Coordination Chemistry Reviews最新文献

{"title":"Peripheral effect promotes single-atom catalysis","authors":"Yicong Chai ,&nbsp;Fenfei Wei ,&nbsp;Liru Cao ,&nbsp;Xiaodong Wang ,&nbsp;Sen Lin ,&nbsp;Jian Lin ,&nbsp;Tao Zhang","doi":"10.1016/j.ccr.2025.216649","DOIUrl":"10.1016/j.ccr.2025.216649","url":null,"abstract":"<div><div>Single-atom catalyst (SAC) attracts extensive interest in heterogeneous catalysis. Although single metal atoms (M₁) can serve as the dominant active site, growing evidences reveal that the directly coordinated heteroatoms usually determine the geometric and electronic structure of single-atom center. However, the impact of the peripheral environment, not bonded to M₁, is in its infancy while plays a significant role. In this review, we survey the recent progresses of optimizing SAC performance through modulation of the peripheral species, either by influencing the main M₁ center or serving as additional active site. Firstly, we introduce the basic principles of single-atom catalysis and the role of the peripheral environment in modifying catalytic behaviors. It is proposed that the single-atom site constitutes an active domain with the microenvironment, and the regulation of peripheral species within this active domain can effectively improve the catalytic performance. Subsequently, the design strategies and characterizations of peripheral environment are summarized. The peripheral effects on thermal, electro-, photo-catalysis and the underlying reaction mechanisms are then elucidated. Finally, the challenges and future prospects regarding the involvement of peripheral species in SAC are put forward. This review underscores the significance of the peripheral environment in SAC, which can provide important implications for the enhancement of catalysis through peripheral dopant engineering.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"536 ","pages":"Article 216649"},"PeriodicalIF":20.3,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143768398","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships","authors":"Junben Huang,&nbsp;Chenglong Zhang,&nbsp;Siying Chen,&nbsp;Ailijiang Abudurusuli","doi":"10.1016/j.ccr.2025.216632","DOIUrl":"10.1016/j.ccr.2025.216632","url":null,"abstract":"&lt;div&gt;&lt;div&gt;Nonlinear optical (NLO) materials have attracted widespread attention since they can greatly expand the spectral range of the laser output through second harmonic generation (SHG). Recently, employing advantageous structural templates to design and fabricate NLO materials has promoted their rapid development, compared with the traditional “trial-and-error” methodology. KBe&lt;sub&gt;2&lt;/sub&gt;BO&lt;sub&gt;3&lt;/sub&gt;F&lt;sub&gt;2&lt;/sub&gt;, an outstanding usually can be as a good structure prototype for oriented exploring NLO materials. In the crystal structure of KBe&lt;sub&gt;2&lt;/sub&gt;BO&lt;sub&gt;3&lt;/sub&gt;F&lt;sub&gt;2&lt;/sub&gt;, the π-conjugated planar triangle anionic group [BO&lt;sub&gt;3&lt;/sub&gt;]&lt;sup&gt;3−&lt;/sup&gt; and tetrahedra [BeO&lt;sub&gt;3&lt;/sub&gt;F]&lt;sup&gt;5−&lt;/sup&gt; can be replaced by other π-conjugated planar groups and tetrahedra/polyhedra to form KBe&lt;sub&gt;2&lt;/sub&gt;BO&lt;sub&gt;3&lt;/sub&gt;F&lt;sub&gt;2&lt;/sub&gt;-like structures, respectively. After the literature survey, the π-conjugated planar groups are [BO&lt;sub&gt;3&lt;/sub&gt;]&lt;sup&gt;3−&lt;/sup&gt; itself or [BO&lt;sub&gt;2&lt;/sub&gt;]&lt;sup&gt;−&lt;/sup&gt;, [B&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt;]&lt;sup&gt;4−&lt;/sup&gt;, [B&lt;sub&gt;3&lt;/sub&gt;O&lt;sub&gt;6&lt;/sub&gt;]&lt;sup&gt;3−&lt;/sup&gt;, [CO&lt;sub&gt;3&lt;/sub&gt;]&lt;sup&gt;2−&lt;/sup&gt;, [BeO&lt;sub&gt;3&lt;/sub&gt;]&lt;sup&gt;4−&lt;/sup&gt;, [BeN&lt;sub&gt;3&lt;/sub&gt;]&lt;sup&gt;7−&lt;/sup&gt;, [BS&lt;sub&gt;3&lt;/sub&gt;]&lt;sup&gt;3−&lt;/sup&gt;, [C(NH&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;3&lt;/sub&gt;]&lt;sup&gt;+&lt;/sup&gt;, while the tetrahedra include [BeO&lt;sub&gt;3&lt;/sub&gt;F]&lt;sup&gt;5−&lt;/sup&gt; itself or [MO&lt;sub&gt;4&lt;/sub&gt;]&lt;sup&gt;&lt;em&gt;n&lt;/em&gt;−&lt;/sup&gt; (M = B, P, S, Si, Li, Be, Al, Ga, Zn, Cl; &lt;em&gt;n&lt;/em&gt; = 1, 2, 3, 4, 5, 6, 7), [SiN&lt;sub&gt;4&lt;/sub&gt;]&lt;sup&gt;8−&lt;/sup&gt;, [BO&lt;sub&gt;3&lt;/sub&gt;T]&lt;sup&gt;4−&lt;/sup&gt; (T = F, (OH)), [MO&lt;sub&gt;2&lt;/sub&gt;F&lt;sub&gt;2&lt;/sub&gt;]&lt;sup&gt;&lt;em&gt;n&lt;/em&gt;−&lt;/sup&gt; (M = P, Si; &lt;em&gt;n&lt;/em&gt; = 1, 2), [MO&lt;sub&gt;3&lt;/sub&gt;F]&lt;sup&gt;&lt;em&gt;n&lt;/em&gt;−&lt;/sup&gt; (M = Li, S, Y; &lt;em&gt;n&lt;/em&gt; = 1, 4, 6), [BeO&lt;sub&gt;3&lt;/sub&gt;(OH)]&lt;sup&gt;5−&lt;/sup&gt;, [AlO&lt;sub&gt;3&lt;/sub&gt;X]&lt;sup&gt;4−&lt;/sup&gt; (X = F, Cl), [ZnO&lt;sub&gt;2&lt;/sub&gt;(OH)&lt;sub&gt;2&lt;/sub&gt;]&lt;sup&gt;4−&lt;/sup&gt;, [ZnO&lt;sub&gt;3&lt;/sub&gt;X]&lt;sup&gt;5−&lt;/sup&gt; (X = (OH), F, Cl, Br), and [ZnS&lt;sub&gt;3&lt;/sub&gt;Br]&lt;sup&gt;5−&lt;/sup&gt;, as well as polyhedra [C&lt;sub&gt;3&lt;/sub&gt;O&lt;sub&gt;4&lt;/sub&gt;H&lt;sub&gt;2&lt;/sub&gt;]&lt;sup&gt;2−&lt;/sup&gt;, [C&lt;sub&gt;3&lt;/sub&gt;H&lt;sub&gt;6&lt;/sub&gt;NO&lt;sub&gt;2&lt;/sub&gt;]&lt;sup&gt;−&lt;/sup&gt;, [AlO&lt;sub&gt;3&lt;/sub&gt;F&lt;sub&gt;2&lt;/sub&gt;]&lt;sup&gt;5−&lt;/sup&gt;, [MgO&lt;sub&gt;4&lt;/sub&gt;F&lt;sub&gt;2&lt;/sub&gt;]&lt;sup&gt;8−&lt;/sup&gt;, [A&lt;sup&gt;II&lt;/sup&gt;O&lt;sub&gt;6&lt;/sub&gt;]&lt;sup&gt;10−&lt;/sup&gt; (A&lt;sup&gt;II&lt;/sup&gt; = Mg, Ca), [LaO&lt;sub&gt;8&lt;/sub&gt;]&lt;sup&gt;13−&lt;/sup&gt;, [LaO&lt;sub&gt;9&lt;/sub&gt;]&lt;sup&gt;15−&lt;/sup&gt;, [PbO&lt;sub&gt;3&lt;/sub&gt;X&lt;sub&gt;3&lt;/sub&gt;]&lt;sup&gt;7−&lt;/sup&gt; (X = Cl, Br, I), and [IO&lt;sub&gt;3&lt;/sub&gt;]&lt;sup&gt;−&lt;/sup&gt;. Accordingly, about 107 related compounds were collected: 37 borate-halides, 17 fluorooxoborates, 16 borates, 13 γ-Be&lt;sub&gt;2&lt;/sub&gt;BO&lt;sub&gt;3&lt;/sub&gt;F analogues, seven hydroxyborates, four borosulfates, three borophosphates, two guanidiniums, two borosilicates, and one malonate, hydroxycarbonate, carbonate-halide, borate-iodate, sulfate, silicate. According to their relationships between crystal structures and NLO properties: (i) KBe&lt;sub&gt;2&lt;/sub&gt;BO&lt;sub&gt;3&lt;/sub&gt;F&lt;sub&gt;2&lt;/sub&gt;-like materials that can achieve deep-ultraviolet NLO behavior all contain π-conjugated planar groups ([BO&lt;sub&gt;3&lt;/sub&gt;]&lt;sup&gt;3−&lt;/sup&gt;, [CO&lt;sub&gt;3&lt;/sub&gt;]&lt;sup&gt;2−","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"536 ","pages":"Article 216632"},"PeriodicalIF":20.3,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143768396","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Toward a molecular-scale picture of water electrolysis: mechanistic insights, fundamental kinetics and electrocatalyst dynamic evolution","authors":"Man Chen,&nbsp;Yingju Yang,&nbsp;Yuandong Ding,&nbsp;Jing Liu","doi":"10.1016/j.ccr.2025.216651","DOIUrl":"10.1016/j.ccr.2025.216651","url":null,"abstract":"<div><div>Scaling up water electrolysis is hindered by the need of low-cost, high-activity, and long-durability electrocatalysts for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Although reviews published previously focus exclusively on the electrocatalysts development, there is a lack of review focusing on the microcosmic knowledge of water electrolysis. The rational design of water-splitting electrocatalysts must be grounded in a fundamental molecular-level understanding of both HER and OER. Herein, we provide a comprehensive review of recent advances in molecular-level understanding of water electrolysis and identify the critical challenges throughout the entire process of splitting water to hydrogen, including reaction mechanism, active sites, reaction intermediates, fundamental kinetics, electric double layer, and dynamic evolution of electrocatalysts. Unusual active sites and reaction intermediates detected experimentally are summarized and <em>in situ</em> techniques are highlighted due to their irreplaceable role in unrevealing the dynamic process at the molecular level. We also delve into the kinetic challenges associated with these electrochemical reactions, particularly the sluggish HER kinetics in alkaline media and the identification of rate-determining step of OER. Moreover, the effects of electric double layer and dynamic surface evolution on catalytic performance are discussed to highlight the importance of <em>in situ</em> monitoring the electrolyte/electrode interface. By integrating insights from experimental and theoretical studies, this review aims to offer valuable guidance for the design and development of efficient and durable water-splitting electrocatalysts. The state-of-the-art electrocatalysts and electrolyzers are also summarized to bridge the gap between the research advances and industrial demands. Finally, we provide the outstanding issues and current challenges for obtaining a more complete molecular-level picture of water electrolysis.