Coordination Chemistry Reviews最新文献_第4页

The design principles and biological applications of fluorescence and phosphorescence lifetime imaging based on functionalized dyes 基于功能化染料的荧光和磷光寿命成像的设计原理及其生物学应用

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2026-06-01 Epub Date: 2026-02-08 DOI: 10.1016/j.ccr.2026.217672

Lipeng Zhang , Yongbin Zhang , Fangjun Huo , Jingying Zhou , Caixia Yin

{"title":"The design principles and biological applications of fluorescence and phosphorescence lifetime imaging based on functionalized dyes","authors":"Lipeng Zhang , Yongbin Zhang , Fangjun Huo , Jingying Zhou , Caixia Yin","doi":"10.1016/j.ccr.2026.217672","DOIUrl":"10.1016/j.ccr.2026.217672","url":null,"abstract":"<div><div>With the rapid advancement of imaging technologies, non-invasive biological imaging with high spatiotemporal resolution has become a pivotal area of research in life sciences and precision medicine. Conventional intensity-based fluorescence and phosphorescence imaging often yields quantitatively unreliable results due to variations in probe concentration and tissue-induced light scattering. In contrast, fluorescence lifetime imaging (FLIM) and phosphorescence lifetime imaging (PLIM) have emerged as robust and reliable quantitative imaging modalities, offering high sensitivity to microenvironmental alterations, strong resistance to optical interference, and consistent data quantification. FLIM enables the precise investigation of subcellular dynamics through nanosecond-scale fluorescence decay from the singlet excited state, whereas PLIM exploits phosphorescence emission from the triplet state, with lifetimes ranging from microseconds to seconds, to achieve deep-tissue imaging with significantly improved signal-to-noise ratios. The complementary temporal resolutions of FLIM and PLIM together provide a multidimensional imaging framework that supports comprehensive biological and biomedical investigations. However, despite their respective advantages, most current studies focus on the isolated application of either technique, with limited systematic comparisons between FLIM and PLIM. This review presents an integrated analysis of the fundamental principles and recent technological advancements in FLIM and PLIM, explores the molecular design strategies that influence probe lifetime modulation, highlights their applications in monitoring cellular microenvironments and organelle communication, and critically assesses the current challenges and future prospects of these imaging technologies, with the ultimate objective of facilitating their translation from basic research into clinical practice.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217672"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146138830","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent advances of metal-organic frameworks/carbon composites for rechargeable batteries 可充电电池用金属-有机骨架/碳复合材料的研究进展

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2026-06-01 Epub Date: 2026-02-11 DOI: 10.1016/j.ccr.2026.217661

Zheng Liu , Luxu Wang , Guoqiang Yuan , Wanchang Feng , Yanfei Zhang , Huan Pang

{"title":"Recent advances of metal-organic frameworks/carbon composites for rechargeable batteries","authors":"Zheng Liu , Luxu Wang , Guoqiang Yuan , Wanchang Feng , Yanfei Zhang , Huan Pang","doi":"10.1016/j.ccr.2026.217661","DOIUrl":"10.1016/j.ccr.2026.217661","url":null,"abstract":"<div><div>Recently, metal-organic frameworks (MOFs) have gradually emerged as a research hotspot due to their highly tunable nanoporous structures and functional diversity. After over three decades of development, MOF-related research was honored with the 2025 Nobel Prize in Chemistry. MOFs demonstrate broad application prospects across multiple fields, particularly excelling in energy storage and conversion. As the global transition to green energy advances, battery technology as a key enabler demands higher material performance. Although MOFs hold significant potential for battery application, their inherently poor conductivity limits further advancement. To address this challenge, researchers have explored diverse strategies, among which the composite construction of multifunctional materials by combining MOFs with carbon-based materials has emerged as an effective approach. Such materials integrate the structural designability of MOFs with the excellent conductivity of carbon material, yielding synergistic effects that significantly enhance electrochemical performance. Currently, systematic reviews on the application of MOFs/carbon composites in batteries remain scarce. Based on recent research advances, beginning with a dimensional classification of carbon materials, this review analyzes the synthesis strategies of composites and their mechanisms for improving electrode performance. It then systematically examines the applications of these composites across representative battery systems, offering insights for future material design and energy storage device development.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217661"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146153134","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Self-assembled luminescent lanthanide complexes in solution as rising stars for sensing and bioimaging 自组装发光镧系化合物在传感和生物成像中的应用

