Coordination Chemistry Reviews最新文献_第8页

Photoinduced hydrofluoroalkylation of alkenes 光诱导烯烃的氢氟烷基化

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2025-09-19 DOI: 10.1016/j.ccr.2025.217189

Vladislav S. Kostromitin , Vitalij V. Levin , Alexander D. Dilman

引用次数: 0

Recent advances of theoretical investigation on lead-free metal halide perovskites 无铅金属卤化物钙钛矿理论研究进展

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2025-09-18 DOI: 10.1016/j.ccr.2025.217182

Lingjun Wu , Hao Huang , Xue Zhang , Guangjun Zhang , Wanqiang Liu , Ziyi Ge , Tao Wu

{"title":"Recent advances of theoretical investigation on lead-free metal halide perovskites","authors":"Lingjun Wu , Hao Huang , Xue Zhang , Guangjun Zhang , Wanqiang Liu , Ziyi Ge , Tao Wu","doi":"10.1016/j.ccr.2025.217182","DOIUrl":"10.1016/j.ccr.2025.217182","url":null,"abstract":"<div><div>Metal halide perovskites (MHPs) have aroused as promising candidates in diverse applications, however, the widespread use of Pb-based MHPs is troubled by issues of toxicity and instability. This has spurred significant research efforts to develop Pb-free alternatives with comparable or superior properties. Theoretical investigations play a critical role in this pursuit, offering unparalleled insights into material behaviors at microscopic spatial scales and ultrafast timescales. This review presents a thorough discussion of the theoretical advancements in Pb-free MHPs, encompassing their crystal structures, electronic properties, optical properties, the lattice dynamics, thermodynamic and chemical stability, mechanical properties, ion migration and thermoelectric properties, and the advantages of theoretical means and their vital role in understanding and optimizing the properties of Pb-free MHPs are systematically highlighted. Furthermore, this review identifies the current challenges and outlines potential directions for advancing the field, offering inspiration for innovation. This work aims to accelerate the replacement of Pb-based MHPs by Pb-free alternatives, fostering the development of sustainable, high-performance Pb-free MHPs for future applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217182"},"PeriodicalIF":23.5,"publicationDate":"2025-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145077427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Versatile electrochemical cells based on nitrate reduction reaction 基于硝酸还原反应的多功能电化学电池

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2025-09-17 DOI: 10.1016/j.ccr.2025.217180

Ming-Lei Sun, Zhong-Yong Yuan

引用次数: 0

Understanding and mitigating interfacial defects in tin‑lead perovskites for robust photovoltaics 了解和减轻锡铅钙钛矿中用于鲁棒光伏的界面缺陷

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2025-09-17 DOI: 10.1016/j.ccr.2025.217177

Aili Wang , Chunna Huang , Kaihuai Du , Luozheng Zhang , Lvzhou Li , Xu Dong , Artem Musiienko , Meng Li , Antonio Abate , Xiangli Wen , Guixiang Li , Jianning Ding

{"title":"Understanding and mitigating interfacial defects in tin‑lead perovskites for robust photovoltaics","authors":"Aili Wang , Chunna Huang , Kaihuai Du , Luozheng Zhang , Lvzhou Li , Xu Dong , Artem Musiienko , Meng Li , Antonio Abate , Xiangli Wen , Guixiang Li , Jianning Ding","doi":"10.1016/j.ccr.2025.217177","DOIUrl":"10.1016/j.ccr.2025.217177","url":null,"abstract":"<div><div>Tin‑lead (Sn<img>Pb) hybrid perovskite solar cells (PSCs) have attracted considerable attention due to their lower bandgaps, enabling higher Shockley-Queisser (S-Q) limit efficiencies and promising applications in all-perovskite tandem solar cells. However, Sn<img>Pb perovskites suffer from abundant defect states, particularly at the interfaces, which primarily stem from the chemical instability of Sn (II) and the inherent weaknesses of the crystal structure. These defects induce severe non-radiative recombination at grain boundaries/film surfaces that hinder charge transport and accelerate film degradation, ultimately limiting the device's efficiency and operational stability. This review systematically discusses the surface/interfacial defect types and their formation mechanisms in Sn<img>Pb perovskites, followed by an in-depth analysis of defect passivation mechanisms. We further summarize the latest advancements in passivation strategies and analyze their impact on device performance. Finally, we outline key challenges and future research directions for achieving high-performance and robust Sn<img>Pb PSCs, which are crucial for shaping the evolution of next-generation perovskite photovoltaic technologies.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217177"},"PeriodicalIF":23.5,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145072192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The promising path of Oral MOFs: Redefining strategies for gastrointestinal detoxification 口服MOFs的前景：重新定义胃肠道解毒策略

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2025-09-17 DOI: 10.1016/j.ccr.2025.217168

Yilin Quan , Ya Wu , Kai Wang , Hong-Xia Ren , Gonghao Zhang , Yang Zhao , Yang-Bao Miao

