Composites Science and Technology最新文献

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A super-stretchable conductive film with strain-insensitive conductivity for stretchable EMI shielding materials and wearable capacitive strain sensors 用于可拉伸 EMI 屏蔽材料和可穿戴电容式应变传感器的具有应变敏感导电性的超拉伸导电薄膜
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2024-09-24 DOI: 10.1016/j.compscitech.2024.110877
Yinfeng Liu , Tong Wang , Jing Wang , Xin Chen , Jianwen Chen , Zunfeng Liu , Yutian Zhu
{"title":"A super-stretchable conductive film with strain-insensitive conductivity for stretchable EMI shielding materials and wearable capacitive strain sensors","authors":"Yinfeng Liu ,&nbsp;Tong Wang ,&nbsp;Jing Wang ,&nbsp;Xin Chen ,&nbsp;Jianwen Chen ,&nbsp;Zunfeng Liu ,&nbsp;Yutian Zhu","doi":"10.1016/j.compscitech.2024.110877","DOIUrl":"10.1016/j.compscitech.2024.110877","url":null,"abstract":"<div><div>Strain-insensitive conductive films as stretchable electromagnetic interference (EMI) shielding materials and stretchable electrodes are highly desired in wearable electronics. However, fabricating super strain-insensitive conductive films under a tensile strain higher than 400 % is still a great challenge. Herein, a super-stretchable conductive film based on the crumple-structured Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> nanosheets-single walled carbon nanotubes/stretchable substrate double-layers is designed for the stretchable EMI shielding materials and electrodes. The resulting film exhibits a strain-insensitive electrical conductivity as high as 3.01 × 10<sup>3</sup> S/m even at a strain up to 500 %, which endows the film with a high and stable electromagnetic interference shielding efficiency (EMI SE) value of ∼45 dB. More interestingly, the EMI SE value of the film remains nearly constant even after 2000 cycles of 500 % tensile strain, indicating the excellent long-term service stability as a stretchable EMI shielding material. Moreover, a capacitive strain sensor with extra-wide sensing range, ultra-high stability, and excellent durability is successfully achieved by employing the as-prepared films as stretchable electrodes. This work proposes a convenient strategy of strain-insensitive conductive film aiming to design stretchable EMI shielding materials and electrodes for wearable electronics.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110877"},"PeriodicalIF":8.3,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142322290","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancing structural health monitoring: Deep learning-enhanced quantitative analysis of damage in composite laminates using surface strain field 推进结构健康监测:利用表面应变场对复合材料层压板的损伤进行深度学习增强型定量分析
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2024-09-23 DOI: 10.1016/j.compscitech.2024.110880
Shiyu Li, Xuanxin Tian, Qiubo Li, Shigang Ai
{"title":"Advancing structural health monitoring: Deep learning-enhanced quantitative analysis of damage in composite laminates using surface strain field","authors":"Shiyu Li,&nbsp;Xuanxin Tian,&nbsp;Qiubo Li,&nbsp;Shigang Ai","doi":"10.1016/j.compscitech.2024.110880","DOIUrl":"10.1016/j.compscitech.2024.110880","url":null,"abstract":"<div><div>Composite materials have been widely used as critical components in aerospace applications due to their excellent performance characteristics. The real-time accurate identification and quantification of various types of damage within composite material structures pose a significant challenge. This study introduces an innovative damage detection method based on strain fields, which centrally employs deep learning techniques. Utilizing the Res-Mask R–CNN, this study accurately detects and categorizes various forms of damage within composite laminates, including open holes, subsurface holes, and delamination. Moreover, this method also enables precise localization and quantification of damaged areas. A series of experiments and simulations have validated the accuracy and robustness of the network model. Damage inversion experiments demonstrate that the area error of the damaged regions has been reduced to 7.4 %, and the positional error does not exceed 3.31 mm. In simulated scenarios, the shape context distance for complex damage contours does not exceed 0.21, indicating that the critical geometric features of the damage have been successfully preserved. This study provides an effective new approach for damage detection and real-time structural health monitoring of composite laminates.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110880"},"PeriodicalIF":8.3,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142356988","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Curing and reinforcement effect of recovered carbon black from waste tires on brominated butyl rubber 废轮胎回收炭黑对溴化丁基橡胶的硫化和补强效果
