Asian Journal of Organic Chemistry最新文献

Brønsted Acid-Catalyzed Regioselective [7+1] Annulation for the Construction of Indole-Fused Oxa-Eight-Membered Rings Brønsted酸催化区域选择性[7+1]环法制备吲哚-氧杂环

IF 2.3 4区化学

Asian Journal of Organic Chemistry Pub Date : 2026-11-05 DOI: 10.1002/ajoc.70591

Xuan Li, Na Dong, Rongkang Huang, Jianghao Yan, Xinying Qiao, Shaolin Zhou, Hao Xu

引用次数: 0

Multicomponent C─H Annulation of 1,3-Diketones, Alkynes, and Hydrazine to Yield (Cationic) Pyrazolo[5,1-a]isoquinolines 1,3-二酮、炔和肼的多组分C─H环化制（阳离子）吡唑啉[5,1-a]异喹啉

IF 2.3 4区化学

Asian Journal of Organic Chemistry Pub Date : 2026-11-05 DOI: 10.1002/ajoc.70590

Fangpeng Liang, Haidan Gao, Dan Yang, Yuqin Wang, Jingjing Huang, Shiqing Li

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A Systematic DFT Investigation of the Reaction Mechanism and Stereoselectivities in Iron-Catalyzed Reductive Diene Cyclization 铁催化还原二烯环化反应机理和立体选择性的系统DFT研究

IF 2.3 4区化学

Asian Journal of Organic Chemistry Pub Date : 2026-11-05 DOI: 10.1002/ajoc.70593

Qian Hu, Wei-Jie Liang, Cheng-Jin Wu, Qi Li, Jie He, Kai Chen

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Synthesis of Diarylboron β-Diketiminate Complexes and Their Thermally Activated Delayed Fluorescence Properties 二芳基硼β-二氯胺酸配合物的合成及其热激活延迟荧光性质

IF 2.3 4区化学

Asian Journal of Organic Chemistry Pub Date : 2026-11-05 DOI: 10.1002/ajoc.70582

Shunichiro Ito, Ryoji Himeno, Shun Omagari, Shota Hosoya, Mengfei Wang, Suguru Yoshida, Katsuhisa Tanaka, Yasuchika Hasegawa, Kazuo Tanaka, Yoshiki Chujo

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Coordination-Driven Metallo-Supramolecular Polymers as Electrochemical Sensing Interfaces: Molecular Design, Charge Transfer, and Applications 配位驱动的金属-超分子聚合物作为电化学传感界面：分子设计、电荷转移和应用

IF 2.3 4区化学

Asian Journal of Organic Chemistry Pub Date : 2026-11-05 DOI: 10.1002/ajoc.70576

Mst. Kaniz Subarna, Abdul Awal, Md. Delwar Hossain, Bong-Joong Kim, A. J. Saleh Ahammad

{"title":"Coordination-Driven Metallo-Supramolecular Polymers as Electrochemical Sensing Interfaces: Molecular Design, Charge Transfer, and Applications","authors":"Mst. Kaniz Subarna, Abdul Awal, Md. Delwar Hossain, Bong-Joong Kim, A. J. Saleh Ahammad","doi":"10.1002/ajoc.70576","DOIUrl":"https://doi.org/10.1002/ajoc.70576","url":null,"abstract":"<div>\u0000 \u0000 Metallo-supramolecular polymers (MSPs) are coordination-driven materials in which reversible metal–ligand interactions couple molecular design with redox-active polymeric interfaces. This review critically examines their synthesis, physicochemical properties, interfacial charge-transfer behavior, and emerging electrochemical sensing applications. Particular attention is given to how ligand denticity and conjugation, metal identity, mono- versus heterometallic organization, counterions, and film-fabrication strategies regulate redox accessibility, conductivity, analyte adsorption, and electrocatalytic response. Terpyridine-based MSPs provide the most developed sensing examples and illustrate how coordination-driven self-assembly can generate mono-, bi-, and trimetallic architectures with tunable electrochemical characteristics. Representative systems for nitrite, sulfite, bisphenol A, glucose, and Cr(VI) detection are compared with related MSPs platforms reported by different research groups to distinguish broadly applicable design principles from system-specific observations. Rather than treating structural characterization as an end point, emphasis is placed on structure–property–performance relationships linking coordination environment and morphology to electron-transfer kinetics and analytical response. Current limitations including the narrow diversity of sensing-active ligand frameworks, modest intrinsic conductivity, mechanistic uncertainty, long-term stability, and limited independent validation are critically assessed. Opportunities in ligand engineering, heterometallic programming, conductive hybrids, controlled film growth, and device integration are highlighted as directions for expanding MSP-based electrochemical sensing beyond the presently limited material space.\u0000 </div>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"15 11","pages":""},"PeriodicalIF":2.3,"publicationDate":"2026-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149356034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ligand-Programmed Small-Molecule Activation: From Redox-Non-Innocent Molecular Ligands to Soft-Oxometalate Microenvironments 配体程序化小分子活化：从氧化还原非无害分子配体到软金属酸氧微环境

