Coordination Chemistry Reviews最新文献

{"title":"Interface engineering of transition-metal-based electrocatalysts for alkaline water splitting","authors":"Lingfeng Zhang ,&nbsp;Haihua Wei ,&nbsp;Runzhi Yuan ,&nbsp;Pengfei Li ,&nbsp;Jin-Tao Ren","doi":"10.1016/j.ccr.2025.217009","DOIUrl":"10.1016/j.ccr.2025.217009","url":null,"abstract":"<div><div>As global fossil fuel reserves diminish and environmental concerns escalate, the quest for sustainable alternative energy sources has become increasingly urgent. Among various methods for hydrogen production, water electrolysis stands out as a promising approach due to its efficiency and environmental compatibility. However, the high overpotential inherent in this process necessitates additional energy input, thereby compromising overall energy conversion efficiency. Non-precious transition metals such as iron, cobalt, and nickel have emerged as attractive candidates for electrocatalysis owing to their abundant supply and diverse structural compositions. Nevertheless, their inherent challenges including low conductivity, limited catalytic activity, and a restricted number of active surface sites pose significant barriers to their widespread applications. This review focuses on the utilization of transition metal nanomaterials and employs interface engineering strategies to construct heterointerfaces, aimed at mitigating these intrinsic limitations and enhancing electrocatalytic performance. Special emphasis is placed on understanding the surface and interface effects that dictate the electrocatalytic properties of these catalysts. Types of interface structures are also categorized and introduced. Furthermore, the progress achieved in heterostructure design through interfacial component coupling effects is comprehensively summarized. Finally, in light of current advancements and applications in interface engineering strategies, the review discusses the challenges associated with future heterostructure catalysts and proposes potential solutions.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"545 ","pages":"Article 217009"},"PeriodicalIF":20.3,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144702286","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Progress of vanadium-based oxides as cathode materials for aqueous zinc-ion batteries","authors":"Hanyu Shi ,&nbsp;Hongliang Fu ,&nbsp;Guanjie Xue ,&nbsp;Yue Lian ,&nbsp;Jing Zhao ,&nbsp;Huaihao Zhang","doi":"10.1016/j.ccr.2025.216984","DOIUrl":"10.1016/j.ccr.2025.216984","url":null,"abstract":"<div><div>Aqueous zinc-ion batteries (AZIBs) present the advantages of high theoretical capacity, good safety and environmental friendliness, also with desirable application prospects in the field of energy storage. Here, vanadium-based cathode materials have attracted wide attention due to their high theoretical specific capacity and various structures. This work offers a comprehensive review of the status and research progress of vanadium-based oxides as cathode materials for AZIBs. At first, we describe the evolution of zinc-ion batteries (ZIBs) and the strengths of AZIBs. Subsequently, we elaborate the classification and Zn storage mechanisms of AZIBs cathode materials, including the mechanisms of Zn²⁺ intercalation/deintercalation, Zn²⁺/H⁺ co-insertion, chemical conversion reactions and dissolution/deposition mechanism. Among them, vanadium-based oxides mainly store energy through the first three mechanisms. Then, this review focuses on the structural characteristics of vanadium-based oxides, and introduces the research progress of vanadium-based monometallic oxides, vanadium-based bimetallic oxides, vanadium-based polymetallic oxides and other types, along with their electrochemical performances summarization. In addition, we discuss the improvement design approaches of vanadium-based oxides, such as morphology optimization, lattice optimization, heterostructure construction and so on. Finally, the shortcomings of vanadium-based oxides in current study of AZIBs cathode materials are summarized, also with their future research prospects.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"545 ","pages":"Article 216984"},"PeriodicalIF":20.3,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144710614","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent advances in the synthesis of MOF-based composites for heavy-metal ion adsorption","authors":"Jing Li ,&nbsp;Guo Lin ,&nbsp;Hua Liang ,&nbsp;Shixing Wang ,&nbsp;Tu Hu ,&nbsp;Shiwei Li ,&nbsp;Libo Zhang","doi":"10.1016/j.ccr.2025.217010","DOIUrl":"10.1016/j.ccr.2025.217010","url":null,"abstract":"<div><div>With rapid industrialization, the industrial wastewater discharge has increased considerably. Treating large volumes of wastewater containing heavy metals is challenging. Heavy metals pose significant risks to human health and various ecosystems owing to their high toxicity and resistance to degradation. A fast, efficient, and economical method for removing heavy metals is adsorption. Metal-organic frameworks (MOFs) have garnered significant attention as adsorbent materials owing to their high specific surface area, tunable pore size, and ease of modification. This review examines the advantages and limitations of traditional MOFs, and presents a comprehensive summary of composites developed to overcome these limitations. Further, the review highlights recent advancements in composite materials, including metal oxides, sulfides, chitosan, and hydrogels, and their role in enhancing the adsorption process. In addition, this review discusses the stability and key synthesis steps of each composite material, providing insights into their respective advantages and challenges. The challenges faced by MOF-based composites are analyzed and synthesis methods that facilitate improved performance and increased scope of application in wastewater treatment are recommended.