Coordination Chemistry Reviews最新文献

{"title":"Understanding the working principle of sustainable catalytic materials for selective hydrogenation of carbonyls bond in α, β-unsaturated aldehydes","authors":"Muhammad Zahid, Ahmed Ismail, Muhammad Farooq Khan, Nauman Ali, Syedul Hasnain Bakhtiar, Atef El Jery, Basem Al Alwan, Rizwan Ullah, Fazal Raziq, Weidong He, K.H.L. Zhang, Jiabao Yi, Xiaoqiang Wu, Sharafat Ali, Liang Qiao","doi":"10.1016/j.ccr.2024.216295","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216295","url":null,"abstract":"The superior hydrogenation of carbonyl (C=O) bonds in α, β-unsaturated aldehydes (UAL) has attracted considerable attention from economic and industrial perspectives. Several efforts have been made because hydrogenation of the olefin (C<img alt=\"double bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/dbnd.gif\" style=\"vertical-align:middle\"/>C) bond is kinetically and thermodynamically preferred over C<img alt=\"double bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/dbnd.gif\" style=\"vertical-align:middle\"/>O bond hydrogenation. Hence, to achieve superior hydrogenation of the targeted C<img alt=\"double bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/dbnd.gif\" style=\"vertical-align:middle\"/>O bond, highly active and durable catalysts are required. Herein, functional hydrogenation catalytic materials and their working principles are thoroughly discussed and apprehended. The active role of noble, non-noble mono/bi-metal catalysts and support materials along with the key factors arising from the structure of catalysts that promotes the C<img alt=\"double bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/dbnd.gif\" style=\"vertical-align:middle\"/>O bond selectivity were thoroughly disclosed. Essential techniques and strategies, such as tuning the surface electronic properties and generating electro-nucleophilic sites via synergistic effects, geometric effects, and applying a confinement or steric effect for improved C<img alt=\"double bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/dbnd.gif\" style=\"vertical-align:middle\"/>O bond hydrogenation, are briefly apprehended. The aggregate analysis suggested two crucial approaches for the engineering of a vastly selective and stable hydrogenation catalytic material: (1) tuning the electronic number of an active noble metal and (2) stabilizing the active noble metal by selecting distinctive support materials, especially metal-organic frameworks (MOFs) owing to its special physiochemical features, to construct robust metal-support interactions. In the end, various crucial key factors and additional active sites that are also encountered to attain the desired selectivity of the C<img alt=\"double bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/dbnd.gif\" style=\"vertical-align:middle\"/>O bond are concisely reviewed. Regardless of the numerous successes, significant development is still essential to expand our understanding of the preferential hydrogenation of challenging C<img alt=\"double bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/dbnd.gif\" style=\"vertical-align:middle\"/>O bonds in UAL.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"11 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142673495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advances of surface-enhanced Raman scattering in gas sensing","authors":"Yu Cui, Kuan Chang, Qinzhi Wang, Yijian Zhao","doi":"10.1016/j.ccr.2024.216320","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216320","url":null,"abstract":"Gas detection technology has assumed an increasingly pivotal role within human society, spanning domains from biomedicine to environmental monitoring, food safety, and national defense. Compared with solid and liquid samples, gas molecules at lower concentrations can be difficult recognized and have always been a challenge. Surface-enhanced Raman scattering (SERS) has gained widespread adoption for trace analysis by virtue of their good selectivity, high sensitivity and superior enrichment performance of enhanced substrates, which also has significant advantages in gas detection. However, few works have focused on the critical reviews of this fascinating SERS method applied in the field of gas sensing. It is worth noting that some of the reviews seem to be similar in that they all focus on a specific topic, either on environmental monitoring or related to human health. Thus, in this work, recent advances and future challenges of SERS in gas sensing are firstly and systematically reviewed. The basic principles of SERS and its application in gas sensing were comprehensively summarized. Subsequently, SERS substrates applied in gas sensing, including plasmonic metal nanoparticles (PMNPs), metal oxide semiconductor (MOS), metal-organic framework (MOF), MXene, etc. were systematically reviewed. In addition, the applications of SERS method used in the detection of toxic, hazardous gases and gaseous biomarkers were emphasized, such as environmental monitoring, human health and disease diagnosis, food safety, and national defense security. Finally, this paper also discussed the challenges and perspectives of SERS method, which will provide innovative ideas for design, construction and application of SERS sensors in the gas sensing.