Advanced Functional Materials最新文献

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Flourishing Organic Active Optical Waveguides with Diversity and Creativity 蓬勃发展的有机有源光波导的多样性和创造性
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-07-22 DOI: 10.1002/adfm.202506412
Jia‐Xuan Zhang, Shuai Zhao, Zhenhuan Lu, Xue‐Dong Wang
{"title":"Flourishing Organic Active Optical Waveguides with Diversity and Creativity","authors":"Jia‐Xuan Zhang, Shuai Zhao, Zhenhuan Lu, Xue‐Dong Wang","doi":"10.1002/adfm.202506412","DOIUrl":"https://doi.org/10.1002/adfm.202506412","url":null,"abstract":"Conventional dielectric waveguides are limited by their propagation mechanisms and relatively large dimensions. A promising alternative lies in replacing electronic devices with photonic ones. In contrast, organic crystals featuring a regular shape can create optical waveguides that confine photons to micro‐ and nanoscales. This paper offers a concise overview of the preparation methods for using organic crystals as optical waveguide media, along with an exploration of the optical waveguide phenomena within these 1D or 2D, monolayer or multi‐tiered microcrystals, demonstrating the broad application prospects of optical waveguides. It is concluded by summarizing the current challenges and future prospects in this field.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"115 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678204","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unilateral Asymmetric Radiation in Bilayer Metasurfaces (Adv. Funct. Mater. 28/2025) 双层超表面的单侧不对称辐射。板牙。28/2025)
IF 18.5 1区 材料科学
Advanced Functional Materials Pub Date : 2025-07-21 DOI: 10.1002/adfm.70263
Junhao Tan, Ruhao Pan, Yuan Xiang, Zhiyang Tang, Bo Wang, Junjie Li
{"title":"Unilateral Asymmetric Radiation in Bilayer Metasurfaces (Adv. Funct. Mater. 28/2025)","authors":"Junhao Tan,&nbsp;Ruhao Pan,&nbsp;Yuan Xiang,&nbsp;Zhiyang Tang,&nbsp;Bo Wang,&nbsp;Junjie Li","doi":"10.1002/adfm.70263","DOIUrl":"https://doi.org/10.1002/adfm.70263","url":null,"abstract":"<p><b>Unilateral Asymmetric Radiation</b></p><p>In article number 2501156, Ruhao Pan, Bo Wang, Junjie Li, and co-workers report a bilayer metasurface of hexagonal lattice. The unilateral asymmetric radiation, which refers to the transmission difference on the same side of the metasurface, is realized and modulated by tuning the interlayer displacement. The results motivate the design of a wide range of functional nano-optical devices.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"35 28","pages":""},"PeriodicalIF":18.5,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adfm.70263","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144666462","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In‐Plane Magnetic Anisotropy and Large Topological Hall Effect in Self‐Intercalated Ferromagnet Cr1.61Te2 自插层铁磁体Cr1.61Te2的面内磁各向异性和大拓扑霍尔效应
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-07-21 DOI: 10.1002/adfm.202510351
Yalei Huang, Na Zuo, Zheyi Zhang, Xiangzhuo Xing, Xinyu Yao, Anlei Zhang, Haowei Ma, Chunqiang Xu, Wenhe Jiao, Wei Zhou, Raman Sankar, Dong Qian, Xiaofeng Xu
{"title":"In‐Plane Magnetic Anisotropy and Large Topological Hall Effect in Self‐Intercalated Ferromagnet Cr1.61Te2","authors":"Yalei Huang, Na Zuo, Zheyi Zhang, Xiangzhuo Xing, Xinyu Yao, Anlei Zhang, Haowei Ma, Chunqiang Xu, Wenhe Jiao, Wei Zhou, Raman Sankar, Dong Qian, Xiaofeng Xu","doi":"10.1002/adfm.202510351","DOIUrl":"https://doi.org/10.1002/adfm.202510351","url":null,"abstract":"Self‐intercalated chromium tellurides Cr<jats:sub>1+</jats:sub><jats:italic><jats:sub>x</jats:sub></jats:italic>Te<jats:sub>2</jats:sub> have garnered growing attention due to their high‐temperature ferromagnetism, tunable spin structures and air stability, all of which are vital for versatile applications in next‐generation memory and information technology. Here, strong magnetic anisotropy and a large topological Hall effect (THE) in self‐intercalated Cr<jats:sub>1.61</jats:sub>Te<jats:sub>2</jats:sub> single crystals are reported, which are both highly desirable properties for future spintronic applications. These results demonstrate that Cr<jats:sub>1.61</jats:sub>Te<jats:sub>2</jats:sub> is