Coordination Chemistry Reviews最新文献_第3页

Water-soluble stimuli-responsive supramolecular nanoagrochemicals based on macrocycle compounds 基于大环化合物的水溶性刺激响应超分子纳米agrochemicals

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2024-11-09 DOI: 10.1016/j.ccr.2024.216299

Ya-Hui Song , Qiang Bian , Fang Wang , Jinpeng Liu , Yi-Hang Yang , Ying-Ming Zhang , Yu Liu

{"title":"Water-soluble stimuli-responsive supramolecular nanoagrochemicals based on macrocycle compounds","authors":"Ya-Hui Song , Qiang Bian , Fang Wang , Jinpeng Liu , Yi-Hang Yang , Ying-Ming Zhang , Yu Liu","doi":"10.1016/j.ccr.2024.216299","DOIUrl":"10.1016/j.ccr.2024.216299","url":null,"abstract":"<div><div>Agrochemicals are extensively utilized to ameliorate agricultural yield and quality, but they also negatively impact ecological cycle and human health as a consequence of indiscriminate pesticide usage and growing anthropogenic interference. To improve the efficiency and biosafety of existing agrochemicals, the dynamic and reversible nature of host–guest complexation with water-soluble macrocycles has been fully exploited in supramolecular chemistry to construct fascinating nanoassemblies with environmental stimuli-responsiveness. This review mainly focuses on (i) the performance-directed molecular recognition properties of common cavity-bearing macrocycles, including crown ethers, cyclodextrins, calixarenes, cucurbiturils, and pillararenes, toward a wide range of agroactive ingredients; (ii) the developmental updates in the emerging realm of macrocycle-based multistimuli-responsive supramolecular nanoagrochemicals, with an emphasis on their molecular basis, operation mechanism, and application toward a series of chemical (pH and redox), physical (photo and temperature), and biological (enzyme and reactive oxygen species) factors as internal and external stimuli relevant to plants and pests; and (iii) the encumbered challenges and perspectives on the translational development of these environmentally adaptive nanomaterials under realistic field conditions. In the wave of intelligentization of modern agricultural practices, we believe the stimuli-responsive supramolecular nanoagrochemicals is now spurring the impending agri-tech revolution at a global scale.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216299"},"PeriodicalIF":20.3,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596707","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Host-guest interactions in the confined spaces of metal–organic frameworks: Design principles, characterizations, and applications 金属有机框架密闭空间中的主客体相互作用：设计原理、特性和应用

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2024-11-08 DOI: 10.1016/j.ccr.2024.216302

Yifang Zhao , Lian Wu , Kun Wu , Rong-Jia Wei , Heng Zeng , Hao Pang , Weigang Lu , Dan Li

{"title":"Host-guest interactions in the confined spaces of metal–organic frameworks: Design principles, characterizations, and applications","authors":"Yifang Zhao , Lian Wu , Kun Wu , Rong-Jia Wei , Heng Zeng , Hao Pang , Weigang Lu , Dan Li","doi":"10.1016/j.ccr.2024.216302","DOIUrl":"10.1016/j.ccr.2024.216302","url":null,"abstract":"<div><div>Metal–organic frameworks (MOFs) are revolutionizing porous materials with their incredible structures and functionalities that have been extensively explored in many fields. Unlike traditional porous materials, MOFs offer a unique opportunity for precise design and modification of the porosities and pore environments. Their nanoscale confined spaces with specific shapes and surface functionalities can selectively interact with certain guest molecules through host-guest interactions, unlocking enhanced performance and related mechanisms that were previously undiscovered. Through advanced experimental and theoretical techniques, the high crystallinity of MOFs allows for detailed and in-depth studies of the structure-performance relationships, leading to breakthroughs in design and optimization. This review delves into recent advancements in the construction, characterization, and host-guest applications of MOF-based systems, showcasing their design strategies for remarkable functionality, porosity, and flexibility. The latest progress in adsorption, separation, catalysis, energy storage, crystalline sponge (CS), and sensing are discussed, unraveling the endless possibilities of MOFs and their challenges.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216302"},"PeriodicalIF":20.3,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596635","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Versatile POMOF-based materials: Synthesis, mechanism, topology and catalytic applications 基于 POMOF 的多功能材料：合成、机理、拓扑结构和催化应用

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2024-11-08 DOI: 10.1016/j.ccr.2024.216304

