Coordination Chemistry Reviews最新文献

{"title":"Coordination structure engineering of single atoms derived from MOFs for Electrocatalysis","authors":"Min Song,&nbsp;Qian Zhang,&nbsp;Guanyu Luo,&nbsp;Hanyu Hu,&nbsp;Deli Wang","doi":"10.1016/j.ccr.2024.216281","DOIUrl":"10.1016/j.ccr.2024.216281","url":null,"abstract":"<div><div>Metal-organic frameworks (MOFs) have attracted increasing attention as potential precursors for the synthesis of single atom catalysts (SACs) due to the high specific surface area, adjustable pore size, and ligand structure. Although significant efforts have been made to synthesize MOFs-derived SACs for electrocatalysis, it is still lack of fundamental regulation principles which governing the intrinsic electrocatalytic performance. In this review, the recent advancements in various MOFs-derived SACs are systematically summarized. The correlation between the central metal atoms, coordination atoms, local environment, morphology, and their corresponding electrocatalytic performance, including activity, selectivity and stability, is comprehensively analyzed. Furthermore, advanced characterization techniques are summarized to elucidate the ligand configuration of MOFs-derived SACs. Finally, the major challenges and future research directions for MOFs-derived SACs are proposed. This review provides a comprehensive understanding and updated information on the design of MOFs-derived SACs with well-confined coordination structures.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216281"},"PeriodicalIF":20.3,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142486606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"State of the art in organometallic ruthenium metallodrugs for breast cancer treatment: Advances and innovations","authors":"Elena Domínguez-Jurado ,&nbsp;Agustín Lara-Sánchez ,&nbsp;Iván Bravo ,&nbsp;Alberto Ocaña ,&nbsp;Carlos Alonso-Moreno","doi":"10.1016/j.ccr.2024.216252","DOIUrl":"10.1016/j.ccr.2024.216252","url":null,"abstract":"<div><div>Cancer is a major health concern and a leading cause of death worldwide. Among all cancer types, breast cancer has the highest incidence rate. The treatment of breast cancer encompasses the use of different drugs, with ruthenium metallodrugs emerging as promising alternatives to platinum derivatives. In this context, organometallic ruthenium(II) compounds are currently the most widely explored.</div><div>This review compiles all the organometallic ruthenium compounds described in the literature to date for the treatment of breast cancer. Additionally, it covers the use of ruthenium-based metallodrugs in combination therapy, phototherapy, and nanotechnology.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216252"},"PeriodicalIF":20.3,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142452628","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Design and engineering of MOF/LDH hybrid nanocomposites and LDHs derived from MOF templates for electrochemical energy conversion/storage and environmental remediation: Mechanism and future perspectives","authors":"Reza Abazari ,&nbsp;Soheila Sanati ,&nbsp;Wei Keen Fan ,&nbsp;Muhammad Tahir ,&nbsp;Susanginee Nayak ,&nbsp;Kulamani Parida ,&nbsp;Mahmoud El-Shahat ,&nbsp;Reda M. Abdelhameed ,&nbsp;Dmytro S. Nesterov ,&nbsp;Alexander M. Kirillov ,&nbsp;Jinjie Qian","doi":"10.1016/j.ccr.2024.216256","DOIUrl":"10.1016/j.ccr.2024.216256","url":null,"abstract":"<div><div>The ongoing search for sustainable and renewable energy solutions to combat energy shortages and mitigate environmental pollution remains an urgent priority. It catalyzes the rapid evolution of cutting-edge technologies for energy storage and environmental remediation, hinging on advanced functional materials. In addition to the unprecedentedly high surface area and tunable porous structures of metal-organic frameworks (MOFs), its well-organized frameworks make them ideal templates for designing layered double hydroxides (LDHs) and their hybrids. MOF-derived LDHs boasts improved conductivity, stability, and structural adjustability. While MOF/LDH hybrids expose more active sites, leading to augmented catalytic activity and adsorption performance. Hence, this review provides a deep dive into the prospects of MOF-derived LDHs and MOF/LDH hybrids as materials for green energy production, storage, and environmental applications. The structure-property relationship, synthetic mechanism and procedure for the MOF-templated LDH and MOF/LDH composites are thoroughly reviewed. The fundamentals, reaction mechanism and active sites involved for electrochemical energy production and storage are discussed. A comprehensive review is then conducted on the recent advances in utilizing these materials for energy storage and conversion (batteries, supercapacitors, electrocatalysts), as well as environmental applications. Finally, it highlights the advantages, challenges, and future directions in designing MOF/LDH hybrids and LDHs derived from MOF templates. This review serves as a roadmap on utilizing MOFs as templates/components to synthesize advanced functional materials for the future of energy security and environmental salvation.