Electrochimica Acta最新文献

{"title":"Intensifying paired hydrogen peroxide (H2O2) electrosynthesis: Influence of electrolyte composition and light irradiation","authors":"Blanca Diana García Morales ,&nbsp;Ismael F․ Mena ,&nbsp;Oscar Andrés Jaramillo-Quintero ,&nbsp;Cristina Sáez Jiménez ,&nbsp;Hugo Olvera-Vargas ,&nbsp;Manuel Andrés Rodrigo Rodrigo","doi":"10.1016/j.electacta.2025.146551","DOIUrl":"10.1016/j.electacta.2025.146551","url":null,"abstract":"<div><div>This study examines the feasibility of greener and more efficient (photo)electrosynthesis of hydrogen peroxide (H₂O₂) by coupling the anodic and cathodic processes within the same cell and evaluating bicarbonate (HCO₃^-) as an alternative electrolyte to sulfate (SO₄^2-). Results confirm the viability of paired H₂O₂ production in (photo)electrolyzers equipped with a carbon-based gas diffusion cathode (GDC) and a BiVO₄-coated FTO anode. Under constant cell potential, higher electrolyte concentrations led to increased current, enhancing H₂O₂ production in the cathodic process but not in the anodic one, suggesting the occurrence of competing anodic reactions. Coulombic and energy efficiencies decreased with electrolyte concentration but improved under light irradiation, with blue light yielding the highest efficiency. The use of HCO₃^- solutions enhanced H₂O₂ production in electrocatalysis but was slightly less efficient than SO₄²⁻ in photoelectrocatalysis. The highest energy efficiency was achieved with SO₄²⁻ under blue light at 3.5 V, reaching 1.91 and 5.14 mmol H₂O₂ Wh^-1 in the anodic and cathodic compartments, respectively, for a total of 7.05 mmol H₂O₂ Wh^-1 (production rate of 0.45 μmol min^-1 and 0.34 mmol <span>l</span>^-1 and faradaic efficiency of 132.4 %). In contrast, with HCO₃^-, the anodic and cathodic efficiencies were 0.84 and 3.79 mmol H₂O₂ Wh^-1, respectively, resulting in a global efficiency of 4.63 mmol H₂O₂ Wh^-1 (0.30 μmol min^-1). These findings highlight the potential of paired (photo)electrosynthesis for improving H₂O₂ production while considering electrolyte sustainability.</div></div>","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"533 ","pages":"Article 146551"},"PeriodicalIF":5.5,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144169028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hydrothermal Synthesis of Spinel Nickel Manganate Nanoparticles Modified Glassy Carbon Electrode: A Potential Tool for Low Level Detection of Fenamate Drug","authors":"Aravind Radha, Sea-Fue Wang","doi":"10.1016/j.electacta.2025.146578","DOIUrl":"https://doi.org/10.1016/j.electacta.2025.146578","url":null,"abstract":"The study aims to create a fast and powerful catalyst for the electrochemical detection of the non-steroidal drug mefenamic acid (MA) for quality control and clinical evaluation. The simple hydrothermal process was used to make NiMn₂O₄, which was then changed with a glassy carbon electrode and used for MA electrochemical sensing. For electrochemical reactions, the NiMn₂O₄ electrode offers efficient electron transport channels, accessible active sites, and efficient ion-transport pathways. Various spectroscopic and voltammetric techniques characterized the synthesized materials. We further analyzed the sensitivity and selectivity of the electrode using the DPV method. The NiMn₂O₄/GCE towards MA exhibits good selectivity, better stability, a low LOD (0.91 nM), a broad linear range (0.002-74.18 µM), and a good recovery percentage ± 98.26–99.24. The results of these tests with NiMn₂O₄ toward MA show that it could be used to find biological samples like urine and blood serum. Further, as a fabricated electrode, it is a potential candidate for future electrochemical sensing applications.