Coordination Chemistry Reviews最新文献

{"title":"Unveiling the photocatalytic properties of cadmium oxide for sustainable approach towards water remediation: A review","authors":"Suresh Kumar ,&nbsp;Vikas Dhiman ,&nbsp;Raman Kumar ,&nbsp;Sarabjeet Kaur ,&nbsp;Prianka Sharma ,&nbsp;Kulvinder Singh","doi":"10.1016/j.ccr.2025.216713","DOIUrl":"10.1016/j.ccr.2025.216713","url":null,"abstract":"<div><div>The current state of water resources demonstrates the contamination caused by industrial wastewater draining's supremacy. Because of the serious health and environmental risks caused by the contaminated waterways, a workable solution is needed to address its effect. This review paper presents a comprehensive investigation of the photocatalytic applications of CdO based nanomaterials, including undoped CdO, doped CdO, and CdO coupled with other semiconductors. Through a systematic analysis, we elucidate the diverse characteristics of these nanomaterials, shedding light on their potential applications in various fields. Moreover, this review explores the promising prospects of utilizing CdO-based nanomaterials for environmental remediation, particularly in the photodegradation of textile dyes. Higher the carrier concentration, higher intrinsic mobility, greater transparency of CdO, its tunable band gap and large surface area are its distinguishable characteristics that make it a promising candidate for photocatalytic applications. By leveraging their unique properties, CdO-based nanomaterials offer a sustainable and efficient approach towards addressing environmental challenges associated with textile dye pollution.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216713"},"PeriodicalIF":20.3,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143868519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Toward rational design of ionic liquid/Metal-Organic Framework composites for efficient gas separations: Combining molecular modeling, machine learning, and experiments to move beyond trial-and-error","authors":"Nitasha Habib ,&nbsp;Hasan Can Gulbalkan ,&nbsp;Ahmet Safa Aydogdu ,&nbsp;Alper Uzun ,&nbsp;Seda Keskin","doi":"10.1016/j.ccr.2025.216707","DOIUrl":"10.1016/j.ccr.2025.216707","url":null,"abstract":"<div><div>This review presents a comprehensive overview of the emerging field of ionic liquid/metal-organic framework (IL/MOF) composites, which synergistically combine the unique properties of two material families, ILs and MOFs, for adsorption- and membrane-based gas separation applications. ILs, with their low volatility and tunable chemical properties, enhance the functionality of MOFs, which are highly porous materials characterized by their large surface areas and adjustable pore sizes. The effective integration of these two materials through various synthesis techniques has led to the development of novel IL/MOF composites exhibiting superior gas adsorption and separation capabilities, particularly for CO₂ capture, compared to pristine MOFs. The use of these composites as fillers in polymers resulted in mixed matrix membranes with enhanced selectivities. This field is advancing rapidly, yet the design of IL/MOF composites still relies on a trial-and-error approach. After providing an overview of the current state-of-the-art in gas separation applications of IL/MOF composites, we specifically focused on the pivotal role of computational studies in both complementing and, beyond that, guiding the experimental design of novel IL/MOF composites. The importance of harnessing experiments, computational modeling, and machine learning methods to accelerate the discovery of new IL/MOF composites as adsorbents and membranes was discussed with recent examples. Finally, we addressed the current challenges and future opportunities in this rapidly evolving field, emphasizing the significant potential of IL/MOF composites to revolutionize the current gas adsorption and separation technologies.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216707"},"PeriodicalIF":20.3,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143868520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Macrocyclic arene-based metal-organic cages","authors":"Yujuan Zhou ,&nbsp;Jie Yang ,&nbsp;Kecheng Jie","doi":"10.1016/j.ccr.2025.216726","DOIUrl":"10.1016/j.ccr.2025.216726","url":null,"abstract":"<div><div>This review explores the field of discrete metal-organic cages (MOCs) constructed using macrocyclic arenes (MAs) as key structural components, a subject that has garnered significant interest in recent years because of their fascinating architectures, precisely structured cavities, along with extensive utility in molecular recognition, host-guest interactions, catalysis, and gas separation, and so on. The review highlights recent advancements in the synthesis of MA-based MOCs, emphasizing two principal assembly approaches: (i) the direct coordination of macrocyclic arenes with metal ions, and (ii) the integration of macrocyclic arenes with metal ions and additional linkers. The discussion is organized according to the types of macrocyclic arenes utilized, including calixarenes, resorcinarenes, pyrogallolarenes, cyclotriveratrylenes, and pillararenes, with a focus on formation mechanisms, structural features, structure-function relationships, and applications of these MA-based MOCs. Additionally, the review addresses current existing challenges in the field and provides perspectives on future directions for the development and utilization of MA-based MOCs.