Coordination Chemistry Reviews最新文献

{"title":"Transformative progress in MOF-based hybrid materials for supercapacitors and gas sensors: multifunctional platforms for sustainable technologies","authors":"Annu Sheokand ,&nbsp;Sarita Sindhu ,&nbsp;Mamta Bulla ,&nbsp;Raman Devi ,&nbsp;Rita Dahiya ,&nbsp;Amit Sanger ,&nbsp;Avnish Kumar Sisodia ,&nbsp;Ajay Kumar Mishra ,&nbsp;Vinay Kumar","doi":"10.1016/j.ccr.2025.217213","DOIUrl":"10.1016/j.ccr.2025.217213","url":null,"abstract":"<div><div>The transition to clean and sustainable energy systems is critical for addressing global environmental challenges, including greenhouse gas emissions, pollution, and climate change. In this context, supercapacitors for energy storage and gas sensors for environmental monitoring have emerged as key technologies for promoting energy and ecological sustainability. Advancements in materials science have enabled the development of multifunctional platforms, with metal-organic frameworks (MOFs) standing out due to their high surface area, tunable porosity, well-defined structures and abundant active sites. These properties make MOFs highly suitable for both supercapacitor and gas sensing applications. Recent advances include the development of both pristine MOF-based materials and their composites with conductive polymers, carbonaceous materials, and metal oxides, aimed at enhancing electrical conductivity, stability and sensitivity. These hybrid systems have led to significant improvements in capacitive performance and gas-sensing selectivity. Despite these advancements, a comprehensive review that addresses the dual application of MOFs and their composites in chemiresistive gas sensors and supercapacitors remains limited. This article bridges that gap by presenting a unified overview of recent progress and examining how material structure influences device functionality. It also outlines current challenges and future opportunities for implementing MOF-based smart materials in sustainable technologies aligned with global development goals.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"549 ","pages":"Article 217213"},"PeriodicalIF":23.5,"publicationDate":"2025-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145261370","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"NIR-II luminescent rare-earth-doped nanomaterials for precision targeted and surgical navigation of tumors","authors":"Bi Lin ,&nbsp;Ruichan Lv ,&nbsp;Ziyue Ju ,&nbsp;Anees A. Ansari","doi":"10.1016/j.ccr.2025.217251","DOIUrl":"10.1016/j.ccr.2025.217251","url":null,"abstract":"<div><div>Rare-earth ion (Ln³⁺)-doped nanomaterials (NMs) have garnered significant attention in the biomedical field owing to their deep-tissue penetration and outstanding spatial resolution in the second near-infrared window (NIR-II, 1000–1700 nm). By conjugating functional molecules such as peptides and small molecules, these NMs can integrate multiple targeting mechanisms, including passive and active targeting, which are of great significance for precise targeting and theranostics of malignant cancers. In this review, we first provide a comprehensive overview of the synthesis strategies of Ln³⁺-doped NMs, highlighting the advantages, limitations, and applicability of various approaches. It then discusses in detail the luminescence mechanisms of Ln³⁺ ions in the NIR-II region, as well as recent advances in emission enhancement strategies and <em>in vivo</em> NIR-II imaging modalities. Subsequently, we summarize the cutting-edge applications of functionalized Ln³⁺-doped NMs in passive targeting, active targeting, physicochemical targeting, and biomimetic nanostructures. Moreover, we analyze their utility in clinical navigation across different scenarios, including small tumor detection, tumor margin delineation, and sentinel lymph node mapping. Finally, we present a forward-looking perspective on future research directions, focusing on key challenges such as improving absorption cross-sections, ensuring biosafety, validating efficacy in large-animal models, and exploring specific biological targets.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"549 ","pages":"Article 217251"},"PeriodicalIF":23.5,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145261369","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advances in mesoporous nanomaterials for photocatalytic degradation of pollutants: fundamentals, material classifications, challenges and future prospects","authors":"Sana Zahoor ,&nbsp;Sheraz Muhammad ,&nbsp;Muhammad Kashif ,&nbsp;Natasha Shahzad ,&nbsp;Yan-cheng Liu ,&nbsp;Cumali Celik ,&nbsp;Nida Ambreen ,&nbsp;Asif Ali ,&nbsp;Hui-Fen Wu ,&nbsp;Shohreh Azizi ,&nbsp;Changchun Wen","doi":"10.1016/j.ccr.2025.217239","DOIUrl":"10.1016/j.ccr.2025.217239","url":null,"abstract":"<div><div>Mesoporous nanomaterials (MNMs) have emerged as a powerful class of materials for photocatalytic applications, with their unique structural advantages such as high surface area and tunable pore architecture playing a pivotal role in enhancing photocatalytic efficiency. This review provides a comprehensive overview of recent advancements in MNMs, focusing on six distinct material classes, including carbon-based, silica-based, polymer-based, mixed-metal-based, metal oxide-based, and covalent organic frameworks (COFs), demonstrating