Coordination Chemistry Reviews最新文献

{"title":"Metal-organic framework-hydrogel composites as emerging platforms for enhanced wound healing applications: Material design, therapeutic strategies, and future prospects","authors":"Fereshte Hassanzadeh Afruzi ,&nbsp;Majid Abdouss ,&nbsp;Ehsan Nazarzadeh Zare ,&nbsp;Erfan Rezvani Ghomi ,&nbsp;Shima Mahmoudi ,&nbsp;Rasoul Esmaeely Neisiany","doi":"10.1016/j.ccr.2024.216330","DOIUrl":"10.1016/j.ccr.2024.216330","url":null,"abstract":"<div><div>Wound healing remains a significant global healthcare challenge, particularly for chronic and complex wounds, imposing the development of advanced therapeutic materials with improved functionality and efficacy. The emergence of hybrid and composite materials offers promising solutions to the multifaceted challenges of wound healing, including infection control and tissue regeneration. Metal-organic frameworks (MOFs) have gained attention due to their high porosity, large surface areas, structural tunability, and potential to incorporate therapeutic agents, making them ideal candidates for wound healing applications. Additionally, hydrogels are recognized for their soft, porous, extracellular matrix-like structure, moisturizing properties, and biocompatibility, which make them valuable in wound care. The integration of MOFs with hydrogels creates synergistic hybrid systems that combine the exceptional cargo-loading capacity and controllable degradation of MOFs with the biocompatibility and moisture-retention properties of hydrogels. This results in enhanced wound healing potential compared to the individual components. This article overviews the wound healing process and current therapeutic challenges, surveys the biomedical applications of MOFs and hydrogels individually, and presents their preparation methods. A detailed analysis of MOF-hydrogel composites (MOF-HCs) is provided including their functionality, wound-healing mechanisms, closure capabilities, and biocompatibility. This article also offers critical insights, supported by a thorough review of current research. Finally, the existing challenges and proposed future directions are highlighted, offering valuable perspectives for researchers in the field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216330"},"PeriodicalIF":20.3,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142610578","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unveiling the mysteries of hydrogen spillover phenomenon in hydrogen evolution reaction: Fundamentals, evidence and enhancement strategies","authors":"Shan Zhao ,&nbsp;Zhen-Hong Wang ,&nbsp;Jing-Yu Wang ,&nbsp;Peng-Fei Wang ,&nbsp;Zong-Lin Liu ,&nbsp;Jie Shu ,&nbsp;Ting-Feng Yi","doi":"10.1016/j.ccr.2024.216321","DOIUrl":"10.1016/j.ccr.2024.216321","url":null,"abstract":"<div><div>The phenomenon of hydrogen spillover is a dynamic behavior during catalytic reactions and has been a prominent area of research in the field of thermal catalysis. This concept has become a new focus of research in the field of hydrogen evolution reaction (HER) in recent years. The hydrogen spillover effect has a pivotal effect on modulating the active sites of catalysts and enhancing catalytic activity, which also provides a novel perspective for optimizing HER catalysts. While some advancements have been achieved in understanding the hydrogen spillover phenomenon, the existing review is deficient in a systematic overview of the mechanism of hydrogen spillover occurrence during HER and a summary of the evidence to confirm the occurrence of the hydrogen spillover phenomenon particularly. Furthermore, a comprehensive summary of the specific strategies to optimize the catalytic system using this effect is lacking. In light of the aforementioned considerations, this review aims to conduct a comprehensive summary of the fundamental mechanisms underlying the phenomenon of hydrogen spillover, with a particular focus on the evidence presented in experimental studies. Following a comprehensive examination of the underlying mechanism and supporting evidence, the discussion turns to the question of how the hydrogen spillover effect can be strategically enhanced to optimize the overall performance of HER. Finally, the opportunities and challenges facing this research area are discussed, and potential future research directions are outlined. This review not only enhances comprehension of how hydrogen spillover occurs in the HER process but also offers invaluable theoretical insight and practical strategies for the creation of new and efficient catalysts.