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"148 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144165035","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Three-dimensional electro-Fenton oxidation of levofloxacin with a cerium doped-acidified red mud and biochar particle electrode","authors":"Mengwei Song, Chunhui Guo, Ziqiao Xia, Bobin Tang, Kaixin Xia, Jinzhong Zhang","doi":"10.1016/j.electacta.2025.146581","DOIUrl":"https://doi.org/10.1016/j.electacta.2025.146581","url":null,"abstract":"In this study, a cerium doped-acidified red mud and powder biochar particle electrode (ARM-PBC/Ce electrode) was fabricated with impregnation-coprecipitation-calcination method, and was employed in a three-dimensional electro-Fenton (3D/EF) system for levofloxacin (LEV) degradation. The preparation conditions of ARM-PBC/Ce electrode were optimized, and the electrode was characterized by various techniques. In contrast with RM, the ARM-PBC/Ce electrode had higher specific surface area, lower charge transfer resistance and excellent electrochemical performance, and the valence state conversions of Fe and Ce facilitated the generation of ⋅OH. Under the optimum degradation conditions (0.03 M Na₂SO₄ solution, initial pH 5, ARM-PBC/Ce dosage 0.4 g, applied voltage 6 V, and aeration rate 300 mL⋅min⁻¹), the removal efficiency of 10 mg·L⁻¹ LEV reached 95.82% in 60 min electro-Fenton oxidation, and the bacterial toxicity decreased significantly. The 3D/EF system demonstrated superior oxidation capability and energy efficiency compared to the 2D/EF system, and ⋅OH and ⋅O₂⁻ were the dominant active species in the electro-Fenton oxidation of LEV. The potential degradation pathways, mainly including decarboxylation, demethylation, piperazine ring opening and hydroxylation, were proposed based on the identification of intermediate products and active species. Moreover, the particle electrode remained remarkable stability and reusability after five cycles, suggesting its promising potential for the efficient treatment of LEV in wastewater.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"366 1","pages":"146581"},"PeriodicalIF":6.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144165094","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Facile preparation of biochar from biomass-derived lignin and cellulose for determination of 4-nitrophenol and 2-nitrophenol","authors":"Tianshuang Bao, Qi Wang, Hongxiang Li, Ying Su, Tong Guo, Jun Cao, Qiaoling Li, Weimeng Si","doi":"10.1016/j.electacta.2025.146420","DOIUrl":"https://doi.org/10.1016/j.electacta.2025.146420","url":null,"abstract":"The complex components in biomass materials exhibit distinct pyrolysis behaviors. These behaviors lead to the diverse structures of biochar prepared by direct pyrolysis. Additionally, Nitrophenols display different electrochemical redox behaviors on various carbon materials. These factors impose limitations on the applications of both the biochar in the determination of nitrophenols. In this study, lignin and cellulose were extracted from poplar biomass via a simple alkaline pulping method. The obtained crude lignin and crude cellulose were pyrolyzed separately to produce two types of carbon materials: lignin-derived and cellulose-derived carbon. Lignin-derived carbon exhibited a closely packed structure of carbon nanoparticles, while cellulose-derived carbon had an interconnected macroporous structure. Lignin-derived carbon possessed an enhanced response for the electrochemical reduction of 4-nitrophenol, while cellulose-derived carbon had a higher response for 2-nitrophenol. During the reduction of 4-nitrophenol, the hydroxyl group content was the dominating factor. Moreover, the trace-doped N-species was more crucial for 2-nitrophenol reduction. The detection limit for 4-nitrophenol on lignin-derived carbon was 0.0174 nm and detection limit for 2-nitrophenol on cellulose-derived carbon 0.0203 μM.