Coordination Chemistry Reviews最新文献

筛选
英文 中文
Fluoride engineering in zinc-ion batteries: principles, strategies, and perspectives 锌离子电池中的氟化物工程:原理、策略和观点
IF 23.5 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-09-15 DOI: 10.1016/j.ccr.2025.217181
Tianrui Liu , Yanxin Liao , Shile Liu , Lingyun Chen , Qichun Zhang
{"title":"Fluoride engineering in zinc-ion batteries: principles, strategies, and perspectives","authors":"Tianrui Liu ,&nbsp;Yanxin Liao ,&nbsp;Shile Liu ,&nbsp;Lingyun Chen ,&nbsp;Qichun Zhang","doi":"10.1016/j.ccr.2025.217181","DOIUrl":"10.1016/j.ccr.2025.217181","url":null,"abstract":"<div><div>Zinc-ion batteries (ZIBs) are considered promising candidates for the next-generation energy storage technology due to their high safety, low cost, and high theoretical capacity. However, its practical application is hampered by irregular dendrite growth, hydrogen evolution reaction (HER), and passivation on the anode, as well as the poor structural stability and sluggish kinetics of the cathode. This review systematically investigates the multifunctional roles of fluoride engineering in ZIBs from a holistic “anode-interface-electrolyte-cathode” perspective, encompassing interface regulation and material design. The fluoride-modification of zinc anode is first discussed, including suppression of dendrite growth, reduction of side reactions, and enhancement of ion transport kinetics. Subsequently, fluoride-based interface engineering and fluoride electrolyte optimization are summarized, covering inorganic fluorine-rich solid-electrolyte interphase (SEI) films, inorganic-organic composite fluorine-rich SEI films, and two design strategies for SEI films. Furthermore, the review summarizes fluoride-related cathode design strategies, including fluorine doping, fluoride-based active materials and binder modification. Finally, a brief summary of the current challenges associated with fluorides in ZIBs research, and theoretical insights and technical prospects for the rational design of high-performance ZIBs are prospected.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217181"},"PeriodicalIF":23.5,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145059255","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Beyond apoptosis: Navigating Cancer therapy with cu/Fe-ligand Nano-complexes through Cuproptosis and Ferroptosis 超越凋亡:铜/铁配体纳米复合物通过铜下沉和铁下沉引导癌症治疗
IF 23.5 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-09-15 DOI: 10.1016/j.ccr.2025.217164
Jaehui Lee , Byung Seok Cha , Dokyoung Kim
{"title":"Beyond apoptosis: Navigating Cancer therapy with cu/Fe-ligand Nano-complexes through Cuproptosis and Ferroptosis","authors":"Jaehui Lee ,&nbsp;Byung Seok Cha ,&nbsp;Dokyoung Kim","doi":"10.1016/j.ccr.2025.217164","DOIUrl":"10.1016/j.ccr.2025.217164","url":null,"abstract":"<div><div>Exploiting distinct metal-dependent cell death pathways offers a promising strategy to overcome apoptosis resistance in cancer. This review explores recent advances in metal-ligand nano-complexes, sophisticated platforms engineered to overcome the systemic toxicity and poor bioavailability of free metal ions, selectively triggering two distinct cell death pathways: cuproptosis (copper (Cu)-dependent protein aggregation) and ferroptosis (iron (Fe)-catalyzed lipid peroxidation). The central thesis of this review is the pivotal role of ligand coordination chemistry in tailoring the physicochemical properties, including stability, redox potential, and metal release kinetics that control the mechanistic specificity of these nano-complexes. This review provides a systematic classification of these nano-complexes based on their coordinating donor atoms (O, N, S) to illustrate how molecular configuration translates into selective anticancer efficacy. The development of dual-mode Cu/Fe nano-complexes is further illustrated to exert amplified therapeutic efficacy through the synergistic co-activation of both pathways. Therefore, this review provides a strategic framework for the rational design of next-generation metal-based nanotherapeutics, opening new avenues for precision oncology.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217164"},"PeriodicalIF":23.5,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145059515","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of MXene based organic polymer nanocomposites as highly efficient Electromagnetic Interference Shielding materials: A review MXene基有机聚合物纳米复合材料作为高效电磁干扰屏蔽材料的研究进展
IF 23.5 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-09-15 DOI: 10.1016/j.ccr.2025.217104
Priyanka Rani, V.R.K. Murthy, S.K. Khadheer Pasha