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2024-09-23 DOI: 10.1016/j.compscitech.2024.110879
Guojie Zhang, Junjie Peng, Hanbing Wang, Yi Lu, Yong Zhang
{"title":"Curing and reinforcement effect of recovered carbon black from waste tires on brominated butyl rubber","authors":"Guojie Zhang,&nbsp;Junjie Peng,&nbsp;Hanbing Wang,&nbsp;Yi Lu,&nbsp;Yong Zhang","doi":"10.1016/j.compscitech.2024.110879","DOIUrl":"10.1016/j.compscitech.2024.110879","url":null,"abstract":"<div><div>The recycling of zinc compound from waste tires and the negative impact of zinc oxide on environment have been major challenges in rubber industry. In this study, the components and microstructure of recovered carbon black (rCB) from waste tires pyrolysis are analyzed, in which the content of the ash and zinc element is 20 % and 6.1 %, and zinc sulfide is the main zinc compound. Zinc sulfide and zinc oxide could crosslink brominated butyl rubber (BIIR), and the crosslinking effect becomes more effective in the presence of carbon black N660. BIIR can be crosslinked and reinforced by rCB in the absence of other additives. BIIR/rCB composites have similar curing behavior and mechanical properties to the BIIR composites filled with N660 and cured by zine oxide. Therefore, rCB could replace commercial carbon black N660 and zinc oxide in BIIR, and this replacement will realize the effective use of carbon black and zinc compound in rCB from waste tires and promote the sustainable development of tire industry.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110879"},"PeriodicalIF":8.3,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142320295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fumed silica additives enables tunable wettability of the resin for improved composite bipolar plate 气相二氧化硅添加剂可调节树脂的润湿性,从而改善复合双极板的性能
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2024-09-23 DOI: 10.1016/j.compscitech.2024.110882
Jing Chen , Nan Qin , Runlin Fan , Liming Jin , Junsheng Zheng , Pingwen Ming , Cunman Zhang , Jim P. Zheng
{"title":"Fumed silica additives enables tunable wettability of the resin for improved composite bipolar plate","authors":"Jing Chen ,&nbsp;Nan Qin ,&nbsp;Runlin Fan ,&nbsp;Liming Jin ,&nbsp;Junsheng Zheng ,&nbsp;Pingwen Ming ,&nbsp;Cunman Zhang ,&nbsp;Jim P. Zheng","doi":"10.1016/j.compscitech.2024.110882","DOIUrl":"10.1016/j.compscitech.2024.110882","url":null,"abstract":"<div><div>Composite bipolar plates (CBP) composed of resin and conductive filler are critical components in proton exchange membrane fuel cell (PEMFC) for achieving mechanical strength and electrical conductivity. The conductive filler entirely enveloped by resin is of significance for the flexibility of the CBP; while connected resin blocks the continued conductive channels and thus weakens the electrical properties of CBP. Herein, we propose a trade-off method between flexibility and conductivity of the CBP by wettability regulations of the resin, in which fumed silica additives are introduced into epoxy as composite adhesives. The abundant hydrogen bonds are demonstrated to be well-formed between epoxy and fumed silica for decreasing surface free energy (SFE) between resin and graphite. As a result, the composite adhesive with 2 % fumed silica delivers moderate wettability enabling much improved CBP, which exhibits high electrical conductivity of 233.33 S cm<sup>−1</sup> as well as flexural strength of 66.4 MPa. Moreover, the CBP also delivers improved areal specific resistance (5.34 mΩ cm<sup>2</sup>), thermal conductivity (10.58 W (m K)<sup>−1</sup>), and corrosion behaviors (0.0701 A cm<sup>−2</sup>) which guarantee the operation of the PEMFC. This work provides new insight from the wettability regulation of resins for improved CBP, which is an easy-operating method and has great potential for application in practical CBP fabrication.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110882"},"PeriodicalIF":8.3,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142322289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Temperature-dependent evolution of synthetic coal-derived graphite fillers and their reinforcement in styrene butadiene rubber composites 合成煤石墨填料及其在丁苯橡胶复合材料中的补强作用随温度的变化
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2024-09-23 DOI: 10.1016/j.compscitech.2024.110883
