Coordination Chemistry Reviews最新文献

{"title":"Recent advances of fluorescent probe for the conjugated enzymes closely related to clinical diseases","authors":"Ren-Wei-Yang Zhang, Han Zhang, Qiu Li, Fa-Ping Li, Rong-Ya Zhang, Wei-Bo Zhao, Hong-Ji Liu, Zhi-Gang Hu, Kai Wang","doi":"10.1016/j.ccr.2025.216471","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.216471","url":null,"abstract":"The four biological enzymes encompassing alkaline phosphatase (ALP), aminopeptidase N (APN), <em>γ</em>-glutamyl transferase (GGT), and Cathepsin B (CTB), play a pivotal role in a myriad of physiological and pathological processes. Hence, the detection of the five indexes could own an important value in the diagnosis of clinical diseases even the subsequent treatments, which is restricted by a traditional method circle mainly consisting of liquid chromatography, gas chromatography, inductively coupled plasma-atomic emission spectrometry, chemiluminescence, and inductively coupled plasma-atomic emission spectrometry with several defaults such as bulky equipment, intricate process of testing, elevated detection expenses, high costs, and the lack of visualization in living organisms. The introduction of fluorescent probes brings a novel perspective to sense the biochemical indicators with a rapid non-invasive effect accompanied by high accuracy and sensitivity in both physiological and pathological contexts. This review introduced the fluorescence probes for these biochemical molecules (ALP, APN, GGT, and CTB) by their optical imaging <em>in vitro</em> assay with the models of various cell lines (HeLa, A549, HepG2, <em>etc.</em>) and wine, the imaging <em>in vivo</em> assay by the models of animals (Mice, zebrafishes, <em>etc.</em>) even human samples as well from 2014 to 2024. Furthermore, we systematically illustrate the optimistic progress of the fluorescent probes targeting the five molecules and expect the bright prospects of the fluorescence chemosensors shortly with a sincere hope of benefit for subsequent studies in the biological processes pivotal for related clinical application.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"23 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143050724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Bi2S3-based photocatalysts: Properties, synthesis, modification strategies, and mechanistic insights towards environmental sustainability and green energy technologies","authors":"Akshay Chawla, Anita Sudhaik, , Rohit Kumar, Pankaj Raizada, Tansir Ahamad, Aftab Aslam Parwaz Khan, Quyet Van Le, Van-Huy Nguyen, Sourbh Thakur, Pardeep Singh","doi":"10.1016/j.ccr.2025.216443","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.216443","url":null,"abstract":"The scientific community has concentrated on semiconductor-based photocatalysis to promote ecologically sustainable living for future generations. This technology has demonstrated its efficacy in tackling environmental and energy challenges. Diverse semiconductors are utilized to deal with various issues due to their multiple properties in the presence of photon particles. Bi₂S₃ stands out as a suitable light absorber material for applications in solar cells, biosensors, photodetectors, X-ray technologies, the medical field, and more, owing to its unique characteristics, including a narrow bandgap and capability to operate with near-infrared and visible light. Unluckily, the narrow bandgap of Bi₂S₃, limited redox potential and photocorrosive features, has resulted in a lack of substantial research interest and shows significant inefficiency in energy conversion and the removal of various hazardous chemicals. Thus, the article elucidates the strategies to improve Bi₂S₃ and its intricate properties through diverse synthetic techniques or modification processes. The article further explains characterization techniques that confirm the augmentation of the inherent properties of Bi₂S₃. The improvement implies an increase in the surface area of Bi₂S₃, augmentation of light-harvesting efficiency, facilitation of photoexcited charge separation, offering additional active sites for reactions, elevation of carrier concentration, and conferment of chemical stability, and mitigating photocorrosion, among other advantages. Moreover, the utilization of Bi₂S₃, both in isolation and in conjunction with other photocatalysts, is deliberated upon, accompanied by a tabular overview. The possible challenges and future perspectives associated with Bi₂S₃-based photocatalysts have also been successfully presented.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"25 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143055186","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Metal-organic frameworks based fluorescent sensing: Mechanisms and detection applications","authors":"Yuanyuan Cai, Tao Dong, Zihan Bian, Huan Liu, Xin Liu, Aihua Liu","doi":"10.1016/j.ccr.2025.216470","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.216470","url":null,"abstract":"Metal-organic frameworks (MOFs) are organic-inorganic hybrid materials with porous network structure by coordinating metal ions with flexible organic linking ligands. The luminescence and chemical-physical properties of MOFs can be regulated by altering the types of metal ions and organic ligands or by further functionalization, making them attractive fluorescent probes. In this review, we summarize the recent advances in MOFs-based fluorescent sensing. Importantly, we overview the fluorescent sensing mechanism of MOFs classified as turn-on type, turn-off type and ratiometric type with intensive discussion. Moreover, the applications of MOFs-based fluorescence sensing of various species are detailed. Finally, the challenges and prospects of MOFs fluorescent sensing are envisioned.