Advanced Functional Materials最新文献

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Climate-Adaptive High-Performance Moisture-Induced Electric Generator Utilizing Electric Double-Layer Gradient 利用电双层梯度的高性能自适应气候湿致发电机
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-06-29 DOI: 10.1002/adfm.202506700
Xian Wen, Zhaoyang Sun, Yujang Cho, Min Soo Kim, Kunlin Qin, Qun Zhou, Chentian Zhang, Liming Wang, Il-Doo Kim, Xiaohong Qin
{"title":"Climate-Adaptive High-Performance Moisture-Induced Electric Generator Utilizing Electric Double-Layer Gradient","authors":"Xian Wen, Zhaoyang Sun, Yujang Cho, Min Soo Kim, Kunlin Qin, Qun Zhou, Chentian Zhang, Liming Wang, Il-Doo Kim, Xiaohong Qin","doi":"10.1002/adfm.202506700","DOIUrl":"https://doi.org/10.1002/adfm.202506700","url":null,"abstract":"Water energy harvesting technologies provide a promising approach for harnessing ubiquitous water for clean, renewable energy generation. However, existing systems often rely on mechanical water movement, liquid water supplementation, or high-humidity conditions, limiting their practical applications in fluctuating environments and wearables. Here, a self-gradient hydrogel-based moisture-induced electric generator (SHMEG) is reported, formed by the self-diffusion of pre-gel solution on carbon blacks loaded knitted fabric and a pair of sliver electrodes, which can maintain high performance and flexibility under various environments. The main driving source of SHMEG is the electric double-layer gradient formed at the hydrogel–carbon interface and the intrinsic properties of electrode. The SHMEG demonstrates a sustained voltage output of 0.75 V for 140 h and a current output of 15 µA at ≈75% RH under room temperature (≈25 °C). Benefitting from the high hygroscopicity, moisture retention, and temperature adaptability, SHMEG reliably delivers a stable electrical output of 0.5 V at 20% RH and 0.7 V at −10 °C. Moreover, SHMEG demonstrates versatility by powering small electronics and functioning as a strain sensor with up to 300% stretchability. This work represents a significant advance in moisture-induced energy harvesting, expanding its applicability to a broader range of environments and wearables.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"52 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144516256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ion Exchange-Based Microreactors Harness Self-Generated pH Gradients and Long-Range Flow for Dual-Enhanced Uranium Extraction 离子交换微反应器利用自产生的pH梯度和远程流进行双强化铀萃取
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-06-29 DOI: 10.1002/adfm.202509597
Ling Chen, Linhui Fu, Kai Feng, Xinle Zhang, Jiang Gong, Jinping Qu, Ran Niu
{"title":"Ion Exchange-Based Microreactors Harness Self-Generated pH Gradients and Long-Range Flow for Dual-Enhanced Uranium Extraction","authors":"Ling Chen, Linhui Fu, Kai Feng, Xinle Zhang, Jiang Gong, Jinping Qu, Ran Niu","doi":"10.1002/adfm.202509597","DOIUrl":"https://doi.org/10.1002/adfm.202509597","url":null,"abstract":"Radioactive uranium presents a significant threat to human health and the aquatic ecosystem. Therefore, uranium extraction technologies with high efficiency, environmental friendliness, and high selectivity are highly required, but remain challenging. In this work, a microreactor based on cation-exchange reaction (CIEX) is designed for dual-enhanced uranium extraction. The microreactor with local pH regulation, self-generated long-range flow, abundant functional groups, and the photoreduction greatly enhances the transport of uranium toward the adsorbent, as well as the adsorption of binding sites by breaking the adsorption–desorption equilibrium in an energy-saving and environmentally friendly manner. Benefited from the above, a significant uranium removal capacity of 1556 ± 44.5 mg g<sup>−1</sup> is reached within 120 min in 30 mg L<sup>−1</sup> uranium solution. Meanwhile, the microreactor shows high selectivity toward uranium among other cations, applicability in various non-marine waters, and good recyclability. This work proposes a unique methodology for autonomous uranium removal with minimized secondary pollution.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"63 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144516246","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of the Effects of Strain and Electric Field on the Spin-State Energetics of Co-Doped BaTiO3 and PbTiO3 应变和电场对共掺杂BaTiO3和PbTiO3自旋态能量学影响的研究
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-06-29 DOI: 10.1002/adfm.202505536
Oliver J. Conquest, Steefan Contractor, Leigh Weston, Catherine Stampfl
