Coordination Chemistry Reviews最新文献

{"title":"Rare earth luminescent nanothermometers for biological thermal sensing","authors":"Yishuo Sun,&nbsp;Mengya Kong,&nbsp;Jiaming Ke,&nbsp;Yuyang Gu,&nbsp;Fuyou Li,&nbsp;Wei Feng","doi":"10.1016/j.ccr.2024.216222","DOIUrl":"10.1016/j.ccr.2024.216222","url":null,"abstract":"<div><div>Temperature is a fundamental parameter closely related to physiological status in various biological cycles. Due to the significant role that temperature plays in life science, thermal sensing has gained extensive attention in the field of biological detection. Thermal sensing based on luminescence signals shows certain advantages, such as being non-invasive and fast. By further reducing the size of luminescent thermometers to the nanoscale, it is expected to accurately detect temperature in small biological settings. Among several nanothermometers, rare earth luminescent nanothermometers exhibit distinctive thermal sensing properties, making them excellent for measuring biological temperatures. This review primarily discusses thermal sensing methods for optimal detection performance. The optical systems used as thermal sensing equipment and the thermal sensing evaluation indexes as the evaluation standards are subsequently summarized. For specific biological scenarios, the selection of thermal sensing methods based on the requirements of relevant biological parameters are specifically analyzed. In particular, state-of-the-art biological applications based on the unique rare earth luminescent properties are highlighted for accurate thermal measurement from the cellular level to the organism. With a multidisciplinary approach that involves material, optical, and biological analysis, the review aims to provide guidance and propose the prospects of rare earth nanothermometers for biological thermal sensing.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216222"},"PeriodicalIF":20.3,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142374425","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unlocking the potential of borophene: Recent progress in synthesis, properties, and applications","authors":"Anuj Kumar ,&nbsp;Alagarsamy S.K. Kumar ,&nbsp;Ganeshraja A. Sundaram ,&nbsp;Felipe Martins de Souza ,&nbsp;Ram K. Gupta ,&nbsp;Phuong V. Pham","doi":"10.1016/j.ccr.2024.216246","DOIUrl":"10.1016/j.ccr.2024.216246","url":null,"abstract":"<div><div>Boron (B), located in close proximity to carbon and positioned between metals and non-metals in the periodic table, is an element that exhibits exceptional chemical and physical versatility. It can be effectively managed to create flat structures with small dimensions, known as borophene, which possess fascinating features. In the ever-expanding landscape of two-dimensional materials, borophene has recently emerged as a compelling focus of research, captivating the interest of scientists globally. Endowed with an extraordinary atomic structure and remarkable properties, borophene stands poised to unlock a multitude of breakthroughs across diverse domains, including supercapacitors, batteries, hydrogen storage, fuel cells, water splitting, biomedical, and beyond. This review provides a comprehensive overview of theoretical and practical advances in borophene synthesis, as well as its unique properties and applications in a variety of fields. This overview describes the decade-long effort to understand the structures of B-clusters, which vary in size, as well as the borophene synthesis strategies, which include bottom-up and up-down approaches. Furthermore, it aims to shed light on recent advancements while delineating future avenues for research and innovation in this burgeoning field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216246"},"PeriodicalIF":20.3,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142374426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Molecular endoperoxides for optical imaging and photodynamic therapy","authors":"Dapeng Chen ,&nbsp;Tian Zhang ,&nbsp;Aihong Jiao ,&nbsp;Xiaozhou Mou ,&nbsp;Xiaochen Dong ,&nbsp;Yu Cai","doi":"10.1016/j.ccr.2024.216258","DOIUrl":"10.1016/j.ccr.2024.216258","url":null,"abstract":"<div><div>Molecular endoperoxide (MEPO) structuring with heterocycle peroxide (-O-O-) has shown tremendous promise for diseases diagnosis and treatment. Upon excitation by visible light, X-ray, or ultrasound, the afterglow or chemiluminescence emitted by MEPOs contribute to the development of autofluorescence-free optical imaging modes with ultrahigh signal-to-background ratio. Meanwhile, the reversible process of trapping and releasing of singlet oxygen from heterocycle substrates enables MEPOs to accomplish unconventional photodynamic effect featuring with dark and hypoxia tolerance. This review highlights the recent trends in the development of MEPOs as a powerful tool for optical imaging and photodynamic therapy (PDT). A summary was delivered to clarify the formation, decomposition, classification, and working mechanisms of MEPOs. Design strategies were also introduced with MEPOs towards a broad range of biomedical applications in optical imaging and PDT of different diseases. Lastly, perspectives and challenges for clinical translations were discussed for the direction of next-generation MEPOs.