Journal of Materials Science最新文献

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Effect of microstructure evolution on mechanical properties and oxidation behavior of Super304H and HR3C after long-term service
IF 3.5 3区 材料科学
Journal of Materials Science Pub Date : 2024-12-08 DOI: 10.1007/s10853-024-10230-5
Lei Zhao, Xinyu Li, Lianyong Xu, Yongdian Han, Kangda Hao, Xiangfeng Zheng
{"title":"Effect of microstructure evolution on mechanical properties and oxidation behavior of Super304H and HR3C after long-term service","authors":"Lei Zhao,&nbsp;Xinyu Li,&nbsp;Lianyong Xu,&nbsp;Yongdian Han,&nbsp;Kangda Hao,&nbsp;Xiangfeng Zheng","doi":"10.1007/s10853-024-10230-5","DOIUrl":"10.1007/s10853-024-10230-5","url":null,"abstract":"<div><p>The oxidation structure, microstructure and mechanical properties of Super304H and HR3C are investigated after running at 630 °C/3 MPa for 40,000 h. After service, a duplex oxide is formed on the steam side of heat-resistant steel, and it is possible that the surface treatment has caused surface deformation of Super304H, leading to an increase in corrosion resistance. For Super304H, a chain-like distribution of M<sub>23</sub>C<sub>6</sub> has been formed at the grain boundaries, causing creep cavities, NbCrN and <i>ɛ</i>-Cu particles have precipitated inside the grains. For HR3C, there is a significant aggregation of Cr at the grain boundaries, with only a small amount of M<sub>23</sub>C<sub>6</sub> and <i>σ</i> phase, and a large number of nanoscale NbCrN particles appear within the grains. The stable and dispersed precipitates inside the grains hinder the movement of dislocations, allowing heat-resistant steel to maintain higher strength than its as-received condition after long-term service. The microstructure evolution at grain boundaries leads to a decrease in toughness and plasticity of heat-resistant steel, and the continuous evaporation of Cr in high-temperature steam will cause a gradual decrease in Cr concentration and a deterioration in oxidation resistance of heat-resistant steel.</p></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"59 48","pages":"22206 - 22227"},"PeriodicalIF":3.5,"publicationDate":"2024-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142811274","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Alkali and alkaline earth metals cation effects on the formation of akageneite in corrosion products of steel artifacts embedded in soil: a study under simulated laboratory conditions
IF 3.5 3区 材料科学
Journal of Materials Science Pub Date : 2024-12-07 DOI: 10.1007/s10853-024-10499-6
Achal Pandya, Jitendra Kumar Singh, Hyun-Min Yang, D. D. N. Singh
{"title":"Alkali and alkaline earth metals cation effects on the formation of akageneite in corrosion products of steel artifacts embedded in soil: a study under simulated laboratory conditions","authors":"Achal Pandya,&nbsp;Jitendra Kumar Singh,&nbsp;Hyun-Min Yang,&nbsp;D. D. N. Singh","doi":"10.1007/s10853-024-10499-6","DOIUrl":"10.1007/s10853-024-10499-6","url":null,"abstract":"<div><p>X-ray diffraction (XRD), electrochemical tests, scanning electron microscopy and energy-dispersive X-ray analysis (SEM-EDXA) techniques were used to study the kinetics and growth of akageneite in corrosion products of steel exposed in moist soil added with chloride salts of sodium, potassium calcium, magnesium, and barium. The cations significantly affected the kinetics of corrosion and nucleation and growth of the akageneite. Divalent cations catalyze the corrosion and akageneite formation. The volume fraction of akageneite determined by XRD for monovalent cations (Na<sup>+</sup> and K<sup>+</sup>) is observed in the range of 10–12% and that for divalent is in the range of 16–19%. This increase in akageneite leads to a decrease in the charge transfer resistance (<i>R</i><sub><i>ct</i></sub>) for monovalent (Na<sup>+</sup>) and divalent cations (Ca<sup>++</sup> and Mg<sup>++</sup>) (0.9 kΩ·cm<sup>2</sup> and 0.4 kΩ·cm<sup>2</sup>, respectively). The mechanism of acceleration of corrosion by akageneite is discussed in light of disruption effects of added cations on electrical double layer formed at the steel-moist soil interface.</p></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"59 48","pages":"22292 - 22309"},"PeriodicalIF":3.5,"publicationDate":"2024-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142811220","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluating the role of nickel-coated carbon fiber in improving high-temperature capabilities of Sn–3.0Ag–0.5Cu solder joints
IF 3.5 3区 材料科学
Journal of Materials Science Pub Date : 2024-12-07 DOI: 10.1007/s10853-024-10472-3