{"title":"The promising path of Oral MOFs: Redefining strategies for gastrointestinal detoxification","authors":"Yilin Quan , Ya Wu , Kai Wang , Hong-Xia Ren , Gonghao Zhang , Yang Zhao , Yang-Bao Miao","doi":"10.1016/j.ccr.2025.217168","DOIUrl":"10.1016/j.ccr.2025.217168","url":null,"abstract":"<div><div>Poisoning from oral toxin exposure remains a pressing global health issue, with current detoxification strategies often limited by poor efficacy and specificity. This review highlights recent advances in gastrointestinal detoxification, emphasizing the emergence of oral metal–organic frameworks (MOFs) as next-generation therapeutic agents. We first examine the physiological characteristics of the gastrointestinal (GI) tract relevant to MOF functionality. Then, we discuss the mechanisms by which oral MOFs achieve selective toxin adsorption and clearance, leveraging their high surface area, structural tunability, and binding specificity. The synergistic interactions between MOFs and gut microbiota are explored, particularly their potential to enhance detoxification and restore intestinal homeostasis. Additionally, we introduce the integration of artificial intelligence (AI) in guiding MOF design, enabling predictive modeling of in vivo performance. Together, these insights showcase oral MOFs as a transformative platform for safe, targeted, and intelligent detoxification, paving the way for future clinical and emergency applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217168"},"PeriodicalIF":23.5,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145072193","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Insights into semiconductor heterojunctions for enhanced photocatalytic performance and applications 半导体异质结对增强光催化性能和应用的见解

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2025-09-17 DOI: 10.1016/j.ccr.2025.217184

Xiaoshuai Wang, Zhong-Yong Yuan

{"title":"Insights into semiconductor heterojunctions for enhanced photocatalytic performance and applications","authors":"Xiaoshuai Wang, Zhong-Yong Yuan","doi":"10.1016/j.ccr.2025.217184","DOIUrl":"10.1016/j.ccr.2025.217184","url":null,"abstract":"<div><div>Semiconductor heterojunction combining with two or more photocatalytic materials has boosted a renovated interest in fields ranging from energy storage to environmental protection, resulting from the special synergistic preponderance in comparison of single-component photocatalysts. Generally speaking, the heterojunction formed at photocatalyst interface promotes the electrons rearrangement due to the discrepancy of Fermi lever, further inducing a robust internal electric field (IEF) which has a positive effect on the photogenerated charge separation and migration, enhancing the photocatalytic performance. The majority of extant research is oriented towards the design, characterization and application of specific heterojunctions, which lacks a comprehensive overview of all the common types of semiconductor heterojunctions. Thus, in order to better understand the photocatalytic mechanisms and construction methods of heterojunction photocatalysts, this review firstly summarizes basic categories of photocatalytic heterojunction systems, and simultaneously takes some typical examples to verify the important function of heterojunction. The design principle of heterostructures, as well as their synthesis methods, are summed up. Furthermore, the practical environmental applications of heterojunction photocatalysts are overall introduced, including environmental wastewater remediation, water splitting, CO<sub>2</sub> conversion, H<sub>2</sub>O<sub>2</sub> synthesis and other applications, and the challenges associated with the construction method of heterojunction and the prospects that motivate future research are comprehensively discussed.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217184"},"PeriodicalIF":23.5,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145077426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Aggregation-induced emission materials for fluorescence analysis: Recent progress in rapid detection of pesticide and veterinary drug residues 荧光分析用聚集诱导发射材料：农药兽药残留快速检测研究进展

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2025-09-17 DOI: 10.1016/j.ccr.2025.217194

Hong Chen , Wang Wang , Yaling Liu , Shu Zhang , Yuying Zhu , Haiyin Li , Xiaojun He

{"title":"Aggregation-induced emission materials for fluorescence analysis: Recent progress in rapid detection of pesticide and veterinary drug residues","authors":"Hong Chen , Wang Wang , Yaling Liu , Shu Zhang , Yuying Zhu , Haiyin Li , Xiaojun He","doi":"10.1016/j.ccr.2025.217194","DOIUrl":"10.1016/j.ccr.2025.217194","url":null,"abstract":"<div><div>Pesticides and veterinary drugs are indispensable for crop cultivation, protection, and storage. However, concerns regarding their persistent residues in soil, water, and agricultural products, which lead to significant environmental pollution and human health risks, cannot be overlooked. Consequently, the urgent development of sensitive, effective, simple, rapid, and user-friendly methods for quantitative residue detection is essential. Fluorescence analysis, characterized by its intuitive readout, high sensitivity, simplicity, speed, and ease of operation, has emerged as a primary technique for this purpose. Aggregation-induced emission (AIE) materials offer a distinct advantage by overcoming the ubiquitous aggregation-caused quenching (ACQ) effect inherent in conventional fluorophores. With high fluorescence quantum yield, tunable photophysical properties, good photostability, and excellent stability, AIE materials provide very slight background signals and high signal intensity, making them extremely effective probes for pesticide and veterinary drug detection. Recent trends in AIE development focus on designing multifunctional and smart probes, integrating AIE materials with portable and on-site detection platforms, and expanding applications toward multiplexed and real-time analysis. This comprehensive review critically surveys the application of AIE material-based fluorescence analysis for detecting various pesticide residues (such as organophosphorus pesticides, paraquat, atrazine, trifluralin, and dithiocarbamates) and veterinary drug residues (including tetracyclines, quinolones, and chloramphenicol). By highlighting recent advancements and key design strategies, this review aims to stimulate further innovation in AIE-based sensors and accelerate their translation into practical, commercial detection technologies to safeguard food safety and environmental health.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217194"},"PeriodicalIF":23.5,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145077433","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Phenylboronic acid biomaterials: from chemical principles to material design 苯硼酸生物材料：从化学原理到材料设计