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"8 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144165034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High-Performance Mesoporous Carbon@Dopamine Nanocomposite Sensor for Simultaneous Detection of Heavy Metal Ions in Environmental Monitoring","authors":"Raheel Akram, Javed Iqbal, S. Lokeswara Reddy, Anila Arshad, Jaroon Jakmunee","doi":"10.1016/j.electacta.2025.146579","DOIUrl":"https://doi.org/10.1016/j.electacta.2025.146579","url":null,"abstract":"Heavy metal ion (HMI) sensors are critical tools for environmental monitoring, given the severe health risks associated with HMI overdosage. In this study, a high-performance mesoporous carbon@dopamine (MC@PDA) nanocomposite was developed as an efficient material for constructing a smart sensor capable of the simultaneous electrochemical detection of Cd²⁺, Cu²⁺ and Hg²⁺ ions. To investigate the role of template material, different electrocatalysts, such as CNT@PDA, CNH@PDA, and MC@PDA were compared. While all C@PDA materials exhibited electroactivity for HMI detection, mesoporous carbon (MC) demonstrated superior electrochemical activity due to its hierarchical micro-/mesoporous nanoarchitecture, optimized pore volume, and high surface area, which support enhanced electron transport, superior adsorption, catalytic activity, and functionalization. The MC@PDA exhibited improved peak currents over a wide large linear range of 100 nM-1.4 mM for the simultaneous detection of Cd²⁺, Cu²⁺ and Hg²⁺, with limit of detections (LODs) of 63, 122, and 82 nM, respectively. For individual ion detection, the sensor achieved even lower LODs of 8.34, 4.36, 6.172 nΜ for Cd²⁺, Cu²⁺ and Hg²⁺, respectively. Density functional theory (DFT) calculations were performed to unravel the distinct interaction mechanisms and energy variations between PDA and HMI. Moreover, the sensor was deployed for real-world water analysis from an industrial mining site with multiple contaminants, effectively detecting Cd²⁺, Cu²⁺ ions. Results were validated using atomic absorption spectroscopy (AAS), confirming the method's reliability and practical applicability. The suggested technique will enable simultaneous detection of multiple analytes and uses interactive forces to efficiently distinguish analogue analytes.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"98 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144165037","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Economical Iron-nickel Bimetallic Electrocatalysis Enhanced Chlorine Evolution for Ammonia Removal in Wastewater","authors":"Zhiyong Zhang, Aixing Chen, Ming-Lai Fu, Wenjie Sun, Huachun Lan, Baoling Yuan","doi":"10.1016/j.electacta.2025.146580","DOIUrl":"https://doi.org/10.1016/j.electacta.2025.146580","url":null,"abstract":"The electrocatalytic removal of ammonia nitrogen (NH₄⁺-N) in wastewater is a promising technology for water treatment, but the high cost and limited catalytic efficiency of traditional electrodes present challenges. This study introduces a novel iron-nickel composite oxide electrode (FeNiO/GP) supported on graphite, achieving breakthrough performance in NH₄⁺-N wastewater remediation. It was exhibited dual enhancement in chlorine evolution reaction (CER) selectivity and oxygen evolution reaction (OER) suppression, as evidenced by an exceptional 0.212 V potential gap between OER (1.48 V) and CER (1.27 V). Through systematic optimization, the electrode demonstrates unparalleled removal efficiencies of 99.56% NH₄⁺-N and 92.09% TN within 40 minutes under controlled conditions, maintaining robust performance (88.68% NH₄⁺-N, 70.52% TN removal) in real industrial wastewater. Mechanistic investigations reveal a self-sustaining chlorine cycle where in situ generated active chlorine species drive ammonia oxidation. This work establishes a new paradigm for non-precious metal electrocatalysts in sustainable wastewater treatment, achieving high reaction kinetics with lower energy consumption. The FeNiO/GP electrode as an effective and low-cost solution for ammonia nitrogen removal, offering significant potential for practical wastewater treatment applications.