Coordination Chemistry Reviews最新文献

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Defect and non-metallic doping co-engineering in two-dimensional transition-metal carbide-based electrocatalysts for renewable energy conversion 可再生能源转换二维过渡金属碳化物电催化剂的缺陷与非金属掺杂协同工程
IF 20.6 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-10-14 DOI: 10.1016/j.ccr.2025.217254
Tai Thien Huynh, Hau Quoc Pham
{"title":"Defect and non-metallic doping co-engineering in two-dimensional transition-metal carbide-based electrocatalysts for renewable energy conversion","authors":"Tai Thien Huynh, Hau Quoc Pham","doi":"10.1016/j.ccr.2025.217254","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.217254","url":null,"abstract":"As an emerging member of the two-dimensional (2D) material family, MXenes have gained significant attention for electrocatalysis because of their unique physical and chemical properties; however, their practical performance is often restricted by nanosheet restacking and inherently low intrinsic activity. To address these challenges, defect and non-metallic doping co-engineering are of interest as efficient strategies to improve the electrocatalytic performance of 2D MXenes. We herein comprehensively and critically discuss theoretical and experimental advances involved in the mechanism, characteristics, fabrication strategies, and applications of defect and doping co-engineered MXene-based materials for electrochemical reactions. Furthermore, the synergistic effects of defects and non-metallic dopants on the electronic structure, adsorption/desorption energies of intermediates, and possible electrocatalytic mechanism on 2D MXene-based materials are highlighted. Current challenges and prospects of defect and doping co-engineered MXene-based electrocatalysts are discussed. This review aims to elucidate the nature of defect and non-metallic doping co-engineering in MXenes, offering valuable insights for designing advanced MXene-based electrocatalysts.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"53 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145283823","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent progress of enzyme-activated small-molecule fluorescent probes in biological systems 酶激活小分子荧光探针在生物系统中的研究进展
IF 20.6 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-10-14 DOI: 10.1016/j.ccr.2025.217255
Shan-Shan Zhang, Hosoowi Lee, Yongqing Zhou, Juyoung Yoon
{"title":"Recent progress of enzyme-activated small-molecule fluorescent probes in biological systems","authors":"Shan-Shan Zhang, Hosoowi Lee, Yongqing Zhou, Juyoung Yoon","doi":"10.1016/j.ccr.2025.217255","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.217255","url":null,"abstract":"Enzymes are specialized biological macromolecules with catalytic functions that play crucial roles in supporting normal physiological activities. Dysregulated enzyme activity is directly connected with the onset and progression of numerous diseases. To investigate their distribution, expression levels, and underlying mechanisms of enzyme in living organisms, developing a credible strategy method for detecting enzyme activity is momentous. Fortunately, small-molecule fluorescent probes demonstrated significant advantages in the detection of enzyme activity, including high sensitivity, satisfactory biocompatibility, <em>in suit</em> and real-time detection. Moreover, based on the easy modifying their structures, small-molecule fluorescent probes can meet various needs for monitoring enzyme fluctuations in living systems, facilitating the exploration of its physiological function in specific diseases, providing vital information for personalized therapy. Therefore, this review aims to summarize the design strategies, identification principles, applications, and pathophysiological mechanisms of representative enzyme-activatable small-molecule fluorescent probes. Our ultimate goal is conduced to prepare high-quality fluorescent probes, which are served as powerful tools for the early warning and therapy of certain diseases.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"43 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145283883","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing the sensitivity of radiotherapy in non-small cell lung cancer through nanotechnology-mediated reactive oxygen species generation 通过纳米技术介导的活性氧生成增强非小细胞肺癌放疗的敏感性
IF 20.6 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-10-14 DOI: 10.1016/j.ccr.2025.217234
Xueying Bao, Zhuangzhuang Zheng, Man Li, Xuanzhong Wang, Qin Zhao, Huanhuan Wang, Ying Xin, Xin Jiang
