Advanced Functional Materials最新文献

Manipulating Anisotropy of Second Harmonic Generation in NbOI2 via Precise Strain Engineering 利用精密应变工程控制NbOI2中二次谐波产生的各向异性

IF 19 1区材料科学

Advanced Functional Materials Pub Date : 2025-09-10 DOI: 10.1002/adfm.202516389

Mengqi Wu, Minghao An, Zhefeng Lou, Lixiong Lin, Zhiyu Zeng, Jialu Wang, Xiaorui Zheng

引用次数: 0

Jahn-Teller Effect: Impact of Distortion on Oxygen Electrocatalysis 姜-泰勒效应：变形对氧电催化的影响

IF 19 1区材料科学

Advanced Functional Materials Pub Date : 2025-09-10 DOI: 10.1002/adfm.202516674

Ashish Gaur, Jatin Sharma, Gagandeep Kaur, Sungwook Mhin, HyukSu Han

引用次数: 0

Enhanced Orbital Torque Efficiency and Magnetization Switching Through M (M = MgO, Gd, and Pt) Doping Ti Orbital Hall Channel for Efficient Orbitronic Devices 通过M （M = MgO， Gd和Pt）掺杂Ti轨道霍尔通道提高轨道转矩效率和磁化开关

IF 19 1区材料科学

Advanced Functional Materials Pub Date : 2025-09-10 DOI: 10.1002/adfm.202505410

Yuhe Yang, Yifan Yang, Pengfei Liu, Delin Zhang, Ping Wang, Cheng Chen, Jinyu Duan, Peng Lu, Heshuang Wei, Wei Jiang, Wentao Hou, Jing Kong, Shuai Hu, Lishu Zhang, Liang Liu, Yue Li, Wenhong Wang, Yong Jiang

引用次数: 0

Oxygen Vacancy-Mediated Oxide Pathway Mechanism in Proton-Exchange Membrane Water Electrolysis 质子交换膜电解中氧空位介导的氧化途径机制

IF 19 1区材料科学

Advanced Functional Materials Pub Date : 2025-09-10 DOI: 10.1002/adfm.202516646

Li Wang, Jieshu Zhou, Yongming Zhou, Kangning Liu, Le Ke, Huamin Li, Shijia Liu, Xi Wang, Weijun Zhu, Yong Li, Kaili Yao, Shengyun Huang, Yongchang Liu, Hongyan Liang

引用次数: 0

Photomultiplication‐Type Organic Photodetectors: Mechanisms, Integration Toward Next‐Generation Sensing Platforms 光电倍增型有机光电探测器：机制，集成到下一代传感平台

IF 19 1区材料科学

Advanced Functional Materials Pub Date : 2025-09-08 DOI: 10.1002/adfm.202518958

Yazhong Wang, Shuaiqi Li, Yijun Huang, Lu Hao, Zhaohong Tan, Johannes Benduhn, Fei Huang

{"title":"Photomultiplication‐Type Organic Photodetectors: Mechanisms, Integration Toward Next‐Generation Sensing Platforms","authors":"Yazhong Wang, Shuaiqi Li, Yijun Huang, Lu Hao, Zhaohong Tan, Johannes Benduhn, Fei Huang","doi":"10.1002/adfm.202518958","DOIUrl":"https://doi.org/10.1002/adfm.202518958","url":null,"abstract":"Photomultiplication‐type organic photodetectors (PM‐OPDs) have garnered considerable attention for their ability to provide high sensitivity and tunable spectral response, positioning them as promising candidates for next‐generation optoelectronic applications. These detectors leverage internal gain mechanisms, enabling external quantum efficiencies (EQE) surpassing the traditional limit of 100%. This review systematically explores the operational principles of PM‐OPDs, focusing on charge carrier dynamics, with an emphasis on trapping mechanisms, and highlights the latest advancements in materials and device architectures. Key areas of exploration include bulk heterojunction traps, interface‐induced carrier trapping, and the role of carrier‐blocking layers in enhancing device performance. Functionalized PM‐OPDs, including narrowband, dual‐band, and dual‐mode, are discussed, emphasizing their innovative designs for spectral selectivity and operational versatility. Moreover, the application potential of PM‐OPDs is explored across various domains, including bio‐sensing, low‐light imaging, optical communication, and miniaturized spectroscopy. Despite their promise, challenges related to noise performance, response speed, operating voltage, and long‐term stability are remaining barriers. The outlook suggests continued advancements in material engineering, device optimization, and integration with flexible platforms. This review serves as a comprehensive guide to the current state of PM‐OPDs and identifies future research directions to address the existing limitations and unlock new opportunities for their application scenarios.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"9 16 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145017409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synergistic Photothermal‐Photocatalytic Accordion‐Like Mo2AlB2 MBene Membrane for High‐Efficiency Solar‐Powered Water Remediation 协同光热-光催化手风琴状Mo2AlB2 MBene膜用于高效太阳能水修复