how their mesoscale porosity optimizes light absorption, charge carrier separation, and reactant mass transfer, thus improving catalytic performance. While metal oxide-based MNMs offer the best balance of activity and stability, emerging COFs provide exceptional design flexibility, allowing for the tailoring of material properties at the molecular level, which enhances reaction efficiency and enables mechanistic insights. A significant challenge is the scalability and long-term stability of these materials, which need to be addressed for successful real-world applications. Key insights suggest that overcoming these barriers requires an interdisciplinary approach, integrating standardized fabrication methods with a deeper understanding of reaction mechanisms at the porous interface. This review ultimately establishes that strategic engineering of mesoporous structures moving beyond a primary focus on composition is the key to unlocking the full potential of photocatalytic technologies for sustainable development.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"549 ","pages":"Article 217239"},"PeriodicalIF":23.5,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248001","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Design of probiotic-nanozyme synergistic systems: A new bio-hybrid strategy for disease therapy","authors":"Chenlin Dai ,&nbsp;Yike Liu ,&nbsp;Wenhan Li ,&nbsp;Qingzhuo Gu ,&nbsp;Jiaqi Han ,&nbsp;Cuicui Ma ,&nbsp;Xuebo Liu ,&nbsp;To Ngai ,&nbsp;Jiaqi Su ,&nbsp;David Julian McClements ,&nbsp;Fuguo Liu","doi":"10.1016/j.ccr.2025.217228","DOIUrl":"10.1016/j.ccr.2025.217228","url":null,"abstract":"<div><div>Redox homeostasis is pivotal to the maintenance of physiological health and the pathogenesis of various diseases. Probiotics offer notable therapeutic advantages, including modulation of the gut microbiota, immune system activation, and site-specific colonization. However, their inherently weak redox-regulatory capacity limits their broader clinical utility. Nanozymes are artificial catalysts that are being developed to address this limitation. Combining probiotics and nanozymes within composite systems leads to synergistic effects that enhance the therapeutic efficacy of the composite systems against multiple diseases. In this review, we summarize current design approaches for constructing probiotic-nanozyme composite systems and discuss their advantages and limitations. We then elucidate the underlying synergistic mechanisms in the treatment of intestinal inflammation and tumors, and highlight their broader application prospects in gastrointestinal disorders, tumors, and other diseases. Finally, we address the translational challenges of probiotic-nanozyme therapies and provide perspectives on future research directions and clinical development.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"549 ","pages":"Article 217228"},"PeriodicalIF":23.5,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145261179","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Structural symmetry breaking in 2D CrOCl enables multiphysics coupling and functional tunability","authors":"Shuai Ye ,&nbsp;Xu Duan ,&nbsp;Liwei Liu ,&nbsp;Junle Qu ,&nbsp;Jiaqing Guo ,&nbsp;Jun Song","doi":"10.1016/j.ccr.2025.217252","DOIUrl":"10.1016/j.ccr.2025.217252","url":null,"abstract":"<div><div>As an emerging low-symmetry two-dimensional (2D) magnetic material, CrOCl provides a unique platform for multidimensional physical effect modulation owing to its orthogonal lattice-induced structural symmetry breaking. This review systematically examines the intrinsic properties of CrOCl in magnetic, optical, and thermal domains, revealing its magnetic-field-dependent resistance switching behavior, significant optical anisotropy, and anomalous thermal transport mechanisms. Furthermore, it elaborates on various property modulation strategies, including strain engineering to enhance magnetic ordering temperature, high-pressure-induced phase transitions, dimensional engineering for topological state construction, and carrier doping to surpass room-temperature ferromagnetism limitations. Regarding heterostructure fabrication, the interfacial synergistic effects between CrOCl and materials such as metals and graphene are comprehensively analyzed, elucidating their critical roles in spin valves, quantum transport, and photodetection. With advancements in synthesis techniques like chemical vapor transport, the application prospects of CrOCl-based devices in polarized optical modulation, spin storage, and three-dimensional integrated logic circuits are prospectively explored. By establishing a comprehensive “structural characteristics-property modulation-interface design-functional expansion” framework, this review provides theoretical guidance and technical support for quantum device development in 2D magnetic materials.