IF 2.3 4区化学

Asian Journal of Organic Chemistry Pub Date : 2026-11-05 DOI: 10.1002/ajoc.70588

Khokan Manna, Goutam Kumar Lahiri, Soumyajit Roy

{"title":"Ligand-Programmed Small-Molecule Activation: From Redox-Non-Innocent Molecular Ligands to Soft-Oxometalate Microenvironments","authors":"Khokan Manna, Goutam Kumar Lahiri, Soumyajit Roy","doi":"10.1002/ajoc.70588","DOIUrl":"https://doi.org/10.1002/ajoc.70588","url":null,"abstract":"<div>\u0000 \u0000 Activating thermodynamically stable small molecules such as CO2, H2O, and N2 requires coordinated management of electrons, protons, substrates, and reaction intermediates. Although conventional catalyst design emphasizes metal centers or extended solids, coordination and supramolecular chemistry show that the surrounding environment can actively mediate redox and proton-transfer processes. This Perspective presents a ligand-centric framework linking redox-non-innocent (RNI) molecular ligands with soft-oxometalate (SOM) assemblies. Redox-active N2O2 chelates and tetrapyrrolic corroles demonstrate how ligand-centered redox states store charge, redistribute electron density, and cooperate with metal centers during O2 and CO2 activation. At larger scales, SOM assemblies can provide distributed redox buffering, proton management, substrate organization, and coupled catalytic reactivity. We define the “mesoscale ligand environment” as a functional, rather than structural, analogue of a molecular ligand. CO2 reduction and water oxidation provide the principal experimentally supported examples, whereas N2 reduction is considered a prospective extension. We propose that catalytic performance can be programmed across a hierarchy-from molecular ligands to SOM-based catalytic microenvironments-by co-designing electron/proton inventories, substrate accessibility, and dynamic organization. This Perspective distinguishes established evidence from future directions and proposes testable hybrid RNI-ligand/SOM catalyst architectures.\u0000 </div>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"15 11","pages":""},"PeriodicalIF":2.3,"publicationDate":"2026-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149356027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Iodine-Promoted Synthesis of Vinyl Sulfones via Decarboxylative Sulfonylation of α, β-Unsaturated Carboxylic Acids Using Aryl Sulfonyl Zinc Chlorides at Room Temperature 室温下芳基磺酰氯锌催化α， β-不饱和羧酸脱羧磺化合成乙烯基砜

IF 2.3 4区化学

Asian Journal of Organic Chemistry Pub Date : 2026-11-05 DOI: 10.1002/ajoc.70575

Bhaskarjyoti Borah, Bharat Kumar Allam, Divya Pratap Singh

引用次数: 0

The Elements of Chiral Brønsted Acids for Stereoselective Transformations 手性Brønsted酸的立体选择转化元素

IF 2.3 4区化学

Asian Journal of Organic Chemistry Pub Date : 2026-11-05 DOI: 10.1002/ajoc.70578

Diego A. Cruz-Aguilar, Margarita Cantú-Reyes, David A. Contreras-Cruz, Eddy I. Jiménez

