Coordination Chemistry Reviews最新文献

{"title":"Porphyrins-based multidimensional nanomaterials: Structural design, modification and applications","authors":"Changyu Hu ,&nbsp;Dong Jiang ,&nbsp;Yin Zhang ,&nbsp;Hu Gao ,&nbsp;Yihan Zeng ,&nbsp;Nithima Khaorapapong ,&nbsp;Zhipeng Liu ,&nbsp;Yusuke Yamauchi ,&nbsp;Mingzhu Pan","doi":"10.1016/j.ccr.2024.216264","DOIUrl":"10.1016/j.ccr.2024.216264","url":null,"abstract":"<div><div>As global demand for renewable energy consumption and environmental treatment intensifies, the development of innovative technologies and green materials for catalytic transformation is increasingly critical. Porphyrins, often referred to as the ‘pigments of life’, are notable for their macrocyclic π-conjugated electronic structures and distinctive light excitation/absorption properties. They have been widely used for oxygen transport, photosynthesis, as well as serving enzymatic catalytic centers in biological processes. However, the inherent strong π–π interactions among rigid porphyrin molecules lead to disordered stacking and self-aggregation, diminishing the accessibility of active sites and the efficiency of charge transfer during practical applications. Hybrid porphyrins with multidimensional nano-substrates, like graphene, metal oxide, et al. is a promising strategy that can not only mitigate self-aggregation of porphyrins but also can achieve a synergetic enhancement effect. Selecting suitable substrates and effective bonding interactions between the porphyrins and substrates are critical for achieving the desired performance in specific applications. This review comprehensively summarizes recent advances in porphyrin-based multidimensional nanomaterials (PMNs), focusing on the influence of nanoscale effects, performance enhancements, and their applications in energy conversion, storage, biomedicine, and environmental protection. It delves deeply into the role of interaction forces in boosting interfacial electron transfer for superior catalytic transformations. Additionally, it critically examines the correlations between the high loading and dispersion of porphyrin molecules, emphasizing strategies, structural design, nanoscale effects, and interfacial interactions. Notably, the discussion extends to the mechanistic links between the structure, properties, and applications of PMNs. The review concludes by addressing the critical challenges and future directions in this field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216264"},"PeriodicalIF":20.3,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142439954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sensitized triplet-triplet annihilation-based photon upconversion: Assembly strategy and key consideration for sustainable energy and biomedical applications","authors":"Prashanth Venkatesan ,&nbsp;Preeti Pal ,&nbsp;Siew Suan Ng ,&nbsp;Jui-Yen Lin ,&nbsp;Ruey-An Doong","doi":"10.1016/j.ccr.2024.216266","DOIUrl":"10.1016/j.ccr.2024.216266","url":null,"abstract":"<div><div>Sensitized Triplet-triplet annihilation (sTTA) photon upconversion (UC) represents a cutting-edge technology with far-reaching implications in both sustainable energy and biomedical realms. By capitalizing on the unique properties of excited triplet states, sTTA-UC enables the conversion of low-energy photons into higher-energy counterparts, offering promising solutions for efficient solar energy utilization and transformative biomedical applications. This review offers a comprehensive exploration of sTTA-UC, delving into its fundamental principles, assembly strategies, and key considerations for applications in sustainable energy and biomedicine. Various materials, including silica, clay, polymers, gels, metal-organic frameworks (MOFs), and covalent organic frameworks (COFs), play integral roles in enhancing sTTA efficiency and overcoming challenges such as oxygen quenching. Additionally, the review surveys the diverse applications of sTTA-UC, in photocatalysis, solar energy conversion, biosensing, bioimaging, and therapeutic interventions. These applications underscore the versatility and potential of sTTA-UC across multifaceted domains, promising significant advancements in various scientific and technological fields. Looking towards the future, the review outlines key areas for further exploration and development in sTTA-UC research. Priorities include optimizing materials, enhancing stability, and exploring innovative integration approaches to fully harness the capabilities of sTTA-UC technology. By elucidating the opportunities and challenges inherent in sTTA-UC, this review seeks to inspire researchers to propel the field forward, driving innovation and sustainability in both energy and biomedical sectors.