{"title":"Development of MXene based organic polymer nanocomposites as highly efficient Electromagnetic Interference Shielding materials: A review","authors":"Priyanka Rani,&nbsp;V.R.K. Murthy,&nbsp;S.K. Khadheer Pasha","doi":"10.1016/j.ccr.2025.217104","DOIUrl":"10.1016/j.ccr.2025.217104","url":null,"abstract":"<div><div>The rapid expansion of electronic devices and wireless communication technologies has significantly increased the demand for high performance electromagnetic interference (EMI) shielding materials. MXene-based organic polymer nanocomposites have emerged as promising candidates due to their exceptional features including high electrical conductivity, mechanical flexibility, and lightweight properties. This review examines the synthesis and properties of MXenes, particularly their layered structure and multifunctionality, and explores various fabrication methods for MXene/polymer EMI shielding nanocomposites. The advantages and limitations of these methods in EMI applications are critically analysed. Additionally, structural characteristics, including morphology and interface interactions, are discussed to assess the dispersion and stability of MXene within polymer matrices. Key factors influencing shielding effectiveness (SE), such as MXene content, polymer type, and composite thickness, are investigated, along with the fundamental mechanisms governing EMI shielding in these nanocomposites. The contributions of total electromagnetic wave attenuation (SE<sub>T</sub>), including absorption (SE<sub>A</sub>), reflection (SE<sub>R</sub>), and multiple reflections (SE<sub>M</sub>), are examined in relation to optimal shielding mechanisms. A comparative analysis with other EMI shielding materials highlights the superior mechanical robustness, flexibility, and processability of MXene/polymer nanocomposites. Finally, the review outlines potential applications in flexible electronics, aerospace, medical, and wearable devices, emphasizing the need for further research on scalability, oxidation resistance, and environmental sustainability. It also addresses current challenges in EMI shielding applications and proposes innovative strategies for developing advanced EMI shielding materials.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217104"},"PeriodicalIF":23.5,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145059257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Frontiers in cellulose@COFs composites: From multiform fabrication toward emerging applications in separation, environment, and energy cellulose@COFs复合材料的前沿:从多形式制造到分离、环境和能源的新兴应用
IF 23.5 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-09-15 DOI: 10.1016/j.ccr.2025.217143
Ya-Ning Xu, Dan Tian
{"title":"Frontiers in cellulose@COFs composites: From multiform fabrication toward emerging applications in separation, environment, and energy","authors":"Ya-Ning Xu,&nbsp;Dan Tian","doi":"10.1016/j.ccr.2025.217143","DOIUrl":"10.1016/j.ccr.2025.217143","url":null,"abstract":"<div><div>As two distinct classes of functional materials, covalent organic frameworks (COFs) and cellulose have respectively emerged as typical synthetic porous crystals and renewable nanoscale building blocks for next-generation applications. Recent advances highlight that their synergistic integration creates composite architectures with emergent properties surpassing individual component capabilities, particularly in crystallinity modulation, pore size engineering, and mechanical reinforcement. Through strategic coupling via covalent conjugation, electrostatic assembly, or supramolecular interactions, these composite systems can be engineered into hierarchical architectures, including freestanding membranes, ultralight aerogels, and stimuli-responsive hydrogels. Such structured composites demonstrate unprecedented performance metrics in critical technological domains spanning molecular separation (nanofiltration/gas purification), sustainable water remediation, solar-driven energy conversion, and environmental energy harvesting. This review systematically examines state-of-the-art fabrication strategies for COF-cellulose composites, with particular emphasis on structure-property correlations. We critically assess their various applications while addressing persistent challenges in scalable manufacturing, interfacial compatibility, and long-term stability. This work establishes a framework for advancing these cpmposite materials toward practical implementation by delineating fundamental design principles and technological bottlenecks. The progressive understanding of their multiscale interactions, coupled with emerging sustainable processing techniques, positions COF-cellulose composites as a transformative materials platform for addressing global sustainability challenges.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217143"},"PeriodicalIF":23.5,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145059258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nature-inspired room-temperature phosphorescence materials: design, mechanisms, and multifunctional applications 受自然启发的室温磷光材料:设计、机制和多功能应用
IF 23.5 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-09-11 DOI: 10.1016/j.ccr.2025.217171