Hao Zhang , Xiaoyu Ding , Yongjie Yang , Qinfu Liu , Leibo Ji , Kuo Li , Junmin Sun , Zhiming Sun , Qianyi Ma , Ying Wu , Xinyang Liu , Chul B. Park , Naisheng Jiang
{"title":"Temperature-dependent evolution of synthetic coal-derived graphite fillers and their reinforcement in styrene butadiene rubber composites","authors":"Hao Zhang ,&nbsp;Xiaoyu Ding ,&nbsp;Yongjie Yang ,&nbsp;Qinfu Liu ,&nbsp;Leibo Ji ,&nbsp;Kuo Li ,&nbsp;Junmin Sun ,&nbsp;Zhiming Sun ,&nbsp;Qianyi Ma ,&nbsp;Ying Wu ,&nbsp;Xinyang Liu ,&nbsp;Chul B. Park ,&nbsp;Naisheng Jiang","doi":"10.1016/j.compscitech.2024.110883","DOIUrl":"10.1016/j.compscitech.2024.110883","url":null,"abstract":"<div><div>This study investigated the structural evolution of synthetic coal-derived graphite (SCG), produced from anthracite through high-temperature treatments ranging from 1000 to 2900 °C, and its reinforcement potential in styrene butadiene rubber (SBR) composites. Upon heating the anthracite to 2000 °C, We observed a gradual structural transformation from an amorphous carbon structure with mixed <em>sp</em><sup><em>2</em></sup>-<em>sp</em><sup><em>3</em></sup> bonding to an ordered <em>sp</em><sup><em>2</em></sup>-bonded nano-sized graphitic structure. This transformation was accompanied by the evaporation of heteroatom functional groups, an increase in high surface energy site as well as micropore and void structures, and enhanced hydrophobic surface property. Beyond 2000 °C, a flake-like graphite with a larger particle size (average lateral size &gt;10 μm) was gradually formed through lateral and vertical crystalline growth mechanisms. The reinforcing potential of SCG fillers was revealed by incorporating them into SBR and evaluating the properties of the resulting composites. It was found that the tensile strength and 300 % tensile modulus initially enhanced with SCG fillers treated up to 2000 °C, but decreased for fillers treated at 2300 and 2900 °C. On the other hand, storage modulus, tear resistance, and gas permeability consistently improved with fillers treated at higher temperatures. These findings highlight the relationship between the temperature-induced structural evolution of SCG fillers and their reinforcement performance in SBR composites, offering valuable insights for industrial rubber applications, particularly enhancing the performance and sustainability of automotive tire.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110883"},"PeriodicalIF":8.3,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142417681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A multifunctional leather composite with good antibacterial and hygrothermal management capabilities 具有良好抗菌和湿热管理能力的多功能皮革复合材料
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2024-09-21 DOI: 10.1016/j.compscitech.2024.110875
Ping Wang , Caiqing Mo , Yanqing Liu , Ying Jiang , Zhicheng Zhang , Huajun Wu , Guiyu Luo , Yu She , En-Tang Kang , Kai Zhang , Liqun Xu
{"title":"A multifunctional leather composite with good antibacterial and hygrothermal management capabilities","authors":"Ping Wang ,&nbsp;Caiqing Mo ,&nbsp;Yanqing Liu ,&nbsp;Ying Jiang ,&nbsp;Zhicheng Zhang ,&nbsp;Huajun Wu ,&nbsp;Guiyu Luo ,&nbsp;Yu She ,&nbsp;En-Tang Kang ,&nbsp;Kai Zhang ,&nbsp;Liqun Xu","doi":"10.1016/j.compscitech.2024.110875","DOIUrl":"10.1016/j.compscitech.2024.110875","url":null,"abstract":"<div><div>If not removed in a timely manner, the large amount of sweat produced by overheated human skin can cause thermal discomfort and health problems. Development of fabrics with cooling and dehumidifying capabilities is advantageous to improving the quality of human life. In this work, a natural leather-based Zn-monoethanolamine@lignin (Zn-MEA@lignin-leather) composite fabric with personal hygrothermal management properties was fabricated by infiltrating the permeable 3D network microstructure of the natural leather collagen fiber bundles with adhering moisture-absorbent hydrogel containing photothermal lignin. Due to the efficiency of the composite hydrogel in trapping water molecules, the fabric can promote evaporation of sweat from overheated skin surfaces. Compared to the conventional textiles, the composite leather fabric can reduce the humidity of simulated skin surface by about 40 % and accelerate the evaporation of sweat from the skin surface to promote reduction in temperature of the overheated body. Thanks to the good photothermal conversion efficiency of lignin, the hydrated composite fabric exhibits a favorable evaporation regeneration rate (0.498 kg m<sup>−2</sup> h<sup>−1</sup>). In addition, the presence of zinc ions in the coordination complex imparts good antimicrobial efficiency to the composite fabric, with inactivation rates approaching 99.99 % for both <em>Staphylococcus aureus</em> (<em>S. aureus</em>) and <em>Escherichia coli</em> (<em>E. coli</em>). Thus, the composite leather fabric holds great promise to personal hygrothermal management and healthcare.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110875"},"PeriodicalIF":8.3,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142320293","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Self-assembled nest-like BN skeletons enable polymer composites with high thermal management capacity 自组装的巢状 BN 骨架使聚合物复合材料具有高热能管理能力