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216321"},"PeriodicalIF":20.3,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142601612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Leveraging mechanistic insight to design hydrolytic nanozymes","authors":"Ziqi Zhang ,&nbsp;Zhen Chen ,&nbsp;Yiqing Zhang ,&nbsp;Zichang Wang ,&nbsp;Dehong Chen ,&nbsp;Jing Liu ,&nbsp;Zhiling Zhu","doi":"10.1016/j.ccr.2024.216340","DOIUrl":"10.1016/j.ccr.2024.216340","url":null,"abstract":"<div><div>Hydrolytic nanozymes have emerged as promising candidates for diverse applications across pharmaceuticals, chemicals, environmental remediation, food, and paper industries. Despite their potential, research on hydrolytic nanozymes remains significantly underdeveloped, accounting for only 14.4 % of all nanozyme studies (1256 papers out of 8737). A critical gap exists in understanding the catalytic mechanisms and design strategies of these nanozymes, hindering their theoretical advancement and practical utilization. This review aims to address this gap by systematically organizing and summarizing the catalytic mechanisms of hydrolytic nanozymes, categorized by structural composition and substrate type, along with the design approaches ranging from biomimetic strategies to the cutting-edge data-driven methods, providing theoretical insights to guide the rational design and efficient development of hydrolytic nanozymes. Furthermore, this review offers perspectives on the future prospects and challenges in the field, aiming to inspire further research and innovation in this rapidly advancing area.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216340"},"PeriodicalIF":20.3,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142601613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The roles of β-diketones and their derivatives in the design of photocatalysts","authors":"Wentao Zhang ,&nbsp;Shuangshuang Wei ,&nbsp;Guoyang Zhang ,&nbsp;Jianghua Yang ,&nbsp;Lele Peng ,&nbsp;Shujuan Zhang","doi":"10.1016/j.ccr.2024.216318","DOIUrl":"10.1016/j.ccr.2024.216318","url":null,"abstract":"<div><div>Organic ligands play pivotal roles in the synthesis and modification of photocatalysts. Small molecular diketones, exemplified by acetylacetone (acac), are a promising class of ligands. Nevertheless, a comprehensive review of their roles in photocatalysis has not yet been conducted. This gap hinders the rational design and application of photocatalysts by using diketones as functional ligands. It is therefore imperative to provide a comprehensive examination of this topic. This review critically summarizes the utilization of acac in photocatalysis from four aspects: the chemical nature and reactivity of acac, the roles of acac in the synthesis and modification of photocatalysts (especially the well-known TiO₂), its influence on the photocatalytic processes, and the existing challenges and future prospects for acac-mediated photocatalysis. By providing a critical analysis of the established applications of acac in photocatalysis, we aim to inspire further advancements in the field rooted in fundamental theoretical principles.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216318"},"PeriodicalIF":20.3,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142609821","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Design of electrocatalysts and electrodes for CO2 electroreduction to formic acid and formate","authors":"Dinh Son Tran ,&nbsp;Nhu-Nang Vu ,&nbsp;Houssam-Eddine Nemamcha ,&nbsp;Cedrik Boisvert ,&nbsp;Ulrich Legrand ,&nbsp;Arthur G. Fink ,&nbsp;Fabiola Navarro-Pardo ,&nbsp;Cao-Thang Dinh ,&nbsp;Phuong Nguyen-Tri","doi":"10.1016/j.ccr.2024.216322","DOIUrl":"10.1016/j.ccr.2024.216322","url":null,"abstract":"<div><div>Electrochemical carbon dioxide (CO₂) reduction reaction (CO₂RR) is gaining attraction as it enables the generation of highly valuable chemicals while mitigating greenhouse gas emissions. Numerous efforts have been dedicated to designing efficient catalysts that selectively reduce CO₂ into various chemicals such as formic acid/formate, carbon monoxide, methane, ethylene, and ethanol. The efficiency of the CO₂RR is evaluated through selectivity to the desired product, overpotential, current density, and stability. This work reviews emerging strategies to improve the CO₂RR performance to produce formate/formic acid by tuning catalyst and electrode structures. The catalyst-developing strategies are discussed in terms of engineering electronic and geometric structures, surface oxidation structure, and enlarging surface active area. The design of gas diffusion electrodes and reactor configuration, which are essential in enhancing the efficiency of the electrochemical system, are also mentioned. Finally, insights and perspectives are given on how to overcome the instability of catalysts and limitations of reactor designs.