Coordination Chemistry Reviews最新文献

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Chemically functionalized polymers as corrosion inhibitors: Effect of solubility, adsorption and coordination bonding
IF 20.3 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-03-26 DOI: 10.1016/j.ccr.2025.216637
Saman Zehra , Ruby Aslam , Jeenat Aslam , Chandrabhan Verma , Zhitao Yan , Qihui Wang , Mohammad Mobin , Akram AlFantazi
{"title":"Chemically functionalized polymers as corrosion inhibitors: Effect of solubility, adsorption and coordination bonding","authors":"Saman Zehra ,&nbsp;Ruby Aslam ,&nbsp;Jeenat Aslam ,&nbsp;Chandrabhan Verma ,&nbsp;Zhitao Yan ,&nbsp;Qihui Wang ,&nbsp;Mohammad Mobin ,&nbsp;Akram AlFantazi","doi":"10.1016/j.ccr.2025.216637","DOIUrl":"10.1016/j.ccr.2025.216637","url":null,"abstract":"<div><div>This article explores the role of chemically functionalized polymers as effective corrosion inhibitors, emphasizing the need for functionalization to enhance their protective properties. The study investigates the functionalization process that impacts polymer characteristics such as solubility, adsorption behavior, and coordination bonding, directly influencing corrosion protection efficiency. The study reviews covalent and non-covalent functionalized polymers, examining their corrosion inhibition mechanisms through interactions with metal surfaces. The potential of polymer-based composites, including metal/metal-oxide/polymer hybrids, graphene/polymer composites, and cluster-based coordination polymers (CCPs), for corrosion control is explored. The literature survey highlights the significant advancements in these areas, mainly focusing on self-healing capabilities and sustainable materials. Moreover, MXene-polymer composites are proposed as promising candidates for efficient corrosion inhibition. The paper also discusses the challenges associated with using polymer nanocomposites in corrosion inhibition and suggests strategies to overcome these challenges, advancing the development of more effective, environmentally friendly solutions.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216637"},"PeriodicalIF":20.3,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143703227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances in metal-organic frameworks (MOFs)-based colorimetric sensors for visual detection of food freshness
IF 20.3 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-03-26 DOI: 10.1016/j.ccr.2025.216638
Weicheng Sun , Yapeng Huo , Xueying Feng , Longxuan Wei , Xiaoyang Lu , Sha Liu , Zhixian Gao
{"title":"Recent advances in metal-organic frameworks (MOFs)-based colorimetric sensors for visual detection of food freshness","authors":"Weicheng Sun ,&nbsp;Yapeng Huo ,&nbsp;Xueying Feng ,&nbsp;Longxuan Wei ,&nbsp;Xiaoyang Lu ,&nbsp;Sha Liu ,&nbsp;Zhixian Gao","doi":"10.1016/j.ccr.2025.216638","DOIUrl":"10.1016/j.ccr.2025.216638","url":null,"abstract":"<div><div>Harmful substances, such as volatile organic amines and biogenic amines released during food spoilage, pose a significant threat to food quality and safety and directly impact consumer health and well-being. Therefore, the exploration and development of efficient and reliable detection technologies for food freshness have become a crucial component in safeguarding public health and maintaining market order. Metal-organic frameworks (MOFs) are a new generation of crystalline porous materials characterized by their hole-like structures, formed through coordination bonds between metal ions or clusters and organic ligands. Due to their exceptional sensitivity, intuitive visual effects, user-friendly operation, and cost-effectiveness, MOFs-based colorimetric sensors have sparked significant advancements in visual detection of food freshness. This article systematically reviews the latest advancements in visual colorimetric sensors based on MOFs for monitoring food freshness. It provides a comprehensive analysis of their capabilities and application potential in identifying and quantifying indicators of food spoilage. Moreover, this review objectively discusses the challenges currently faced by MOFs-based visual colorimetric sensing assays, including material stability, environmental adaptability, and the scalability of practical applications. It also explores the future development pathways and vast prospects of this technology. Based on existing findings, the review provides a critical perspective for understanding the current application status of visual colorimetric sensors in monitoring food freshness, with the aim of offering insights for its future applications and research and development.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216638"},"PeriodicalIF":20.3,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143703027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Clusterization-triggered room-temperature phosphorescent synthetic polymeric materials 簇化触发室温磷光合成聚合物材料
