Coordination Chemistry Reviews最新文献_第8页

Magnetic nanoprobe-enabled lateral flow assays in the applications of food safety and in vitro diagnostic

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-09 DOI: 10.1016/j.ccr.2025.216588

Shipeng Gao , Xueyun Zheng , Jun Zhu , Yang Zhang , Ruinyun Zhou , Tianxing Wang , Jaroslav Katona , Di Zhang , Xiaobo Zou

{"title":"Magnetic nanoprobe-enabled lateral flow assays in the applications of food safety and in vitro diagnostic","authors":"Shipeng Gao , Xueyun Zheng , Jun Zhu , Yang Zhang , Ruinyun Zhou , Tianxing Wang , Jaroslav Katona , Di Zhang , Xiaobo Zou","doi":"10.1016/j.ccr.2025.216588","DOIUrl":"10.1016/j.ccr.2025.216588","url":null,"abstract":"<div><div>Early-stage disease and food contamination identification can enable timely medical care and avert possible food poisoning incidents. With their remarkable benefits of affordability, speed, portability, real sample applicability, and reliability, lateral flow assays (LFAs) are common point-of-care instruments that have been extensively investigated in the fields of food safety, in vitro diagnostics, and environmental monitoring. Nanoprobes are the essential components of LFAs that produce sensitive, specific, and reliable signals for determining trace levels of analytes in food and clinical samples. Magnetic nanocomposites have become impressive signal probes for LFAs thanks to the magnetic enrichment capability of magnetic nanocomponents, which significantly reduces the matrix effect and improves the signal-to-noise ratio. This review systematically presents recent advancements in key aspects of magnetic LFA preparation and application, including 1) describing different magnetic nanoprobes that simultaneously integrate the properties of magnetic and secondary nanoparticles (plasmonic, fluorescent, and photothermal features) and their corresponding signal readout mode, as well as 2) highlighting protocols and strategies for the preparation of magnetic nanocomposites with distinct analytical characteristics, and 3) introducing the utilization of magnetic LFA in food safety (pathogens, pesticide and antibiotic residues, mycotoxins, and allergens) and in vitro diagnostic applications (respiratory bacteria and biomarkers). Potential strategies for converting magnetic LFAs from laboratory to practical applications are also explored. This review paves the way for the broader implementation of magnetic LFA in food safety and in vitro diagnostics by systematically covering the current applications, challenges, opportunities, and potential prospects for magnetic LFA.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"534 ","pages":"Article 216588"},"PeriodicalIF":20.3,"publicationDate":"2025-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143577268","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Comprehensive insights into molecular simulation-driven advances in functional materials for pollutant mitigation 全面了解分子模拟驱动的功能材料在减缓污染物方面的进展

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-08 DOI: 10.1016/j.ccr.2025.216580

Iman Salahshoori , Majid Namayandeh Jorabchi , Morteza Asghari , Sebastian Wohlrab , Mehdi Golriz , Hossein Ali Khonakdar

{"title":"Comprehensive insights into molecular simulation-driven advances in functional materials for pollutant mitigation","authors":"Iman Salahshoori , Majid Namayandeh Jorabchi , Morteza Asghari , Sebastian Wohlrab , Mehdi Golriz , Hossein Ali Khonakdar","doi":"10.1016/j.ccr.2025.216580","DOIUrl":"10.1016/j.ccr.2025.216580","url":null,"abstract":"<div><div>Removing gaseous pollutants from the environment is a pressing global concern due to their detrimental effects on human health and ecosystems. Adsorbents, materials capable of capturing and retaining gaseous molecules, play a crucial role in addressing this issue. While laboratory experiments are indispensable for adsorbent development, they can be time-consuming and resource-intensive. On the other hand, molecular simulation methods offer a powerful alternative by providing insights into the adsorption process at the molecular level. This review article explores the application of molecular simulation in designing and optimizing functional materials for gaseous pollutant mitigation. It discusses the fundamental principles of molecular simulation techniques and their advantages over traditional laboratory methods. A wide range of adsorbent materials, including polymers, carbon nanotubes, graphene oxide, zeolites, metal-organic frameworks, zeolitic imidazolate frameworks, and covalent organic frameworks, are examined in detail. Numerous practical examples illustrate how molecular simulation can predict adsorption capacities, selectivity, and kinetics. This review aims to empower researchers to create more efficient and sustainable solutions for gaseous pollutant removal by providing a comprehensive overview of molecular simulation methods and their applications in adsorbent development. The insights gained from molecular simulation can accelerate the development of innovative adsorbents, ultimately contributing to a cleaner and healthier environment.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"534 ","pages":"Article 216580"},"PeriodicalIF":20.3,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143576193","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Progress of supported Pt-based catalysts for electrochemical methanol energy conversion