Yihui Du, Xiaoliang Ji, Aiwei Liu, Yishu Wang, Fu Guo
{"title":"Evaluating the role of nickel-coated carbon fiber in improving high-temperature capabilities of Sn–3.0Ag–0.5Cu solder joints","authors":"Yihui Du,&nbsp;Xiaoliang Ji,&nbsp;Aiwei Liu,&nbsp;Yishu Wang,&nbsp;Fu Guo","doi":"10.1007/s10853-024-10472-3","DOIUrl":"10.1007/s10853-024-10472-3","url":null,"abstract":"<div><p>The study explores the possible application of nickel-coated carbon fiber (Ni@CF) to enhance the high-temperature reliability of Sn–3.0Ag–0.5Cu solder connections. It thoroughly examines the growth behavior of intermetallic compounds (IMC) during high-temperature aging. The research results show that after 192 h of aging at 200 °C, the overall IMC layer thickness was reduced because of the more tortuous grain boundaries of the interfacial IMC in the Ni@CF composite solder joints. Additionally, the incorporation of Ni@CF led to decreasing disparities in hardness and modulus between the solder matrix and IMC near the joining interface and improved solder matrix and substrate compliance. Enhanced high-temperature hardness of composite solder matrix up to 200 °C while maintaining solder joint integrity was observed. The study provides a comprehensive insight into the influence of Ni@CF on interfacial IMC grain structure and the reliability of the composite solder joints in high-temperature environments.</p></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"59 48","pages":"22250 - 22265"},"PeriodicalIF":3.5,"publicationDate":"2024-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142811221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Probing the difference in improving the ignition and combustion of micro/nano-sized aluminum powder modified by VitonA
IF 3.5 3区 材料科学
Journal of Materials Science Pub Date : 2024-12-07 DOI: 10.1007/s10853-024-10486-x
Yang Chen, Jiquan Wang, Yanan Wang, Baozhong Zhu, Yunlan Sun
{"title":"Probing the difference in improving the ignition and combustion of micro/nano-sized aluminum powder modified by VitonA","authors":"Yang Chen,&nbsp;Jiquan Wang,&nbsp;Yanan Wang,&nbsp;Baozhong Zhu,&nbsp;Yunlan Sun","doi":"10.1007/s10853-024-10486-x","DOIUrl":"10.1007/s10853-024-10486-x","url":null,"abstract":"<div><p>Aluminum (Al) powder is commonly used in solid propellants because of its high energy density. However, Al powder is prone to agglomeration during combustion, resulting in lower combustion efficiency. The energy-containing composites of micro/nano-sized Al powder modified by the hexafluoropropylene and vinylidene fluoride dipolymers (VitonA) were fabricated by an evaporation solvent method, and the morphology, thermal behavior, and ignition and combustion (IAC) properties were investigated. The IAC performance of the nano-sized aluminum (nAl) is improved obviously when the coating concentration of VitonA reaches 15%, and higher combustion intensity is attained, which confirms the occurrence of the preignition reaction between nAl and fluoropolymer. Although the IAC properties of micro-sized Al (μAl) powder are also improved by VitonA, there is different impact mechanism of VitonA on the nAl and μAl. These results provide guidance for inhibiting the agglomeration of Al powder and improving its combustion efficiency.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"59 48","pages":"22091 - 22108"},"PeriodicalIF":3.5,"publicationDate":"2024-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142811219","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unlocking the lead-free new all inorganic cubic halide perovskites of Ba3MI3 (M = P, As, Sb) with efficiency above 29%
IF 3.5 3区 材料科学
Journal of Materials Science Pub Date : 2024-12-06 DOI: 10.1007/s10853-024-10487-w
Md. Monirul Islam, Md. Ferdous Rahman, Md. Hafizur Rahman, Mutasem Z. Bani-Fwaz, Rahul Pandey, Md. Harun-Or-Rashid
{"title":"Unlocking the lead-free new all inorganic cubic halide perovskites of Ba3MI3 (M = P, As, Sb) with efficiency above 29%","authors":"Md. Monirul Islam,&nbsp;Md. Ferdous Rahman,&nbsp;Md. Hafizur Rahman,&nbsp;Mutasem Z. Bani-Fwaz,&nbsp;Rahul Pandey,&nbsp;Md. Harun-Or-Rashid","doi":"10.1007/s10853-024-10487-w","DOIUrl":"10.1007/s10853-024-10487-w","url":null,"abstract":"<div><p>The solar industry is increasingly shifting its attention toward lead (Pb)-free inorganic cubic halide perovskite materials due to their outstanding structural, mechanical, electronic, and optoelectronic properties. In our study, we conducted a thorough examination of the structural, mechanical, electronic, and optical properties of Ba<sub>3</sub>MI<sub>3</sub> (M = P, As, Sb), and assessed their photovoltaic potential using