{"title":"Copper-triggered adjacent S sites activating for enhancing the hydrogen evolution reaction in acid media","authors":"Guidong Xu, Shuo Geng","doi":"10.1016/j.jelechem.2025.119276","DOIUrl":"10.1016/j.jelechem.2025.119276","url":null,"abstract":"<div><div>Activating the inert basal plane of MoS<sub>2</sub> is considered to be an efficient strategy to enhance the HER activity of MoS<sub>2</sub>. Herein, the adjacent S sites in the basal plane were activated by doping cu into MoS<sub>2</sub> nanosheets (cu-MoS<sub>2</sub>). The density functional theory (DFT) calculation and experimental results show that the electronic structure of S sites adjacent to cu was adjusted. Furthermore, the ∆GH* of adjacent S sites around cu in the basal plane is closer to zero, indicating that the adsorption of H on MoS<sub>2</sub> was also optimized. Benefiting from the activation of adjacent S sites around cu in the basal plane, the obtained cu-MoS<sub>2</sub> nanosheets exhibit a small overpotential of 172 mV to achieve 10 mA cm<sup>−2</sup> in acid media with a low Tafel slope of 49 mV decade<sup>−1</sup>. This strategy, which involves doping-triggered activation of adjacent inert active sites, can be expanded to other two-dimensional materials for boosting electrocatalytic activity</div></div>","PeriodicalId":355,"journal":{"name":"Journal of Electroanalytical Chemistry","volume":"994 ","pages":"Article 119276"},"PeriodicalIF":4.1,"publicationDate":"2025-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144338699","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Enhanced performance of Fe2O3/MXene based supercapacitors with redox-electrolyte strategy","authors":"Jing Xu , Xinye Xu , Xiaoqing Bin, Yingyi Liao, Xuedong He, Wenxiu Que","doi":"10.1016/j.jelechem.2025.119278","DOIUrl":"10.1016/j.jelechem.2025.119278","url":null,"abstract":"<div><div>MXene-based supercapacitors are regarded as advanced energy storage devices owing to their high power density and extended cycle life. However, re-stacking of MXene significantly restricts its electrochemical performance while limited capacitance degrades the energy density. To address these limitations, we propose a dual-optimization strategy which integrates Fe<sub>2</sub>O<sub>3</sub>/MXene composite electrode design with redox-active electrolyte engineering, and thus achieves a high-performance Fe<sub>2</sub>O<sub>3</sub>/MXene-based asymmetric supercapacitor. Fe<sub>2</sub>O<sub>3</sub> nanoparticles anchored on MXene nanosheets via filtration and annealing mitigate re-stacking and provide redox-active sites, while their interfacial charge synergy with a Cu<sup>2+</sup>-rich electrolyte accelerates Cu<sup>2+</sup>/Cu<sup>+</sup> redox kinetics. The optimized composite electrode achieves a specific capacitance of 643.8 F g<sup>−1</sup> at 2 A g<sup>−1</sup> in 3 M H₂SO₄ + 30 mM CuSO₄ redox electrolyte. Moreover, the assembled asymmetric supercapacitor exhibits a high energy density of 20.1 Wh kg<sup>−1</sup> at a power density of 1292.5 W kg<sup>−1</sup>, outperforming most reported MXene-based devices. This work demonstrates a feasible strategy for designing high-performance supercapacitors with hybrid redox electrolytes.</div></div>","PeriodicalId":355,"journal":{"name":"Journal of Electroanalytical Chemistry","volume":"994 ","pages":"Article 119278"},"PeriodicalIF":4.1,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144338698","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pengfei Zhang , Henghao You , Chao Wang , Zhiqiang Liu , Yehong Zhang , Jixue Shen , Hui Li
{"title":"Constructing Co9S8/MoS2 heterostructures by one-step pyrolysis deep eutectic solvents enhancing lithium-ion storage","authors":"Pengfei Zhang , Henghao You , Chao Wang , Zhiqiang Liu , Yehong Zhang , Jixue Shen , Hui Li","doi":"10.1016/j.jelechem.2025.119271","DOIUrl":"10.1016/j.jelechem.2025.119271","url":null,"abstract":"<div><div>Co<sub>9</sub>S<sub>8</sub> emerges as a promising anode material for lithium-ion batteries (LIBs) due to its high theoretical capacity and eco-friendliness. However, its practical application is hindered by poor electrical conductivity, severe volume expansion, and rapid capacity decay. This study hypothesizes that constructing Co<sub>9</sub>S<sub>8</sub>/MoS<sub>2</sub> heterostructures within a carbon matrix via a simplified synthesis route can synergistically enhance charge transfer kinetics and structural stability. Herein, a one-step pyrolysis strategy utilizing a deep eutectic solvent (DES) is introduced to fabricate Co<sub>9</sub>S<sub>8</sub>/MoS<sub>2</sub>@C heterostructures, effectively streamlining the complex heterojunction preparation process. The optimized anode delivers exceptional cycling stability, retaining a high reversible capacity of 1022 mA h g<sup>−1</sup> after 550 cycles at 0.5 A g<sup>−1</sup>, alongside improved rate capability. The integrated heterostructure design and carbon confinement mitigate volume changes and facilitate rapid ion/electron transport, as validated by electrochemical and structural analyses. This work demonstrates a scalable synthesis approach for advanced heterostructured anodes, providing insights into overcoming the limitations of conversion-type materials for high-performance LIBs.</div></div>","PeriodicalId":355,"journal":{"name":"Journal of Electroanalytical Chemistry","volume":"994 ","pages":"Article 119271"},"PeriodicalIF":4.1,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144321395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jun Yi , Zuming He , Kai Lin , Long Shen , Yongmei Xia , Bin Tang , Guihua Chen
