Coordination Chemistry Reviews最新文献

{"title":"Titanium-based metal-organic frameworks: Synthesis innovations and multifunctional applications","authors":"Ruiying Fu ,&nbsp;Lianchao Wang ,&nbsp;Kuaibing Wang ,&nbsp;Chao Li ,&nbsp;Mingjun Ouyang ,&nbsp;Cheng Zhang ,&nbsp;Hua Wu ,&nbsp;Qichun Zhang","doi":"10.1016/j.ccr.2025.216832","DOIUrl":"10.1016/j.ccr.2025.216832","url":null,"abstract":"<div><div>Metal-organic frameworks (MOFs) have attracted a lot of interests in many different sectors due to their remarkable structural tunability and variety of characteristics. Titanium-based metal–organic frameworks (Ti-MOFs), a prominent subset of MOFs, possess distinct advantages over other MOF-based materials owing to the unique electronic structure, redox activity, high stability, and coordination chemistry of titanium ions. Furthermore, these MOFs exhibit superior performance in photocatalysis, electrocatalysis, energy storage, and sensing, offering novel approaches and potential solutions to address the critical challenges in practical applications. This review provides a comprehensive summary of Ti-MOFs, focusing on their synthesis strategies, structural characteristics, and multifunctional applications in catalysis, energy storage, and sensing. We summarize the recent advancements in the field, highlighting key achievements and addressing the challenges faced in the synthesis and application of Ti-MOFs. This work aims to offer new insights and guidance for future research, emphasizing innovative approaches to enhance the performance of Ti-MOFs and expand their practical applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"541 ","pages":"Article 216832"},"PeriodicalIF":20.3,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144170195","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Small molecule photosensitizers: Paving the way for improved photodynamic therapy in dermatology","authors":"Tongyuan Wu ,&nbsp;Wei-Tao Dou ,&nbsp;Changyin Yang ,&nbsp;Leyong Zhou ,&nbsp;Feifei Wang ,&nbsp;Li He ,&nbsp;Xuhong Qian ,&nbsp;Lin Xu","doi":"10.1016/j.ccr.2025.216839","DOIUrl":"10.1016/j.ccr.2025.216839","url":null,"abstract":"<div><div>The skin, the largest and most exposed organ, plays a vital role in protecting internal organs and regulating metabolic processes. Dermatological diseases such as psoriasis, acne, and skin cancer significantly affect patients' quality of life and present considerable therapeutic challenges. Conventional treatments often suffer from limitations, including side effects, low efficacy, invasiveness, and high costs, underscoring the need for alternative, non-invasive therapies. Photodynamic therapy (PDT) has emerged as a promising, selective, and minimally damaging approach for treating skin diseases. PDT relies on photosensitizers that, upon light activation, generate reactive oxygen species (ROS) to selectively damage affected cells. However, PDT is constrained by issues such as poor solubility, low photostability, and inadequate tissue targeting. Recent advances in small molecule photosensitizers, including FDA-approved agents and those in clinical trials, have addressed these limitations by enhancing solubility, stability, and targeting capabilities. The integration of nanotechnology, particularly nanocarriers, further improves PDT efficacy by enhancing delivery and enabling deeper penetration of photosensitizers. This review examines recent developments in small molecule-based PDT, with a focus on photosensitizer modifications, their photophysical properties, and strategies to optimize solubility, stability, and targeting. The role of nanocarriers in enhancing delivery and the challenges in clinical application of PDT are also discussed.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"541 ","pages":"Article 216839"},"PeriodicalIF":20.3,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144178596","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent advances in nickel Catalysis for thermoplastic polyethylene elastomers: Synthesis strategies, properties, and future perspectives","authors":"Qaiser Mahmood ,&nbsp;Zexu Hu ,&nbsp;Geng Ren ,&nbsp;Wen-Hua Sun","doi":"10.1016/j.ccr.2025.216833","DOIUrl":"10.1016/j.ccr.2025.216833","url":null,"abstract":"<div><div>Polyolefins, particularly polyethylene (PE), rank among the most significantly applied synthetic polymers due to their exceptional chemical, thermal, and physical properties, which underpin their broad application spectrum. The characteristics of these polymers, such as flexibility, elasticity, and mechanical strength, are largely dictated by the polymerization process, catalyst selection, and polymer molecular architecture. Thermoplastic polyolefin elastomers (POEs) represent a notable subclass, prized for their ease of processing—allowing shaping, molding, and recycling—combined with their characteristic elastic properties. These materials are typically synthesized as branched or block copolymers of ethylene and α-olefins using early transition metal catalysts. The advent of late transition metal catalysts, particularly those based on nickel, has paved the way for a more direct approach to produce thermoplastic elastomers. These catalysts, with their distinctive chain-walking capability, obviate the need for comonomers, enabling the synthesis of branched polyethylene elastomers (PEEs) with the potential to replace traditional POEs. This review delves into the advancements in PEE synthesis via nickel catalysis, focusing on the design principles behind nickel catalysts that facilitate controlled branching. It critically evaluates the interplay between catalyst structure, reaction conditions, and polymer properties, emphasizing how these variables can be optimized to enhance elasticity, strength, and processability of PEE. Additionally, the review compares PEEs with conventional POEs, highlighting the superior balance of elasticity and thermoplasticity that makes PEEs advantageous for specific applications. Finally, the article addresses current challenges in fine-tuning the catalyst design, branching architectures and offers perspectives on future research directions in the development of catalyst design for high-performance PEEs.