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"174 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142670990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Metal-organic frameworks (MOFs) and related other advanced porous materials for sequestration of heavy metal-based toxic oxo-pollutants from water","authors":"Writakshi Mandal, Sahel Fajal, Aamod V. Desai, Sujit K. Ghosh","doi":"10.1016/j.ccr.2024.216326","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216326","url":null,"abstract":"In recent years, environmental pollution and its effects have demanded attention from all over the world. In this context, water pollution has been regarded as one of the biggest threats to all living forms among all types of pollution in recent years, and things are forecasted to get worse if remediating steps are not adopted soon. Water recycling has gained importance in the twenty-first century as more areas of the world experience a water crisis. Given this, ground-water pollution by heavy metal-based toxic oxo-pollutants such as CrO₄²⁻, Cr₂O₇²⁻, AsO₄³⁻, SeO₃²⁻, SeO₄²⁻, TcO₄⁻, ReO₄⁻ etc. have been becoming rapidly growing global concerns and pose a major risk to both human health and the environment. These hazardous and persistent chemicals have been designated as priority pollutants by the US Environmental Protection Agency (EPA) due to their extreme toxicity following bioaccumulation. Therefore, it is crucial to get rid of them from contaminated water in an efficient manner. In this regard, now a days, Advanced Functional Porous Materials (AFPMs) such as metal-organic frameworks (MOFs), porous organic polymers (POPs), covalent organic frameworks (COFs), and porous hybrid composite have drawn significant attention from researchers looking into wastewater treatment owing to their advantages of tunable porosity, high surface area, and an abundance of functional groups over traditional adsorbents. This review provides an overview of the latest advancements in Advanced Functional Porous Materials, including MOFs and related porous materials, used as effective adsorbents to remove harmful oxoanions derived from heavy metals from contaminated water. Additionally, the review suggests practical solutions for ensuring the safety and cleanliness of drinking water. Furthermore, their adsorption mechanisms are discussed which may enable better designing of new MOFs/AFPMs-based adsorbents with superior performance for future study as well as for understanding the adsorption process between MOFs/AFPMs and heavy metal oxoanions contaminants. Lastly, in order to fully comprehend the developing prospects for the future, the potential and challenges of MOFs/AFPMs were thoroughly discussed.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"112 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142671098","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Black phosphorene: A versatile allotrope revolutionizing environmental, energy, and biomedical applications","authors":"Soumya Ranjan Mishra, Vishal Gadore, Vishwajit Chavda, Subhasree Panda, Saptarshi Roy, Pooja Sahoo, Lipi Pradhan, Harshita Rai, Shyam S. Pandey, Md. Ahmaruzzaman","doi":"10.1016/j.ccr.2024.216345","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216345","url":null,"abstract":"Black phosphorene (BP), an exciting allotrope of phosphorus, has sparked widespread attention owing to its unique physicochemical characteristics and numerous potentials in the environmental, energy, and biological sectors. The current review delves further into BP, concentrating on its layered structure, unusual features, and broad applications. Methods of synthesis of BP, such as liquid exfoliation, chemical vapor deposition, and mechanical exfoliation, are reviewed, and characterization procedures critical to ensuring the quality of BP are described. Its anisotropic mechanical, electrical, and optical properties are investigated using insights gained from its hexagonal lattice atomic structure and puckered layers. In environmental contexts, BP shows potential for water purification due to its strong adsorption and degradation capabilities against various contaminants, including dyes, medicines, pesticides, heavy metals, and organic compounds. Its potential in environmental sensing is also emphasized, notably for detecting gasses, heavy metals, and pollutants. Moving on to energy applications, BP is used in batteries, supercapacitors, and hydrogen generation, where its unique electrical and structural properties improve energy storage and conversion efficiency. BP improves medication delivery systems in biomedical applications by providing biocompatibility and customizable delivery capabilities. Furthermore, its biological imaging and diagnostics applications are reviewed, focusing on optical properties and contrast enhancement capabilities. Nonetheless, despite BP's significant potential, serious hurdles persist. Issues including stability under ambient settings, large-scale synthesis limits, and biocompatibility difficulties require resolution for more considerable practical use. The paper concludes by exploring future challenges and solutions to motivate readers. In summary, BP stands as a flexible material prepared to drive innovation in environmental, energy, and biological applications, although attaining its revolutionary influence will depend on overcoming present technological, scientific, and scaling limitations.