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216266"},"PeriodicalIF":20.3,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142431784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Organic-inorganic hybrid materials for catalytic transfer hydrogenation of biomass-derived carbonyl-containing compounds","authors":"Mei Wu ,&nbsp;Li Bai ,&nbsp;Fengjuan Deng ,&nbsp;Jian He ,&nbsp;Ke Song ,&nbsp;Hu Li","doi":"10.1016/j.ccr.2024.216259","DOIUrl":"10.1016/j.ccr.2024.216259","url":null,"abstract":"<div><div>Upgrading biomass-derived platform molecules into valuable chemicals and biofuels is critical in bio-refinery to establish bio-based sustainable chemical processes. Catalytic transfer hydrogenation represents a fascinating strategy for the reductive upgradation of bio-based oxygenated compounds owing to bypassing the potential security risks and tedious safety precautions associated with using flammable and explosive pressurized H₂. Organic-inorganic hybrid materials (OIHMs), bearing the merits of strong Lewis acid-base ability, high specific-surface-area and pore size, tunable structure/properties and easy preparation, have been confirmed to be promising catalysts for transfer hydrogenation. In this contribution, an overview of OIHMs in transfer hydrogenation of bio-based oxygenated compounds is presented, which mainly involves diverse organic ligands with oxygen-rich groups like −OH, −COOH, −PO₃H₂, and − SO₃H for constructing OIHMs. The corresponding characterization means for clarifying the structures/properties of OIHMs, structure-reactivity relationships, reaction pathways and/or mechanisms together with catalyst durability are elucidated. In addition, the general challenges and future research on the applications of OIHMs in transfer hydrogenation are also discussed. Expectedly, this review can provide an instructive viewpoint for the rational design and practical application of OIHMs in reductive upgrading of bio-based oxygenated compounds via hydrogen transfer processes.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216259"},"PeriodicalIF":20.3,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142434170","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Driving sustainable energy: The role of polyoxometalates (POMs) in photoelectrochemical hydrogen production","authors":"Shahzad Ameen ,&nbsp;Aleena Tahir ,&nbsp;Tanveer ul Haq ,&nbsp;Ammar Ahmed Khan ,&nbsp;Mira Tul Zubaida Butt ,&nbsp;Irshad Hussain ,&nbsp;Syed Zajif Hussain ,&nbsp;Habib ur Rehman","doi":"10.1016/j.ccr.2024.216265","DOIUrl":"10.1016/j.ccr.2024.216265","url":null,"abstract":"<div><div>This review elucidates the pivotal role of polyoxometalates (POMs) in photoelectrochemical (PEC) water splitting, an emerging field with profound implications for sustainable hydrogen production. POMs, characterized by their versatile metal oxide clusters, exhibit remarkable efficacy as co-catalysts, enhancing the efficiency and performance of PEC systems. Through precise modulation of charge separation dynamics and promotion of efficient charge transfer kinetics at the semiconductor-electrolyte interface, POMs significantly augment the overall efficiency of PEC devices. Their inherent attributes, including broad-spectrum light absorption and exceptional chemical stability, underscore their suitability for solar-driven electrolysis, offering a viable pathway towards sustainable hydrogen generation. This review underscores the strategic importance of POMs in optimizing the functionality of key semiconductors employed in PEC, such as BiVO₄, CdS, Si, Fe₂O₃, and TiO₂, thereby advancing the frontiers of renewable energy conversion technologies. Additionally, the exploration of innovative strategies for enhancing POM-based photoelectrodes, encompassing tailored surface modifications and synergistic tandem cell configurations, underscores the indispensable role of POMs in catalyzing the transition towards efficient and scalable hydrogen production methodologies.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216265"},"PeriodicalIF":20.3,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142431785","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Metal-nitrogen coordinated single atomic photocatalysts for solar energy conversion","authors":"Yiqiao Wang ,&nbsp;Liling Liao ,&nbsp;Gangqiang Zhu ,&nbsp;Weiqiang Xie ,&nbsp;Qian Zhou ,&nbsp;Fang Yu ,&nbsp;Hongpeng Zhou ,&nbsp;Haiqing Zhou","doi":"10.1016/j.ccr.2024.216254","DOIUrl":"10.1016/j.ccr.2024.216254","url":null,"abstract":"<div><div>The utilization of solar energy to synthesize fuels offers a promising and sustainable solution for energy storage, but inefficient utilization of the solar spectrum and inadequate charge separation currently hinder its commercial viability. Designing and developing efficient photocatalytic materials are fundamental to achieve high energy conversion efficiency. Single atom catalysts (SACs), with well-defined single atoms (SAs) as active sites, have demonstrated excellent intrinsic activity, high atomic utilization efficiency, and a well-understood structure-activity relationship. These catalysts are widely applied in photocatalytic H₂ evolution, photoreduction of CO₂, photofixation of N₂ and photocatalytic H₂O₂ production. Importantly, compared to other elements, the unpaired electrons of nitrogen atoms are more readily bonded with metal atoms and subsequently form M-N based SACs. In this review, we will present a systematical overview of the synthetic approaches of M-N based SACs in photocatalysis and also discusses the effect of SACs modifications on light responsiveness, carrier transfer dynamics and surface reaction efficiency in photocatalytic systems. Then, we propose the key principles of SACs design and photocatalytic applications based on recent advancements. Finally, we discuss the major challenges and potential opportunities that lie ahead in the development of SACs.