{"title":"Enhancing the sensitivity of radiotherapy in non-small cell lung cancer through nanotechnology-mediated reactive oxygen species generation","authors":"Xueying Bao, Zhuangzhuang Zheng, Man Li, Xuanzhong Wang, Qin Zhao, Huanhuan Wang, Ying Xin, Xin Jiang","doi":"10.1016/j.ccr.2025.217234","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.217234","url":null,"abstract":"Radiotherapy (RT) is the cornerstone treatment for non-small cell lung cancer (NSCLC); however, the intrinsic radiation resistance of NSCLC and the inherent limitations of RT frequently lead to suboptimal therapeutic outcomes and poor clinical prognoses. RT primarily eliminates tumors by generating reactive oxygen species (ROS), which trigger oxidative cell death. Exogenous ROS-inducing agents can amplify this effect by exceeding the oxidative stress threshold in cancer cells, potentially enabling dose reduction and minimizing damage to surrounding healthy tissue. Despite this potential, conventional ROS inducers are hampered by poor solubility, low targeting specificity, and systemic toxicity, all of which limit their clinical applicability. Recent advances in nanomedicine have facilitated the development of nanotechnology-based strategies for ROS generation, offering promising alternatives to overcome these limitations. This review elucidates the mechanisms of ROS-mediated cell death and identifies key targets within the redox homeostasis network. It also evaluates therapeutic strategies for modulating these targets and highlights the advantages of nanodelivery systems, focusing on material properties, mechanistic insights, recent innovations, and the respective strengths and limitations of various ROS-generating nanoplatforms in radiosensitizing NSCLC. Finally, the review discusses future perspectives and outstanding challenges, providing a conceptual framework for the clinical translation of ROS-based radiosensitization strategies in NSCLC therapy.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"78 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145283824","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The application of carbon dot-based nanoprobes in advanced optical imaging and multimodality imaging 碳点纳米探针在先进光学成像和多模态成像中的应用
IF 20.6 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-10-13 DOI: 10.1016/j.ccr.2025.217256
Yupeng Shi, Miaoqing Li, Ruiyang Zhang, Yaning Xia, Mengyang Zhou, Rui Cao, Yong Zhang
{"title":"The application of carbon dot-based nanoprobes in advanced optical imaging and multimodality imaging","authors":"Yupeng Shi, Miaoqing Li, Ruiyang Zhang, Yaning Xia, Mengyang Zhou, Rui Cao, Yong Zhang","doi":"10.1016/j.ccr.2025.217256","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.217256","url":null,"abstract":"Carbon dots (CDs), as versatile fluorescent nanomaterials, demonstrate immense potential for revolutionizing bioimaging due to their facile synthesis, excellent photophysical properties, biocompatibility, and tunable surface chemistry. Their high quantum yield, superior photostability, and tunable emission wavelengths make them ideal materials for highly sensitive fluorescence imaging, including confocal microscopy and super-resolution imaging techniques, enabling detailed subcellular visualization. Their unique fluorescence lifetime characteristics also facilitate fluorescence lifetime imaging microscopy (FLIM) for sensing microenvironments and multiplexing. Furthermore, CDs excel in multiphoton excitation microscopy (MPEM), utilizing their large multiphoton absorption cross-sections for deep-tissue imaging with reduced background and photodamage. Crucially, the ease of functionalizing CDs allows for their integration with other contrast agents (e.g., magnetic nanoparticles, radionuclides, photosensitizers), enabling the construction of sophisticated multimodal nanoprobes. These probes synergistically combine the high sensitivity and resolution of optical imaging with the deep penetration capabilities of techniques such as magnetic resonance imaging (MRI), positron emission tomography (PET), computed tomography (CT), and photoacoustic imaging (PAI). Such multimodal systems provide complementary anatomical, functional, and molecular information, significantly enhancing diagnostic accuracy and enabling real-time image-guided interventions. This review focuses on the applications of CD-based nanoprobes in cutting-edge advanced optical imaging and multimodality imaging technologies. It begins with a brief introduction to mainstream synthesis methods and functional modifications of current CDs. Then, based on the current research landscape, it details the applications and principles of CDs in advanced optical imaging and multimodal imaging. Moreover, we have made a brief summary of the biosafety of carbon dots in biological applications. Finally, it outlines their challenges and prospects in biomedical applications.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"34 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145283822","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Harnessing nuclear energy irradiation: tailoring advanced catalysts for environmental restoration and energy conversion 利用核能辐照:为环境恢复和能量转换定制先进催化剂
IF 20.6 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-10-13 DOI: 10.1016/j.ccr.2025.217248
Sihan Ma, Zheng Han, Xue Bai, Jianglong Kong, Guang Ran