Zhengxiang Sun , Rui Wang , Ivan V. Kozhevnikov

{"title":"Versatile POMOF-based materials: Synthesis, mechanism, topology and catalytic applications","authors":"Zhengxiang Sun , Rui Wang , Ivan V. Kozhevnikov","doi":"10.1016/j.ccr.2024.216304","DOIUrl":"10.1016/j.ccr.2024.216304","url":null,"abstract":"<div><div>The interactions and contradictions among energy, resources, environment, human health and social development are perennial subjects of scientific research. Multifunctional, adjustable, and high-performance composite catalysts are an effective means of coordinating and resolving the tensions between social development, energy and the environment. Polyoxometalate chemistry, represented by polyoxometalates (POMs), has made a breakthrough due to its superior catalytic activity and wide range of applications. This has significantly promoted the combination of catalytic chemistry and production practice. Metal-organic frameworks (MOFs) are a class of porous materials that combine organic and inorganic properties. MOFs are highly crystalline and have a flexible structure with a large surface area. Combining POMs with MOFs to form POMOF-based materials offers the advantages of both materials and a synergistic effect greater than the sum of its parts. Although there have been several reviews on POMOF composites, especially in the field of catalysis, comprehensive discussions on the latest advances and specific applications remain limited. To promote the development of the field and explore the conformational relationship in depth, this review focuses on the frontiers of catalysis of POMOF-based materials. It discusses the composition, coupling strategy, and reaction mechanism of these materials using pioneering classifications and descriptions. A comprehensive review of research work in the field, classified by application areas, is presented to stimulate catalysis research and provide a new framework, new perspectives, and new horizons.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216304"},"PeriodicalIF":20.3,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596634","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Metal-polymer-coordinated complexes: An expedient class of hybrid functional materials 金属聚合物配位复合物：一类便捷的混合功能材料

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2024-11-08 DOI: 10.1016/j.ccr.2024.216286

Sandeep Kumar , Brij Mohan , Brian Musikavanhu , Xintian Wang , Raeesh Muhammad , Xuemei Yang , Peng Ren

{"title":"Metal-polymer-coordinated complexes: An expedient class of hybrid functional materials","authors":"Sandeep Kumar , Brij Mohan , Brian Musikavanhu , Xintian Wang , Raeesh Muhammad , Xuemei Yang , Peng Ren","doi":"10.1016/j.ccr.2024.216286","DOIUrl":"10.1016/j.ccr.2024.216286","url":null,"abstract":"<div><div>Innovation in materials, aided by recent advancements in science and technology, is shaping a better future. Among these, porous materials, including covalent-organic frameworks (COFs), metal-organic frameworks (MOFs), organic polymers, zeolites, silica, and metal-polymer-coordination complexes (MPCCs), have garnered significant attention due to their rigid structure and higher stability with respect to humid conditions. MPCCs have been of particular interest lately. This review first compares MPCCs to MOFs and COFs, then focuses on their synthesis and properties. It also highlights the unique characteristics that distinguish MPCCs from MOFs and organic polymers. Subsequently, it discusses the use of MPCCs in generating polymeric gels and other applications such as catalysis, sensing, and adsorption/separation of organic molecules and gases. Finally, it delves into the challenges and prospects for their design, synthesis, characterization, properties, and applications. This review aims to guide researchers in exploring the potential of porous materials in various fields.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216286"},"PeriodicalIF":20.3,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596749","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Metal-organic framework (MOF)-based materials for photocatalytic antibacterial applications 基于金属有机框架 (MOF) 的光催化抗菌应用材料

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2024-11-06 DOI: 10.1016/j.ccr.2024.216298

Tuan Duy Doan , Nhu-Nang Vu , Thi Linh Giang Hoang , Phuong Nguyen-Tri

引用次数: 0

Control of spin switchability and electron transfer in Prussian blue analogues: Insights into secondary interactions and chemical modifications 控制普鲁士蓝类似物的自旋切换性和电子转移：深入了解次级相互作用和化学修饰

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2024-11-04 DOI: 10.1016/j.ccr.2024.216283

