Coordination Chemistry Reviews最新文献

In-situ characterization technologies and theoretical calculations in carbon dioxide reduction: In-depth understanding of reaction mechanisms and rational design of electrocatalysts

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-28 DOI: 10.1016/j.ccr.2025.216541

Rutao Wang, Xiaokun Yang, Jianpeng Zhang, Shilong Wen, Liting Yan, Xuebo Zhao, Enyan Guo

{"title":"In-situ characterization technologies and theoretical calculations in carbon dioxide reduction: In-depth understanding of reaction mechanisms and rational design of electrocatalysts","authors":"Rutao Wang, Xiaokun Yang, Jianpeng Zhang, Shilong Wen, Liting Yan, Xuebo Zhao, Enyan Guo","doi":"10.1016/j.ccr.2025.216541","DOIUrl":"10.1016/j.ccr.2025.216541","url":null,"abstract":"<div><div>The electrochemical reduction of carbon dioxide (CO<sub>2</sub>RR) enables the transformation of CO<sub>2</sub> into valuable chemicals and fuels using renewable electricity, offering a crucial pathway toward addressing the global energy crisis and achieving carbon neutrality. Traditional theories of catalyst stability and activity can be complicated by the dynamic reorganization of catalysts under operating circumstances, which is a significant issue in this subject. To address this, advanced in-situ technologies and theoretical calculations reveal the dynamic evolution of catalysts and intermediates during CO<sub>2</sub>RR. In this review, we systematically analyze the integration of in-situ characterization technologies with theoretical calculations which underscores their critical role in understanding the mechanisms of CO<sub>2</sub>RR and facilitating the design of efficient catalysts. Subsequently, we systematically summarize the recent advances in-situ studies and theoretical calculations on probing the reaction mechanisms during the CO<sub>2</sub>RR. In this perspective, we can deepen our understanding of reaction mechanisms by combining advanced real-time monitoring and theoretical calculation approaches that relate the dynamic evolution of variable response environments to theoretical evolutionary models. Finally, this review seeks to enhance the understanding of reaction mechanisms and provide guidance for the rational design of efficient catalysts through the integration of in-situ characterization techniques and theoretical calculations.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216541"},"PeriodicalIF":20.3,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143510999","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A comprehensive review of the advancement of transition metal oxide nanocomposites for microwave absorption

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-27 DOI: 10.1016/j.ccr.2025.216535

Muhammad Rizwan Tariq , Mudasir Ahmad , Mehraj-ud-din Naik , Idrees Khan , Baoliang Zhang

{"title":"A comprehensive review of the advancement of transition metal oxide nanocomposites for microwave absorption","authors":"Muhammad Rizwan Tariq , Mudasir Ahmad , Mehraj-ud-din Naik , Idrees Khan , Baoliang Zhang","doi":"10.1016/j.ccr.2025.216535","DOIUrl":"10.1016/j.ccr.2025.216535","url":null,"abstract":"<div><div>Microwave absorbing materials (MAMs) have garnered consequential attention due to their multifaceted utilities across the civilian and military domains. Initially conceived in the mid to late 20th century predominantly for military purposes, particularly in the realm of stealth technology. These MAMs have played a pivotal role in mitigating the harmful impacts of electromagnetic waves (EMWs) generated from burgeoning 5th generation wireless systems (5G), which causes the proliferation of EMWs as microwave pollution and healthcare related concerns. Acting as a protective barrier, MAMs shield individuals from EMWs interference. These MAMs comprises on diverse substances, encompassing singular and composite forms, sourced from ferrites, metal oxides, alloys, conducting polymers (CP), and ceramics. These MAMs exhibit exceptional physicochemical characteristics, including high-temperature resilience, a wide effective absorbing bandwidth range (EAB), compatibility with infrared stealth operations, and robustness in harsh environmental conditions.</div><div>Furthermore, composite MAMs offers sophisticated functionalities as programmable control, optimal EMWs absorption properties, biomimetic structural emulation, and adaptability as intelligent MAMs. This review provides a comprehensive analysis of MAMs, elucidating their applications across various sectors, including military applications, radar detection and stealth properties (2.00–18.00 GHz), infrared-compatible materials (visible, radar, and laser), and multifrequency adaptable stealth MAMs. Additionally, this review article addresses the challenges inherent in MAM design and development, elucidates electromagnetic response mechanisms, absorption calculations, and outlines current and prospective research trajectories in this field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216535"},"PeriodicalIF":20.3,"publicationDate":"2025-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143507371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Harnessing the power of nanoagents in acute kidney injury: A versatile platform for imaging and treatment