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2025-09-16 DOI: 10.1016/j.ccr.2025.217166

Haifei Kang , Ranran Yang , Wenying Wei , Kun Liu , Yingxin Xu , Xiaopei Wu , Honglian Dai

{"title":"Phenylboronic acid biomaterials: from chemical principles to material design","authors":"Haifei Kang , Ranran Yang , Wenying Wei , Kun Liu , Yingxin Xu , Xiaopei Wu , Honglian Dai","doi":"10.1016/j.ccr.2025.217166","DOIUrl":"10.1016/j.ccr.2025.217166","url":null,"abstract":"<div><div>Phenylboronic acid (PBA) and its derivatives have become an important platform for the construction of advanced functional biomaterials due to their unique chemistry. We systematically explore the key chemical properties of PBA and their applications in biomaterial design. The main topics include: 1) the Lewis acidity of PBA, in particular the formation of boron‑nitrogen (B<img>N) coordination bonds with nitrogen-containing compounds, and its applications in drug loading, bioorthogonal chemistry, and molecular sensing, 2) the reversible covalent esterification between PBA and cis-diols, its responsiveness to pH and glucose, as well as its sensitivity to reactive oxygen species (ROS) collectively constitute the basis of its multi-stimuli responsiveness, 3) taking phenylboronic ester hydrogels as an example, the discussion is on the regulation of macroscopic properties and responsive behaviors through precise structural design of PBA units and diol units. This review emphasizes that an in-depth understanding of the chemistry of PBA is crucial for the rational design of next-generation biomaterials with specific functions (e.g., targeted delivery, smart response, and real-time monitoring), providing theoretical guidance and design ideas to promote their applications in drug delivery, biosensing, and tissue engineering.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217166"},"PeriodicalIF":23.5,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145067867","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Bioinspired bi- or trinuclear FeMoS model complexes for the partial region of FeMo cofactor of nitrogenase 生物启发的双核或三核FeMo模型配合物部分区域的FeMo辅助因子

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2025-09-16 DOI: 10.1016/j.ccr.2025.217128

Maxime Laurans , Philippe Schollhammer

引用次数: 0

Explosive advances of metal-organic frameworks-derived single atom catalysts modified by metal species in diverse sizes for electrocatalysis: Synthesis, collaboration, and mechanism 电催化用不同尺寸金属改性金属有机骨架衍生单原子催化剂的爆炸性进展：合成、协同作用和机理

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2025-09-16 DOI: 10.1016/j.ccr.2025.217167

Ziyue Yuan , Min Cheng , Jing Tong , Suhua Chen , Guangfu Wang , Hongda Liu , Huayue Kang , Qingkai Shi , Ao Chen , Yawen Guo

{"title":"Explosive advances of metal-organic frameworks-derived single atom catalysts modified by metal species in diverse sizes for electrocatalysis: Synthesis, collaboration, and mechanism","authors":"Ziyue Yuan , Min Cheng , Jing Tong , Suhua Chen , Guangfu Wang , Hongda Liu , Huayue Kang , Qingkai Shi , Ao Chen , Yawen Guo","doi":"10.1016/j.ccr.2025.217167","DOIUrl":"10.1016/j.ccr.2025.217167","url":null,"abstract":"<div><div>Metal-organic frameworks derived single atom catalysts (MOF-derived SACs) have attracted widespread attention in the electrocatalysis field due to the maximum atomic economy and exceptional reactivity toward catalysis. However, one pivotal obstacle to the catalytic performance is the complex multiple electron reactions, which still encounter challenges by solely relying on the single active sites. Fortunately, the introduction of metal species of diverse sizes into SACs (DSM-SACs) is expected to integrate their respective advantages and significantly enhance the activity and selectivity of catalysts. A comprehensive review is urgently needed to offer a concise overview of the recent progress in DSM-SACs. Herein, this review initially systematically examined the synthesis strategies for MOF-derived DSM-SACs, focusing on the discrepancy of metal sources provided by MOFs. Subsequently, the distinctive cross-size multiple synergistic mechanisms of MOF-derived DSM-SACs were thoroughly elucidated. Furthermore, in conjunction with the mechanisms underlying various electrocatalytic reactions, the significant breakthroughs across different electrocatalytic processes were delineated. Finally, the research challenges and the future development directions of synergistic structures were discussed. This review will facilities the fundamental understanding of molecular mechanisms and provided efficient principles aimed at improving electrocatalytic performance for MOF-derived SACs and beyond.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"548 ","pages":"Article 217167"},"PeriodicalIF":23.5,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145067866","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0