Jyoti Yadav, Ranjan Kharel, Sanjit Konar

{"title":"Control of spin switchability and electron transfer in Prussian blue analogues: Insights into secondary interactions and chemical modifications","authors":"Jyoti Yadav, Ranjan Kharel, Sanjit Konar","doi":"10.1016/j.ccr.2024.216283","DOIUrl":"10.1016/j.ccr.2024.216283","url":null,"abstract":"<div><div>The research progress on 3D Prussian blue analogues (PBAs) and their successful downsizing using capping ligands to achieve 2D, 1D, and even discrete molecular analogues has greatly enhanced our understanding of the switchable phenomena such as spin crossover (SCO) and electron transfer coupled spin transition (ETCST) in these systems. These molecules exhibit diverse optical and magnetic properties, making them highly attractive for next-generation compact smart devices. However, better control over switchability is necessary to fulfil specific purposes. While substantial work over the past three decades has elucidated the rationale behind ETCST occurrence in some complexes but not in others, parallel investigations into the peculiar ETCST behaviour in response to subtle changes in ligand field, reaction conditions, and guest molecule size have provided improved control over parameters like H-bonding and π⋅⋅⋅π interactions. Efforts to increase the operational temperature range for chemical, thermal, piezo, and photo-responsive switchability of these molecules to practical levels and preserve their pristine properties after integration into devices require further exploration to unlock the optimisation possibilities. This review discusses factors affecting various stimuli-responsive ETCST behaviour in both solid (ligand field strength, lattice solvents, counter-ions and crystal packing) and solution phases (solvent polarity and protonation/deprotonation) with representative examples. We envisage that a better understanding of the factors controlling ETCST properties will enable precise design and targeted synthesis of these molecules.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216283"},"PeriodicalIF":20.3,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142577884","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A critical review of coordination chemistry of pyrimidine and pyridazine compounds: Bonding, chelation and corrosion inhibition 嘧啶和哒嗪化合物配位化学综述：键合、螯合和腐蚀抑制

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2024-11-02 DOI: 10.1016/j.ccr.2024.216285

Taiwo W. Quadri , Ekemini D. Akpan , Saheed E. Elugoke , Omar Dagdag , Nnaemeka J. Nnaji , Chandrabhan Verma , Lukman O. Olasunkanmi , Akram AlFantazi , Valentine Chikaodili Anadebe , Rakesh Chandra Barik , Eno E. Ebenso

{"title":"A critical review of coordination chemistry of pyrimidine and pyridazine compounds: Bonding, chelation and corrosion inhibition","authors":"Taiwo W. Quadri , Ekemini D. Akpan , Saheed E. Elugoke , Omar Dagdag , Nnaemeka J. Nnaji , Chandrabhan Verma , Lukman O. Olasunkanmi , Akram AlFantazi , Valentine Chikaodili Anadebe , Rakesh Chandra Barik , Eno E. Ebenso","doi":"10.1016/j.ccr.2024.216285","DOIUrl":"10.1016/j.ccr.2024.216285","url":null,"abstract":"<div><div>Metallic deterioration remains a formidable challenge in numerous industrial sectors, necessitating the continuous, intense search for effective, sustainable and non-toxic chemical inhibitors. Pyrimidines and pyridazines belong to a class of heterocycles that have garnered significant attention as potential corrosion inhibitors due to their versatile chemical configuration and promising protection performances. Notably, the nitrogen atoms in the six-membered heterocyclic ring of pyrimidine (C<sub>4</sub>H<sub>4</sub>N<sub>2</sub>), pyridazine (C<sub>4</sub>H<sub>4</sub>N<sub>2</sub>), and their derivatives are well known for their capacity to form coordination bonds with metal surfaces. Pyrimidine, pyridazine, and their derivatives form corrosion-inhibitive hydrophobic layers through their adsorption on the metal surfaces. The widespread conjugation of π-electrons enhances the durability and efficacy of the hydrophobic film. They demonstrate excellent inhibition efficiencies ranging from 70 to 100 % at low concentrations (<1 mM) for different metal/electrolyte systems. This review provides an overview of the properties and application of these heterocyclic compounds in chelation and coordination. Furthermore, their potential applications as aqueous phase inhibitors for different metal/electrolyte systems were comprehensively covered. Using experimental and computational tools, emphasis was placed on the coordination chemistry of pyrimidine and pyridazine, and its adsorption behaviour against metallic degradation in diverse corrosive environments was highlighted. Finally, patent literature on the effectiveness of pyrimidine and pyridazine and future perspectives were presented.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216285"},"PeriodicalIF":20.3,"publicationDate":"2024-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142566073","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

ZIF-67 derivatives in electrocatalysis 电催化中的 ZIF-67 衍生物

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2024-11-02 DOI: 10.1016/j.ccr.2024.216296

Guoliang Gao , Chengzhi Xiao , Rongrong Zhang , Wangwei Chen , Conghu Liu , Guang Zhu , Bowen Sun , Lei Dai , Andreu Cabot , Zixu Sun