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-27 DOI: 10.1016/j.ccr.2025.216570

Peng Liu , Yajie Zhao , Ying Peng , Jessica C. Hsu , Ming Zhou , Wenhu Zhou , Shuo Hu , Weibo Cai

{"title":"Harnessing the power of nanoagents in acute kidney injury: A versatile platform for imaging and treatment","authors":"Peng Liu , Yajie Zhao , Ying Peng , Jessica C. Hsu , Ming Zhou , Wenhu Zhou , Shuo Hu , Weibo Cai","doi":"10.1016/j.ccr.2025.216570","DOIUrl":"10.1016/j.ccr.2025.216570","url":null,"abstract":"<div><div>Acute kidney injury (AKI), a severe complication marked by a sudden decline in renal function, is a significant public health concern with high morbidity and mortality rates. The early diagnosis and effective treatment of AKI remain challenging due to the complex etiology and pathophysiology of the disease. Nanoagents have emerged as a promising strategy for improving AKI management by enabling early detection, monitoring disease progression and enhancing treatment efficacy. This review provides a comprehensive overview of the recent advances in nanoagent-based approaches for AKI imaging and treatment. We first discuss the pathophysiological characteristics of AKI and their influence on nanoparticle targeting, accumulation, and clearance in diseased renal tissues. Next, we present a variety of nanoagent-based imaging techniques for monitoring kidney function and diagnosing AKI. We also outline the therapeutic principles of AKI and summarize the broad array of nanotherapeutic agents developed for AKI treatment. Finally, the review discusses the challenges of bringing nanoagent research into clinical use and explores future directions, emphasizing key opportunities to drive progress in this field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216570"},"PeriodicalIF":20.3,"publicationDate":"2025-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143507370","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Development of small-molecule NIR-II photothermal agents for image-guided tumor therapy

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-27 DOI: 10.1016/j.ccr.2025.216549

Long He , Yi Li , Chonghua Zhang , Xingxing Zhang , Benhua Wang , Tianbing Ren , Lin Yuan

引用次数: 0

Supramolecular light-harvesting systems based on cucurbit[n]urils: SS-FRET and TS-FRET mechanisms and functional applications

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-27 DOI: 10.1016/j.ccr.2025.216555

Wei Zhang , Mao-Qin Liu , Yang Luo

{"title":"Supramolecular light-harvesting systems based on cucurbit[n]urils: SS-FRET and TS-FRET mechanisms and functional applications","authors":"Wei Zhang , Mao-Qin Liu , Yang Luo","doi":"10.1016/j.ccr.2025.216555","DOIUrl":"10.1016/j.ccr.2025.216555","url":null,"abstract":"<div><div>Supramolecular light-harvesting systems constructed based on SS-FRET and TS-FRET are promising for chemical sensing leadership, information encryption, biomedical imaging, etc. These systems typically exhibit extremely large Stokes shifts, high quantum yields, and long-wavelength-emitting fluorescence (especially in the near-infrared) with tunable colors. This review summarizes cucurbit[n]urils-based supramolecular light-harvesting systems that restrict the rotation and vibration of organic fluorescent/phosphorescent molecules, and briefly discusses ALHSs based on other macrocyclic compounds and their functional applications. A wide range of cucurbit[n]urils are encompassed for practical reading value, including single-cavity Q[n]s, (<em>n</em> = 5–8, 10) and double-cavity <em>t</em>Q[13–15]) and <em>ns</em>-Q[10]). The rigid cavity structure and high affinity of Q[n]s could induce spatial confinement effects, which effectively limit or reduce the decay of radiative/non-radiative transitions, promote inter-system crossing, reduce the distance between donor-acceptor pairs, and effectively improve energy transfer efficiency. We contribute to the promotion of the further development of Q[n]s-based FRET systems by discussing and summarizing the advantages, importance, and functional applications of Q[n]s in the construction of FRET systems, e.g., tunable multicolor luminescent materials, information encryption/anti-counterfeiting, photocatalysis, and biologically targeted therapeutics/imaging.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216555"},"PeriodicalIF":20.3,"publicationDate":"2025-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143507372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

GSH-responsive nanomedicine for disease smart imaging and therapy

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-27 DOI: 10.1016/j.ccr.2025.216554

