Coordination Chemistry Reviews最新文献_第4页

Ionic liquids: The emerging “cardiotonic” for photocatalytic materials

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-01-24 DOI: 10.1016/j.ccr.2025.216461

Bin He , Sheng Zhong , Kexin Li , Shuang Wei , Mengyue Li , Ruixia Liu

{"title":"Ionic liquids: The emerging “cardiotonic” for photocatalytic materials","authors":"Bin He , Sheng Zhong , Kexin Li , Shuang Wei , Mengyue Li , Ruixia Liu","doi":"10.1016/j.ccr.2025.216461","DOIUrl":"10.1016/j.ccr.2025.216461","url":null,"abstract":"<div><div>Photocatalysis has been regarded as “21st century dream technology” and inspired increasing scientific interest due to their environmental and economic applicability. Due to the bottlenecks of photocatalytic materials (PMs) faced, such as low carrier separation efficiency, insufficient active sites, and incompatibility between surface interface properties and targeted reaction, restricting its advance from laboratory to application. The emergence of ionic liquids (ILs) provides a favorable term for the development of PMs due to their tailorability and diversity. This review starts with the properties of ILs (hydrogen bonds effect, electrostatic effect, polarity effect, and coordination effect), followed by analyzing the potential of ILs in PMs modification. Specifically, this review systematically summarized the regulatory mechanisms and unique advantages of ILs on the particle size, morphology, electron transport and interface properties of PMs. Finally, a summary and outlook on the major challenges, opportunities for future research in high-powered PMs by the strategy of ILs modification was proposed.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"529 ","pages":"Article 216461"},"PeriodicalIF":20.3,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143026673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Nanocatalytic medicine: An advanced catalysis-based imaging and therapy methodology

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-01-24 DOI: 10.1016/j.ccr.2024.216430

Lingdong Jiang , Zhaokui Jin , Qianjun He

引用次数: 0

Recent advances in hydrotreating and hydrocracking catalysts for the preparation of light aromatics: Influencing factors, catalytic mechanisms and performance relationship descriptors

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-01-24 DOI: 10.1016/j.ccr.2025.216444

Lingjing Yu , Hong Nie , Ping Yang , Linmeng Wang , Shihao Feng , Hongyi Gao , Ge Wang

{"title":"Recent advances in hydrotreating and hydrocracking catalysts for the preparation of light aromatics: Influencing factors, catalytic mechanisms and performance relationship descriptors","authors":"Lingjing Yu , Hong Nie , Ping Yang , Linmeng Wang , Shihao Feng , Hongyi Gao , Ge Wang","doi":"10.1016/j.ccr.2025.216444","DOIUrl":"10.1016/j.ccr.2025.216444","url":null,"abstract":"<div><div>Sustainability and environmental concerns have posed significant challenges to the petrochemical industry. To maintain the overall balance of materials and enhance the resilience of the refining and petrochemical industry chain, it is crucial to focus on the development of high-value products and clean energy. Light aromatic hydrocarbons (BTX) are an important chemical raw material, and their production can not only meet the requirements of environmental protection but also realize the high-value utilization of aromatic materials. Hydrotreating (HT) and hydrocracking (HYC) have emerged as promising technologies for BTX production and have been extensively researched in the past few decades. Various catalytic materials, including metal-doped, phosphide-loaded, carbon-based composites, as well as noble and non-noble metal-based materials, are commonly employed in these processes to enhance reaction efficiency and improve product selectivity. This paper summarizes and discusses the recent advances in catalyst materials for HT and HYC reactions, including 1) factors influencing the catalytic reactions of HT and HYC, 2) advances in the characterization and performance understanding of HT and HYC catalysts in the preparation of light aromatics, and 3) computer-assisted design and mechanism investigation of HT and HYC catalysts, as well as the mining of quantitative relationship descriptors. We also concisely discuss some of the scientific challenges and provide a brief outlook on the future development of HT and HYC catalysts. This paper aims to provide insights and strategies for the discovery, optimization, and design of HT and HYC catalysts, as well as understanding their structure-performance relationships.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"529 ","pages":"Article 216444"},"PeriodicalIF":20.3,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143026675","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Artificial intelligence interventions in 2D MXenes-based photocatalytic applications

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-01-24 DOI: 10.1016/j.ccr.2025.216460

Durga Madhab Mahapatra , Ashish Kumar , Rajesh Kumar , Navneet Kumar Gupta , Baranitharan Ethiraj , Lakhveer Singh

