Coordination Chemistry Reviews最新文献_第10页

Chalcophosphates: A plentiful source of infrared nonlinear optical materials

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-26 DOI: 10.1016/j.ccr.2025.216524

Yingying Kong , Guansong Zheng , Yinxia Du , Junjie Li , Shilie Pan

{"title":"Chalcophosphates: A plentiful source of infrared nonlinear optical materials","authors":"Yingying Kong , Guansong Zheng , Yinxia Du , Junjie Li , Shilie Pan","doi":"10.1016/j.ccr.2025.216524","DOIUrl":"10.1016/j.ccr.2025.216524","url":null,"abstract":"<div><div>Developing high-performance nonlinear optical (NLO) crystals is an urgent need for advanced photoelectric technologies. However, the discovery of novel infrared (IR) NLO materials with desired properties is challenging. Chalcophosphate, combining the structural advantages of chalcogenide & phosphate, and showing a high probability (∼30 %, much higher than the one of ∼15 % in the inorganic compounds) to generate non-centrosymmetric crystal structures, was demonstrated as a promising system for searching new IR NLO crystals with excellent optical properties, and a great many NLO-active chalcophosphates were ‌reasonably designed and fabricated. To advance the targeted design of high-performance IR NLO crystals, this review provides a systematic and up-to-date summary on the abundant structural and chemical diversities of chalcophosphates, with a particular emphasis on the connection modes of distinguished [P<sub>x</sub>Q<sub>y</sub>] units; and the efficient progress on the structural design that achieved in the thiophosphate-, selenophosphate-, and mixed anionic-based chalcophosphate IR NLO candidates in recent years. Finally, the upcoming opportunities and challenges in the captivating fields were discussed.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216524"},"PeriodicalIF":20.3,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143496182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Novel bio-carriers for radionuclide delivery in cancer radiotherapy

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-26 DOI: 10.1016/j.ccr.2025.216557

Lishan Wang , Qing He , Jianping Man , Yechen Gao , Guangming Zhou , Hongwei Si , Kai Yang , Lin Hu , Pei Pei

{"title":"Novel bio-carriers for radionuclide delivery in cancer radiotherapy","authors":"Lishan Wang , Qing He , Jianping Man , Yechen Gao , Guangming Zhou , Hongwei Si , Kai Yang , Lin Hu , Pei Pei","doi":"10.1016/j.ccr.2025.216557","DOIUrl":"10.1016/j.ccr.2025.216557","url":null,"abstract":"<div><div>Internal radionuclide therapy (IRT) is a crucial component of cancer radiotherapy, focusing on delivering radionuclides to the tumor site via an optimal carrier and using high-energy radiation (including α particles, β particles, γ rays, and Auger electrons) to kill tumor cells. To further enhance the efficacy and safety of IRT, developing new bio-carriers to optimize the stable and efficient labelling, targeting delivery efficiency, biosafety, and multi-functionality of radionuclides has become a current research focus. In this review, we first briefly revisit the commonly used radionuclide delivery carriers in clinical practice, including antibodies, peptides, microspheres, and discuss their associated challenges. Subsequently, we focus on the development and research progress of novel bio-carriers, analyzing their roles and mechanisms in optimizing radionuclide labelling, delivery, and enhancing the efficacy of IRT. Finally, the review provides insights into the existing challenges faced in the field and suggests potential future research directions. Our work aims to advance the use of radionuclides in cancer radiotherapy with innovative bio-carriers, offering theoretical support and a vision for developing highly multifunctional and clinically useful bio-carriers.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216557"},"PeriodicalIF":20.3,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488503","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Microenvironment engineering of MOFzymes for biomedical applications

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-26 DOI: 10.1016/j.ccr.2025.216539