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-07 DOI: 10.1016/j.ccr.2025.216603

Jiaojiao Li , Fulin Yang , Ligang Feng

{"title":"Progress of supported Pt-based catalysts for electrochemical methanol energy conversion","authors":"Jiaojiao Li , Fulin Yang , Ligang Feng","doi":"10.1016/j.ccr.2025.216603","DOIUrl":"10.1016/j.ccr.2025.216603","url":null,"abstract":"<div><div>Electrochemical methanol energy conversion based on direct methanol fuel cells (DMFCs) and methanol-assisted water splitting (MAWS) for hydrogen generation has received increasing attention. However, the slow kinetics of the methanol oxidation reaction (MOR), a key challenge that limits their efficiency and performance, remains a major obstacle to large-scale commercial applications. Supported platinum (Pt)-based electrocatalysts have shown significant potential to enhance MOR performance by leveraging coordination synergistic effects between the catalyst and support materials. This review provides an in-depth overview of the recent progress in developing supported Pt-based electrocatalysts for methanol energy conversion systems. We first outline the established mechanism of methanol oxidation and highlight recent advancements in situ techniques that provide deeper insights into the MOR process. Then, the emphasis on support impact on catalytic activity and mechanism, various modification strategies and preparation methods for developing supported Pt-based catalysts were highlighted. The practical applications of Pt-based catalysts in DMFCs and MAWS were presented, with a particular focus on different support types, including carbon-based, non‑carbon-based, and hybrid materials. The review also provides a comprehensive understanding of the catalytic challenges and opportunities, offering valuable insights and guidance for the future development of supported Pt-based electrocatalysts in methanol-relevant energy conversion systems.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"534 ","pages":"Article 216603"},"PeriodicalIF":20.3,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143562493","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ferrites/carbon allotropes nanocomposites for photocatalytic applications: A review

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-07 DOI: 10.1016/j.ccr.2025.216537

Hesham A. Hamad , Moemen Adel , Mahmoud M. Emara , Mohamed Elsenety , Ibrahim M.A. Mohamed , Ahmed G. Bedir , Zineb Gargar , Marwa M. Abouelela , Nada A. Eldeeb , Islam Ibrahim , Abdelhamied A. Hassan , Mouna El Abboubi , Khaled M. Amin

{"title":"Ferrites/carbon allotropes nanocomposites for photocatalytic applications: A review","authors":"Hesham A. Hamad , Moemen Adel , Mahmoud M. Emara , Mohamed Elsenety , Ibrahim M.A. Mohamed , Ahmed G. Bedir , Zineb Gargar , Marwa M. Abouelela , Nada A. Eldeeb , Islam Ibrahim , Abdelhamied A. Hassan , Mouna El Abboubi , Khaled M. Amin","doi":"10.1016/j.ccr.2025.216537","DOIUrl":"10.1016/j.ccr.2025.216537","url":null,"abstract":"<div><div>Metal ferrites have low bandgap (E<sub>g</sub>) values between 1.8 and 2.9 eV so that they can absorb visible light. They are applied in lithium batteries, supercapacitor electrodes, electronic and magnetic devices, and photocatalysis thanks to their significant electrical conductivity and magnetic properties. Being magnetic allows metal ferrites to be recycled. Metal ferrites, however, can aggregate due to the magnetic interactions of their particles that reduce their effective surface area. Metal ferrites have low stability in highly acidic media. All these demerits are added to the electron-hole recombination problem. Various supports were investigated to anchor metal ferrites to minimize these problems. These supports include biopolymers, conductive polymers, and carbon-based supports. Carbon-based supports have surface oxygen-containing groups, extended sp<sup>2</sup> <span><math><mi>π</mi></math></span>-conjugation system, and highly porous scaffolds, and they are highly stable in extremely acidic and basic media. Carbon supports anchor metal ferrites via their surface oxygenated functional groups to retard metal ferrites aggregation and accept the conduction band electrons of metal ferrites via their <span><math><mi>π</mi></math></span>-bonds system. Composing carbon supports with metal ferrites acquires these supports magnetic properties that ease the composite reuse. In this review, we will explore the different applications of composites of metal ferrites with various carbon allotropes as photocatalysts.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"534 ","pages":"Article 216537"},"PeriodicalIF":20.3,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143562602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Macrocycle-based metal–organic and covalent organic framework membranes

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-07 DOI: 10.1016/j.ccr.2025.216559

