Coordination Chemistry Reviews最新文献

Electron Magnetic Resonance (EMR) and related studies of transition metal (3dN) dopants in titanium dioxide (TiO2) systems: guide in tailoring the material's properties for specific technological applications 电子磁共振（EMR）和二氧化钛（TiO2）体系中过渡金属（3dN）掺杂剂的相关研究：为特定技术应用量身定制材料特性的指南

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-05-02 DOI: 10.1016/j.ccr.2025.216740

Muhammed Açıkgöz , Czesław Rudowicz

{"title":"Electron Magnetic Resonance (EMR) and related studies of transition metal (3dN) dopants in titanium dioxide (TiO2) systems: guide in tailoring the material's properties for specific technological applications","authors":"Muhammed Açıkgöz , Czesław Rudowicz","doi":"10.1016/j.ccr.2025.216740","DOIUrl":"10.1016/j.ccr.2025.216740","url":null,"abstract":"<div><div>Doping the transition metal (TM) ions into TiO₂, both anatase and rutile forms, has garnered significant interest due to their impact on the structural, spectroscopic and magnetic properties of these materials. By different doping concentrations of specific TM ions, these key physical properties can be customized for specific applications in diverse areas such as catalysis, optoelectronics, spintronics, and metamaterials. Electron Magnetic Resonance (EMR) spectroscopy techniques are particularly powerful tools for investigating TM ions in coordination complexes. To lay the groundwork, we overview crystallography, synthesis, and spectroscopic techniques. The basics of spin Hamiltonian (SH) theory are recapped. This enables interpretation of EMR spectra and physical properties of TM ions in TiO₂ systems in terms of SH parameters. Experimental EMR-related studies of TM (3d<sup>N</sup>) ions in doped and undoped TiO₂ systems are comprehensively surveyed to identify key aspects and highlight important issues. Computational studies utilizing various approaches to model SH parameters and thus verify experimentally measured parameter values are also surveyed. This review signifies that integrating experimental techniques with modeling approaches enables a more profound understanding of the key physical properties. The systematic analysis of literature data and categorization of various aspects and issues may facilitate creation of innovative materials with customized properties for particular applications. This may encourage additional research to discover new capabilities of the TiO₂-based adaptable semiconductors.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216740"},"PeriodicalIF":20.3,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143899130","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Integrative gas-based therapeutics for cancer treatment: Recent advances and multi-therapy innovations 以气体为基础的癌症综合疗法：最新进展和多疗法创新

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-05-02 DOI: 10.1016/j.ccr.2025.216746

Jiaqing Zhang , Xiang Cao , Huiyun Wen , Quazi T.H. Shubhra , Xiaowen Hu , Xiaosong He , Xiaojun Cai

{"title":"Integrative gas-based therapeutics for cancer treatment: Recent advances and multi-therapy innovations","authors":"Jiaqing Zhang , Xiang Cao , Huiyun Wen , Quazi T.H. Shubhra , Xiaowen Hu , Xiaosong He , Xiaojun Cai","doi":"10.1016/j.ccr.2025.216746","DOIUrl":"10.1016/j.ccr.2025.216746","url":null,"abstract":"<div><div>Gas therapy has emerged as a promising modality for tumor treatment due to its unique advantages, including safety and efficiency, ability to enhance the drug sensitivity of cancer cells, and almost no drug resistance. In this review, we comprehensively explore the anticancer mechanisms, advantages and disadvantages of four key gas therapies: carbon monoxide (CO), nitric oxide (NO), hydrogen sulfide (H<sub>2</sub>S) and sulfur dioxide (SO<sub>2</sub>). Recognizing the challenges of single gas therapies, we discuss their integration with advanced multi-therapy approaches, including photodynamic therapy (PDT), photothermal therapy (PTT), sonodynamic therapy (SDT), and chemodynamic therapy (CDT), to maximize therapeutic efficacy. Emphasis is placed on the synergistic effects of these combinations, particularly in overcoming tumor microenvironment (TME) challenges. Finally, we address the future potential of gas therapies in clinical oncology, highlighting key obstacles such as precise delivery, dose control, and translational barriers to clinical implementation.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216746"},"PeriodicalIF":20.3,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143895445","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advances in gas-solid-liquid triple-phase interface engineering towards efficient oxygen reduction reaction 高效氧还原反应的气固液三相界面工程研究进展