a soft ferromagnet with strong in‐plane magnetic anisotropy. Remarkably, distinct THE behaviors are observed in different temperature regimes, reflecting the intricate spin structures and competing exchange interactions. More interestingly, a large topological Hall resistivity, induced by microscopic non‐coplanar spin structures, emerges in the temperature range 70–240 K, reaching a maximum value of 0.93 µΩ cm at 150 K. Moreover, a sign‐reversed and weak THE is observed at low temperatures below ≈ 70 K, indicating the emergence of an additional topological spin structure with opposite topological charges. This work not only offers valuable insights into the correlation between magnetocrystalline anisotropy and topological phenomena in Cr<jats:sub>1+</jats:sub><jats:italic><jats:sub>x</jats:sub></jats:italic>Te<jats:sub>2</jats:sub> systems, but also provides a robust platform for engineering the evolution of complex spin textures that can be leveraged in diverse spintronic device applications.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"14 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144669653","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simultaneous Self-Healing and Corrosion Protection Using Disulfide Bonds (Adv. Funct. Mater. 29/2025) 利用二硫键同时自愈和腐蚀保护。板牙。29/2025)
IF 18.5 1区 材料科学
Advanced Functional Materials Pub Date : 2025-07-21 DOI: 10.1002/adfm.70418
Jenpob Sokjorhor, Chaichana Phantan, Kanisorn Ratanathawornkit, Daniel Crespy
{"title":"Simultaneous Self-Healing and Corrosion Protection Using Disulfide Bonds (Adv. Funct. Mater. 29/2025)","authors":"Jenpob Sokjorhor,&nbsp;Chaichana Phantan,&nbsp;Kanisorn Ratanathawornkit,&nbsp;Daniel Crespy","doi":"10.1002/adfm.70418","DOIUrl":"https://doi.org/10.1002/adfm.70418","url":null,"abstract":"<p><b>Anticorrosion Coatings</b></p><p>In article number 2508274, Daniel Crespy and co-workers present a novel polymer-inhibitor coating system that demonstrates self-healing capability and long-term corrosion resistance on metal surfaces. Both functions are activated through the reversibility of disulfide linkages upon heating, hence facilitating damage healing while releasing the inhibitor. The smart release mechanism ensures efficient protection, making this design highly suitable for advanced material applications in harsh environments.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"35 29","pages":""},"PeriodicalIF":18.5,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adfm.70418","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144666170","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An Intranasal Nanomedicine Functions as Both Potent Broad-spectrum Viral Inhibitor and Quasi-Vaccine (Adv. Funct. Mater. 28/2025) 一种鼻内纳米药物作为有效的广谱病毒抑制剂和准疫苗。板牙。28/2025)
IF 18.5 1区 材料科学
Advanced Functional Materials Pub Date : 2025-07-21 DOI: 10.1002/adfm.70262
Jingran Chen, Ying Li, Li Xiao, Zhanchen Guo, Weihua Lu, Jin Huang, Jizong Li, Bin Li, Zhen Liu
{"title":"An Intranasal Nanomedicine Functions as Both Potent Broad-spectrum Viral Inhibitor and Quasi-Vaccine (Adv. Funct. Mater. 28/2025)","authors":"Jingran Chen,&nbsp;Ying Li,&nbsp;Li Xiao,&nbsp;Zhanchen Guo,&nbsp;Weihua Lu,&nbsp;Jin Huang,&nbsp;Jizong Li,&nbsp;Bin Li,&nbsp;Zhen Liu","doi":"10.1002/adfm.70262","DOIUrl":"https://doi.org/10.1002/adfm.70262","url":null,"abstract":"<p><b>Photothermal Nanomedicine</b></p><p>In article number 2501533, Bin Li, Zhen Liu, and co-workers present a brand-new antiviral concept that integrates antivirals and vaccines for providing rapid viral inhibition and long-term prevention simultaneously. The elaborately designed photothermal nanomedicine exerts multiple antiviral mechanisms including broad-spectrum virus binding, blocking virus-cell attachment, inducing viral aggregation, enhancing macrophage phagocytosis, promoting virions lysis, and initiating immune response.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"35 28","pages":""},"PeriodicalIF":18.5,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adfm.70262","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144666562","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phototropic Self‐Growing Hydrogels Enabled by a Tricyanofuran Derivatized Photoswitch 由三氰呋喃衍生化光开关实现的自生长光凝胶