IF 19 1区材料科学

Advanced Functional Materials Pub Date : 2025-09-08 DOI: 10.1002/adfm.202518856

Ruiqi Zhao, Xushuai Chen, Xi Chen, Panpan Zhang, Chunjia Luo, Min Chao, Luke Yan

{"title":"Synergistic Photothermal‐Photocatalytic Accordion‐Like Mo2AlB2 MBene Membrane for High‐Efficiency Solar‐Powered Water Remediation","authors":"Ruiqi Zhao, Xushuai Chen, Xi Chen, Panpan Zhang, Chunjia Luo, Min Chao, Luke Yan","doi":"10.1002/adfm.202518856","DOIUrl":"https://doi.org/10.1002/adfm.202518856","url":null,"abstract":"Addressing the global freshwater crisis demands advanced solutions where solar‐driven interfacial evaporation (SDIE) shows promise, yet integrated photothermal‐photocatalytic synergy within a single platform remains fundamentally challenging. An accordion‐like Mo2AlB2 MBene is pioneered and engineered into a crosslinked MBene/Polyvinylachohol (PVA)/meso‐tetra (4‐carboxyphenyl) porphyrin (TCPP) composite membrane (MPTM) that synergistically unifies solar harvesting and catalytic degradation. This architecture leverages accordion‐like MBene nanosheets and interfacial porphyrin coordination to establish a dynamic hydrophilic network with exceptional broadband absorption (93.3% average, 200–2500 nm). Through Schottky junction formation and charge redistribution, the system achieves unprecedented solar evaporation rates (2.24 kg m−2 h−1 under 1 sun) while concurrently generating reactive oxygen species (•OH/•O2−) that degrade 98.7% organic pollutants (10 ppm rhodamine B) in 2 h. The MPTM sustains > 85% evaporation efficiency during long‐term stability operation (Bohai seawater, 200 h) with < 4% efficiency decay, establishing a new paradigm for solar‐powered water purification.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"34 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145017333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Dual Regulation of Bulk Heterostructure and Engineered Cathode‐Electrolyte Interphase in Vanadium Cathodes for Durable Zinc Storage 钒阴极中体积异质结构和工程阴极-电解质界面的双重调节用于持久储锌

IF 19 1区材料科学

Advanced Functional Materials Pub Date : 2025-09-08 DOI: 10.1002/adfm.202518162

Dapeng Wang, Chang Wen, Tianyu Liu, Yuting Wu, Yibing Wei, Jing Tu, Guangyue Zhu, Zijian Zhou, Zhengkai Tu