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2024-09-21 DOI: 10.1016/j.compscitech.2024.110869
Jiangang Zhou, Congzhen Xie, Huasong Xu, Bin Gou, An Zhong, Daoming Zhang, Hangchuan Cai, Chunhui Bi, Licheng Li, Rui Wang
{"title":"Self-assembled nest-like BN skeletons enable polymer composites with high thermal management capacity","authors":"Jiangang Zhou,&nbsp;Congzhen Xie,&nbsp;Huasong Xu,&nbsp;Bin Gou,&nbsp;An Zhong,&nbsp;Daoming Zhang,&nbsp;Hangchuan Cai,&nbsp;Chunhui Bi,&nbsp;Licheng Li,&nbsp;Rui Wang","doi":"10.1016/j.compscitech.2024.110869","DOIUrl":"10.1016/j.compscitech.2024.110869","url":null,"abstract":"<div><div>The lagging development of thermally conductive but electrically insulating materials has become a bottleneck problem for the next generation of advanced high-power density electronic devices. Although second-phase reinforced composites are promising materials for addressing thermal management issues, the inherent mechanism of severe phonon scattering at the interphase results in actual thermal conductivity enhancement efficiency far below expectations. Here, we report a high-performance polymer composite with a nest-like interconnected boron nitride skeleton. This nest-like interconnected BN skeleton without mechanical contact can provide high-efficiency and long-distance phonon transport channel, realizing high thermal conductivity of 1.827 W m<sup>−1</sup> K<sup>−1</sup> in polymer composite with ultra-low content (4.7 vol%). Meanwhile, the EP/nest-like BS composites possess ideal electrical properties and dimensional stability. In the actual heat dissipation process of LED chips, the optimal composite material as the thermal interface material can display a temperature drop of more than 34.8 % compared to neat epoxy, which proves the broad application prospects of this strategy in advanced electronic devices.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110869"},"PeriodicalIF":8.3,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142310721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Lightweight composites derived from carbonized taro stems for microwave energy attenuation and thermal energy storage 用于微波能量衰减和热能储存的碳化芋头茎轻质复合材料
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2024-09-21 DOI: 10.1016/j.compscitech.2024.110874
Tian Yang , Qing Qi , Li Ma , Tian Li , Jiatong Li , Qian Yang , Fanbin Meng
{"title":"Lightweight composites derived from carbonized taro stems for microwave energy attenuation and thermal energy storage","authors":"Tian Yang ,&nbsp;Qing Qi ,&nbsp;Li Ma ,&nbsp;Tian Li ,&nbsp;Jiatong Li ,&nbsp;Qian Yang ,&nbsp;Fanbin Meng","doi":"10.1016/j.compscitech.2024.110874","DOIUrl":"10.1016/j.compscitech.2024.110874","url":null,"abstract":"<div><div>A novel strategy has been developed for preparing porous carbon materials derived from taro stems, aimed at enhancing electromagnetic wave (EMW) attenuation and thermal energy storage. The materials were synthesized through the carbonization of taro stems to form a porous carbon structure, subsequently enhanced with polyethylene glycol (PEG) containing carbon nanotubes (CNTs) and nickel (Ni) nanoparticles. By adjusting the carbonization temperature and the loading of CNTs and Ni, the resulting carbon materials exhibited exceptional EMW attenuation performance. Specifically, the PC-800 sample demonstrated a remarkable minimum reflection loss of −61.4 dB across the frequency range of 8.2–11 GHz, with a low density of 0.054 g/cm³. The PC-1200 sample exhibited EMI SE values of 23.6 dB axially and 21.5 dB radially in the X-band, with an ultra-low density of 0.033 g/cm³. Further enhancements were observed in the PC/CNT2 and PC/CNT2-Ni15 composites, achieving EMI SE values of 26.3 dB and 26.8 dB, respectively. Additionally, these composites exhibited effective thermal energy storage and release, as confirmed by heating experiments. This study not only introduces a method for creating absorption-dominated biomass electromagnetic shielding materials but also provides a dual-functional solution for enhancing the performance of electronic devices.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110874"},"PeriodicalIF":8.3,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142310723","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of atomic oxygen and vacuum thermal aging on graphene and glass fibre reinforced cyanate ester-based shape memory polymer composite for deployable thin wall structures 原子氧和真空热老化对用于可部署薄壁结构的石墨烯和玻璃纤维增强型氰酸酯基形状记忆聚合物复合材料的影响
