Coordination Chemistry Reviews最新文献

{"title":"C–N electro-coupling of CO2/bio-derived carbonaceous molecules and nitrogenous small molecules: Mechanism, catalysts, and applications","authors":"Qianqian Song,&nbsp;Yingbing Zhang,&nbsp;Lin Gu,&nbsp;Min Kuang,&nbsp;Jianping Yang","doi":"10.1016/j.ccr.2024.216248","DOIUrl":"10.1016/j.ccr.2024.216248","url":null,"abstract":"<div><div>The electrochemical C<img>N coupling, utilizing carbon dioxide or bio-derived carbonaceous molecules and nitrogenous small molecules (N₂, NO₃⁻, NO₂⁻, NO and NH₃, etc.) as C and N reactants, offers a sustainable and environmentally friendly strategy for the production of high-value-added organonitrogen chemicals. Understanding the C<img>N electro-coupling mechanism and designing high-performance electrocatalysts are crucial for achieving highly selective and efficient electrosynthesis of organonitrogen chemicals. In this regard, the latest advances in electrochemical C<img>N coupling reactions in the product selectivity and electrocatalytic activity are firstly summarized. Then, mechanistic studies from the perspective of C and N coupling intermediates are investigated, offering insights into design catalysts. Strategies for devising electrocatalysts that facilitate key elementary steps in organonitrogen chemicals production are further presented. Additionally, various applications of C<img>N coupling for synthesizing organonitrogen chemicals such as urea, amides, amines, amino acids, and oximes are also summarized. Finally, crucial challenges and promising opportunities in the future development of electrochemical C<img>N coupling systems are discussed.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216248"},"PeriodicalIF":20.3,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142326509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Functional utility of gold complexes with phosphorus donor ligands in biological systems","authors":"Adedamola S. Arojojoye ,&nbsp;Samuel G. Awuah","doi":"10.1016/j.ccr.2024.216208","DOIUrl":"10.1016/j.ccr.2024.216208","url":null,"abstract":"<div><div>Metallo-phosphines are ubiquitous in organometallic chemistry with widespread applications as catalysts in various chemical transformations, precursors for organic electronics, and chemotherapeutic agents or chemical probes. Here, we provide a comprehensive review of the exploration of the current biological applications of Au complexes bearing phosphine donor ligands. The goal is to deepen our understanding of the synthetic utility and reactivity of Au-phosphine complexes to provide insights that could lead to the design of new molecules and enhance the cross-application or repurposing of these complexes.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216208"},"PeriodicalIF":20.3,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142326638","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unveiling the potential of ingenious copper-based metal-organic frameworks in gas storage and separation","authors":"Sandeep Kumar ,&nbsp;Raeesh Muhammad ,&nbsp;Abdulkarem Amhamed ,&nbsp;Hyunchul Oh","doi":"10.1016/j.ccr.2024.216230","DOIUrl":"10.1016/j.ccr.2024.216230","url":null,"abstract":"<div><div>This study reviews copper-based metal–organic frameworks (Cu-MOFs) designed for enhanced gas adsorption and separation. These MOFs exhibit strategically designed structural features, resulting in optimized performance in gas storage and separation applications. The tailored ingenious Cu-MOFs demonstrate remarkable efficiency in the selective capture of hydrogen (H₂), carbon dioxide (CO₂), and various other gases including hydrocarbons and noble gases, with potential in industrial gas storage and separation, and environmental remediation. The systematic design approach of Cu-MOFs enables precise control over pore structures, pore size, surface area, open metal site and pore functionality, enhancing gas adsorption and selective separation capacities. This study highlights the storage and separation of various gases, unveiling potential of Cu-MOFs providing innovative solutions for addressing challenges in clean energy, and environmental sustainability.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216230"},"PeriodicalIF":20.3,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142318974","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Vanadium- and manganese-based metal-organic frameworks for potential environmental and catalysis applications","authors":"Yangdan Pan ,&nbsp;Soheila Sanati ,&nbsp;Reza Abazari ,&nbsp;Agata Jankowska ,&nbsp;Joanna Goscianska ,&nbsp;Varsha Srivastava ,&nbsp;Ulla Lassi ,&nbsp;Junkuo Gao","doi":"10.1016/j.ccr.2024.216231","DOIUrl":"10.1016/j.ccr.2024.216231","url":null,"abstract":"<div><div>Industrialization has significantly compromised air quality, environmental health, and human well-being. Therefore, it is highly necessary to develop efficient and cost-effective strategies to resolve the issue of environmental pollution while promoting