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216254"},"PeriodicalIF":20.3,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142436283","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"In situ formulation of biomaterials for disease therapy: Recent advances in peptide assembly strategies","authors":"Wenmin Xiong ,&nbsp;Na Song ,&nbsp;Xiaowei Mo ,&nbsp;Zeyu Zhang ,&nbsp;Jinyan Song ,&nbsp;Yushi Wang ,&nbsp;Junyu Li ,&nbsp;Zhilin Yu","doi":"10.1016/j.ccr.2024.216251","DOIUrl":"10.1016/j.ccr.2024.216251","url":null,"abstract":"<div><div>Biomaterials aim to address healthy issues and contribute to improve life quality for human beings. Currently available biomaterials have been challenged in performing theranostic objectives under real dynamic physiological conditions and at precise targeting sites. To address this concern, over the past few years in situ formulation of biomaterials has been developed to perform disease diagnosis and therapy in a precise manner involving different components. In this review, we introduced the concept of in situ-formed biomaterials and their design principles, specifically summarizing the progress of in situ-formed biomaterials based on stimulus-responsive self-assembly of peptides in living systems. We highlighted the recent examples of in situ assembling systems of peptides with applications ranging from cancer therapy, anti-inflammation and anti-bacteria, as well as tissue engineering and regeneration. The challenges met by in situ biomaterials and the prospects of in situ peptide assembly towards biomedicines are also discussed, which hopefully elucidates the great potential of in situ-formed biomaterials for future healthcare.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216251"},"PeriodicalIF":20.3,"publicationDate":"2024-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142415724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Piezoelectric effect coupled advanced oxidation processes for environmental catalysis application","authors":"Bofan Zhang ,&nbsp;Mengyi Zhao ,&nbsp;Kai Cheng ,&nbsp;Juanjuan Wu ,&nbsp;Shiro Kubuki ,&nbsp;Liang Zhang ,&nbsp;Yang-Chun Yong","doi":"10.1016/j.ccr.2024.216234","DOIUrl":"10.1016/j.ccr.2024.216234","url":null,"abstract":"<div><div>The swift progression of industrialization poses a profound threat to environmental integrity, giving rise to environmental pollution and a consequential imbalance in ecosystems, thereby compromising public health. Consequently, the exigency for environmental remediation has become both urgent and imperative. Within this context, the burgeoning research field of piezoelectric catalysis has ushered in transformative and sustainable advancements in catalytic processes, untethered from the reliance on luminous energy or electricity inputs. This novel approach exhibits efficacy in generating reactive substances tailored to combat refractory contaminations. This comprehensive review delineates state-of-the-art progressions in piezoelectric materials, characterization instruments, mechanisms, and their applications in environmental decontamination. The exploration encompasses piezoelectric catalysis, piezo-photocatalysis, and various piezo-Fenton-like processes, including piezocatalytic H₂O₂ evolution, piezo-self cycled Fenton-like, and piezocatalytic persulfate and ozonation. A meticulous exposition begins with a detailed analysis of conventional and emerging piezoelectric materials, accompanied by a discussion on effectual and popular characterizations. The subsequent sections delve into the prevailing origin of the piezoelectric effect, prerequisites, improving strategies, and unresolved issues pertaining to the discernment of piezocatalytic mechanisms. Further, this review systematically explores the application of piezoelectric-coupled advanced oxidation processes and their intrinsic mechanisms in organic decontamination, H₂O₂ evolution, heavy metal reduction, bacterial disinfection, and CO₂ reduction. In conclusion, the paper articulates the challenges inherent in piezocatalytic techniques and proposes directions for future development. The aim is to contribute to an enhanced foundational understanding of piezoelectric catalysis and piezoelectric-based Advanced Oxidation Processes (AOPs) as potent tools for addressing contemporary environmental challenges.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216234"},"PeriodicalIF":20.3,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142405408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent advances in sorption-based photocatalytic materials for the degradation of antibiotics","authors":"Jiaomei Yang ,&nbsp;Shufang Tian ,&nbsp;Zhen Song ,&nbsp;Yingge Hao ,&nbsp;Minghua Lu","doi":"10.1016/j.ccr.2024.216257","DOIUrl":"10.1016/j.ccr.2024.216257","url":null,"abstract":"<div><div>The misuse of antibiotics and insufficient water treatment practices have resulted in significant issues, including the emergence of drug-resistant genes, posing grave threats to both human health and the ecosystem. Despite antibiotics being present in minute quantities within wastewater, their enrichment is crucial for effective removal. Thus, synthesizing photocatalysts with exceptional adsorption properties becomes pivotal factor. While previous studies have extensively covered the adsorption or photocatalytic breakdown of antibiotics, a comprehensive compilation of adsorption photocatalysts proficient in antibiotic degradation is lacking. This work explores major antibiotic classes and their fundamental properties, analyzes the impact of solution pH on antibiotic adsorption, and outlines the basic principles and key factors influencing