Coordination Chemistry Reviews最新文献_第3页

Metal complexes containing (cycloN5)− anion: History, modernity and development prospects

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-04-01 DOI: 10.1016/j.ccr.2025.216671

Oleg V. Mikhailov

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Covalent organic cages in supramolecular separation 超分子分离中的共价有机笼

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-31 DOI: 10.1016/j.ccr.2025.216648

Ishfaq Ahmad Rather , Fei Wang , Rafia Siddiqui , Meiyue Zhang , Wei Zhou , Xiao Cai , Qing He

{"title":"Covalent organic cages in supramolecular separation","authors":"Ishfaq Ahmad Rather , Fei Wang , Rafia Siddiqui , Meiyue Zhang , Wei Zhou , Xiao Cai , Qing He","doi":"10.1016/j.ccr.2025.216648","DOIUrl":"10.1016/j.ccr.2025.216648","url":null,"abstract":"<div><div>Covalent organic cages (COCs), distinguished by their discrete, three-dimensional architectures with customizable cavities, represent a rapidly advancing class of molecular materials with broad applications, including microreactors, heterogeneous catalysis, high-permeability membranes, and porous liquids. Recent advancements in synthetic strategies and supramolecular chemistry have enabled a diverse range of COC structures, which, like metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and porous organic polymers (POPs), provide high surface areas, accessible porosities, and tunable architectures. Unlike these extended porous networks, COCs are composed of discrete, solvent-soluble units, facilitating enhanced dispersion, processability, and recyclability. Their dynamic features, including reversible polymorphism and supramolecular interactions, support dissociation and recombination, further enhancing their adaptability and shape persistence. This review examines recent progress in the use of COCs for supramolecular separations, with a focus on their utility in separating gases, ions, enantiomers, and positional isomers, as well as in the development of pure and hybrid porous membranes. By synthesizing current findings, we aim to assist researchers in designing COCs tailored to specific industrial separation applications, highlighting the increasing relevance of these materials in separation science.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216648"},"PeriodicalIF":20.3,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143737303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Optical properties and photonic applications of molecular spin-crossover materials

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-29 DOI: 10.1016/j.ccr.2025.216628

Karl Ridier , Ayman Hoblos , Stéphane Calvez , Maciej Lorenc , William Nicolazzi , Saioa Cobo , Lionel Salmon , Lucie Routaboul , Gábor Molnár , Azzedine Bousseksou

{"title":"Optical properties and photonic applications of molecular spin-crossover materials","authors":"Karl Ridier , Ayman Hoblos , Stéphane Calvez , Maciej Lorenc , William Nicolazzi , Saioa Cobo , Lionel Salmon , Lucie Routaboul , Gábor Molnár , Azzedine Bousseksou","doi":"10.1016/j.ccr.2025.216628","DOIUrl":"10.1016/j.ccr.2025.216628","url":null,"abstract":"<div><div>We review the current knowledge on the optical properties of molecular spin-crossover (SCO) materials, which exhibit reversible switching between low-spin and high-spin electronic configurations, as well as their use for practical applications in the fields of optics and photonics. We focus on the physical origins and magnitude of the complex refractive index change (both real and imaginary parts) in SCO materials, including a brief excursion to less-studied lower frequency ranges (THz–Hz). Until now, the optical property changes have primarily been used as a means of detection to characterize the SCO phenomenon itself (particularly at the nanometric scale) or to develop optical sensors for monitoring variations in an external stimulus. However, more recently, optical signal processing and modulation have also been explored using SCO nanomaterials as active elements in tunable photonic devices. Herein, we review the current state of the art of such functional devices, showing that molecular SCO compounds are emerging as a promising class of phase-change materials with high potential for specific active photonic applications, particularly in the visible spectral range. Key results on light-induced spin transitions and the photoswitching dynamics of SCO materials are also briefly reviewed in the context of photonic devices. Finally, the results of recent studies reporting strong light-matter coupling phenomena between SCO molecules and confined electromagnetic fields in resonant optical cavities are also discussed, with, in sight, the fascinating perspectives of manipulating the molecular properties using light.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216628"},"PeriodicalIF":20.3,"publicationDate":"2025-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143724463","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Beyond chemotherapy: Spatiotemporal activation of metal complexes for deep-tissues precision medicine