{"title":"Investigation of the Effects of Strain and Electric Field on the Spin-State Energetics of Co-Doped BaTiO3 and PbTiO3","authors":"Oliver J. Conquest, Steefan Contractor, Leigh Weston, Catherine Stampfl","doi":"10.1002/adfm.202505536","DOIUrl":"https://doi.org/10.1002/adfm.202505536","url":null,"abstract":"First principles investigations are performed to study the effect of in-plane strain and application of an electric field on the spin state energetics of cobalt doped ferroelectric perovskites, BaTiO<sub>3</sub> (BTO) and PbTiO<sub>3</sub> (PTO). The variation of strain has a large and systematic effect on the unit cell volume, and the spin splitting is clearly correlated with the volume, where increased volume favors the HS state. At equilibrium geometry, the local density approximation (LDA) favors the LS state, while the generalized-gradient approximation (GGA) favors the HS state. However, when using the experimental lattice parameters, the GGA also favors the LS. The more accurate HSE and r<sup>2</sup>SCAN functionals both favor the HS state, but for BTO, on application of a small in-plane compressive uniaxial strain of 2–3%, both the HS and LS states become degenerate in energy thus exhibiting bistable magnetism. Investigation of the magnetic anisotropy (including spin-orbit coupling) shows a change in the (001) to (010) direction of the spin easy axis from the tetragonal to orthorhombic structural phases of Co:PTO/Co:BTO. The application of an external electric field on a Co:PTO slab has a small effect on the magnetic and structural properties of the system.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"1 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144516229","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
V‐Shaped 3D Electrothermal Dual‐Function Metamaterials: Dynamic Dual‐Field Cloak Through Geometric Transformation V形三维电热双功能超材料:基于几何变换的动态双场斗篷
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-06-27 DOI: 10.1002/adfm.202509862
Yinuo Zhou, Xianrong Cao, Zhenghong Wang, Jiachang Li, Ziang Zhang, Yixin Liu, Yuyao Zhu, Xiaogang He, Zhengdong Cheng, Peng Hu, Liqun He, Gang Zhao
{"title":"V‐Shaped 3D Electrothermal Dual‐Function Metamaterials: Dynamic Dual‐Field Cloak Through Geometric Transformation","authors":"Yinuo Zhou, Xianrong Cao, Zhenghong Wang, Jiachang Li, Ziang Zhang, Yixin Liu, Yuyao Zhu, Xiaogang He, Zhengdong Cheng, Peng Hu, Liqun He, Gang Zhao","doi":"10.1002/adfm.202509862","DOIUrl":"https://doi.org/10.1002/adfm.202509862","url":null,"abstract":"Multifunctional metamaterials have emerged as a transformative platform for controlling multi‐physical fields, promising applications in intelligent manufacturing, flexible electronics, thermal management, and energy conversion. However, conventional metamaterial designs typically prioritize optimizing single‐field responses, constraining their adaptability and functional integration potential in complex multi‐physics scenarios where coordinated regulation of multiple fields is required. Here, a V‐shaped 3D electrothermal dual‐function metamaterial (V‐ETDFM) architecture is proposed, enabling efficient and reconfigurable control of both electric and thermal transport. By expanding conduction pathways into 3D space, the proposed V‐shaped structure introduces additional degrees of freedom, enhancing its functional integration and adaptability. Through theoretical and numerical analysis, the feasibility of dynamically controlling cloak parameters, including size, shape, and spatial positioning, is demonstrated by reversibly stretching and compressing the V‐shaped framework based on transformation principles that maintain effective parameter invariance. Experimentally, a series of electrothermal cloaks with varying cloaked regions are fabricated to validate key design principles, confirming the static properties of the theoretical framework, while the implementation of real‐time dynamic tuning presents an avenue for future exploration. The work establishes a novel design strategy for electrothermal multifunctional metamaterials and provides a foundational theoretical framework for flexible and reconfigurable multi‐physics materials.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"246 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144500534","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Lithography‐Free and High‐Generation Fractal Plasmonic Nanoantenna for Multispectral Infrared Sensing 用于多光谱红外传感的无光刻和高生成分形等离子体纳米天线
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-06-27 DOI: 10.1002/adfm.202509258
Ningfei Sun, Shuolei Zhang, Xingyu Liu, Peng Zhao, Xiaobo Xue, Nyachieo Kennedy Momanyi, Jianyu Sun, Limin Liu, Xiaoguang Wei, Ling Li, Yong Xie
