Electrochimica Acta最新文献

{"title":"Gold Nanoparticle-Manganese Oxide-Modified ITO Electrode for Simultaneous Electrochemical Detection of Pb2+, Cd2+, and Cu2+","authors":"Nurul Hidayah Ramli, Tan Min Yuan, Noorhashimah Mohamad Nor, Nor Dyana Zakaria, Khairunisak Abdul Razak","doi":"10.1016/j.electacta.2026.150360","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.150360","url":null,"abstract":"Heavy metal pollution in coastal waters requires rapid and sensitive monitoring methods, as conventional techniques are costly, time-consuming, and unsuitable for on-site analysis. Electrochemical sensors are advantageous as a simple and portable technique. However, unmodified electrodes have limited active surface area, slow electron-transfer kinetics, low signal stability, and limited sensitivity and selectivity. Nanoparticle modification can overcome these limitations by increasing the number of active sites and enhancing charge transfer at the electrode-electrolyte interface. In this study, manganese oxide (MnO<ce:inf loc=\"post\">2</ce:inf>) nanoparticles were used because they have a high surface area, many oxygen-containing adsorption sites, strong affinity for heavy-metal ions, low toxicity, and low cost. However, MnO<ce:inf loc=\"post\">2</ce:inf> has low electrical conductivity that limits its electrochemical performance. To overcome this limitation, gold nanoparticles (AuNPs) were used with MnO<ce:inf loc=\"post\">2</ce:inf> to enhance conductivity, promote electrochemical activity, and improve signal enhancement. In addition, Nafion was added to improve the stability of the modified electrode. A Nafion/AuNPs–MnO<ce:inf loc=\"post\">2</ce:inf>/ITO electrode was fabricated using the drop-casting method and optimized by varying the MnO<ce:inf loc=\"post\">2</ce:inf> concentration and AuNP loading. The optimized Nafion/15µl AuNPs/4 MnO<ce:inf loc=\"post\">2</ce:inf>/ITO electrode simultaneously detected Cd(II), Pb(II), and Cu(II), with sensitivities of 1.6067, 3.1411 and 1.4897 µA ppb<ce:sup loc=\"post\">-1</ce:sup> and detection limits of 1.89, 1.10, and 2.89 ppb, respectively. The optimized electrode has two linear ranges (1–5 and 10–100 ppb) and successfully detected Cd(II), Pb(II), and Cu(II) ions in seawater samples. These results demonstrated that the Nafion/15µl AuNPs/4 MnO<ce:inf loc=\"post\">2</ce:inf>/ITO electrode provides high sensitivity and shows good potential for the simultaneous detection of heavy-metal ions in complex environmental samples.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"41 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149358719","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Cobalt Nanoparticle-Encapsulated Nitrogen-Doped Carbon Nanotube Interwoven Catalyst for Acidic Hydrogen Peroxide Electrosynthesis and Integrated Oxidation Reactions","authors":"Kun Wan, Jinglei Yang, Zhaoli Yang, Yan Pei, Minghua Qiao, Hexing Li, Xiaoxin Zhang, Baoning Zong","doi":"10.1016/j.electacta.2026.150352","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.150352","url":null,"abstract":"Direct electrosynthesis of hydrogen peroxide (H<ce:inf loc=\"post\">2</ce:inf>O<ce:inf loc=\"post\">2</ce:inf>) through the two-electron oxygen reduction reaction (2e<ce:sup loc=\"post\">–</ce:sup>-ORR) in acidic media holds great promise for practical applications, but simultaneously achieving high activity, selectivity, and durability remains challenging. Herein, we report a Co@NCNT/ZC catalyst prepared by pyrolyzing ZIF-67 synthesized in the presence of graphene oxide (GO). The catalyst featured an electrochemically relevant architecture of Co nanoparticle (NP)-encapsulated nitrogen-doped carbon nanotubes (NCNTs) growing on the ZIF-67-derived carbonaceous particle (ZC) and intertwining neighboring ZC particles, forming a three-dimensional (3D) conductive network. In 0.1 M HClO<ce:inf loc=\"post\">4</ce:inf> electrolyte, Co@NCNT/ZC displayed a near theoretical onset potential of 0.670 V, maintained &gt; 90% H<ce:inf loc=\"post\">2</ce:inf>O<ce:inf loc=\"post\">2</ce:inf> selectivity (max. 95.4%) in a wide potential window of 0.20–0.60 V in the RRDE measurement. In an H-cell, the catalyst delivered an H<ce:inf loc=\"post\">2</ce:inf>O<ce:inf loc=\"post\">2</ce:inf> production rate of 21.1 mol g<ce:inf loc=\"post\">cat</ce:inf><ce:sup loc=\"post\">–1</ce:sup> h<ce:sup loc=\"post\">–1</ce:sup> with stable performance over 170 h of continuous operation. Mechanistic studies combined with density functional theory (DFT) calculations collectively support that the 3D conductive network reduces charge-transfer resistance, while the electronic coupling between the encapsulated Co NPs and NCNTs contributes to optimizing the adsorption free energy of *OOH <ce:italic>(</ce:italic>Δ<ce:italic>G</ce:italic><ce:inf loc=\"post\">*OOH</ce:inf>) to thermodynamic optimum for 2e<ce:sup loc=\"post\">–</ce:sup>-ORR, thus rendering high intrinsic activity and high H<ce:inf loc=\"post\">2</ce:inf>O<ce:inf loc=\"post\">2</ce:inf> selectivity. Furthermore, the electrogenerated H<ce:inf loc=\"post\">2</ce:inf>O<ce:inf loc=\"post\">2</ce:inf> enables in situ tandem Rhodamine B (RhB) removal and propylene oxidation to 1,2-propylene glycol (1,2-PG) with high efficiency. This study contributes to the development of effective electrocatalysts by structure optimization for practical H<ce:inf loc=\"post\">2</ce:inf>O<ce:inf loc=\"post\">2</ce:inf> electrosynthesis and integrated downstream applications.