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"545 ","pages":"Article 217010"},"PeriodicalIF":20.3,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144697029","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ion exchange membranes for valorizing CO2 Electroreduction: A deep dive into their pivotal role, challenges, and innovations","authors":"Sheraz Yousaf ,&nbsp;Yaogang Chen ,&nbsp;Aziz Ur Rahim Bacha ,&nbsp;Iqra Nabi ,&nbsp;Yanqin Li ,&nbsp;Zhixue Zou ,&nbsp;Yinghe Zhang ,&nbsp;Lei Yang","doi":"10.1016/j.ccr.2025.216986","DOIUrl":"10.1016/j.ccr.2025.216986","url":null,"abstract":"<div><div>The escalating atmospheric levels of carbon dioxide (CO₂) demand urgent breakthroughs in electrochemical CO₂ reduction (e-CO₂R) to convert CO₂ to value-added chemicals and fuels. Ion exchange membranes (IEMs) are crucial to optimizing e-CO₂R operations through ion conduction, charge balance, and reaction selectivity. This review provides an extensive comparison of the role, challenges, and recent advances in IEMs in the case of anion exchange membranes (AEMs), cation exchange membranes (CEMs), and bipolar membranes (BPMs) with a comparative analysis of the variations within each membrane. For AEMs, the comparison involves polymers like polysulfones, poly (arylene ether), and functional groups like quaternary ammonium to imidazolium to assess their contribution to hydroxide conductivity and alkaline stability. The comparison of fluorinated (e.g., Nafion) to non-fluorinated (e.g., sulfonated polyether ether ketone) materials follows the case of CEMs to determine proton conduction efficiency and cost. BPMs are considered through the aspect of layer composition (e.g., sulfonic acid to carboxylate interfaces) and how it affects water dissociation kinetics. The important performance characteristics like ion conductance, permselectivity, chemical stability, and mechanical durability are carefully considered within the various classes of materials. Methods like polymer backbone engineering, chemical crosslinking, nanostructured composites, and low-cost fabrication are reviewed within the frame of optimizations specific to the materials. The identification of research gaps like the lack of standardizing the comparison of the variations within the materials lays the emphasis on the need to create high-performance low-cost IEMs specific to the case of e-CO₂R to move the pursuit towards a zero‑carbon economy.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"545 ","pages":"Article 216986"},"PeriodicalIF":20.3,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144693631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Metal–organic framework-based dual-mode biosensors: Mechanisms and applications","authors":"Yi Huang ,&nbsp;Xi Sun ,&nbsp;Ziyu Zhang ,&nbsp;Chaonan Huang ,&nbsp;Lingxia Wu ,&nbsp;Weiqiang Tan ,&nbsp;Huining Chai ,&nbsp;Guangyao Zhang","doi":"10.1016/j.ccr.2025.217006","DOIUrl":"10.1016/j.ccr.2025.217006","url":null,"abstract":"<div><div>To address the growing complexity of detection scenarios, biosensing technology is transitioning from single-modal to dual-mode systems. Metal-organic frameworks (MOFs), with their high surface area, tunable pore structures, and multifunctional properties, have emerged as ideal substrates for dual-mode biosensors. Their advantages include: (1) precisely engineered coordination between metal nodes and ligands enables synergistic optical-electrochemical signal outputs; (2) intrinsic enzyme-like or photo/electrocatalytic activities (when present) can amplify detection signals through substrate conversion; (3) modular design allows simultaneous integration of signal transduction and, where applicable, catalytic functions, establishing a robust sensing synergy. This technology has been successfully applied in detecting biomolecules, pathogens, biotoxins, pesticides, heavy metals, and emerging contaminants. Current research focuses on structure-activity optimization, yet challenges remain, such as matrix interference and stability issues. Future efforts require interdisciplinary collaboration to develop intelligent MOFs, micro-nano integrated systems, and practical validation. This review systematically analyzes the synthetic strategies of MOFs for dual-mode biosensors, sensing mechanisms, current challenges, and future prospects, thereby providing theoretical and technical guidance for the design of high-precision biosensing platforms.