Xiaoping Zhao , Rui Gao , Heng Sun , Peng Chen , Haixue Zheng , Lingjie Meng

{"title":"Microenvironment engineering of MOFzymes for biomedical applications","authors":"Xiaoping Zhao , Rui Gao , Heng Sun , Peng Chen , Haixue Zheng , Lingjie Meng","doi":"10.1016/j.ccr.2025.216539","DOIUrl":"10.1016/j.ccr.2025.216539","url":null,"abstract":"<div><div>Nanozymes, a type of nanomaterials with enzyme-like activity, have attracted growing attention in recent years due to their remarkable stability, tunable catalytic performance, multifunctionalities, and cost-effectiveness. Although significant progress has been made in the past decade, designing nanozymes with high selectivity, excellent catalytic activity, and new types of catalytic activities beyond oxidation-reduction reactions remains highly challenging. This is primarily due to the difficulties in fabricating well-defined nanozymes and precisely tailoring the microenvironment of catalytic sites at atomic level. Metal-organic frameworks (MOFs) with enzyme-mimicking activities (MOFzymes) offer several advantages over other nanozymes, including well-defined molecular structure and catalytic sites, high porosity, and large surface areas. MOFzymes mainly mimic various oxidoreductases, such as oxidase, peroxidase, catalase, superoxide dismutase, and glutathione peroxidase, making them suitable for various biomedical applications. In this article, the structures and properties of MOFzymes and the latest developments are thoroughly discussed. We particularly focus on the physical and chemical methods for microenvironment regulation of MOFzymes, and the working mechanisms. Furthermore, the applications of MOFzymes for biosensing, cancer therapy, antibacterial therapy, and anti-inflammatory therapy are described. Finally, we discuss the future opportunities and challenges of MOFzymes.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216539"},"PeriodicalIF":20.3,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fungal detection and elimination based on AIEgens

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-26 DOI: 10.1016/j.ccr.2025.216548

Pu Chen , Jiawen Zhao , Dongmi Li , Yu Zhang , Chunxuan Qi , Hai-Tao Feng , Ben Zhong Tang

{"title":"Fungal detection and elimination based on AIEgens","authors":"Pu Chen , Jiawen Zhao , Dongmi Li , Yu Zhang , Chunxuan Qi , Hai-Tao Feng , Ben Zhong Tang","doi":"10.1016/j.ccr.2025.216548","DOIUrl":"10.1016/j.ccr.2025.216548","url":null,"abstract":"<div><div>Fungi are closely related to people's production and living. It is very crucial to achieve the accurate detection and effective elimination of fungi in the reasonable utilization of fungi and the efficient treatment of fungi-infected diseases. Aggregation-induced emission (AIE) luminogens (AIEgens), which can overcome the aggregation-caused quenching (ACQ) effect and emit bright emission in aggregated states, have great potential in imaging, detection and therapy with high photostability and abundant generation of reactive oxygen species (ROS). In this review, we summarized relevant studies on fungal detection and elimination that utilize AIEgens. In fungal detection, some works involving AIEgens in fungal viability evaluation, imaging, activity assessment, discrimination and quantification were described. In fungal elimination, several works in fungal killing due to dark toxicity or phototoxicity of AIEgens <em>in vitro</em> were represented, and some works in fungal elimination and treatment of superficial fungal infection <em>in vivo</em> relying on phototoxicity of AIEgens were depicted. At the end of the review, we conclude the structural features of AIEgens for binding to fungi and present the existing challenges in this field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216548"},"PeriodicalIF":20.3,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488502","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Achiral and chiral metal-organic frameworks (MOFs) as an efficient catalyst for organic synthesis

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-26 DOI: 10.1016/j.ccr.2025.216536

Narendra Pal Singh Chauhan , Panneerselvam Perumal , Narendra Singh Chundawat , Sapana Jadoun

引用次数: 0

Amphiphilic quinoline-malononitrile AIE probes: From molecule design to bio-applications

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-24 DOI: 10.1016/j.ccr.2025.216550

