Coordination Chemistry Reviews最新文献

{"title":"Harnessing tetrahedral diversity: The path to superior diamond-like IR NLO crystals","authors":"Ailijiang Abudurusuli ,&nbsp;Linan Wang ,&nbsp;Junben Huang ,&nbsp;Xueling Hou ,&nbsp;Miriding Mutailipu ,&nbsp;Shilie Pan ,&nbsp;Junjie Li","doi":"10.1016/j.ccr.2026.217642","DOIUrl":"10.1016/j.ccr.2026.217642","url":null,"abstract":"<div><div>Diamond-like (DL) compounds constitute a pivotal class of materials for advanced optoelectronic applications, particularly as infrared (IR) nonlinear optical (NLO) crystals, owing to their intrinsically high proportion of non-centrosymmetric structures and oriented tetrahedral units that synergistically enhance second-order NLO responses. Over the past decades, more than 300 DL compounds have been rationally designed and synthesized, with over 90 demonstrating significant NLO activity. However, performance-driven DL structural design remains highly challenging in this field. To advance the targeted design of high-performance IR NLO materials, this review provides a systematic and updated summary of DL IR NLO compounds, with a particular emphasis on emerging and promising alkaline earth metal tetrahedral and mixed anionic NLO-active tetrahedral units, chemical and structural diversity, structural evolution, and property modifications in DL chalcogenide, pnictide, and halide systems. Finally, future opportunities and challenges in DL functional material discovery are discussed, with the aim of providing a clear chemical perspective to stimulate the discovery of new DL IR NLO materials with desired properties.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217642"},"PeriodicalIF":23.5,"publicationDate":"2026-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146098424","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Single- and multi-metal engineered, functionalized hybrid biochars for heavy metal adsorption: synthesis, structure-function relationships, and coordination mechanisms","authors":"Dharma Raj Kandel ,&nbsp;Prem Gaudel ,&nbsp;Milan Babu Poudel ,&nbsp;Wooseop Yun ,&nbsp;Jaewoo Lee","doi":"10.1016/j.ccr.2025.217521","DOIUrl":"10.1016/j.ccr.2025.217521","url":null,"abstract":"<div><div>Heavy metals pose a serious threat to global water systems due to their toxicity, persistence, and strong bioaccumulative potential in ecosystems and humans. Among various remediation strategies, adsorption is regarded one of the most effective and versatile approaches. Biochar (BC) has gained significant attention as a sustainable and low-cost adsorbent owing to its simple preparation, tunable porosity, high surface area, and intrinsic functional groups. However, pristine BC often exhibits limited adsorption efficiency toward diverse metal ions, necessitating targeted engineering and surface modification. To address this, two modification approaches, namely metal-based nano-architected BC (NA-BC) and surface-functionalized BC (f-BC), have emerged as leading platforms. NA-BCs are synthesized from either single metals (<em>e</em>.<em>g</em>., oxides, hydroxides, and metal-organic frameworks) or multi-metal systems (<em>e</em>.<em>g</em>., layered double hydroxides, spinel oxides), with magnesium, manganese, calcium, aluminum, zinc, and iron commonly used as precursors for their low toxicity, cost-effectiveness, and chemical versatility. Meanwhile, surface functionalization introduces hydroxyl, amino, sulfonic, thiol, carboxylic, and phosphate groups <em>via</em> inorganic or organic modifications, yielding f-BCs and f-NA-BCs with tunable porosity, enriched surface functionalities, and enhanced stability. These features collectively improve adsorption capacity, selectivity, and reusability. The heavy metal removal by BC composites involves physisorption and chemisorption, including pore diffusion, electrostatic attraction, chelation/coordination, ion exchange, precipitation, and redox reactions, which can be validated through XRD, FTIR, XPS, and DFT analyses. Looking ahead, advancing scalability, environmental safety, and machine-learning-guided material design will be crucial for developing next-generation engineered BCs capable of practical implementation in fixed-bed filters in disaster-affected zones and industrial wastewater treatment.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217521"},"PeriodicalIF":23.5,"publicationDate":"2026-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146072739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A review of interfacial engineering and performance modulation of hollow/porous nanostructures synthesized via the Kirkendall effect for synergistic remediation of water co-contaminated by heavy metals and organics","authors":"Xiaofei Li ,&nbsp;Rui Xu ,&nbsp;Guangfei Qu ,&nbsp;Dehui Kong ,&nbsp;Chenyang Yin ,&nbsp;Yingying Cai ,&nbsp;Minhua Cheng ,&nbsp;Yaoze Wang ,&nbsp;Linjin Li ,&nbsp;Ping Ning","doi":"10.1016/j.ccr.2026.217633","DOIUrl":"10.1016/j.ccr.2026.217633","url":null,"abstract":"<div><div>The synergistic remediation of heavy metal-organic compound pollution has emerged as a major challenge in environmental restoration. Traditional techniques often suffer from low efficiency and secondary pollution risks due to complex interactions between pollutants. This review systematically summarized recent advances in leveraging the Kirkendall effect for