{"title":"The Elements of Chiral Brønsted Acids for Stereoselective Transformations","authors":"Diego A. Cruz-Aguilar, Margarita Cantú-Reyes, David A. Contreras-Cruz, Eddy I. Jiménez","doi":"10.1002/ajoc.70578","DOIUrl":"https://doi.org/10.1002/ajoc.70578","url":null,"abstract":"Chiral Brønsted acids (CBAs) are powerful organocatalysts for asymmetric synthesis, with their performance governed by three modular elements: the acidic core, the chiral scaffold, and peripheral substituents\u0000. This review systematically examines each component. The acidic core (O─H, N─H, S─H, or C─H) dictates proton donor strength and conjugate base stability, ranging from classical phosphoric acids to superacidic imidodiphosphorimidates (IDPis) and disulfonimides. The chiral scaffold establishes the asymmetric environment; axial (BINOL, SPINOL), central (TADDOL, BPOL), planar (paracyclophane, ferrocene), and helical architectures each offer distinct steric and electronic profiles. Peripheral substituents fine‑tune the chiral pocket via steric shielding (e.g., 2,4,6‑triisopropylphenyl, triphenylsilyl), electronic modulation (π‑interactions, pKa control), and additional functionalities (Brønsted acid-assisted systems, photoactive groups). Recent advances highlight synergistic effects where noncovalent interactions complement or override pure steric control, enabling enantio‑ and diastereodivergent pathways. This review combines three design elements to frame rational catalyst development, guide optimal CBA architectures for challenging reactions, and outline future directions.","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"15 11","pages":""},"PeriodicalIF":2.3,"publicationDate":"2026-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ajoc.70578","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149356031","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Photocatalytic Cascade Cyclization of Unactivated Alkenes With N-Aminopyridinium Salts Toward Tetrahydropyridazine and Dihydropyrazole Derivatives n -氨基吡啶盐催化非活化烯烃级联环化制备四氢吡啶和二氢吡唑衍生物

IF 2.3 4区化学

Asian Journal of Organic Chemistry Pub Date : 2026-10-31 DOI: 10.1002/ajoc.70586

Mengna Li, Yuting Leng, Kaixia Sui, Junpei Chen, Panpan Wang, Wenhao Xu, Yusheng Wu, Yangjie Wu

引用次数: 0

Tandem Allene Formation/Intramolecular Cyclization of Phosphorus-Substituted Propargylic Alcohols and Substituted Phenols to Access C4-Phosphorylated 2H-Chromenes 磷取代丙炔醇和取代酚的串联烯形成/分子内环化以获得c4磷酸化的2h -铬

IF 2.3 4区化学

Asian Journal of Organic Chemistry Pub Date : 2026-10-31 DOI: 10.1002/ajoc.70585

Hai-Liang Ni, Huan-Zhu Xue, Mei-Ting Zhao, Kai-Cheng Yang, Long Chen

{"title":"Tandem Allene Formation/Intramolecular Cyclization of Phosphorus-Substituted Propargylic Alcohols and Substituted Phenols to Access C4-Phosphorylated 2H-Chromenes","authors":"Hai-Liang Ni, Huan-Zhu Xue, Mei-Ting Zhao, Kai-Cheng Yang, Long Chen","doi":"10.1002/ajoc.70585","DOIUrl":"https://doi.org/10.1002/ajoc.70585","url":null,"abstract":"<div>\u0000 \u0000 In this study, we demonstrated that phosphorus-substituted propargylic alcohols could undergo tandem allene formation/intramolecular cyclization to afford phosphorylated heterocycles. In the presence of 5 mol% of In(ClO4)3·8H2O or Hg(ClO4)2·3H2O, the reaction between phosphorus-substituted propargylic alcohols and substituted phenols proceeded via a tandem regioselective SN1’ substitution/intramolecular 6-endo-trig cyclization, which served as an alternative procedure for the preparation of C4-phosphorylated 2H-chromenes under mild conditions (air, 40°C or 60°C, 0.5–24 h). The richer diversity of substituents and their positions on the aryl ring of 2H-chromenes and its tolerance to P(O)(OR)2 groups make this protocol as a good supplement to previous report. The synthetic utilities were illustrated by the scaled synthesis and further elaboration of the obtained products to polycyclic compounds bearing phosphoryl groups, 2H-chromene and five or six-membered O-heterocycles. Control experiments further confirmed the tandem allene formation/intramolecular cyclization sequence.\u0000 </div>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"15 11","pages":""},"PeriodicalIF":2.3,"publicationDate":"2026-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149312800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0