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2024-09-19 DOI: 10.1016/j.compscitech.2024.110870
Sandaruwan Jayalath , Eduardo Trifoni , Jayantha Epaarachchi , Madhubhashitha Herath , Eleftherios E. Gdoutos , Bandu Samarasekara
{"title":"Effect of atomic oxygen and vacuum thermal aging on graphene and glass fibre reinforced cyanate ester-based shape memory polymer composite for deployable thin wall structures","authors":"Sandaruwan Jayalath ,&nbsp;Eduardo Trifoni ,&nbsp;Jayantha Epaarachchi ,&nbsp;Madhubhashitha Herath ,&nbsp;Eleftherios E. Gdoutos ,&nbsp;Bandu Samarasekara","doi":"10.1016/j.compscitech.2024.110870","DOIUrl":"10.1016/j.compscitech.2024.110870","url":null,"abstract":"<div><div>Deployable components and structures are a crucial part of space exploration. Due to fewer parts, low weight and cost, shape memory polymers (SMPs) and their composites (SMPCs) are considered ideal candidates for this. However, lower thermal stability and poor durability in the space environment have limited their applicability. This research work details the development of Graphene Nanoplatelets (GNP) filled Glass Fibre (GF) reinforced cyanate ester-based SMPC with 0/90° and ±45° sandwich fibre lay-up configuration capable of multidirectional shape programming. The SMP matrix was synthesised by mixing Cyanate Ester and Polyethylene Glycol (PEG) with added GNP. SMPC was fabricated by pouring the SMP mixture into a pre-prepared glass mould with the added GF layers. The synthesised SMPC showed shape programming and recovery at 169.01 ± 0.62 °C and stable thermomechanical properties at the temperature of 130 °C. Durability tests at extreme environmental conditions including Atomic Oxygen exposure, thermal vacuum aging, and elevated-temperature behaviour tests were conducted as these tests evaluate the durability and applicability of the SMPC for use in Earth's orbits and lunar environments. The performances of the samples before and after durability tests were measured through mechanical tests, shape memory effect tests and a series of characterisation methods such as microscopic image analysis, FTIR and dynamic mechanical analysis. According to the results, AO exposure affected the SMPCs by eroding their surface. There were no changes in the chemical structure of the SMPC yet the thermomechanical, mechanical and shape memory properties were decreased without compromising their safe operational levels such as storage onset temperatures (128.79 ± 3.08 °C), maximum tensile stress (114.99 ± 21.52 MPa), shape fixity (100 %) and recovery ratios (100 %). The erosion resistance of the GNP-filled SMPCs was improved with ∼54.35 % less erosion than the SMPC without GNP. The vacuum thermal aging slightly slowed shape recovery from 31.17 % to 8.32 % at 160 °C due to PEG crosslink degradation, however, 100 % shape recovery was achieved at the end. Further durability tests under cryogenic temperatures and effects after vacuum thermal cycles are warranted to observe the synergistic effect on the SMPC for future developments. Exploring the scalability and additive manufacturability of the developed SMPC can be advantageous in the future while mitigating challenges such as complex shape programming, long-term materials degradation, resource efficiency and compliance with safety standards.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110870"},"PeriodicalIF":8.3,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0266353824004408/pdfft?md5=cf157681a76f26bb6a51b08259c2e02e&pid=1-s2.0-S0266353824004408-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142310717","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermal-mechanical-chemical coupled model and three-dimensional damage evaluation based on computed tomography for high-energy laser-ablated CFRP 基于计算机断层扫描的高能激光照射 CFRP 的热-机械-化学耦合模型和三维损伤评估
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2024-09-19 DOI: 10.1016/j.compscitech.2024.110867
Yaoran Li, Jiawei Chen, Shengyu Duan, Panding Wang, Hongshuai Lei, Zeang Zhao, Daining Fang
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