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-29 DOI: 10.1016/j.ccr.2025.216664

Yida Pang , Fang Zhao , Yuting Wang , Qiao Song , Qian Wang , Junrong Li , Ruiping Zhang , Yao Sun

{"title":"Beyond chemotherapy: Spatiotemporal activation of metal complexes for deep-tissues precision medicine","authors":"Yida Pang , Fang Zhao , Yuting Wang , Qiao Song , Qian Wang , Junrong Li , Ruiping Zhang , Yao Sun","doi":"10.1016/j.ccr.2025.216664","DOIUrl":"10.1016/j.ccr.2025.216664","url":null,"abstract":"<div><div>Metal-based complexes have emerged as powerful agents in anticancer therapy, demonstrating exceptional activity and positioning themselves as highly promising candidates in the field. Among these, platinum-based antitumor drugs are extensively employed in current chemotherapy protocols. However, their clinical utility is significantly constrained by challenges such as drug resistance, non-specific biodistribution, and irreversible toxicities. Recent advances underscore that precise spatiotemporal activation of metal-based drugs through external radiation offers a novel mechanism of action distinct from conventional chemotherapy. This approach enhances therapeutic efficacy while simultaneously mitigating side effects and cross-resistance, addressing pivotal limitations inherent to traditional metal-based therapeutics. External stimuli, including near-infrared (NIR) light, ultrasound (US), and X-rays, possess superior tissue penetration compared to ultraviolet-visible light, rendering them particularly advantageous for targeting deep-seated tumors. Within this framework, we comprehensively review recent developments in the activation of metal-based drugs <em>via</em> NIR light, US, and X-rays, with a focus on molecular metal complexes, supramolecular coordination complexes, and metal-organic frameworks. Critical aspects covered include their design principles, photophysical and photochemical properties, and biomedical applications. Finally, we address the difficulties and future directions for the biomedical field and clinical translation of these metal complexes.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216664"},"PeriodicalIF":20.3,"publicationDate":"2025-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143734835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent progress in atomically precise metal nanoclusters: From bio-related properties to biological applications

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-29 DOI: 10.1016/j.ccr.2025.216633

Lizhong He , Tingting Dong , De-en Jiang , Qichun Zhang

{"title":"Recent progress in atomically precise metal nanoclusters: From bio-related properties to biological applications","authors":"Lizhong He , Tingting Dong , De-en Jiang , Qichun Zhang","doi":"10.1016/j.ccr.2025.216633","DOIUrl":"10.1016/j.ccr.2025.216633","url":null,"abstract":"<div><div>Atomically precise noble metal nanoclusters (e.g. gold and silver nanoclusters), consisting of a few to a hundred atoms, have emerged as promising materials in the field of nanoscience and life science. They have attracted significant interest owing to their discrete energy levels, intriguing molecular-like behaviors, and unique bio-related properties such as controllable optical absorption, adjustable photoluminescence, circularly polarized luminescence and clusterzyme activity, which can be tailored through tuning the size, composition distribution and types of the capping agents. These valuable bio-related properties of noble metal nanoclusters with defined structures have ensured them to become an emerging and promising class of artificial theranostic agents in biological applications, including bioimaging, modern antibacterial agents, drug delivery systems and cancer therapy. This review comprehensively and systematically summarizes recent advances in the bio-application of gold and silver nanoclusters for fluorescent bioimaging, antibacterial agents, drug delivery and cancer therapy, highlighting the key factors or efficient strategies to tailor these bio-related properties. Moreover, the current challenges and the future development directions of noble metal nanoclusters are also discussed.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216633"},"PeriodicalIF":20.3,"publicationDate":"2025-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143724464","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Applications of smart responsive nanomaterials in the theranostics of gastrointestinal malignancies: Current status and future perspectives