Guobin Yang , Yajing Zhang , Chuang Lei , Jiancai Chen , Huijing Li , Yanchao Wu
{"title":"Nature-inspired room-temperature phosphorescence materials: design, mechanisms, and multifunctional applications","authors":"Guobin Yang ,&nbsp;Yajing Zhang ,&nbsp;Chuang Lei ,&nbsp;Jiancai Chen ,&nbsp;Huijing Li ,&nbsp;Yanchao Wu","doi":"10.1016/j.ccr.2025.217171","DOIUrl":"10.1016/j.ccr.2025.217171","url":null,"abstract":"<div><div>Room temperature phosphorescent (RTP) materials have broad application prospects in optoelectronics and biomedicine. Due to the limitations of traditional petroleum-based materials face limitations in terms of sustainability, natural molecules offer a renewable and eco-friendly alternative, and their inherent luminescent properties open new avenues for the development of sustainable RTP systems. Nevertheless, a systematic summary of the design principles and structure–performance relationships in natural RTP materials remain lacking. Accordingly, molecular design, emission regulation and functional applications of nature-inspired RTP materials are comprehensively evaluated. This review analyzes RTP enhancement in biomass derivatives and highlights the influence of natural structural diversity on exciton dynamics. It explores the potential applications of these materials and discusses the challenges and prospects of large-scale synthesis and precise control of optical properties.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217171"},"PeriodicalIF":23.5,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145043713","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Azolate-based metal-organic frameworks and derivatives for electrochemical CO2 reduction reactions: Recent advances and perspectives 电化学CO2还原反应的氮酸盐基金属有机骨架及其衍生物:最新进展与展望
IF 23.5 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-09-11 DOI: 10.1016/j.ccr.2025.217158
Muhammad Imran Anwar , Muhammad Asad , Xiaofang Su , Zdenek Sofer , Muhammad Saqib Rabbani , Muhammad Naeem Ashiq , Guang Yang , Yanan Gao
{"title":"Azolate-based metal-organic frameworks and derivatives for electrochemical CO2 reduction reactions: Recent advances and perspectives","authors":"Muhammad Imran Anwar ,&nbsp;Muhammad Asad ,&nbsp;Xiaofang Su ,&nbsp;Zdenek Sofer ,&nbsp;Muhammad Saqib Rabbani ,&nbsp;Muhammad Naeem Ashiq ,&nbsp;Guang Yang ,&nbsp;Yanan Gao","doi":"10.1016/j.ccr.2025.217158","DOIUrl":"10.1016/j.ccr.2025.217158","url":null,"abstract":"<div><div>The electrocatalytic carbon dioxide reduction reaction (<em>e</em>CO<sub>2</sub>RR) is a potential solution to reduce carbon emissions in the future, but there are still challenges in adopting current technology for industrial applications. Therefore, an urgent need is to design and develop active, selective, and stable materials. Among the porous materials, azolate (imidazolate, tetrazolate, triazolate, and pyrazolate) metal-organic frameworks (MOFs) are a subclass of MOFs that have attracted tremendous attention in various applications, specifically <em>e</em>CO<sub>2</sub>RR, due to their differentiated key characteristics, i.e., flexible frameworks, abundant active sites, adjustable porosity, high stability, and customized morphology. Despite the salient characteristics and ongoing research, no critical review has been published that covers azolate MOFs for <em>e</em>CO<sub>2</sub>RR. This review presents a comprehensive introduction, the conversion mechanism of <em>e</em>CO<sub>2</sub>RR, carbon product formation, and strategies for analyzing and identifying products, followed by the chemistry of azolate MOFs, framework design principles, local coordination geometries, synthesis considerations, and the impact of morphology on performance. Subsequently, attention is directed toward surface modification via ligand tailoring, alongside an in-depth examination of structural conductivity, durability, influencing parameters, the role of electrolytes, and the impact of device configuration on performance. Later, recent developments in azolate MOFs and their derivatives and composites are discussed, focusing on the chemical composition and performance of <em>e</em>CO<sub>2</sub>RR. Finally, a comprehensive understanding of the most recent advancements, underlying challenges, suggestions, and insights on improving the performance of azolate MOFs for state-of-the-art electrocatalysts has also been presented.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217158"},"PeriodicalIF":23.5,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145043711","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Harness of multifunctional nanozymes: Focusing on material construction to food safety detection and monitoring 多功能纳米酶的利用:聚焦于食品安全检测与监测的材料构建
IF 23.5 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-09-11 DOI: 10.1016/j.ccr.2025.217153