{"title":"ZIF-67 derivatives in electrocatalysis","authors":"Guoliang Gao , Chengzhi Xiao , Rongrong Zhang , Wangwei Chen , Conghu Liu , Guang Zhu , Bowen Sun , Lei Dai , Andreu Cabot , Zixu Sun","doi":"10.1016/j.ccr.2024.216296","DOIUrl":"10.1016/j.ccr.2024.216296","url":null,"abstract":"<div><div>ZIF-67-derived materials, obtained by processes such as annealing, electrochemical reconstruction, and ion exchange, effectively overcome the limitations of low conductivity and stability that are inherent in ZIF-67, all while preserving their porous structure and high specific surface area. These derivatives not only address these issues but also offer the flexibility to modulate the component structure, rendering them promising candidates for electrocatalytic applications. This review delves into the novel application of ZIF-67 derivatives in conventional electrocatalysis, filling a crucial gap in the existing literature. The review begins by elucidating common strategies for catalyst modification, providing a foundation for understanding the subsequent sections. It then offers a detailed overview of the methods used to synthesize ZIF-67 derivatives, followed by a comprehensive examination of their application in electrocatalysis. This exploration covers a range of applications, including water splitting, CO<sub>2</sub> reduction, fuel cells, and metal-air batteries. Furthermore, the review analyzes how the modification and synthesis of MOF derivatives impact the microstructure and catalytic performance of these materials. Finally, the review critically assesses the challenges encountered in the integration of MOF derivatives into electrocatalytic systems and offers insights into potential future research directions. By exploring these aspects, this work aims to inspire and guide researchers in overcoming existing obstacles, thereby unlocking the full potential of MOF derivatives in the field of electrocatalysis.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216296"},"PeriodicalIF":20.3,"publicationDate":"2024-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142566072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent advances in BiFeO₃-based nanostructures: Properties and applications 基于 BiFeO₃ 的纳米结构的最新进展：特性与应用

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2024-11-01 DOI: 10.1016/j.ccr.2024.216297

Ali Khorsand Zak , Abdul Manaf Hashim

{"title":"Recent advances in BiFeO₃-based nanostructures: Properties and applications","authors":"Ali Khorsand Zak , Abdul Manaf Hashim","doi":"10.1016/j.ccr.2024.216297","DOIUrl":"10.1016/j.ccr.2024.216297","url":null,"abstract":"<div><div>Bismuth Ferrite (BiFeO₃) is a widely researched multiferroic material that exhibits ferroelectric, antiferromagnetic, and piezoelectric properties at room temperature, making it an exceptional candidate for a range of applications across multiple fields. This review explores the fundamental properties of BiFeO₃-based nanostructures, including their high Curie temperature, significant piezoelectric and photovoltaic responses, and magnetoelectric coupling. The combination of these properties enables BiFeO₃ nanostructures to be utilized in various devices, such as energy harvesting systems, optoelectronic components, and sensors. Applications in photovoltaic devices and light-emitting diodes (LEDs) further demonstrate the material's versatility and potential for innovation. Moreover, advances in thin-film fabrication techniques and interface engineering have led to improved performance and stability in BiFeO₃-based devices. Despite challenges related to carrier mobility, leakage currents, and fabrication complexity, ongoing research continues to enhance the functionality of BiFeO₃ nanostructured materials, driving their adoption in next-generation technologies. This article reviews the current state of research on BiFeO₃ nanostructures, highlighting their properties and optical applications while providing insights into their future potential in both scientific and commercial domains.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216297"},"PeriodicalIF":20.3,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142562024","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Zeolite and metal-organic framework based microporous crystalline materials in adsorption separation of C4 hydrocarbons 基于沸石和金属有机框架的微孔晶体材料在 C4 碳氢化合物吸附分离中的应用

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2024-10-30 DOI: 10.1016/j.ccr.2024.216293

Meng Zhao, Xue-Song Gu, Lanlan Sun, Yun Yang, Tong Li

{"title":"Zeolite and metal-organic framework based microporous crystalline materials in adsorption separation of C4 hydrocarbons","authors":"Meng Zhao, Xue-Song Gu, Lanlan Sun, Yun Yang, Tong Li","doi":"10.1016/j.ccr.2024.216293","DOIUrl":"10.1016/j.ccr.2024.216293","url":null,"abstract":"<div><div>The quest for energy-efficient and environmentally benign methods for separating C4 hydrocarbon mixtures has led to the exploration of porous materials, with zeolites and metal-organic frameworks (MOFs), especially MOFs at the forefront. These materials exhibit tunable pore sizes, diverse chemical functionalities, and the capacity for structural transformation in response to external stimuli, attributes that are highly desirable for separation processes. This review provides an in-depth analysis of the fundamental principles governing the adsorptive separation of C4 hydrocarbons, including thermodynamic, kinetic, molecular sieving, responsive framework separation, and guest conformation-controlled mechanisms. It also examines strategies to enhance the selectivity and stability of porous materials, such as the introduction of open metal sites, functional group modifications, and the engineering of flexible frameworks. The discussion extends to the current limitations and challenges in the industrial application of these materials. By synthesizing recent breakthroughs and identifying pivotal research directions, this review aims to offer a strategic roadmap for future research endeavors.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216293"},"PeriodicalIF":20.3,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142542068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0