the design of environmental functional materials. It specifically elucidated the physical mechanism by which this effect induces the formation of hollow/porous structures through the regulation of non-equilibrium diffusion kinetics in heterogeneous components, highlighting its unique advantages for synergistic pollutant removal. Researches demonstrated that Kirkendall effect derived functional materials possessed high specific surface areas, tunable pore size distributions, and abundant active sites. These properties enabled the simultaneous efficient adsorption-catalytic reduction of heavy metal ions and the deep degradation of organic pollutants. Further optimization of the material's electronic structure and mass transfer behavior, achievable through surface functionalization (e.g., phosphorylation, amination) and heterojunction interface engineering, significantly enhanced pollutant removal efficiency and structural stability within complex environmental matrices. However, the practical application of this technology still faced critical challenges, including complex synthesis procedures, insufficient long-term stability, and an incomplete understanding of synergistic removal mechanisms. Future efforts should focus on developing green, scalable synthesis strategies, providing an in-depth elucidation of interfacial reaction mechanisms under multifactor coupling, and advancing engineering scale validation. These endeavors are crucial for providing the theoretical foundation and technical support necessary for the innovative development of next generation environmental remediation technologies.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217633"},"PeriodicalIF":23.5,"publicationDate":"2026-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146072753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Green synthesis and biomedical applications of CuO/MgO nanocomposite: Antibacterial, antioxidant, and antidiabetic efficacies","authors":"S. Priyadharshini ,&nbsp;M. Karnan ,&nbsp;M. Ayyanar ,&nbsp;C. Jenipher ,&nbsp;Arun Thirumurugan ,&nbsp;N. Chidhambaram","doi":"10.1016/j.ccr.2026.217637","DOIUrl":"10.1016/j.ccr.2026.217637","url":null,"abstract":"<div><div>Oxidative stress and its associated complications pose serious threats to human health, demonstrating the pressing need for effective redox-active materials. This study presents the biogenic synthesis of a redox-active Copper oxide/Magnesium oxide (CuO/MgO) nanocomposite using <em>Citrus limonium</em> extract and evaluates its antibacterial, antioxidant, and antidiabetic activities, along with CuO nanoparticles for comparison. X-ray diffraction (XRD) analysis divulges the interwoven CuO and MgO phase in a single matrix with a crystallite size of 44 nm. Fourier transform infrared (FTIR) spectra expose the vibrational bands at 864, 678, and 570 cm⁻¹, corresponding to Cu<img>O, Mg<img>O, and Cu–O–Mg. Optical analysis reveals a bandgap energy of 1.47 eV for the CuO/MgO composite, higher than 1.29 eV observed for CuO nanoparticles, indicating the improved visible-light absorption. Morphological examination reveals irregular aggregates with porous surface texture of the CuO/MgO composite. X-ray photoelectron spectroscopy (XPS) analysis substantiates the Cu²⁺, Mg²⁺, and O²⁻ oxidation states of rudiments in the nanocomposite. Biologically, the CuO/MgO nanocomposite exhibits potential antibacterial activity against <em>S. epidermidis</em> and <em>E. coli</em>, with inhibition zones of 27.4 ± 0.15 mm and 25.2 ± 0.1 mm, respectively, and shows enhanced antioxidant activity with IC₅₀ values of 140.72 ± 0.6 μg/mL. Furthermore, it demonstrates stronger inhibition of α-amylase and α-glucosidase enzymes, 79.8% and 86.1%, respectively, compared to CuO nanoparticles. Overall, this study confirms that the CuO/MgO nanocomposite, synthesized via a green approach, exhibits enhanced structural, optical, and biological properties, making it a promising candidate for biomedical applications targeting oxidative stress-related disorders.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217637"},"PeriodicalIF":23.5,"publicationDate":"2026-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146071869","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Thermocatalytic CO2 cycloaddition with epoxides by d-block metal complexes: Mechanistic insights, ligand design, and catalytic trends","authors":"Shahzad Rasheed ,&nbsp;Shezma Shakeel Ahmed ,&nbsp;Sahar Sadiq ,&nbsp;Yong Yang ,&nbsp;Ghayoor Abbas Chotana ,&nbsp;Qandeel Almas","doi":"10.1016/j.ccr.2026.217640","DOIUrl":"10.1016/j.ccr.2026.217640","url":null,"abstract":"<div><div>The rising concentration of CO₂ in the atmosphere has intensified efforts to convert it into value-added chemicals. Among various strategies, the cycloaddition of CO₂ with epoxides to produce cyclic carbonates represents an atom-efficient and industrially relevant transformation. This review provides a mechanism-anchored survey of thermocatalytic CO₂ activation by d-block metal complexes, focusing on developments over the past fifteen years. Particular attention is paid to how oxidation state, ligand architecture, and/or secondary coordination sphere affect activity and selectivity. Both terminal and internal epoxides are evaluated to highlight performance gaps and design priorities. Key ligand families, including salen