{"title":"Harnessing nuclear energy irradiation: tailoring advanced catalysts for environmental restoration and energy conversion","authors":"Sihan Ma, Zheng Han, Xue Bai, Jianglong Kong, Guang Ran","doi":"10.1016/j.ccr.2025.217248","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.217248","url":null,"abstract":"Nuclear radiation engineering has emerged as a transformative platform technology, capitalizing on radiation-matter interaction phenomena to enable multidimensional applications. Particularly in accelerating the evolutionary trajectory of catalytic science, this modality has emerged as a pivotal enabler. Although numerous studies have documented irradiation-enabled enhancement of catalytic activity, thereby facilitating efficient environmental remediation and energy conversion implementations, systematic reviews on the improvement of catalyst performance achieved by irradiation technology are still lacking. The crux resides in the insufficient mechanistic elucidation of material structure-catalytic activity interdependencies between radiation effects and catalytic enhancement, which substantially impedes the rational exploitation of synergistic potentials in radiation-catalysis hybrid systems for broad and transformative applications. Within this background, the review systematically delineates fundamental principles governing nuclear radiation technology, radiation-enabled fabrication protocols and mechanism for catalyst synthesis, and intrinsic mechanistic relationships between irradiation effects and catalytic performance evolution. Furthermore, this review underscores the latest breakthroughs in the application of irradiation technology within the fields of energy and environmental catalysis research, aiming to showcase the forefront advancements in the interdisciplinary integration of irradiation techniques with catalytic systems. Finally, we reasonably evaluate the existing constraints of irradiation technology and its prospective future developments. Driven by continuous advancements in materials fabrication and irradiation engineering, irradiation technology is poised to assume a pivotal role across a series of critical domains in the foreseeable future.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"1 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145283819","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Catalytic electrochemical oxidation of a bio-model, 5-hydroxymethyl furfural, toward a circular plastic economy 生物模型5-羟甲基糠醛的催化电化学氧化,以实现循环塑料经济
IF 20.6 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-10-13 DOI: 10.1016/j.ccr.2025.217241
Weijin Cao, Changlong Wang, Zhiyan Hou, Yufeng Wu, Didier Astruc
{"title":"Catalytic electrochemical oxidation of a bio-model, 5-hydroxymethyl furfural, toward a circular plastic economy","authors":"Weijin Cao, Changlong Wang, Zhiyan Hou, Yufeng Wu, Didier Astruc","doi":"10.1016/j.ccr.2025.217241","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.217241","url":null,"abstract":"Electrochemical oxidation has emerged as a pivotal green technology for synthesizing 2,5-furandicarboxylic acid (FDCA). As a bio-based platform molecule prioritized by the U.S. Department of Energy, FDCA serves as a sustainable alternative to petroleum-derived terephthalic acid, facilitating the transition toward a circular plastic economy. Traditional oxidation of 5-hydroxymethylfurfural (HMF) relies on high-temperature and high-pressure conditions, resulting in significant energy consumption and environmental drawbacks. In contrast, electrochemical oxidation enables efficient conversion of hydroxymethyl and aldehyde groups to carboxyl groups through a six-electron transfer process, making it a rapidly growing research focus. This review systematically examines key advancements in the field. It distinguishes between direct and indirect oxidation pathways: direct oxidation maintains stable catalyst valence states, while indirect oxidation employs redox mediators for electron transfer. The regulatory mechanisms of electrolyte pH, composition, and substrate concentration on product selectivity are elucidated. Strategies for modulating catalytic performance are proposed, including active metal type, size, support, and coordination environment optimization. Combined with defect engineering, strain regulation, and doping techniques, these approaches significantly enhance catalytic efficiency and FDCA selectivity. Furthermore, pairing this process with hydrogen evolution or CO<sub>2</sub> reduction reactions reduces electrolysis voltage and improves energy conversion efficiency. Through life cycle assessment, the article analyzes techno-economic viability and environmental benefits. Critical challenges for industrialization are identified, including suppressing non-Faradaic biomass degradation under alkaline conditions and developing efficient reactors. Finally, the importance of interdisciplinary collaboration is emphasized. Future efforts should prioritize advanced catalyst design, precise reaction condition control, and process scale-up optimization to bridge the gap between laboratory research and industrial production.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"8 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145283821","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photocatalytic Reduction of Low-Concentration CO2: Progress and Challenges 光催化还原低浓度CO2:进展与挑战
IF 20.6 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-10-13 DOI: 10.1016/j.ccr.2025.217246
Deng Long, Jianxing Li, Guolin Qian, Liye Tang, Sihan Ma, Wentao Li, Xinglin Yu