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216256"},"PeriodicalIF":20.3,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142486585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Transformation of metal-organic frameworks (MOFs) under different factors","authors":"Yilei Xiang ,&nbsp;Suosu Wei ,&nbsp;Taoxiang Wang ,&nbsp;Huang Li ,&nbsp;Yan Luo ,&nbsp;Bing Shao ,&nbsp;Ningyuan Wu ,&nbsp;Yiji Su ,&nbsp;Linbin Jiang ,&nbsp;Jin Huang","doi":"10.1016/j.ccr.2024.216263","DOIUrl":"10.1016/j.ccr.2024.216263","url":null,"abstract":"<div><div>Metal-organic frameworks (MOFs) have been widely used in physics, chemistry, and medicine due to their large porosity and adjustable pores, high specific surface area, and good chemical and thermal stability. Most MOFs are structurally stable, but they still undergo morphological transformation and structural transformation under the stimulating factors, and these transformations are unavoidable. In this paper, we focus on the transformations of MOF under the different factors, such as chemistry, electrochemistry, photochemistry, thermochemistry and so on. Structure-property relationship is also discussed. What's more, the future development trends and challenges of MOF are also described.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216263"},"PeriodicalIF":20.3,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142452085","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Development and prospects of covalent organic framework-based ratiometric fluorescent sensors","authors":"Yin-sheng Liu ,&nbsp;Rui Xue ,&nbsp;Bing Yan","doi":"10.1016/j.ccr.2024.216280","DOIUrl":"10.1016/j.ccr.2024.216280","url":null,"abstract":"<div><div>Ratiometric fluorescence sensors attract more and more attention in the field of fluorescence sensors due to their excellent properties. The advanced material with high luminescent properties is the key to developing ratiometric fluorescence sensors. The covalent organic frameworks (COFs) stand out as an exceptional candidate for fluorescence sensing due to their expansive specific surface area and abundant active sites. However, the design, preparation, and application of COF-based ratiometric fluorescent sensors still represent a promising area for further development. This review collects the design principle of COFs and summarizes the design idea, sensing mode, and mechanism of COF-based ratiometric fluorescent sensors. Furthermore, the approaches to achieving a more comprehensive application of ratiometric fluorescent sensors with two emission centers are discussed. This review presents the research progress, challenges, and future directions in the field of COFs for fluorescent sensors, which is important for the development of high-performance ratiometric fluorescence sensors and the expansion of the application of COFs.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216280"},"PeriodicalIF":20.3,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142450223","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent advances in the treatment of heavy/precious metal pollution, resource recovery and reutilization: Progress and perspective","authors":"Shihua Liu ,&nbsp;Qiuhong Sun ,&nbsp;Nuo Xu ,&nbsp;Yawen Wang ,&nbsp;Yang Li ,&nbsp;Jinhao Li ,&nbsp;Zilong Li ,&nbsp;Vishnu D. Rajput ,&nbsp;Tatiana Minkina ,&nbsp;Xianggui Kong ,&nbsp;Guangchao Li ,&nbsp;Yanjun Lin ,&nbsp;Yufei Zhao ,&nbsp;Xue Duan","doi":"10.1016/j.ccr.2024.216268","DOIUrl":"10.1016/j.ccr.2024.216268","url":null,"abstract":"<div><div>With the advancement of industrial development and urbanization, the indiscriminate discharge of industrial pollutants and wastes containing heavy metals and precious metals poses a significant threat to human health and ecosystems. Despite the widespread use of several traditional therapeutic procedures, these treatments frequently exhibit low efficacy and significant environmental consequences. The extraction and reuse of metal resources in pollutant treatment can effectively alleviate the current resource crisis; however, achieving a balance between recovery efficiency and environmental impact during the extraction process remains a major challenge. To tackle these challenges, emerging treatment materials along with advancements in thermal/photo/electrochemical methods offer additional possibilities for efficiently remediating/mineralizing heavy/precious metal pollution. This paper introduces traditional techniques for treating precious and heavy metals from water and soil while discussing the prospects of new treatment materials as well as effective thermal/photo/electrochemical methods for removing such metals. Furthermore, various strategies for recovering metals from municipal waste and wastewater containing heavy/precious metal are discussed, emphasizing sustainable approaches to enhance recycling performance.