Coordination Chemistry Reviews最新文献

{"title":"The rise of halogen bonding in (stereo)selective supramolecular catalysis","authors":"Anton Vidal-Ferran","doi":"10.1016/j.ccr.2026.217624","DOIUrl":"10.1016/j.ccr.2026.217624","url":null,"abstract":"<div><div>Since its emergence in the late 1970s, supramolecular chemistry has become a cornerstone of modern chemical science. Defined by the controlled assembly of molecular components through reversible interactions, it encompasses a wide spectrum of forces, among which halogen bonding (XB) has gained prominence as a versatile and directional interaction with unique applications in molecular design and catalysis. This review highlights catalytic systems in which halogen bonding functions either (i) as an activating interaction toward functional groups; (ii) as a promoter of halogen abstraction in organic substrates and metal complexes; or (iii) as a structural element directing the assembly of the catalyst framework. To maintain a focused and critical perspective, only catalytic systems employing 10 mol% of catalyst or less and demonstrating applicability to the synthesis of structurally diverse product arrays are discussed. The review is organized according to the role of the catalyst, providing a coherent framework for understanding how halogen bonding governs activation, selectivity, and molecular organization. Collectively, the studies discussed herein illustrate how halogen bonding has evolved from a supramolecular curiosity into a tool in catalysis, expanding both the conceptual and practical boundaries of modern supramolecular catalysis.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217624"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146138826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fundamentals and solid-state applications of π-hole-driven molecular recognition","authors":"Akiko Hori,&nbsp;Keiko Yokomizo","doi":"10.1016/j.ccr.2026.217605","DOIUrl":"10.1016/j.ccr.2026.217605","url":null,"abstract":"<div><div>The π-hole is an electron-deficient region formed at the center of an aromatic π-plane, characterized by a positive electrostatic potential (ESP) and a positive quadrupole moment (<em>Q</em>_zz). This inversion of the charge distribution relative to conventional aromatic π-systems arises when electron-withdrawing elements such as fluorine or nitrogen are incorporated into aromatic frameworks, generating electrophilic π-surfaces capable of selectively recognizing electron-rich π-systems. The concept of the π-hole was first identified in arene–perfluoroarene interactions and has since evolved into a fundamental design principle in crystal engineering. In this review, the π-hole is not treated merely as a specific type of intermolecular interaction, but is positioned as a unifying electrostatic design principle within hole chemistry that connects solid-state molecular organization and host–guest recognition. Accordingly, the electronic origin, design strategies, and solid-state manifestations of π-hole···π interactions in both organic and metal–organic systems are systematically summarized, with particular emphasis on how quadrupole inversion governs molecular assembly in the solid state.</div><div>The first part of the review focuses on π-hole-driven co-crystallization phenomena, while the latter part highlights nonporous adaptive crystals (NACs) that reversibly encapsulate aromatic hydrocarbons through electronically programmed hole sites within the crystal lattice. Particular attention is devoted to perfluorinated Cu(II) complexes that lack permanent voids, which represent archetypal molecular crystals in which guest inclusion arises not from persistent porosity but from adaptive electrostatic reorganization of the crystal structure. As a result, molecular recognition and guest encapsulation are driven purely by electrostatic complementarity, without reliance on preformed pores. Furthermore, π-hole design enables discrimination among nonpolar molecules with nearly identical size and shape, such as benzene/cyclohexene/cyclohexane, benzene/trifluorobenzene/hexafluorobenzene, and CO₂/C₂H₂. These examples demonstrate that subtle differences in quadrupole character can be translated into practical molecular separations that are inaccessible to conventional adsorbents. Finally, recent advances reveal that π-hole–induced charge inversion also provides a rational basis for solid-state color modulation and sensor design based on intermolecular charge transfer. Collectively, π-hole chemistry bridges fundamental electrostatic theory with practical applications in selective adsorption, molecular recognition, and responsive materials.