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-07-21 DOI: 10.1002/adfm.202509972
Peixi Han, Xuehan Yang, Shuailong Zhou, Yifan Zheng, Zhaomiao Chu, Mengqi Du, Chuang Li
{"title":"Phototropic Self‐Growing Hydrogels Enabled by a Tricyanofuran Derivatized Photoswitch","authors":"Peixi Han, Xuehan Yang, Shuailong Zhou, Yifan Zheng, Zhaomiao Chu, Mengqi Du, Chuang Li","doi":"10.1002/adfm.202509972","DOIUrl":"https://doi.org/10.1002/adfm.202509972","url":null,"abstract":"Phototropism is ubiquitous in plants that endows them directional movement and substantial growth toward light sources. Simultaneous replication of such phototropic movement and volumetric growth in synthetic polymers is important but currently remains challenging. Here, the molecular design of a photoswitchable tricyanofuran (TCF) based hydrogel is reported that can concurrently display such phototropic movement and self‐growth in water under stimulation of light and pH. The macroscale growth of the hydrogel originates directly from the volume swelling induced by charge rise of TCF upon isomerization, which dramatically facilicates water/nutrients diffusion into the network. As the growing rate under each stimulation is independently regulated, TCF hydrogels are successfully developed displaying heterogeneous growth accompanied with phototropic bending deformation by taking the advantage of the differential growing rates induced by light and pH. Importantly, the phototropic deformation direction after secondary polymerization growth can be reversibly switched between positive and negative states modulating light irradiation and pH conditions. This tunability enables biomimetic replication of natural light‐responsive systems. The work provides a novel molecular design strategy for advancing the development of biomimetic systems with capability of phototropic deformation and self‐growth.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"26 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144669716","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Facile Engineering of a Rosin‐Derived Natural Electron Acceptor toward Twisted Intramolecular Charge Transfer‐Active BioAIE Materials with Dual Functionality 松香衍生的天然电子受体对具有双重功能的扭曲分子内电荷转移活性生物aie材料的简易工程研究
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-07-21 DOI: 10.1002/adfm.202508618
Yanchen Wu, Zhuo‐Yang Xin, Yuting Lin, Shilong Yang, Zheng Zhao, Wen‐Jin Wang, Ben Zhong Tang, Xu‐Min Cai
{"title":"Facile Engineering of a Rosin‐Derived Natural Electron Acceptor toward Twisted Intramolecular Charge Transfer‐Active BioAIE Materials with Dual Functionality","authors":"Yanchen Wu, Zhuo‐Yang Xin, Yuting Lin, Shilong Yang, Zheng Zhao, Wen‐Jin Wang, Ben Zhong Tang, Xu‐Min Cai","doi":"10.1002/adfm.202508618","DOIUrl":"https://doi.org/10.1002/adfm.202508618","url":null,"abstract":"With the deepening of sustainable development strategies, the monotonous skeletal structure and poor renewability of traditional petroleum‐based aggregation‐induced emission (AIE) materials have constrained their further advancements. In contrast, natural biomass‐derived materials have demonstrated tremendous potential due to their inherent renewability, superior biocompatibility, and unique structural skeletons. This study proposes a rational molecular design strategy to produce rosin‐derived dehydroabietic acid‐quinoxaline (DAQx) as a natural electron acceptor, and triphenylamine is incorporated as an electron donor to construct a donor–acceptor (D–A) type structure. This approach develops biomass‐based aggregation‐induced emission (BioAIE) materials with twisted intramolecular charge transfer characteristics. By adjusting the conjugation extent and electron‐withdrawing capability of the DAQx skeleton, dynamic optimization of photophysical properties is achieved. The results indicate that the modified D–A‐type BioAIE materials not only exhibit remarkable solvent stimuli‐responsive behavior, enabling dynamic encryption‐decryption, but also realize precisely targeted imaging of subcellular organelles, benefiting from the inherent biocompatibility of the natural DAQx skeleton. This work provides a novel strategy for designing high‐performance BioAIE materials based on natural rosin‐based electron acceptor, while expanding the application potential of biomass‐based luminescent materials in intelligent anti‐counterfeiting and bioimaging fields, offering new insights for the high‐value utilization of rosin.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"97 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144669718","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Anionic COF Aerogels for Selective Pollutant Removal and Ultrasensitive SERS Detection 阴离子COF气凝胶用于选择性污染物去除和超灵敏SERS检测