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216322"},"PeriodicalIF":20.3,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142599870","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Emerging metal-organic framework-based photocatalysts for solar-driven fuel production","authors":"Chunxue Li ,&nbsp;Ning-Yu Huang ,&nbsp;Yingkui Yang ,&nbsp;Qiang Xu ,&nbsp;Guangfu Liao","doi":"10.1016/j.ccr.2024.216292","DOIUrl":"10.1016/j.ccr.2024.216292","url":null,"abstract":"<div><div>Metal organic framework (MOF)-based photocatalysts for solar-driven fuel generation have seen significant advancement owing to their structural and porous controllability, high surface area, and distinctive semiconductor property. In this review, the opto-electronic characteristics of MOF-based photocatalysts are firstly introduced. After that, the fabrication strategies for MOF-based photocatalysts are illustrated. Then, some typical MOF-based photocatalysts for energy-related applications are exhibited. Lastly, this review also offers some in-depth perceptions into significant difficulties, advantageous situations, and heuristic possibilities for future improvement. There is no question that the newly developed MOF-based photocatalysts can achieve new innovations for energy-related applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216292"},"PeriodicalIF":20.3,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142598547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nanoprobes based on optical imaging techniques for detecting biomarkers in liver injury diseases","authors":"Ye Sun ,&nbsp;Jing Wang ,&nbsp;Yanyan Zhu ,&nbsp;Tingting Han ,&nbsp;Yi Liu ,&nbsp;Hai-Yan Wang","doi":"10.1016/j.ccr.2024.216303","DOIUrl":"10.1016/j.ccr.2024.216303","url":null,"abstract":"<div><div>The liver injury diseases caused by multiple factors have attracted widespread attention and good monitoring strategies are essential in the treatment process. In the past few decades, optical imaging techniques including fluorescence imaging, photoacoustic imaging and magnetic resonance imaging were gradually mastered and applied in clinical diagnosis and treatment of liver injury diseases. Such imaging techniques depend on probes generating signals in response to the critical biomarkers in liver injury diseases, and then the signals can be detected by corresponding instruments. Among them, we consider that nanoprobes with excellent aqueous solubility and biocompatibility have better application prospects. In this review, we focused on discussing the common design strategies, targeted biomarkers, detecting principles and biological applications of nanoprobes that have been developed, and we hope this review can inspire the development of nanoprobes utilized in the field of liver injury treatment.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216303"},"PeriodicalIF":20.3,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596623","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Electron-reservoir applications of ferrocenes and other late transition-metal sandwich complexes: Flow batteries, sensing, catalysis, and biomedicine","authors":"Tiansheng Wang ,&nbsp;Didier Astruc","doi":"10.1016/j.ccr.2024.216300","DOIUrl":"10.1016/j.ccr.2024.216300","url":null,"abstract":"<div><div>This review presents the applications of first-row late transition-metal sandwich complexes, including derivatives of ferrocene, FeCp₂ (Cp = η⁵-C₅H₅), and of salts of cobalticenium [CoCp₂]⁺ and mixed sandwich complexes [FeCp(η⁶-arene)]⁺ as molecular or macromolecular electron reservoirs. Forty-five years ago, the concept of electron reservoirs was proposed for the permethylated 19-electron d⁷ Fe(I) sandwich complexes, in particular [FeCp(η⁶-C₆Me₆)] and [FeCp*(η⁶-C₆Me₆)] (Cp* = C₅Me₅), because they were the electron richest neutral molecules known, given their extremely low ionization potentials, and their ability to stoichiometrically or catalytically transfer one electron to a variety of organic and inorganic substrates. These processes occurred without any breakdown of their molecular structure, so that the cationic 18-electron d⁶ structure was easily recovered. Thus, in this concept, the robustness of both redox forms of the electron-reservoir redox couple is essential. Later, the concept was extended to isolobal sandwich molecules with various numbers of methyl substituents on the ligands in both the [CoCp₂]⁺ and [FeCp(η⁶-arene)]⁺ salts in order to cover a wide range of redox potentials. It was also extended to electron hole reservoirs with the 17-electron d⁵ cations FeCp₂⁺, FeCp*₂⁺ and [FeCp*(η⁵-C₆Me₆)]²⁺. Along the time, the structural flexibility of these Fe and Co sandwich complexes, bringing about modulation of the redox potentials of the redox systems, enriched the concept and its applications. The latter are summarized here including examples of stoichiometric reactions with monometallic complexes and dendritic metalla-macromolecules, redox-flow metallocene batteries and redox sensing. Catalytic applications include redox catalysis, electrocatalysis, i.e. electron-transfer-chain (ETC) catalysis, and Fenton reaction in nanomedicine of ferrocenes, ferrocene dendrimers and metal-organic-framework (MOF)-ferrocenes, utilized in particular as ferroptosis media. Concluding remarks outline key aspects of applications and offer perspectives.