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"545 ","pages":"Article 217006"},"PeriodicalIF":20.3,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144694786","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hydroformylation of specific substrates as a perspective route to monomers and valuable bifunctional compounds","authors":"M.V. Nenasheva ,&nbsp;E.A. Karakhanov ,&nbsp;A.L. Maximov ,&nbsp;D.N. Gorbunov","doi":"10.1016/j.ccr.2025.216990","DOIUrl":"10.1016/j.ccr.2025.216990","url":null,"abstract":"<div><div>This review considers hydroformylation as a pivotal step in the synthesis of bifunctional molecules, the majority of which are critical monomers. The synthesis of bifunctional molecules <em>via</em> hydroformylation is only possible through the transformation of specific substrates (formaldehyde, lower epoxides, 1,3-butadiene, vinyl-, acryl-, allyl-, and oleic derivatives). Consequently, the catalysts utilized and the approaches to the reaction are unique and require a detailed study for each case. The review pays close attention to the distinctive features of these transformations for each group of substrates and undertakes a thorough analysis of the progress and achievements made, while also acknowledging the limitations. Additionally, the role of significant modern developments in the field of hydroformylation, which can also be applied as a powerful and versatile tool for the transformation of more complex substrates (potential monomer precursors), is emphasized. These include the development of new phosphorus-containing ligands for highly active and regioselective homogeneous systems, approaches to tandem transformations (isomerization-hydroformylation, reductive hydroformylation, hydroaminomethylation), and the design of new stable biphasic and heterogeneous systems for simplified catalyst recycling. The most significant advances are highlighted, which may serve for the development of more atom-efficient and environmentally friendly monomer synthesis processes using the hydroformylation step.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"545 ","pages":"Article 216990"},"PeriodicalIF":20.3,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144693703","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advancing catalyst design for H₂O₂ electrosynthesis via oxygen reduction reaction","authors":"Tao Sun ,&nbsp;Xinyi Ma ,&nbsp;Zhiqi Zhang ,&nbsp;Mengxuan Li ,&nbsp;Jing Li","doi":"10.1016/j.ccr.2025.217008","DOIUrl":"10.1016/j.ccr.2025.217008","url":null,"abstract":"<div><div>The electrocatalytic reduction of O₂ presents a sustainable pathway for producing hydrogen peroxide (H₂O₂), characterized by green solvents, zero‑carbon emissions, on-site production, and environmentally friendliness. Developing catalysts that are highly selective, active, stable, and derived from low-cost, earth-abundant materials is crucial for advancing this technology. In recent years, a diverse range of such catalysts, including metal-free carbon materials, covalent organic frameworks, metal-site decorated carbon materials, metal-organic framework-based materials, and earth-abundant metal compounds, have shown promise in selectively producing H₂O₂ via the oxygen reduction reaction (ORR). This review provides a comprehensive analysis of the underlying mechanisms in the electrochemical synthesis of H₂O₂ via ORR, highlighting the role of catalysts derived from abundant and inexpensive resources. Key factors such as microstructures, electrocatalytic performance, and strategies for tuning activities are systematically discussed, with a focus on regulating dopants, surficial functional groups, catalytic site configurations, phases, defects, and heterojunction hybridization. The challenges in material synthesis and optimization are thoroughly analyzed. Finally, the review highlights the remaining hurdles in H₂O₂ production via ORR and offers future directions for designing high-performance, low-cost electrocatalysts to enable sustainable and scalable H₂O₂ production.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"545 ","pages":"Article 217008"},"PeriodicalIF":20.3,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144697030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Coordination chemistry-driven oxygen vacancy strategy for rational design of high-performance catalysts in BTX oxidation","authors":"Chenkai Dong ,&nbsp;Youcai Zhu ,&nbsp;Chunlin Qu ,&nbsp;Yuxin Chen ,&nbsp;Yingshuai Ma ,&nbsp;Yang Yu ,&nbsp;Caiting Li","doi":"10.1016/j.ccr.2025.217007","DOIUrl":"10.1016/j.ccr.2025.217007","url":null,"abstract":"<div><div>With the rapid development of modern industry, volatile organic compounds (VOCs) are used in all walks of life. The widespread dissemination of VOCs, especially benzene, toluene, and xylene (BTX), has emerged as a critical environmental issue, posing significant threats to both human health and ecological systems due to their ubiquitous distribution and persistent nature. As a result, there is an urgent need for effective treatment methods to mitigate their impact. This review focuses on catalytic oxidation, a leading technology for the treatment of low to medium