IF 20.3 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-03-26 DOI: 10.1016/j.ccr.2025.216629
Wenya Yan , Peixuan Dong , Qiyu Zhang , Yongfeng Zhang , Ruhui Deng , Luojie Zhu , Tao Wang , Jianbing Shi , Junge Zhi , Bin Tong , Peng Sun , Zhengxu Cai , Yuping Dong
{"title":"Clusterization-triggered room-temperature phosphorescent synthetic polymeric materials","authors":"Wenya Yan ,&nbsp;Peixuan Dong ,&nbsp;Qiyu Zhang ,&nbsp;Yongfeng Zhang ,&nbsp;Ruhui Deng ,&nbsp;Luojie Zhu ,&nbsp;Tao Wang ,&nbsp;Jianbing Shi ,&nbsp;Junge Zhi ,&nbsp;Bin Tong ,&nbsp;Peng Sun ,&nbsp;Zhengxu Cai ,&nbsp;Yuping Dong","doi":"10.1016/j.ccr.2025.216629","DOIUrl":"10.1016/j.ccr.2025.216629","url":null,"abstract":"<div><div>Clusterization-triggered room-temperature phosphorescent (CTRTP) polymeric materials do not contain classical chromophores, and possess the advantages of long emission lifetime, robust mechanical properties, good processability and low biotoxicity, holding immense potential for applications across various fields, including flexible displays, organic optoelectronic devices, and in vivo imaging. In recent years, considerable progress has been made in this field, leading to an expanded variety of polymeric materials, a deeper understanding of the photo-luminescence mechanisms, and substantial improvements in the emission properties. This review provides a comprehensive overview of the research advancements in the CTRTP synthetic polymeric materials. It begins with a discussion of the photo-luminescence mechanisms, offering a detailed introduction of the variety of CTRTP synthetic polymeric materials. Next, the key strategies to construct the CTRTP polymeric materials are summarized, including introducing heteroatoms, crystallization, and ionization. This review also explores the practical applications of CTRTP polymeric materials, particularly in anti-counterfeiting and information encryption. The final section highlights the current research progress and offers perspectives on future directions for the CTRTP synthetic polymeric materials. It's highly anticipated that this review will provide guidance for the continued development of CTRTP polymeric materials.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216629"},"PeriodicalIF":20.3,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143705135","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances in nanomaterials for integrated phototherapy and immunotherapy
IF 20.3 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-03-25 DOI: 10.1016/j.ccr.2025.216608
Zhuqing Sun , Nannan Wang , Yelin Wu , Shihui Wen , Dayong Jin
{"title":"Recent advances in nanomaterials for integrated phototherapy and immunotherapy","authors":"Zhuqing Sun ,&nbsp;Nannan Wang ,&nbsp;Yelin Wu ,&nbsp;Shihui Wen ,&nbsp;Dayong Jin","doi":"10.1016/j.ccr.2025.216608","DOIUrl":"10.1016/j.ccr.2025.216608","url":null,"abstract":"<div><div>The integration of immunotherapy with phototherapy represents a synergistic approach, combining the localized effects of nanomaterial-enabled phototherapy with systemic immune activation to achieve comprehensive therapeutic outcomes. Nanomaterials enhance light-based therapies through superior photon conversion, efficient drug delivery, and co-delivery of immune adjuvants, thereby amplifying immune responses and addressing the limitations of traditional treatments. This review highlights recent advancements in the design, classification, and application of nanomaterials for integrated phototherapy and immunotherapy. Key topics include innovative nanomaterials systems, therapeutic models, and imaging techniques that improve precision and efficacy. Despite significant progress, challenges remain in optimizing nanomaterial biocompatibility, delivery efficiency, and immune modulation. Looking ahead, the development of multifunctional nanomaterials and deeper understanding of their synergistic mechanisms hold immense potential to transform precision medicine, paving the way for innovative and highly effective therapeutic strategies.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216608"},"PeriodicalIF":20.3,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143703029","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Subcellular organelle targeted tumor phototherapy