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216726"},"PeriodicalIF":20.3,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143868521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Cu(I) chelators: Useful tools to reveal and control Cu(I) homeostasis and toxicity","authors":"Charlène Esmieu ,&nbsp;Sarah Hostachy ,&nbsp;Christelle Hureau","doi":"10.1016/j.ccr.2025.216684","DOIUrl":"10.1016/j.ccr.2025.216684","url":null,"abstract":"<div><div>Copper (Cu) is an essential trace element for numerous biological processes, including energy production, aerobic respiration, and antioxidant defense. Despite its importance, disruptions in Cu homeostasis can lead to severe pathological conditions, such as Wilson's disease (WD), Menkes disease (MD), Alzheimer's disease (AD), and cancer. The present review focuses on the role of Cu(I) probes and chelators as molecular tools for understanding and managing copper-related toxicity and misregulation. It provides an overview of Cu(I) coordination chemistry, trafficking pathways, and the dual toxicity mechanisms of Cu (both ROS-dependent and ROS-independent). Key experimental approaches to study Cu(I), including chromophoric and fluorescent probes, are highlighted, with a focus on their design, applications, and limitations. Finally, the therapeutic potential of Cu(I)-targeting ligands is discussed, showcasing their role in fighting oxidative stress and restoring metal homeostasis in diseases. Hence, this review offers a comprehensive perspective on Cu(I) chelation's role in advancing both fundamental understanding and therapeutic strategies against copper-related disorders.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216684"},"PeriodicalIF":20.3,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143863796","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Application of metal polyphenol nanonetworks in phototherapy","authors":"Gen Li ,&nbsp;Meng Cui ,&nbsp;Chunxiu Cai ,&nbsp;Ning Zhang ,&nbsp;Siyu Chen ,&nbsp;Zijia Wang ,&nbsp;Quan Liu ,&nbsp;Xiangyu Zhang ,&nbsp;Shenzhen Ren ,&nbsp;Hailong An","doi":"10.1016/j.ccr.2025.216743","DOIUrl":"10.1016/j.ccr.2025.216743","url":null,"abstract":"<div><div>Phototherapy, characterized as a minimally invasive and highly selective therapeutic modality, encounters significant challenges, primarily due to constraints related to light penetration and treatment specificity. Metal-Phenolic Networks (MPNs), synthesized through dynamic coordination between polyphenols and transition metals, present a versatile platform for phototherapy applications. In contrast to conventional nanomaterials, MPNs offer distinct advantages, including exceptional tunability, facilitating precise modulation of composition, optical characteristics, and therapeutic efficacy. This review specifically emphasizes innovations pertaining to MPNs within the phototherapy domain, examining how they address traditional bottlenecks through biointerface engineering, tailored photophysical properties, multimodal synergy, and phototherapy-guided bioimaging. Furthermore, we analyze the specific applications of MPNs across various phototherapeutic strategies, highlighting recent advancements in photothermal therapy (PTT), photodynamic therapy (PDT), bioimaging, and additional phototherapeutic modalities. Finally, we summarize the prevailing findings and provide a perspective on the future development of MPNs. Unlike other reviews primarily focused on material synthesis and tumor therapy, this comprehensive exploration elucidates the unique value and significant advantages of MPNs within the phototherapy landscape, offering novel insights and avenues for future research and clinical applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216743"},"PeriodicalIF":20.3,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143863793","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Detection and degradation of phenolic compounds based on metal-organic complexes","authors":"Tong-Qing Chai ,&nbsp;Guo-Ying Chen ,&nbsp;Mao-Ling Luo ,&nbsp;Huan Zhu ,&nbsp;Ting-Ting Li ,&nbsp;Jia-Xin Li ,&nbsp;Lei Xu ,&nbsp;Jing-Jing Dai ,&nbsp;Li-Xian Li ,&nbsp;Feng-Qing Yang","doi":"10.1016/j.ccr.2025.216721","DOIUrl":"10.1016/j.ccr.2025.216721","url":null,"abstract":"<div><div>Phenolic compounds are a category of aromatic substances that serve various purposes, including pharmaceuticals, disease markers, pesticides, endocrine disruptors, and industrial chemical feedstocks. Consequently, accurately measuring and effectively breaking down these compounds holds significant research importance. Metal-organic complexes (MOCs), which consist of metal centers