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217605"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146116559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Small-molecule fluorescent probes for imaging Golgi stress-associated biochemical changes","authors":"Xiao Wang ,&nbsp;Ziwei Huang ,&nbsp;Mengran Xu,&nbsp;Guangyang Xu,&nbsp;Yu Han,&nbsp;Xin Sun","doi":"10.1016/j.ccr.2026.217694","DOIUrl":"10.1016/j.ccr.2026.217694","url":null,"abstract":"<div><div>The Golgi apparatus, as an essential membrane-bound organelle in cells, is responsible for the modification, packaging, and transport of proteins and lipids, playing a crucial role in maintaining cellular homeostasis. Recent studies have shown that the Golgi apparatus is not only a hub for the transport of proteins and lipids but also actively participates in stress responses, autophagy, and apoptosis. Golgi stress plays a critical role in various pathological conditions, especially in inflammation, cancer, and neurodegenerative diseases. Prolonged or severe stress can lead to Golgi dysfunction, structural breakdown, and protein accumulation, ultimately triggering cell death and loss of function. To study the dynamic changes of Golgi stress, molecular fluorescent probe technology provides a real-time, non-invasive tool that targets specific chemical environments or proteins within the Golgi, enabling efficient localization and imaging. In this review, we systematically summarize the reported Golgi-targeted fluorescent probes, covering the recognition and labeling mechanisms of different targeting groups, as well as their applications in biological imaging and related diseases. Furthermore, we discuss the challenges and opportunities these probes face from a perspective of diagnostic and therapeutic integration.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217694"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146153343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Chiral nanomaterials for cancer theranostics","authors":"Xinxin Sun ,&nbsp;Xinhao Wang ,&nbsp;Feihong Chen ,&nbsp;Zhonggui He ,&nbsp;Jin Sun ,&nbsp;Cong Luo ,&nbsp;Shenwu Zhang","doi":"10.1016/j.ccr.2026.217695","DOIUrl":"10.1016/j.ccr.2026.217695","url":null,"abstract":"<div><div>Chiral nanomaterials hold significant promise in the field of cancer nanotheranostics. Their potential stems from the systematic integration of chirality, a fundamental stereochemical property, into the structural and functional design of nanomaterials. By mimicking and leveraging the inherent stereochemical environment of biological systems, this strategy provides an effective pathway to enhance the selectivity and specificity of cancer diagnosis and therapy. This review elucidates the pivotal role of chirality in nanomaterial construction, with a focused discussion on the controllable assembly methods of chiral nanomaterials, their stereoselective biological effects, and their multimodal applications in cancer diagnosis and treatment. We analyze the mechanisms of chirality transfer and amplification from the molecular to the nanoscale, dissect the regulatory role of chiral nanomaterials in <em>in vivo</em> delivery processes and bio-interface interactions, and summarize recent advances in their use for diagnostics and therapy. Finally, we present a perspective on the current key challenges and future directions in this field, aiming to provide a theoretical foundation for the development of efficient and safe cancer nanotheranostic systems.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217695"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146160638","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The multifaceted roles of carbon dots in smart semiconductor photocatalytic systems for solar-driven chemistry","authors":"Weiwen Hao ,&nbsp;Yihao Wen ,&nbsp;Ruotian Deng ,&nbsp;Cheng Zhu ,&nbsp;Zhenhui Kang","doi":"10.1016/j.ccr.2026.217703","DOIUrl":"10.1016/j.ccr.2026.217703","url":null,"abstract":"<div><div>Efficient conversion of solar energy into chemicals is regarded as one of the most promising technologies to alleviate the energy crisis and environmental issues. Smart semiconductor photocatalytic systems (SSPS) have garnered significant attention due to their potential in sustainable energy production, green chemical industry, and environmental remediation. Herein, the ‘smart’ nature of SSPS refers to their abilities to adjust reaction pathways, synergize various effects, and integrate multiple functions, thereby enhancing catalytic performance and surpassing the ordinary composite semiconductor photocatalytic systems (CSPS). Among the various nanomaterials explored to date, Carbon dots (CDs) have emerged as a promising “element” to design SSPS due to their unique physical and chemical properties, e.g., abundant functional groups, structural designability, superior optical properties, low toxicity, high stability, and outstanding electron-transfer ability. In this review, we summarize the latest advancements that utilize CDs to design highly efficient SSPS to address interdisciplinary challenges especially in water splitting, organic synthesis, CO₂ reduction reaction (CO2RR), and pollutant degradation. We especially highlight the roles of CDs in adjusting reaction pathways, synergizing various effects, and integrating multiple functions with up-to-date examples and applications. In the last part, we discuss the challenges people are facing and look ahead to the future expectations, along with viable suggestions for the future development of CDs-based SSPS.