the photocatalytic degradation of antibiotics in advanced oxidation processes (AOPs). It also briefly describes the adsorption mechanisms involving the main atoms and functional groups, including electrostatic, hydrophobic, acid-base, π-π, cation-π interactions, pore-filling, and hydrogen-bonding. Additionally, the study summarizes the energy band structures of six prevalent adsorptive photocatalytic materials and their corresponding primary mechanisms for antibiotic degradation, elucidating their applications in both antibiotic adsorption and photodegradation. These materials include graphitic carbon nitride-based, bismuth-based, metal-organic frameworks (MOFs)-based, semiconducting metal oxides-based, silver-based, graphene-based, and other photocatalysts. Moreover, it elucidates the factors augmenting adsorption performance and photocatalytic efficacy of these composite materials, underscoring the pivotal synergy between adsorption and photocatalysis for enhanced efficiency. Lastly, this paper encapsulates current concerns and outlines future research prospects in the realm of photocatalytic antibiotic degradation. It stands as a valuable resource, offering guidance for research aimed at purging antibiotics from water bodies, providing theoretical insights indispensable in crafting and synthesizing efficient photocatalytic materials for antibiotic degradation.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216257"},"PeriodicalIF":20.3,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142405701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Utilizing the metal coordination and supramolecular chemistry of macrocycles to tackle medicinal issues","authors":"Carl Redshaw","doi":"10.1016/j.ccr.2024.216147","DOIUrl":"10.1016/j.ccr.2024.216147","url":null,"abstract":"<div><div>In this review, recent (post-2018) prominent examples of metal coordination and/or supramolecular chemistry of macrocycles, which have been employed against a variety of diseases are highlighted. The broad range of macrocycles available as well as their facile modification and, in some cases, the ability to act as hosts is leading to a growth in the use of macrocyclic metal-based agents against a number of common health issues as well as some of the lesser-known ailments. The focus here is mostly on the use of systems comprised of either calixarenes or cucurbiturils, but we also note some of the highlights that have emerged from the use of other metal-containing macrocyclic systems such as those based on pillarenes, cyclodextrins, crown ethers, and Schiff-base macrocycles. Much of the work is centered around improving the delivery and effectiveness of metal-containing anti-cancer drugs, particularly those based on platinum, however, there have also been advances in a number of other areas such as their use as agents against bacteria, TB or HIV. A significant body of work has also been conducted in conjunction with nanoparticles, where the surface of the nanoparticles has been modified with a view to subsequent use in medicine.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216147"},"PeriodicalIF":20.3,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142405412","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Automated synthesis and processing of functional nanomaterials: Advances and perspectives","authors":"Masoud Negahdary ,&nbsp;Samuel Mabbott","doi":"10.1016/j.ccr.2024.216249","DOIUrl":"10.1016/j.ccr.2024.216249","url":null,"abstract":"<div><div>Integration of nanotechnology and information technology has seen an enormous leap in growth with the invention of automated systems capable of synthesizing and processing nanomaterials, thus presenting notable advantages over traditional techniques, particularly improved accuracy, reproducibility, and scalability. Automated systems minimize human errors, and nanomaterials can also be produced on a large scale at a speedy rate while controlling material properties in great detail, hence giving rise to specific functionalities that may not be realized through manual methods. Here, the most recent advancements in automated synthesis and processing of nanomaterials will be discussed, covering various types of nanomaterials which can be categorized as either coordinated or non-coordinated including metal-organic frameworks (MOFs), MXenes, quantum dots (QDs), nanocomposites, carbon-based nanomaterials, and others. Additionally, we will address the technological breakthroughs that have led to automation, from microfluidic synthesis to robots coupled with artificial intelligence (AI) and machine learning. In a new age of synthetic approaches, advanced developments within automation provide the controllable and predictable production of high-quality known nanomaterials while also providing the catalyst for generating novel nanomaterials. The primary object of this review is to provide a comprehensive and critical assessment of the current trends and breakthroughs in automated nanomaterial synthesis and processing, which brings out the research principles and the advantages of different automated platforms. It is equally important to address some limitations of current approaches to ignite a discussion about future research directions.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216249"},"PeriodicalIF":20.3,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142405407","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}