{"title":"Synergistic enhancement of sodium-ion storage performance in Na3V2(PO4)3/C cathode materials via Eu3+ doping and carbon coating","authors":"Jun Yi , Zuming He , Kai Lin , Long Shen , Yongmei Xia , Bin Tang , Guihua Chen","doi":"10.1016/j.jelechem.2025.119275","DOIUrl":"10.1016/j.jelechem.2025.119275","url":null,"abstract":"<div><div>In recent years, Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub>(NVP) has emerged as a promising cathode material for sodium-ion batteries (SIBs) due to its stable NASICON-type framework, high theoretical capacity (∼117.6 mAhg<sup>−1</sup>), and suitable operating voltage (∼3.4 V vs. Na<sup>+</sup>/Na). However, the practical application of NVP is hindered by its intrinsically low electronic conductivity, which significantly limits its electrochemical performance. This study systematically investigates the effects of Eu<sup>3+</sup> doping on the crystal structure, electronic conductivity, and electrochemical properties of NVP. The results findings demonstrate that optimal Eu<sup>3+</sup> doping effectively expands sodium-ion diffusion pathways while stabilizing the NASICON framework. Structural analyses (XRD, XPS) confirmed successful Eu<sup>3+</sup> incorporation without altering the host framework. Electrochemically, the optimized 0.03Eu-NVP/C composite delivered a reversible capacity of 109.94 mAhg<sup>−1</sup> at 0.1C, outstanding cycling stability (93.69 % retention after 600 cycles at 1C), and remarkable long-term performance (92.15 % retention after 3000 cycles at 20C). Kinetic studies revealed enhanced Na<sup>+</sup> diffusion coefficients and pseudocapacitive contributions, underscoring the efficacy of this dual-modification approach for high-performance sodium-ion batteries. Furthermore, the introduction of a carbon-coating layer substantially enhances the overall electronic conductivity of the material. The results conclusively demonstrate that Eu<sup>3+</sup>-doped Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub>/C represents a highly promising cathode material for high-performance sodium-ion batteries.</div></div>","PeriodicalId":355,"journal":{"name":"Journal of Electroanalytical Chemistry","volume":"994 ","pages":"Article 119275"},"PeriodicalIF":4.1,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144329746","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Computing the inverse Butler–Volmer relationship","authors":"L.K. Bieniasz","doi":"10.1016/j.jelechem.2025.119206","DOIUrl":"10.1016/j.jelechem.2025.119206","url":null,"abstract":"<div><div>A detailed discussion is presented, of the problem of computing the inverse Butler-Volmer (electrode potential vs. current) relationship efficiently and with a high accuracy. A number of limiting cases of this problem is identified, and approximations valid for these cases are deduced. A hybrid algorithm is constructed, that combines the various approximations and improves them by Newton iterations. The algorithm is implemented in C++, employing extended precision variables. It is found that the modulus of the relative error of the calculated electrode potential is predominantly close to ca. <span><math><mrow><mn>1</mn><msup><mrow><mn>0</mn></mrow><mrow><mo>−</mo><mn>18</mn></mrow></msup></mrow></math></span> and locally increases to ca. <span><math><mrow><mn>1</mn><msup><mrow><mn>0</mn></mrow><mrow><mo>−</mo><mn>15</mn></mrow></msup></mrow></math></span>. However, there are also well defined and unavoidable (albeit rather unlikely from the physical point of view) special situations in which the relative error may approach 100%, independently of the numerical algorithm used. The C++ code elaborated is made available. The code can be used for simulations of controlled current experiments, and for the analysis of diverse experimental data in electroanalytical and electrochemical engineering studies. An example application of the code, to the calculation of chronopotentiograms for a quasi-reversible charge transfer at a planar electrode, is also presented.</div></div>","PeriodicalId":355,"journal":{"name":"Journal of Electroanalytical Chemistry","volume":"994 ","pages":"Article 119206"},"PeriodicalIF":4.1,"publicationDate":"2025-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144321388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ziqi Wang, Yahui Ji, Nana You, Xiaoping Hu, Fangxin Du, Gen Liu