Zhirong Zhu , Yiqi Shi , Chenxu Yan , Ming Liu , Wei-Hong Zhu , Zhi Su

{"title":"Amphiphilic quinoline-malononitrile AIE probes: From molecule design to bio-applications","authors":"Zhirong Zhu , Yiqi Shi , Chenxu Yan , Ming Liu , Wei-Hong Zhu , Zhi Su","doi":"10.1016/j.ccr.2025.216550","DOIUrl":"10.1016/j.ccr.2025.216550","url":null,"abstract":"<div><div>Traditional aggregation-induced emissions (AIE) probes are prone to aggregate in aqueous biosystem, leading to non-specific fluorescence signals prior to binding to specific receptors (targets), which hinders precise <em>in situ</em> detection of the target substances. To address this challenge, we propose a novel design strategy termed “amphiphilic AIEgens”, which ensures that the probes exhibit excellent dispersibility in both aqueous biological environments and lipophilic organelles, remaining in a fluorescence-off state to effectively mitigate false fluorescence signals. Upon binding to specific receptors (targets), the restriction of molecular motion activates AIE fluorescence, thereby selectively illuminating the targeted substances. This minireview summarizes recent advancements of amphiphilic AIEgens, particularly focusing on the innovative AIE building block quinoline-malononitrile (QM). These amphiphilic AIE probes are constructed by chemically grafting functional hydrophilic groups onto lipophilic QM, effectively addressing dilemmas of undesirable-aggregation and non-specific fluorescence activation typically associated with traditional AIE probes, thereby enabling high-fidelity and long-term imaging of target substances at cellular, tissue, and even <em>in vivo</em> levels. Herein, we delineate the molecular engineering design strategy that integrates various functional blocks for amphiphilic AIE-active probes, and elaborate their applications in biosensing, diagnosis, and photodynamic therapy. Finally, we delve into the challenges and opportunities for AIE biological probes in conclusion section.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216550"},"PeriodicalIF":20.3,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143474413","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Applications of high-entropy MOFs and their derivatives

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-24 DOI: 10.1016/j.ccr.2025.216546

Anaer Husile, Zhenlu Wang, Jingqi Guan

引用次数: 0

Gold clusters: A promising NIR-II probe for bioimaging and biosensing

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-24 DOI: 10.1016/j.ccr.2025.216544

Jiaqi Sun , Wanyu Cheng , Xu Liu , Huixin Xiang , Chenhao Ruan , Fenzhen Chen , Chuanhao Yao

{"title":"Gold clusters: A promising NIR-II probe for bioimaging and biosensing","authors":"Jiaqi Sun , Wanyu Cheng , Xu Liu , Huixin Xiang , Chenhao Ruan , Fenzhen Chen , Chuanhao Yao","doi":"10.1016/j.ccr.2025.216544","DOIUrl":"10.1016/j.ccr.2025.216544","url":null,"abstract":"<div><div>Optical imaging and biosensing in the second near-infrared window (NIR-II, 1000–1700 nm) have gained significant interest due to their high signal-to-noise ratio (SNR) and excellent spatial and temporal resolution. These features enable accurate monitoring and treatment of deeper bio-pathological processes. Gold nanoclusters (Au NCs) have emerged as promising candidates for NIR-II emission, offering advantages such as their ultra-small size, outstanding biocompatibility, large Stokes shift, and favorable photoluminescence (PL) properties. This review begins by highlighting the benefits and applications of NIR-II luminescent Au NCs in bioimaging and biosensing. We then explore current strategies to enhance the photoluminescence quantum yield (PLQY) of Au NCs, including techniques such as metal doping, ligand engineering, and the aggregation-induced emission (AIE). Furthermore, we discuss advancements in red-shifting the emission wavelength of Au NCs. Our goal is to provide researchers with fresh insights into improving and fine-tuning the photoluminescent properties of Au NCs, thereby broadening their potential applications in NIR-II bioimaging and biosensing.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216544"},"PeriodicalIF":20.3,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143474414","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Preparation strategies of waste-derived MOF and their applications in water remediation: A systematic review

