Glass Physics and Chemistry最新文献

Electrical and Ionic Conduction Phenomena of Tl2O3 Mixed Multi-Component Li2O–PbO–B2O3–SiO2–Bi2O3–V2O5 Glass System

IF 0.8 4区材料科学

Glass Physics and Chemistry Pub Date : 2025-03-23 DOI: 10.1134/S1087659624601175

P. Ramesh Babu, Kishor Palle, L. Srinivasa Rao, Sambhani Naga Gayatri, L. Vijayalakshmi, Seong Jin Kwon, R. Vijay, Rafa Almeer

{"title":"Electrical and Ionic Conduction Phenomena of Tl2O3 Mixed Multi-Component Li2O–PbO–B2O3–SiO2–Bi2O3–V2O5 Glass System","authors":"P. Ramesh Babu, Kishor Palle, L. Srinivasa Rao, Sambhani Naga Gayatri, L. Vijayalakshmi, Seong Jin Kwon, R. Vijay, Rafa Almeer","doi":"10.1134/S1087659624601175","DOIUrl":"10.1134/S1087659624601175","url":null,"abstract":"The synthesis of lithium lead borosilicate bismuth vanadate glasses with varying Tl2O3 concentrations (between 0 to 5.0 mol %) was achieved through the implementation of the melt quenching technique. A comprehensive analysis has been conducted to examine the electrical and dielectric properties over a broad spectrum of frequencies (102–106 Hz) and temperatures (303–573 K). According to the findings of conductivity studies, mixed conduction (both electronic and ionic) occurs in the produced glasses. As the concentration of Tl2O3 increases in the base glass, the dielectric properties, including dielectric loss, dielectric constant, and ac conduction, exhibit a decreasing trend. An increasing number of V5+ ions has been identified as being involved in the formation of networks near crystal structures of VO5. The quantitative study of ac conductivity and dielectric property data revealed that increasing the concentration of Tl2O3 in the glass network increases the insulating character of the glass. In the glass structure, the migration of thallium ions to tetrahedral coordination from octahedral coordination occurs, accompanied by a de-clustering effect of these ions.","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"50 5","pages":"483 - 495"},"PeriodicalIF":0.8,"publicationDate":"2025-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143676397","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of SiO2/Al2O3 Ratio on Porcelain Tile Glazes for Digital Application

IF 0.8 4区材料科学

Glass Physics and Chemistry Pub Date : 2025-03-23 DOI: 10.1134/S108765962460073X

Tarhan Şefik Baran, Taymur Serkan

{"title":"Effect of SiO2/Al2O3 Ratio on Porcelain Tile Glazes for Digital Application","authors":"Tarhan Şefik Baran,  Taymur Serkan","doi":"10.1134/S108765962460073X","DOIUrl":"10.1134/S108765962460073X","url":null,"abstract":"Production of porcelain tiles has been increasing rapidly with the increasing demand for both technological and aesthetic features for years. Especially tiles produced with digital applications attract much more attention. Digital glazes (glass-ceramic) can be matte or glossy features. In this study, the effect of the SiO2/Al2O3 ratio on technological properties was examined by keeping other oxide ratios constant in matte glaze compositions for digital applications. Seven glass ceramic compositions were prepared and trials were carried out under industrial conditions. The microstructure was measured with the use of a SEM, phases were determined by XRD, and sintering behavior was characterized by heating microscopy. The color and gloss of glazes were measured using a spectrophotometer and a gloss meter. As the SiO2/Al2O3 ratio decreased, especially the amount of anorthite crystal increased, which resulted in the formation of more matte glaze surfaces. Glaze whiteness and hardness increased due to the crystal formation. As the amount of Al2O3 increased, the softening and melting temperature points of the glazes also increased. It has been determined that surface properties can be modified for digital applications by changing the SiO2/Al2O3 ratio.","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"50 6","pages":"639 - 646"},"PeriodicalIF":0.8,"publicationDate":"2025-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143676412","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Innovative Organosilicate Coatings for Nuclear Energy