first-principles density functional theory (FP-DFT) and the SCAPS-1D solar cell simulator. Our results revealed that all the perovskite materials exhibited a direct band gap at the Γ-point, favorable tolerance factors, mechanical durability, minimal energy losses, and excellent absorption coefficients. This makes them promising candidates for use in photovoltaic cells and various optoelectronic devices. Additionally, we employed the SCAPS-1D simulator to perform an in-depth analysis of photovoltaic efficiency in solar cell architectures with Ba<sub>3</sub>PI<sub>3</sub>, Ba<sub>3</sub>AsI<sub>3</sub>, and Ba<sub>3</sub>SbI<sub>3</sub> as absorber layers, incorporating a SnS<sub>2</sub> electron transport layer (ETL). The study explored the effects of variations in thickness, defect densities, and doping concentrations. The highest power conversion efficiencies (PCE) achieved were 29.50% for Ba<sub>3</sub>PI<sub>3</sub>, 27.16% for Ba3AsI3, and 21.29% for Ba<sub>3</sub>SbI<sub>3</sub>, with open-circuit voltages (V<sub>OC</sub>) of 1.02, 0.96, and 0.91 V; short-circuit current densities (J<sub>SC</sub>) of 32.92, 32.19, and 27.51 mA/cm<sup>2</sup>, and fill factors (FF) of 87.75%, 87.56%, and 85.16%, respectively. We observed that variations in the M-anion size influenced the bandgap energy, band structure, mechanical, and optoelectronic properties, as well as the solar cell performance. This research provides valuable insights into the development of lead-free hybrid solar cells and other optoelectronic applications.</p></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"59 48","pages":"22109 - 22131"},"PeriodicalIF":3.5,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142811218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced interfacial interaction of basalt fiber/PP composites by in-situ grown ZnO nanorods: preparation, structure, property and mechanistic study
IF 3.5 3区 材料科学
Journal of Materials Science Pub Date : 2024-12-05 DOI: 10.1007/s10853-024-10480-3
Zuoxian She, Guanxi Zhao, Ming Li, Pan He, Yuanchao Jiang, Zhongzui Wang, Guangzhao Li, Hong Jiang, Rui Han, Shuai Zhang
{"title":"Enhanced interfacial interaction of basalt fiber/PP composites by in-situ grown ZnO nanorods: preparation, structure, property and mechanistic study","authors":"Zuoxian She,&nbsp;Guanxi Zhao,&nbsp;Ming Li,&nbsp;Pan He,&nbsp;Yuanchao Jiang,&nbsp;Zhongzui Wang,&nbsp;Guangzhao Li,&nbsp;Hong Jiang,&nbsp;Rui Han,&nbsp;Shuai Zhang","doi":"10.1007/s10853-024-10480-3","DOIUrl":"10.1007/s10853-024-10480-3","url":null,"abstract":"<div><p>Basalt fiber (BF) is a new type of environmentally friendly high-performance fiber, but the smooth and chemically inert surface limits its practical application. In order to increase the interfacial interaction of the BF based composites, ZnO nanorods were in-situ grown on the BF by hydrothermal method. Polymer composites based on polypropylene (PP) and modified BF were prepared by melt blending and micro injection molding. The structure and properties of the composites were investigated in detail and a three-dimensional representative volume element (RVE) model was applied to verify the effect of ZnO nanorods on the interfacial failure behavior of the composites. The results showed that the growth of ZnO nanorods increased the transverse strain of interfacial debonding and altered the damage pattern of the composites. Specifically, the rod-like ZnO enhanced the surface roughness and specific surface area of BF, produced higher shear force during micro injection molding process, caused more physical interlock and entanglement in the composites. As the result, the interface thickness, crystallinity and crystal orientation were increased. Consequently, the mechanical strength of the composites improved.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"59 48","pages":"22073 - 22090"},"PeriodicalIF":3.5,"publicationDate":"2024-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142811143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of welding methods on the microstructure of nickel-based weld metal for liquid hydrogen tanks
IF 3.5 3区 材料科学
Journal of Materials Science Pub Date : 2024-12-05 DOI: 10.1007/s10853-024-10505-x
Chenjun Yu, Tomoya Kawabata, Shigetoshi Kyouno, Xixian Li, Shohei Uranaka, Daiki Maeda