and salophen scaffolds, Schiff bases, porphyrins, and N-heterocyclic carbenes (NHCs), have enabled significant advances, with electronic tuning and steric design improving reactivity under mild conditions (≤100 °C, ≤5 bar CO₂). Bimetallic and multinuclear complexes are highlighted for their synergistic behavior, which impacts turnover numbers (TON) and turnover frequencies (TOF) while broadening substrate scope. Mechanistic insights are evaluated to identify rate-determining steps and to guide rational catalyst design. The review also benchmarks representative systems across the d-block, identifying state-of-the-art examples as models for future development. Persistent challenges, including reliance on harsh conditions (&gt;120 °C, &gt;10 bar CO₂), low enantioselectivity, limited activity with internal epoxides, and catalyst recyclability, are discussed alongside emerging directions such as secondary-sphere engineering, halide-free nucleophiles, and integration with CO₂ capture. Together, these perspectives outline pathways toward efficient and industrially viable d-block catalysts for CO₂ utilization.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217640"},"PeriodicalIF":23.5,"publicationDate":"2026-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146076410","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Well-defined group 12 metal complexes for CO2 functionalisation","authors":"Geetika Gupta ,&nbsp;Sandip Munshi ,&nbsp;Samuel Dagorne","doi":"10.1016/j.ccr.2026.217636","DOIUrl":"10.1016/j.ccr.2026.217636","url":null,"abstract":"<div><div>The present contribution comprehensively reviews well-defined group 12 metal complexes that react with CO₂, an area primarily dominated by Zn(II) complexes. Discrete Zn(II) complexes have received significant attention for both stoichiometric and catalytic CO₂ functionalisation over the past 15 years, although initial stoichiometric studies in this area date back to the 1980s. Catalytic Zn-based CO₂ functionalisation, most notably including hydrosilylation/boration catalysis and cyclic carbonates formation from CO₂ and epoxides, has recently been extensively studied. Very recent developments on the use of Zn-based systems for electro- and photocatalytic CO₂ reduction catalysis are also noteworthy. Besides its chronological importance, stoichiometric CO₂ fixation by various Zn species remains an attractive research line, for instance, to better understand the structure and function of Zn-containing enzymes such as carbonic anhydrase. The diverse aspects of Zn-based CO₂ functionalisation, along with the associated Zn complexes, are thus discussed herein. Finally, the few Cd(II) and Hg(II) complexes known to react with CO₂ are reviewed.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217636"},"PeriodicalIF":23.5,"publicationDate":"2026-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146072746","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Programmable Zn-based nanozymes","authors":"Xingtan Zhu ,&nbsp;Yanguo Guo ,&nbsp;Tiedong Sun","doi":"10.1016/j.ccr.2026.217630","DOIUrl":"10.1016/j.ccr.2026.217630","url":null,"abstract":"<div><div>Programmable nanocatalytic systems represent an emerging frontier that integrates nanotechnology, catalytic science, and stimuli-responsive materials to achieve precise control over catalytic behaviors through the synergistic interplay of external stimuli and internal modular architectures. Among various nanozymes, Zn-based nanozymes have recently gained significant research attention owing to their excellent biocompatibility, low toxicity, and highly tunable catalytic properties. This review presents a survey of programmable nanocatalytic systems driven by Zn-based nanozymes, covering recent advances in synthesis strategies, modular design principles, and mechanisms for precise catalytic regulation. It also explores their diverse applications across biomedical, environmental, and energy-related fields. Furthermore, the review provides a critical discussion on prevailing challenges and future research directions, spanning from fundamental mechanistic studies to the rational design of efficient, stable, and translation-ready systems. By consolidating current knowledge and highlighting pathways for innovation, this work aims to serve as a foundational reference for accelerating the development and practical deployment of Zn-based nanozyme technologies.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217630"},"PeriodicalIF":23.5,"publicationDate":"2026-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146071865","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Graphitic carbon nitride nano-sheets and their composites for next generation emerging electrochemical devices: Fundamentals, material modifications and architectural design","authors":"Valentine Chikaodili Anadebe ,&nbsp;Collince Omondi Awere ,&nbsp;Abhinay Thakur ,&nbsp;Vinoth Selvaraj ,&nbsp;Tolulope Oluokun ,&nbsp;Bakang M. Mothudi ,&nbsp;Bhekie B. Mamba ,&nbsp;Eno E. Ebenso","doi":"10.1016/j.ccr.2026.217658","DOIUrl":"10.1016/j.ccr.2026.217658","url":null,"abstract":"<div><div>Graphitic carbon nitride (g-C₃N₄) is a versatile 2D polymeric material characterized by distinctive physicochemical features, including abundant nitrogen functionality, tunable structure, excellent thermal and chemical stability. In this review, the