{"title":"Photovoltaics Literature Survey (No. 194)","authors":"Ziv Hameiri","doi":"10.1002/pip.3857","DOIUrl":"https://doi.org/10.1002/pip.3857","url":null,"abstract":"<p>In order to help readers stay up-to-date in the field, each issue of <i>Progress in Photovoltaics</i> will contain a list of recently published journal articles that are most relevant to its aims and scope. This list is drawn from an extremely wide range of journals, including <i>IEEE Journal of Photovoltaics</i>, <i>Solar Energy Materials and Solar Cells</i>, <i>Renewable Energy</i>, <i>Renewable and Sustainable Energy Reviews</i>, <i>Journal of Applied Physics</i>, and <i>Applied Physics Letters</i>. To assist readers, the list is separated into broad categories, but please note that these classifications are by no means strict. Also note that inclusion in the list is not an endorsement of a paper's quality. If you have any suggestions please email Ziv Hameiri at <span>[email protected]</span>.</p><p>Wang B, Chen Q, Wang MM, et al. <b>PVF-10: A high-resolution unmanned aerial vehicle thermal infrared image dataset for fine-grained photovoltaic fault classification.</b> <i>Applied Energy</i> 2024; <b>376</b>: 124187.</p><p>Ozturk E, Ogliari E, Sakwa M, et al. <b>Photovoltaic modules fault detection, power output, and parameter estimation: A deep learning approach based on electroluminescence images.</b> <i>Energy Conversion and Management</i> 2024; <b>319</b>: 118866.</p><p>Almora O, Lopez-Varo P, Escalante R, et al. <b>Instability analysis of perovskite solar cells via short-circuit impedance spectroscopy: A case study on NiO</b><sub><b>x</b></sub> <b>passivation.</b> <i>Journal of Applied Physics</i> 2024; <b>136</b>(9): 094502.</p><p>El Khoury M, Moret M, Tiberj A, et al. <b>Determination of light-independent shunt resistance in CIGS photovoltaic cells using a collection function-based model.</b> <i>Journal of Applied Physics</i> 2024; <b>136</b>(2): 024502.</p><p>Li JC, Ji Q, Wang R, et al. <b>Charge generation dynamics in organic photovoltaic blends under one-sun-equivalent illumination detected by highly sensitive terahertz spectroscopy.</b> <i>Journal of the American Chemical Society</i> 2024; <b>146</b>(29): 20312-20322.</p><p>Sandner D, Sun K, Stadlbauer A, et al. <b>Hole localization in bulk and 2D lead-halide perovskites studied by time-resolved infrared spectroscopy.</b> <i>Journal of the American Chemical Society</i> 2024; <b>146</b>(29): 19852-19862.</p><p>Li Y, Wright B, Hameiri Z. <b>Deep learning-based perspective distortion correction for outdoor photovoltaic module images.</b> <i>Solar Energy Materials and Solar Cells</i> 2024; <b>277</b>: 113107.</p><p>Wang S, Wright B, Zhu Y, et al. <b>Extracting the parameters of two-energy-level defects in silicon wafers using machine learning models.</b> <i>Solar Energy Materials and Solar Cells</i> 2024; <b>277</b>: 113123.</p><p>Zhou YN, Zhang HH, Li ZF, et al. <b>Heavy boron-doped silicon tunneling inter-layer enables efficient silicon heterojunction solar cells.</b> <i>Acs Applied Materials and Interfaces</i> 2024; <b>16</b>(35): 46889-46896.</p><p>Li WK, Zhou R, Wang YK, et al. <b","PeriodicalId":223,"journal":{"name":"Progress in Photovoltaics","volume":"32 12","pages":"950-956"},"PeriodicalIF":8.0,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/pip.3857","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142664825","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Junchuan Zhang, Haodong Wu, Yi Zhang, Fangfang Cao, Zhiheng Qiu, Minghui Li, Xiting Lang, Yongjie Jiang, Yangyang Gou, Xirui Liu, Abdullah M. Asiri, Paul J. Dyson, Mohammad Khaja Nazeeruddin, Jichun Ye, Chuanxiao Xiao