Ziying Pan , Zhengzheng Wang , Mengxia Zou , Huichan Zhai , Congyu Zhou , Qingping Wu , Jiahui Zeng , Xiuhua Lin , Tingting Liu , Yu Ding , Juan Wang
{"title":"Harness of multifunctional nanozymes: Focusing on material construction to food safety detection and monitoring","authors":"Ziying Pan ,&nbsp;Zhengzheng Wang ,&nbsp;Mengxia Zou ,&nbsp;Huichan Zhai ,&nbsp;Congyu Zhou ,&nbsp;Qingping Wu ,&nbsp;Jiahui Zeng ,&nbsp;Xiuhua Lin ,&nbsp;Tingting Liu ,&nbsp;Yu Ding ,&nbsp;Juan Wang","doi":"10.1016/j.ccr.2025.217153","DOIUrl":"10.1016/j.ccr.2025.217153","url":null,"abstract":"<div><div>Abstract</div><div>As people pay more and more attention to food safety, the demand for fast, sensitive and reliable detection technologies is also growing. However, traditional detection technologies usually have the disadvantages of low sensitivity, complicated procedures and poor adaptability to various food matrices. Natural enzymes, due to their rapid reaction rates, are widely used in various rapid detection platforms, driving the development of traditional detection methods. However, the complexity of their extraction and relatively high cost limit their application. Nanozymes, which mimic the catalytic activity of natural enzymes, offer advantages, including lower costs, ease of preparation, and excellent stability, making them a promising alternative to natural enzymes. However, most nanozymes are monofunctional, and such single-function systems often exhibit limited substrate scope, poor adaptability, and weak signal amplification, restricting their broader application. In contrast, multifunctional nanozymes (MFNZs) can combine enzyme-mimicking catalysis (e.g., peroxidase) with the intrinsic physical properties (optical, magnetic, photothermal) endowed by nanoscale coordination structures, providing a revolutionary solution for food safety by enabling synergistic cascade reactions, signal amplification, and simplified sample processing. However, how to accurately combine multiple functions based on the different mechanisms of action of MFNZs has not yet been clearly explained. Therefore, it is necessary to conduct a systematic review of the design principles, classification and functional combination of MFNZs. This review systematically explores the rational design strategies, catalytic mechanisms, and functional classification of MFNZs, emphasizing how engineered coordination environments at the nanoscale underpin their multifunctionality. We assess the application of MFNZ-based multi-mode biosensors for detecting diverse food contaminants. This review aims to provide foundational insights for advancing MFNZs as powerful, coordination chemistry-driven tools in next-generation food safety monitoring and biosensing.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217153"},"PeriodicalIF":23.5,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145043712","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cascade nanozymes as ROS scavengers for the treatment of aseptic inflammation 级联纳米酶作为活性氧清除剂治疗无菌性炎症
IF 23.5 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-09-11 DOI: 10.1016/j.ccr.2025.217163
Qing Miao , Hongyu Yang , Xinyuan Zhu , Xuesong Feng , Jinghui Yang , Youfu Wang
{"title":"Cascade nanozymes as ROS scavengers for the treatment of aseptic inflammation","authors":"Qing Miao ,&nbsp;Hongyu Yang ,&nbsp;Xinyuan Zhu ,&nbsp;Xuesong Feng ,&nbsp;Jinghui Yang ,&nbsp;Youfu Wang","doi":"10.1016/j.ccr.2025.217163","DOIUrl":"10.1016/j.ccr.2025.217163","url":null,"abstract":"<div><div>Aseptic inflammatory diseases, including autoimmune disorders and chronic tissue injuries, pose significant health challenges globally, with ROS playing a key pathogenic role. While nanozymes have been explored as ROS scavengers for anti-inflammatory therapy, their clinical application is limited by suboptimal catalytic performance. Recent advances focus on cascade nanozymes, which integrate multiple enzymatic activities to mimic natural metabolic pathways. These cascade nanozymes are classified into linear, triangular, cyclic, orthogonal, and parallel configurations, each offering distinct advantages in spatial organization and sequential reaction control. Cascade nanozymes combine the stability and reusability of traditional nanozymes with enhanced catalytic efficiency, reducing diffusion barriers and improving intermediate utilization. By precisely modulating inflammatory responses, they mitigate oxidative stress and cytokine overproduction while preserving host defense mechanisms. This review highlights technological progress, applications, challenges, and future directions in cascade nanozyme development, paving the way for improved functional validation and therapeutic innovation.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217163"},"PeriodicalIF":23.5,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145043774","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances in triplet-state materials: A perspective towards bioimaging and biosensing 三态材料的最新进展:生物成像和生物传感的前景