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2026-06-01 Epub Date: 2026-02-10 DOI: 10.1016/j.ccr.2026.217676

Alvaro Ruiz-Arias , Francisco Fueyo-González , Angel Orte , Juan A. González-Vera

{"title":"Self-assembled luminescent lanthanide complexes in solution as rising stars for sensing and bioimaging","authors":"Alvaro Ruiz-Arias , Francisco Fueyo-González , Angel Orte , Juan A. González-Vera","doi":"10.1016/j.ccr.2026.217676","DOIUrl":"10.1016/j.ccr.2026.217676","url":null,"abstract":"<div><div>Luminescent lanthanide (Ln<sup>3+</sup>) complexes are highly attractive for diverse applications, particularly as luminescent probes, owing to their exceptional photophysical properties, including long-lived photoluminescence, narrow-band emissions, and large Stokes shifts. These characteristics enable advanced techniques like time-gated detection, significantly enhancing signal-to-noise ratios in biological samples. Traditional luminescent Ln<sup>3+</sup> complexes are characterized by bulky organic cryptands and/or conjugated chromophoric antennae for prompting the metal excitation prior to emission. This strategy is usually synthetically demanding, including complexation reactions that last for several days. To overcome this limitation, self-assembly strategies in solution have recently emerged as a powerful approach. This review discusses recent advancements in self-assembled luminescent Ln<sup>3+</sup> complexes across various solvents, with particular emphasis on their behavior and performance in aqueous environments. It highlights the growing importance of water-compatible self-assembled luminescent Ln<sup>3+</sup> complexes for biological applications, underscoring their potential in cell imaging and biosensing. By addressing key design challenges and showcasing diverse functionalities, this review provides a comprehensive and accessible overview for researchers in chemistry, biochemistry, and biology interested in the rapidly evolving field of lanthanide luminescence.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217676"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146153142","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Halogen bonding in hypervalent halogen-based systems: Structural determinants and supramolecular diversity 高价卤素基体系中的卤素键：结构决定因素和超分子多样性

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2026-06-01 Epub Date: 2026-02-12 DOI: 10.1016/j.ccr.2026.217585

Natalia S. Soldatova , Elizaveta V. Knyazeva , Vadim Yu. Kukushkin , Pavel S. Postnikov

{"title":"Halogen bonding in hypervalent halogen-based systems: Structural determinants and supramolecular diversity","authors":"Natalia S. Soldatova , Elizaveta V. Knyazeva , Vadim Yu. Kukushkin , Pavel S. Postnikov","doi":"10.1016/j.ccr.2026.217585","DOIUrl":"10.1016/j.ccr.2026.217585","url":null,"abstract":"<div><div>This review presents the first systematic analysis of supramolecular organization in halonium-based systems driven by halogen bonding (XB) interactions. Through comprehensive examination of approximately 600 crystal structures from the Cambridge Structural Database, we establish major principles governing XB-directed assembly patterns across diverse halonium species. Monocationic halonium salts paired with monoanionic counterions constitute over 50% of characterized structures, predominantly forming 0D (85%) and 1D (15%) assemblies. Heterotetrameric motifs—cyclic assemblies comprising two cations and two anions connected through four intermolecular XBs—emerge as the dominant organizational principle (58% of structures). Critically, anion geometry plays the decisive role in directing supramolecular architecture, while cation structure exerts minimal influence. Iodonium (91%) and bromonium derivatives follow consistent assembly trends favoring heterotetrameric motifs, whereas chloronium salts exhibit anomalous behavior. Polycharged systems generate more complex 1D and 2D networks through linking of basic heterotetrameric units. Zwitterionic halonium compounds utilize analogous dimeric motifs as building blocks for extended 1D, 2D, and 3D assemblies, demonstrating promise as building blocks for noncovalent organic frameworks. These findings establish halonium salts as reliable platforms for predictable XB-based crystal engineering.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217585"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146160633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent advances in coordination chemistry-driven metal-organic frameworks for cancer drug delivery and therapeutics 配合化学驱动的金属-有机框架在癌症药物传递和治疗中的最新进展

