Coordination Chemistry Reviews最新文献

{"title":"Pt(II) complexes with tetradentate ligands: Toward commercially applicable blue organic electroluminescence devices","authors":"Youngmin You","doi":"10.1016/j.ccr.2024.216374","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216374","url":null,"abstract":"Tetradentate Pt(II) complexes have emerged as highly promising materials for phosphorescent electroluminescence devices, particularly in the blue emission region. These complexes exhibit desirable characteristics such as high photoluminescence quantum yields, narrow spectral widths, and excellent intrinsic stability. This review highlights recent advancements in the development of electroluminescent tetradentate Pt(II) complexes, with emphasis on their blue emission properties. To provide a comprehensive understanding, fundamental concepts are briefly discussed, including the synthetic methodologies for tetradentate Pt(II) complexes and the electronic structures governing their phosphorescent behaviors. The core discussion emphasizes the relationship between phosphorescence and the structural features of the platinacycles. More than 170 complexes are systematically categorized on the basis of the size of three consecutive platinacycles, including 5–5–5, 5–6–5, 5–5–6, 5–6–6, 5–7–5, 6–5–6, and 6–6–6 structures. Photophysical parameters are provided in tabulated form to allow for rapid comparison of structure-performance relationships. The review concludes with a discussion of the challenges and future directions for advancing electroluminescence applications of tetradentate Pt(II) complexes.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"1 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142782978","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Photoluminescent metal-organic frameworks and their composites: Fundamentals, applications, and outlooks","authors":"Rui Huang, Zhehan Yu, Zi Li, Xi Lin, Jingwei Hou, Zhigang Hu, Jianxin Zou","doi":"10.1016/j.ccr.2024.216358","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216358","url":null,"abstract":"Metal-organic frameworks (MOFs) have garnered considerable attention as exceedingly promising materials recently due to their enduring porosity and adaptable host-guest interactions. Over the past few decades, extensive investigations have been dedicated to the synthesis and diverse applications of MOF materials, encompassing, yet not restricted to, gas storage and separation, sensing, and catalysis. In addition, photoluminescence in MOFs has emerged as a significant area of interest. Herein, we provide an in-depth insight into the origins and fundamentals of MOF photoluminescence, which include basic concepts of photoluminescence and main mechanisms that depict the photoluminescence in MOFs (ligand-centered, metal-centered, ligand-to-metal charge transfer, metal-to-ligand charge transfer, and guest induced). Besides, our review also delineates a perspective to design MOFs and their composites by tuning fluorescent ligands and metal centers, and incorporating fluorescent guest molecules, which are highly beneficial for sensing, white-light emission, optical information protection, and so forth. In addition, the current challenges and promising research directions are pinpointed.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"28 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142788665","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent advances on oxidation of alcohols over various types of materials as effective catalysts: An overview","authors":"Zahra Shariatinia, Zahra Karimzadeh","doi":"10.1016/j.ccr.2024.216372","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216372","url":null,"abstract":"Alcohols belong to a family of priceless chemicals that are employed as raw materials for the production of several key intermediates in crucial industrial processes. The production of value-added compounds relies on oxidation, a critical step in organic synthesis. Oxidation of alcohols is very vital for production of a range of ketones, aldehydes, and acids needed to obtain plastics, detergents, paints, cosmetics, food additives, and medication intermediates industrially. A notable instance is benzyl alcohol oxidation to commercially essential substrates such as benzaldehyde that is a very important reaction because benzaldehyde is commonly used in textiles, agricultural, cosmetics, and pharmaceutical industries. It is noteworthy that the catalytic oxidation of alcohols can be regarded as an environmentally benign process because it avoids using toxic oxidants or high temperatures and instead it uses inexpensive sustainable oxidants like molecular oxygen. This work seeks to provide a review on recent investigations performed on oxidation of alcohols catalyzed by several types of catalyst materials such as inorganic metal complexes, metal organic frameworks (MOFs), zeolites, perovskites, spinels, metal oxides, metals, carbonaceous compounds, g-C₃N₄ composites, salts, and organic materials. Furthermore, characterization as well as catalytic tests are summarized to allow comparisons of catalysts performances, including reaction rate, product selectivity, conversion, and other factors. In fact, this study presents characteristics that affect selectivity, conversion, activity, reusability, and stability of catalysts. Besides, the critical underlying mechanisms behind the oxidation of alcohols are investigated in order to realize which oxidizing species are formed in practical applications of the processes. For performance optimization, effects of factors and reaction circumstances including temperature, solvents, catalyst dose, and oxidant are studied. Therefore, this review provides an overview of the underlying knowledge about employed catalysts indicating oxidation processes of alcohols can be carried out in various solvents employing diverse catalysts.