{"title":"Influence of welding methods on the microstructure of nickel-based weld metal for liquid hydrogen tanks","authors":"Chenjun Yu,&nbsp;Tomoya Kawabata,&nbsp;Shigetoshi Kyouno,&nbsp;Xixian Li,&nbsp;Shohei Uranaka,&nbsp;Daiki Maeda","doi":"10.1007/s10853-024-10505-x","DOIUrl":"10.1007/s10853-024-10505-x","url":null,"abstract":"<div><p>This study investigates the microstructure and hardness of weld metals used in liquid hydrogen storage tanks, with a focus on the effects of three welding methods: Gas Tungsten Arc Welding (GTAW), Submerged Arc Welding (SAW), and Shielded Metal Arc Welding (SMAW). Finite element simulations were employed to model the temperature field during welding, aiding in the explanation of observed microstructural differences. The results show that while GTAW and SMAW produce weld metals with similar microstructures, SAW generates significantly larger grains with a pronounced preferential orientation. The use of weaving techniques play a key role in shaping the solidification microstructures. Additionally, the hardness of the weld metal is comparable to that of the base material, with a slight reduction corresponding to increased grain size. This research offers valuable insights into optimizing welding processes for liquid hydrogen storage tanks by addressing the microstructural characteristics that influence weld joint performance.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"59 48","pages":"22310 - 22326"},"PeriodicalIF":3.5,"publicationDate":"2024-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10853-024-10505-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142811141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative investigation of surface-electrical properties of functionalized graphene and MXene thin films for CO2 gas sensing
IF 3.5 3区 材料科学
Journal of Materials Science Pub Date : 2024-12-04 DOI: 10.1007/s10853-024-10440-x
Pradeep Kumar, Huzein Fahmi Hawari, Monika Gupta, Wei Xian Rebecca Leong, Mohamed Shuaib Mohamed Saheed, Goran M. Stojanović, Lila Iznita Izhar
{"title":"Comparative investigation of surface-electrical properties of functionalized graphene and MXene thin films for CO2 gas sensing","authors":"Pradeep Kumar,&nbsp;Huzein Fahmi Hawari,&nbsp;Monika Gupta,&nbsp;Wei Xian Rebecca Leong,&nbsp;Mohamed Shuaib Mohamed Saheed,&nbsp;Goran M. Stojanović,&nbsp;Lila Iznita Izhar","doi":"10.1007/s10853-024-10440-x","DOIUrl":"10.1007/s10853-024-10440-x","url":null,"abstract":"<div><p>Nowadays, CO<sub>2</sub> detection has become significant in many applications such as monitoring of air quality and human health. CO<sub>2</sub> sensors are majorly based on solid-state materials, but they require high operating temperatures. Recently, two-dimensional materials have been explored to achieve room-temperature CO<sub>2</sub> detection. Among them, graphene and MXene gained attraction owing to their outstanding chemical and electronic properties. Sensing materials’ properties such as surface and electrical properties are very crucial to achieve highly sensitive gas sensors. In this work, we comprehensively investigate and compare the impact of surface-electrical properties of graphene and MXene on their CO<sub>2</sub> sensors’ performance. Initially, we synthesize and characterize the surface-electrical properties of functionalized graphene (FG) and Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXene. Later, chemiresistive CO<sub>2</sub> gas sensors are fabricated with these materials as sensing layers and their performance is examined. From material characterizations, we find that MXene surface is more hydrophilic, showing 1.5-fold higher interfacial energy, and has ~ 1.2-fold higher electrical conductivity than FG, whereas FG demonstrates lower surface roughness and outstanding stability over the period. The sensing behavior of both sensors is found to be repeatable, selective, and reproducible. The CO<sub>2</sub> sensor with the MXene layer reveals a lower response/recovery time (12/17 s) than that of FG (32/43 s). Also, MXene-based sensor exhibits a 25% response, revealing a 6% higher gas response than FG-based sensor. However, from the stability point of view, FG sensor outperforms the MXene sensors. We believe this study is extremely beneficial in realizing highly efficient gas sensors for air quality and health monitoring.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"59 48","pages":"22132 - 22148"},"PeriodicalIF":3.5,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142811072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A platform of gold nanoparticles coated with silica as controlled drug delivery for application in cancer treatment
IF 3.5 3区 材料科学
Journal of Materials Science Pub Date : 2024-12-04 DOI: 10.1007/s10853-024-10490-1
Isabela Barreto da Costa Januário Meireles, André Felipe Oliveira, Michele Angela Rodrigues, Edésia Martins Barros de Sousa