sustainable energy production. Catalysts play a crucial role in the synthesis and conversion of valuable chemicals by providing more active sites that accelerate catalytic reactions, leading to proper activity and selectivity. However, challenges such as catalyst stability, cost-effectiveness, high surface area, reusability, and low loading amount need to be addressed. In this regard, metal organic frameworks (MOFs) could be an intelligent choice due to their tunable structure through altering metal centers and organic ligands along with their structural flexibility, high specific surface area, and diversity. These porous materials have found extensive application in heterogeneous catalysis and environmental remediation thanks to their low cost, abundance in nature and feasible preparation routes. Among first-row transition metal-based MOFs like vanadium (V)- and manganese (Mn)-containing structures have gained popularity in environmental remediation and catalysis due to their different redox states, stability, cost-effectiveness. As limited number of review articles have addressed V and Mn-containing MOFs compared to other first-row transition metals like Ni, Co, Cu and Fe, this review aims at exploring recent advancements in the V- and Mn-based MOFs, their composites, and derivatives within heterogeneous catalysis, highlighting applications in oxidative fuel desulfurization, CO₂ reduction, epoxidation, hydroxylation, oxidation of organic compounds, and environmental remediation, including the adsorption and elimination of organic dyes and CO₂ capture and conversion. Also, the review emphasizes the structure-performance relationship, offering new insights for overcoming existing challenges and advancing the field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216231"},"PeriodicalIF":20.3,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142318972","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Magnetic hydrogel (MagGel): An evolutionary pedestal for anticancer therapy","authors":"Prajkta V. Londhe ,&nbsp;Maithili V. Londhe ,&nbsp;Ashwini B. Salunkhe ,&nbsp;Suvra S. Laha ,&nbsp;O. Thompson Mefford ,&nbsp;Nanasaheb D. Thorat ,&nbsp;Vishwajeet M. Khot","doi":"10.1016/j.ccr.2024.216228","DOIUrl":"10.1016/j.ccr.2024.216228","url":null,"abstract":"<div><div>Recent advancement in biomaterials have led to the development of magnetic hydrogel as promising tool for anticancer therapy. Magnetic hydrogels improve injectability over bare nanoparticles by controlling particle dispersion and reducing aggregation, ensuring uniform delivery and minimizing clogging, thereby enhancing anticancer therapy effectiveness and safety. This review explores the fundamental crosslinking methodologies and chemical strategies for the formation of hydrogels, transitioning into detailed discussions on the synthesis of magnetic hydrogels, emphasizing their unique properties essential for biomedical applications. Key properties such as injectability, shear thinning, biocompatibility, porosity, mechanical properties, and biodegradability underpinning the efficacy of magnetic hydrogels in biomedical applications are discussed. Furthermore, the review highlights the diverse applications of magnetic hydrogels in the biomedical field, including hyperthermia, MRI-guided therapy, targeted drug delivery, and tissue engineering. These properties and applications demonstrate the potential of magnetic hydrogels to revolutionize cancer treatment and other medical therapies, offering a multifunctional platform that can address various biomedical challenges with enhanced precision and effectiveness. Finally, future research trends and applications of magnetic hydrogels are also recommended and examined.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216228"},"PeriodicalIF":20.3,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142318971","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sonocatalytic biomaterials","authors":"Kexing Li ,&nbsp;Shuangshuang Wang ,&nbsp;Chunmei Chen ,&nbsp;Yujie Xie ,&nbsp;Xinyue Dai ,&nbsp;Yu Chen","doi":"10.1016/j.ccr.2024.216242","DOIUrl":"10.1016/j.ccr.2024.216242","url":null,"abstract":"<div><div>Ultrasound (US)-triggered catalysts can initiate various redox catalytic reactions in complex living conditions, presenting significant application prospects for versatile disease treatments, which is described as a collective term “sonocatalytic therapy” (SCT). Typically, a series of organic or inorganic sonosensitizers originating from sonocatalytic biomaterials are stimulated by US to generate abundant reactive radicals, including superoxide ions (·O₂⁻), hydroxyl radicals (·OH), and singlet oxygen (¹O₂), which hold promise for tissue repair, sterilization, and tumor therapy. To promote the clinical transformation of sonocatalytic biomaterials in SCT, this review comprehensively summarizes and outlines the underlying sonocatalytic mechanism, synthesis, modification, and functionalization of sonocatalytic biomaterials, and focuses on their versatible biomedical applications in antitumor therapy, tissue regeneration, and antibacterial treatment. Especially, the facing challenges and future outlook of sonocatalytic biomaterials in sonocatalytic medicine are discussed. With the insight into the sonocatalytic mechanism and the development of methodological and technologies, further clinical transformation of sonocatalytic biomaterials-enabled/augmented SCT is expected to ultimately benefit the human health.