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-05-02 DOI: 10.1016/j.ccr.2025.216752

Yongxia Wang , Huanhuan Zhang , Shuang Li , Jingjing Liu , Jiahui Wang , Jingru Lv , Songmei Sun , Xiangzhi Cui , Jinli Qiao , Jianlin Shi

{"title":"Advances in gas-solid-liquid triple-phase interface engineering towards efficient oxygen reduction reaction","authors":"Yongxia Wang , Huanhuan Zhang , Shuang Li , Jingjing Liu , Jiahui Wang , Jingru Lv , Songmei Sun , Xiangzhi Cui , Jinli Qiao , Jianlin Shi","doi":"10.1016/j.ccr.2025.216752","DOIUrl":"10.1016/j.ccr.2025.216752","url":null,"abstract":"<div><div>Oxygen reduction reaction (ORR) as a key electrochemical reaction for the advanced energy storage and conversion technology, is a complex surface-dominated process comprising several indispensable steps of electron transfer, mass diffusion and adsorption/desorption of reactant/products at the gas-solid-liquid triple-phase interface. In the past few years, great processes have been made in regulating the interface micro-environment based on the optimal design of electrode structure and controllable construction of electrocatalysts, resulting in the boosted electro-catalytic performances and the in-depth understanding of the underlying fundamentals of ORR. In this review, the most recent progresses in the triple-phase interface engineering for ORR have been reviewed in a comprehensive manner by emphasizing the issues such as the general design principles of electrode and catalyst, and the extensive ORR mechanism exploration at the triple-phase interface both experimentally and theoretically. This review focuses on the advanced topic of triple-phase interface engineering for efficient ORR, presenting and discussing the most recent advancements. Additionally, it addresses the challenges and offers an in-depth exploration of the prospective future directions in this field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216752"},"PeriodicalIF":20.3,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143895446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Peptide-harnessed supramolecular and hybrid nanomaterials for stimuli-responsive theranostics 用于刺激反应治疗的肽利用超分子和杂化纳米材料

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-05-01 DOI: 10.1016/j.ccr.2025.216737

Jinhyeok Choi , Yerim Kim , Jihwan Park , Chaeyeon Park , Seoyeon Sung , Heemin Kang , Yongju Kim , Sehoon Kim

{"title":"Peptide-harnessed supramolecular and hybrid nanomaterials for stimuli-responsive theranostics","authors":"Jinhyeok Choi , Yerim Kim , Jihwan Park , Chaeyeon Park , Seoyeon Sung , Heemin Kang , Yongju Kim , Sehoon Kim","doi":"10.1016/j.ccr.2025.216737","DOIUrl":"10.1016/j.ccr.2025.216737","url":null,"abstract":"<div><div>Theranostics has emerged as a promising approach to integrate therapy and diagnosis. However, existing systems have limitations such as low tumor specificity and potential toxicity. Recent efforts have focused on harnessing smart, stimuli-responsive materials to tackle these shortcomings. Among them, peptide-based supramolecular and hybrid nanomaterials offer remarkable potential: their ability to form diverse secondary structures (e.g., α-helices, β-sheets) enables precise control over drug release, imaging, and other functions in response to single or dual stimuli such as pH, enzymes, redox, or light. These materials have shown increased tumor selectivity, controlled drug release, and improved imaging accuracy through their secondary structures, supramolecular assemblies, and hybrid structures. Furthermore, they have shown promise in overcoming the limitations of existing theranostics in various fields including drug delivery, tissue engineering, phototherapy, wound healing, bioimaging, and clinical trials. In this review, we highlight the importance of stimuli-responsive mechanisms and peptide-based nanomaterial design and suggest directions for developing precise and efficient next-generation theranostics.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216737"},"PeriodicalIF":20.3,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143890644","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Stimuli-responsive smart nanomaterials for theranostics of urological cancers 刺激反应型智能纳米材料在泌尿系统癌症治疗中的应用