concentrations of VOCs. The catalyst, as the pivotal component of this technology, has attracted substantial research attention. Among diverse strategies for enhancing catalytic performance, oxygen vacancies (OVs) engineering has emerged as a particularly promising approach. This study provides a systematic and comprehensive review, structured around five key aspects: (1) Characterization of BTX Compounds: A comprehensive analysis of their properties, sources, and environmental and health implications. (2) Catalytic Functionality of OVs: An in-depth investigation into the mechanistic role of OV engineering in promoting BTX catalytic oxidation. (3) Reaction Mechanisms: A detailed elucidation of the catalytic oxidation pathways mediated by OV-rich catalysts. (4) Data Mining: an analysis of the relationship between catalyst structural features, reaction conditions, and catalytic efficiency based on the Random Forest algorithm in machine learning (5) Coordination Engineering of OVs Catalysts: A theoretical framework for optimizing OV configurations through coordination chemistry principles. (6) Sustainability Assessment: A comprehensive evaluation of catalyst systems using integrated techno-economic analysis and life cycle assessment methodologies, identifying pathways for economic and environmental optimization. Furthermore, this work also provides a forward-looking perspective on the future of catalyst development. Through identifying critical research gaps and emerging opportunities, it aims to contribute to the advancement of next-generation VOC treatment technologies, ultimately facilitating the development of more efficient and sustainable environmental remediation solutions.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"545 ","pages":"Article 217007"},"PeriodicalIF":20.3,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144693629","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Molecular engineering of non-covalent interactions for controlled nanomaterial assembly: Chemical principles and materials design","authors":"Navid Rabiee ,&nbsp;Mohammad Rabiee","doi":"10.1016/j.ccr.2025.217005","DOIUrl":"10.1016/j.ccr.2025.217005","url":null,"abstract":"<div><div>Non-covalent interactions (NCIs) are pivotal in directing nanomaterial assembly, offering tunability and reversibility absent in traditional covalent methods. This review explores the foundational thermodynamic and kinetic principles underlying NCI-driven processes, the quantum and classical mechanical modeling used for design, characterization techniques used in evaluating nanomaterials, and the primary classes of NCIs. Key topics include coordination, π-π stacking, hydrogen bonding, and host-guest chemistry, and their interplay in controlling assembly. Emerging approaches that combine disparate NCIs or connect molecular systems to advanced computational techniques that use large datasets are also highlighted. This work examines challenges, opportunities, emerging techniques, and the use of the most sophisticated modeling to showcase the promise of these powerful methods in the ever-expanding field of soft nanomaterials.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"545 ","pages":"Article 217005"},"PeriodicalIF":20.3,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144693630","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biohybrid catalysis in biomedicine","authors":"Xiaoye Li ,&nbsp;Yu Zhang ,&nbsp;Ao He ,&nbsp;Qiang Li ,&nbsp;Siyu Wang ,&nbsp;Jingyang Shan ,&nbsp;Shengke Li ,&nbsp;Dongliang Yang ,&nbsp;Guan Wu ,&nbsp;Weijun Xiu ,&nbsp;Yuxin Liu ,&nbsp;Heng Dong","doi":"10.1016/j.ccr.2025.217003","DOIUrl":"10.1016/j.ccr.2025.217003","url":null,"abstract":"<div><div>Biohybrid catalysis has emerged as a transformative approach in biomedicine, which integrate biological components (such as enzymes, proteins, cytomembrane, or cells) with non-biological synthetic materials (such as nanozymes, metal complexes, or polymers) to address the limitations of traditional catalytic systems in terms of catalytic performance, biocompatibility, operational conditions, and specificity. This synergy enhances catalytic performance, biocompatibility, stability, and specificity, overcoming the limitations of traditional catalysts in biomedical applications. The article delves into the design and integration strategies of biohybrid catalysts, as well as their applications in antimicrobial therapy, biosensing and diagnostics, cancer treatment, treatment for reactive oxidative specie (ROS) overload-related diseases, tissue engineering, neural machine interfaces, drug delivery and prodrug activation. The future of biohybrid catalysis holds immense promise for transforming biomedical research and clinical practice. As the field continues to advance, it is expected that these hybrid systems will become increasingly integral to developing innovative therapies and diagnostic tools, ultimately improving patient outcomes.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"545 ","pages":"Article 217003"},"PeriodicalIF":20.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144684851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}