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Achieving near-isotropic strength and ductility in laser additively manufactured zinc via columnar-to-equiaxed grain transition under thermoelectric magnetic effect 热电磁效应下柱状晶向等轴晶转变激光增材制造锌的近各向同性强度和延展性
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-26 DOI: 10.1016/j.jmst.2025.09.023
Zhi Dong, Hongtao Du, Shentao Xu, Yujin Zou, Wei Xu, Zhongwei Yan, Di Wang, Changhui Song, Yongqiang Yang, Changjun Han
{"title":"Achieving near-isotropic strength and ductility in laser additively manufactured zinc via columnar-to-equiaxed grain transition under thermoelectric magnetic effect","authors":"Zhi Dong, Hongtao Du, Shentao Xu, Yujin Zou, Wei Xu, Zhongwei Yan, Di Wang, Changhui Song, Yongqiang Yang, Changjun Han","doi":"10.1016/j.jmst.2025.09.023","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.09.023","url":null,"abstract":"This work explored the modulation of grain characteristics in Zn during the laser powder bed fusion (LPBF) process by leveraging the thermoelectric magnetic effect induced by an static magnetic field (SMF) for the first time, aiming to reduce the mechanical anisotropy of the printed Zn material while retaining its excellent ductility at specified strength levels. The solidification behavior in the Zn molten pool during the LPBF process under the influence of thermoelectric magnetic effects was simulated using a physical model that integrated SMF. The results indicated that the thermal electromagnetic force induced by SMF reached up to 10<sup>6</sup> N/m<sup>3</sup>, effectively fragmenting regular Zn columnar dendrites and enhancing heterogeneous nucleation efficiency, thus promoting the columnar-to-equiaxed transition and grain refinement. Consequently, compared to samples printed without SMF assistance, the mechanical anisotropy index of yield strength and elongation in the SMF-assisted LPBF-printed Zn sample was significantly reduced from 18.63% and 16.49% to 2.46% and 2.58%, respectively, while maintaining superior strength-ductility synergy. This nearly isotropic mechanical behavior primarily resulted from well-modulated grain characteristics that served as a sustainable source of strength-ductility by coordinating grain boundary strengthening and dislocation strengthening mechanisms, as well as utilizing balanced basal &lt;<em>a</em>&gt; slip and pyramidal &lt;<em>c</em>+<em>a</em>&gt; slip deformation modes. These findings can provide a microstructure manipulation strategy to effectively mitigate the mechanical anisotropy of laser powder bed fusion additively manufactured Zn-based materials for biomedical applications.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"23 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145141520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
NbP-NbO Heterostructures with Engineered Built-In Electric Fields for Accelerated Lithium Polysulfide Conversion. NbP-NbO异质结构与工程内置电场加速锂多硫化转化。
IF 10.8 1区 材料科学
Nano Letters Pub Date : 2025-09-26 DOI: 10.1021/acs.nanolett.5c04018
Jin Guo,Tao Ren,Xinyuan Wang,Yanqiu Zhu,Jinliang Zhu
{"title":"NbP-NbO Heterostructures with Engineered Built-In Electric Fields for Accelerated Lithium Polysulfide Conversion.","authors":"Jin Guo,Tao Ren,Xinyuan Wang,Yanqiu Zhu,Jinliang Zhu","doi":"10.1021/acs.nanolett.5c04018","DOIUrl":"https://doi.org/10.1021/acs.nanolett.5c04018","url":null,"abstract":"To effectively regulate lithium polysulfides (LiPSs) and enhance their conversion kinetics, we designed a novel NbP-NbO heterostructure catalyst. Density functional theory calculations demonstrate that the NbP-NbO heterostructure generates a built-in electric field, which induces significant interfacial electron flow. This electron redistribution effectively lowers the reaction energy barrier for LiPS reduction and accelerates their conversion kinetics. Galvanostatic intermittent titration and in situ electrochemical impedance spectroscopy further elucidate the roles of activation energy and concentration gradients in LiPS conversion, while highlighting the influence of kinetic barriers and transport limitations on sulfur utilization efficiency. The NbP-NbO/C@S cathode delivers exceptional electrochemical performance, achieving a high specific capacity of 1463.6 mAh g-1 at 0.2 C, outstanding cycling stability, and superior rate capability (704.9 mAh g-1 at 5 C). Notably, a practical pouch cell incorporating this cathode exhibits a high energy density of 403 Wh kg-1, underscoring its potential for real-world Li-S battery applications.","PeriodicalId":53,"journal":{"name":"Nano Letters","volume":"63 1","pages":""},"PeriodicalIF":10.8,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145140471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Pill That Prints-An Ingestible Bioprinter for Non-Invasive Structured Bioink Deposition. 一种可打印的药丸——用于非侵入性结构生物链接沉积的可食用生物打印机。