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-04-30 DOI: 10.1016/j.ccr.2025.216745

Yi Xu , Madineh Moradialvand , Francesca Della Sala , Ehsan Nazarzadeh Zare , Kiavash Hushmandi , Ilnaz Rahimmanesh , Assunta Borzacchiello , Siavash Iravani , Iman Zare , Jungah Shin , Juyoung Yoon , Heemin Kang , Pooyan Makvandi

{"title":"Stimuli-responsive smart nanomaterials for theranostics of urological cancers","authors":"Yi Xu , Madineh Moradialvand , Francesca Della Sala , Ehsan Nazarzadeh Zare , Kiavash Hushmandi , Ilnaz Rahimmanesh , Assunta Borzacchiello , Siavash Iravani , Iman Zare , Jungah Shin , Juyoung Yoon , Heemin Kang , Pooyan Makvandi","doi":"10.1016/j.ccr.2025.216745","DOIUrl":"10.1016/j.ccr.2025.216745","url":null,"abstract":"<div><div>Urological cancers, including prostate, bladder, and kidney cancers, contribute significantly to the global burden of cancer-related mortality. While numerous reviews have addressed these cancers individually, this is the first comprehensive review that exclusively focuses specifically on nanotheranostics as a transformative approach for urological cancer. The distinct tumor microenvironments (TMEs) associated with these cancers pose both challenges and opportunities for precise nanotherapeutic interventions. This review provides a thorough examination of current advancements in nanotechnology-based diagnostics and therapeutics tailored to urological cancers. For each primary urological cancer type, we outline key strategies for leveraging nanotheranostics in the detection and treatment of tumors. Furthermore, we address the persisting challenges in enhancing tumor specificity and treatment efficacy. In essence, nanotheranostics offer a promising therapeutic avenue for urological cancers by enabling targeted drug delivery and controlled release of therapeutics within the tumor microenvironment. The objective of this pioneering review is to underscore recent developments and future prospects in utilizing nanotechnology to meet the unmet needs in the diagnosis and treatment of urological cancers.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216745"},"PeriodicalIF":20.3,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143886047","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Flexible surface-enhanced Raman scattering substrates: A review on design strategies, fabrication technologies, and applications 柔性表面增强拉曼散射衬底：设计策略、制造技术和应用综述

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-04-30 DOI: 10.1016/j.ccr.2025.216739

Tongmei Jing , Rongke Gao , Changbiao Zhan , Yiyue Yu , Xiaozhe Chen , Yang Lu , Han Ku Nam , Young-Jin Kim , Liandong Yu

{"title":"Flexible surface-enhanced Raman scattering substrates: A review on design strategies, fabrication technologies, and applications","authors":"Tongmei Jing , Rongke Gao , Changbiao Zhan , Yiyue Yu , Xiaozhe Chen , Yang Lu , Han Ku Nam , Young-Jin Kim , Liandong Yu","doi":"10.1016/j.ccr.2025.216739","DOIUrl":"10.1016/j.ccr.2025.216739","url":null,"abstract":"<div><div>Surface-enhanced Raman scattering (SERS) has drawn great attention due to its sensitive detection and fingerprint identification. Plasmonic structures built on supporting substrate to integrate SERS devices have broadened its practical applications. Compared with rigid materials for supporting substrate, flexible materials have received great interest, in terms low-cost, non-invasive, and easy-operation, especially for curved surface samples. Herein, an in-depth exploration of the latest progress in flexible SERS substrates was presented, which focused on both design strategies for optimizing SERS signal enhancement and the fabrication techniques that enable large-scale production. We introduced two novel approaches for manipulating the hotspot distribution in flexible SERS substrates, a critical factor for improving signal sensitivity and reproducibility, which was underexplored in previous reviews. Furthermore, we provided a comprehensive overview of various flexible materials-based SERS substrates, including polymers, cellulose, and other biomaterials, along with their typical fabrication methods. This review also highlights cutting-edge applications of FSS in biosensors, <em>in-situ</em> detection of food pesticides, environmental pollutants monitoring and microfluidic technology with an emphasis on practical application challenges, such as substrate uniformity, stability, and scalability. It is believed that this review would help the researchers in diverse fields related to materials, nanophotonics, and SERS to design and develop novel FSS with highly sensitive and simply reproducible toward real-world applications in chemical and biological sensing.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216739"},"PeriodicalIF":20.3,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143886048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Nanocluster-based aggregates: Assembled forms, driving forces, and structure-related properties 基于纳米团簇的聚集体：组装形式、驱动力和结构相关性质

