Understanding the Effects of Ethylene as an Airborne Contaminant in Proton Exchange Membrane Fuel Cells and its Mitigation via Filtration

IF 3.5 4区 化学 Q2 ELECTROCHEMISTRY
Mahmoud Amirsalehi, Connor Miles, Justin Jordan, Karen E. Swider-Lyons, William Earl Mustain
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Abstract

Proton exchange membrane fuel cells (PEMFCs) are a promising clean energy technology, but their performance and durability are highly sensitive to contaminants in both the fuel and oxidant streams. Among these, ethylene (C2H4) is of particular interest due to its presence in industrial and warehouse environments. This study investigates the impact of ethylene contamination on PEMFC performance when introduced into the cathode air feed. A combination of fuel cell performance testing, cyclic voltammetry, and gas chromatography is used to analyze the interaction of ethylene with the cathode catalyst. The presence of 20–300 ppm ethylene in air causes an immediate drop in the fuel cell operating voltage that is quickly recovered once the contaminant is removed, suggesting a reversible adsorption mechanism on the surface of the platinum cathode electrocatalyst, rather than the formation of strongly bound oxidation intermediates. Additionally, the study explores mitigation strategies by evaluating conventional and chemically modified air filters. While commercial air filters prove ineffective, a carbon supported platinum (Pt/Vulcan)-coated filter demonstrates partial ethylene removal, reducing performance losses. These findings provide critical insights into ethylene contamination mechanisms and offer potential mitigation strategies to improve PEMFC reliability in real-world applications.

Abstract Image

了解乙烯作为空气污染物在质子交换膜燃料电池中的影响及其通过过滤的缓解
质子交换膜燃料电池(pemfc)是一种很有前途的清洁能源技术,但其性能和耐用性对燃料和氧化剂流中的污染物高度敏感。其中,乙烯(C2H4)由于其在工业和仓库环境中的存在而特别令人感兴趣。研究了在阴极进气中引入乙烯污染对PEMFC性能的影响。结合燃料电池性能测试、循环伏安法和气相色谱法来分析乙烯与阴极催化剂的相互作用。空气中含有20-300 ppm的乙烯会导致燃料电池的工作电压立即下降,一旦污染物被去除,工作电压就会迅速恢复,这表明铂阴极电催化剂表面存在可逆吸附机制,而不是形成强结合的氧化中间体。此外,该研究还通过评估传统和化学改性空气过滤器来探索缓解策略。虽然商用空气过滤器被证明是无效的,但碳支撑铂(Pt/Vulcan)涂层过滤器可以去除部分乙烯,减少性能损失。这些发现为了解乙烯污染机制提供了重要见解,并提供了潜在的缓解策略,以提高PEMFC在实际应用中的可靠性。
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来源期刊
ChemElectroChem
ChemElectroChem ELECTROCHEMISTRY-
CiteScore
7.90
自引率
2.50%
发文量
515
审稿时长
1.2 months
期刊介绍: ChemElectroChem is aimed to become a top-ranking electrochemistry journal for primary research papers and critical secondary information from authors across the world. The journal covers the entire scope of pure and applied electrochemistry, the latter encompassing (among others) energy applications, electrochemistry at interfaces (including surfaces), photoelectrochemistry and bioelectrochemistry.
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