IF 20.3 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-03-25 DOI: 10.1016/j.ccr.2025.216635
Man Lu , Mingjing Huang , Jing Chen , Xingyan Xu , Shudi Liu , Wenjun Wang , Weili Si , Xin Huang , Xiaochen Dong
{"title":"Subcellular organelle targeted tumor phototherapy","authors":"Man Lu ,&nbsp;Mingjing Huang ,&nbsp;Jing Chen ,&nbsp;Xingyan Xu ,&nbsp;Shudi Liu ,&nbsp;Wenjun Wang ,&nbsp;Weili Si ,&nbsp;Xin Huang ,&nbsp;Xiaochen Dong","doi":"10.1016/j.ccr.2025.216635","DOIUrl":"10.1016/j.ccr.2025.216635","url":null,"abstract":"<div><div>Phototherapy has emerged as a promising approach for cancer treatment, attributed to its advantages of being minimally invasive, low toxicity, high efficiency, and controllability. Subcellular organelle-targeted phototherapy plays a crucial role in phototherapy by ensuring precise targeted drug delivery, reducing medication dosage, and improving therapeutic efficiency. This review focuses on recent advancements in subcellular organelle-targeted tumor phototherapy. Firstly, it introduces the structure and function of various subcellular organelles, including mitochondria, lysosomes, endoplasmic reticulum, nucleus, Golgi apparatus, and cell membrane. Then, the advances of photosensitizers/photothermal agents with subcellular organelle-targeting properties for tumor phototherapeutics are presented based on organic small molecules, metal complexes, and other nanomaterials. Specifically, these materials developed on the particular features of subcellular organelles and related mechanisms to eradicate malignancies are discussed. Lastly, the challenges of subcellular organelle-targeted phototherapy for cancer are summarized.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216635"},"PeriodicalIF":20.3,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143695330","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Insights into carbon dots and conventional semiconductors hybrids: A trendsetter in photocatalytic hydrogen generation
IF 20.3 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-03-25 DOI: 10.1016/j.ccr.2025.216646
Arun Annamalai , Sambasivam Sangaraju , Sundaravadivel Elumalai
{"title":"Insights into carbon dots and conventional semiconductors hybrids: A trendsetter in photocatalytic hydrogen generation","authors":"Arun Annamalai ,&nbsp;Sambasivam Sangaraju ,&nbsp;Sundaravadivel Elumalai","doi":"10.1016/j.ccr.2025.216646","DOIUrl":"10.1016/j.ccr.2025.216646","url":null,"abstract":"<div><div>Sustainable conversion and storage of energy will create demand in the future. There is ample research on constructing composites with conventional semiconductor materials to overcome their common challenges, which are currently in progress to empower the water-splitting performance by the photocatalysis process. It is better to modify the existing low-cost semiconductor photocatalyst instead of finding a newer, effective photocatalytic material for hydrogen production. CDs (Carbon dots) are shining stars in material research; because of their unlimited exciting properties, they were engrossed in the photocatalysis area to expand the efficiency and stability of conventional photocatalytic material. Quite a lot of research reports support existing CDs that grandly improve the photocatalytic water-splitting character. Modifying conventional semiconductor-based photocatalysts with CDs to improve the photocatalytic water splitting to generate hydrogen was less reported in the photocatalytic research area. The present summarised research report involves a broad view of the multiple roles of CDs and how it effectively improves the conventional photocatalytic material towards photocatalytic water splitting.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216646"},"PeriodicalIF":20.3,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143703028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Catalytic oxidation of volatile organic compounds: A review of recent advances in supported and non-supported catalysts