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"25 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144165038","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hierarchical Assembly of RuO2/MoOx/CoNi-LDH Nanocomposite for Enhanced Performance in Acidic Overall Water Splitting","authors":"Amir Said, Binbin Qian, Ruiqian Zhang, Chunlei Yang, Ke Xu, Kunfeng Chen, Dongfeng Xue","doi":"10.1016/j.electacta.2025.146577","DOIUrl":"https://doi.org/10.1016/j.electacta.2025.146577","url":null,"abstract":"The development of electrocatalysts with bifunctionality in acidic media is crucial for advancing proton exchange membrane water electrolyzers to produce clean hydrogen fuel. Herein, an efficient bifunctional <strong>RuO₂/MoO_x/CoNi-LDH</strong> nanocomposite was synthesized for the first time via a coprecipitation and two-step hydrothermal method and used as an electrocatalyst for hydrogen evolution (HER) and oxygen evolution reaction (OER), thereby contributing to efficient overall water splitting (OWS). When used as an electrocatalyst in 0.5 M H₂SO₄, the <strong>RuO₂/MoO_x/CoNi-LDH</strong> requires an overpotential of 185, 221, and 262 mV for OER and 33, 65, and 101 mV for HER to reach the current density of 20, 50, and 100 mA/cm², respectively. The improved electrochemical performances of <strong>RuO₂/MoO_x/CoNi-LDH</strong> are well supported by a low charge transfer resistance, high electrochemical surface area, optimized nanocomposite structure, and the synergistic interaction among the RuO₂ NPs, MoO_x nanosheet (NSs), and CoNi-LDH. Importantly, in acidic OWS, bifunctional <strong>RuO₂/MoO_x/CoNi-LDH</strong> exhibits excellent activities and merely requires a low voltage of 1.53 V to reach the current density of 20 mA/cm², lower than most of the mixed-metal-based bifunctional electrocatalysts reported in acidic media. This study provides an efficient and cost-effective method for preparing high-performance mixed-metal nanocomposites for electrochemical water splitting in acidic environments and beyond.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"5 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144165039","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Li3InCl6 electrolyte with high voltage compatibility for Ni-rich layered oxide cathodes-based all-solid-state batteries","authors":"Chen Liu, Siwu Li, Lin Li, Qiyue Luo, Liang Ming, Ziling Jiang, Ziyu Lu, Miao Deng, Jie Yang, Shijie Cheng, Chuang Yu","doi":"10.1016/j.electacta.2025.146568","DOIUrl":"https://doi.org/10.1016/j.electacta.2025.146568","url":null,"abstract":"The sulfide electrolyte-based all-solid-state batteries with high-nickel layered oxide cathodes face significant challenges due to the narrow electrochemical window of sulfides and severe side reactions caused by direct contact with high-voltage oxide cathode materials such as LiNi_0.9Mn_0.05Co_0.05O₂ (NCM90). Here, we successfully synthesized Li₃InCl₆ (LIC) halide electrolytes through ball-milling followed by annealing method, achieving the ionic conductivity of 2.0 mS cm⁻¹ at room-temperature. The interface between this electrolyte and NCM90 cathode material without any interface modification is stable. By introducing the LIC electrolyte layer, the NCM90/LIC+Cl1.5/Li-In battery exhibits significantly improved electrochemical performance at different temperatures, particularly in terms of initial discharge capacity. Notably, the battery demonstrates outstanding discharge capacity and cycling stability at low temperatures. Experimental investigations reveal that the introduction of the LIC electrolyte with high oxidation potential facilitates the H2-H3 phase transition in NCM90 during high-voltage operation, which is critical for enhancing the discharge capacity. This work provides fundamental insights into interfacial engineering strategies for high-voltage sulfide-based all-solid-state battery systems.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"134 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144153883","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Electrochemical impedance of nitrogen-doped carbon with tunable mesoporous structure","authors":"A.V. Syugaev, K.A. Yazovskikh, A.N. Maratkanova","doi":"10.1016/j.electacta.2025.146570","DOIUrl":"https://doi.org/10.1016/j.electacta.2025.146570","url":null,"abstract":"Mesoporous nitrogen-doped carbon is a promising material in energy storage and conversion technologies, including efficient electrocatalyst supports. One of the effective techniques for producing mesoporous N-doped