Dyes and Pigments最新文献

Recent developments in the bioimaging and chemosensing applications of rhodamine derivatives for metal ions detection: A review

IF 4.1 3区工程技术

Dyes and Pigments Pub Date : 2024-11-28 DOI: 10.1016/j.dyepig.2024.112568

Alaa Shafie , Amal Adnan Ashour

{"title":"Recent developments in the bioimaging and chemosensing applications of rhodamine derivatives for metal ions detection: A review","authors":"Alaa Shafie , Amal Adnan Ashour","doi":"10.1016/j.dyepig.2024.112568","DOIUrl":"10.1016/j.dyepig.2024.112568","url":null,"abstract":"<div><div>Rhodamine derivatives have garnered extensive attention in recent years due to their significant sensing properties and structural adaptability, making them indispensable tools in sensing applications for the detection of different analytes. The ability to selectively interact with target species, coupled with their high sensitivity and rapid response, has positioned rhodamine derivatives as key components in the development of novel chemosensors for various applications in biomedical diagnostics, pharmaceutical analysis, and environmental monitoring. In addition, rhodamine derivatives have garnered significant interest in recent years due to their remarkable fluorescence properties and structural versatility, making them invaluable tools in visualizing cellular structures and processes. In this study, we review the advancements in rhodamine-based chemosensors for metal ion detection such as Cu<sup>2+</sup>, Cd<sup>2+</sup>, Co<sup>2+</sup>, Ag<sup>+</sup>, Mn<sup>2+</sup>, Cd<sup>2+</sup>, Cr<sup>3+</sup>, Fe<sup>2+</sup>, Ni<sup>2+</sup>, Hg<sup>2+</sup>, Pb<sup>2+</sup>, Zn<sup>2+</sup>, Fe<sup>3+</sup>, etc. and their applications in bioimaging, focusing on developments from 2021 to 2024. Also examines the sensing mechanisms of rhodamine derivatives toward the these metal ions. Additionally, the versatility of rhodamine derivatives in designing chemosensors for bioimaging applications of these cations in various live cells such as MCF7, HeLa, HEK293T, HepG2, L929, U-87, MIA PaCa-2, SiHa, HCT -116, A549, L6, MC3T3 and plant root tissues as well as in lampfishes, zebrafishes, drosophila, caenorhabditis elegans and adult mice are discussed.</div></div>","PeriodicalId":302,"journal":{"name":"Dyes and Pigments","volume":"235 ","pages":"Article 112568"},"PeriodicalIF":4.1,"publicationDate":"2024-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757593","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

In search for a new lead white: Understanding the historical production processes for industrial-age lead white pigments (1740–1940)

IF 4.1 3区工程技术

Dyes and Pigments Pub Date : 2024-11-28 DOI: 10.1016/j.dyepig.2024.112566

Iryn Bijker , Nina Deleu , Yvan Darcis , Koen Janssens , Geert Van der Snickt

{"title":"In search for a new lead white: Understanding the historical production processes for industrial-age lead white pigments (1740–1940)","authors":"Iryn Bijker , Nina Deleu , Yvan Darcis , Koen Janssens , Geert Van der Snickt","doi":"10.1016/j.dyepig.2024.112566","DOIUrl":"10.1016/j.dyepig.2024.112566","url":null,"abstract":"<div><div>In heritage science, lead white pigments are of great significance due to their omnipresence in historical polychrome and finishing layers. However, although lead white dominated the artist's palette from Antiquity until the early 20th century, modern production processes have remained largely unstudied. This paper explores the manufacturing methods from 1740 to 1940, as these differ fundamentally from the traditional ‘Dutch Stack Method’. Moreover, the technological breakthroughs of the industrial-age initiated an intensive search for improved production pathways, as attested by the 185 process descriptions found during this survey of historical textual sources. A thorough understanding of these innovative processes and their ensuing end-products is particularly relevant for the conservation field as recent studies demonstrated that the production method influences the resulting lead white subtype and its painting properties. Drawing on process descriptions in patents, technical manuals and treatises, a classification is proposed based on the underlying chemical methodology; the main categories are methods based on corrosion, precipitation, electrolysis and volatilisation. In addition, the real-life, commercial prevalence of these categories was assessed by studying literature and archival information on large-scale trade and industry. Surprisingly, these findings indicate that, despite the many innovative chemical pathways registered, the lion's share of lead white manufacturers across Europe and North America continued to employ the corrosion methods, which remain the most indebted to the traditional stack method. Nevertheless, a significant number of factories adopted the novel pathways (i.e. precipitation methods), even though the ensuing products were often considered as of lesser quality in contemporary literature.</div></div>","PeriodicalId":302,"journal":{"name":"Dyes and Pigments","volume":"235 ","pages":"Article 112566"},"PeriodicalIF":4.1,"publicationDate":"2024-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757596","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Intermolecular C–H⋯O hydrogen bond–induced H-aggregates for rapid, real-time detection of cyanide