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"33 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142777106","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unveiling cellular mysteries: Advances in BODIPY dyes for subcellular imaging","authors":"Haroon Ahmad, Sibtain Muhammad, Maria Mazhar, Ahmad Farhan, Muhammad Sohaib Iqbal, Hind Hiria, Chen Yu, Yinghe Zhang, Bing Guo","doi":"10.1016/j.ccr.2024.216383","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216383","url":null,"abstract":"Fluorescence imaging has become crucial in cell biology, mainly because of its ability to visualize the cells at the molecular level. Subcellular organs including mitochondria, lysosomes, the endoplasmic reticulum, and the Golgi apparatus play a pivotal role in the physiological and pathological processes in living cells. Among the great number of fluorescent trackers developed so far is 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY), which has the following features: high quantum yields, sharp excitation and emission maxima, high stability, and feasibility to tune chemical, physical, and biological properties. Lately, there has been great progress towards enhancing BODIPY dyes that are water-soluble, cell membrane-permeable, and precisely targeted. Herein, this review article will introduce the BODIPY probes for subcellular imaging with application to various regions of living cells or tissues. Furthermore, we describe the process of functionalizing BODIPY probes to enhance their selectivity and preferential localization in organelles. Moreover, the targeting mechanism is explained to give insights into how different cellular microenvironments dictate the nature of moieties to be attached to the BODIPY scaffold. In addition, confocal microscopy and colocalization studies are reported to verify the desired subcellular distribution of the probes. Importantly, in vitro and in vivo studies are reported to ascertain the safety of the probes for clinical uses. We hope this review will stimulate interest among researchers and students and expedite the development of BODIPY chemistry in biomedical applications.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"10 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142783187","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Metal-organic framework-based fibers for next-generation wearable applications","authors":"Yun-Long Hou, Leiming Guo, Nikos Hadjichristidis","doi":"10.1016/j.ccr.2024.216360","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216360","url":null,"abstract":"Advanced MOF-based wearable textiles are highly desired by people when facing harsh environments; however, some key features related to these materials, such as robustness, performance and reproducibility, have yet to be revealed. Considering the urgent need to use durable wearable textiles to protect human health, it is necessary to critically review the recent developments of robust MOF-based fibers, which have not yet been reported, in this context. Therefore, we summarize the state-of-the-art fibers derived from various multifunctional MOFs in this review. Attention is paid to the stability of MOFs used for wearable textiles in different applications, especially under radiation, corrosive gas, humidity, and dryness. The latest progress made in developing hierarchically structural MOFs into flexible fibers is particularly addressed. Four categories of applications are elaborated: 1) Adsorption of water vapor and toxic gases, 2) Catalytic pollutant detoxification and production of valuable chemicals, 3) Selective sensing of specific chemicals, 4) Wearable electronics such as batteries and supercapacitors. Finally, challenges and prospects for practical applications of MOF-based fibers are highlighted. We anticipate that pursuing a new generation of MOF-based wearable textiles, imbued with enhanced stability and emerging features, will meet the ever-growing demands for human protection.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"13 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142777068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Contemporary challenges in photochemistry and photophysics of coordination compounds","authors":"Benjamin Dietzek-Ivanšić, Katja Heinze, Sven Rau, Oliver S. Wenger, Andrea Pannwitz","doi":"10.1016/j.ccr.2024.216362","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216362","url":null,"abstract":"<h2>Section snippets</h2><section><section><h2>Declaration of interests</h2>The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.</section></section><section><section><h2>Acknowledgment</h2>The Deutsche Forschungsgemeinschaft (DFG) is acknowledged for funding through the <span>SPP2102</span>, project number <span>HE 2778/18-1</span>, and project TRR234 ‘CataLight’, project number <span>364549901</span>.</section></section>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"122 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142783142","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The state-of-the-art of molecularly imprinted polymers based electrochemical sensors and their applications in drug assay","authors":"Mingyue Wang, Wenhai Wang, Shi Chen, Mingfu Ye, Turghun Muhammad, Konglin Wu, Kui Zhang, Xianwen Wei, Xavier Cetó, Manel del Valle","doi":"10.1016/j.ccr.2024.216384","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216384","url":null,"abstract":"Pharmaceutical analysis holds great importance in various fields covering drug quality control, disease treatment, food safety and environmental monitoring. As a kind of artificial antibody with designed specific recognition sites, molecularly imprinted polymers (MIPs) have aroused great interest among researchers due to their remarkable merits of being customizable, reusable, and highly stable in harsh conditions. To date, MIP-based electrochemical sensors (MIP-ECSs) have been considerably reported for detecting varieties of pharmaceutical compounds, thus a systematic review is necessary to retrospect the latest development in this topic. Herein, we comprehensively review the recent progress in preparing MIPs and the novel detection strategies for improving the sensing performance of MIP-ECSs. In addition, the applications of MIP-ECSs in pharmaceutical analysis are overall investigated and reviewed, encompassing the detection of antibiotics and antivirals, anticancer drugs, psychotropic and addictive substances, and other kinds of drugs in different matrices. Finally, the potential challenges and prospectives of MIP-ECSs are discussed to further improve their detecting performance and achieve better feasibility and expanded applicability in pharmaceutical analysis.