Shi-Qi Cheng , Yi Liu , Yue Sun

{"title":"Macrocycle-based metal–organic and covalent organic framework membranes","authors":"Shi-Qi Cheng , Yi Liu , Yue Sun","doi":"10.1016/j.ccr.2025.216559","DOIUrl":"10.1016/j.ccr.2025.216559","url":null,"abstract":"<div><div>Membranes are a disruptive technology that can reduce the energy consumption of chemical separation processes. There are many remarkable materials that can be used for membrane building blocks; for example, covalent organic frameworks (COFs) and metal-organic frameworks (MOFs) are emerging porous materials with uniform, tunable pores, ultrahigh surface areas, and accessible active sites. However, the aggregation of COF and MOF layers can affect the application properties of the material. Supramolecular macrocyclic hosts with well-defined cavities are easy to functionalize. In addition, it is beneficial to adjust the interpenetration effect, porosity, stability, and functionalities of MOF or COF materials, broadening their scope of applications. Therefore, macrocycle-based MOFs (M-MOFs) and COFs (M-COFs) are attractive candidates for building blocks for the construction of precise separation membranes and multifunctional membranes. This review focuses on the development and fabrication strategies of M-MOF and M-COF membranes and their emerging applications. The remaining challenges and proposals for M-MOF and M-COF membranes are also summarized. It is anticipated that this review will inspire further research in supramolecular chemistry and membrane separations.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"534 ","pages":"Article 216559"},"PeriodicalIF":20.3,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143562601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Single-atom catalysts for electrocatalytic conversion of biomass-derived small molecules

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-06 DOI: 10.1016/j.ccr.2025.216576

Yulu Yang, Shengkai Li, Wenjie Wu, Shuangyin Wang, Yuqin Zou

{"title":"Single-atom catalysts for electrocatalytic conversion of biomass-derived small molecules","authors":"Yulu Yang, Shengkai Li, Wenjie Wu, Shuangyin Wang, Yuqin Zou","doi":"10.1016/j.ccr.2025.216576","DOIUrl":"10.1016/j.ccr.2025.216576","url":null,"abstract":"<div><div>The utilization of renewable energy to drive the electrocatalytic transformation of biomass into high-value chemicals has emerged as one of the effective tactics for sustainable energy utilization and chemical green production. However, developing efficient catalysts is a considerable challenge due to the complexity of biomass electrocatalytic conversion. Single-atom catalysts demonstrate outstanding performance in electrocatalytic reactions because of the maximized atom utilization, well-defined structure, and distinctive electronic properties. This review first introduces the advances in the metal-support interactions and characterization techniques of SACs. Recent research advances of SACs in electrocatalytic biomass derivatives conversion are further systematically summarized, including anodic oxidation and cleavage bond reactions of alcohols (monohydric and polyhydric), aldehydes, and lignin; and cathodic hydrogenation of aldehydes (5-hydroxymethylfurfural and furfural) and electrocatalytic biomass hydrogenation mediated C<img>N coupling for the preparation of amino acids and oximes. Finally, the perspectives and challenges within the domain of SACs for the advanced electrocatalytic conversion of biomass are proposed. This review offers guidance for the rational design and precise preparation of SACs for the conversion of biomass.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"534 ","pages":"Article 216576"},"PeriodicalIF":20.3,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143551945","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electrocatalysis for liquid chemical hydrogen storage

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-06 DOI: 10.1016/j.ccr.2025.216562

Hao Chen , Yongbing Ma , Qilong Wu , Hanshuai Xu , Lubo Zhang , Xin Wang , Xiao Lyu , Jun Chen , Yi Jia

{"title":"Electrocatalysis for liquid chemical hydrogen storage","authors":"Hao Chen , Yongbing Ma , Qilong Wu , Hanshuai Xu , Lubo Zhang , Xin Wang , Xiao Lyu , Jun Chen , Yi Jia","doi":"10.1016/j.ccr.2025.216562","DOIUrl":"10.1016/j.ccr.2025.216562","url":null,"abstract":"<div><div>Faced with the challenges posed by the energy shortages and environmental degradation, hydrogen energy presents significant potential for realizing global sustainable development of energy today. Although hydrogen holds a variety of merits as a direct energy carrier, its large-scale storage, and transportation remain major technical hurdles. For comparison, electrocatalytic synthesized high hydrogen-containing liquid chemicals offer notable advantages in terms of controllable catalytic hydrogen evolution and superior storage and transportation capabilities. To expedite reaction speed and enhance hydrogen storage capacity in hydrogen-containing liquid chemicals, it is crucial to design novel and efficient electrocatalysts alongside high-performance electrolytic cell systems. This review aimed to summarize representative and efficient catalysts employed in the electrocatalytic production of various liquid chemicals crucial for hydrogen storage and transportation, such as methanol, formic acid, liquid ammonia, and methylcyclohexane. Additionally, new designs for electrolytic cell systems will be discussed, including electrode hydrophilicity optimization and flow field design.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"534 ","pages":"Article 216562"},"PeriodicalIF":20.3,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143551988","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Exploring the principles and applications of non-metal photothermal catalysts: Insights from mechanistic differences with metal counterparts