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"541 ","pages":"Article 216833"},"PeriodicalIF":20.3,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144178595","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Open hollow metal-organic frameworks: Synthesis strategies, applications and challenges","authors":"Wen-Da Zhang ,&nbsp;Han Zhao ,&nbsp;Yong Liu ,&nbsp;Zhi-Guo Gu","doi":"10.1016/j.ccr.2025.216829","DOIUrl":"10.1016/j.ccr.2025.216829","url":null,"abstract":"<div><div>Open hollow metal-organic frameworks (MOFs) represent an emerging class of porous materials featured by interconnected voids, accessible pore channels, and surface openings. These architectures combine the advantages of traditional hollow structures (e.g., enhanced mass transfer, high surface-to-volume ratios) with the dynamic functionality of open frameworks, enabling unprecedented control over guest molecule diffusion and active site exposure. This review summarizes recent advances in synthetic strategies for open hollow MOFs, including hard/soft templating, self-templating, Marangoni effect-driven crystallization, competitive coordination, and selective chemical etching. Furthermore, we review the cutting-edge applications of open hollow MOFs-based materials in gas separation, pollutant adsorption, catalysis, and electrochemical energy storage. Finally, we outline future directions for rational design and large-scale production, addressing current limitations in robustness and application-specific optimization. This work provides a comprehensive reference for developing next-generation open hollow MOFs with tailored functionalities.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"541 ","pages":"Article 216829"},"PeriodicalIF":20.3,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144170255","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"First-row transition metal complexes of naturally occurring anticancer chelators for cancer treatment","authors":"Arpan Bera ,&nbsp;Tukki Sarkar ,&nbsp;Aarti Upadhyay ,&nbsp;Akhtar Hussain","doi":"10.1016/j.ccr.2025.216847","DOIUrl":"10.1016/j.ccr.2025.216847","url":null,"abstract":"<div><div>Ligands in a metal complex are crucial in determining the therapeutic effectiveness of the complex. This activity modulation is multifaceted, influenced by factors such as enhanced lipophilicity, alterations in redox and spectroscopic properties, cellular uptake, solubility, and synergistic enhancement of cytotoxicity. Complexes of first-row bioessential transition metals from vanadium (V) to copper (Cu), characterized by their variable oxidation states, intriguing redox properties, and bioessential nature, present promising avenues for developing next-generation metal complexes with organic ligands possessing intrinsic anticancer properties, particularly those derived from natural sources. This review article explores recent and up-to-date advancements in first-row transition metal complexes (V to Zn) incorporating five distinct types of naturally occurring anticancer ligands endowed with chelating properties, namely, curcumin, flavonoids, coumarin, naphthoquinone, and hypocrellins. Curcumin inherently contains an O,O-donor bidentate coordination site, while natural derivatives from the other four classes of compounds were selected for their intrinsic bidentate O,O-donor sites. These coordination sites typically consist of either two oxygen atoms from two adjacent hydroxyl (OH) groups (coumarin) or one oxygen atom from a carbonyl (C=O) group and another from a hydroxyl (OH) group (for flavonoids, naphthoquinone, and hypocrellins), ensuring sufficient thermodynamic stability of the chelate rings formed upon complexation. Emphasizing findings from our laboratory and other investigators in this burgeoning field, we explore the potential of these complexes in anticancer applications. Additionally, we explore studies involving first-row transition metal complexes coupled with naturally occurring photoactive ligands, serving as potent photosensitizers for cancer phototherapy. We conclude by addressing the prospects and challenges in this vital research area. We believe this timely compilation will benefit researchers by providing insights into recent and up-to-date findings and fostering further advancements in this emerging area.