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-07-21 DOI: 10.1002/adfm.202510861
Lulu Qu, Yingdi Zhang, Yunsheng Shang, Bohan Gu, Xinyue Hong, Shuang Zhao, Yingqiu Gu, Guohai Yang, Xiaochen Dong
{"title":"Anionic COF Aerogels for Selective Pollutant Removal and Ultrasensitive SERS Detection","authors":"Lulu Qu, Yingdi Zhang, Yunsheng Shang, Bohan Gu, Xinyue Hong, Shuang Zhao, Yingqiu Gu, Guohai Yang, Xiaochen Dong","doi":"10.1002/adfm.202510861","DOIUrl":"https://doi.org/10.1002/adfm.202510861","url":null,"abstract":"The simultaneous removal and real‐time monitoring of organic pollutants in complex water matrices remains challenging due to interference from coexisting substances and limitations in detection sensitivity. Here, an anionic covalent organic framework (COF)‐based aerogel (denoted as CCGA) is presented with both excellent selectivity and ultrahigh surface‐enhanced Raman scattering (SERS) detection sensitivity. The hierarchical architecture of CCGA synergistically integrates macroporous graphene scaffolds with micro‐mesoporous COF channels, facilitating rapid and selective capture of cationic dyes (&gt;92% removal efficiency) via <jats:italic>π–π</jats:italic> stacking and electrostatic interactions, while exhibiting negligible affinity for anionic counterparts. This aerogel‐based enrichment strategy enables SERS detection of trace pollutants down to 1.65 × 10<jats:sup>−5</jats:sup> mg mL<jats:sup>−1</jats:sup> for rhodamine B (RhB) and 2.27 × 10<jats:sup>−6</jats:sup> mg mL<jats:sup>−1</jats:sup> for malachite green (MG). Furthermore, the heterojunction reduces the bandgap of graphitic carbon nitride and promotes visible‐light‐driven photocatalytic degradation, allowing self‐regeneration of the aerogel across nine cycles. Demonstrating practical applicability, the CCGA exhibits versatility in addressing complex cationic pollutants and operates effectively within real wastewater matrices via a portable filtration system. This work advances multifunctional material design by integrating selective adsorption, molecular‐level detection, and solar‐driven regeneration strategies, presenting a scalable approach for next‐generation water remediation technologies.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"14 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144669749","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cu‐MOF Functionalized Hydroxyapatite/Bacterial Cellulose Composite Separator Enabling Dendrite‐Free Fast Charging and Enhanced Thermal Safety for High‐Loading Graphite Anode Cu - MOF功能化羟基磷灰石/细菌纤维素复合分离器,实现无枝晶快速充电和提高高负载石墨阳极的热安全性
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-07-21 DOI: 10.1002/adfm.202515523
Long Cheng, Yaxin Zhang, Dandan Li, Rui Li, Hao Ouyang, Honggang He, Shi Chen, Shiyou Zheng, Heng Li
{"title":"Cu‐MOF Functionalized Hydroxyapatite/Bacterial Cellulose Composite Separator Enabling Dendrite‐Free Fast Charging and Enhanced Thermal Safety for High‐Loading Graphite Anode","authors":"Long Cheng, Yaxin Zhang, Dandan Li, Rui Li, Hao Ouyang, Honggang He, Shi Chen, Shiyou Zheng, Heng Li","doi":"10.1002/adfm.202515523","DOIUrl":"https://doi.org/10.1002/adfm.202515523","url":null,"abstract":"Fast charging of high‐loading graphite anodes in lithium‐ion batteries (LIBs) is hampered by sluggish Li<jats:sup>+</jats:sup> ion transport kinetics, leading to detrimental Li dendrite formation and safety hazards. Herein, a copper‐based metal‐organic framework (Cu‐MOF) functionalized hydroxyapatite/bacterial cellulose (Cu‐MOF@HB) composite nanofibers separator is designed to address these critical challenges. The hierarchical porous structure of the Cu‐MOF@HB separator enhances