IF 0.8 4区材料科学

Glass Physics and Chemistry Pub Date : 2025-03-23 DOI: 10.1134/S1087659624600601

L. N. Krasil’nikova, A. V. Smeshko, T. A. Kochina, V. N. Epimakhov, O. A. Shilova

引用次数: 0

Supramolecular Composite Materials Based on Cobalt(II) Ferrite and Biochar for Purifying Aqueous Solutions from Chromium(VI) Ions

IF 0.8 4区材料科学

Glass Physics and Chemistry Pub Date : 2025-03-23 DOI: 10.1134/S108765962460042X

N. P. Shabel’skaya, A. M. Radzhabov, S. S. Mandzhieva, T. V. Bauer, T. M. Minkina, A. V. Arzumanova

{"title":"Supramolecular Composite Materials Based on Cobalt(II) Ferrite and Biochar for Purifying Aqueous Solutions from Chromium(VI) Ions","authors":"N. P. Shabel’skaya, A. M. Radzhabov, S. S. Mandzhieva, T. V. Bauer, T. M. Minkina, A. V. Arzumanova","doi":"10.1134/S108765962460042X","DOIUrl":"10.1134/S108765962460042X","url":null,"abstract":"The possibility of synthesizing supramolecular composite organo-inorganic materials based on cobalt(II) ferrite and biochars from rice husk and sunflower husk is studied. It is established that the morphology of the biochar determines the structural characteristics of the composite. The synthesized materials are characterized by X-ray phase analysis, BET, and scanning electron microscopy. Cobalt(II) ferrites crystallize on the surface of the carbon carrier in the form of a film, whose crystallite size is 80–96 nm, which is lower than for CoFe2O4, obtained using sol-gel technology. It is established that the synthesized composites exhibit significant catalytic activity in the process of decomposition of hydrogen peroxide and sorption of chromium(VI) compounds from an aqueous solution. The increase in the sorption capacity is associated with the formation of the Fenton system Fe3+/Fe2+. The obtained results can be used for the synthesis of innovative products from agricultural waste and their use in water treatment processes.","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"50 5","pages":"561 - 571"},"PeriodicalIF":0.8,"publicationDate":"2025-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143676221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Structure and Properties of Borosilicate Glass Containing Cesium and/or Strontium Oxides

IF 0.8 4区材料科学

Glass Physics and Chemistry Pub Date : 2025-03-23 DOI: 10.1134/S1087659624600455

N. F. Karpovich, A. S. Aloy, P. V. Slastikhina, T. I. Koltsova, V. A. Orlova, N. G. Tyurnina, Z. G. Tyurnina

{"title":"Structure and Properties of Borosilicate Glass Containing Cesium and/or Strontium Oxides","authors":"N. F. Karpovich, A. S. Aloy, P. V. Slastikhina, T. I. Koltsova, V. A. Orlova, N. G. Tyurnina, Z. G. Tyurnina","doi":"10.1134/S1087659624600455","DOIUrl":"10.1134/S1087659624600455","url":null,"abstract":"The study object is borosilicate glass with separate and combined inclusion of Cs and/or Sr oxides in amounts of 5, 10 and 15 wt %. This can be used in the fractionation scheme of liquid high-level waste from the spent nuclear fuel reprocessing. The main attention was paid to their compliance with the quality criteria established in the regulatory document NP-019-15, when studying the physicochemical, thermophysical and mechanical properties of synthesized glass. The glass structure changes slightly relative to the structure of the initial glass frit according to Raman spectroscopy. The exception was glass containing 15 wt % Cs2O, which contained new bands in the Raman spectra, in addition there were an increase in its molar volume and a decrease in the glass transition temperature. However, these changes had virtually no effect on the thermophysical and mechanical characteristics. The obtained data showed that the glass properties in the studied range of Cs and/or Sr oxides concentrations satisfy the current quality criteria for the product in the form of 137Cs and 90Sr vitrified concentrates after fractionation of liquid HLW.","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"50 6","pages":"647 - 654"},"PeriodicalIF":0.8,"publicationDate":"2025-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143676410","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Change in Plasticity of Ag2S during the Transition from the Monoclinic to the Superionic Cubic Phase