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-04-30 DOI: 10.1016/j.ccr.2025.216738

Hao Li , Xi Kang , Manzhou Zhu

{"title":"Nanocluster-based aggregates: Assembled forms, driving forces, and structure-related properties","authors":"Hao Li , Xi Kang , Manzhou Zhu","doi":"10.1016/j.ccr.2025.216738","DOIUrl":"10.1016/j.ccr.2025.216738","url":null,"abstract":"<div><div>Atomically precise nanoclusters have gained significant attention due to their ultra-small size and strong quantum-size effects. These nanoclusters possess unique and exceptional properties, making them excellent building blocks for various applications. With their precisely arranged structures, nanoclusters enable the development of multifunctional nanomaterials with enhanced characteristics. Owing to their well-defined molecular compositions, improved stability, and versatile functionalities, nanoclusters provide an excellent platform for creating superstructures through self-assembly. The self-assembly process, driven by the interactions between surface ligands and metal cores, is a key aspect that informs and enhances our understanding of nanoclusters. In this review, we summarized the recent progress of research on the aggregation of nanoclusters, especially their orderly assembled superstructures. We focus on the driving forces behind the aggregation of metal nanoclusters, including ligand-ligand interactions, metal-ligand interactions, metal-metal interactions, and interactions between nanoclusters and other particles. The aggregates, composed of nanoclusters, exhibit complex hierarchical structures and enhance performance, paving the way for the construction of novel functional nanocluster-based materials.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216738"},"PeriodicalIF":20.3,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143886046","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Mixed-valence halide perovskites 混合价卤化物钙钛矿

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-04-30 DOI: 10.1016/j.ccr.2025.216719

Christina R. Deschene , Clara Zwanziger , Roc Matheu , Hemamala I. Karunadasa

{"title":"Mixed-valence halide perovskites","authors":"Christina R. Deschene , Clara Zwanziger , Roc Matheu , Hemamala I. Karunadasa","doi":"10.1016/j.ccr.2025.216719","DOIUrl":"10.1016/j.ccr.2025.216719","url":null,"abstract":"<div><div>Mixed-valence compounds—which feature an element in at least two different oxidation states—can display emergent optical and transport phenomena stemming from electron transfer between the different valences (intervalence charge-transfer; IVCT). As halide perovskites show promise as active materials in numerous optoelectronic devices, it is an opportune moment to incorporate and study the effects of mixed-valence in this versatile materials family, to access tunable electronic structures ranging from insulators to semiconductors to metals. Herein, we introduce the basic concepts of mixed-valence in molecules and discuss how these concepts may be extended to mixed-valence in extended solids. We then review the few studies of mixed valence in 3D and 2D halide perovskites and halide perovskites with mixed-valence impurities, ranging from studies in the early 1900s to the present day. Through judicious choice of metal ion, its coordinating ligands and their geometry, and overall structural dimensionality, chemists can exert powerful synthetic control over electronic delocalization in mixed-valence perovskites, and we hope to see this intriguing materials class expand to encompass new compositions.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216719"},"PeriodicalIF":20.3,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143886544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent trends and prospects in electrochemical nitrate reduction to ammonia with an emphasis on cobalt catalysts 硝酸电化学还原制氨的最新趋势与展望，重点是钴催化剂