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"541 ","pages":"Article 216847"},"PeriodicalIF":20.3,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144170254","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nanoparticle-integrated hydrogels as versatile colorimetric sensors","authors":"Hyewon Song ,&nbsp;Do Hyeon Jung ,&nbsp;Yejin Cho ,&nbsp;Hui Hun Cho ,&nbsp;Vasily G. Panferov ,&nbsp;Juewen Liu ,&nbsp;Jun Hyuk Heo ,&nbsp;Jung Heon Lee","doi":"10.1016/j.ccr.2025.216835","DOIUrl":"10.1016/j.ccr.2025.216835","url":null,"abstract":"<div><div>Nanoparticles have been extensively employed as probes in colorimetric sensors due to their ease of surface functionalization and combined optical and catalytic properties. However, their intrinsic tendency to aggregate impairs the unique plasmonic properties and diminishes catalytic activity associated with their nanoscale size, potentially compromising long-term performance. To address these limitations, recent studies have focused on integrating nanoparticles into hydrogels, thereby limiting nanoparticle diffusion to overcome challenges in colorimetric sensing applications. In particular, nanoparticle-integrated hydrogels can preserve the colloidal stability of nanoparticles, ensuring practical applicability that is unattainable with free nanoparticles for on-site scenarios. This article comprehensively reviews recent advances in nanoparticle-integrated hydrogels for colorimetric sensing applications, with particular emphasis on their abilities to detect biological and environmental targets. The unique physicochemical properties of these hydrogels provide ideal platforms for deploying various polymeric and metallic nanoparticles that are highly sensitive to environmental changes and can visually indicate the presence of specific targets. Hydrogels also enhance sensor performance owing to their high-water contents, concentration effect, and distinctive swelling properties, which amplify sensor responses to target molecules. In the end, this review article outlines promising avenues for future research in this dynamic field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"541 ","pages":"Article 216835"},"PeriodicalIF":20.3,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144170198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Flexible metal-organic frameworks for hydrocarbon separations","authors":"Feng Xie ,&nbsp;Fu-An Guo ,&nbsp;Hao Wang ,&nbsp;Jing Li","doi":"10.1016/j.ccr.2025.216831","DOIUrl":"10.1016/j.ccr.2025.216831","url":null,"abstract":"<div><div>The separation of hydrocarbons is crucial for producing diverse raw materials in the petrochemical industry. Nevertheless, the structural and chemical similarities among these hydrocarbons require substantial energy input and poses significant challenges. Compared to conventional energy-intensive techniques such as heat-driven distillations, adsorptive separation using porous solids offers a promising alternative to reduce energy consumption while enhancing efficiency. Among current solid adsorbents, flexible metal-organic frameworks (FMOFs)-a dynamic subset of MOFs-have emerged as unparalleled crystalline porous materials for highly selective adsorption-based hydrocarbon separation and purification. By leveraging the adsorption-induced structural flexibility of FMOFs, selective adsorption of specific hydrocarbons can be achieved. In recent years, we and others have demonstrated the efficient separation of industrially relevant hydrocarbon mixtures using a diverse array of FMOFs. Their unique dynamic structures enable simultaneous high adsorption capacity, remarkable selectivity, and fast adsorption kinetics, overcoming the trade-offs faced by traditional adsorbents and rigid MOFs (RMOFs). In this <strong>Review</strong>, we highlight the recent advancements in utilizing FMOFs as adsorbents for hydrocarbons separation and purification, including both gaseous (C1-C4) and liquid (C6-C8) hydrocarbons, with a focus on the interplay between their dynamic structures and unique adsorption properties. We explore their intriguing and predominant temperature- and adsorbate-dependent adsorption behavior and the corresponding molecular-sieving separation mechanisms. Lastly, we address key challenges and propose future research directions to enhance their performance for potential petrochemical applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"541 ","pages":"Article 216831"},"PeriodicalIF":20.3,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144170200","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Engineering high-performance BiVO4 homo- and heterojunction Photoanodes for solar-driven Photoelectrochemical water splitting applications","authors":"Inn Jynn Teh ,&nbsp;Lutfi Kurnianditia Putri ,&nbsp;Chong Siang Yaw ,&nbsp;Wen Cai Ng ,&nbsp;Meng Nan Chong ,&nbsp;Siang-Piao Chai","doi":"10.1016/j.ccr.2025.216773","DOIUrl":"10.1016/j.ccr.2025.216773","url":null,"abstract":"<div><div>Green hydrogen has secured its foothold as the most promising fossil fuel-alternative, with over half a century of intensive research focusing on the development of photoelectrochemical (PEC) water splitting system. The higher overpotential required for an oxygen evolution reaction necessitates the development of a highly performing photoanode as compared to photocathode, as it reduces the externally applied bias needed for a water splitting reaction. Bismuth vanadate (BiVO₄) has emerged as an immensely potential candidate, due to its favorable bandgap, earth abundance and good chemical stability. However, the rapid charge carrier recombination and sluggish oxygen evolution reaction have severely undermined BiVO₄'s water splitting performance. To fully unleash its potential, modifications are necessary, with the formation of homo- and heterojunctions showing significant contributions in enhancing PEC water oxidation. This review comprehensively discusses and highlights the strategies for constructing homo- and heterojunction of BiVO₄, as well as the insights in boosting the solar water splitting performance. The review on the formation