and organic ligands, offer several benefits, such as excellent stability, adjustability, and ease of preparation and functionalization. These complexes display unique properties in the analysis and treatment of phenolic compounds. This paper provides a comprehensive review of the synthesis processes, performance characteristics, and activity regulation strategies of various MOCs from 2019 to 2024. The MOCs included in this review are monometallic MOCs, bimetallic MOCs, metal nanomaterials@MOCs, metal oxides/sulfides@MOCs, MOCs@MOCs, and molecularly imprinted polymers (MIPs)@MOCs, immobilized MOCs, calcined MOCs, and others. Based on these multifunctional MOCs, a range of methods and technologies have been developed to accurately detect and effectively degrade phenolic compounds. The quantitative assays include colorimetric analysis, colorimetric sensor array (CSA), fluorescence, electrochemical, surface-enhanced Raman scattering (SERS), electrochemiluminescence (ECL), chemiluminescence (CL), high-performance liquid chromatography (HPLC), and multi-mode detection. The efficient degradation technologies include advanced oxidation processes of catalyst activation oxygen sources (CAO-AOP), photocatalytic degradation, and enzyme-like catalyzed degradation. The underlying principles, strengths, weaknesses, and improvements of these detection methods and degradation techniques are thoroughly examined. Furthermore, the limitations of existing research and future trends are discussed from various viewpoints. This review aims to foster the creation of innovative multifunctional MOCs and to enhance methods for detecting and degrading phenolic compounds.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"538 ","pages":"Article 216721"},"PeriodicalIF":20.3,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143860252","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advances in ZIF-8 variants: Synthesis, design, and applications in gas sensing","authors":"Waheed Ahmad ,&nbsp;Muhammad Tahir ,&nbsp;Batoul Bibi ,&nbsp;Fengming Gong ,&nbsp;Liang He ,&nbsp;Hui Tang ,&nbsp;Longbing Qu ,&nbsp;Fazal Ul Nisa ,&nbsp;Mizna Naseem ,&nbsp;Habib Ullah ,&nbsp;Saira Manzoor ,&nbsp;Jibing Chen ,&nbsp;Kaiqing Zhang ,&nbsp;Zhen Peng ,&nbsp;Zeyu Ma ,&nbsp;Arif Ullah Khan ,&nbsp;Yibo Xiong ,&nbsp;Muhammad Sabir ,&nbsp;Xin Tang ,&nbsp;Jun Dai","doi":"10.1016/j.ccr.2025.216733","DOIUrl":"10.1016/j.ccr.2025.216733","url":null,"abstract":"<div><div>Zeolitic imidazolate framework-8 (ZIF-8), a subgroup of metal-organic frameworks, has garnered significant focus due to its remarkable structural tunability, chemical stability, and high surface area. These attributes make ZIF-8 and its derivatives desirable materials for drug delivery, catalysis, absorption of different gases, and gas sensing applications. This review comprehensively explains the current advances in the synthesis of ZIF-8 and its derivatives, emphasizing the various approaches, including solvothermal, mechanochemical, sonochemical, and seed-assisted methods, etc. The influence of critical parameters like linkers, solvents, pH, temperature, reaction flow rate, viscosity, interfacial tension, and reaction conditions on the morphology and performance of ZIF-8 is systematically analyzed. Furthermore, it explores the roles of ZIF-8-based materials in electrochemical sensing, highlighting their performance in sensing gases such as CO₂, NH₃, H₂S, volatile organic compounds, NO₂, and H₂. The mechanisms behind the sensing capabilities of pure, composite, and hybrid ZIF-8 are explained, emphasizing the structure-property relationship and the development of composites. Challenges such as reproducibility, scalability, and environmental stability are also addressed, alongside prospects for integrating ZIF-8 into next-generation gas sensors. This review provides insight into the synthesis-application nexus, aiming to guide future research towards the rational design of ZIF-8-based gas sensors with improved performance and practical utility.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"539 ","pages":"Article 216733"},"PeriodicalIF":20.3,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143863795","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nanotechnology applications in the regulation of metabolic diseases","authors":"Yan Li ,&nbsp;Yongfei Fan ,&nbsp;Haibo Yang ,&nbsp;Jiao Chang ,&nbsp;Meng Li ,&nbsp;Feng Peng ,&nbsp;Dong Xie ,&nbsp;Zhongmin Tang","doi":"10.1016/j.ccr.2025.216736","DOIUrl":"10.1016/j.ccr.2025.216736","url":null,"abstract":"<div><div>Metabolic diseases—such as diabetes mellitus, cardiovascular diseases, obesity, gout, and thyroid disorders—are characterized by disruptions in normal metabolic processes. Traditional regulation of these conditions often faces challenges like adverse side effects, limited patient adherence, and suboptimal efficacy; for instance, conventional diabetes therapies can lead to hypoglycemia and require frequent dosing, affecting patient compliance. Nanotechnology offers innovative solutions by leveraging nanomaterials for targeted