IF 4.1 3区工程技术

Dyes and Pigments Pub Date : 2024-11-27 DOI: 10.1016/j.dyepig.2024.112567

Sachin D. Padghan , Jiun-Wei Hu , Li-Ching Wang, Yin-Hsuan Hsu, Kew-Yu Chen

{"title":"Intermolecular C–H⋯O hydrogen bond–induced H-aggregates for rapid, real-time detection of cyanide","authors":"Sachin D. Padghan , Jiun-Wei Hu , Li-Ching Wang, Yin-Hsuan Hsu, Kew-Yu Chen","doi":"10.1016/j.dyepig.2024.112567","DOIUrl":"10.1016/j.dyepig.2024.112567","url":null,"abstract":"<div><div>A specialized chemodosimeter, <strong>H1</strong>, incorporates a solid red fluorophore formed using a nearly planar dimethylaniline–indanedione conjugate, leveraging an intramolecular charge transfer (ICT) mechanism engineered for cyanide detection. Chemodosimeter <strong>H1</strong> exhibits strong ICT-induced emission in polar organic solvents, although its fluorescence diminishes in the solid state. Compared with the J-aggregated solid red fluorophore <strong>J1</strong>, which has a similar dimethylaniline–indanedione conjugate structure, chemodosimeter <strong>H1</strong>, with an extended vinyl conjugation, displays a relatively weak and blue-shifted red emission in the solid state because of formation of H-aggregates induced by intermolecular C–H⋯O hydrogen bonds. Binding between cyanide and chemodosimeter <strong>H1</strong> results in color and emission changes for the latter, resulting in formation of a highly twisted structure, denoted as <strong>H1</strong>–<strong>CN</strong>, which subsequently impedes ICT. Furthermore, test strips employing the H-aggregated red fluorophore <strong>H1</strong> present a promising approach for quantitative and rapid detection of cyanide (CN<sup>−</sup>). These results provide a new approach to designing solid red fluorophores based on H-aggregation for CN<sup>−</sup> detection.</div></div>","PeriodicalId":302,"journal":{"name":"Dyes and Pigments","volume":"235 ","pages":"Article 112567"},"PeriodicalIF":4.1,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fluorescent sensing for boronic acid derivatives: Design, synthesis, mechanism, application and perspective in Boron Neutron Capture Therapy (BNCT)

IF 4.1 3区工程技术

Dyes and Pigments Pub Date : 2024-11-26 DOI: 10.1016/j.dyepig.2024.112561

Yuanfeng Qi , Wenwen Sun , Le Wang , Xiao Zhang , Xuetao Wu , Yingbo Li , Junfeng Wang