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"22 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142670989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nanoparticles and quantum dots as emerging optical sensing platforms for Ni(II) detection: Recent approaches and perspectives","authors":"Sudhanshu Naithani, , Pooja Sharma, Samar Layek, Franck Thetiot, Tapas Goswami, Sushil Kumar","doi":"10.1016/j.ccr.2024.216331","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216331","url":null,"abstract":"Over the preceding years, nickel (Ni) and its compounds have been increasingly employed in various aspects of human social life, metallurgical/industrial manufactures, healthcare and chemical processes. Although Ni is considered as an essential trace element in biological system, excessive intake or metabolic deficiency of Ni²⁺ ions may cause detrimental health effects to the living organisms. Therefore, a facile and accurate detection of Ni²⁺, especially in environment and biological settings, is of huge significance. As an efficient detection method, assaying Ni²⁺ using optical (colorimetric and/or fluorogenic) sensors has experienced quite a vigorous growth period with large number of excellent researches. Nanomaterial-based optical sensors including metal nanoparticles (MNPs), quantum dots (QDs), and carbon dots (CDs) offer distinct advantages over conventional small-molecule organic and inorganic sensors. This study mainly provides an overview of the recent advancements and challenges related to the design strategies of various optical nanosensors to selectively detect Ni²⁺ ion. Emphasis has also been placed on comparing the sensing performance of various nanosensors along with exploring future perspectives.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"21 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665361","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biomimetic drug delivery for anticancer: Focusing on the relationship between drugs and biomimetic carriers","authors":"Tian Liu ,&nbsp;Qi Lu ,&nbsp;Hao Zhang ,&nbsp;Fudan Dong ,&nbsp;Zhonggui He ,&nbsp;Jin Sun ,&nbsp;Bingjun Sun","doi":"10.1016/j.ccr.2024.216328","DOIUrl":"10.1016/j.ccr.2024.216328","url":null,"abstract":"<div><div>Biomimetic carriers utilizing cells and cellular components revolutionize the field of anticancer drug delivery systems. Existing reviews in this field have predominantly approached biomimetic drug delivery systems by focusing on either the carrier or the payload. However, recognizing the intrinsic inseparability of the drug and the biomimetic carrier is imperative, as their mutual influences decisively shape the drug delivery system. This review delineated the recent progress in biomimetic carriers for antitumor therapeutics from a distinct perspective, concentrating on the relationship between the drug and the carrier. The relationship involves drug-loading mode, the loading position, and the mechanism of drug-release strategies. This review highlighted the crucial roles of drug loading morphologies and loading positions in enhancing the efficiency of carrier delivery and overcoming barriers to cancer treatment. Additionally, innovative strategies for controlled drug release from biomimetic carriers were summarized, and an extensive discussion on the future prospects and potential challenges in this field was provided.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216328"},"PeriodicalIF":20.3,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142642671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Machine learning for gas–solid interaction materials and devices","authors":"Peiyuan Liu ,&nbsp;Xiaoyang Zhu ,&nbsp;Xu Ran ,&nbsp;Hengchang Bi ,&nbsp;Xiao Huang ,&nbsp;Ning Gu","doi":"10.1016/j.ccr.2024.216329","DOIUrl":"10.1016/j.ccr.2024.216329","url":null,"abstract":"<div><div>Gas–solid interactions that involve various chemical and physical processes are important in various research fields such as gas storage and separation, catalysis, and gas sensing. The design and study of gas–interfacing materials and processes require thorough considerations on the structural, chemical and electrical properties at the gas–solid interfaces. However, due to the large number of materials available, conventional trial-and-error attempts take long development cycles and high costs. The recent advancement of machine learning (ML) for gas–solid interactions adequately addresses this challenge and provides new insights into materials design and property prediction, thus deserving a critical review and in-depth discussion. In this contribution, we reviewed the application of various ML methods in the development of materials and devices involving gas–solid interactions, focusing on the elaboration of the structure–property relationship established by ML models. We also discussed the potential opportunities and challenges for the future development in this field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216329"},"PeriodicalIF":20.3,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142637650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Preparation