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2026-06-01 Epub Date: 2026-02-11 DOI: 10.1016/j.ccr.2026.217683

Arzoo Saini, Neelam Yadav

{"title":"Recent advances in coordination chemistry-driven metal-organic frameworks for cancer drug delivery and therapeutics","authors":"Arzoo Saini, Neelam Yadav","doi":"10.1016/j.ccr.2026.217683","DOIUrl":"10.1016/j.ccr.2026.217683","url":null,"abstract":"<div><div>Metal-organic frameworks (MOFs) are crystalline materials with porous structures exhibiting unique coordination chemistry. They have been garnering extensive attention for industrial, environmental, and biomedical applications. The use of MOFs as a potent drug delivery solution has overcome the limitations of conventional cancer therapy. Unlike conventional nanocarriers, MOFs provide precise control over organic linkers, metal nodes, pore environment, <em>etc.</em> The rational design of these smart drug delivery platforms can make them responsive to internal and external stimuli. The exceptional coordination chemistry enables high drug loading, simultaneous delivery of imaging and therapeutic substances, their protection, and controlled release. However, certain challenges still exist, but with the progressing research, MOFs have immense potential in revolutionizing cancer therapeutics. This review article comprehensively discusses the coordination chemistry aspects of MOFs, including their synthesis, drug loading, and release kinetics. This article also provides a detailed and comparative outlook of the application of MOFs in cancer therapy, along with translational and regulatory aspects, and the emerging role of AI. Altogether, this review aims to provide comprehensive insights and a roadmap for future research of next-generation and state-of-the-art MOF-based cancer drug delivery systems.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217683"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146153136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent advances in organic small-molecule fluorescent probes for the detection of iron ions 有机小分子荧光探针检测铁离子的研究进展

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2026-06-01 Epub Date: 2026-02-11 DOI: 10.1016/j.ccr.2026.217671

Ning Duan , Jianxiong Hao , Dandan Zhao , Hongyu Tian , Shaoxiang Yang

{"title":"Recent advances in organic small-molecule fluorescent probes for the detection of iron ions","authors":"Ning Duan , Jianxiong Hao , Dandan Zhao , Hongyu Tian , Shaoxiang Yang","doi":"10.1016/j.ccr.2026.217671","DOIUrl":"10.1016/j.ccr.2026.217671","url":null,"abstract":"<div><div>Accurate detection of iron ions is essential for maintaining ecological balance, ensuring food safety, and advancing pathological research. Consequently, there is a pressing need for rapid, simple, highly selective, and low-cost testing methods. Organic small-molecule fluorescent probes have emerged as a powerful alternative to conventional techniques, owing to their high sensitivity, excellent selectivity, rapid response times, and capacity for spatiotemporal imaging. This review systematically analyses and compares 128 organic fluorescent probes reported since 2015 for the detection of Fe<sup>3+</sup>, Fe<sup>2+</sup>, and total iron (Fe<sup>3+/2+</sup>). The analysis focuses on coordination mechanisms, design strategies, and practical applications, encompassing composition, structural design, luminescence mechanisms, theoretical calculations, and application progress. Furthermore, a practical design framework, supported by theoretical models, is outlined to guide the rational development of novel iron probes. Finally, perspectives and challenges are discussed to inform future work and accelerate the development of this promising class of analytical tools.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217671"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146160639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Gold-based nanoclusters precisely engineered for catalytic performance 金基纳米团簇精确设计用于催化性能

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2026-06-01 Epub Date: 2026-02-11 DOI: 10.1016/j.ccr.2026.217698