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"536 ","pages":"Article 216651"},"PeriodicalIF":20.3,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143768397","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Lanthanide-doped nanoprobes for microRNA detection","authors":"Yunya Liu ,&nbsp;Yin Huang ,&nbsp;Yijun Luo ,&nbsp;Yuxia Luo ,&nbsp;Lijun Jiang ,&nbsp;David Gallego-Ortega ,&nbsp;Yuen Yee Cheng ,&nbsp;Philip A. Gale ,&nbsp;Guochen Bao","doi":"10.1016/j.ccr.2025.216644","DOIUrl":"10.1016/j.ccr.2025.216644","url":null,"abstract":"<div><div>MicroRNAs (miRNAs), a sub-class of non-coding RNAs approximately 20–24 nucleotides in length, have emerged as valuable biomarkers for disease diagnosis and prognosis, and potential forensic evidence. Advances in lanthanide-doped nanoprobes offer great promise for sensitive miRNA detection due to their high photostability, long luminescence lifetimes, and large anti-Stokes shifts. This review provides a comprehensive overview of strategies for developing lanthanide-doped nanoparticle (LnNP)-based biosensors for miRNA detection. We begin by introducing miRNAs as biomarkers in disease diagnostics and discussing synthesis and surface modification approaches for upconversion nanoprobes. We then highlight various detection strategies using lanthanide-doped nanoprobes—including clustered regularly interspaced short palindromic repeats (CRISPR)-based, sandwich structure-based, energy transfer-based, and inductively coupled plasma (ICP)-based detection. Finally, we address current challenges, potential applications and future perspectives for LnNP-based biosensors and their potential for clinical translation.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"536 ","pages":"Article 216644"},"PeriodicalIF":20.3,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143759830","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Cu-based metal oxide catalysts for NH₃-SCR of NOx: From fundamentals to mechanistic insights","authors":"Sher Ali ,&nbsp;Sharafat Ali ,&nbsp;Ahmed Ismail ,&nbsp;Muhammad Zahid ,&nbsp;Fazal Raziq ,&nbsp;Liang Qiao","doi":"10.1016/j.ccr.2025.216676","DOIUrl":"10.1016/j.ccr.2025.216676","url":null,"abstract":"<div><div>In today's world, emissions from automobile exhaust and industrial chimneys are the major contributors to atmospheric nitrogen oxides (NO_<em>x</em>). NO_<em>x</em> has detrimental effects on both plants and animals and can cause various diseases. Ammonia (NH₃)-based selective catalytic reduction (SCR) is a highly effective method for controlling and mitigating NO_<em>x</em> emissions. Cu-based oxides are extensively utilized in NH₃-SCR processes due to their widespread availability, cost-effectiveness, and outstanding redox capabilities, making them a preferred choice among MO catalysts. The presence of copper in both Cu²⁺ and Cu⁺ oxidation states offers favorable potential for combination with other transition elements, enhancing catalytic performance. In addition, the synthesis methods use in the SCR process, regeneration, and disposal of Cu-oxide-based catalysts are more cost-effective and environment friendly than those of precious metal oxide SCR catalysts, making Cu-based technology a more sustainable and economical choice. While numerous review papers have explored the role of copper in zeolite-based catalysts for NO_<em>x</em> reduction but concise reports focusing on Cu in MO-based catalysts for SCR remain scarce. Therefore, in this work, we aim to review the synthesis methods, reaction mechanisms, structure-activity relationships, economic feasibility, environmental impact assessment and durability of Cu-based oxide catalysts in NH₃-SCR, particularly against water, alkali and alkaline earth metals, SO₂, and other relevant factors.