drug delivery and controlled release, while also harnessing their intrinsic properties—including catalytic activity for redox modulation, regulation of lipid and glucose metabolism, and photothermal conversion—to address current shortcomings and introduce new therapeutic possibilities. This review explores how nanotechnology can overcome existing limitations in the regulation of metabolic diseases by enhancing drug stability and bioavailability, and by leveraging the intrinsic antioxidant and anti-inflammatory properties of nanomaterials. By examining recent advancements, the review highlights the significant potential of nanotechnology to transform the management and regulation of metabolic health disorders, offering more precise, effective, and patient-friendly therapies.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"538 ","pages":"Article 216736"},"PeriodicalIF":20.3,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143860250","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biocompatible lipid nanovehicles for preventive and therapeutic vaccine development","authors":"Yaru Jia ,&nbsp;Ziran Zhou ,&nbsp;Luksika Jiramonai ,&nbsp;Jianxin Chen ,&nbsp;Qian Hua ,&nbsp;Mengliang Zhu ,&nbsp;Jinchao Zhang ,&nbsp;Xing-Jie Liang","doi":"10.1016/j.ccr.2025.216718","DOIUrl":"10.1016/j.ccr.2025.216718","url":null,"abstract":"<div><div>Vaccines are widely recognized as one of the most economical and time-efficient medical interventions. Lipid-based nanovehicles have emerged as transformative platforms in clinical applications due to their unique biocompatibility, precision-designed delivery efficacy, and scale-up accessibility for mass production. These nanovaccines are actively being developed for the prevention of infectious diseases and the immunotherapy for conditions such as cancers. This review provides a comprehensive overview of lipid-based nanovaccines, covering their material sources, classification of delivery vehicles, and unique advantages. Lipid-based nanovehicles are highlighted for their ability to enhance antigen stability, improve immune response precision, and enable diverse administration routes, including intramuscular, subcutaneous, oral, and inhalation methods. Additionally, lipid-based nanovaccines in the aspect of clinical application are discussed, emphasizing their potential in the optimization of immune responses, reducing adverse effects, and overcoming physiological barriers. The development of lipid-based nanovaccines faces some challenges, including balancing safety, efficacy, and production scalability. Therefore, further strategies, such as targeted delivery, intelligent controlled release, and adjuvant incorporation, crucially contribute to the advancement of preventive and therapeutic vaccines.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"538 ","pages":"Article 216718"},"PeriodicalIF":20.3,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143860251","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Exploration of bismuth-based nanomaterials: From fundamental concepts to innovative synthesis techniques and emerging applications","authors":"Muhammad Khan ,&nbsp;Xiaohui Sun ,&nbsp;Muhammad Kashif ,&nbsp;Amir Zada ,&nbsp;Shohreh Azizi ,&nbsp;Ahmed H. Ragab ,&nbsp;Mostafa A. Taher ,&nbsp;Qumber Abbas ,&nbsp;Khurram Shehzad","doi":"10.1016/j.ccr.2025.216687","DOIUrl":"10.1016/j.ccr.2025.216687","url":null,"abstract":"<div><div>Bismuth-based nanoparticles have been the subject of recent scientific research due to their exceptional characteristics and diverse applications, which have sparked a new materials revolution in the nanotechnology sphere. These materials demonstrate exceptional chemical stability, low toxicity, and diverse electronics features for nemerous applications. This article thoroughly reviews the prospects of bismuth-based nanostructures and nanocomposites. A detailed information on various synthesis techniques of bismuth-based nanomaterials is provided here. The merits and demerits of each strategy are thoroughly evaluated, allowing for an in-depth knowledge of the most effective approaches. The review emphasizes the diverse uses of bismuth-based nanomaterials in medical and healthcare fields, advancement in the scaffold and regenerative solutions in tissue engineering, in the efficient degradation of toxic pollutants for environmental remediation, and in solar cells. In addition, this review provides information on the unique features of bismuth-based nanomaterials for enhancing performance and sensitivity of supercapacitors and sensors, respectively. Utilizing them in agriculture can result in enhance crop protection and increase output. This review seeks to offer significant insights to researchers and professionals, promoting innovation and sustainable progress in the growing field of nano-science and nanotechnology.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"538 ","pages":"Article 216687"},"PeriodicalIF":20.3,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143855963","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}