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-29 DOI: 10.1016/j.ccr.2025.216641

Wenpeng Huang , Jingwei Zhou , Yutong Liang , Rachel J. Saladin , Liming Li , Lei Kang , Chen Hua , Weibo Cai

{"title":"Applications of smart responsive nanomaterials in the theranostics of gastrointestinal malignancies: Current status and future perspectives","authors":"Wenpeng Huang , Jingwei Zhou , Yutong Liang , Rachel J. Saladin , Liming Li , Lei Kang , Chen Hua , Weibo Cai","doi":"10.1016/j.ccr.2025.216641","DOIUrl":"10.1016/j.ccr.2025.216641","url":null,"abstract":"<div><div>Gastrointestinal (GI) malignancies remain to be one of the most prevalent malignancies that are often characterized by a dismal prognosis. Nanoplatforms present a groundbreaking avenue for enhancing targeting strategies and multifunctionality in cancer treatment. The emergence of nanotechnology, particularly the innovation of smart responsive nanomaterials, has revolutionized cancer diagnosis and therapy. This review begins by exploring the design principles of smart responsive nanomaterials, focusing on the various exogenous and endogenous stimuli that drive their functionality. Furthermore, we provide a comprehensive summary of the applications of smart responsive nanomaterials in the treatment of GI malignancies over the past five years. Our aim is to contribute to the growing body of knowledge on smart responsive nanomaterials in GI malignancies, spark innovative ideas, and encourage further advancements in this field. Finally, we discuss the prospects and challenges associated with the use of smart responsive nanomaterials in GI malignancies.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216641"},"PeriodicalIF":20.3,"publicationDate":"2025-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143734839","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cross-material synergies of carbon nanomaterials, MOFs, and COFs: Innovative approaches for sustainable environmental remediation and resource recovery 碳纳米材料、MOFs 和 COFs 的跨材料协同作用：可持续环境修复和资源回收的创新方法

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-27 DOI: 10.1016/j.ccr.2025.216669

Prathmesh Bhadane , Swaroop Chakraborty

{"title":"Cross-material synergies of carbon nanomaterials, MOFs, and COFs: Innovative approaches for sustainable environmental remediation and resource recovery","authors":"Prathmesh Bhadane , Swaroop Chakraborty","doi":"10.1016/j.ccr.2025.216669","DOIUrl":"10.1016/j.ccr.2025.216669","url":null,"abstract":"<div><div>Sustainable environmental remediation and resource recovery are critical to addressing pollution, resource depletion, and ecosystem degradation. This review introduces the new concept of cross-material synergies, integrating carbon nanomaterials (CNMs), Metal-Organic Frameworks (MOFs), and Covalent Organic Frameworks (COFs) into multi-functional composite systems. By leveraging their complementary properties, these materials overcome key challenges such as structural instability, poor selectivity, and scalability limitations. Cross-material composites—including MOF@COF hybrids and CNM-MOF integrations—enhance adsorption performance, stability, and reusability compared to their individual components. Our review demonstrate how these hybrid systems improve pollutant removal, catalytic degradation, and resource recovery, aligning with sustainability goals. Their ability to transform waste into valuable materials supports circular economy principles and key Sustainable Development Goals (SDGs), including SDG 6 (Clean Water and Sanitation), SDG 12 (Responsible Consumption and Production), and SDG 13 (Climate Action). Furthermore, the review highlights strategies for optimising material performance, ensuring industrial scalability, and minimising environmental impact through Safe and Sustainable by Design (SSbD) approaches. Unlike previous reviews that focus on individual materials, this work provides a holistic roadmap for designing and deploying cross-material composites for real-world applications. By bridging fundamental research with industrial implementation, these systems present a transformative step toward sustainable material science, with far-reaching implications for environmental remediation and resource recovery. Future research should focus on enhancing synthesis efficiency, ensuring long-term material stability, and addressing economic feasibility for large-scale deployment.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216669"},"PeriodicalIF":20.3,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143705136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Coupling nitric oxide photo-uncaging with radiotherapy