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"17 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143050725","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent advances in Fe-based metal-organic frameworks: Structural features, synthetic strategies and applications","authors":"Keaoleboga Mosupi, Mike Masukume, Guoming Weng, Nicholas M. Musyoka, Henrietta W. Langmi","doi":"10.1016/j.ccr.2025.216467","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.216467","url":null,"abstract":"Metal organic frameworks (MOFs) are very exciting porous materials owing to their unique properties such as high surface areas, high pore volume, tunable functionalities and great thermal stabilities. The properties of MOFs can be diversely constructed by precise control of synthesis conditions. Amongst the thousands of MOFs that have been discovered to date, Fe-MOFs make up a percentage of these MOFs. Fe-MOFs are increasingly gaining great interest due to their unique properties and chemical versatility. However, comprehensive reviews on their emerging architectural features and designs as well as strategies for tailoring their applications. Therefore, in this review, we present a panoptic summary of the recent developments of Fe-MOFs, which includes synthetic strategies, activation methods, functionalization, overview of selected applications, current challenges impeding their commercialization, and suggested remedial actions. A holistic view of the interconnectedness of Fe-MOFs structural features, synthetic strategies and applications provides greater insights that highlight challenges hindering their wide-scale industrial applications. Moreover, newer approaches such as utilization of machine learning technique that are providing an opportunity for out-of-sight insights for material design and prediction of material properties are briefly highlighted. Remedial actions for challenges of transitioning Fe-based MOFs towards commercialization and industrial applications are also explored, and suggestions for these aspects are presented.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"35 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143050742","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ionic liquids: The emerging “cardiotonic” for photocatalytic materials","authors":"Bin He, Sheng Zhong, Kexin Li, Shuang Wei, Mengyue Li, Ruixia Liu","doi":"10.1016/j.ccr.2025.216461","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.216461","url":null,"abstract":"Photocatalysis has been regarded as “21st century dream technology” and inspired increasing scientific interest due to their environmental and economic applicability. Due to the bottlenecks of photocatalytic materials (PMs) faced, such as low carrier separation efficiency, insufficient active sites, and incompatibility between surface interface properties and targeted reaction, restricting its advance from laboratory to application. The emergence of ionic liquids (ILs) provides a favorable term for the development of PMs due to their tailorability and diversity. This review starts with the properties of ILs (hydrogen bonds effect, electrostatic effect, polarity effect, and coordination effect), followed by analyzing the potential of ILs in PMs modification. Specifically, this review systematically summarized the regulatory mechanisms and unique advantages of ILs on the particle size, morphology, electron transport and interface properties of PMs. Finally, a summary and outlook on the major challenges, opportunities for future research in high-powered PMs by the strategy of ILs modification was proposed.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"38 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143026673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nanocatalytic medicine: An advanced catalysis-based imaging and therapy methodology","authors":"Lingdong Jiang, Zhaokui Jin, Qianjun He","doi":"10.1016/j.ccr.2024.216430","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216430","url":null,"abstract":"Nanocatalytic medicine is an emerging and promising field involving catalysis, medicine and nanotechnology, displaying inimitable advantages over traditional drug therapeutics and imaging agents. In this review, we conduct a systematic summary of representative catalytic reactions to provide understanding/learning/application guidance, and then condenses a cascade of methodologies for catalysis-augmented imaging and catalysis-enabled therapy. Finally, the status quo, challenges and future prospect on advanced nanocatalysts for disease diagnosis and therapy are discussed. This unique review is expected helpful for principle learning and application inspiration of nanocatalytic medicine.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"110 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143026672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent advances in hydrotreating and hydrocracking catalysts for the preparation of light aromatics: Influencing factors, catalytic mechanisms and performance relationship descriptors","authors":"Lingjing Yu, Hong Nie, Ping Yang, Linmeng Wang, Shihao Feng, Hongyi Gao, Ge Wang","doi":"10.1016/j.ccr.2025.216444","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.216444","url":null,"abstract":"Sustainability and environmental concerns have posed significant challenges to the petrochemical industry. To maintain the overall balance of materials and enhance the resilience of the refining and petrochemical industry chain, it is crucial to focus on the development of high-value products and clean energy. Light aromatic hydrocarbons (BTX) are an important chemical raw material, and their production can not only meet the requirements of environmental protection but also realize the high-value utilization of aromatic materials. Hydrotreating (HT) and hydrocracking (HYC) have emerged as promising technologies for BTX production and have been extensively researched in the past few decades. Various catalytic materials, including metal-doped, phosphide-loaded, carbon-based composites, as well as noble and non-noble metal-based materials, are commonly employed in these processes to enhance reaction efficiency and improve product selectivity. This paper summarizes and discusses the recent advances in catalyst materials for HT and HYC reactions, including 1) factors influencing the catalytic reactions of HT and HYC, 2) advances in the characterization and performance understanding of HT and HYC catalysts in the preparation of light aromatics, and 3) computer-assisted design and mechanism investigation of HT and HYC catalysts, as well as the mining of quantitative relationship descriptors. We also concisely discuss some of the scientific challenges and provide a brief outlook on the future development of HT and HYC catalysts. This paper aims to provide insights and strategies for the discovery, optimization, and design of HT and HYC catalysts, as well as understanding their structure-performance relationships.