Advanced Functional Materials最新文献

{"title":"Morphology and Function Dual-Adjustable Biomimetic 4D-Printed Scaffold for the Regenerative Restoration of Complex Bone Defects","authors":"Xiaodong Guo, Jundan Yi, Zhuqing Wan, Xin Wang, Zhiruo Yuan, Waisze Cheung, Xiaoqiang Bai, Yang Fu, Mo Zhai, Longwei Lv, Yongsheng Zhou","doi":"10.1002/adfm.202509961","DOIUrl":"https://doi.org/10.1002/adfm.202509961","url":null,"abstract":"","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"3 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145056895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Universal, High-Fidelity and Efficient Approach for Nanostructure Transfer and Exfoliation via a Polymeric Carrier","authors":"Xiangzhe Zhang, Xingheng Yan, Tongcheng Yu, Bowen Lv, Yuehua Wei, Gang Peng, Wei Luo, Zhengwei Zhang, Junhao Cai, Yaping Yang, Shiqiao Qin","doi":"10.1002/adfm.202514101","DOIUrl":"https://doi.org/10.1002/adfm.202514101","url":null,"abstract":"","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"1 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145056896","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Twist, Recover, Repeat: Helical Tensegrity Metamaterials with Compression-Torsion Coupling, Negative Dissipation, and Programmable Energy Response","authors":"Jianwei Sun, Haoran Zhang, Meiling Zhang, Guangsheng Song, Yuyang Wei, Jinkui Chu, Luquan Ren","doi":"10.1002/adfm.202516110","DOIUrl":"https://doi.org/10.1002/adfm.202516110","url":null,"abstract":"","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"28 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145056903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nanoscale Color Center Sensing of Adsorbed Water in Contact With Oil","authors":"Kang Xu, Kapila Elkaduwe, Rohma Khan, Sang-Jun Lee, Dennis Nordlund, Gustavo E. López, Abraham Wolcott, Daniela Pagliero, Nicolas Giovambattista, Carlos A. Meriles","doi":"10.1002/adfm.202517457","DOIUrl":"https://doi.org/10.1002/adfm.202517457","url":null,"abstract":"","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"36 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145056892","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Reply to “Unsubstantiated Anomalous Electron Doping in CdS via Cu Substitution for Cd”","authors":"Anming Mo, Binxin Yang, Xinzhou Lu, Yanjun Duan, Xiaoyang Liang, Zheng Zhang, Yingnan Guo, Zhiqiang Li","doi":"10.1002/adfm.202514642","DOIUrl":"https://doi.org/10.1002/adfm.202514642","url":null,"abstract":"This is a response to a comment, “Unsubstantiated Anomalous Electron Doping in CdS via Cu Substitution for Cd”. This reply responds to concerns regarding electron doping in copper‐doped cadmium sulfur (CdS: Cu) thin films. Here, both experimental and theoretical calculation results confirming the doping effect are presented: 1) Hall effect measurements conducted across other independent laboratories consistently demonstrate carrier concentrations of ≈10<jats:sup>20</jats:sup> cm<jats:sup>−3</jats:sup> in Cu‐doped CdS films; 2) theoretical calculations demonstrate a significant enhancement in carrier concentration through Cu doping; 3) inductively coupled plasma mass spectrometry (ICP‐MS) analysis exhibits Cu/Cd mole ratios of 2.63–7.02% in samples (Cu‐50 to Cu‐150). The results demonstrate the doping effect and highlight the necessity for advanced structural characterization and multi‐scale modeling to address composition and structure challenges of solution‐processed CdS films in future studies.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"73 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145035763","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Tailoring Redox Active Sites with Dual‐Interfacial Electric Fields for Concurrent Photocatalytic Biomass Valorization and H2 Production","authors":"Shiqing Li, Sugang Meng, Huijun Zhang, Alain R. Puente‐Santiago, Zhongliao Wang, Shifu Chen, Mario J. Muñoz‐Batista, Yu‐Ming Zheng, Bo Weng","doi":"10.1002/adfm.202513682","DOIUrl":"https://doi.org/10.1002/adfm.202513682","url":null,"abstract":"Light‐driven photocatalytic conversion of biomass‐derived substrates into value‐added chemicals, coupled with hydrogen (H<jats:sub>2</jats:sub>) evolution, offers a promising route for solar energy utilization and sustainable chemical production. However, achieving high efficiency and selectivity in such dual‐functional systems remains a challenge. Herein, the rational construction of a hierarchical Au/Zn<jats:sub>3</jats:sub>In<jats:sub>2</jats:sub>S<jats:sub>6</jats:sub>/Co<jats:sub>3</jats:sub>O<jats:sub>4</jats:sub> (Au/ZIS/Co<jats:sub>3</jats:sub>O<jats:sub>4</jats:sub>) photocatalyst is reported for selective dehydrogenation of 5‐hydroxymethylfurfural (HMF) to 2,5‐diformylfuran (DFF), coupled with H<jats:sub>2</jats:sub> generation. The