension structure-activity relationship remain unclear. Here, two types of polyamide-based nanofibrous veils (NF1 and NF2), characterized by distinct molecular structures, were integrated into carbon fiber/epoxy laminates to assess differences in interlaminar fracture toughness. Mode I and Mode II loading tests demonstrated significant yet distinct improvements in interlaminar fracture toughness for the two nanomodified CFRPs, attributed to intrinsic and extrinsic toughening mechanisms. NF1-modified composites exhibited superior toughening properties than NF2-modified composites, with a 186 % enhancement in <em>G</em><sub><em>IC</em></sub> and a 134 % enhancement in <em>G</em><sub><em>IIC</em></sub>. This superiority can be attributed to NF1's higher crystallinity, smaller diameter, stronger tensile strength, and greater interaction energy with epoxy resin, all of which are closely related to the molecular structure of the nanofibers. Molecular dynamics (MD) simulations provided theoretical insights into how the molecular structure of nanofibers influences interlaminar toughness. Furthermore, the original laminate static flexural properties, dynamic stiffness, and glass-transition temperature (<em>T</em><sub>g</sub>) are all maintained for NF1-modified composites, suggesting that enhancing interlaminar toughness can compensate for potential declines in mechanical and thermomechanical properties. Consequently, the multi-level structure-activity relationship between polymer molecular structure, nanofiber morphology, interlaminar topology, and composite macroscopic properties was established to pave the way for precise atomic-level construction of interlaminar structures in laminates.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"267 ","pages":"Article 111205"},"PeriodicalIF":8.3,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143860245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Waste-free recycling of multifunctional epoxy resins and carbon fiber composites enabled by dynamic aminal bonds 通过动态动物键实现多功能环氧树脂和碳纤维复合材料的无废物回收
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-22 DOI: 10.1016/j.compscitech.2025.111204
Fei Cong , Baolong Wang , Yunling Li , Pengxiang Liu , Xinzhe Fu , Xiuxian Liu , Yudong Huang , Zhen Hu
{"title":"Waste-free recycling of multifunctional epoxy resins and carbon fiber composites enabled by dynamic aminal bonds","authors":"Fei Cong ,&nbsp;Baolong Wang ,&nbsp;Yunling Li ,&nbsp;Pengxiang Liu ,&nbsp;Xinzhe Fu ,&nbsp;Xiuxian Liu ,&nbsp;Yudong Huang ,&nbsp;Zhen Hu","doi":"10.1016/j.compscitech.2025.111204","DOIUrl":"10.1016/j.compscitech.2025.111204","url":null,"abstract":"<div><div>As one of the most widely used thermosetting resins, epoxy resins have extensive applications in composite materials. Growing environmental concerns and the need for resource optimization have brought increased attention to the degradation and recycling of these composites. In this study, a hardener incorporating aminal bonds was synthesized using 3-methylaminopropylamine, which contains both primary and secondary amine groups. Subsequently, a series of epoxy resins was prepared, accompanied by the development of a sustainable and efficient strategy for their recycling. Among these, EP-H4 resin undergoes rapid degradation in amines at 80 °C within 2 h via the dynamic exchange of aminal bonds, demonstrating shape-memory, self-healing and reprocessability properties. Compared to traditional epoxy resins, EP-H4 exhibits comparable thermal and mechanical properties. A composite material was fabricated using EP-H4 and CF fabrics, and the CF fabrics achieved non-destructive recycling at 80 °C for 4 h. The degradation products can be directly utilized as curing agents for epoxy resins. HMB can be readily synthesized, recycled, reused, and the whole process is entirely waste-free.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"267 ","pages":"Article 111204"},"PeriodicalIF":8.3,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143873392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of boron nitride on the pyroresistive properties of smart conductive polymer composites: eliminating the negative temperature coefficient effect 氮化硼对智能导电聚合物复合材料热阻性能的影响:消除负温度系数效应
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-21 DOI: 10.1016/j.compscitech.2025.111203
Yushen Wang , Bijoy Das , Thomas D.S. Thorn , Yi Liu , Dimitrios G. Papageorgiou , Emiliano Bilotti , Han Zhang
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