IF 23.5 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-09-10 DOI: 10.1016/j.ccr.2025.217160
Navid Rabiee , Hossein Daneshgar , Payam Arghavani , Mohammad Edrisi , Mohammad Rabiee , Mohammad Akrami-Hasan-Kohal , Sidi A. Bencherif
{"title":"Recent advances in triplet-state materials: A perspective towards bioimaging and biosensing","authors":"Navid Rabiee ,&nbsp;Hossein Daneshgar ,&nbsp;Payam Arghavani ,&nbsp;Mohammad Edrisi ,&nbsp;Mohammad Rabiee ,&nbsp;Mohammad Akrami-Hasan-Kohal ,&nbsp;Sidi A. Bencherif","doi":"10.1016/j.ccr.2025.217160","DOIUrl":"10.1016/j.ccr.2025.217160","url":null,"abstract":"<div><div>Triplet-state materials have become valuable tools in bioimaging and biosensing due to their unique photophysical properties. These materials are characterized by long-lived emission lifetimes, high signal-to-noise ratios, and sensitivity to changes in their microenvironment. In this review, we examine over 500 publications and critically compare 287 highly cited studies to evaluate the current landscape of organic, inorganic, and hybrid triplet-state materials. We explain the design principles and emission mechanisms of organic systems, including thermally activated delayed fluorescence emitters and metal-organic complexes, and contrast these with inorganic counterparts, such as transition metal-doped nanomaterials and lanthanide-based probes, known for their photostability and sharp emission profiles. The review also discusses hybrid materials that combine features from both domains to address limitations and enhance biomedical applications. Key areas of focus include emerging red and near-infrared triplet emitters, surface engineering for biocompatibility and targeting, and multimodal imaging integration. We address challenges such as oxygen quenching, biological safety, and targeted <em>in vivo</em> delivery. By presenting a comparative framework supported by quantitative and qualitative data, this work is intended to offer a valuable resource for researchers working toward the development of next-generation triplet-state materials for high-resolution bioimaging, real-time diagnostics, and theranostic applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217160"},"PeriodicalIF":23.5,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145025800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improving the optical response of chemosensors through the use of surfactant micelles 利用表面活性剂胶束改善化学传感器的光学响应
IF 23.5 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-09-09 DOI: 10.1016/j.ccr.2025.217130
Alan J. Zhou , Brady S. Gentle , Genevieve H. Dennison , Rico F. Tabor , Kellie L. Tuck
{"title":"Improving the optical response of chemosensors through the use of surfactant micelles","authors":"Alan J. Zhou ,&nbsp;Brady S. Gentle ,&nbsp;Genevieve H. Dennison ,&nbsp;Rico F. Tabor ,&nbsp;Kellie L. Tuck","doi":"10.1016/j.ccr.2025.217130","DOIUrl":"10.1016/j.ccr.2025.217130","url":null,"abstract":"<div><div>This review provides a comprehensive insight into recent (post-2020) examples of supramolecular micelles and their use in tandem with chemosensors/fluorophores to design and generate supramolecular-micelle-based sensing systems. Due to the broad range of surfactants available, the supramolecular micelles formed in these systems have both the ability to be tailored towards a specific analyte (metal cations with anionic surfactants, anions with cationic surfactants), and to work in tandem with the incorporated sensor system through encapsulation of the chemosensor and (or) through forming co-micellar aggregates. The examined supramolecular micelle-based sensing systems demonstrate an ability to enable functionality of previously non-responsive sensors, and (or) improve fluorescent/colorimetric responses, by providing stronger emissions and signal-to-noise clarity. A substantial portion of the reported work focuses on metal-ion based sensors working synergistically with anionic surfactants, with Hg<sup>2+</sup> and Cu<sup>2+</sup> ions as the most prominent analytes due to their well-known fluorescent quenching mechanisms. Cases involving Fe<sup>3+</sup> and Cd<sup>2+</sup> ions are also discussed within. Anion sensing is also a significant body of work covered in this review, with cationic surfactants assisting chemosensors for the detection of CN<sup>−</sup>, HS<sup>−</sup>, HSO<sub>3</sub><sup>−</sup>/SO<sub>3</sub><sup>2−</sup> and NO<sub>2</sub><sup>−</sup>. In addition to ion-based sensors, recent small molecule and large macromolecule sensors are also reviewed within, with hydrophobic fluorophores encapsulated by a variety of supramolecular surfactant micelles.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217130"},"PeriodicalIF":23.5,"publicationDate":"2025-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145020048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信