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"56 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149358754","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Corrigendum to “Enhancing electrochemical performance of FeNi(PPA) bimetallic MOF by incorporating polyaniline and sulfur for advanced supercapacitor applications” [582 (2027) 1–12/150261]","authors":"Emeka Kingsley Oparaku, Azubuike Josiah Ekpunobi, Gabriel Emeka Orizu, Solomon Ugochukwu Offiah, Assumpta Chinwe Nwanya, Fabian Ifeanyichukwu Ezema","doi":"10.1016/j.electacta.2026.150293","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.150293","url":null,"abstract":"","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"81 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149358756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ruthenium as a CMOS-Compatible Alternative to Platinum Electrodes for Electrochemical DNA Synthesis","authors":"Yujie Lu, Shuoyu Liu, Dan Wu, Yiming Dong, Xin Zhao","doi":"10.1016/j.electacta.2026.150346","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.150346","url":null,"abstract":"Recent advances in semiconductor-based DNA synthesis platforms have enabled high-density integration of electrochemical synthesis sites. In response to the issues associated with traditional platinum electrodes in electrochemical DNA synthesis—namely high cost, poor compatibility with CMOS processes, and difficulties in high-density integration [<ce:cross-refs ref>1–4</ce:cross-refs>]—this paper evaluated candidate electrode materials for electrochemical DNA synthesis, including ruthenium (Ru) and titanium nitride (TiN), with Pt as the control, and validated the feasibility of ruthenium (Ru) as a CMOS-compatible alternative electrode material [<ce:cross-refs ref>5–7</ce:cross-refs>]. Electrochemical characterization revealed that TiN exhibited limited catalytic activity in the present system, whereas Ru displays kinetic performance similar to that of Pt (approximately 250 mV·dec⁻¹). Combining single-base fluorescence experiments, Fluorescence in situ hybridization experiments on 50-nt DNA sequences (20-nt target sequence for FISH probe binding), and synthesis and sequencing experiments on 80-nt DNA sequences, this paper suggests that Ru electrodes may serve as a promising alternative to Pt electrodes for electrochemical DNA synthesis. Among the tested conditions, at a current of 1400 nA per pixel, the Ru electrode achieved a sequence accuracy of 99.6% (supported by over one million high-quality sequencing reads), comparable to the performance of Pt. Ru combines low cost with CMOS compatibility, providing an ideal electrode solution for the development of high-density, low-cost DNA synthesis chips [<ce:cross-ref ref>8</ce:cross-ref>,<ce:cross-ref ref>9</ce:cross-ref>].","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"34 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149358755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Molybdenum-doped nickel trithiocyanurate coordination polymer for alkaline hydrogen evolution and durable AEM water electrolysis","authors":"Ali Aman, Hao Sun, Sheraz Muhammad, Rahmat Ullah, Sumayya Khan, Chunting He, Zongjun Li, Momin Khan, Fuqin Zheng, Wei Chen","doi":"10.1016/j.electacta.2026.150355","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.150355","url":null,"abstract":"The transition towards a hydrogen economy demands economic, highly efficient and durable electrocatalysts capable of sustaining high current densities. Herein, a solvent mediated morphological engineering strategy is developed to construct a self-supported Mo-modulated coordination polymer based catalyst grown directly on nickel foam (Mo<ce:inf loc=\"post\">0.5</ce:inf>TCA/NF). The robust metal-ligand coordination enables the formation of a hierarchal needle like nanostructure, improving active site accessibility and facilitating interfacial charge transfer. Mo incorporation induces favorable electronic structure regulation and optimizes hydrogen adsorption free energy from −1.18 to −0.81 eV. Consequently, Mo<ce:inf loc=\"post\">0.5</ce:inf>TCA/NF catalyst exhibits good hydrogen evolution reaction (HER) performance, requiring low overpotentials