unique dual‐interfacial electric fields at the Au/ZIS and ZIS/Co<jats:sub>3</jats:sub>O<jats:sub>4</jats:sub> interfaces enable directional and spatially separated migration of photogenerated electrons and holes to Au and Co<jats:sub>3</jats:sub>O<jats:sub>4</jats:sub>, respectively. As a result, Au/ZIS/Co<jats:sub>3</jats:sub>O<jats:sub>4</jats:sub> achieves a remarkable H<jats:sub>2</jats:sub> evolution rate of 2012.4 µmol g<jats:sup>−1</jats:sup> h<jats:sup>−1</jats:sup>, with 67.2% of DFF yield and excellent recyclability, which is 7.7 times higher than blank Zn<jats:sub>3</jats:sub>In<jats:sub>2</jats:sub>S<jats:sub>6</jats:sub> (260.4 µmol g<jats:sup>−1</jats:sup> h<jats:sup>−1</jats:sup>). This H<jats:sub>2</jats:sub> yield rate is the highest among reported photocatalysts for concurrent HMF valorization and H<jats:sub>2</jats:sub> production. Furthermore, the intrinsic quantum efficiency of the system is quantitatively evaluated for the first time by solving the radiative transfer equation in a tubular photoreactor. This work demonstrates a generalizable strategy for engineering redox‐site‐separated photocatalysts for biomass valorization and solar hydrogen production, offering valuable insights into the design principles of next‐generation photocatalytic systems for sustainable energy.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"9 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145035779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Precision Cuproptosis Activation via HER2‐Targeted Bimetallic MOF Nanoreactors Breaks Metabolic Adaptation in Aggressive Breast Cancers","authors":"Mingjiang Liu, Hongkun Miao, Tong Ye, Jingchao Gao, Lian Tan, Yi Tian, Zhiguang Fu, Li Wen, Maohui Yan, Weijie Gu, Guoli Gu, Yingjie Wang, Yu Wang","doi":"10.1002/adfm.202512905","DOIUrl":"https://doi.org/10.1002/adfm.202512905","url":null,"abstract":"Tumor heterogeneity and the single‐pathway inhibition mechanisms of trastuzumab represent major contributors to treatment failure in human epidermal growth factor receptor 2‐positive (HER2+) breast cancer. Cuproptosis, a promising copper‐dependent cell death mechanism, remains clinically constrained by its inherent reliance on copper bioavailability and tumor metabolic heterogeneity. Building upon these insights, this work developed an Elesclomol (ES)‐loaded delivery system employing copper‐based metal–organic frameworks (Cu MOFs) as carriers. This innovation effectively addresses rapid drug metabolism while enabling tumor microenvironment‐responsive controlled release. To enhance targeting capability and biocompatibility, the MOF is further coated with trastuzumab for HER2+ tumor‐specific delivery. This targeted biomimetic delivery system exhibits several critical features: 1) Active targeting of HER2‐overexpressing breast cancer cells; 2) Establishment of self‐amplifying copper accumulation through ES‐mediated efflux‐rebinding dynamics, decoupling therapeutic efficacy from endogenous copper levels; 3) Glutathione‐mediated Cu<jats:sup>2+</jats:sup>→Cu<jats:sup>+</jats:sup> conversion driving Fenton reactions that generate hydroxyl radicals to disrupt redox homeostasis; 4) Cu<jats:sup>+</jats:sup> binding to lipoylated tricarboxylic acid (TCA) cycle proteins, inducing mitochondrial proteotoxicity via iron‐sulfur cluster destabilization. In HER2+ breast cancer models, Zr‒Cu MOF@ES@aH (ZCEH) demonstrated 67% suppression of primary tumor growth with concurrent inhibition of lung metastasis. Collectively, this study enhances therapeutic drug sensitivity through material‐mediated cuproptosis, providing a strategic blueprint for advancing next‐generation cancer nanomedicine.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"27 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145035760","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Output Performance Optimization of NbOCl2‐Based 2D Piezoelectric Energy Harvester Via Synergy of Polarization Orientation and Built‐In Field for Strain Array Sensing","authors":"Song Zhao, Puen Zhou, Haixiang Sun, Zifa Wang, Zhongkun Wang, Yaju Zhang, Jinyang Liu, Wenbo Peng, Yuanzheng Zhang, Haiwu Zheng","doi":"10.1002/adfm.202515475","DOIUrl":"https://doi.org/10.1002/adfm.202515475","url":null,"abstract":"2D piezoelectric devices have a bright future in wearable devices due to their conformal monitoring. However, weak performance and low information density restrict the functionality of these devices. Here, the output performance of the 2D piezoelectric energy harvesters (PEHs) is optimized through the synergistic effect of the piezoelectric polarization field and the built‐in field. 