{"title":"A platform of gold nanoparticles coated with silica as controlled drug delivery for application in cancer treatment","authors":"Isabela Barreto da Costa Januário Meireles,&nbsp;André Felipe Oliveira,&nbsp;Michele Angela Rodrigues,&nbsp;Edésia Martins Barros de Sousa","doi":"10.1007/s10853-024-10490-1","DOIUrl":"10.1007/s10853-024-10490-1","url":null,"abstract":"<div><p>The optical properties of gold nanoparticles are widely investigated with interest in their application in photohyperthermia cancer treatments. Coating these nanoparticles with MCM-41 silica not only protects the gold nanoparticles but also has the potential for use as a nanocarrier, because of its textural properties. This nanocarrier allows the incorporation of drugs, such as methotrexate (MTX), for use in chemotherapy. Therefore, this nanoplatform shows promise for the treatment of cancer by photohyperthermia and chemotherapy, making the therapy more targeted and effective. This study aimed to investigate the incorporation and release of MTX from a nanoplatform of gold nanoparticles coated with MCM-41, which presents relevant properties for application in photohyperthermia treatments. The results showed that the proposed nanosystem has high cell viability and low cytotoxicity, indicating its potential for application in biological systems. Furthermore, our findings demonstrated that FITC-conjugated MCM-41 nanoparticles were internalized by the cells. Additionally, it was observed that nanomaterials containing MTX showed high cytotoxicity only to tumor cells and that these nanocarriers were taken up by cells, suggesting their specificity in cancer treatment. The synthesized nanocomposite shows promise for applications in cancer treatment through photohyperthermia and chemotherapy.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"59 48","pages":"22181 - 22205"},"PeriodicalIF":3.5,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142811073","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling the influence of nickel on the erosion and the tribological performance of AlSi-based abradable coatings
IF 3.5 3区 材料科学
Journal of Materials Science Pub Date : 2024-12-04 DOI: 10.1007/s10853-024-10492-z
Bruno E. Arendarchuck, Kaue Bertuol, Francisco Rivadeneira, Bruno C. N. M. de Castilho, Barry Barnett, Christian Moreau, Pantcho Stoyanov
{"title":"Unveiling the influence of nickel on the erosion and the tribological performance of AlSi-based abradable coatings","authors":"Bruno E. Arendarchuck,&nbsp;Kaue Bertuol,&nbsp;Francisco Rivadeneira,&nbsp;Bruno C. N. M. de Castilho,&nbsp;Barry Barnett,&nbsp;Christian Moreau,&nbsp;Pantcho Stoyanov","doi":"10.1007/s10853-024-10492-z","DOIUrl":"10.1007/s10853-024-10492-z","url":null,"abstract":"<div><p>The efficiency of gas turbine engines can significantly be enhanced by reducing the clearance between stationary and rotating parts. AlSi-polymer composite abradable coatings are commonly employed for such applications to serve as sacrificial materials while maintaining the pressure within compressors and seals. However, these coatings can face premature failure during operation, particularly due to corrosion and erosion. More specifically, due to the ductile behavior of AlSi-polymer-based abradables, the erosion rates at low impingement angles are particularly high. Thus, there is a strong desire to develop an abradable system capable of maintaining high erosion resistance at various impingement angles while maintaining suitable abradability (i.e., high wear of the abradable during interaction with the blade tip). The main purpose of this study is to critically evaluate the influence of Ni in AlSi-polymer-based abradable coatings on their erosion and tribological performance. The AlSi-polymer powders were mechanically mixed to develop the powders that were subsequently deposited using atmospheric plasma spray (APS). Microstructure analysis using field emission scanning electron microscopy (FESEM) and HR15Y hardness tests was employed to assess the microstructural and mechanical properties of the coating. Ball-on-flat, ball-on-disk, and air jet erosion tests were performed, followed by ex situ surface analysis to elucidate the wear mechanism. The results revealed that the incorporation of Ni preserved the lamellar microstructure characteristic of AlSi and polyester abradable coatings, while concurrently decreasing average wear rates at lower impingement angles, as observed throughout the erosion tests.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"59 48","pages":"22266 - 22282"},"PeriodicalIF":3.5,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142811070","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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