基于MWCNT/TiO2/TiO2的新一代土壤和不同水样中达托霉素伏安传感器的研制

IF 3.5 4区 化学 Q2 ELECTROCHEMISTRY
Nida Aydogdu Ozdogan, Ersin Demir, Sibel A. Ozkan
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引用次数: 0

摘要

达托霉素是应用于临床的环脂肽类抗生素的先驱。它对革兰氏阳性菌有效,但它的广泛使用引起了环境样品污染的问题。为此,需要快速、灵敏、选择性和适用的环境基质中达托霉素的分析方法。本文采用吸附溶出差分脉冲伏安法,采用玻璃碳电极(GCE)和新开发的多壁碳纳米管/二氧化钛纳米颗粒/二氧化钛纳米颗粒修饰的玻璃碳电极(MWCNT/TiO2/TiO2/GCE)进行达托霉素的电化学检测。对支撑式传感器的表面特性进行了研究。优化条件下,未修饰电极与MWCNT/TiO2/TiO2/GCE的线性范围分别为0.2 ~ 1.0 μM和0.06 ~ 5.0 μM,检出限分别为0.086 μM和0.001 μM。通过干扰实验考察了该传感器对影响达托霉素检测的有机和无机化合物的选择性。所提出的测定不同环境(土壤、天然泉水和自来水)样品中达托霉素的方法的准确度在回收率研究中以回收率%计算。首次开发了一种新型、快速、可靠、经济、环保、敏感、高选择性的环境样品中达托霉素传感器,为文献中引入了一种新的分析方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Development of a New Generation MWCNT/TiO2/TiO2-Based Voltammetric Sensors for the Detection of Daptomycin in Soil and Different Water Samples

Development of a New Generation MWCNT/TiO2/TiO2-Based Voltammetric Sensors for the Detection of Daptomycin in Soil and Different Water Samples

Daptomycin is a pioneer cyclic lipopeptide antibiotic introduced for clinical use. It is effective against gram-positive bacteria, but its widespread use raises the problem of pollution in environmental samples. For this purpose, rapid, sensitive, selective, and applicable analytical methods for daptomycin in these environmental matrices are needed. In this work, electrochemical method was advanced with a glassy carbon electrode (GCE) and newly developed multi-walled carbon nanotubes/titanium dioxide nanoparticles/titanium dioxide nanoparticles modified GCE (MWCNT/TiO2/TiO2/GCE) for the daptomycin detection using adsorptive stripping differential pulse voltammetry. The surface characterization of the supported sensor was researched. Under optimized conditions, the linear range for the unmodified electrode and MWCNT/TiO2/TiO2/GCE was 0.2–1.0 μM and 0.06–5.0 μM, with detection limits of 0.086 μM and 0.001 μM. The selectivity of the proposed sensor was investigated for organic and inorganic compounds that could affect the detection of daptomycin by interference studies. The accuracy of the methods proposed for determining daptomycin in different environmental (soil, natural spring, and tap water) samples was calculated as % recovery in recovery studies. A novel, fast, reliable, cost-effective, eco-friendly, sensitive, and highly selective sensor was developed for the first time to determine daptomycin in environmental samples, introducing a new analytical method to the literature.

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来源期刊
ChemElectroChem
ChemElectroChem ELECTROCHEMISTRY-
CiteScore
7.90
自引率
2.50%
发文量
515
审稿时长
1.2 months
期刊介绍: ChemElectroChem is aimed to become a top-ranking electrochemistry journal for primary research papers and critical secondary information from authors across the world. The journal covers the entire scope of pure and applied electrochemistry, the latter encompassing (among others) energy applications, electrochemistry at interfaces (including surfaces), photoelectrochemistry and bioelectrochemistry.
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