{"title":"Fluorescent sensing for boronic acid derivatives: Design, synthesis, mechanism, application and perspective in Boron Neutron Capture Therapy (BNCT)","authors":"Yuanfeng Qi , Wenwen Sun , Le Wang , Xiao Zhang , Xuetao Wu , Yingbo Li , Junfeng Wang","doi":"10.1016/j.dyepig.2024.112561","DOIUrl":"10.1016/j.dyepig.2024.112561","url":null,"abstract":"<div><div>Boron is ubiquitous in nature, and drugs based on boronic acid and esters are now widely developed and used. Boron Neutron Capture Therapy (BNCT), with its high selectivity in targeting cancer cells while minimizing damage to healthy tissues, is currently an innovative cancer treatment technology being explored worldwide. The treatment process of BNCT primarily involves delivering targeted <sup>10</sup>B drugs to the tumor site. After neutron irradiation, the <sup>10</sup>B drugs will absorb neutrons and undergo nuclear transformation into <sup>11</sup>B which subsequently decays to produce <sup>7</sup>Li and alpha particles, thereby damaging DNA and killing cancer cells. The concentration and location of the <sup>10</sup>B drugs delivered to tumor cells are critical determinants of the therapeutic effect of BNCT, making the sensing of boronic acid drugs particularly important. In this review, the design and synthesis of various boronic acid sensors with different chelating ligands were discussed, as well as the applications in BNCT. Finally, we analyze the current limitations and propose future perspectives for these sensors to improve their utility in biomedical applications.</div></div>","PeriodicalId":302,"journal":{"name":"Dyes and Pigments","volume":"235 ","pages":"Article 112561"},"PeriodicalIF":4.1,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746126","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Benzobisthiazole and rhodanine based low energy level small molecule donors for organic solar cells 基于苯并二噻唑和罗丹宁的有机太阳能电池低能级小分子供体

IF 4.1 3区工程技术

Dyes and Pigments Pub Date : 2024-11-22 DOI: 10.1016/j.dyepig.2024.112564

Dong Han , Shuguang Wen , Kai Song , Jing Lv , Chunming Yang , Tao Zhuang , Aziz Saparbaev , Mingliang Sun , Xichang Bao

引用次数: 0

Fabrication of 3D TPU microfiber structures with embedded dye probes for cyanide ion sensing via charge-reversed electro jet writing 通过电荷反向电动喷射写入技术，制备内嵌染料探针的三维热塑性聚氨酯微纤维结构，用于氰化物离子传感

IF 4.1 3区工程技术

Dyes and Pigments Pub Date : 2024-11-22 DOI: 10.1016/j.dyepig.2024.112563

Palanisamy Jayasudha , Ramalingam Manivannan , Jaeyu Lee , Kyung Jin Lee , Young-A Son

{"title":"Fabrication of 3D TPU microfiber structures with embedded dye probes for cyanide ion sensing via charge-reversed electro jet writing","authors":"Palanisamy Jayasudha , Ramalingam Manivannan , Jaeyu Lee , Kyung Jin Lee , Young-A Son","doi":"10.1016/j.dyepig.2024.112563","DOIUrl":"10.1016/j.dyepig.2024.112563","url":null,"abstract":"<div><div>An extremely organized sensing system that indicates the prompt indication of the cyanide ion in water was synthesized. The design of the sensing probe comprises the phenothiazine fluorophore system as an electron donor and tetramethyl-3<em>H</em>-indol-1-ium as an electron acceptor unit. A notable color change in daylight and UV light was observed in the probe when it comes in contact with the solution of cyanide ion. The probe interaction with the cyanide ion results in color change from purple to colorless and these changes occurs in the probe with the disconnection in the ICT process. The detection limit (LOD) 1.3 μM (UV–visible method) and 25 nM (Fluorescence method), denotes that the probe preferentially reacts with cyanide, which is less than the tolerable level of 1.9 μM. The probe reacts with cyanide ions via nucleophilic addition reaction mechanism and it is confirmed through the <sup>1</sup>H NMR data. Furthermore, the HRMS value also confirms the same. For practical application of the probe a 3D structure composed of TPU microfiber containing probe molecule was fabricated by charge reversed electro jet writing (CREW) method by 3D printer has been efficiently sense cyanide ion. Also, for cyanide ion sensing probe successfully determines real resources, including cyanide containing various water samples. Besides, the developed <strong>PBI</strong>-encapsulated Polysulfone (PSF) capsule kit effectively sense cyanide ion in water. Moreover, the test strips, was also employed to detect the cyanide ion in presence of competing anions. Therefore, the synthesized probe displays an outstanding sensing ability towards the cyanide ion.</div></div>","PeriodicalId":302,"journal":{"name":"Dyes and Pigments","volume":"234 ","pages":"Article 112563"},"PeriodicalIF":4.1,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142722569","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Unravelling the intricacies of fluorescence enhancement in heptamethine cyanine dyes induced by heavy halogen atoms 揭示重卤素原子诱导七甲烷氰基染料荧光增强的复杂性