{"title":"Lithography‐Free and High‐Generation Fractal Plasmonic Nanoantenna for Multispectral Infrared Sensing","authors":"Ningfei Sun, Shuolei Zhang, Xingyu Liu, Peng Zhao, Xiaobo Xue, Nyachieo Kennedy Momanyi, Jianyu Sun, Limin Liu, Xiaoguang Wei, Ling Li, Yong Xie","doi":"10.1002/adfm.202509258","DOIUrl":"https://doi.org/10.1002/adfm.202509258","url":null,"abstract":"Fractal plasmonic nanoantennas are widely used in plasmon‐enhanced infrared spectroscopy and multiband sensing applications due to their inherent broadband and multispectral characteristics. However, conventional fractal antennas are typically fabricated by high‐cost, unscalable, and complicated lithography processes. The inevitable diffraction limit restricts the fabrication of higher‐order fractals and the improvement of multiband infrared response. In this study, a lithography‐free Au fractal nanoantenna platform is developed via film dewetting. The antennas can support multiple resonances over a broad spectral range spanning from near‐infrared to mid‐infrared. The fractal orders can be controlled by adjusting dewetting times. Moreover, due to the spontaneous fractal growth mechanism, the iteration number is theoretically unlimited. Through electromagnetic field simulation and infrared spectroscopy, the fractal order‐dependent multiband resonance mode and dense “hot spots” enabled electric‐field enhancement are revealed. Based on the infrared‐enhanced antenna, a minimum detection limit of 6 nm for the thickness of poly(methyl methacrylate) nanolayers is achieved. Additionally, a noninvasive sensor concept for glucose molecules in aqueous solution is demonstrated. This study presents a lithography‐free approach for constructing high‐generation and large‐area fractal nanoantennas with multiband resonance capabilities, which holds great promise for trace detection and high‐sensitivity biochemical sensing of various analytes in the near‐ to mid‐infrared spectral region.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"630 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144500537","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Customizing Oxygen Reduction Reaction Pathways for High‐Efficiency H2O2 Photosynthesis by Anionic Intermediate‐Generating Polymer Photocatalysts 利用阴离子中间体生成聚合物光催化剂定制H2O2高效光合作用的氧还原反应途径
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-06-27 DOI: 10.1002/adfm.202513175
Wenwen Chi, Bing Liu, Chengsi Pan, Jiawei Zhang, Yuming Dong, Yongfa Zhu
{"title":"Customizing Oxygen Reduction Reaction Pathways for High‐Efficiency H2O2 Photosynthesis by Anionic Intermediate‐Generating Polymer Photocatalysts","authors":"Wenwen Chi, Bing Liu, Chengsi Pan, Jiawei Zhang, Yuming Dong, Yongfa Zhu","doi":"10.1002/adfm.202513175","DOIUrl":"https://doi.org/10.1002/adfm.202513175","url":null,"abstract":"Artificial photosynthesis of hydrogen peroxide (H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub>) is of great importance, yet faces the challenge of diversified oxygen reduction pathways, resulting in low‐efficiency H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> production. Herein, a novel strategy is proposed to customize the direct one‐step two‐electron O<jats:sub>2</jats:sub> reduction pathway for H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> synthesis by modulating the electron transport kinetics of anionic intermediate‐generating organic polymer photocatalysts. Combined experimental and characterization results revealed the relationship between the electron transfer kinetics of anionic intermediates and ORR pathways under thermodynamically favorable conditions. Specifically, anionic intermediates with optimized electron transfer kinetics effectively mediate oxygen reduction to H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> via a direct one‐step two‐electron pathway. In contrast, sluggish electron transfer leads to an indirect two‐step two‐electron pathway for slow H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> production, whereas rapid electron transfer induces side reactions for undesired H<jats:sub>2</jats:sub>O formation. The naphthalene diimide anionic intermediate (NTEA<jats:sup>−•</jats:sup>) with moderated electron transfer speed exhibited an outstanding H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> generation rate of 6372 µ mol g<jats:sup>−1</jats:sup> h<jats:sup>−1</jats:sup> and a remarkable solar‐to‐H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> conversion efficiency of 1.02 %. Notably, the engineered NTEA membrane photocatalyst demonstrated an impressive H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> concentration of up to 1150 µ mol L<jats:sup>−1</jats:sup> in continuous‐flow reactor over 80 h. This work highlights that regulating the surface photoreaction pathways from the perspective of reaction kinetics is key to improving solar‐to‐chemical energy conversion efficiency.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"22 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144500612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polyelectrolyte Gradient Hydrogels for Efficient Solar Evaporation 高效太阳能蒸发用多电解质梯度水凝胶