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216242"},"PeriodicalIF":20.3,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142318973","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Homocysteine fluorescent probes: Sensing mechanisms and biological applications","authors":"Waqas Pervez ,&nbsp;Laraib ,&nbsp;Caixia Yin ,&nbsp;Fangjun Huo","doi":"10.1016/j.ccr.2024.216202","DOIUrl":"10.1016/j.ccr.2024.216202","url":null,"abstract":"<div><div>Homocysteine, cysteine, and glutathione are small molecules containing thiols that have important functions in several physiological and pathological processes in living beings. Homocysteine specifically, is a biological thiol linked with various kinds of diseases and conditions, including cancer, atherothrombosis, Alzheimer's disease, osteoporosis, mental disorders, etc. Consequently, real-time detection of Homocysteine holds significant value in preserving normal physiological conditions and monitoring the advancement of specific diseases. Therefore, advancing the development of fluorescent probes and elucidating their sensing mechanisms for homocysteine is paramount. This review highlights recent developments in fluorescent probes designed for detecting Homocysteine and explores their sensing mechanisms based on recent literature. This review discusses the development and application of homocysteine-specific probes in biomedical imaging. Additionally, our focus extends to the design strategies employed in creating fluorescent probe compounds and their derivatives, encompassing compounds such as coumarin, nitrobenzofurazan, cyanine, pyronin, BODIPY, and metal complexes. We also delve into the sensing mechanisms involved in the reaction of homocysteine, including the Michael addition reaction, Aromatic substitution rearrangement, Nucleophilic substitution rearrangement, cyclization reactions, metal complexes, and other reaction mechanisms. Discussions in all sections revolved around specific sensing mechanisms tailored for homocysteine, focusing on emission, color changes, detection limits, and their practical applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216202"},"PeriodicalIF":20.3,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142315699","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Multimodal synergistic ferroptosis cancer therapy","authors":"Nem Singh ,&nbsp;Dahee Kim ,&nbsp;Sunhong Min ,&nbsp;Eunji Kim ,&nbsp;Shiyoung Kim ,&nbsp;Yu Shrike Zhang ,&nbsp;Heemin Kang ,&nbsp;Jong Seung Kim","doi":"10.1016/j.ccr.2024.216236","DOIUrl":"10.1016/j.ccr.2024.216236","url":null,"abstract":"<div><div>Ferroptosis, driven by iron-dependent lipid peroxidation, has shown considerable promise in cancer therapy due to its distinct biochemical properties and potential for synergistic interaction with other treatments. This review comprehensively explores multimodal synergistic ferroptosis cancer therapy, elucidating mechanistic insights and therapeutic potential. The synergistic dual activation of ferroptosis enhances cancer cell death by overwhelming cellular antioxidant defenses and potentiating cytotoxic effects, offering tailored therapy. Combining ferroptosis with photodynamic therapy (PDT), photothermal therapy (PTT), sonodynamic therapy (SDT) and chemodynamic therapy (CDT) demonstrates synergistic effects in enhancing reactive oxygen species (ROS) generation, disrupting cellular membranes, and inducing immunogenic cell death (ICD), improving treatment outcomes. Integrating ferroptosis therapy with immunotherapy harnesses the immune system to target cancer cells, priming the tumor microenvironment for immune recognition and activation, enhancing immunotherapy efficacy. Challenges and opportunities for multimodal synergistic ferroptosis cancer therapy consist of identifying optimal combinations, elucidating treatment resistance mechanisms, optimizing protocols, and developing targeted delivery systems. The integration of ferroptosis therapy with other modalities holds promise for revolutionizing cancer treatment and advancing precision medicine.