IF 14.1 1区 材料科学
Advanced Science Pub Date : 2025-09-26 DOI: 10.1002/advs.202512411
Sanjay Manoharan, Vivek Subramanian
{"title":"A Pill That Prints-An Ingestible Bioprinter for Non-Invasive Structured Bioink Deposition.","authors":"Sanjay Manoharan, Vivek Subramanian","doi":"10.1002/advs.202512411","DOIUrl":"https://doi.org/10.1002/advs.202512411","url":null,"abstract":"<p><p>A foundational demonstration of a tetherless, ingestible bioprinter capable of controlled bioink deposition and patterning for potential applications in endoluminal tissue repair is presented. This ingestible microdevice, the first-of-its-kind, operates without tethers or onboard electronics and is guided using external imaging and magnetic actuation. By integrating near-infrared triggering and magnetic guidance, both applied from outside the body, the ability to guide the pill over target sites and deposit bioink in defined patterns, for ulcer coverage or hemorrhage sealing in ex vivo models is demonstrated. To enable this, the interplay is modeled and optimized between magnetic forces and stick-slip dynamics at the tissue interface, facilitating predictable surface-mediated navigation and patterning. In vivo studies in rabbit models showcase the technical feasibility of deployment, positioning, and controlled extrusion under fluoroscopic guidance. This work thus establishes core engineering principles for future development of non-invasive and untethered endoluminal bioprinting systems.</p>","PeriodicalId":117,"journal":{"name":"Advanced Science","volume":" ","pages":"e12411"},"PeriodicalIF":14.1,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145147094","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dislocation Introduction via Domain Engineering in Mg2Sn Single Crystal to Improve its Thermoelectric Properties (Small Methods 9/2025) 利用畴工程引入位错改善Mg2Sn单晶的热电性能(Small Methods 9/2025)
IF 9.1 2区 材料科学
Small Methods Pub Date : 2025-09-26 DOI: 10.1002/smtd.70049
Zhicheng Huang, Kei Hayashi, Wataru Saito, Hezhang Li, Jun Pei, Jinfeng Dong, Toshiaki Chiba, Xue Nan, Bo-Ping Zhang, Jing-Feng Li, Yuzuru Miyazaki
{"title":"Dislocation Introduction via Domain Engineering in Mg2Sn Single Crystal to Improve its Thermoelectric Properties (Small Methods 9/2025)","authors":"Zhicheng Huang,&nbsp;Kei Hayashi,&nbsp;Wataru Saito,&nbsp;Hezhang Li,&nbsp;Jun Pei,&nbsp;Jinfeng Dong,&nbsp;Toshiaki Chiba,&nbsp;Xue Nan,&nbsp;Bo-Ping Zhang,&nbsp;Jing-Feng Li,&nbsp;Yuzuru Miyazaki","doi":"10.1002/smtd.70049","DOIUrl":"https://doi.org/10.1002/smtd.70049","url":null,"abstract":"<p><b>Thermoelectric Materials</b></p><p>In article number 2500385, Hayashi and co-workers proposed domain engineering for developing high-performance thermoelectric materials. Mg vacancies introduced into Mg<sub>2</sub>Sn single crystals formed nanoparticle-like domains, around which dislocations were located. The boron doping varied the size and density of the domains and increased the lattice defects. A higher performance than polycrystals was achieved for n-type and p-type Mg<sub>2</sub>Sn single crystals through decoupling carrier-phonon transport.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":229,"journal":{"name":"Small Methods","volume":"9 9","pages":""},"PeriodicalIF":9.1,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/smtd.70049","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145135719","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Multipotent Precursor Approach for the Preparation of High-Molecular Weight Conjugated Polymers with Redox Active Units (Small Methods 9/2025) 制备具有氧化还原活性单元的高分子量共轭聚合物的多能前驱体方法(Small Methods 9/2025)
IF 9.1 2区 材料科学
Small Methods Pub Date : 2025-09-26 DOI: 10.1002/smtd.70047