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"536 ","pages":"Article 216676"},"PeriodicalIF":20.3,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143759831","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Single-atom catalysts: Enzyme-mimicking coordinations, platform designs, and biomedical applications","authors":"Xuan Thien Le ,&nbsp;Yu Seok Youn","doi":"10.1016/j.ccr.2025.216642","DOIUrl":"10.1016/j.ccr.2025.216642","url":null,"abstract":"<div><div>Recent advancements in nanotechnology have resulted in the appearance of single-atom catalysts (SACs), along with a novel class of materials with the potential to mimic the performance of natural enzymes for a wide range of biological applications. Characterized by atomically dispersed metal sites anchored on appropriate substrates, SACs render unique electronic configurations and maximized metal atom utilization. These properties enhance catalytic activity, selectivity, and stability, which makes SACs more efficient than normal nanocatalysts. These intriguing features allow SACs to address key challenges in biomedicine, including enzyme-like activity for biosensing, targeted therapy, and disease prevention. SACs have shown significant potential in cancer treatment, oxidative stress reduction, antimicrobial therapies, real-time biosensing, and bioimaging, closing the disparity gap between nanozymes and natural enzymes. Furthermore, SAC platforms are versatile, allowing surface modifications and the integration of other materials to improve biocompatibility, catalytic performance, and multi-functionality. This study reviews progress in SAC synthesis, coordination environments, and platform designs, proving their transformative potential in biomedicine. In addition, the main challenges of SACs for clinical use, such as improving substrate selectivity and biocompatibility or ensuring long-term stability, are also considered. When these limitations are addressed, SACs promise to revolutionize therapeutic strategies and allow new solutions for diagnostic innovations, precision medicine and disease management. This work contributes to the growing understanding of SACs and their future applications in catalytic biomedicine.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"536 ","pages":"Article 216642"},"PeriodicalIF":20.3,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143759829","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent progress of advanced Nanozymes for targeted oncotherapy and synergistic immunotherapy","authors":"Wenying Zhang ,&nbsp;Meifang Wang ,&nbsp;Ping’an Ma ,&nbsp;Jun Lin","doi":"10.1016/j.ccr.2025.216674","DOIUrl":"10.1016/j.ccr.2025.216674","url":null,"abstract":"<div><div>Nanozymes are a type of simulated artificial enzymes that possess both the unique properties of nanomaterials and enzyme functions, making them promising alternatives to natural enzymes in the biomedical field. In recent years, with the cross-fusion of nanomedicine and nanocatalysis, significant efforts have been made to regulate the nanozymes further to realize specific antitumor therapy and simultaneously minimize their side effects. In this review, we introduced the latest advances in the intelligent regulation of nanozymes over the past three years, focusing on their activity and specificity. Through machine learning, bionics and chemical design, the catalytic properties of nanozymes can be reasonably predicted and designed, enabling their application in various scenarios. A brief description was also provided on improving their specificity and biosafety through surface modification, multi-stimulation, and tumorous in-situ synthesis. Furthermore, strategies for augmenting antitumor immunity based on nanozymes were well summarized. Finally, main challenges and prospects were proposed for the further biomedical development of nanozymes, including precise manipulation of catalytic route on demand at the molecular level, the relationship between nanozymes and cellular metabolism, the development of more types of nanozyme activities and the challenges faced in clinical translation.