{"title":"Photocatalytic Reduction of Low-Concentration CO2: Progress and Challenges","authors":"Deng Long, Jianxing Li, Guolin Qian, Liye Tang, Sihan Ma, Wentao Li, Xinglin Yu","doi":"10.1016/j.ccr.2025.217246","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.217246","url":null,"abstract":"The photocatalytic resource utilization of low-concentration CO<sub>2</sub> (LC-CO<sub>2</sub>) technology offers a green and environmentally friendly approach to addressing greenhouse gases in the environment. However, it currently faces several challenges, including inefficient selective adsorption of LC-CO<sub>2</sub> molecules at the interface leading to limited mass transfer, high activation energy barriers for LC-CO<sub>2</sub> on catalyst surface active sites, and low photon energy utilization and charge separation efficiencies. To address these challenges, this review provides a detailed exploration of the mechanisms for CO<sub>2</sub> adsorption/activation, reaction pathways, and photogenerated carrier dynamics, emphasizing the controlling role of the adsorption-activation step in the overall photocatalytic process. The design strategies such as enhancing CO<sub>2</sub> adsorption capacity, optimizing electronic and geometric structures, and modulating surface microenvironments are summarized. Recent studies demonstrate that constructing porous structures, surface functionalization, heterojunction engineering, facet engineering, defect engineering, and hydrophobic surface engineering can effectively enhance LC-CO<sub>2</sub> adsorption efficiency, improve the separation and migration efficiency of photogenerated carriers, and optimize reaction pathways, thereby significantly enhancing the efficiency and selectivity of photocatalytic LC-CO<sub>2</sub> reduction. Furthermore, interdisciplinary integration should be pursued, leveraging advanced scientific technologies such as machine learning and artificial intelligence to accelerate the discovery and optimization of novel materials and advance research to improve photocatalytic LC-CO<sub>2</sub> reduction research. The aim of this review is to provide relevant design insights for photocatalytic LC-CO<sub>2</sub> reduction research.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"19 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145283820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in coordination engineering of M-N-C single atom catalysts for superior oxygen reduction performance 优异氧还原性能的M-N-C单原子催化剂配位工程研究进展
IF 20.6 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-10-12 DOI: 10.1016/j.ccr.2025.217244
Anuj Kumar, Naina Goyal, Sanjay Mathur, Ibragimov Aziz Bakhtiyarovich, Yufeng Zhao, Mohammad Khalid, Mohd Ubaidullah, Abdullah M. Al-Enizi
{"title":"Advances in coordination engineering of M-N-C single atom catalysts for superior oxygen reduction performance","authors":"Anuj Kumar, Naina Goyal, Sanjay Mathur, Ibragimov Aziz Bakhtiyarovich, Yufeng Zhao, Mohammad Khalid, Mohd Ubaidullah, Abdullah M. Al-Enizi","doi":"10.1016/j.ccr.2025.217244","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.217244","url":null,"abstract":"The oxygen reduction reaction (ORR) is a cornerstone of sustainable energy conversion technologies, such as fuel cells, metal–air batteries, and green synthesis of H<ce:inf loc=\"post\">2</ce:inf>O<ce:inf loc=\"post\">2</ce:inf>. However, the widespread adoption of ORR is hindered by persistent challenges in terms of catalytic activity, selectivity, and durability of the catalysts. A transformative approach to overcome these limitations is the chemical engineering of metal‑nitrogen‑carbon single-atom catalysts (M-N-C SACs), which allows precise tuning of electronic structures and coordination environments to mimic the efficiency of natural metalloenzymes. The electronic structure of M-N-C SACs can be modulated by incorporation of heteroatoms (e.g., S, B), which alter the d-band structure to enhance O<ce:inf loc=\"post\">2</ce:inf> adsorption and O<ce:glyph name=\"sbnd\"></ce:glyph>O bond cleavage, consequently reducing the overpotential for ORR. Atomic-scale engineering of bond lengths, coordination numbers, and electronic states in metal‑nitrogen‑carbon single-atom catalysts (M-N-C SACs) significantly improves their ORR performance. Specifically, the engineering of the first and higher coordination spheres through ligand design or hetero-element doping enhances charge transfer dynamics and selectivity of 4e- process, which is a key step in ORR. This review systematically evaluates the influence of coordination engineering in M-N-C SACs on benchmark ORR metrics, while highlighting breakthroughs in <ce:italic>operando</ce:italic> techniques and advanced electron microscopy that resolve active-site dynamics under working conditions. This study highlights the integration of density functional theory (DFT) predictions with experimental validation to demonstrate the synergy between tailored coordination environments and catalytic activity. Finally, the existing challenges, such as the scalability of defect-engineered SACs and their long-term stability in acidic media, are discussed in the context of emerging catalytic materials. In addition, the opportunities in machine learning-guided design and plasma-enhanced synthesis of hierarchical N-doped carbons for electrode engineering are discussed.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"40 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145261846","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
From material-derived to artificial intelligence-empowered intelligent hydrogels 从材料衍生到人工智能智能水凝胶