Benedetta Bertoncini, Andrea Taddeucci, Sabrina Trano, Sofia Raviolo, Ilaria Valdrighi, Federico Maria Vivaldi, Virgilio Mattoli, Federico Bella, Marco Carlotti
{"title":"A Multipotent Precursor Approach for the Preparation of High-Molecular Weight Conjugated Polymers with Redox Active Units (Small Methods 9/2025)","authors":"Benedetta Bertoncini,&nbsp;Andrea Taddeucci,&nbsp;Sabrina Trano,&nbsp;Sofia Raviolo,&nbsp;Ilaria Valdrighi,&nbsp;Federico Maria Vivaldi,&nbsp;Virgilio Mattoli,&nbsp;Federico Bella,&nbsp;Marco Carlotti","doi":"10.1002/smtd.70047","DOIUrl":"https://doi.org/10.1002/smtd.70047","url":null,"abstract":"<p><b>Conjugated Polymers</b></p><p>In article number 2500488, Bella, Carlotti, and co-workers introduce a multipotent precursor strategy for the preparation of high molecular weight conjugated polymers. Through selective post-polymerization reactions, a single precursor yields distinct materials that were employed in organic field-effect transistors and lithium-ion battery cathodes. This unified approach enables tunable redox and electronic properties, advancing multifunctional polymer design for energy and electronic applications.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":229,"journal":{"name":"Small Methods","volume":"9 9","pages":""},"PeriodicalIF":9.1,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/smtd.70047","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145135733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nano-Interconnected 1D/2D Boron Nitride Hybrid Networks: Unlocking Superior Thermal Conductivity in Electrically Insulating Thermal Interface Nanocomposites Based on Hybrid Thermal Percolation Model (Small Methods 9/2025) 纳米互连1D/2D氮化硼杂化网络:基于杂化热渗透模型解锁电绝缘热界面纳米复合材料的优越导热性(Small Methods 9/2025)
IF 9.1 2区 材料科学
Small Methods Pub Date : 2025-09-26 DOI: 10.1002/smtd.70044
Seung Yeon Jang, Ji-un Jang, Gyun Young Yoo, Ki Hoon Kim, Seong Hun Kim, Jaewoo Kim, Seong Yun Kim
{"title":"Nano-Interconnected 1D/2D Boron Nitride Hybrid Networks: Unlocking Superior Thermal Conductivity in Electrically Insulating Thermal Interface Nanocomposites Based on Hybrid Thermal Percolation Model (Small Methods 9/2025)","authors":"Seung Yeon Jang,&nbsp;Ji-un Jang,&nbsp;Gyun Young Yoo,&nbsp;Ki Hoon Kim,&nbsp;Seong Hun Kim,&nbsp;Jaewoo Kim,&nbsp;Seong Yun Kim","doi":"10.1002/smtd.70044","DOIUrl":"https://doi.org/10.1002/smtd.70044","url":null,"abstract":"<p><b>Thermal Interface Materials</b></p><p>In article number 2500453, J. Kim, S. Y. Kim, and co-workers systematically investigated the synergistic enhancement of thermal conductivity in composites based on 1D and 2D boron nitride hybrid fillers. The fabricated composites achieved a maximum thermal conductivity of 10.93 W m<sup>−1</sup> K. Additionally, a novel hybrid thermal percolation model was proposed to identify the optimal synergistic effect for enhanced thermal management performance.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":229,"journal":{"name":"Small Methods","volume":"9 9","pages":""},"PeriodicalIF":9.1,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/smtd.70044","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145135748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polymorphism Crystal Structure Prediction with Adaptive Space Group Diversity Control. 基于自适应空间群分集控制的多态晶体结构预测。
IF 14.1 1区 材料科学
Advanced Science Pub Date : 2025-09-26 DOI: 10.1002/advs.202510792
Sadman Sadeed Omee, Lai Wei, Sourin Dey, Jianjun Hu
{"title":"Polymorphism Crystal Structure Prediction with Adaptive Space Group Diversity Control.","authors":"Sadman Sadeed Omee, Lai Wei, Sourin Dey, Jianjun Hu","doi":"10.1002/advs.202510792","DOIUrl":"https://doi.org/10.1002/advs.202510792","url":null,"abstract":"<p><p>Crystalline materials can form different structural arrangements (i.e., polymorphs) with the same chemical composition, exhibiting distinct physical properties depending on how they are synthesized or the conditions under which they operate. For example, carbon can exist as graphite (soft, conductive) or diamond (hard, insulating). Computational methods that can predict these polymorphs are vital in materials science, which help understand stability relationships, guide synthesis efforts, and discover new materials with desired properties without extensive trial-and-error experimentation. However, effective crystal structure prediction (CSP) algorithms for inorganic polymorph structures remain limited. ParetoCSP2 is proposed, a multi-objective genetic algorithm for polymorphism CSP that incorporates an adaptive space group diversity control technique and the sustainable age-fitness Pareto optimized evolutionary mechanism, preventing over-representation of any single space group in the population guided by a neural network interatomic potential. Using an improved population initialization method and performing iterative structure relaxation, ParetoCSP2 not only alleviates premature convergence but also achieves improved convergence speed. These results show that ParetoCSP2 achieves excellent performance in polymorphism prediction, including a nearly perfect space group and structural similarity accuracy for formulas with two polymorphs but with the same number of unit cell atoms. Evaluated on a benchmark dataset, it outperforms baseline algorithms by factors of 2.46-8.62 for these accuracies and improves by 44.8-87.04% across key performance metrics for regular CSP. This source code is freely available at https://github.com/usccolumbia/ParetoCSP2.</p>","PeriodicalId":117,"journal":{"name":"Advanced Science","volume":" ","pages":"e10792"},"PeriodicalIF":14.1,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145147158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Illuminating liver fibrosis: recent progress in the design and applications of highly sensitive fluorescent probes. 照亮肝纤维化:高灵敏度荧光探针的设计和应用的最新进展。
IF 10.7 2区 材料科学
Materials Horizons Pub Date : 2025-09-26 DOI: 10.1039/d5mh01447f
Yutong Lv, Zhe Ma, Yue Chong, Zhenlong Wang, Li Xue, Fu Wang
{"title":"Illuminating liver fibrosis: recent progress in the design and applications of highly sensitive fluorescent probes.","authors":"Yutong Lv, Zhe Ma, Yue Chong, Zhenlong Wang, Li Xue, Fu Wang","doi":"10.1039/d5mh01447f","DOIUrl":"https://doi.org/10.1039/d5mh01447f","url":null,"abstract":"<p><p>Liver fibrosis involves excessive, disorganized extracellular matrix deposition in the liver, critically driving progression from chronic liver disease to cirrhosis and determining patient prognosis. Although histological examination of liver tissue biopsies continues to serve as the most reliable diagnostic approach, the development of precise detection methods remains crucial for enabling timely therapeutic interventions and improving patient management. Recent advances in fluorescent probes have transformed the detection of liver fibrosis, enabling real-time, non-invasive visualization of biomarkers and microenvironmental changes. Based on its design strategy, targeted objects and functional characteristics, this review systematically classifies state-of-the-art fluorescent probes into five categories: probes directly targeting liver fibrosis markers, enzyme-activated probes, microenvironment-responsive probes, intracellular targeting probes, and multifunctional theranostic probes. Among them, near-infrared II (NIR-II, 1000-1700 nm) imaging and genetically encoded probes boost molecular precision and resolution, yet clinical application faces challenges from limited tissue penetration and poor biocompatibility. Consequently, future research in this field will concentrate on the development of NIR II probes, the discovery of biomarkers in biofluids, and the design of new therapeutic interventions. By elucidating design principles and applications, this review aims to bridge the gap between molecular innovation and clinical practice, ultimately advancing precision medicine for liver fibrosis.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":10.7,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145147248","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photoregulated Assembly-Disassembly Dynamics of Interfering with Organelle Membrane Integrity. 干扰细胞器膜完整性的光调节装配-拆卸动力学。
IF 10.8 1区 材料科学
Nano Letters Pub Date : 2025-09-26 DOI: 10.1021/acs.nanolett.5c04030
Sangpil Kim,Dohyun Kim,Youngji Jo,Sehee Son,Youjung Sim,Haewon Ok,Jaeeun Lee,Ja-Hyoung Ryu