carbon is the sacrificial support method that provides a mesoporous structure with a narrow pore size distribution and easy control of the specific surface area. The method involves three stages: (i) mixing nitrogen-rich organic compounds used as a precursor and colloidal silica as a sacrificial agent; (ii) pyrolysis of the prepared mixture; (iii) chemical removal of sacrificial silica. In this work, we present, for the first time, a detailed electrochemical impedance spectroscopy (EIS) study of the mesoporous N-doped carbon obtained from methyl (2-benzimidazole) carbamate mixed with colloidal silica (10-40 wt.%). The frequency response, real and imaginary parts of the complex capacitance, as well as the Mott-Schottky plots measured at different <em>a.c.</em> frequencies have been analyzed. With 20-40 wt.% SiO₂ added to the precursor, the mesoporous N-doped carbon samples have been shown to behave in the electrolyte as an almost ideal capacitor due to the high homogeneity of interfaces in open, easy-to-access mesopores with a narrow pore size range. The frequency response is well described by a short equivalent circuit, with distinguishing between contributions made by surfaces of pores formed under removal of SiO₂ and those formed under pyrolysis of the precursor, which are charged consecutively. It has been shown that the parameters calculated from the Mott-Schottky analysis (flat band potential, linear dependence coefficient) are almost independent of the <em>a.c.</em> frequency, which also indicates high homogeneity of the carbon material in mesoporous matrix obtained by the sacrificial support method.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"50 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144153885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhancing Li-storage ability of FeC2O4 anode enabled by oxygen-vacancy-enriched amorphous carbon microspheres compositing via hydrogen bonding interactions","authors":"Keqi Chen, Zengmou Li, Keyu Zhang, Rui Yan, Binbin Li, Yaochun Yao, Shaoze Zhang, Bin Yang","doi":"10.1016/j.electacta.2025.146567","DOIUrl":"https://doi.org/10.1016/j.electacta.2025.146567","url":null,"abstract":"Iron oxalate (α-FeC₂O₄), with a stable Li⁺ diffusion pathway, exhibits excellent cycling stability but is limited in commercial applications due to its low electronic conductivity. To overcome this issure, we introduced an organic β-cyclodextrin (β-CD) compound with partial oxygen functional groups after thermal decomposition, to prepare an amorphous carbon microspheres (AMCs) composite. Considering the stable sustaining force supported by crystal water between FeC₂O₄·2H₂O interlayer, a unique composite technology with α-FeC₂O₄ and AMCs through the interactions of hydrogen bonds (FCO/AMCs) was proposed. By adjusting the solvent ratio, FCO/AMCs 1:3 with high concentration of oxygen vacancies and conductive network established by AMCs, exhibits excellent discharge specific capacity of 1183.78 mAh g^-1 at current density of 1 A g^-1 after 1000 cycles and stable cycling performance with the capacity retention rate of 72.8% even over 750 cycles at 5 A g^-1. Based on the catalytic effect of oxygen vacancies and faster average Li⁺ diffusion rate, FCO/AMCs 1:3 electrode also shows higher exchange current density (<em>j</em>₀ = 2.35 × 10^-3 A cm^-2) and apparent electron transfer rate constant (<em>k</em>_app = 1.02 cm s^-1), leading higher reversibility. Additionally, an in-depth analysis of kinetic parameters Li-ion tendentious behavior differences in transformation reactions, reveals that more oxygen vacancies can promote the ionization of Fe⁰, releasing more spin-polarized electrons to form spin-polarized capacitance. This research provides a novel strategy on carbon compositing and offers more comprehensive understanding of the kinetic processes involved in the oxalate-based anode material.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"60 1","pages":"146567"},"PeriodicalIF":6.6,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144165095","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}