of 23 and 81 mV to deliver current densities of 10 and 100 mA cm⁻² respectively, while maintaining stable operation for 80 h at 400 mA cm<ce:sup loc=\"post\">–2</ce:sup> with degradation rate of only 0.191 mV h<ce:sup loc=\"post\">–1</ce:sup>. X-ray photoelectron spectroscopy (XPS) and in-situ Raman spectroscopy provide insights into electronic redistribution and dynamic reconstruction of the catalytic interface under operating conditions. When integrated into an anion exchange membrane water electrolyzer (AEMWE), Mo<ce:inf loc=\"post\">0.5</ce:inf>TCA/NF requires only 2.1 V to achieve 1.0 A cm<ce:sup loc=\"post\">−2</ce:sup> at 60 °C and maintains stable performance for 160 h with a low degradation rate of 0.38 mV h<ce:sup loc=\"post\">–1</ce:sup>. This study establishes an integrated strategy that combines solvent regulated structural engineering with Mo-induced electronic modulation for HER at industrially relevant current densities.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"15 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149358752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Electrochemical signatures of L-Cysteine on gold nanoparticles under the combined influence of particle size and pH","authors":"Peter Slovenský, Seyedeh Marzieh Kalantarian, Zoltan Wolfgang Richter-Bisson, Daria Baskova, Yolanda Susanne Hedberg","doi":"10.1016/j.electacta.2026.150354","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.150354","url":null,"abstract":"Gold–thiol interactions play a critical role in nanomaterials, catalysis, and biomedical systems, however, how nanoparticle size effects couple with solution pH to control cysteine-mediated Au oxidation and thiol/disulfide chemistry remains insufficiently resolved. In this work, we systematically investigated the electrochemical behaviour of commercial gold nanoparticles (AuNPs) with diameters ranging from 5 to 60 nm in the presence of L-Cysteine under biologically relevant conditions. Cyclic voltammetry was performed at 37°C across a pH range of 2.0-7.4 using AuNP-modified glassy carbon electrodes, while high-resolution mass spectrometry was employed to monitor cysteine oxidation and cystine (disulfide) formation. The voltammetric response showed a strong pH dependence, evolving from a sharp anodic peak at low pH to broad and poorly defined oxidation waves at neutral pH. In contrast, nanoparticle size primarily affected the position of the anodic feature, with smaller AuNPs exhibiting oxidation at lower potentials than larger particles. Conversion of peak potentials to the reversible hydrogen electrode scale revealed a non-Nernstian pH dependence, indicating that the anodic response was not governed by a simple proton-coupled Au oxidation process. Instead, the results suggest overlapping contributions from Au oxidation and dissolution, cysteine adsorption, cysteine-to-cystine oxidation, and the formation of mixed sulfur-containing surface species. These findings provide new insight into the environment-dependent electrochemical reactivity of Au nanomaterials and highlight the importance of interfacial chemistry in biologically relevant thiol-containing systems.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"18 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149358923","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sn-doped Nb2O5 nanorods as high-performance anode materials for lithium-ion batteries","authors":"Shucun Li, Hui Wang, Jing zhai","doi":"10.1016/j.electacta.2026.150351","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.150351","url":null,"abstract":"As a typical transition metal oxide, Nb<ce:inf loc=\"post\">2</ce:inf>O<ce:inf loc=\"post\">5</ce:inf> has attracted widespread attention as an anode material for lithium-ion batteries owing to its high theoretical capacity and robust structural stability. However, its intrinsic low electronic conductivity and sluggish ion transport kinetics limit its rate capability. In this work, Sn-doped Nb<ce:inf loc=\"post\">2</ce:inf>O<ce:inf loc=\"post\">5</ce:inf> nanorods are synthesized via a solvothermal method using ammonium niobate oxalate hydrate as the niobium source, followed by the introduction of tin tetrachloride as a Sn dopant and subsequent heat treatment. The influence of Sn doping on the electrochemical performance of Nb<ce:inf loc=\"post\">2</ce:inf>O<ce:inf loc=\"post\">5</ce:inf> is systematically investigated.