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217703"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146186653","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Organic frameworks-based optical sensors for uranyl ions: Unveiling mechanisms and applications","authors":"Chengze Song ,&nbsp;Hongbo Gou ,&nbsp;Yapeng Huo ,&nbsp;Kai Li ,&nbsp;Qiyang Gu ,&nbsp;Jiaqi He ,&nbsp;Sha Liu","doi":"10.1016/j.ccr.2026.217685","DOIUrl":"10.1016/j.ccr.2026.217685","url":null,"abstract":"<div><div>Uranyl ions (UO₂²⁺), significant nuclear contaminants, pose severe risks to ecosystems and human health. Although conventional detection techniques such as radiochemical analysis and instrumental methods provide high accuracy, they are often hindered by large equipment size and prolonged analysis time, limiting their suitability for rapid environmental screening and emergency scenarios. In response, optical sensing technologies have attracted significant attention due to their high sensitivity and signal visibility. Among them, organic frameworks—including metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and hydrogen-bonded organic frameworks (HOFs)—offer suitable platforms for constructing high-performance UO₂²⁺ optical sensors, owing to their high surface areas, tunable pores, and tailorable optical properties. This review systematically summarizes advances from 2021 to 2025 in UO₂²⁺ optical sensors based on such materials, with a focus on underlying sensing mechanisms. In fluorescence sensing, “turn-off” designs based on photoinduced electron transfer (PET), fluorescence resonance energy transfer (FRET), inner filter effect (IFE), and charge transfer (CT) mechanisms are detailed, along with refined “turn-on” and self-calibrating ratiometric sensors. Beyond fluorescence, the review also addresses colorimetric sensing via nanozyme activity, electrochemiluminescence (ECL) sensing using organic frameworks as co-reaction promoters, and surface-enhanced Raman spectroscopy (SERS) and X-ray fluorescence (XRF) techniques enhanced by substrate preconcentration. While laboratory-scale detection has reached high sensitivity and selectivity, real-world applications remain challenging due to material instability in complex media, slow mass transfer, and difficulties in device integration. Future development should prioritize stable composites, multimodal sensing platforms, and AI-assisted systems to enable intelligent, on-site, real-time UO₂²⁺ monitoring.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217685"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146153138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Multidimensional design of silicon anode binders: from molecular interactions to macroscopic functionality","authors":"Siqi Zhu ,&nbsp;Panpan Li ,&nbsp;Tongyu He ,&nbsp;Xuanxuan Fu ,&nbsp;Hu Tian ,&nbsp;Yuan Du ,&nbsp;Yongxin Wang ,&nbsp;Kangning Li ,&nbsp;Buyin Shi ,&nbsp;Xiaojiao Yang ,&nbsp;Xiaofei Lou ,&nbsp;Kunyu Lv ,&nbsp;Hui Zhang","doi":"10.1016/j.ccr.2026.217686","DOIUrl":"10.1016/j.ccr.2026.217686","url":null,"abstract":"<div><div>Silicon-based anodes are promising candidates for next-generation lithium-ion batteries (LIBs) due to their high theoretical capacity (4200 mAh g⁻¹). However, significant volume expansion (∼400%) during lithiation/delithiation leads to electrode degradation, including particle pulverization, electrical isolation and unstable solid electrolyte interphase (SEI) formation. Binders, as critical components, play a pivotal role in maintaining structural integrity and mitigating these challenges. This review comprehensively examines the mechanisms of lithium storage and failure in silicon anodes, focusing on the interactions between binders and silicon, including van der Waals forces, hydrogen bonds and chemical bonds (covalent and ionic). We categorize binders by composition and structure, highlighting their roles in stress dissipation, conductivity enhancement and SEI stabilization. Advanced functionalities such as self-healing, flame resistance and electrochemical performance optimization are discussed. Furthermore, computational approaches like density functional theory (DFT) and molecular dynamics (MD) simulations for binder design are explored. Finally, future directions emphasize multifunctional binders with robust mechanical properties, high conductivity and scalable production for practical applications. This review provides valuable insights into the development of high-performance binders to advance silicon anode technology in LIBs.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217686"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146153133","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent advances in size-specific spectroscopy of metal carbonyl complexes","authors":"Hua Xie ,&nbsp;Gang Li ,&nbsp;Ling Jiang","doi":"10.1016/j.ccr.2026.217718","DOIUrl":"10.1016/j.ccr.2026.217718","url":null,"abstract":"<div><div>Metal carbonyl complexes provide unique platforms for probing metal–ligand bonding, electronic structures, and catalytic mechanisms. This review focusses on recent advances in a series of novel homometallic and heterobimetallic carbonyl complexes studied by infrared–vacuum ultraviolet spectroscopy, photoelectron spectroscopy, and quantum chemical calculations. This combined approach enables accurate determination of vibrational characteristics, electron detachment energies, and bonding motifs, allowing clear differentiation between σ-donation, π-back-donation, and metal–metal interactions. Investigations of group-3 homoleptic carbonyls identified the first neutral confinement-free species: Sc(CO)₇ and M(CO)₈ (M = Y, La). Spectroscopic observation of neutral OTiCCO(CO)<em>ₙ</em> (<em>n</em> = 2–5) served as the fresh evidence for efficient C<img>O cleavages and concomitant C<img>C formations. Studies of heterobimetallic carbonyl complexes MFe(CO)₄⁻ (M = Ti, <em>V</em>, Cr, Si, Ge, Sn) and MNi(<em>CO</em>)_<em>n</em>⁻ (M = Sc, Y, Ti, Zr, Hf, V; <em>n</em> = 3–5) indicated coordination preferences dictated by both cluster size and metal identity, along with associated charge redistribution and CO-activation pathways, all of which bear direct relevance to surface catalysis. Collectively, these studies established the well-defined clusters as functional molecular analogues of catalytically active sites, effectively bridging fundamental bonding concepts with applications in CO/CO₂ utilization, syngas chemistry, and energy-conversion processes.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217718"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146186872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Research advances on exploring the FRET mechanism using various sensitizers for latent-finger print technologies: A comprehensive review","authors":"Ramaswamy Sandeep Perala,&nbsp;Myung Jong Kim","doi":"10.1016/j.ccr.2026.217678","DOIUrl":"10.1016/j.ccr.2026.217678","url":null,"abstract":"<div><div>Rare-earth ions, known for their distinctive optical, magnetic, and electrical characteristics have been studied extensively as active dopants in inorganic crystal lattices since the 18th century. The incorporation of foreign ions is crucial in modifying the properties of nanomaterials, influencing their crystal structures, morphology, and functionalities. Different sensitizers exhibit unique energy transfer pathways as well as excitation wavelengths to various activators, resulting in distinct upconversion luminescence (UCL) characteristics. In this review, we emphasize that creating a variety of functional nanomaterials for real-world applications requires a deeper comprehension of the critical role of rare-earth doping. We will also delve into the progress made in rare-earth based nanomaterials, the impact of coordination and non-coordination materials chemistry in the preparation of lanthanide (Ln³⁺) doped upconversion nanoparticles (UCNPs). The principles of UCNPs process in Ln3+ doped nanoparticles like energy transfer, energy migration conversion, excited-state absorption, photon avalanche and cooperative sensitization upconversion nanoparticles along with the perception of luminescence/fluorescence resonance energy transfer (LRET/FRET) mechanism. Furthermore, the essential nanomaterials for FRET investigation along with detailed study on the upconversion luminescence based on the role of lanthanide-sensitizer, their mechanisms and the exchange of energies from sensitizers to their respective activators have been thoroughly discussed. Besides, their potential applications in latent finger print (LFP), anti-counterfeiting/security as well as emerging frontiers and future outlook for research are discussed.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217678"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146135101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Emerging bimetallic metal-organic frameworks for photocatalytic carbon dioxide reduction","authors":"Zihe Chen ,&nbsp;Yin Xiao ,&nbsp;Xin Liu ,&nbsp;Hao Lu ,&nbsp;Xusheng Wang ,&nbsp;Guixiang Ding ,&nbsp;Zhaoqiang Wang ,&nbsp;Peng Wang ,&nbsp;Guangfu Liao ,&nbsp;Lihui Chen","doi":"10.1016/j.ccr.2026.217704","DOIUrl":"10.1016/j.ccr.2026.217704","url":null,"abstract":"<div><div>Photocatalytic carbon dioxide (CO₂) reduction has become a pivotal strategy for regulating the global carbon cycle, promoting carbon neutrality, and generating sustainable fuels. As a class of microporous-mesoporous hybrid materials, metal-organic frameworks (MOFs) have recently gained prominence as efficient photoactive catalysts for CO₂ conversion, owing to their exceptional CO₂ adsorption capabilities and unique structural characteristics. Notably, bimetallic MOFs demonstrate superior photocatalytic performance compared to their monometallic analogs in CO₂ reduction reactions, primarily due to synergistic effects between dual metal centers that enhance both selectivity and activity. This review provides a systematic overview of recent advancements in bimetallic MOFs-based photocatalysts for CO₂ reduction. First, the primary synthetic approaches for these materials are summarized. Subsequently, the fundamental design principles are discussed, with particular focus on the critical roles of organic ligands and metal components. Furthermore, the mechanistic advantages of dual-metal systems in photocatalytic processes are elucidated. Finally, the current challenges are identified and future research directions in this field are proposed. Overall, this comprehensive review aims to offer valuable guidance for the development of next-generation bimetallic MOFs-based photocatalysts to achieve efficient and selective CO₂ conversion, thereby contributing to sustainable energy solutions.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217704"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146186865","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}