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-06-27 DOI: 10.1002/adfm.202512350
Jie Zhu, Shaoen Qiu, Mingyu Duan, Qihao Xie, Oushuo Jiang, Xinran Zhao, Dong Wu, Yaxi Liu, Guang Chen, Xiayun Huang, Zhihong Nie
{"title":"Polyelectrolyte Gradient Hydrogels for Efficient Solar Evaporation","authors":"Jie Zhu, Shaoen Qiu, Mingyu Duan, Qihao Xie, Oushuo Jiang, Xinran Zhao, Dong Wu, Yaxi Liu, Guang Chen, Xiayun Huang, Zhihong Nie","doi":"10.1002/adfm.202512350","DOIUrl":"https://doi.org/10.1002/adfm.202512350","url":null,"abstract":"Freshwater scarcity is an escalating global challenge, and solar evaporation has emerged as a promising and sustainable desalination strategy. Although Janus‐structured solar evaporators offer improved directional water transport compared to bulk‐structured counterparts, their fabrication is complex, and the top polyelectrolyte layer is often relatively thick. Sustaining a high and homogeneous osmotic pressure within this layer remains challenging, thereby impeding continuous water delivery to the evaporative surface and constraining overall efficiency. In this study, a facile and controllable method to fabricate polyelectrolyte gradient hydrogels via an electric‐field‐driven grafting method is presented. The resulting surface‐localized polyelectrolyte gradient generates an exponentially increasing osmotic pressure, significantly enhancing directional water transport. Quaternized poly(4‐vinylpyridine) is employed as the functional polyelectrolyte owing to its strong hydrogen‐bond disrupting capability, which effectively lowers the energy required for evaporation. The optimized gradient evaporator, fabricated within just 10 min, exhibited an impressive osmotic pressure difference of 125 kPa and evaporation rate of 4.5 kg m<jats:sup>−2</jats:sup> h<jats:sup>−1</jats:sup>. Field experiments demonstrated excellent stability under 7‐day operation, achieving a high salt rejection ratio of 99.99% and a freshwater production rate of 14 kg m<jats:sup>−2</jats:sup> day<jats:sup>−1</jats:sup>.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"94 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144500681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structuring Liquids Through the Tailored Progressive Directed Assembly of Lignin Nanoparticles at the Liquid–Liquid Interface 木质素纳米颗粒在液-液界面的定向组装
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-06-27 DOI: 10.1002/adfm.202507247
Mingzhu Yao, Fang Liu, Cuiying Deng, Liuyi Wei, Baojie Liu, Chengrong Qin, Chen Liang, Caoxing Huang, Shuangquan Yao
{"title":"Structuring Liquids Through the Tailored Progressive Directed Assembly of Lignin Nanoparticles at the Liquid–Liquid Interface","authors":"Mingzhu Yao, Fang Liu, Cuiying Deng, Liuyi Wei, Baojie Liu, Chengrong Qin, Chen Liang, Caoxing Huang, Shuangquan Yao","doi":"10.1002/adfm.202507247","DOIUrl":"https://doi.org/10.1002/adfm.202507247","url":null,"abstract":"Emerging structured liquids have a lot of potential for transport channels in the liquid state because of their mobility, reconfigurability, and substance exchange. However, achieving stable drug delivery channels by precisely managing the structured liquid network still faces significant challenges. The design of nanoparticles is inspired by the tentacles of squid that deformed arbitrarily and exchanged substances with the external environment. A strategy to effectively reduce the energy barrier between liquid–liquid interfaces and amphiphilic lignin nanoparticles (LNPs) with interfacial activities through progressive directed assembly is proposed to achieve stable, reconfigurable encapsulation of liquids. An anisotropic nanoparticle structure consisting of a mixture of hydrophilic and lipophilic sites distributed on a spherical surface is designed to improve adsorption stability at the liquid–liquid interface. The surface polarity and spherical nanoscale dimensions of LNPs are regulated by modulating the phenolic hydroxyl content and molecular weight of lignin. Furthermore, a regulatory pathway between the molecular structure of lignin and the interfacial properties of LNPs is constructed. This strategy yielded more stable equilibrium sites for LNPs interfacial anchoring, resulting in highly integrated and stable structured liquids. This opens a wider range of possibilities for the interfacial design of encapsulation materials, drug delivery channels, and microreactors.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"53 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144503662","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cl−‐Doped Polypyrrole Nanotubes Toward Robust Thermal Dissipation and Tunable Microwave Absorbing/Shielding Properties Cl−掺杂聚吡咯纳米管具有强大的热耗散和可调谐的微波吸收/屏蔽性能
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-06-27 DOI: 10.1002/adfm.202511825