{"title":"Nanoconfinement-enchanced electrochemiluminescence based on a Ru(bpy)32+-loaded mesoporous silica nanoparticles for ribavirin detection","authors":"Ziqi Wang, Yahui Ji, Nana You, Xiaoping Hu, Fangxin Du, Gen Liu","doi":"10.1016/j.jelechem.2025.119274","DOIUrl":"10.1016/j.jelechem.2025.119274","url":null,"abstract":"<div><div>Testing ribavirin (RBV) is essential to promote its appropriate clinical use, mitigate resistance development, reduce adverse effects, and safeguard public health. Electrochemiluminescence (ECL) outperforms conventional methods in RBV detection, offering superior sensitivity and reduced background noise. In this work, ECL micro-reactors were prepared by incorporating Ru(bpy)<sub>3</sub><sup>2+</sup> into a mesoporous silica matrix with two-dimensional hexagonal structure (SBA-15). In this configuration, tripropylamine (TPA) was employed as a co-reactant, which interacted with Ru(bpy)<sub>3</sub><sup>2+</sup> to enhance the ECL signal. The quenching effect of ribavirin (RBV) on the Ru(bpy)<sub>3</sub><sup>2+</sup>-TPA system was confirmed through its significant suppression of ECL emission. A glassy carbon electrode (GCE) modified with SBA-15 loaded with Ru(bpy)<sub>3</sub><sup>2+</sup> (SBA-15@Ru) was fabricated as a novel ECL sensor. This sensor enabled the detection of RBV over a wide concentration range 1.0 × 10<sup>−9</sup> mol·L<sup>−1</sup> to 1.0 × 10<sup>−5</sup> mol·L<sup>−1</sup>, achieving a detection limit (LOD) of 3.33 × 10<sup>−10</sup> mol·L<sup>−1</sup>. Additionally, the sensor exhibited outstanding stability and selectivity and was successfully applied for accurate quantification of RBV in pharmaceutical samples.</div></div>","PeriodicalId":355,"journal":{"name":"Journal of Electroanalytical Chemistry","volume":"994 ","pages":"Article 119274"},"PeriodicalIF":4.1,"publicationDate":"2025-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144298495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Fabrication of Pt nanoparticles encapsulated by N, P co-doped carbon via solution plasma for the oxygen reduction reaction","authors":"Junzo Ukai , Pengfei Wang , Sangwoo Chae , Garbis Atam Akceoglu , Nutthira Pakkang , Yasuyuki Sawada , Nagahiro Saito","doi":"10.1016/j.jelechem.2025.119273","DOIUrl":"10.1016/j.jelechem.2025.119273","url":null,"abstract":"<div><div>The oxygen reduction reaction (ORR) remains a performance-limiting step in fuel cells due to sluggish kinetics and the high cost of platinum-based catalysts. In this study, we report the synthesis of nitrogen and phosphorus co-doped carbon (NPC) encapsulating Pt nanoparticles via a solution plasma process, aiming to reduce Pt usage while enhancing catalyst activity and durability. Structural characterization confirmed a core–shell morphology, with Pt cores uniformly embedded in a conductive, heteroatom-doped carbon shell. X-ray photoelectron spectroscopy revealed active nitrogen species (pyridinic and graphitic N) and P-doping contributing to electron redistribution and active site formation. Electrochemical tests in alkaline media demonstrated that the resulting NPC@Pt catalyst exhibits superior ORR activity, with a four-electron transfer pathway, higher limiting current density, and significantly improved long-term stability compared to commercial Pt/C. These findings highlight the synergy of heteroatom doping and core–shell structuring in advancing cost-effective, durable ORR electrocatalysts for alkaline fuel cells.</div></div>","PeriodicalId":355,"journal":{"name":"Journal of Electroanalytical Chemistry","volume":"994 ","pages":"Article 119273"},"PeriodicalIF":4.1,"publicationDate":"2025-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144329745","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Straightforward and affordable electrochemical sensing for collagen quality assessment in supplements: A novel strategy for hydroxyproline quantification","authors":"Kantima Kaewjua , Phanumas Yomthiangthae , Orawon Chailapakul , Weena Siangproh","doi":"10.1016/j.jelechem.2025.119272","DOIUrl":"10.1016/j.jelechem.2025.119272","url":null,"abstract":"<div><div>Hydroxyproline (Hyp) is one of the most significant biomarkers of collagen content. It is useful not only for clinical tracking but also for proving the quality of collagen-based dietary supplements. Due to the increasing popularity of collagen supplement consumption, this work presents a novel approach for the determination of collagen content using the hydroxyproline method. This study is the first report that describes the use of an unmodified screen-printed carbon electrode as an efficient and streamlined sensor for the detection of Hyp. The highlight of this research is eliminating any need for complicated preparation and detection processes. The measurement relies on the indirect detection of Hyp by comparing the signal of Cu(II) ions in the absence and presence of Hyp, using a sequential drop mixture of the sample and Cu(II) in a basic