IF 20.3 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-03-24 DOI: 10.1016/j.ccr.2025.216617
Ahmed Ismail , Muhammad Zahid , Bilal Ahmad , Fazal Raziq , Syed ul Hasnain Bakhtiar , Sher Ali , Adnan Khan , Nauman Ali , Xiaoqiang Wu , Sharafat Ali , Weidong He , Jiabao Yi , Liang Qiao
{"title":"Catalytic oxidation of volatile organic compounds: A review of recent advances in supported and non-supported catalysts","authors":"Ahmed Ismail ,&nbsp;Muhammad Zahid ,&nbsp;Bilal Ahmad ,&nbsp;Fazal Raziq ,&nbsp;Syed ul Hasnain Bakhtiar ,&nbsp;Sher Ali ,&nbsp;Adnan Khan ,&nbsp;Nauman Ali ,&nbsp;Xiaoqiang Wu ,&nbsp;Sharafat Ali ,&nbsp;Weidong He ,&nbsp;Jiabao Yi ,&nbsp;Liang Qiao","doi":"10.1016/j.ccr.2025.216617","DOIUrl":"10.1016/j.ccr.2025.216617","url":null,"abstract":"<div><div>Volatile organic compounds (VOCs) are air pollutants that have garnered considerable consideration because of their detrimental effects on both public health and the environment. Catalytic oxidation is extensively recognized as an emerging technology for VOC elimination, as it produces no secondary pollutants and requires low energy input. This review systematically examines recent advancements in supported noble metal catalysts (SNM), supported transition metal catalysts (STM) and non-supported transition metal oxides (NSTM) for VOC oxidation. First, various types of VOCs and their emission sources are discussed. Next, recent progress in the catalytic oxidation of different VOCs using SNM, STM and NSTM is reviewed. The oxidation mechanisms of VOCs are then comprehensively summarized. Additionally, the effects of reaction conditions, including the presence of H<sub>2</sub>O, CO<sub>2</sub>, SO<sub>2</sub>, Cl species as well as reactant composition, concentration, and space velocity, on catalyst performance, deactivation, and regeneration approaches are explored. Finally, the key scientific obstacles and future perspectives in this field are addressed. This review provides as a solid experimental and theoretical basis for the development and design of stable SNM, STM and NSTM catalysts for VOC oxidation in the years to come.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216617"},"PeriodicalIF":20.3,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143678031","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dendritic metallodrugs: An overview of their anticancer properties
IF 20.3 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-03-22 DOI: 10.1016/j.ccr.2025.216606
Anne-Marie Caminade , Vania Bernardes-Génisson , Aurélien Hameau , Régis Laurent , Valérie Maraval , Manuel S. Rodriguez , Cédric-Olivier Turrin
{"title":"Dendritic metallodrugs: An overview of their anticancer properties","authors":"Anne-Marie Caminade ,&nbsp;Vania Bernardes-Génisson ,&nbsp;Aurélien Hameau ,&nbsp;Régis Laurent ,&nbsp;Valérie Maraval ,&nbsp;Manuel S. Rodriguez ,&nbsp;Cédric-Olivier Turrin","doi":"10.1016/j.ccr.2025.216606","DOIUrl":"10.1016/j.ccr.2025.216606","url":null,"abstract":"<div><div>Dendrimers are highly branched macromolecules synthesized in a stepwise manner. They can be easily functionalized on their surface to fulfill the desired properties, and to entrap diverse guests inside their structure. This review displays the different types of dendritic metal complexes which have been tested as anticancer drugs, at least on cells, and sometimes <em>in vivo</em>. The metal is located in most cases on the surface of the dendritic structure, but it can also be located inside the structure, in the branches or at the core. This review is mainly organized according to the type of dendrimers, in particular PAMAM (poly(amidoamide)), PPI (poly(propyleneimine)), PPH (poly(phosphorhydrazone)), CSi (poly(carbosilane)), and poly(arylether). The dendrimer can be a metal drug by itself, or it can function as a prodrug carrying and releasing the metal drug complexed at the branches. The IC<sub>50</sub> values (the drug concentration necessary to kill 50 % of the cells) are given in most cases, to assess the efficiency of the dendritic drugs. The use of dendritic complexes for photodynamic therapy (PDT) against cancers is also reviewed.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216606"},"PeriodicalIF":20.3,"publicationDate":"2025-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143675468","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, characterizations, properties, modifications and applications of zero-dimensional monoelemental selenium nanomaterials