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216258"},"PeriodicalIF":20.3,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142374453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent progress on modification strategies of both metal zinc anode and manganese dioxide cathode materials for high-performance aqueous zinc-ion batteries","authors":"Xiaozhong Zhou,&nbsp;Xiangyuan Li,&nbsp;Junjun Pang,&nbsp;Ziqiang Lei","doi":"10.1016/j.ccr.2024.216255","DOIUrl":"10.1016/j.ccr.2024.216255","url":null,"abstract":"<div><div>Aqueous zinc-ion batteries (AZIBs) are of the most potential energy storage systems for large-scale applications due to their low redox potential (−0.76 V vs standard hydrogen electrode, SHE), high theoretical specific capacity (820 mA h g⁻¹ and 5855 mA h cm⁻³), safety, low toxicity and price, eco-friendliness and abundant reserves. In spite of many hurdles before their practical application, great progress has been achieved on high-performance AZIBs. In this review, the main issues and their root causes faced by metal zinc anode and manganese dioxide cathode of AZIBs are analyzed, and the recent research progress on the modification strategies and their working mechanisms of both metal zinc anode and manganese dioxide cathode are focused on, and their challenges and future development prospects are also proposed, which provide a perspective for high-performance AZIBs, and further promote their practical process.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216255"},"PeriodicalIF":20.3,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142374427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Optimizing the coordination environment of active sites to enhance heterogeneous electrocatalytic performances","authors":"Yuhao Duan ,&nbsp;Dehong Chen ,&nbsp;Ruiyong Zhang ,&nbsp;Yunmei Du ,&nbsp;Lei Wang","doi":"10.1016/j.ccr.2024.216243","DOIUrl":"10.1016/j.ccr.2024.216243","url":null,"abstract":"<div><div>The design of the structure and catalytic function of electrocatalysts is an important core technology to solve the energy crisis. To realize the construction of ideal electrocatalysts, it is necessary to understand the structure-activity relationship between the internal structure (physical structure, electronic structure, electrochemical structure, etc.) of the active sites in electrocatalysts and the heterogeneous electrocatalytic performance from a comprehensive perspective. Obviously, the internal structure of electrocatalysts mainly depends on the actual coordination environment of their active sites. Generally, the coordination environment of the active site covers many aspects, such as coordination number (C.N.), bonding type, steric hindrance, bond length and bond angle, density of active center, etc. By establishing a structure-activity relationship between the coordination environment and the heterogeneous electrocatalytic performance, the design of the ideal coordination environment model of the active site is guided. Moreover, according to the type of catalyst and the location of the active site, the appropriate coordination environment control strategies were proposed for the active site at the bulk catalyst, the heterointerface, the carrier, as well as the electrocatalytic reaction interface, respectively. In particular, the local coordination environment of electrocatalytic reaction interface, as an important factor that directly affects the electrocatalytic performance, is often neglected. Then, the visualization of the coordination environment of the active site is realized by electron microscopy, spectroscopy configuration and In-situ monitoring techniques. Finally, this work summarizes the optimization of the coordination environment for the heterogeneous electrocatalytic reaction, and puts forward personal perspectives on the current challenges. We believe that this work will achieve the directional construction of high-efficiency electrocatalysts guided by the coordination environment of active sites, pointing out the direction for developing new energy in the future.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216243"},"PeriodicalIF":20.3,"publicationDate":"2024-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142369965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent advances in recognition, sensing and extraction of halides: 2019 onwards","authors":"Abu S.M. Islam,&nbsp;Iti Ghosh ,&nbsp;Ambreen Rashid ,&nbsp;Sourav Pramanik ,&nbsp;Pradyut Ghosh","doi":"10.1016/j.ccr.2024.216225","DOIUrl":"10.1016/j.ccr.2024.216225","url":null,"abstract":"<div><div>Over the past few decades, selective halide recognition has garnered widespread attention due to its crucial roles in the environmental and biological processes. However, synthetic receptors capable of binding halides in aqueous media remains a key challenge in modern supramolecular chemistry. Consequently, there have been hitherto a number of reviews published, which mainly focus on specific halides recognition based on colorimetric and/or fluorometric methods. This review article provides a comprehensive overview and highlights the effective strategies, particularly on receptors designing principles, mechanism, extraction, and real time applications for the halides recognition. It is expected that this review could facilitate advancements in the design and synthesis of receptors for recognizing and extracting halides in water.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216225"},"PeriodicalIF":20.3,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142369593","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Confinement strategies for the design of efficient heterogeneous Fenton-like catalysts: From nano-space to atomic scale","authors":"Dengsheng Ma ,&nbsp;Cui Lai ,&nbsp;Huan Yi ,&nbsp;Xiuqin Huo ,&nbsp;Ling Li ,&nbsp;Mingming Zhang ,&nbsp;Fuhang Xu ,&nbsp;Huchuan Yan ,&nbsp;Shuyuan Hu ,&nbsp;Yucan Luo","doi":"10.1016/j.ccr.2024.216241","DOIUrl":"10.1016/j.ccr.2024.216241","url":null,"abstract":"<div><div>In this paper, we review the different confinement strategies of heterogeneous Fenton-like catalysts based on their important roles in catalyst design. Confinement effects can effectively promote the mass transfer ability and interference resistance of heterogeneous Fenton-like reaction processes, and modify the electronic state of the active site to enhance the Fenton-like reaction activity. In this paper, from the different confinement dimensions of the active center (including 3D, 2D, 1D and 0D), we review the effects of confinement strategies on the Fenton-like catalytic reaction in different dimensions. The influence of the morphology and type of confinement substrates on space-confined heterogeneous Fenton-like catalysts, as well as strategies for coordination modification of single-atom active sites on heterogeneous Fenton-like catalysts are described. Finally, we summarize and look forward to the challenges that still exist in the design of confinement strategies and future developing directions for heterogeneous Fenton-like catalysts.