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"549 ","pages":"Article 217252"},"PeriodicalIF":23.5,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145247999","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Smart microneedles empowering programmable and sustained drug delivery","authors":"Weishu Zeng ,&nbsp;Qihang Ding ,&nbsp;Zhe Zhang ,&nbsp;Jiaqi Zhao ,&nbsp;Xu Ding ,&nbsp;Pengfei Gao ,&nbsp;Minghan Chi ,&nbsp;Kun Qian ,&nbsp;Manlin Qi ,&nbsp;Zhen Cheng ,&nbsp;Lin Wang","doi":"10.1016/j.ccr.2025.217209","DOIUrl":"10.1016/j.ccr.2025.217209","url":null,"abstract":"<div><div>Microneedles (MNs) have emerged as a promising platform for transdermal drug delivery, offering minimally invasive, programmable, and patient-friendly alternatives to conventional routes. Advances in fabrication and materials science have transformed MNs from simple metallic structures to multifunctional, biodegradable systems capable of dynamic drug release. This review analyzes MNs from the perspectives of structural design, material composition, and drug release kinetics. We examine key design parameters such as needle geometry and array configuration, and their effects on mechanical performance and delivery efficiency. MNs are categorized by type and functionality, highlighting innovations in tip design and backing layers for enhanced tissue penetration and payload control. A comparison of fabrication materials—including metals, inorganic nonmetals, natural and synthetic polymers—is presented, focusing on their degradation behavior and correlation with drug release timelines. Drug formulation strategies and pharmacokinetic models are also discussed, linking material–drug interactions to release profiles. Finally, recent applications in wound care, vaccination, hormone therapy, oncology, and ocular treatment are explored. This review bridges design, material, and pharmacokinetic considerations to support the development of next-generation MN systems with optimized spatiotemporal control for clinical applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217209"},"PeriodicalIF":23.5,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145247615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The chemistry of lower boranes: from synthesis and structure to reactivity and applications","authors":"V.V. Avdeeva,&nbsp;N.T. Kuznetsov","doi":"10.1016/j.ccr.2025.217222","DOIUrl":"10.1016/j.ccr.2025.217222","url":null,"abstract":"<div><div>This review provides a systematic overview of the chemistry and properties of lower boranes (boron hydride clusters in the B₃ to B₉ range)., with emphasis on their structural features, synthesis methods, physical and spectroscopic properties, and reactivity. Although elemental boron does not react directly with hydrogen, the extensive class of boron-hydrogen compounds exhibits unique structural and reactive diversity, stemming from the electron-deficient nature of boron and the formation of multicenter bonds (e.g., three-center two-electron B–H–B and B–B–B bonds). The work systematizes synthesis methods and details the molecular structure and spectral characteristics of key representatives of this class: diborane (B₂H₆), tetraborane (B₄H₁₀), pentaboranes (B₅H₉, B₅H₁₁), hexaboranes (B₆H₁₀, B₆H₁₂), octaboranes (B₈H₁₂, B₈H₁₄, B₈H₁₈), nonaborane (B₉H₁₅), and the octahydrotriborate anion [B₃H₈]^–. For each compound, methods of preparation, molecular structure, spectroscopic data, and key physicochemical properties are discussed. The historical role of Alfred Stock and William Lipscomb in establishing this field is emphasized. On one hand, this work aims to consolidate the extensive yet fragmented knowledge on boron hydrides; on the other hand, the vastness of the field has necessitated a selective presentation of the most essential data. Although borohydrides have been known for decades, they continue to offer a rich and dynamic domain for research, with ongoing discoveries and applications in modern chemistry and materials science. We hope this review will serve as a valuable resource for researchers, students, and industrial practitioners, facilitating further exploration and innovation in this promising area.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217222"},"PeriodicalIF":23.5,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145247611","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Chiral assembly of atomically precise metal nanoclusters","authors":"Wenjun Du ,&nbsp;Lirong Jiang ,&nbsp;Shan Jin ,&nbsp;Manzhou Zhu","doi":"10.1016/j.ccr.2025.217232","DOIUrl":"10.1016/j.ccr.2025.217232","url":null,"abstract":"<div><div>The chiral assembly of atomically precise nanoclusters (NCs) into hierarchical superstructures is an emerging frontier that enables the design of functional materials with tailored chiroptical, catalytic, and photonic performance. This review provides a systematic synthesis of recent advances, with emphasis on the relationships linking assembly strategies to enhanced properties and applications. Mechanistically, directional supramolecular interactions (e.g., hydrogen bonding, π-π stacking, halogen bonding) and coordination chemistry drive diverse architectures, including fibrous helical bands, single/double/multi-helical motifs, and extended frameworks. Chirality arises intrinsically from asymmetric NC cores or ligand environments, or is extrinsically induced by chiral linkers or counterions. Assembly-induced confinement and anisotropic coupling suppress nonradiative decay pathways, thereby boosting photoluminescence (PL), circularly polarized luminescence (CPL), circularly polarized phosphorescence (CPP), and electrochemiluminescence (ECL). These enhancements underpin applications in circularly polarized light-emitting diodes <strong>(</strong>CP-LEDs), sensing, catalysis, and low-loss optical waveguides. We highlight a “structure-property-application\" continuum, further informed by kinetic control, chiral amplification, and guest-responsive adaptive assembly. Finally, we outline key challenges and opportunities, including in situ mechanistic interrogation, exploration beyond coinage metals, and advanced directions in quantum optics and enantioselective technologies.