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216268"},"PeriodicalIF":20.3,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142444359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Perspectives and challenges in circularly polarized luminescence of lanthanide(III) complexes: From solution-based systems to solid-state applications","authors":"Airton G. Bispo-Jr ,&nbsp;Nagyla A. Oliveira ,&nbsp;Isabela M.S. Diogenis ,&nbsp;Fernando A. Sigoli","doi":"10.1016/j.ccr.2024.216279","DOIUrl":"10.1016/j.ccr.2024.216279","url":null,"abstract":"<div><div>This review provides a comprehensive examination of circularly polarized luminescence (CPL) in Lanthanide(III) systems, encompassing their historical development, present challenges, and future applications. Starting with early discoveries and key milestones, we trace the evolution of CPL studies, highlighting seminal works and breakthroughs that have shaped current understanding. Special emphasis is placed on the processing of these complexes in both solution and solid-state forms, delineating how different environments affect CPL properties. We delve into the challenges that researchers face in this field, including synthetic hurdles, stability issues, and the need for enhanced dissymmetry factors and emission quantum yields. Additionally, the review explores strategies to overcome these obstacles, such as innovative coordination chemistry design, advanced characterization techniques, and novel processing methods. Finally, we discuss potential applications of Lanthanide(III) CPL complexes, from security and display technologies to biological fingerprint. By providing a historical perspective, identifying current challenges, and outlining future directions, this review aims to serve as a valuable resource for researchers and practitioners in the field of luminescent materials and beyond.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216279"},"PeriodicalIF":20.3,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142439955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Porphyrins-based multidimensional nanomaterials: Structural design, modification and applications","authors":"Changyu Hu ,&nbsp;Dong Jiang ,&nbsp;Yin Zhang ,&nbsp;Hu Gao ,&nbsp;Yihan Zeng ,&nbsp;Nithima Khaorapapong ,&nbsp;Zhipeng Liu ,&nbsp;Yusuke Yamauchi ,&nbsp;Mingzhu Pan","doi":"10.1016/j.ccr.2024.216264","DOIUrl":"10.1016/j.ccr.2024.216264","url":null,"abstract":"<div><div>As global demand for renewable energy consumption and environmental treatment intensifies, the development of innovative technologies and green materials for catalytic transformation is increasingly critical. Porphyrins, often referred to as the ‘pigments of life’, are notable for their macrocyclic π-conjugated electronic structures and distinctive light excitation/absorption properties. They have been widely used for oxygen transport, photosynthesis, as well as serving enzymatic catalytic centers in biological processes. However, the inherent strong π–π interactions among rigid porphyrin molecules lead to disordered stacking and self-aggregation, diminishing the accessibility of active sites and the efficiency of charge transfer during practical applications. Hybrid porphyrins with multidimensional nano-substrates, like graphene, metal oxide, et al. is a promising strategy that can not only mitigate self-aggregation of porphyrins but also can achieve a synergetic enhancement effect. Selecting suitable substrates and effective bonding interactions between the porphyrins and substrates are critical for achieving the desired performance in specific applications. This review comprehensively summarizes recent advances in porphyrin-based multidimensional nanomaterials (PMNs), focusing on the influence of nanoscale effects, performance enhancements, and their applications in energy conversion, storage, biomedicine, and environmental protection. It delves deeply into the role of interaction forces in boosting interfacial electron transfer for superior catalytic transformations. Additionally, it critically examines the correlations between the high loading and dispersion of porphyrin molecules, emphasizing strategies, structural design, nanoscale effects, and