{"title":"Investigation of Potential-Induced Degradation and Recovery in Perovskite Minimodules","authors":"Junchuan Zhang, Haodong Wu, Yi Zhang, Fangfang Cao, Zhiheng Qiu, Minghui Li, Xiting Lang, Yongjie Jiang, Yangyang Gou, Xirui Liu, Abdullah M. Asiri, Paul J. Dyson, Mohammad Khaja Nazeeruddin, Jichun Ye, Chuanxiao Xiao","doi":"10.1002/pip.3848","DOIUrl":"https://doi.org/10.1002/pip.3848","url":null,"abstract":"<div>\u0000 \u0000 <p>Potential-induced degradation (PID) is a prevalent concern in current commercial photovoltaic technologies, impacting their reliability, with the mechanistic basis for PID in perovskite photovoltaic technologies being poorly understood. Here, we investigate the PID mechanism in perovskite minimodules. Our findings reveal nonuniform degradation in the photoluminescence intensity and spectral blue shift. After 60-h laboratory PID stress tests at −1500 V and 60°C, device efficiency drastically decreases by 96%, and the shunt resistance decreases by 97%, accompanied by a significant quantity of Na<sup>+</sup> ions (derived from the soda lime glass) throughout the device structure, leading to a typical PID-shunting effect. Interestingly, we observed a rapid recovery of device performance during room-temperature dark storage, in which Na<sup>+</sup> ions located close to the glass substrate side rapidly migrated out of the device. Moreover, we also found that the Na<sup>+</sup> ions do not appear to diffuse through the grain boundaries but rather their neighboring area and grain interiors, judging by microscopic conductivity mappings.</p>\u0000 </div>","PeriodicalId":223,"journal":{"name":"Progress in Photovoltaics","volume":"32 12","pages":"941-949"},"PeriodicalIF":8.0,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sinju Thomas, Wolfram Witte, Dimitrios Hariskos, Rico Gutzler, Stefan Paetel, Chang-Yun Song, Heiko Kempa, Matthias Maiberg, Daniel Abou-Ras
{"title":"Role of Ag Addition on the Microscopic Material Properties of (Ag,Cu)(In,Ga)Se2 Absorbers and Their Effects on Losses in the Open-Circuit Voltage of Corresponding Devices","authors":"Sinju Thomas, Wolfram Witte, Dimitrios Hariskos, Rico Gutzler, Stefan Paetel, Chang-Yun Song, Heiko Kempa, Matthias Maiberg, Daniel Abou-Ras","doi":"10.1002/pip.3845","DOIUrl":"https://doi.org/10.1002/pip.3845","url":null,"abstract":"<p>Ag alloying of Cu(In,Ga)Se<sub>2</sub> (CIGSe) absorbers in thin-film solar cells leads to improved crystallization of these absorber layers at lower substrate temperatures than for Ag-free CIGSe thin films as well as to enhanced cation interdiffusion, resulting in reduced Ga/In gradients. However, the role of Ag in the microscopic structure–property relationships in the (Ag,Cu)(In,Ga)Se<sub>2</sub> thin-film solar cells as well as a correlation between the various microscopic properties of the polycrystalline ACIGSe absorber and open-circuit voltage of the corresponding solar cell device has not been reported earlier. In the present work, we study the effect of Ag addition by analyzing the differences in the various bulk, grain-boundary, optoelectronic, emission, and absorption-edge properties of ACIGSe absorbers with that of a reference CIGSe absorber. By comparing thin-film solar cells with similar band-gap energies ranging from about 1.1 to about 1.2 eV, we were able to correlate the differences in their absorber material properties with the differences in the device performance of the corresponding solar cells. Various microscopic origins of open-circuit voltage losses were identified, such as strong Ga/In gradients and local compositional variations within individual grains of ACIGSe layers, which are linked to absorption-edge broadening, lateral fluctuations in luminescence-energy distribution, and band tailing, thus contributing to radiative <i>V</i><sub>OC</sub> losses. A correlation established between the effective electron lifetime, average grain size, and lifetime at the grain boundaries indicates that enhanced nonradiative recombination at grain boundaries is a major contributor to the overall <i>V</i><sub>OC</sub> deficit in ACIGSe solar cells. Although the alloying with Ag has been effective in increasing the grain size and the effective electron lifetime, still, the Ga/In gradients and the grain-boundary recombination in the ACIGSe absorbers must be reduced further to improve the solar-cell performance.</p>","PeriodicalId":223,"journal":{"name":"Progress in Photovoltaics","volume":"32 12","pages":"930-940"},"PeriodicalIF":8.0,"publicationDate":"2024-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/pip.3845","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Marlon Schlemminger, Dennis Bredemeier, Alexander Mahner, Raphael Niepelt, Michael H. Breitner, Rolf Brendel