IF 4.1 3区工程技术

Dyes and Pigments Pub Date : 2024-11-21 DOI: 10.1016/j.dyepig.2024.112548

Dmytro Kobzev, Olesia Kulyk, Olga Semenova, Valeriia Ananieva, Oleg Zhikol, Iryna Omelchenko, Anatoliy Tatarets

{"title":"Unravelling the intricacies of fluorescence enhancement in heptamethine cyanine dyes induced by heavy halogen atoms","authors":"Dmytro Kobzev, Olesia Kulyk, Olga Semenova, Valeriia Ananieva, Oleg Zhikol, Iryna Omelchenko, Anatoliy Tatarets","doi":"10.1016/j.dyepig.2024.112548","DOIUrl":"10.1016/j.dyepig.2024.112548","url":null,"abstract":"<div><div>The classic heavy-atom effect refers to the photophysical phenomenon observed in fluorophores, where the interaction with heavy atoms quenches fluorescence emission. Many fluorophores containing heavy halogen atoms, such as xanthenes, BODIPYs, porphyrins, and anthracenes, adhere to this effect, while the photophysical behavior of others, <em>e.g</em>. halogenated heptamethine cyanine dyes, is poorly studied having contradicting results. In this study, we explored for the first time unexpected fluorescence enhancement induced by heavy halogen atoms in heptamethine dyes, contrasting the classic heavy-atom effect. To this end, a series of novel heptamethine cyanine dyes were synthesized and their photophysical properties were experimentally and theoretically investigated. Heavy halogen atoms were found to significantly affect the fluorescence behaviour of heptamethine dyes depending on the number and position of the attached halogens. Thus, the introduction of bromine and iodine atoms at the non-conjugated positions to the chromophore moieties led to an increase in the fluorescence quantum yields, which contradicts the classic principle and could be explained by heavy halogen-induced vibration restrictions. The value of halogen atom-promoted singlet oxygen generation quantum yield Φ<sub>Δ</sub> is also not straightforward and depends on the number, position and weight of the halogen atom. The breaking of the classic heavy-atom effect in halogenated heptamethine dyes provides an effective strategy to substantially increase the fluorescence intensity of long-wavelength cyanine dyes, providing new functional advantages for fluorescence imaging, diagnostics, and photodynamic therapy, among other applications.</div></div>","PeriodicalId":302,"journal":{"name":"Dyes and Pigments","volume":"234 ","pages":"Article 112548"},"PeriodicalIF":4.1,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142722568","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis and photophysical characterization of push-pull azobenzene derivatives featuring different π-bridges for photoresponsive applications 具有不同 π 桥的推挽式偶氮苯衍生物的合成与光物理特性分析，用于光致发光应用