condition. Key parameters related to square wave anodic stripping voltammetry (SWASV) for detection were systematically examined to improve sensitivity and accuracy. Under optimal conditions, the modification-free sensor offers good performance for Hyp detection with a linear range of 0.5–10 mM and a detection limit of 0.15 mM. In practical analysis, Hyp in the collagen supplement samples was detected with an acceptable recovery range of 80.36–107.89 % (<em>n</em> = 3). In addition, the results obtained from the suggested approach were validated against the conventional standard technique. A paired <em>t</em>-test at the confidence level of 95 % shows no significant difference between the two methods. Therefore, this proposed method offers a promising assay for routine and real-time collagen analysis in food quality and safety control.</div></div>","PeriodicalId":355,"journal":{"name":"Journal of Electroanalytical Chemistry","volume":"994 ","pages":"Article 119272"},"PeriodicalIF":4.1,"publicationDate":"2025-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144313693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Electric field assisted migration of H+ and Cu+/Cu++ ions through the Nafion in Cu-Cl electrolyzer for hydrogen Generation: Molecular dynamics simulations","authors":"Pooja Sahu , Sk. Musharaf Ali","doi":"10.1016/j.jelechem.2025.119267","DOIUrl":"10.1016/j.jelechem.2025.119267","url":null,"abstract":"<div><div>This study explores the transport of proton and copper ions in hydrated Nafion membranes within a Cu–Cl electrolyzer, a key component of hybrid Cu-Cl cycle for hydrogen production. Particular focus is given to the effects of membrane hydration level and applied electric field strength. Molecular dynamics (MD) simulations reveal that electric fields enhance proton mobility by promoting water structuring and aligning hydronium ion trajectories, leading to a transition from diffusive to drift-dominated transport. Conversely, copper ions—especially Cu<sup>2+</sup>—disrupt the hydrogen-bonding network through solvation shell formation, thereby significantly diminish the ionic conductivity. While both hydration and field strength improve transport, hydration exerts a stronger influence. Conductivity increases with both factors but saturates at high field strengths, suggesting a threshold beyond which water drag impedes ion mobility. The presence of acidic medium was found to boost conductivity, whereas copper ions were seen to suppress it—markedly by Cu<sup>2+</sup>. These insights reveal the microscopic mechanisms of hydronium transport and copper-induced nafion degradation, offering guidance for the design of advanced ionomer membranes in electrolyzer and energy conversion applications.</div></div>","PeriodicalId":355,"journal":{"name":"Journal of Electroanalytical Chemistry","volume":"994 ","pages":"Article 119267"},"PeriodicalIF":4.1,"publicationDate":"2025-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144270878","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ding Shen, TianYu Li, ZhaoQi Ren, Ran Zhang, MingXue Yang, Duo Zhang, Wei Dong
{"title":"Research progress on coal-based hard carbon anode materials for sodium-ion batteries","authors":"Ding Shen, TianYu Li, ZhaoQi Ren, Ran Zhang, MingXue Yang, Duo Zhang, Wei Dong","doi":"10.1016/j.jelechem.2025.119265","DOIUrl":"10.1016/j.jelechem.2025.119265","url":null,"abstract":"<div><div>Sodium-ion batteries (SIBs) are considered an effective alternative to lithium-ion batteries due to their abundant resources and extensive industrialization potential. However, the synthesis and preparation of anode materials directly affect the industrialization process of SIBs. Carbon materials are favored for their stable structure, abundant resources, and practical applications. In this paper, the most abundant coal is selected as the hard carbon precursor. Yet, the internal structure of coal is complex, and there is a lack of systematic discussion on the various structural configurations of coal-based hard carbon materials. Therefore, the four mechanisms of sodium storage are discussed in depth, and the latest research progress on effectively improving the electrochemical performance of coal-based hard carbon anodes is comprehensively introduced. The above include coal selection, heteroatom incorporation, pore adjustment, soft and hard carbon compounding. Additionally, personal insights are provided on the challenges and issues faced by coal-based hard carbon materials in this review,thereby offering useful guidance for the development of high-end advanced energy storage electrode materials and the formulation of design rules to promote the industrialization of SIBs.</div></div>","PeriodicalId":355,"journal":{"name":"Journal of Electroanalytical Chemistry","volume":"994 ","pages":"Article 119265"},"PeriodicalIF":4.1,"publicationDate":"2025-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144313692","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}