Sha Yang, Shenao Wu, Feng Qian, Haizhu Yu, Jinsong Chai, Manzhou Zhu

{"title":"Gold-based nanoclusters precisely engineered for catalytic performance","authors":"Sha Yang, Shenao Wu, Feng Qian, Haizhu Yu, Jinsong Chai, Manzhou Zhu","doi":"10.1016/j.ccr.2026.217698","DOIUrl":"10.1016/j.ccr.2026.217698","url":null,"abstract":"<div><div>Atomic-precise gold nanoclusters (Au NCs) offer an ideal platform for elucidating catalytic mechanisms at the atomic level, marking a shift from empirical exploration to rational design in catalytic research. This review systematically discusses how to achieve “customized” design of the catalytic performance of gold nanoclusters through multi-dimensional, precise control strategies. Doping engineering introduces heteroatoms (e.g., Cd, Pd) to precisely regulate the electronic structure of clusters, optimize the adsorption energies of reaction intermediates, and effectively guide reaction pathways. Ligand engineering goes beyond stability and functionality, using the electronic and steric effects of ligands to fine-tune the charge state of the metal core and the transport pathways of reactants. Defect and symmetry-breaking strategies actively disrupt perfect structures to create highly active unsaturated sites and induce built-in electric fields, significantly enhancing adsorption capacity and selectivity. Based on this, active centers are directly constructed to achieve precise assembly of multi-site synergistic catalytic mechanisms. Additionally, carrier interfaces stabilize clusters through strong mutual interactions (SMSI) and induce interfacial charge transfer, creating new synergistic catalytic interfaces. However, this field still faces challenges such as structural stability under harsh conditions, large-scale preparation, and in situ characterization. Through the aforementioned multi-dimensional synergistic regulation, the rational design of gold nanocluster catalysts has become a key frontier driving the development of energy conversion and environmental catalysis.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217698"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146160641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Computational approaches to the study of chalcogen bonding interactions 研究碳键相互作用的计算方法

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2026-06-01 Epub Date: 2026-02-06 DOI: 10.1016/j.ccr.2025.217514

Massimiliano Arca , Vito Lippolis , M. Carla Aragoni , Enrico Podda , Gianluca Ciancaleoni , Anna Pintus

引用次数: 0

A critical review of the toxicity, safety, and regulatory landscape of metal-organic frameworks in food packaging 对食品包装中金属有机框架的毒性，安全性和监管前景的批判性审查

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2026-06-01 Epub Date: 2026-02-11 DOI: 10.1016/j.ccr.2026.217689

Kunpeng Zhao , Abubakar Shuaibu , Zuyao Fu , Jing Xie , Zhaoyang Ding

引用次数: 0

Modified metal-organic frameworks as efficient heterogeneous catalysts for the ring-opening of epoxides with alcohols 改性金属-有机骨架作为环氧化合物与醇开环的高效非均相催化剂

IF 23.5 1区化学

Coordination Chemistry Reviews Pub Date : 2026-06-01 Epub Date: 2026-02-11 DOI: 10.1016/j.ccr.2026.217684

Maryam Mohammadikish, Majid Masteri-Farahani

{"title":"Modified metal-organic frameworks as efficient heterogeneous catalysts for the ring-opening of epoxides with alcohols","authors":"Maryam Mohammadikish, Majid Masteri-Farahani","doi":"10.1016/j.ccr.2026.217684","DOIUrl":"10.1016/j.ccr.2026.217684","url":null,"abstract":"<div><div>Metal-organic frameworks (MOFs) have appeared as a class of versatile heterogeneous catalysts due to their adjustable porosity, structural diversity, and functionalizable active sites. Among their several catalytic applications, the catalytic ring-opening of epoxides with alcohols has attracted significant attention, as it provides efficient access to beneficial beta-alkoxy alcohols under mild and environmentally benign conditions. This review provides a summary of recent progress in the design and post-synthetic modification of MOFs that promote their activity, selectivity, and stability in the ring-opening of epoxides with alcohols. Emphasis is placed on key strategies, including defect engineering, incorporation of Brønsted and Lewis acidic sites, and ligand-functionalization approaches, which adjust the catalytic efficiency. Representative studies reveal how structural tuning, node modification, and the creation of cooperative catalytic sites enable their high activity and selectivity. By providing an integrated perspective on the structure-activity relationships, this review underscores the potential of MOFs as durable, recyclable, and highly efficient catalysts for sustainable epoxide transformations. Future directions for rational design of MOFs and development for broader substrate scope and industrial utilization are also discussed.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"556 ","pages":"Article 217684"},"PeriodicalIF":23.5,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146160640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0