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-06 DOI: 10.1016/j.ccr.2025.216579

Yaocheng Deng , Huiling Liu , Zhanpeng Zhou , Ling Li , Yu Shi , Rongdi Tang , Ying Huang

{"title":"Exploring the principles and applications of non-metal photothermal catalysts: Insights from mechanistic differences with metal counterparts","authors":"Yaocheng Deng , Huiling Liu , Zhanpeng Zhou , Ling Li , Yu Shi , Rongdi Tang , Ying Huang","doi":"10.1016/j.ccr.2025.216579","DOIUrl":"10.1016/j.ccr.2025.216579","url":null,"abstract":"<div><div>Photothermal catalysts can effectively harness the near-infrared (NIR) spectrum of sunlight to facilitate non-radiative relaxation and exhibit significant potential in environmental and energy-related applications. However, the photothermal performance of metal-based catalysts is hindered by the narrow bandwidth of their metal plasma resonance and the high material costs. Consequently, researchers are actively investigating new non-metal photothermal catalysts that offer simplified fabrication and operation. Non-metal photothermal catalysts include carbon-based photothermal catalysts and organic photothermal catalysts. In recent years, considerable attention has been dedicated to pursuing innovative and high-performance photothermal catalysts. Therefore, this review explores the differences in photothermal catalysis mechanisms between metal and non-metal photothermal catalysts, focusing explicitly on the development of carbon-based and donor–acceptor organic photothermal catalysts. It includes the thermal aggregation effect of carbon-based materials, twisted intramolecular charge transfer (TICT) effect, aggregation induction effect, and organic conjugation effect of organic photothermal catalysts. In addition, this review encompasses utilizing non-metal photothermal catalysts in diverse applications such as seawater resource utilization, carbon dioxide (CO<sub>2</sub>) conversion, pollutant degradation, and photothermal therapy. In short, this review endeavors to provide researchers with an in-depth and holistic perspective on non-metal photothermal catalysts and broaden the application range for non-metal photothermal catalysts within the energy and environmental science fields.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"534 ","pages":"Article 216579"},"PeriodicalIF":20.3,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143551989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Comparative analysis of seawater uranium extraction materials: Toward the development of bio-based and biomimetic materials

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-05 DOI: 10.1016/j.ccr.2025.216589

Wansheng Zhang , Mengqin Wu , Yangyang Xin , Huizhou Liu , Fengwei Li , Yun Fa

{"title":"Comparative analysis of seawater uranium extraction materials: Toward the development of bio-based and biomimetic materials","authors":"Wansheng Zhang , Mengqin Wu , Yangyang Xin , Huizhou Liu , Fengwei Li , Yun Fa","doi":"10.1016/j.ccr.2025.216589","DOIUrl":"10.1016/j.ccr.2025.216589","url":null,"abstract":"<div><div>Globally, the identified exploitable uranium resources are being rapidly depleted, while the escalating demand for uranium is placing unprecedented pressure on the supply chain. Although the ocean contains more than 1000 times the uranium reserves found on land, the extremely low concentration of uranium in seawater and the complexity of the marine environment have hindered the economic viability of seawater uranium extraction compared to land-based mining. Over the past six decades, researchers have concentrated on two critical areas to reduce the costs associated with seawater uranium extraction: the discovery of novel uranium adsorption materials and the scaling-up of the extraction process. This review synthesizes advancements in various types of uranium extraction materials, provides a comparative analysis of their performance and efficiency, and offers insights into the potential development of bio-based materials or biosorbents for uranium adsorption under the unique conditions of the marine environment. The aim is to pave new avenues and directions for the future development of seawater uranium extraction technologies.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"534 ","pages":"Article 216589"},"PeriodicalIF":20.3,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143546933","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Reevaluating feature importance in gas–solid interaction predictions: A call for robust statistical methods

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-03-05 DOI: 10.1016/j.ccr.2025.216584

Yoshiyasu Takefuji

引用次数: 0