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"29 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142763276","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sonochemistry: Materials science and engineering applications","authors":"Chengjiao Wang, Rao Tao, Jingningxi Wu, Haiyan Jiang, Zhi Hu, Baoling Wang, Yepeng Yang","doi":"10.1016/j.ccr.2024.216373","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216373","url":null,"abstract":"Ultrasound is a kind of propagating mechanical wave possessing high energy. It offers a distinctive approach characterized by instantaneous and extremely local high temperature as well as high pressure, thereby triggering and even accelerating chemical reactions. In recent years, the sonochemical synthesis of functional materials has garnered considerable attention owing to its distinctive reaction conditions. Improved ultrasonic technologies have been developed in the area of materials science, which will further promote the production of novel implementing equipment. In this comprehensive review, the fundamental principle of sonochemistry is initially described. Subsequently, the chemical and physical effects of ultrasonic cavitation in material synthesis are systematically discussed by summarizing and analyzing quite numerous materials synthesized through sonochemistry. Meanwhile, laboratory-scale engineering progress of these involved materials in catalysis, energy storage/conversion, environmental management, and biology/medicine are strongly emphasized. Besides, the engineering challenges on industry-scale applications are outlined as well. This contribution will boost the application of ultrasonic synthesis technology in the controlled preparation of functional materials and further facilitate their engineering applications and outreach.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"82 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142763277","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Coordination chemistry of ligands bearing heavy group 14 and 15 elements: Comparative analysis of their influence on transition metal chemistry","authors":"Yeong Jun Son, Dongyoung Kim, Jae Wan Park, Yeongjun Yu, Seung Jun Hwang","doi":"10.1016/j.ccr.2024.216317","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216317","url":null,"abstract":"Interest in developing new ligand platforms beyond utilizing conventional elements like carbon, nitrogen, oxygen and phosphorus is growing. In particular, the heavier analogs of the lighter counterpart elements, such as germanium, tin, antimony, and bismuth, manifest distinct chemical properties and are progressively employed in creating new ligands for transition metal catalysis. This review addresses recent developments in ligands containing heavy elements from group 14 (Ge and Sn) and group 15 (As, Sb, and Bi) as coordinating atoms. It highlights the interactions between transition metals and these new ligands, comparing them with their lighter counterparts, and emphasizes the resulting differences in reactivity.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"1 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142760821","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Molecular modeling of clay minerals: A thirty-year journey and future perspectives","authors":"Annan Zhou, Jiapei Du, Ali Zaoui, Wassila Sekkal, Muhammad Sahimi","doi":"10.1016/j.ccr.2024.216347","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216347","url":null,"abstract":"The growing demand for a deeper understanding and improved utilization of clay minerals has raised a pressing need for a comprehensive review of the latest advancements and future prospects for their molecular-scale modeling. This paper addresses this need by providing an in-depth review of the topics investigated during the past 30 years. Beginning with an introduction to classification of clay minerals, molecular modeling of clay minerals and a concise historical overview, this paper delves into the molecular simulation methods for clay minerals, with detailed discussions on force fields, computational packages, and simulation ensembles. The nanoscale energy variation within clay minerals is described, covering hydration, interaction, free and adsorption energies. The analysis is then extended to the nanoscale mechanical response and properties of clay minerals, including basal spacing, swelling pressures, and elastic moduli and simulation of complex stress states, while considering the effect of various factors on such properties. Furthermore, the paper discusses adsorption and diffusion of water, ions, and organic molecules, along with the capture and mineralization of CO<ce:inf loc=\"post\">2</ce:inf> within clay minerals. The review concludes by summarizing key findings and outlining the ongoing need for clay mineral modeling, emphasizing the potential for significant advancements in various applications through a better understanding of the behavior of clay minerals.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"13 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142763024","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}