interfacial interactions. Notably, the discussion extends to the mechanistic links between the structure, properties, and applications of PMNs. The review concludes by addressing the critical challenges and future directions in this field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216264"},"PeriodicalIF":20.3,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142439954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sensitized triplet-triplet annihilation-based photon upconversion: Assembly strategy and key consideration for sustainable energy and biomedical applications","authors":"Prashanth Venkatesan ,&nbsp;Preeti Pal ,&nbsp;Siew Suan Ng ,&nbsp;Jui-Yen Lin ,&nbsp;Ruey-An Doong","doi":"10.1016/j.ccr.2024.216266","DOIUrl":"10.1016/j.ccr.2024.216266","url":null,"abstract":"<div><div>Sensitized Triplet-triplet annihilation (sTTA) photon upconversion (UC) represents a cutting-edge technology with far-reaching implications in both sustainable energy and biomedical realms. By capitalizing on the unique properties of excited triplet states, sTTA-UC enables the conversion of low-energy photons into higher-energy counterparts, offering promising solutions for efficient solar energy utilization and transformative biomedical applications. This review offers a comprehensive exploration of sTTA-UC, delving into its fundamental principles, assembly strategies, and key considerations for applications in sustainable energy and biomedicine. Various materials, including silica, clay, polymers, gels, metal-organic frameworks (MOFs), and covalent organic frameworks (COFs), play integral roles in enhancing sTTA efficiency and overcoming challenges such as oxygen quenching. Additionally, the review surveys the diverse applications of sTTA-UC, in photocatalysis, solar energy conversion, biosensing, bioimaging, and therapeutic interventions. These applications underscore the versatility and potential of sTTA-UC across multifaceted domains, promising significant advancements in various scientific and technological fields. Looking towards the future, the review outlines key areas for further exploration and development in sTTA-UC research. Priorities include optimizing materials, enhancing stability, and exploring innovative integration approaches to fully harness the capabilities of sTTA-UC technology. By elucidating the opportunities and challenges inherent in sTTA-UC, this review seeks to inspire researchers to propel the field forward, driving innovation and sustainability in both energy and biomedical sectors.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216266"},"PeriodicalIF":20.3,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142431784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Organic-inorganic hybrid materials for catalytic transfer hydrogenation of biomass-derived carbonyl-containing compounds","authors":"Mei Wu ,&nbsp;Li Bai ,&nbsp;Fengjuan Deng ,&nbsp;Jian He ,&nbsp;Ke Song ,&nbsp;Hu Li","doi":"10.1016/j.ccr.2024.216259","DOIUrl":"10.1016/j.ccr.2024.216259","url":null,"abstract":"<div><div>Upgrading biomass-derived platform molecules into valuable chemicals and biofuels is critical in bio-refinery to establish bio-based sustainable chemical processes. Catalytic transfer hydrogenation represents a fascinating strategy for the reductive upgradation of bio-based oxygenated compounds owing to bypassing the potential security risks and tedious safety precautions associated with using flammable and explosive pressurized H₂. Organic-inorganic hybrid materials (OIHMs), bearing the merits of strong Lewis acid-base ability, high specific-surface-area and pore size, tunable structure/properties and easy preparation, have been confirmed to be promising catalysts for transfer hydrogenation. In this contribution, an overview of OIHMs in transfer hydrogenation of bio-based oxygenated compounds is presented, which mainly involves diverse organic ligands with oxygen-rich groups like −OH, −COOH, −PO₃H₂, and − SO₃H for constructing OIHMs. The corresponding characterization means for clarifying the structures/properties of OIHMs, structure-reactivity relationships, reaction pathways and/or mechanisms together with catalyst durability are elucidated. In addition, the general challenges and future research on the applications of OIHMs in transfer hydrogenation are also discussed. Expectedly, this review can provide an instructive viewpoint for the rational design and practical application of OIHMs in reductive upgrading of bio-based oxygenated compounds via hydrogen transfer processes.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216259"},"PeriodicalIF":20.3,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142434170","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}