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-24 DOI: 10.1016/j.ccr.2025.216534

Jia-Hang Wang , Fanying Kong , Bing-Feng Liu , Nan-Qi Ren , Hong-Yu Ren

{"title":"Preparation strategies of waste-derived MOF and their applications in water remediation: A systematic review","authors":"Jia-Hang Wang , Fanying Kong , Bing-Feng Liu , Nan-Qi Ren , Hong-Yu Ren","doi":"10.1016/j.ccr.2025.216534","DOIUrl":"10.1016/j.ccr.2025.216534","url":null,"abstract":"<div><div>The severity of aquatic environmental problems has been acknowledged widely. To mitigate the escalating water pollution, it is imperative to adopt appropriate functional environmental materials for water purification. Metal–organic frameworks (MOFs) have emerged as a favorable option because of their porous and stable characteristics. Conventional MOF preparation relies on the integration of metal ions/clusters and organic ligands. However, the increasing demand for MOF materials emphasizes the need for sustainable and eco-friendly production methods. Utilizing waste resources such as metals and organic contaminants as precursors for hydrolysis/purification facilitates waste reuse and enables the production of waste-derived MOFs (W-MOFs). These W-MOFs can be used extensively in wastewater purification. Given the adsorption and advanced oxidation mechanisms, the selection and preparation of suitable W-MOFs for eliminating diverse pollutants in aquatic environments hold significant potential. The pollutant-removal mechanisms of these high-value W-MOFs should be studied further. In this review, available information regarding the production processes of W-MOF and their physicochemical characterization is discussed. Additionally, the current status of W-MOF applications in wastewater treatment and the underlying purification mechanisms are analyzed. The overarching goal is to provide alternative material preparation methods that promote a green environment and align these with the concept of sustainable waste utilization.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216534"},"PeriodicalIF":20.3,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143474411","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent advances in lateral flow immunoassay based on sandwich format for whole-cell pathogen detection

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-02-21 DOI: 10.1016/j.ccr.2025.216538

Min Yang , Xinxin Xu , Meng Zhang , Jialu Wang , Yutong Wu , Ningning Wang , Zhaohui Li

{"title":"Recent advances in lateral flow immunoassay based on sandwich format for whole-cell pathogen detection","authors":"Min Yang , Xinxin Xu , Meng Zhang , Jialu Wang , Yutong Wu , Ningning Wang , Zhaohui Li","doi":"10.1016/j.ccr.2025.216538","DOIUrl":"10.1016/j.ccr.2025.216538","url":null,"abstract":"<div><div>Pathogenic bacteria infections pose significant threats to public health. Therefore, developing methods for rapid, sensitive, and selective detection of whole-cell pathogens is key for their prevention and control. Lateral flow immunoassay (LFIA) with portability, simplicity in operation, cost-effectiveness, on-site detection, and fast responsiveness, has been widely used to detect whole-cell pathogens. This review provides a systematical summary of recent advances in lateral flow immunoassay based on sandwich format for whole-cell pathogen detection. The composition and detection principles of LFIA strips are described. Conjugation method of antibody with nanomaterials and sandwich strategies based on different recognition mechanisms have been presented. Some advances in pathogen detection based on sandwich format LFIA with different signal detection strategies are comprehensively summarized, including colorimetric-based assays, fluorescent-based assays, surface-enhanced Raman scattering-based assays, electrical-based assays, magnetic-based assays, and photothermal-based assays. These achievements involve the use of different signal labels, the incorporation of other techniques, and the utilization of signal amplification systems. Finally, the challenges and future directions of LFIA for whole-cell pathogen detection are also briefly summarized. Hopefully, our review will bridge the design of signal labels and rational construction of LFIA, supporting the extensive research for whole-cell pathogen detection.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"533 ","pages":"Article 216538"},"PeriodicalIF":20.3,"publicationDate":"2025-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143463957","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0