{"title":"Dual Regulation of Bulk Heterostructure and Engineered Cathode‐Electrolyte Interphase in Vanadium Cathodes for Durable Zinc Storage","authors":"Dapeng Wang, Chang Wen, Tianyu Liu, Yuting Wu, Yibing Wei, Jing Tu, Guangyue Zhu, Zijian Zhou, Zhengkai Tu","doi":"10.1002/adfm.202518162","DOIUrl":"https://doi.org/10.1002/adfm.202518162","url":null,"abstract":"Vanadium‐based cathodes for aqueous zinc‐ion batteries (AZIBs) face critical challenges in practical capacity and low‐current‐density cycling stability. Herein, a synergistic strategy is introduced that overcomes these limitations through the co‐engineering of an activatable bulk precursor and a dynamic in situ‐formed interface. A porous, V3+‐rich 0.3CaV2O4‐0.7V2O3 heterostructure (CaVO‐4) specifically designed to undergo a profound in situ electrochemical activation into highly active phases is first constructed. Concurrently, by leveraging supplemental SO42− in the electrolyte, a stable CaSO4·2H2O cathode‐electrolyte interphase (CEI) layer is formed in situ via reaction with Ca2+ released during cycling. By serving a dual role, the CEI ensures structural durability and simultaneously enables the intrinsic kinetics of the bulk. This “bulk‐to‐interface” synergy manifests in electrochemical performance, including 89.3% capacity retention over 300 cycles at 0.5 A g−1, an extraordinary rate capability of 424.4 mAh g−1 at 20 A g−1, and a high specific capacity of 479.2 mAh g−1 at 0.2 A g−1. Advanced characterizations, including in situ XRD and ex situ XPS/XAFS, combined with DFT calculations, unravel the synergistic mechanisms underpinning the enhanced Zn2+ storage. This work pioneers a paradigm that unites rational bulk activation with interfacial self‐optimization, providing a strategy for durable, high‐performance cathodes in advanced energy storage.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"24 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145017285","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Accelerated 3D Percolation Network for Ultra‐High Critical Current Density of Composite Solid‐State Electrolyte 复合固态电解质超高临界电流密度的加速3D渗透网络

IF 19 1区材料科学

Advanced Functional Materials Pub Date : 2025-09-08 DOI: 10.1002/adfm.202512441

Pengcheng Wang, Jin Tan, Zhenfang Liu, Cheng Wang, Chenguang Bao, Xiaohong Xia, Baohua Li, Qi Liu

{"title":"Accelerated 3D Percolation Network for Ultra‐High Critical Current Density of Composite Solid‐State Electrolyte","authors":"Pengcheng Wang, Jin Tan, Zhenfang Liu, Cheng Wang, Chenguang Bao, Xiaohong Xia, Baohua Li, Qi Liu","doi":"10.1002/adfm.202512441","DOIUrl":"https://doi.org/10.1002/adfm.202512441","url":null,"abstract":"Solid‐state batteries (SSBs) have attracted widespread attention due to their high safety and energy density. However, the sluggish ion transport and interfacial instability of solid‐state electrolytes has emerged as fundamental barriers in practical applications, resulting in the unsatisfied critical current density (CCD< 2 mA cm−2). Herein, a high‐flux 3D percolating composite polymer electrolyte (P‐CPE) is proposed, fabricated through in situ polymerization of a localized high‐concentration gel polymer electrolyte (LHCE‐GPE) integrating within a free‐standing porous Li1.3Al0.3Ti1.7(PO4)3 (LATP) skeleton. Such P‐CPE electrolyte enables the fast Li+ flux along the continuous LATP and LATP/GPE interface to achieve a fantastic conductivity of 1.36 × 10−3 S cm−1 and LiF‐rich solid electrolyte interphase (SEI) chemistry for robust Li|P‐CPE interfacial stability. Consequently, the as‐assembled Li||Li symmetrical cells demonstrate a recorded CCD exceeding 4.5 mA cm−2 and durable long‐term stability over 3000 h at 0.2 mA cm−2 and as well as stable rate‐cycling even under a larger current density over 3 mA cm−2, highly surpassing the controlled one (0.5 mA cm−2). This work thereby provides a highly promising strategy to high‐flux composite electrolytes designing to boost practical dendrite‐free SSBs.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"35 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145017330","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The Rise of Hydrogel‐Based Moist‐Induced Electric Generators: Comprehensive Review and Future Directions 基于水凝胶的湿致发电机的兴起：综合回顾和未来方向

IF 19 1区材料科学

Advanced Functional Materials Pub Date : 2025-09-08 DOI: 10.1002/adfm.202514780

Kunlin Qin, Xian Wen, Zhaoyang Sun, Qun Zhou, Liming Wang, Dongxiao Ji, Xiaohong Qin