{"title":"Rooftop PV Potential Determined by Backward Ray Tracing: A Case Study for the German Regions of Berlin, Cologne, and Hanover","authors":"Marlon Schlemminger, Dennis Bredemeier, Alexander Mahner, Raphael Niepelt, Michael H. Breitner, Rolf Brendel","doi":"10.1002/pip.3844","DOIUrl":"10.1002/pip.3844","url":null,"abstract":"<p>Photovoltaics (PV) on building rooftops is a major contributor to the decarbonization of energy systems. We simulate the PV energy yield potential for 2.5 million individual roofs in three German regions. We cumulate the results for each single roof to calculate the cost-potential curves for the three cities Berlin, Cologne, and Hanover. These curves give the amount of electricity that can be generated at less than a given cost per kWh. We find that these curves have the shape of a hockey stick. Neglecting the dependence of PV investment on building size and thus on the system sizes causes largely different cost-potential curves that differ by 11%–18% for flat roofs due to their heterogeneous building size distribution. The cost-potential curves of the three cities are very similar when appropriately normalized, for example, by the local solar irradiation and the settlement area of the city, despite substantial variations in population density. This allows for an extrapolation of our results. For Germany, we reveal an upper limit for the total electricity generation from rooftop PV of 762 TWh/a with cost as low as 6.9 ct/kWh without accounting for area losses due to chimneys, air conditioning systems, and so forth. We estimate the actual potential to be at least half of that figure.</p>","PeriodicalId":223,"journal":{"name":"Progress in Photovoltaics","volume":"32 12","pages":"912-929"},"PeriodicalIF":8.0,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/pip.3844","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142255949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dirk Hauschild, Frank Meyer, Andreas Benkert, Thomas Dalibor, Monika Blum, Wanli Yang, Friedrich Reinert, Clemens Heske, Lothar Weinhardt
{"title":"Chemical and Electronic Structure of the i-ZnO/InxSy:Na Front Contact Interface in Cu(In,Ga)(S,Se)2 Thin-Film Solar Cells","authors":"Dirk Hauschild, Frank Meyer, Andreas Benkert, Thomas Dalibor, Monika Blum, Wanli Yang, Friedrich Reinert, Clemens Heske, Lothar Weinhardt","doi":"10.1002/pip.3840","DOIUrl":"10.1002/pip.3840","url":null,"abstract":"<p>The chemical and electronic structure of the front contact i-ZnO/In<sub>x</sub>S<sub>y</sub>:Na interface for Cu(In,Ga)(S,Se)<sub>2</sub>-based thin-film solar cells is investigated using a combination of x-ray and electron spectroscopies. Upon i-ZnO sputter deposition on the In<sub>x</sub>S<sub>y</sub>:Na buffer layer, we find an intermixed heterojunction and the formation of InO<sub>x</sub> and Na<sub>2</sub>SO<sub>4</sub>. The window layer is shown to consist of a mixture of Zn(OH)<sub>2</sub> and ZnO, with decreasing relative Zn(OH)<sub>2</sub> content for thicker window layers. Moreover, we observe diffusion of sodium to the surface of the window layer. We derive electronic surface band gaps of the i-ZnO and In<sub>x</sub>S<sub>y</sub>:Na layers of 3.86 ± 0.18 eV and 2.60 ± 0.18 eV, respectively, and find a largely flat conduction band alignment at the i-ZnO/In<sub>x</sub>S<sub>y</sub>:Na interface.