IF 4.1 3区工程技术

Dyes and Pigments Pub Date : 2024-11-20 DOI: 10.1016/j.dyepig.2024.112550

Ismi Simpang Anggia , Dini Hayati , Jongin Hong

{"title":"Synthesis and photophysical characterization of push-pull azobenzene derivatives featuring different π-bridges for photoresponsive applications","authors":"Ismi Simpang Anggia , Dini Hayati , Jongin Hong","doi":"10.1016/j.dyepig.2024.112550","DOIUrl":"10.1016/j.dyepig.2024.112550","url":null,"abstract":"<div><div>This study presents the synthesis, development, and comprehensive evaluation of a series of novel azobenzene derivatives – DMAC, DMAF, and DMAT – engineered with push-pull configuration by varying π-bridge substituents (benzene, furan, and thiophene, respectively). The research employs a combination of computational and experimental methods, including density functional theory (DFT) and time-resolved UV–Vis absorption spectroscopy, to explore the impact of these π-bridge modifications on the electronic, photophysical, and isomerization properties of the derivatives. Interestingly, the findings suggest that the π-bridge structure significantly influences the charge transfer characteristics, with DMAC exhibiting the most effective charge transfer and the highest photoisomerization efficiency. Time-resolved UV–Vis absorption spectroscopy demonstrates that all derivatives exhibit rapid initial <em>E</em>-to-<em>Z</em> isomerization upon light irradiation, followed by a slower approach to the photostationary state (PSS). Thermal <em>Z</em>-to-<em>E</em> isomerization kinetics are consistent with the activation energy barriers predicted by potential energy surface (PES) scans, with DMAC showing the slowest reversion due to its highest activation energy. This study contributes valuable insights into the structural influences on the photochemical dynamics of azobenzene derivatives, with implications for their applications in photoresponsive technologies.</div></div>","PeriodicalId":302,"journal":{"name":"Dyes and Pigments","volume":"234 ","pages":"Article 112550"},"PeriodicalIF":4.1,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142698928","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Rational integration of fluorogenic and quenching activity of dopamine for reversed ratiometric and semi-quantitative visual detection of tyramine 合理整合多巴胺的荧光活性和淬灭活性，实现酪胺的反向比率测量和半定量视觉检测

IF 4.1 3区工程技术

Dyes and Pigments Pub Date : 2024-11-20 DOI: 10.1016/j.dyepig.2024.112559

Mingyue You , Lingling Liu , Yuanmin Gong , Rui Shi , Long Yuan , Jiaqi Chen , Kai Zhou , Xueping Tao , Gaoyi Yi , Zhining Xia , Qifeng Fu

{"title":"Rational integration of fluorogenic and quenching activity of dopamine for reversed ratiometric and semi-quantitative visual detection of tyramine","authors":"Mingyue You , Lingling Liu , Yuanmin Gong , Rui Shi , Long Yuan , Jiaqi Chen , Kai Zhou , Xueping Tao , Gaoyi Yi , Zhining Xia , Qifeng Fu","doi":"10.1016/j.dyepig.2024.112559","DOIUrl":"10.1016/j.dyepig.2024.112559","url":null,"abstract":"<div><div>A facile and efficient reversed ratiometric fluorescence (RF) method has been developed for the sensitive and accurate detection of tyramine (Tyr), an essential marker for food spoilage in fermented or aged foods. This method utilizes an “activation-quenching integration” strategy involving the fluorogenic reactivity and quenching capacity of dopamine (DA), the tyrosinase (TYR) catalyzed products of Tyr. Under alkaline conditions, DA reacts with resorcinol to form azamonardine, exhibiting strong blue emission. Additionally, DA is oxidized to <em>o</em>-dopaquinone by TYR, which quenches the red fluorescence of CdTe quantum dots (QDs). Under optimized conditions, a Tyr-specific RF sensor was established, featuring a linear detection range from 0.1 to 6 mg/mL and a detection limit of 8.50 × 10<sup>−3</sup> mg/L. The fabricated reversed RF sensing system was successfully applied for quantitative analysis of Tyr in real samples and semi-quantitative visual detection of Tyr in fermented food samples upon integration with a pseudo-color-assisted approach.</div></div>","PeriodicalId":302,"journal":{"name":"Dyes and Pigments","volume":"234 ","pages":"Article 112559"},"PeriodicalIF":4.1,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142698927","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Selective and sensitive detection of glutathione with a novel fluorescein-based probe in fully aqueous media and its application in food samples 利用新型荧光素探针在全水介质中选择性灵敏检测谷胱甘肽及其在食品样品中的应用

IF 4.1 3区工程技术

Dyes and Pigments Pub Date : 2024-11-20 DOI: 10.1016/j.dyepig.2024.112551

Garen Suna , Sema Topal , Erman Karakuş

引用次数: 0