and functionalization of metal-organic frameworks, MOF-808s, and their application in adsorption","authors":"Gyudong Lee,&nbsp;Imteaz Ahmed,&nbsp;Md Abul Hossain,&nbsp;Hye Jin Lee,&nbsp;Sung Hwa Jhung","doi":"10.1016/j.ccr.2024.216325","DOIUrl":"10.1016/j.ccr.2024.216325","url":null,"abstract":"<div><div>Recently, metal-organic frameworks (MOFs) have attracted much attention because of their huge porosity, designable structure/pore, possible functionalization, and potential applications. Among them, a Zr, Hf, or Ce-benezenetricarboxylate named MOF-808 is very attractive thanks to its wide pore and good stability, together with the facile functionalization; therefore, the development of MOF-808 both in the synthesis and application is remarkable. However, to the best of our knowledge, there is no review paper on MOF-808. Here, we summarize the recent achievements in the preparation and modification/functionalization of MOF-808. Moreover, the application of MOF-808 in adsorption will also be analyzed. Finally, a future prospect will be given to readers who are interested in MOFs and relevant fields.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216325"},"PeriodicalIF":20.3,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142637651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Exploring Carbon-based Materials as a tailored platform for Suzuki–Miyaura Coupling Reaction: A Review","authors":"Sobia Jabeen ,&nbsp;Yaxi Li ,&nbsp;Xin Wu ,&nbsp;Yuanyuan Cheng ,&nbsp;Yunliang Liu ,&nbsp;Jingwen Yu ,&nbsp;Naiyun Liu ,&nbsp;Jun Huang ,&nbsp;Haitao Li","doi":"10.1016/j.ccr.2024.216323","DOIUrl":"10.1016/j.ccr.2024.216323","url":null,"abstract":"<div><div>Carbon-based materials, such as activated carbon, graphene, graphitic carbon nitride, carbon nanotubes, carbon nanofibers, and other carbonaceous derivatives, are being considered as a promising strategy for catalyst immobilization because of their exceptional characteristics, such as large surface area, tailored surface functionalities, and high chemical stability. Their use as catalyst support in Suzuki coupling reactions has made a significant contribution to enhancing catalytic durability, reusability, and reaction selectivity. Although the Suzuki Miyaura coupling reaction is an industrial established process, but significant research in academia is currently being conducted to enhance the substrate scope, developing more efficient catalysts, and improve its practicality. This review provides a thorough analysis of the application of carbon-based materials as catalyst supports in Suzuki coupling reactions between the years 2015–2023. The synthesis methodologies used to produce carbon-based support and the processes involved in the immobilization of Suzuki coupling catalysts onto the supports have been discussed, providing insight into the influence of these materials on catalytic performance, reaction kinetics, and product yields. This review will provide insightful information to scientists and industry professionals to assist in directing future avenues for catalyst design and advance the development of more environmentally friendly and effective catalytic processes.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216323"},"PeriodicalIF":20.3,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142637836","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent progress in nonlinear optical molybdenum/tungsten tellurites: Structures, crystal growth and characterizations","authors":"Jingfang Zhou ,&nbsp;Qian Wu ,&nbsp;Aimin Ji ,&nbsp;Zhen Jia ,&nbsp;Mingjun Xia","doi":"10.1016/j.ccr.2024.216332","DOIUrl":"10.1016/j.ccr.2024.216332","url":null,"abstract":"<div><div>The pursuit of second-order nonlinear optical (NLO) materials for mid-infrared (mid-IR, 3–5 μm) applications has been a significant research frontier due to their potential in optoelectronic technologies. In this review, we focus on noncentrosymmetric (NCS) molybdenum/tungsten tellurites incorporating <em>d</em>⁰ transition metal cations (Mo⁶⁺/W⁶⁺) and Te⁴⁺ cation with stereo-chemically active lone electron pair, which are prone to the second-order Jahn-Teller (SOJT) distortions. These compounds exhibit exceptional NLO effects, high optical transmittance in the 3–5 μm range, moderate birefringence, and ease of crystal growth in ambient conditions. Furthermore, they possess wider band gaps compared to conventional mid-IR NLO materials like metal phosphides and chalcogenides, enhancing their laser damage resistances. We categorize the notable NCS molybdenum/tungsten tellurites into nine series based on their cationic types, concentrating on ternary and quaternary systems. The review outlines their synthesis methods, crystal structures, growth techniques, and physical properties, with an emphasis on the relationship between SOJT-active units, NCS structures, and NLO performances. This work provides a clear perspective on the understanding of these materials and aims to accelerate the exploration of high-performance mid-IR NLO crystals to meet the increasing technological demands.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216332"},"PeriodicalIF":20.3,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142609824","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}