{"title":"The Rise of Hydrogel‐Based Moist‐Induced Electric Generators: Comprehensive Review and Future Directions","authors":"Kunlin Qin, Xian Wen, Zhaoyang Sun, Qun Zhou, Liming Wang, Dongxiao Ji, Xiaohong Qin","doi":"10.1002/adfm.202514780","DOIUrl":"https://doi.org/10.1002/adfm.202514780","url":null,"abstract":"Moisture‐induced electricity generation as an emerging technology can harvest clean and renewable energy from ubiquitous atmospheric moisture, offering promising solutions to alleviate the global energy crisis. Among the various functional materials explored, hydrogels have emerged as highly promising candidate for constructing high‐performance hydrogel‐based moist‐induced electric generators (HMEGs), due to their superior water absorption, outstanding mechanical flexibility, and adjustable physicochemical properties. However, a comprehensive understanding of the underlying material design principles, performance optimization strategies, and practical applications remains lacking. In this review, the fundamental working mechanisms and relevant development of HMEGs are first briefed, followed by current system classifications based on composition and structural characteristics. Next, efficient strategies to improve energy conversion efficiency and output power of HMEGs through rational material engineering, electrode design, and synergistic energy harvesting approaches are summarized. Moreover, representative applications of advanced HMEGs, including self‐powered electronics, sensors, and information displays are presented. Finally, the existing challenges and the perspective of HMEGs are proposed for potential new developments of this emerging technology.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"37 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145017329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

NIR‐Inducible Pyroelectric Nanocomposite Membrane Promotes Macrophage Reprogramming for Superior Bone Regeneration 近红外诱导热释电纳米复合膜促进巨噬细胞重编程，促进骨再生

IF 19 1区材料科学

Advanced Functional Materials Pub Date : 2025-09-08 DOI: 10.1002/adfm.202502329

Yusi Guo, Yijun Wang, Yaru Guo, Xiaohan Dai, Minzheng Yang, Dingxin Wang, Ruining Jiang, Youde Liang, Qun Cui, Xiaona Zheng, Jia Song, Yanhui Lu, Yingying Zhou, Boon Chin Heng, Xuehui Zhang

{"title":"NIR‐Inducible Pyroelectric Nanocomposite Membrane Promotes Macrophage Reprogramming for Superior Bone Regeneration","authors":"Yusi Guo, Yijun Wang, Yaru Guo, Xiaohan Dai, Minzheng Yang, Dingxin Wang, Ruining Jiang, Youde Liang, Qun Cui, Xiaona Zheng, Jia Song, Yanhui Lu, Yingying Zhou, Boon Chin Heng, Xuehui Zhang","doi":"10.1002/adfm.202502329","DOIUrl":"https://doi.org/10.1002/adfm.202502329","url":null,"abstract":"Electroactive materials have demonstrated positive efficacy in facilitating bone repair, but often fail to dynamically adapt to complex and variable immune responses within the bone defect microenvironment, leading to unsatisfactory repair outcomes. Here, a dynamic and non‐invasive osteo‐immunomodulatory strategy based on electrothermal synergistic effects is developed. By utilizing the photothermal absorption property of polydopamine, PDA@BTO/P(VDF‐TrFE) nanocomposite membranes can be heated by near‐infrared (NIR) irradiation and maintained at 41 °C. Simultaneously, the temperature increase also releases polarized charges due to pyroelectric effects on the nanocomposite membrane. These induce stage‐specific M1 or M2 polarization during the early phases of bone regeneration on days 2 and 7, respectively, thereby enhancing new bone formation in a rat calvarial defect model via the HSP70/AKT‐NF‐κB signaling pathway. Hence, the effective synergy of the photothermal and pyroelectric effects through NIR irradiation of PDA@BTO/P(VDF‐TrFE) nanocomposite membranes is able to exert a positive immunomodulatory effect on macrophages for superior bone repair. This remote, non‐invasive, long‐acting, and controllable strategy represents a novel clinical approach for bone immunomodulation and regeneration.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"69 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145017332","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0