{"title":"Photoregulated Assembly-Disassembly Dynamics of Interfering with Organelle Membrane Integrity.","authors":"Sangpil Kim,Dohyun Kim,Youngji Jo,Sehee Son,Youjung Sim,Haewon Ok,Jaeeun Lee,Ja-Hyoung Ryu","doi":"10.1021/acs.nanolett.5c04030","DOIUrl":"https://doi.org/10.1021/acs.nanolett.5c04030","url":null,"abstract":"Assembly-disassembly dynamics driven by fuel-driven out-of-equilibrium processes play a key role in biological function. Here, we present a photoregulated assembly-disassembly dynamic system based on synthetic building blocks composed of an azobenzene moiety and an organelle membrane-targeting unit. Upon localization to the organelle membrane, these photoresponsive monomers self-assemble into supramolecular fibrils that interact multivalently with the membrane. UV irradiation (365 nm) induces trans-to-cis isomerization of the azobenzene units, resulting in a morphological transition from fibrillar to amorphous assemblies with reduced membrane affinity. Subsequent exposure to visible light (450 nm) restores the fibrillar state. This reversible assembly-disassembly process enables dynamic control of the membrane binding strength, ultimately disrupting organelle membrane integrity through cyclic weakening and strengthening of supramolecular interactions. Our findings highlight the potential of light-driven, multivalent self-assembly as a strategy for modulating subcellular structures and regulating cellular fate with high spatial and temporal precision.","PeriodicalId":53,"journal":{"name":"Nano Letters","volume":"100 1","pages":""},"PeriodicalIF":10.8,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145140475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modulation of crystal nucleation and growth enables tailoring the mechanical properties of Zr55Cu30Al10Ni5 powder 晶体成核和生长的调制使Zr55Cu30Al10Ni5粉末的机械性能得以调整
IF 6.2 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2025-09-26 DOI: 10.1016/j.jallcom.2025.184046
Jintao Luo, Fengchen Chen, Chenhui Wang, Luojia Zhang, Jie Li, Yulai Gao, Bingge Zhao
{"title":"Modulation of crystal nucleation and growth enables tailoring the mechanical properties of Zr55Cu30Al10Ni5 powder","authors":"Jintao Luo, Fengchen Chen, Chenhui Wang, Luojia Zhang, Jie Li, Yulai Gao, Bingge Zhao","doi":"10.1016/j.jallcom.2025.184046","DOIUrl":"https://doi.org/10.1016/j.jallcom.2025.184046","url":null,"abstract":"Nucleation and crystal growth are essential factors influencing the crystallization kinetics, microstructure, and mechanical properties of metallic glasses. In this study, the gas-atomized Zr<sub>55</sub>Cu<sub>30</sub>Al<sub>10</sub>Ni<sub>5</sub> (at.%) metallic glass powder was heated by differential scanning calorimetry (DSC) and nanocalorimetry to investigate the crystallization behaviors at rates spanning five orders of magnitude. At a slow heating rate, CuZr<sub>2</sub> and NiZr<sub>2</sub> are identified as the primary crystallization phases. Upon rapid heating, nevertheless, crystallization predominantly produces various Cu-Zr-based intermetallic compounds, including Cu<sub>5</sub>Zr, CuZr<sub>2</sub> and Cu<sub>10</sub>Zr<sub>7</sub> while the formation of NiZr<sub>2</sub> is limited. Based on the crystallization kinetics and microstructure evolution, the nucleation and crystal growth rates between <em>T</em><sub>g</sub> and <em>T</em><sub>m</sub> were calculated using classical nucleation theory and an improved Wilson-Frenkel model. Accordingly, the critical temperature for the decoupling of diffusivity and viscosity is 730.9<!-- --> <!-- -->K. The contact angle for nucleation is estimated to be 23.5° with a maximum nucleation rate occurring at 0.72 <em>T</em><sub>m</sub>. The maximum crystal growth rate is determined to be 2.3 × 10<sup>-5<!-- --> </sup>m/s at 0.95 <em>T</em><sub>m</sub>. The roles of nucleation and crystal growth in tailoring the mechanical properties of the powder were further revealed through the single-powder compression method. Slow heating facilitates the formation of nanocrystals due to the ultrahigh nucleation rate but low growth rate, resulting in exceptionally high microhardness but limited compressive strength and toughness. At rapid heating, in contrast, the formation of Cu-Zr-based crystals leads to the reduction of hardness while compressive fracture strength peaks at 2,000<!-- --> <!-- -->K/s with increased toughness.","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"91 1","pages":""},"PeriodicalIF":6.2,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145140620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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