Zi Fu , Di Zhou , Zeyang Liu , Dalong Ni

{"title":"GSH-responsive nanomedicine for disease smart imaging and therapy","authors":"Zi Fu , Di Zhou , Zeyang Liu , Dalong Ni","doi":"10.1016/j.ccr.2025.216554","DOIUrl":"10.1016/j.ccr.2025.216554","url":null,"abstract":"<div><div>Glutathione (GSH) is a main component of the antioxidant system in organisms, scavenging reactive oxygen species and protecting cells from oxidative stress, thus playing important roles in many physiological processes. An imbalance of GSH level within the microenvironment is a characteristic of many diseases, which makes this biochemical property of the disease site be exploited as a potential target for disease treatment. Recent advances in nanomedicine have led to a proliferation of nanomedicines targeting GSH, with which a variety of emerging imaging and therapeutic modalities have been achieved on multiple disease models. Here, we review recent advances in nanomedicine for diseases characterized by imbalanced GSH levels. First, the design strategies and chemical mechanisms of GSH-responsive nanomedicine are described. Then, we provide a systematic review of the application of GSH-responsive nanomaterials for disease smart imaging including fluorescence imaging, photoacoustic imaging, magnetic resonance imaging and computed tomography imaging. Moreover, GSH-responsive nanomaterials-based tumor smart therapeutic strategies including chemotherapy, phototherapy, chemo-dynamic therapy and ferroptosis are detailedly introduced. An in-depth discussion of current challenges and future prospects for GSH-responsive nanomedicine are given at the end of this review.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216554"},"PeriodicalIF":20.3,"publicationDate":"2025-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143507326","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Theoretical insights into performance descriptors and their impact on activity optimization strategies for cobalt-based electrocatalysts

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-27 DOI: 10.1016/j.ccr.2025.216560

Xinxin Zhang, Lei Wang, Ying Xie, Honggang Fu

{"title":"Theoretical insights into performance descriptors and their impact on activity optimization strategies for cobalt-based electrocatalysts","authors":"Xinxin Zhang, Lei Wang, Ying Xie, Honggang Fu","doi":"10.1016/j.ccr.2025.216560","DOIUrl":"10.1016/j.ccr.2025.216560","url":null,"abstract":"<div><div>The hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR) are crucial half-reactions in energy storage and conversion systems. As ideal alternatives to precious metal catalysts, cobalt (Co)-based catalysts have attracted significant attention due to their adjustable oxidation states, multifunctionality, and structural diversity. Nevertheless, because of the complexities in composition, stoichiometry, and structures, fully understanding the microscopic origin of relevant reaction mechanisms and the inherent structural and performance relationships remains a great challenge. Therefore, utilizing the theoretical descriptors to distinguish and reveal the factors that limit the electrocatalytic activities of the Co-based electrocatalysts is thus of great importance, which is very crucial for appropriate adjustment of the synthetic strategies, the structure/composition optimizations, and finally the enhancement of the electrocatalytic performance. In this review, the computational hydrogen electrode and HER, OER, and ORR mechanisms are first introduced. Then, the performance descriptors related to the conductivity, reactivity, and stability were derived and discussed in-depth from density functional theory (DFT) calculations. Inspired by these descriptors, various strategies to comprehensively optimize the structures and electronic properties of the Co-based catalysts are summarized. Finally, current status, challenges, and future prospects of Co-based catalysts in practical Zn-air batteries (ZABs) and water splitting applications were reviewed.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216560"},"PeriodicalIF":20.3,"publicationDate":"2025-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143507327","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Harnessing stimuli-responsive NO nanomaterials for advanced multi-disease therapy

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-27 DOI: 10.1016/j.ccr.2025.216540

Junjie Zhang , Haiyang Guo , Longguang Tang , Jiannan Liu , Qiang Fang , Dongliang Yang , Wenpei Fan