electrolyte wettability and adsorption. Density functional theory (DFT) calculation reveals that abundant open metal sites within the Cu‐MOF promote PF<jats:sub>6</jats:sub><jats:sup>−</jats:sup> anion immobilization via <jats:italic>Lewis</jats:italic> acid‐base interactions, effectively increasing the Li<jats:sup>+</jats:sup> ion transference number and facilitating faster Li<jats:sup>+</jats:sup> ion migration within the separator. Consequently, the Cu‐MOF@HB separator effectively mitigates concentration polarization at the graphite anode/separator interfaces, suppressing Li dendrite formation and improving Coulombic efficiency. This significantly improves fast‐charging performance in high‐loading LiFePO<jats:sub>4</jats:sub> (15.5 mg cm<jats:sup>−2</jats:sup>)||graphite (7.5 mg cm<jats:sup>−2</jats:sup>) batteries, achieving 79% capacity retention after 600 cycles at 3 C, compared to only 16% with a conventional polypropylene (PP) separator. Critically, the Cu‐MOF@HB separator also exhibits exceptional thermal stability and flame retardancy, enhancing battery safety. This work highlights the significant potential of interfacial engineering of separators, particularly through the incorporation of functional MOFs and thermally stable inorganic nanofibers, for achieving safe and high‐performance fast‐charging LIBs.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"29 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144669708","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An Electrostatic‐Interaction Engineering on Phytate‐Coordinated Polyamide Membranes for High‐Efficiency Lithium Extraction 植酸配位聚酰胺膜的静电相互作用工程用于高效锂提取
IF 19 1区 材料科学
Advanced Functional Materials Pub Date : 2025-07-21 DOI: 10.1002/adfm.202514394
Xing Lai, Weiye Xu, Yukui Gou, Hongxiang Zhang, Jianying Huang, Weilong Cai, Yuekun Lai
{"title":"An Electrostatic‐Interaction Engineering on Phytate‐Coordinated Polyamide Membranes for High‐Efficiency Lithium Extraction","authors":"Xing Lai, Weiye Xu, Yukui Gou, Hongxiang Zhang, Jianying Huang, Weilong Cai, Yuekun Lai","doi":"10.1002/adfm.202514394","DOIUrl":"https://doi.org/10.1002/adfm.202514394","url":null,"abstract":"Phytate (PhA) holds considerable promise for constructing molecular sieve membranes due to its high density of long‐range electrostatic attractions, customizable charge density, and excellent polymer affinity. Herein, PhA‐Fe<jats:sup>3+</jats:sup> complexes constructed by controllable coordination assembly are presented, based on metal‐organophosphorus biphasic interfacial coordination reactions, and use the PhA‐Fe<jats:sup>3+</jats:sup> complexes to regulate the interfacial polymerization (IP) process to generate polyamide (PA) nanofiltration membranes. The PhA‐Fe<jats:sup>3+</jats:sup> complexes impart a high density of long‐range electrostatic and short‐range hydrogen bonding forces to the amine monomers and provide tunable charge densities through flexible metal‐organophosphate coordination. Hydrogen bonding and strong electrostatic interactions spatially enrich the amine monomers and temporally slow down their diffusion into the hexane phase, as demonstrated by molecular simulations, resulting in a PA/PhA‐Fe<jats:sup>3+</jats:sup> membrane with increased surface area, enhanced microporosity, lower thickness, higher water density near pores, and nanoscale spotted structures. Those structures are recognized as the key factor in achieving a water permeance of 19.2 L m<jats:sup>−2</jats:sup> h<jats:sup>−1</jats:sup> bar<jats:sup>−1</jats:sup>, alongside a MgCl<jats:sub>2</jats:sub> rejection of 96.7% and a Li<jats:sup>+</jats:sup>/Mg<jats:sup>2+</jats:sup> selectivity of 24.1 (Mg<jats:sup>2+</jats:sup>/Li<jats:sup>+</jats:sup> mass ratio = 20), surpassing those of reported nanofiltration membranes. This PhA‐Fe<jats:sup>3+</jats:sup> complexes‐modulated IP strategy offers fresh perspectives for constructing a highly permeable membrane for lithium extraction from salt lake brines.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"52 1","pages":""},"PeriodicalIF":19.0,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144669747","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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