Baoxin Fan, Ran Ji, Bingran Huang, Yang Yu, Cheng Xie, Qian Lin, Guoxiu Tong, Liyan Xie, Tong Wu
{"title":"Cl−‐Doped Polypyrrole Nanotubes Toward Robust Thermal Dissipation and Tunable Microwave Absorbing/Shielding Properties","authors":"Baoxin Fan, Ran Ji, Bingran Huang, Yang Yu, Cheng Xie, Qian Lin, Guoxiu Tong, Liyan Xie, Tong Wu","doi":"10.1002/adfm.202511825","DOIUrl":"https://doi.org/10.1002/adfm.202511825","url":null,"abstract":"Developing multifunctional electromagnetic (EM) protection materials with high thermal conductivity is of great significance for next‐generation wearable electronics. However, balancing the different functionalities is a challenging task due to performance incompatibility. Therefore, this study aims to develop Cl<jats:sup>−</jats:sup>‐doped PPy nanotubes as a new multifunctional EM protection material via a simple soft template‐assisted oxidation polymerization process. The Cl<jats:sup>−</jats:sup> doping level and nanotube structure are precisely tuned by controlling the concentrations of MO and FeCl<jats:sub>3</jats:sub>, benefiting not simply conductivity but multiple polarizations and thermal transfer rates. Theoretical analyses confirm that controlling the Cl<jats:sup>−</jats:sup> doping level can adjust the PPy energy band structure and enable its conversion from semiconductor to conductor. The Cl<jats:sup>−</jats:sup>‐doped PPy nanotubes (PPy‐M‐4) exhibit efficient wide‐band microwave absorption (3.32 GHz mm<jats:sup>−1</jats:sup>) and RCS reduction (33.45 dBm<jats:sup>2</jats:sup>) at a 4 wt.% load, and attain a high EMI SE value of 66.36 dB with 99.9% shielding over 2–18 GHz at a 20 wt.% load. Furthermore, the Cl<jats:sup>−</jats:sup>‐doped PPy nanotubes/silicone membranes possess high tensile strength, exceptional flexibility, and high thermal conductivity (3.597 W m<jats:sup>−1</jats:sup> K<jats:sup>−1</jats:sup>), resulting from their 3D‐interconnected network, electrons, multifrequency active phonons, and coupling. These properties outperform those of most other materials.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"56 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144503658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Soft and Highly Adhesive Wearable Electronics for Hand Reconstruction Based on PMUT and PPA‐CNTs Strain Sensors 基于PMUT和PPA‐CNTs应变传感器的手部重建柔软和高粘性可穿戴电子设备
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-06-27 DOI: 10.1002/adfm.202510611
Dongze Lv, Ziwen Tang, Yingzhi Wang, Jiaquan Xu, YeJia Wu, Guoqiang Wu, Jin Xie
{"title":"Soft and Highly Adhesive Wearable Electronics for Hand Reconstruction Based on PMUT and PPA‐CNTs Strain Sensors","authors":"Dongze Lv, Ziwen Tang, Yingzhi Wang, Jiaquan Xu, YeJia Wu, Guoqiang Wu, Jin Xie","doi":"10.1002/adfm.202510611","DOIUrl":"https://doi.org/10.1002/adfm.202510611","url":null,"abstract":"3D hand reconstruction is an advanced technology in human‐machine interaction (HMI), robotic control, and medical rehabilitation applications. However, methods based on optical cameras and data gloves suffer from high equipment costs, complex algorithms, susceptibility to ambient light interference, and high drift of inertial measurement units (IMUs). Here, a soft electronic skin (E‐skin) for 3D hand reconstruction, inspired by human biology is proposed, which integrates a multi‐sensor fusion of stretchable carbon nanotubes (CNTs) strain sensors and microelectromechanical system (MEMS) ultrasonic transducers. A straightforward screen‐printing process is introduced‐ to fabricate a multi‐layer stacked structure of the E‐skin. The substrates of both the E‐skin and strain sensors use the same material, a polyethylene glycol (PEG) mixed polydimethylsiloxane (PDMS) adhesive (PPA), which strengthens the bonding between the layers. The optimized PPA exhibits a low modulus (186 kPa), high elongation (&gt;220%), and strong adhesion (1.2 N cm<jats:sup>−1</jats:sup>), while the PPA‐CNT composite strain sensor demonstrates excellent sensitivity linearity (0.99) and minimal resistance drift over 500 stretching cycles. The PPA material combines the waterproof and biocompatible properties of PDMS, while also achieving high adhesion and softness, allowing it to maintain conformal contact during finger bending (strain &gt;70%) without glue or bandage. A Quantile Regression Neural Network (QRNN) algorithm is introduced to improve dynamic accuracy and robustness in finger joint angle detection. The system's application in gesture recognition and VR interaction is demonstrated, achieving high accuracy in sign language recognition and robust hand tracking.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"22 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144500536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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