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216241"},"PeriodicalIF":20.3,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142369592","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Triggered factors and structure-activity relationship in the dynamic reconstruction processing of MOF for the alkaline oxygen evolution reaction","authors":"Qianglong Qi ,&nbsp;Chengxu Zhang ,&nbsp;Jue Hu","doi":"10.1016/j.ccr.2024.216235","DOIUrl":"10.1016/j.ccr.2024.216235","url":null,"abstract":"<div><div>Metal-organic frameworks (MOF) are promising electrocatalysts for the oxygen evolution reaction (OER). MOFs precatalysts undergo a structural reconstruction that results in the formation of transition metal hydroxyoxides (MOOH) during the OER process, which are widely regarded as the authentic catalytic species for OER. This review comprehensively summarizes the recent progress in the research field of MOF-based OER electrocatalysts in terms of structural reconstruction and analyzes in depth the intrinsic relationship between dynamic reconstruction mechanisms and structural activity. By studying two primary triggering factors for reconstruction: the manipulation of the electrochemical environment and the MOF structure, we aim to understand in detail the dynamic pathway of MOF reconstruction and its correlation with the OER catalytic activity in real time. In addition, this review also addresses the self-healing capabilities of reconstructed MOFs and the stability of their framework structures, providing important insights into the long-term performance of these catalysts. Finally, we propose a new direction for future research based on the current state of knowledge, aimed to better understanding how the microchemical environment affects catalytic activity during dynamic reconstruction, in order to facilitate the design and development of highly efficient MOF-based OER catalysts in the future and make it easier to navigate the future.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216235"},"PeriodicalIF":20.3,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142369591","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent design strategies and applications of small molecule fluorescent probes for food detection","authors":"Peng Zhang ,&nbsp;Jiali Su ,&nbsp;Hui Zhen ,&nbsp;Tong Yu ,&nbsp;Liangchen Wei ,&nbsp;Mingyue Zheng ,&nbsp;Chaoyuan Zeng ,&nbsp;Wei Shu","doi":"10.1016/j.ccr.2024.216232","DOIUrl":"10.1016/j.ccr.2024.216232","url":null,"abstract":"<div><div>Food safety issues have become society's focus and are closely related to consumer health. Therefore, the development of novel food testing technologies that are efficient, accurate, and convenient is of important significance to ensure food safety and public health. The small molecule fluorescent probes have been widely used in food detection because of their high sensitivity, high specificity of recognition, and simplicity of operation in recent years. In this paper, the application of small molecule fluorescent probes in food detection in recent years was reviewed, mainly including the detection of analytes such as metal ions, reactive sulfur species, reactive oxygen species, reactive carbonyl species, biogenic amines, and enzymes. This paper also discusses the current challenges and future research directions of fluorescent probes for food detection, providing a reference for the development of subsequent probes.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216232"},"PeriodicalIF":20.3,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142357405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nanoporous structures-based biosensors for environmental and biomedical diagnostics: Advancements, opportunities, and challenges","authors":"Seyedeh Mehrnoush Nokandeh ,&nbsp;Reza Eivazzadeh-Keihan ,&nbsp;Milad Salimi Bani ,&nbsp;Iman Zare ,&nbsp;Heemin Kang ,&nbsp;Mohammad Tavakkoli Yaraki ,&nbsp;Mohammad Mahdavi ,&nbsp;Ali Maleki ,&nbsp;Rajender S. Varma","doi":"10.1016/j.ccr.2024.216245","DOIUrl":"10.1016/j.ccr.2024.216245","url":null,"abstract":"<div><div>As emerging platforms, nanoporous-based biosensors have potentially useful applications for sensitive and selective detection of various analytes. The integration of nanoporous materials (<em>e.g.</em>, nanocarbons, mesoporous, metal–organic frameworks (MOFs), and MOF-based nanocomposites, <em>etc.</em>) with various transduction techniques, such as electrochemical, optical, and mass-sensitized, has led to the development of biosensors for a wide spectrum of applications in healthcare, environmental monitoring, and food safety. These biosensors take advantage of the unique properties of nanoporous materials, such as tunable pore size and selective surface chemistry with high surface area, and enhance the interaction between the analyte and the recognition element. Overall, biosensors based on nanoporous material have very low limits of detection and appropriate linear range. This review focuses on recent developments in the design of biosensors based on nanoporous materials, including sensing mechanisms and applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"522 ","pages":"Article 216245"},"PeriodicalIF":20.3,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142357404","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}