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-04-28 DOI: 10.1016/j.ccr.2025.216751

Gaihong Wang , Zhijie Chen , Jiangzhou Xie , Lei Ding , Jinliang Zhu , Wei Wei , Yi-Ming Yan , Dewei Chu , Bing-Jie Ni

{"title":"Recent trends and prospects in electrochemical nitrate reduction to ammonia with an emphasis on cobalt catalysts","authors":"Gaihong Wang , Zhijie Chen , Jiangzhou Xie , Lei Ding , Jinliang Zhu , Wei Wei , Yi-Ming Yan , Dewei Chu , Bing-Jie Ni","doi":"10.1016/j.ccr.2025.216751","DOIUrl":"10.1016/j.ccr.2025.216751","url":null,"abstract":"<div><div>Ammonia is gaining recognition as a promising energy carrier due to its high energy density, ease of liquefaction, and existing robust production and distribution infrastructure, particularly within the agricultural sector. The electrochemical nitrate reduction reaction (NO<sub>3</sub>RR), conducted under ambient conditions, offers a sustainable alternative to the energy-intensive Haber–Bosch (H<img>B) process, addressing both environmental and energy challenges. Recent advancements in understanding catalytic mechanisms, optimizing catalytic systems, and designing advanced catalysts have substantially enhanced the efficiency of nitrate-to-ammonia conversion. Among these, cobalt (Co)-based electrocatalysts have emerged as a cost-effective and efficient alternative to noble metals, owing to their earth abundance, low cost, and favorable catalytic properties. This review provides a comprehensive overview of recent progress in NO<sub>3</sub>RR, emphasizing Co-based electrocatalysts. It delves into NO<sub>3</sub>RR mechanism analysis, critical considerations for system optimization, and innovative Co-based catalyst design strategies. Additionally, we explore current challenges and propose future directions for improving Co-based electrocatalyst performance, aiming to advance the rational design of efficient catalysts for sustainable ammonia synthesis.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216751"},"PeriodicalIF":20.3,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143882217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent advances in metal-organic frameworks for real-world application toward adsorptive capturing of gaseous aromatic volatile organic compounds in air 金属有机框架在吸附捕获空气中气态芳香族挥发性有机化合物中的实际应用的最新进展

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-04-27 DOI: 10.1016/j.ccr.2025.216744

Bhaskar Anand , Younes Ahmadi , Jan E. Szulejko , Ki-Hyun Kim , Jechan Lee

{"title":"Recent advances in metal-organic frameworks for real-world application toward adsorptive capturing of gaseous aromatic volatile organic compounds in air","authors":"Bhaskar Anand , Younes Ahmadi , Jan E. Szulejko , Ki-Hyun Kim , Jechan Lee","doi":"10.1016/j.ccr.2025.216744","DOIUrl":"10.1016/j.ccr.2025.216744","url":null,"abstract":"<div><div>Metal-organic frameworks (MOFs) are porous crystalline materials with a high degree of tunability in terms of chemical functionality and morphology (e.g., pore size). Because of such advantageous properties, MOFs are recognized as effective adsorbents against diverse pollutants including volatile organic compounds (VOCs). However, as the use of MOFs has generally been confined to lab bench-top small-scale studies, their real-world applications can encounter various operational challenges (e.g., flow constriction, performance impairment due to humidity, framework collapse, secondary pollution, low regenerability, exorbitant upfront cost, and limited scalability). To help overcome these issues, this review focuses on the scalability of MOF-based adsorbent in relation to their physicochemical properties (relative to the “gold standard” BPL AC as a commercial activated carbon produced by Calgon Carbon) along with their performance evaluation toward nonpolar aromatic VOCs (e.g., the sorption partition coefficient [PC] at specific inlet partial pressure [for air purification <0.1 Pa]). This review is thus expected to offer a better understanding of the synthesis, modification, and functionalization of MOFs to realize their upscaled application for large-scale air purification systems.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216744"},"PeriodicalIF":20.3,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143876940","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0