IF 0.8 4区材料科学

Glass Physics and Chemistry Pub Date : 2025-03-23 DOI: 10.1134/S1087659624601254

Yu. S. Tver’yanovich, K. S. Kravchuk

引用次数: 0

The Role of SiO2 Shell in the Formation of Hybrid Molecular Plasmonic Core–Shell Nanoparticles

IF 0.8 4区材料科学

Glass Physics and Chemistry Pub Date : 2025-03-23 DOI: 10.1134/S1087659624601059

D. A. Soldatova, E. S. Chebanova, A. Del Carpio Rocha, A. S. Konev, I. A. Sokolov, A. V. Povolotskiy

引用次数: 0

Recycling of Fly Ash and Waste Glass to Fabricate Environment Friendly Fly Ash Bricks 回收利用粉煤灰和废玻璃制造环保型粉煤灰砖

IF 0.8 4区材料科学

Glass Physics and Chemistry Pub Date : 2025-03-23 DOI: 10.1134/S1087659623600874

Amit Kumar Yadav, Prananjay Ekka, Ekta Patel, Sunipa Bhattacharyya

{"title":"Recycling of Fly Ash and Waste Glass to Fabricate Environment Friendly Fly Ash Bricks","authors":"Amit Kumar Yadav, Prananjay Ekka, Ekta Patel, Sunipa Bhattacharyya","doi":"10.1134/S1087659623600874","DOIUrl":"10.1134/S1087659623600874","url":null,"abstract":"Fly ash is the most abundantly produced waste material from thermal power plants and steel industries. Management of this fly ash is a tedious task as it creates economic and environmental problems for society. One popular way to recycle fly ash is to produce fly ash-based bricks for construction. However, as the binding capacity of fly ash is significantly less, it pollutes the surrounding environment of the working site. Fly ash brick is usually made using cement as a binder by cold compaction technique. Cement manufacturing is an expensive industrial process that releases carbon dioxide into the atmosphere. Therefore, the scrap glass powder is used here as an alternate binder. The glass powder is mixed with the fly ash to prepare glass-ceramic brick to reduce the brick firing temperature and trap the pollutants within the silica-rich glassy phase. The glass used in this work was the scrap glass collected from the chemical laboratory of the ceramic department (NIT Rourkela). Different batches were studied concerning the glass percentage and fly ash percentage. The fabricated green bodies were sintered at 900 and 1000°C for 2 h. X-ray diffraction study revealed the presence of mullite and cristobalite phases in the sintered brick. FESEM microstructure confirms the presence of the glassy phase in the sintered brick. It is found that with an increase in glass content, the bulk density increases, and apparent porosity decreases. The mechanical properties of the glass-ceramic composite bricks are also superior to the fly ash brick.","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"50 6","pages":"674 - 680"},"PeriodicalIF":0.8,"publicationDate":"2025-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143676283","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Study of the Structure of Composite Materials Based on PbSb2Te4 Obtained by the Czochralski Method

IF 0.8 4区材料科学

Glass Physics and Chemistry Pub Date : 2025-03-23 DOI: 10.1134/S1087659624600467

S. A. Nemov, V. D. Andreeva, A. V. Povolotskiy, A. Yu. Alyab’ev

引用次数: 0

Study of the Four-Component Salt KI–KBr–K2CO3–K2SO4 System

IF 0.8 4区材料科学

Glass Physics and Chemistry Pub Date : 2025-03-23 DOI: 10.1134/S1087659624600376

A. A. Finogenov, E. I. Frolov, I. K. Garkushin, E. Yu. Moshchenskaya

引用次数: 0