IF 20.6 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-10-12 DOI: 10.1016/j.ccr.2025.217198
Shiwei Zheng, Zhiwei Zhu, Da-Wen Sun
{"title":"From material-derived to artificial intelligence-empowered intelligent hydrogels","authors":"Shiwei Zheng, Zhiwei Zhu, Da-Wen Sun","doi":"10.1016/j.ccr.2025.217198","DOIUrl":"https://doi.org/10.1016/j.ccr.2025.217198","url":null,"abstract":"Material-derived intelligent hydrogels have demonstrated remarkable application potential in biomedicine, flexible electronics, food, and other fields due to their dynamic response capabilities to external environmental factors. In recent years, machine learning (ML)-empowered intelligent hydrogels have promoted the transformation of material-derived intelligent hydrogels into intelligent systems with “intelligent design-perception-decision” functions. However, previous studies have focused on the intelligent response mechanisms and regulatory optimization of material-derived hydrogels, lacking a systematic review of ML-empowered intelligent hydrogel systems. This review combines material-derived intelligent hydrogels with ML systematically reviews their regulation strategies ML-empowered mechanisms and practical applications and points out the main challenges and future research directions. Starting from the material derivation mechanism, it elucidates how the mechanism supports basic intelligent responses. Then, macroscopic regulation methods for shape changes are discussed, including swelling/shrinking, bending, rigidity, and self-healing capabilities. Additionally, advanced ML-empowered intelligent hydrogel systems are highlighted, discussing ML in intelligent hydrogel systems, data-driven material design, and intelligent analysis of multi-dimensional response behaviors. Finally, this paper summarizes the innovative applications of ML-empowered intelligent systems in multiple fields and proposes the challenges and prospects they face.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"5 8 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2025-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145261884","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Lanthanide f-orbitals in MOFs: Unlocking multifunctionality for corrosion protection, energy storage, and smart sensing mof中的镧系f轨道:解锁防腐,储能和智能传感的多功能
IF 23.5 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-10-11 DOI: 10.1016/j.ccr.2025.217221
Fatemeh Haj sadeghi , Helia Heydarinasab , Vahid Haddadi-Asl , Hossein Eivaz Mohammadloo , Bahram Ramezanzadeh
{"title":"Lanthanide f-orbitals in MOFs: Unlocking multifunctionality for corrosion protection, energy storage, and smart sensing","authors":"Fatemeh Haj sadeghi ,&nbsp;Helia Heydarinasab ,&nbsp;Vahid Haddadi-Asl ,&nbsp;Hossein Eivaz Mohammadloo ,&nbsp;Bahram Ramezanzadeh","doi":"10.1016/j.ccr.2025.217221","DOIUrl":"10.1016/j.ccr.2025.217221","url":null,"abstract":"<div><div>The distinct electrical and magnetic characteristics of its lanthanide (Ln<sup>3+</sup>) ions have made lanthanide-based Metal-Organic Frameworks (Ln-MOFs) an important family of materials. This paper offers a thorough summary of how these ions' unique f-orbitals allow for a variety of innovative applications, especially in the areas of energy storage, corrosion prevention, and smart sensing. After providing an overview of the synthesis processes of Ln-MOFs, which frequently involve solvothermal or hydrothermal methods, the paper provides a detailed account of their complex structures, emphasizing their large surface areas, high porosity, and adjustable frameworks. The coordination chemistry basics of these MOFs are covered in considerable detail, highlighting the vital function of the f-orbitals, which are protected from outside ligands and environments and maintain the inherent characteristics of the lanthanide ions. Their multifunctional capabilities are largely due to the persistent magnetic moments and bright, distinctive luminescence spectra that result from this shielding. The review's main focus is on the various uses of MOFs based on lanthanides. Since their porous nature allows them to incorporate corrosion inhibitors for on-demand release, lanthanide structures are being considered as possible protective coatings or self-healing systems for corrosion protection. The article looks at how they are used in energy storage in supercapacitors and batteries, where their large surface area and structural stability allow for dependable cycling performance and quick ion diffusion. Lastly, the paper explores their application in smart sensing, where Ln-MOFs' special luminescence characteristics, specifically, their long luminescence lifetimes and narrow emission bands, make them perfect for highly sensitive and selective analyte detection. The purpose of this review is to provide insights for future materials science research and development by relating the advanced functionalities of Ln-MOFs to the basic coordination chemistry of lanthanides.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"549 ","pages":"Article 217221"},"PeriodicalIF":23.5,"publicationDate":"2025-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145261887","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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