{"title":"Improving the corrosion resistance of Ti-Zr-Nb alloy in hydrochloric acid environment via varying Zr content","authors":"Jing Wang, Pengfei Chui, Yizhe He, Siyu Wang, Taotao Ai, Wenhu Li, Ran Jing, Jianghua Li, Zixiang Gao","doi":"10.1016/j.electacta.2025.147488","DOIUrl":null,"url":null,"abstract":"In this work, the aim is to develop a corrosion resistant Ti alloy for acidic environments by systematically investigating the influence of Zr content on the microstructure evolution and corrosion behavior of Ti-Zr-Nb alloy. The results indicate that the addition of Zr significantly enhances the passivation ability and corrosion stability of the alloy in hydrochloric acid environments. The Ti<sub>45</sub>Zr<sub>45</sub>Nb<sub>10</sub> alloy exhibits superior performance with a corrosion potential of -153.07 mV, corrosion current density of 0.11 μA·cm<sup>-2</sup> and corrosion rate of only 0.003 mm·year<sup>-1</sup>. Interestingly, under identical corrosion conditions, different specimens displayed distinct interference color variations. These findings offer valuable insights for the design of Ti alloys with improved corrosion resistance, achieved through the optimization of their composition.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"7 1","pages":""},"PeriodicalIF":5.6000,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Electrochimica Acta","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1016/j.electacta.2025.147488","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0
Abstract
In this work, the aim is to develop a corrosion resistant Ti alloy for acidic environments by systematically investigating the influence of Zr content on the microstructure evolution and corrosion behavior of Ti-Zr-Nb alloy. The results indicate that the addition of Zr significantly enhances the passivation ability and corrosion stability of the alloy in hydrochloric acid environments. The Ti45Zr45Nb10 alloy exhibits superior performance with a corrosion potential of -153.07 mV, corrosion current density of 0.11 μA·cm-2 and corrosion rate of only 0.003 mm·year-1. Interestingly, under identical corrosion conditions, different specimens displayed distinct interference color variations. These findings offer valuable insights for the design of Ti alloys with improved corrosion resistance, achieved through the optimization of their composition.
期刊介绍:
Electrochimica Acta is an international journal. It is intended for the publication of both original work and reviews in the field of electrochemistry. Electrochemistry should be interpreted to mean any of the research fields covered by the Divisions of the International Society of Electrochemistry listed below, as well as emerging scientific domains covered by ISE New Topics Committee.