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217232"},"PeriodicalIF":23.5,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145247614","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Exploring Fmoc-Phe-OH self-assembly for the development of functional soft biomaterials","authors":"Soumen Kuila,&nbsp;Laboni Ghosh,&nbsp;Jayanta Nanda","doi":"10.1016/j.ccr.2025.217225","DOIUrl":"10.1016/j.ccr.2025.217225","url":null,"abstract":"<div><div>The design and development of self-assembling materials derived from amino acids and short peptides have gained growing significance in functional soft biomaterials. Attaching aromatic functional groups to these molecules enhances their self-assembly and gelation capabilities. Among these, 9-fluorenylmethoxy carbonyl (Fmoc), commonly used for N-terminal protection of amino acids, has been extensively studied over the past two decades. These aromatic groups primarily promote self-assembly through aromatic–aromatic interactions, supported by other non-covalent interactions present in the peptide structures. Approximately 16 years ago, the Fmoc derivative of phenylalanine (Fmoc-Phe-OH) was first reported to form a supramolecular hydrogel. Since then, extensive research has been carried out on the gelation behavior of Fmoc-Phe-OH and its related compounds. This review systematically shed lights on the conditions under which Fmoc-Phe-OH and its derivatives undergo gelation, including buffer systems, pH adjustment, and solvent-switching techniques. Further discussion is provided on how modifications, such as ring substitutions on the phenyl ring and alterations at the C-terminal of phenylalanine, affect self-assembly and gelation. Co-assembly with various small molecules has also been shown to enhance the mechanical properties and additional functionality of the resulting biomaterials. Finally, the review highlights diverse applications of these materials, including their use in drug delivery, antimicrobial formulations, nanomaterial scaffolds, and hybrid gels with tunable properties. We hope this work will be beneficial in understanding the molecular engineering approach in advancing amino-acid-based functional materials in different research areas of supramolecular chemistry.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217225"},"PeriodicalIF":23.5,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145247372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent advances in piezo-photo heterojunction: a review on dual catalytic function for wastewater remediation and simultaneous hydrogen generation.","authors":"Amartya Sau ,&nbsp;Dhananjoy Mondal ,&nbsp;Jhilik Roy ,&nbsp;Neelanjana Bag ,&nbsp;Saheli Ghosh ,&nbsp;Debasish Biswas ,&nbsp;Sukhen Das","doi":"10.1016/j.ccr.2025.217240","DOIUrl":"10.1016/j.ccr.2025.217240","url":null,"abstract":"<div><div>Water pollution and the energy crisis have become a persistent threat to modern civilization. Organic dyes, pharmaceuticals, pathogens, pesticides, fertilizers, etc., disrupt the ecological balance and create several health hazards to humankind. On the other hand, the depletion of non-renewable energy sources like coal, petroleum, etc., is also affecting modernization, the environment, and industrial production. In the last few decades, piezo catalysis and photocatalysis have emerged as successful and promising advanced oxidation processes to degrade such contaminants from wastewater and catalytic energy generation, like green H₂ evolution. The limitations, like high reaction time, recombination rate of photogenerated electron-hole pair, energy efficiency, etc., of such catalytic systems motivated the researchers to advance the systems by composite formation, metal ion implantation, heterostructure development, etc. This article delves into the piezo-photo heterostructure and its augmented multi-dynamic catalytic efficacy and green hydrogen generation. The sandwich structure of heterostructure enhances the catalytic performances by augmented reactive oxygen species (ROS) generation, lowering recombination rate, and enhancing the stability of the catalyst as well as H₂ evolution. This article also includes the underlying mechanism of mechanical stress-driven piezo-catalysis and photo-impulse-generated photocatalysis, and different types of heterostructure systems and their electronic structures. The fabrication strategies, operational conditions, and performance matrix of different types of heterostructures and their challenges in terms of stability, real-world applicability, and recent and future progress are also discussed in this article, which validates the environmental remediation and clean energy generation capability of this multifunctional system.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217240"},"PeriodicalIF":23.5,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145247374","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}