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"3 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149358758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Interfacial coupling between framework nitrogen sites and the I−/I3− couple in an amino-imino-triazine framework supercapacitor electrode","authors":"Preeti Rawat, Debmalya Roy, Kaushik Pal","doi":"10.1016/j.electacta.2026.150350","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.150350","url":null,"abstract":"The redox-active electrolytes are a promising way for improving the energy density of aqueous supercapacitors, provided that there is an electrode with an effective chemical interaction of its surface with the redox mediator. We introduce a nitrogen-rich amino-imino-triazine framework (AITF), fabricated by non-template-based synthesis via Schiff base condensation reaction, featuring nano-rose-like architecture, hierarchical meso-microporous structure (BET surface area 776 m<ce:sup loc=\"post\">2</ce:sup> g<ce:sup loc=\"post\">−1</ce:sup>), and extremely high nitrogen content (%). AITF electrode in the conventional 1 M H<ce:inf loc=\"post\">2</ce:inf>SO<ce:inf loc=\"post\">4</ce:inf> electrolyte operates on the principle of a pseudocapacitive nitrogen-based mechanism and delivers 452 F g<ce:sup loc=\"post\">−1</ce:sup> at 1 A g<ce:sup loc=\"post\">−1</ce:sup> in a three-electrode configuration. Upon addition of potassium iodide (0.1- 0.3 M) to the electrolyte, I<ce:sup loc=\"post\">−</ce:sup>/I<ce:inf loc=\"post\">3</ce:inf><ce:sup loc=\"post\">−</ce:sup> redox pair becomes involved in the electrochemical process through activation of the redox couple at the electrode/electrolyte interface. The optimized amount of potassium iodide (0.2 M KI) yields a capacitive performance of 843 F g<ce:sup loc=\"post\">−1</ce:sup> at 1 A g<ce:sup loc=\"post\">−1</ce:sup> in a three-electrode setup, with the overwhelming portion attributable to the redox electrolyte. The asymmetric AITF/activated carbon device at 1.2 V delivers an energy density of 33.7 Wh kg<ce:sup loc=\"post\">−1</ce:sup> and a power density of 480 W kg<ce:sup loc=\"post\">−1</ce:sup>, while retaining 90.6% of its capacitance after 10,000 cycles.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"6 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149358759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Corrigendum to “Prussian blue over stainless steel plates as a catalyst for OER reaction; interfacial kinetics using SECM” [Electrochimica Acta 578 (2026) 149883]","authors":"Kalpesh Tambe, Ashis Kumar Satpati","doi":"10.1016/j.electacta.2026.150224","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.150224","url":null,"abstract":"","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"10 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149358787","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biomimetic Liposomal Encapsulation of Formate Dehydrogenase Enables Efficient Electrochemical Formate Detection","authors":"Gizem Çelik, Esra Meşe Erdoğan, Hilal Yılmaz, Melek Özkan, Pınar Ergenekon","doi":"10.1016/j.electacta.2026.150349","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.150349","url":null,"abstract":"A biomimetic electrochemical sensing system for formate detection was developed using enzyme-loaded proteoliposomes incorporating the membrane channel protein NirC. Liposomes composed of DOPC were prepared via the thin-film hydration method and subsequently transformed into proteoliposomes by incorporating the NirC channel together with <ce:italic>Candida boidinii</ce:italic> formate dehydrogenase (<ce:italic>Cb</ce:italic>FDH) and the cofactors NAD<ce:sup loc=\"post\">+</ce:sup> or NADH during the rehydration step. The resulting proteoliposomes were immobilized onto glassy carbon electrodes using a chitosan matrix to construct the electrochemical sensing interface. By contrast electrodes modified with proteoliposomes containing NirC, FDH and NAD<ce:sup loc=\"post\">+</ce:sup> displayed a pronounced, concentration-dependent electrochemical response to formate. The presence of NirC channels significantly improved substrate accessibility by facilitating transmembrane transport across the lipid bilayer, thereby enhancing the enzymatic faradaic response. The developed proteoliposomal electrode produced stable and reproducible electrochemical signals in response to formate, emphasizing the importance of incorporating membrane transport elements into liposome-based biosensing architectures. The optimized GCE_Chit_Lip(<ce:italic>Cb</ce:italic>FDH_NAD_ NirC) electrode exhibited two distinct linear response ranges toward formate of 131 µM –1 mM and 1-8 mM; over the lower range, a limit of detection (LOD) of 131 µM and a sensitivity of 760.6 mA M<ce:sup loc=\"post\">−1</ce:sup> cm<ce:sup loc=\"post\">−2</ce:sup> were obtained. This study introduces a bioinspired method to improve enzymatic electrochemical sensing by channel-assisted substrate transport, providing a promising framework for formate detection in electrochemical and carbon conversion systems.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"258 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149358785","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}