IF 20.3 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-03-21 DOI: 10.1016/j.ccr.2025.216626
Rijun Gui , Hui Jin
{"title":"Synthesis, characterizations, properties, modifications and applications of zero-dimensional monoelemental selenium nanomaterials","authors":"Rijun Gui ,&nbsp;Hui Jin","doi":"10.1016/j.ccr.2025.216626","DOIUrl":"10.1016/j.ccr.2025.216626","url":null,"abstract":"<div><div>The past two decades have witnessed a rapid development in the field of zero-dimensional (0D) monoelemental selenium nanomaterials (Me-SeNMs). Especially, 0D Me-SeNMs exhibit multiple properties and functionalized modifications, which endow them with multifunctional and effective applications in a wide range of currently promising fields. To promote a further development in this significant topic, thereby this present work has comprehensively reviewed recent progress on 0D Me-SeNMs. Firstly, various experimental synthesis methods are properly classified and introduced. Then, characterization and essential properties are emphatically analyzed and summarized. After that, different strategies for functional modifications are wholly compared and commented. Finally, versatile potential applications are methodically highlighted and discussed. These review sections are in well combination of representative and state-of-the-art related studies about 0D Me-SeNMs and derivatives. Meanwhile, the current status, probable challenges and forthcoming prospects are rationally elaborated and expected. According to opportune, comprehensive and in-depth features, this review will facilitate further exploration of monoelemental and functionalized nanomaterials, focusing on efficient synthesis and modifications toward high-performance practical applications, especially in important biomedicine, therapeutics, opto-electronics, energy storage and conversion, catalysis, sensors, nutrition, environment repairing, etc.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216626"},"PeriodicalIF":20.3,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143665929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Harnessing interfacial engineering in covalent organic frameworks for lithium metal batteries
IF 20.3 1区 化学
Coordination Chemistry Reviews Pub Date : 2025-03-20 DOI: 10.1016/j.ccr.2025.216604
Xiao-Meng Lu , Junaid Aslam , Muhammad Ahsan Waseem , Yifan Zhang , Weiwei Sun , Yong Wang
{"title":"Harnessing interfacial engineering in covalent organic frameworks for lithium metal batteries","authors":"Xiao-Meng Lu ,&nbsp;Junaid Aslam ,&nbsp;Muhammad Ahsan Waseem ,&nbsp;Yifan Zhang ,&nbsp;Weiwei Sun ,&nbsp;Yong Wang","doi":"10.1016/j.ccr.2025.216604","DOIUrl":"10.1016/j.ccr.2025.216604","url":null,"abstract":"<div><div>The application of lithium metal anodes (LMAs) in batteries promises high energy density but faces challenges due to uncontrollable Li dendrite formation and instability of the solid electrolyte interphase (SEI). The architectural features and diversity of fabrication methods of covalent organic frameworks (COFs), such as well-ordered pores, functionalities tunability, and remarkable stability, endow COF-based interfacial layers with homogenizing ion flux and accelerating ion transport, have demonstrated to be a straightforward and efficient way to tackle LMA problems. This review thoroughly reviews the general structure and linking modes of COFs, the Li<sup>+</sup> interfacial chemistry and associated characteristics as well as the prominent progress occurring from 2019 to 2024. Meanwhile, this review attempts to propose some tactics anticipated in the future development of COFs for LMA applications in terms of large-scale manufacturing, improvement of battery performance, and exploration of the mechanism. It is widely believed that optimizing the synergistic effects between the building blocks of COFs will offer valuable insights and guidance for both researchers and practitioners working in this area.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"535 ","pages":"Article 216604"},"PeriodicalIF":20.3,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143661117","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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