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216300"},"PeriodicalIF":20.3,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596706","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Water-soluble stimuli-responsive supramolecular nanoagrochemicals based on macrocycle compounds","authors":"Ya-Hui Song ,&nbsp;Qiang Bian ,&nbsp;Fang Wang ,&nbsp;Jinpeng Liu ,&nbsp;Yi-Hang Yang ,&nbsp;Ying-Ming Zhang ,&nbsp;Yu Liu","doi":"10.1016/j.ccr.2024.216299","DOIUrl":"10.1016/j.ccr.2024.216299","url":null,"abstract":"<div><div>Agrochemicals are extensively utilized to ameliorate agricultural yield and quality, but they also negatively impact ecological cycle and human health as a consequence of indiscriminate pesticide usage and growing anthropogenic interference. To improve the efficiency and biosafety of existing agrochemicals, the dynamic and reversible nature of host–guest complexation with water-soluble macrocycles has been fully exploited in supramolecular chemistry to construct fascinating nanoassemblies with environmental stimuli-responsiveness. This review mainly focuses on (i) the performance-directed molecular recognition properties of common cavity-bearing macrocycles, including crown ethers, cyclodextrins, calixarenes, cucurbiturils, and pillararenes, toward a wide range of agroactive ingredients; (ii) the developmental updates in the emerging realm of macrocycle-based multistimuli-responsive supramolecular nanoagrochemicals, with an emphasis on their molecular basis, operation mechanism, and application toward a series of chemical (pH and redox), physical (photo and temperature), and biological (enzyme and reactive oxygen species) factors as internal and external stimuli relevant to plants and pests; and (iii) the encumbered challenges and perspectives on the translational development of these environmentally adaptive nanomaterials under realistic field conditions. In the wave of intelligentization of modern agricultural practices, we believe the stimuli-responsive supramolecular nanoagrochemicals is now spurring the impending agri-tech revolution at a global scale.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216299"},"PeriodicalIF":20.3,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596707","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Host-guest interactions in the confined spaces of metal–organic frameworks: Design principles, characterizations, and applications","authors":"Yifang Zhao ,&nbsp;Lian Wu ,&nbsp;Kun Wu ,&nbsp;Rong-Jia Wei ,&nbsp;Heng Zeng ,&nbsp;Hao Pang ,&nbsp;Weigang Lu ,&nbsp;Dan Li","doi":"10.1016/j.ccr.2024.216302","DOIUrl":"10.1016/j.ccr.2024.216302","url":null,"abstract":"<div><div>Metal–organic frameworks (MOFs) are revolutionizing porous materials with their incredible structures and functionalities that have been extensively explored in many fields. Unlike traditional porous materials, MOFs offer a unique opportunity for precise design and modification of the porosities and pore environments. Their nanoscale confined spaces with specific shapes and surface functionalities can selectively interact with certain guest molecules through host-guest interactions, unlocking enhanced performance and related mechanisms that were previously undiscovered. Through advanced experimental and theoretical techniques, the high crystallinity of MOFs allows for detailed and in-depth studies of the structure-performance relationships, leading to breakthroughs in design and optimization. This review delves into recent advancements in the construction, characterization, and host-guest applications of MOF-based systems, showcasing their design strategies for remarkable functionality, porosity, and flexibility. The latest progress in adsorption, separation, catalysis, energy storage, crystalline sponge (CS), and sensing are discussed, unraveling the endless possibilities of MOFs and their challenges.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216302"},"PeriodicalIF":20.3,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596635","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}