{"title":"Harnessing stimuli-responsive NO nanomaterials for advanced multi-disease therapy","authors":"Junjie Zhang , Haiyang Guo , Longguang Tang , Jiannan Liu , Qiang Fang , Dongliang Yang , Wenpei Fan","doi":"10.1016/j.ccr.2025.216540","DOIUrl":"10.1016/j.ccr.2025.216540","url":null,"abstract":"<div><div>Nitric oxide (NO) is a critical signaling molecule with diverse physiological functions and significant therapeutic potential across various diseases. However, its clinical application faces substantial challenges due to its inherently short half-life, rapid diffusion, and potential systemic toxicity. Recent advancements in nanotechnology have enabled the development of sophisticated nanomaterials that precisely control and target NO delivery, thereby overcoming these limitations. This paper provides an in-depth review of cutting-edge NO delivery nanomaterials, emphasizing both organic and inorganic carriers engineered to respond to specific endogenous (<em>e.g.</em>, pH, glucose, GSH, <em>etc.</em>) and exogenous (<em>e.g.</em>, light, X-rays, ultrasound, <em>etc.</em>) stimuli. The review particularly focuses on the synergistic integration of NO therapy with other modalities such as photothermal therapy, photodynamic therapy, sonodynamic therapy, starvation therapy, immunotherapy, radiotherapy, gene therapy, chemodynamic therapy, and magnetothermal therapy. These versatile nanomaterials have shown significant efficacy in treating complex conditions, including cancer, cardiovascular disorders, inflammatory, and other diseases. Furthermore, the review discusses current challenges in NO delivery technologies, exploring the limitations and potential future developments in this field. By highlighting the latest advances, this paper underscores the promising avenues for translating NO-based therapies into clinical practice, aiming to substantially enhance therapeutic outcomes and improve patient care.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216540"},"PeriodicalIF":20.3,"publicationDate":"2025-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143507348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Chalcophosphates: A plentiful source of infrared nonlinear optical materials

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-26 DOI: 10.1016/j.ccr.2025.216524

Yingying Kong , Guansong Zheng , Yinxia Du , Junjie Li , Shilie Pan

{"title":"Chalcophosphates: A plentiful source of infrared nonlinear optical materials","authors":"Yingying Kong , Guansong Zheng , Yinxia Du , Junjie Li , Shilie Pan","doi":"10.1016/j.ccr.2025.216524","DOIUrl":"10.1016/j.ccr.2025.216524","url":null,"abstract":"<div><div>Developing high-performance nonlinear optical (NLO) crystals is an urgent need for advanced photoelectric technologies. However, the discovery of novel infrared (IR) NLO materials with desired properties is challenging. Chalcophosphate, combining the structural advantages of chalcogenide & phosphate, and showing a high probability (∼30 %, much higher than the one of ∼15 % in the inorganic compounds) to generate non-centrosymmetric crystal structures, was demonstrated as a promising system for searching new IR NLO crystals with excellent optical properties, and a great many NLO-active chalcophosphates were ‌reasonably designed and fabricated. To advance the targeted design of high-performance IR NLO crystals, this review provides a systematic and up-to-date summary on the abundant structural and chemical diversities of chalcophosphates, with a particular emphasis on the connection modes of distinguished [P<sub>x</sub>Q<sub>y</sub>] units; and the efficient progress on the structural design that achieved in the thiophosphate-, selenophosphate-, and mixed anionic-based chalcophosphate IR NLO candidates in recent years. Finally, the upcoming opportunities and challenges in the captivating fields were discussed.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216524"},"PeriodicalIF":20.3,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143496182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Novel bio-carriers for radionuclide delivery in cancer radiotherapy

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-26 DOI: 10.1016/j.ccr.2025.216557

Lishan Wang , Qing He , Jianping Man , Yechen Gao , Guangming Zhou , Hongwei Si , Kai Yang , Lin Hu , Pei Pei

{"title":"Novel bio-carriers for radionuclide delivery in cancer radiotherapy","authors":"Lishan Wang , Qing He , Jianping Man , Yechen Gao , Guangming Zhou , Hongwei Si , Kai Yang , Lin Hu , Pei Pei","doi":"10.1016/j.ccr.2025.216557","DOIUrl":"10.1016/j.ccr.2025.216557","url":null,"abstract":"<div><div>Internal radionuclide therapy (IRT) is a crucial component of cancer radiotherapy, focusing on delivering radionuclides to the tumor site via an optimal carrier and using high-energy radiation (including α particles, β particles, γ rays, and Auger electrons) to kill tumor cells. To further enhance the efficacy and safety of IRT, developing new bio-carriers to optimize the stable and efficient labelling, targeting delivery efficiency, biosafety, and multi-functionality of radionuclides has become a current research focus. In this review, we first briefly revisit the commonly used radionuclide delivery carriers in clinical practice, including antibodies, peptides, microspheres, and discuss their associated challenges. Subsequently, we focus on the development and research progress of novel bio-carriers, analyzing their roles and mechanisms in optimizing radionuclide labelling, delivery, and enhancing the efficacy of IRT. Finally, the review provides insights into the existing challenges faced in the field and suggests potential future research directions. Our work aims to advance the use of radionuclides in cancer radiotherapy with innovative bio-carriers, offering theoretical support and a vision for developing highly multifunctional and clinically useful bio-carriers.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216557"},"PeriodicalIF":20.3,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488503","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0