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"12 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143026675","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Artificial intelligence interventions in 2D MXenes-based photocatalytic applications","authors":"Durga Madhab Mahapatra, Ashish Kumar, Rajesh Kumar, Navneet Kumar Gupta, Baranitharan Ethiraj, Lakhveer Singh","doi":"10.1016/j.ccr.2025.216460","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.216460","url":null,"abstract":"Artificial Intelligence powered application have become the norms in day-to-day life. This has a tremendous role for material investigations catering diverse applications. Present day advanced materials as various MAX phases transformed into MXenes have immense applications for environmental use. MXenes have shown great potential in photocatalysis application targetingCO₂ reduction, H₂O₂ production, wastewater and dye treatment and nitrogen fixation. For an AI based implementation and model development, the basics of photon capture and charge transfer characteristics of photocatalytic materials, right from biological systems to organic/inorganic solar cells are crucial. This had been very thoroughly worked by compelling computational model and theories. The AI-ML based approaches have been instrumental in identification, screening, scrutiny of advanced materials, especially MXenes for varied applications via the supervised, unsupervised and reinforcement learning techniques. These exercises have provided the models that can be potentially more equipped for parallelly performing the classification and regression with a higher prediction accuracy. Use of advanced deep learning techniques have aided in establishing relation between structure-feature-properties and applications for MXenes based materials. Finally, a Criteria based AI aided Decision Support System is also discussed that prioritises environmentally sound and green MAX phase precursors for the development of photocatalytic materials. This will aid in developing technically feasible, economically viable and environmentally sustainable approaches for MXenes commercialization targeting environmentally friendly photocatalytic applications, thereby achieving sustainability development goals.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"7 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143031316","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Controllable synthesis of layered double hydroxides: From macroscopic morphology to microscopic coordination at the atomic level","authors":"Sha Bai, Guihao Liu, Tianyang Shen, Zhaohui Wu, Wei Chen, Yu-Fei Song","doi":"10.1016/j.ccr.2025.216437","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.216437","url":null,"abstract":"Layered double hydroxides (LDHs), as a typical inorganic two-dimensional layered material, have been widely studied in the fields of photoelectrocatalysis, energy, and environment due to their unique layered structure and excellent catalytic activity. In addition, the flexible and adjustable laminate composition of LDHs, the flexible anion exchange and column-supported exfoliation of the domain-limited space allow the reactivity of LDHs to be modulated with the changes in their composition, size, thickness, morphology, etc. Therefore, the precise synthesis of LDHs from macroscopic to microscopic is the key to promoting their development in fundamental science and industrial application. Herein, we summarize the controllable synthesis methods of LDHs in recent years, including the precise tuning strategies of macroscopic structure, such as morphology, size, thickness, etc. Furthermore, controllable preparation strategies of coordination structure at the atomic level, including the intercalation ions, coordination number, and coordination environment were also reviewed. Meanwhile, the application of synthesized LDHs with specific structures in photocatalysis, batteries, environment, and other fields has also been mentioned. Finally, the major challenges and prospects of LDHs are discussed in terms of further improving the controllability of precise synthesis.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"57 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143020059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Surface site design in photocatalytic carbon conversion applications","authors":"Yi Zhang, Yixing Zhou, Molly Meng-Jung Li, Jun Di","doi":"10.1016/j.ccr.2025.216459","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.216459","url":null,"abstract":"Photocatalysis offers innovative solutions to the pressing issues of energy scarcity and environmental pollution. Many photocatalytic reactions are related to the carbon conversion process. Therefore, the targeted construction of reaction-oriented photocatalysts is both meaningful but challenging. This review summarizes the most recent research achievements in the design of surface active sites on photocatalysts. The main functions of custom-made sites are described in details, such as light absorption, charge separation and interfacial reaction properties. Various methods for achieving precise site design on photocatalytic substrates are compiled, including surface exposure, interacting force, chemical bonding, multi-step integration and hybridization modification. Moreover, the review delves into the integral relationship between site design and photocatalytic applications, viewed through the lens of carbon atoms state transitions during reactions. Ultimately, we provide a prospective outline of the current challenges of site design and suggest potential trajectories for future investigations.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"142 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143026671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}