</p>","PeriodicalId":223,"journal":{"name":"Progress in Photovoltaics","volume":"32 12","pages":"904-911"},"PeriodicalIF":8.0,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/pip.3840","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Electrical Performance, Loss Analysis, and Efficiency Potential of Industrial-Type PERC, TOPCon, and SHJ Solar Cells: A Comparative Study","authors":"Qinqin Wang, Kaiyuan Guo, SiWen Gu, Wei Huang, Hui Peng, Wangping Wu, Jianning Ding","doi":"10.1002/pip.3839","DOIUrl":"10.1002/pip.3839","url":null,"abstract":"<div>\u0000 \u0000 <p>Currently, the efficiency of p-type passivated emitter and rear contact (PERC) cells has been growing at an absolute efficiency of 0.5% per year and has reached 23%–23.5% in mass production while getting closer to its theoretical efficiency limit. n-Type tunnel oxide passivated contact (TOPCon) and silicon heterojunction (SHJ) cells with their superior “passivating selective contacts” technology were the most interesting photovoltaics (PV) technology in the industry. The effect of different passivated contact layers with respect to their influence on the <i>J</i><sub><i>0</i></sub>, <i>J</i><sub><i>0,metal</i></sub>, <i>ρ</i><sub>c</sub>, and the carrier selectivity (S<sub>10</sub>) and the loss analysis and efficiency potential of industrial-type PERC, TOPCon, and SHJ solar cells were studied and compared. The results showed that TOPCon structure with a high passivation performance and good optical performance is more suitable for bifacial solar cell and the highest theoretical limiting efficiency with metal shading on the n-type Si wafer (<i>η</i><sub><i>b,e,h,m,max</i></sub>) can be achieved to 27.62%. Although SHJ structure with the highest passivation performance but the worst optical performance owing to the parasitic absorption of a-Si:H layer and high contact resistivity, the value of <i>η</i><sub><i>b,e,h,m,max</i></sub> is 0.7% lower than that of TOPCon solar cells. PERC structure has superior optical performance than SHJ structure, but due to poor passivation performance, the <i>η</i><sub><i>b,e,h,m,max</i></sub> is only 26.42%. The next-generation products may be heterojunction back-contact (HBC) and TOPCon back-contact (TBC) cells with high <i>η</i><sub><i>b,e,h,m,max</i></sub> of 28.12% and 27.99%, respectively. Exploiting a perfect passivation of the noncontact area, the wide process window and low cost are required and transferring these new concepts to industrial solar cell production will be the next major challenge.</p>\u0000 </div>","PeriodicalId":223,"journal":{"name":"Progress in Photovoltaics","volume":"32 12","pages":"889-903"},"PeriodicalIF":8.0,"publicationDate":"2024-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191332","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Giuseppe Marco Tina, Amr Osama, Raniero Cazzaniga, Monica Cicu, Jon Hancock, Eamon Howlin, Marco Rosa-Clot, Paolo Rosa-Clot
{"title":"PVSails: Harnessing Innovation With Vertical Bifacial PV Modules in Floating Photovoltaic Systems","authors":"Giuseppe Marco Tina, Amr Osama, Raniero Cazzaniga, Monica Cicu, Jon Hancock, Eamon Howlin, Marco Rosa-Clot, Paolo Rosa-Clot","doi":"10.1002/pip.3841","DOIUrl":"10.1002/pip.3841","url":null,"abstract":"<p>In the context of offshore floating photovoltaic systems (FPVs), this paper explores the use of bifacial photovoltaic modules installed in the vertical position. The energy harvested from the rear face of vertically configured bifacial PV modules compensates for the reduced production at the front face of the module, and this demonstrates the potential of bifacial technology for offshore applications. By comparison, most existing horizontally tilted bifacial FPV systems gain only a small benefit in production from the rear face of the module due to the minimum radiation received, and what also must be taken into consideration is the negative effect of significant soiling owing to the low tilt angle of the PV modules. Hence, to overcome these drawbacks, we have developed the innovative “PVSail” concept, which explores the deployment of vertical FPV systems on floats, buoys, or poles/minipiles. Floating vertical bifacial PV systems (VBPVs) have huge potential to harness all the energy generation capabilities enhance by reflected light, especially from snow-covered surfaces in northern regions. Our analysis considers a patented mooring and vertical PV system that allows the VBPV structure to align with the prevailing wind direction to shed wind loads, and our numerical analysis explores the potential of VBPV applied to Catania in Italy and Nigg Bay in the United Kingdom. Our analysis study has revealed that across an azimuth angle range (0°–180°), vertical bifacial modules experience roughly a 9% decrease in energy yield at Catania and about a 5% energy yield gain in higher latitude regions like Nigg Bay. Additionally, increasing the latitude of the installation location of VBPV reduces the energy yield sensitivity to the orientation, that is, azimuth angle. The PVSail concept opens the door to novel deployment possibilities in offshore renewable energy projects.