2D PEHs with a gold‐indium electrode structure have built‐in electric fields oriented in the same direction as the piezoelectric field, which increases the total polarization field to optimize the output performance and stability. The peak‐to‐peak open‐circuit voltage is up to 164.7 mV, which is 8.95 times that of the symmetric gold electrodes. The novel integrated arrays fabricated based on 2D PEHs exhibit superior overall performance compared to previously reported piezoelectric sensors, enabling the reconstruction of the surface weak strain field, benefiting from the good linear relationship between output voltage and strain. Combined with deep learning techniques, the 2D PEH integrated array recognizes eight wrist motion states of small amplitude differences with 98.44% accuracy. This work not only provides a synergistic strategy of piezoelectric orientation and built‐in fields for developing intelligent sensor arrays, but also broadens the application fields of 2D piezoelectric devices.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"54 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145035903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ion‐Selective Microporous Membranes via One‐Step Copolymerization Enable High‐Performance Redox Flow Batteries","authors":"Jiaye Liu, Chunchun Ye, Ying Ma, Rui Tan, Xiangwen Wang, Huiting Zhang, Peng Song, Quan‐Fu An","doi":"10.1002/adfm.202513137","DOIUrl":"https://doi.org/10.1002/adfm.202513137","url":null,"abstract":"Redox flow batteries are a promising solution for grid‐scale energy storage but are constrained by ion‐exchange membranes that struggle to simultaneously achieve high ionic conductivity and effective selectivity against redox‐active species. Traditional nanophase‐separated membranes inherently suffer from trade‐offs between conductivity and selectivity; while emerging microporous polymer membranes typically involve complex synthetic routes and high production costs. Herein, a straightforward, one‐step copolymerization strategy is introduced that integrates rigid nanopore‐forming, hydration‐regulating, and ion‐conductive monomers into microporous membranes with precisely tunable properties. These membranes exhibit interconnected ultra‐microporous channels, providing exceptional dimensional stability, optimized hydration networks, and uniformly distributed ion‐conductive functionalities, thereby facilitating rapid ion transport alongside ion.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"21 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145035683","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"3D NASICON Ceramic Skeleton Enabled 18 µm‐Thick High Performance Bicontinuous‐Phase Ultrathin Composite Quasi‐Solid‐State Electrolyte","authors":"Lin Zeng, Chengshuai Bao, Xianshuang Xin, Haitao Lu, Pan Xiong, Xiaorong Dong, Huan Chen, Jun Jin, B. V. R. Chowdari, Xiangwei Wu, Zhaoyin Wen","doi":"10.1002/adfm.202517736","DOIUrl":"https://doi.org/10.1002/adfm.202517736","url":null,"abstract":"Ultrathin composite solid‐state electrolytes with ultrathin thicknesses and ultra‐low weight exhibit significant prospects for constructing high‐energy‐density solid‐state sodium metal batteries (SSSMBs). However, composite quasi‐solid‐state electrolytes (CSSEs) based on ceramic powder usually show discontinuous ionic transport channels and uneven agglomeration of the powder, which limits their practical performance. In this work, a 3D continuous self‐supporting Na<jats:sub>3.3</jats:sub>Mg<jats:sub>0.15</jats:sub>Zr<jats:sub>1.85</jats:sub>Si<jats:sub>2</jats:sub>PO<jats:sub>12</jats:sub> (NMZSP) ultrathin ceramic skeleton is sintered and further combined with an in situ UV curing process of trihydroxymethylpropyl triacrylate (TMPTA) to achieve an 18 µm‐thick ultrathin NMZSP ceramic skeleton composite quasi‐solid‐state electrolyte (UNSCE). The introduction of a ceramic skeleton effectively prevents ceramic powder agglomeration. Moreover, the synergistic interaction between the ceramic skeleton and the polymer matrix creates an abundant continuous two‐phase interface, which promotes the selective and rapid transportation of Na<jats:sup>+</jats:sup>. Therefore, UNSCE demonstrates a high Na<jats:sup>+</jats:sup> transference number (0.76). COMSOL simulations confirm that the 3D ceramic skeleton facilitates uniform current density, reducing dendrite formation risks. The Na | UNSCE | Na<jats:sub>3</jats:sub>V<jats:sub>2</jats:sub>(PO<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub> cell obtains a capacity retention of 91% after 500 cycles at 1C and a discharge capacity of 83.8 mAh g<jats:sup>−1</jats:sup> at 10C. In summary, this work presents a scalable fabrication strategy for high‐performance ultrathin CSSEs based on a non‐inert ceramic skeleton, advancing practical deployment in SSSMBs.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"39 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145035778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}