cutting edge progress of g-C₃N₄ and its composites for next generation elelctrochemical devices were comprehensively summarized, including material modification strategies, such as elemental doping, defect engineering, heterostructure formation, and nanocomposite fabrication, alongside architectural design approaches, such as hierarchical frameworks, porous assemblies, and hybrid nanostructures. In contrast to earlier studies, it bridges the knowledge gap between laboratory-scale synthesis and practical application by highlighting both fundamental problems and workable answers. By correlating structural, electronic, and interfacial features with electrochemical performance, we provide a cohesive structure–property–function map that bridges fundamental understanding and practical device implementation. Furthermore, a strong link between device-level performance and nanoscale design principles is established by considering hybrid nanoscale assemblies, porous frameworks, and hierarchical designs. Although a more thorough integration of theoretical predictions with experimentally discovered differences would further enhance its scientific rigor, the work also leverages computational insights. Finally, this review provides the critical gaps in scalability, stability, and interfacial engineering, and proposes strategic directions for future research, highlighting the potential of g-C₃N₄-based systems to advance high-performance electrochemical technologies.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217658"},"PeriodicalIF":23.5,"publicationDate":"2026-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185478","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Donor-acceptor type metal-organic frameworks: Synthesis, unique advantages, and applications","authors":"Hong-Guang Jin ,&nbsp;Yong-Tao Liu ,&nbsp;Peng-Cheng Zhao ,&nbsp;Huapeng Sun","doi":"10.1016/j.ccr.2026.217631","DOIUrl":"10.1016/j.ccr.2026.217631","url":null,"abstract":"<div><div>Metal-organic frameworks (MOFs) have become one of the star materials in diverse fields benefiting from their obvious advantages of tailorable topology structures, adjustable pore sizes, and abundant active sites. However, the intrinsic charge and energy transfer (CT and EnT) efficiencies of MOFs are still limited due to the lack of specific CT and EnT pathways that leads to inevitable charge recombination and energy loss. In recent years, to tackle this issue, the donor-acceptor (D-A) type MOFs with integrated electron/energy donor and acceptor units wherein extended carrier lifetime could be achieved, have made great progress. In this review, the synthetic strategies of D-A type MOFs are first outlined. Then the unique advantages of D-A type MOFs including photo- and electroconductivity are discussed. Subsequently, the applications of D-A type MOFs in luminophores, fluorescent sensors, photocatalysis, photothermal conversion, magnetism, and X-ray detection and imaging are systematically summarized. Finally, the challenges and prospects on the development of D-A MOFs are presented. This review aims to inspire more incisive research in the design and development of D-A MOFs with improved performance for multifunctional applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217631"},"PeriodicalIF":23.5,"publicationDate":"2026-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146072738","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nanotechnology for single-cell bacterial activity monitoring","authors":"Fangbin Xiao ,&nbsp;Tao Yang ,&nbsp;Miral Javed ,&nbsp;Chaoyong Yang ,&nbsp;Xingyu Lin","doi":"10.1016/j.ccr.2026.217645","DOIUrl":"10.1016/j.ccr.2026.217645","url":null,"abstract":"<div><div>Bacterial infections are one of the main threats to human health, and the rapid, highly sensitive monitoring of bacteria is crucial for ensuring public health safety. However, most reviews have focused on discussing the progress of bacterial identification and sensing technologies, overlooking the significance of monitoring bacterial activity. In recent years, advanced nanotechnologies based on optical, electrochemical, and spatiotemporal resolved imaging have rapidly developed and been applied to the monitoring of bacterial activity at the single-cell resolution, providing powerful tools for high-resolution bacterial analysis. Here, the progress and application of advanced nanotechnologies for monitoring bacterial activity at the single-cell resolution are comprehensively reviewed. We comprehensively discuss the behaviors of single bacterial activity (including nanovibration, motion, bioelectricity, growth, and metabolism), coordination engineering strategies for improving the sensing performance of nanomaterials, and the latest developments in advanced nanotechnologies for monitoring various physiological activities of bacteria, introducing their principles, performance, and applicability. Finally, the challenges and prospects for the application of advanced nanotechnologies in single-cell bacterial activity monitoring are proposed to guide the design and development of novel single-cell bacterial monitoring platforms.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217645"},"PeriodicalIF":23.5,"publicationDate":"2026-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146076411","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}