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-27 DOI: 10.1016/j.ccr.2025.216630

Peter C. Ford , Issa Frigino , James R. Tinsley , John A. DiBenedetto

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Chemically functionalized polymers as corrosion inhibitors: Effect of solubility, adsorption and coordination bonding

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-26 DOI: 10.1016/j.ccr.2025.216637

Saman Zehra , Ruby Aslam , Jeenat Aslam , Chandrabhan Verma , Zhitao Yan , Qihui Wang , Mohammad Mobin , Akram AlFantazi

{"title":"Chemically functionalized polymers as corrosion inhibitors: Effect of solubility, adsorption and coordination bonding","authors":"Saman Zehra , Ruby Aslam , Jeenat Aslam , Chandrabhan Verma , Zhitao Yan , Qihui Wang , Mohammad Mobin , Akram AlFantazi","doi":"10.1016/j.ccr.2025.216637","DOIUrl":"10.1016/j.ccr.2025.216637","url":null,"abstract":"<div><div>This article explores the role of chemically functionalized polymers as effective corrosion inhibitors, emphasizing the need for functionalization to enhance their protective properties. The study investigates the functionalization process that impacts polymer characteristics such as solubility, adsorption behavior, and coordination bonding, directly influencing corrosion protection efficiency. The study reviews covalent and non-covalent functionalized polymers, examining their corrosion inhibition mechanisms through interactions with metal surfaces. The potential of polymer-based composites, including metal/metal-oxide/polymer hybrids, graphene/polymer composites, and cluster-based coordination polymers (CCPs), for corrosion control is explored. The literature survey highlights the significant advancements in these areas, mainly focusing on self-healing capabilities and sustainable materials. Moreover, MXene-polymer composites are proposed as promising candidates for efficient corrosion inhibition. The paper also discusses the challenges associated with using polymer nanocomposites in corrosion inhibition and suggests strategies to overcome these challenges, advancing the development of more effective, environmentally friendly solutions.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216637"},"PeriodicalIF":20.3,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143703227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent advances in metal-organic frameworks (MOFs)-based colorimetric sensors for visual detection of food freshness

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-26 DOI: 10.1016/j.ccr.2025.216638

Weicheng Sun , Yapeng Huo , Xueying Feng , Longxuan Wei , Xiaoyang Lu , Sha Liu , Zhixian Gao

{"title":"Recent advances in metal-organic frameworks (MOFs)-based colorimetric sensors for visual detection of food freshness","authors":"Weicheng Sun , Yapeng Huo , Xueying Feng , Longxuan Wei , Xiaoyang Lu , Sha Liu , Zhixian Gao","doi":"10.1016/j.ccr.2025.216638","DOIUrl":"10.1016/j.ccr.2025.216638","url":null,"abstract":"<div><div>Harmful substances, such as volatile organic amines and biogenic amines released during food spoilage, pose a significant threat to food quality and safety and directly impact consumer health and well-being. Therefore, the exploration and development of efficient and reliable detection technologies for food freshness have become a crucial component in safeguarding public health and maintaining market order. Metal-organic frameworks (MOFs) are a new generation of crystalline porous materials characterized by their hole-like structures, formed through coordination bonds between metal ions or clusters and organic ligands. Due to their exceptional sensitivity, intuitive visual effects, user-friendly operation, and cost-effectiveness, MOFs-based colorimetric sensors have sparked significant advancements in visual detection of food freshness. This article systematically reviews the latest advancements in visual colorimetric sensors based on MOFs for monitoring food freshness. It provides a comprehensive analysis of their capabilities and application potential in identifying and quantifying indicators of food spoilage. Moreover, this review objectively discusses the challenges currently faced by MOFs-based visual colorimetric sensing assays, including material stability, environmental adaptability, and the scalability of practical applications. It also explores the future development pathways and vast prospects of this technology. Based on existing findings, the review provides a critical perspective for understanding the current application status of visual colorimetric sensors in monitoring food freshness, with the aim of offering insights for its future applications and research and development.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216638"},"PeriodicalIF":20.3,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143703027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0