of homojunction is classified into doping, facet and morphology-engineered homojunction, while the formation of heterojunction is classified based on the functional properties, <em>n</em>-<em>n</em>, <em>p</em>-<em>n</em> and <em>Z</em>-scheme heterojunction. The development of an unbiased solar-driven PEC water splitting system based on heterostructured BiVO₄ is also thoroughly discussed, along with perspective on current and future research related to PEC water oxidation. This review aims to provide an extensive coverage of research on engineering homo- and heterojunctions for BiVO₄-based photoanode, which will also serve as a reference for other semiconductors in enhancing their various PEC applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"541 ","pages":"Article 216773"},"PeriodicalIF":20.3,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144170256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Responsive biomaterials for tumor sensing and therapy","authors":"Ge Wang ,&nbsp;HuiFeng Chen ,&nbsp;Yafu Wang ,&nbsp;Na Chen ,&nbsp;Shikuo Fu ,&nbsp;Xuexia Chen ,&nbsp;Xiaoli Wang ,&nbsp;Tianjun Ni ,&nbsp;Kui Wang ,&nbsp;Hua Zhang","doi":"10.1016/j.ccr.2025.216821","DOIUrl":"10.1016/j.ccr.2025.216821","url":null,"abstract":"<div><div>An increasing number of smart biomaterials have garnered significant attention in biomedical applications owing to their self-repair capabilities, adaptability to complex environments, and responsiveness to external stimuli. These properties enable these materials to exhibit on-demand intelligence in intricate biological settings. Specifically, for smart biomaterials that autonomously respond to the specific physicochemical properties of the tumor microenvironment (TME) as well as bioactive molecules or functional biomacromolecules within it, a systematic summary of their inherent structural advantages and the unique characteristics of the TME is urgently needed. This review focuses on responsive biomaterials, encompassing inorganic, organic, and organic-inorganic hybrid biomaterials. By analyzing their surface-active sites, functional groups, molecular configurations, and other relevant characteristics, this review aims to elucidate the structure-activity relationship between the structural features of responsive biomaterials, their chemical reactivity, and their adaptive responsiveness to the complex TME. Additionally, intelligent design and optimization strategies are also discussed to enhance the practicality of responsive biomaterials in complex biological environments. We anticipate that this review will assist researchers in gaining a deeper understanding of responsive biomaterials and facilitate the development of more effective and advanced multifunctional tools for tumor bioimaging, biosensing, and disease therapy.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"541 ","pages":"Article 216821"},"PeriodicalIF":20.3,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144170196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Catalytic Nanozyme: Unlocking new horizons in articular cartilage degeneration treatment","authors":"Ke Ma,&nbsp;Ting Liu,&nbsp;Cong-Zheng Zhou,&nbsp;Yan-Li Li,&nbsp;Xue-Gang Yu,&nbsp;Sheng-Lin Qiao,&nbsp;Ke-Zheng Chen","doi":"10.1016/j.ccr.2025.216845","DOIUrl":"10.1016/j.ccr.2025.216845","url":null,"abstract":"<div><div>Articular cartilage diseases rank among the most prevalent and debilitating health conditions worldwide, substantially impairing patients' quality of life and placing significant burdens on healthcare systems. Existing therapeutic strategies primarily focus on alleviating symptoms and decelerating disease progression; however, their efficacy is often constrained and may be associated with substantial adverse effects. Owing to their unique catalytic properties and biocompatibility, nanozymes have emerged as promising therapeutic agents for articular cartilage diseases. They can mitigate joint inflammation via antioxidant and anti-inflammatory pathways while promoting cartilage regeneration and repair, thereby providing innovative treatment opportunities. Recent years have witnessed the design and application of diverse nanozymes for articular cartilage disease management. This review provides a comprehensive overview of the progress in nanozyme-based therapies for articular cartilage diseases. It begins by examining the pervasive impact of these diseases, addresses the constraints of current therapeutic approaches, and highlights advances in nanozyme research. Next, it discusses the rational design and synthesis of nanozymes through techniques such as density functional theory, machine learning, biomimetic design, and chemical engineering. The catalytic mechanisms through which nanozymes exert therapeutic effects are also briefly elucidated. Subsequently, attention is directed to the inflammatory microenvironment in articular cartilage, which is central to both the onset and progression of these diseases. The review then summarizes the latest findings on nanozyme applications in articular cartilage disease treatment and describes the clinical challenges involving nanozyme-based interventions. Finally, it identifies current challenges and explores future prospects for integrating nanozymes into therapeutic strategies against articular cartilage diseases.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"541 ","pages":"Article 216845"},"PeriodicalIF":20.3,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144170197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}