</p>","PeriodicalId":223,"journal":{"name":"Progress in Photovoltaics","volume":"32 12","pages":"872-888"},"PeriodicalIF":8.0,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/pip.3841","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191330","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of solution-processed cesium carbonate on Cu(In,Ga)Se2 thin-film solar cells","authors":"Ishwor Khatri, Alec P. LaGrow, Oleksandr Bondarchuk, Nicoleta Nicoara, Sascha Sadewasser","doi":"10.1002/pip.3838","DOIUrl":"10.1002/pip.3838","url":null,"abstract":"<p>Heavy alkali-metal treatments have been the most recent breakthrough in improving the efficiency of Cu(In,Ga)Se<sub>2</sub> (CIGS) solar cells. Alkali halides are generally evaporated onto the surface of the CIGS thin film by a vacuum process. Here, we report an alternative, low-cost solution process for the surface treatment of CIGS thin films using cesium carbonate (CsCO<sub>3</sub>) as a new route to incorporate cesium (Cs) for improving solar cell performance. CIGS thin films were fabricated using pulsed hybrid reactive magnetron sputtering and the surface treatment was performed by spin-coating CsCO<sub>3</sub> solution on the surface of CIGS at room temperature, followed by vacuum annealing at 400°C. The surface chemistry of the CIGS thin film changed after the treatment and the efficiency of respective solar cells improved by more than 30%, mostly driven by an enhancement in open-circuit voltage. X-ray photoelectron spectroscopy revealed the depletion of copper and the presence of Cs on the surface of the CIGS thin film. Ultraviolet photoelectron spectroscopy showed the lowering of the valence band maximum by around 0.25 eV after the treatment, which plays a positive role in reducing interfacial recombination. High-resolution transmission electron microscopy indicates the presence of Cs and depletion of Cu at the grain boundaries of the CIGS thin film. These findings open a low-cost route for improving the performance of CIGS solar cells by surface modification using a solution process.</p>","PeriodicalId":223,"journal":{"name":"Progress in Photovoltaics","volume":"32 12","pages":"864-871"},"PeriodicalIF":8.0,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/pip.3838","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Updated sustainability status of cadmium telluride thin-film photovoltaic systems and projections","authors":"Vasilis Fthenakis, Enrica Leccisi, Parikhit Sinha","doi":"10.1002/pip.3837","DOIUrl":"10.1002/pip.3837","url":null,"abstract":"<p>This paper provides a comprehensive assessment of the up-to-date life-cycle sustainability status of cadmium-telluride based photovoltaic (PV) systems. Current production modules (Series 6 and Series 7) are analyzed in terms of their energy performance and environmental footprint and compared with the older series 4 module production and current single-crystalline Silicon (sc-Si) module production. For fixed-tilt systems with Series 6 modules operating under average US irradiation of 1800 kWh/m<sup>2</sup>/year, the global warming potential (GWP) is reduced from 16 g CO<sub>2eq</sub>/kWh in Series 4 systems to 10 CO<sub>2eq</sub>/kWh in Series 6 systems. For operation in US-SW irradiation of 2300 kWh/m<sup>2</sup>/year, the GWP is reduced from 11 to 8 CO<sub>2eq</sub>/kWh and for 1-axis tracking systems operating in Phoenix, Arizona, with point-of array irradiation of 3051 kWh/m<sup>2</sup>/year the GWP is reduced to 6.5 CO<sub>2eq</sub>/kWh. Similar reductions have happened in all environmental indicators. Energy payback times (EPBT) of currently installed systems range from 0.6 years