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"536 ","pages":"Article 216674"},"PeriodicalIF":20.3,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143759832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nanoarchitectured bismuth-based structures for diverse applications: Recent advancements and latest breakthroughs","authors":"Ruo-Yin Meng ,&nbsp;Ying-Tong Ye ,&nbsp;Hong-Ying Xia ,&nbsp;Shi-Bin Wang ,&nbsp;Ai-Zheng Chen ,&nbsp;Ranjith Kumar Kankala","doi":"10.1016/j.ccr.2025.216645","DOIUrl":"10.1016/j.ccr.2025.216645","url":null,"abstract":"<div><div>Among various inorganics, bismuth (Bi)-based nanomaterials have gained vast interest due to their high X-ray absorption coefficient, diamagnetism, and metal-semiconductor properties, which are of specific interest in metallurgy, engineering, and medicine-related fields. Although not as popular as copper, iron, and platinum in terms of availability and features, this high atomic number (Z-value)-based Bi element offers similar properties to gold along with a low synthesis cost, facile operation, and unique properties with broad prospects, conquering a significant position among these inorganics. Despite the success in fabricating various Bi-based nanomaterials by altering their structure and shape, these materials suffer from some shortcomings, such as deprived conductivity and catalytic properties, as well as accumulation-induced safety risks and environmental pollution due to poor degradability, impacting aquatic organisms and human health. In this article, a comprehensive view of diverse Bi-based materials for various applications is provided, presenting recent advancements and the latest breakthroughs. Initially, we present the chemistry and configuration of Bi, emphasizing the feasibility for fabricating various composites. Then, we introduce various commonly used fabrication strategies of Bi-based composites, highlighting the factors affecting their morphological properties. Further, various major classes of Bi-based materials are presented, exploring the influence of structural forms and their roles in various applications. Finally, we synopsize the article with interesting perspectives, presenting challenges and opportunities that still exist for these Bi-based materials.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"536 ","pages":"Article 216645"},"PeriodicalIF":20.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143746777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Molecular weight enlargement of homogeneous catalysts for enhanced recovery via organic solvent nanofiltration: A critical review","authors":"Vitaliy Masliy,&nbsp;Sophie M. Guillaume,&nbsp;Cédric Fischmeister,&nbsp;Jean-François Carpentier","doi":"10.1016/j.ccr.2025.216640","DOIUrl":"10.1016/j.ccr.2025.216640","url":null,"abstract":"<div><div>Organic solvent nanofiltration (OSN), also known as Solvent resistant nanofiltration (SRNF), is an emerging technology for separating molecules in organic solvents, offering significant advantages over other separation techniques, including low solid waste generation and high energy efficiency. One of the critical factors that influence the performance of OSN membranes is the molecular weight of the catalysts used. However, over the last decade, it became evident that other physico-chemical factors, such as catalyst flexibility and polarity also affect the separation efficiency. This review critically examines the recent advances in the molecular weight enlargement of catalysts, typically through the tuning of ancillary ligands that coordinate onto the active metal centers, focusing on how these modifications affect the overall separation effectiveness in OSN. Key strategies for molecular weight enlargement, such as addition of bulky substituents, dendrimer formation, and use of macromolecular ligands, are analyzed in terms of their impact on catalyst retention and rejection efficiency. By providing a comprehensive overview of the current state of research, this review aims to guide future developments in the field and highlight the critical areas where further investigation is needed to optimize catalyst design for OSN applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"536 ","pages":"Article 216640"},"PeriodicalIF":20.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143746283","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Special issue for 9th asian conference on coordination chemistry","authors":"David Harding, Masahiro Yamashita, Thanthapatra Bunchuay, Pannee Leeladee","doi":"10.1016/j.ccr.2025.216665","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.216665","url":null,"abstract":"<h2>Section snippets</h2><section><section><h2>Declaration of competing interest</h2>The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.</section></section>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"34 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143758208","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}