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216236"},"PeriodicalIF":20.3,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142315702","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Experimental and computational journey on transition-metal-catalyzed CH functionalization with fluorinated π-systems","authors":"Zhongyi Zeng ,&nbsp;Huiying Xu ,&nbsp;Hui Gao,&nbsp;Zhi Zhou,&nbsp;Wei Yi","doi":"10.1016/j.ccr.2024.216244","DOIUrl":"10.1016/j.ccr.2024.216244","url":null,"abstract":"<div><div>Transition-metal-catalyzed direct C<img>H functionalization utilizing unsaturated hydrocarbons have been established as a robust strategy to increase molecular complexity without the need of substrate prefunctionalization. Especially, the C<img>H functionalization mode involving several innovative fluorinated π-systems, including difluorinated alkynes, cyclopropenes as well as allenes, has been intensively investigated in recent years, which not only enriches the new connotation of this hot topic but also opens up a new field of vision on how to promote organic integration of transition-metal-catalyzed C<img>H functionalization with fluorine chemistry, even with pharmaceutical science. Induced by their inherently distinctive fluorine effects, these fluorine-functionalized π-compounds have efficiently expanded the scope of the C<img>H functionalization reactions by introducing enhanced chemoselectivity, regioselectivity and stereoselectivity, which greatly enriches the connotation of C<img>H activation chemistry, and ultimately, promoting the development of organic chemistry. In this review, we provide a comprehensive summary of the latest progress in transition-metal-catalyzed C<img>H functionalization with recently developed fluorinated π-systems since 2017, with particular focus on a rational analysis on reaction development and the elucidation of their mechanisms revealed by integrating computational investigation with experimental data. Finally, several challenges and future perspectives on this topic are also discussed. We believe that this review can offer a profound insight into the synergistic combination of experimental and theoretical studies for the future design of unexplored C<img>H functionalization reaction modes driven by diverse C<img>H activation substrates and fluorinated π-partners. This, in turn, is expected to spur the discovery and development of innovative reaction paradigms in this field of transition-metal-catalyzed C<img>H activation/functionalization.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216244"},"PeriodicalIF":20.3,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142315701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The photocatalytic H2O2 production: Design strategies, Photocatalyst advancements, environmental applications and future prospects","authors":"Asif Hayat ,&nbsp;Zeeshan Ajmal ,&nbsp;Abdullah Yahya Abdullah Alzahrani ,&nbsp;Sana Ben Moussa ,&nbsp;Manal Khered ,&nbsp;Naif Almuqati ,&nbsp;Ahmad Alshammari ,&nbsp;Yas Al-Hadeethi ,&nbsp;Hamid Ali ,&nbsp;Yasin Orooji","doi":"10.1016/j.ccr.2024.216218","DOIUrl":"10.1016/j.ccr.2024.216218","url":null,"abstract":"<div><p>Hydrogen peroxide (H₂O₂) is a multipurpose and highly efficient agent that may be used as an oxidizing agent in several fields, including the bleaching industry, pollution control, medical treatments, and chemical synthesis. The existing approach for producing H₂O₂ is regarded as neither affordable nor environmentally friendly owing to its high energy requirements and the emission of hazardous organic compounds. The photocatalytic H₂O₂ production is a sustainable and economical process that uses water (H₂O) and gaseous oxygen (O₂) as its primary inputs and light as the energy source. However, the low capacity to absorb light, rapid interaction of the particles, and insufficient internal functioning of activated sites in unmodified photocatalysts hinder the achievement of high yields in photocatalytic H₂O₂ generation. The sustainable production of H₂O₂ from H₂O and O₂ through photocatalysis has been a persistent challenge. Nevertheless, it has the potential to substitute for conventional production methods. The current article outlines methods for improving the efficiency of H₂O₂ generation and optimizing the design and properties of metal-free-based photocatalysts at the molecular level. These techniques are intended to enhance the overall efficiency of photocatalysis. We provide a brief overview of significant developments in the research and development of advanced photocatalytic materials that are especially engineered for generating H₂O₂ via the use of light energy. This study provides a comprehensive discussion of the core principles and advantages of H₂O₂ photosynthesis. Subsequently, it classifies and precisely evaluates the key components included in this procedure. Finally, it provides an overview outlook on how to address possible challenges and realize opportunities in the area of photocatalytic H₂O₂ production. This work aims to validate present challenges and progress in the photosynthesis of H₂O₂, while providing insights for the production of exceptionally effective photocatalysts to allow that follows the development of photocatalytic H₂O₂ production.</p></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216218"},"PeriodicalIF":20.3,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142272972","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}