for fixed-tilt ground-mounted installations at average US irradiation at latitude tilt installations to 0.3 years for one-axis trackers at high US-SW irradiation, considering average fossil-fuel dominated electricity grids with fuel to electricity conversion efficiency of 0.3. The resulting energy return on energy investment (EROI) also depends on the conversion efficiency of the electricity grid and on the operation life expectance. For a 30-year operational life and grid conversion efficiency of 0.3, EROI ranges from 50 (at US average irradiation) to 70 for US-SW irradiation. The EROI declines with increased grid conversion efficiency; for CdTe PV operating in south California with grid conversion efficiency of 49%, the EROI is about 50 and is projected to fall to 30 when the state's 2030 target of 80% renewable energy penetration materializes. Material alternatives that show a potential of further reductions in degradation rates and materials for enhanced encapsulation that would enable longer operation lives have also been investigated. A degradation rate of 0.3%/year, which has been verified by accelerated testing, is assumed in 30-year scenarios; this is projected to be reduced to 0.2%/year in the near-term and potentially to 0.1%/year in the longer term. With such low degradation rates and enhanced edge-sealing, modules can last 40- to 50-years. Consequently, all impact indicators will be proportionally reduced while EROI will increase. This detailed LCA was conducted according to ISO standards and IEA PVPS Task 12 guidelines. The study revealed that the choices of system models, methods and temporal system boundaries can significantly impact the results and points out to the need to include assumptions regarding these choices in the “transparency in reporting” requirements listed in the IEA PVPS Task 12 Guidelines.</p>","PeriodicalId":223,"journal":{"name":"Progress in Photovoltaics","volume":"32 12","pages":"846-863"},"PeriodicalIF":8.0,"publicationDate":"2024-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141940695","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Rosemary Davis, Ochai Oklobia, Stuart J. C. Irvine, Dan Lamb
{"title":"Comparative study of cadmium telluride solar cell performance on different TCO-coated substrates under concentrated light intensities","authors":"Rosemary Davis, Ochai Oklobia, Stuart J. C. Irvine, Dan Lamb","doi":"10.1002/pip.3836","DOIUrl":"10.1002/pip.3836","url":null,"abstract":"<p>Concentrating photovoltaics is an attractive route for achieving high power output with thin film solar cells, using low-cost optics. In this work, the performance of CdTe:As thin film solar cells on two different transparent conducting oxide (TCO)-coated substrates is investigated and compared under varying concentrated light intensities (1–6.3 Suns). Samples tested had CdZnS/CdTe:As devices deposited atop of either a soda-lime glass with a fluorine-doped tin oxide TCO or an ultra-thin glass (UTG) with an aluminium zinc oxide TCO and ZnO high-resistive transparent (HRT) layer. Device current density was found to increase linearly with increased light intensities, for both sample configurations. Power conversion efficiencies of both device samples decreased with increased light intensity, due to a decrease in fill factor. The fill factor, for both sample configurations, was affected by reducing shunt resistance with increasing illumination intensity. The two device types performed differently at the high illumination intensities due to their series resistance. Light-soaking devices under 6.3 Suns illumination intensity for 90 min showed no significant performance degradation, indicative of relatively stable devices under the highest illumination intensity tested. Efficiency limiting factors are assessed, evaluated and discussed.</p>","PeriodicalId":223,"journal":{"name":"Progress in Photovoltaics","volume":"32 12","pages":"839-845"},"PeriodicalIF":8.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/pip.3836","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141772547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}