{"title":"Artificial intelligence interventions in 2D MXenes-based photocatalytic applications","authors":"Durga Madhab Mahapatra , Ashish Kumar , Rajesh Kumar , Navneet Kumar Gupta , Baranitharan Ethiraj , Lakhveer Singh","doi":"10.1016/j.ccr.2025.216460","DOIUrl":"10.1016/j.ccr.2025.216460","url":null,"abstract":"<div><div>Artificial Intelligence powered application have become the norms in day-to-day life. This has a tremendous role for material investigations catering diverse applications. Present day advanced materials as various MAX phases transformed into MXenes have immense applications for environmental use. MXenes have shown great potential in photocatalysis application targetingCO<sub>2</sub> reduction, H<sub>2</sub>O<sub>2</sub> production, wastewater and dye treatment and nitrogen fixation. For an AI based implementation and model development, the basics of photon capture and charge transfer characteristics of photocatalytic materials, right from biological systems to organic/inorganic solar cells are crucial. This had been very thoroughly worked by compelling computational model and theories. The AI-ML based approaches have been instrumental in identification, screening, scrutiny of advanced materials, especially MXenes for varied applications via the supervised, unsupervised and reinforcement learning techniques. These exercises have provided the models that can be potentially more equipped for parallelly performing the classification and regression with a higher prediction accuracy. Use of advanced deep learning techniques have aided in establishing relation between structure-feature-properties and applications for MXenes based materials. Finally, a Criteria based AI aided Decision Support System is also discussed that prioritises environmentally sound and green MAX phase precursors for the development of photocatalytic materials. This will aid in developing technically feasible, economically viable and environmentally sustainable approaches for MXenes commercialization targeting environmentally friendly photocatalytic applications, thereby achieving sustainability development goals.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"529 ","pages":"Article 216460"},"PeriodicalIF":20.3,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143031316","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Controllable synthesis of layered double hydroxides: From macroscopic morphology to microscopic coordination at the atomic level 层状双氢氧化物的可控合成：从宏观形态到微观原子配位

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-01-23 DOI: 10.1016/j.ccr.2025.216437

Sha Bai , Guihao Liu , Tianyang Shen , Zhaohui Wu , Wei Chen , Yu-Fei Song

{"title":"Controllable synthesis of layered double hydroxides: From macroscopic morphology to microscopic coordination at the atomic level","authors":"Sha Bai , Guihao Liu , Tianyang Shen , Zhaohui Wu , Wei Chen , Yu-Fei Song","doi":"10.1016/j.ccr.2025.216437","DOIUrl":"10.1016/j.ccr.2025.216437","url":null,"abstract":"<div><div>Layered double hydroxides (LDHs), as a typical inorganic two-dimensional layered material, have been widely studied in the fields of photoelectrocatalysis, energy, and environment due to their unique layered structure and excellent catalytic activity. In addition, the flexible and adjustable laminate composition of LDHs, the flexible anion exchange and column-supported exfoliation of the domain-limited space allow the reactivity of LDHs to be modulated with the changes in their composition, size, thickness, morphology, etc. Therefore, the precise synthesis of LDHs from macroscopic to microscopic is the key to promoting their development in fundamental science and industrial application. Herein, we summarize the controllable synthesis methods of LDHs in recent years, including the precise tuning strategies of macroscopic structure, such as morphology, size, thickness, etc. Furthermore, controllable preparation strategies of coordination structure at the atomic level, including the intercalation ions, coordination number, and coordination environment were also reviewed. Meanwhile, the application of synthesized LDHs with specific structures in photocatalysis, batteries, environment, and other fields has also been mentioned. Finally, the major challenges and prospects of LDHs are discussed in terms of further improving the controllability of precise synthesis.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"529 ","pages":"Article 216437"},"PeriodicalIF":20.3,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143020059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Surface site design in photocatalytic carbon conversion applications

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-01-23 DOI: 10.1016/j.ccr.2025.216459

Yi Zhang , Yixing Zhou , Molly Meng-Jung Li , Jun Di

引用次数: 0

Unlocking the potential of MBenes for sensing applications: A review of gas and biosensor innovations 释放MBenes在传感应用中的潜力：气体和生物传感器创新综述

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-01-22 DOI: 10.1016/j.ccr.2025.216458

Ahmad Husain , Prem Gunnasegaran , Mohtaram Danish

{"title":"Unlocking the potential of MBenes for sensing applications: A review of gas and biosensor innovations","authors":"Ahmad Husain , Prem Gunnasegaran , Mohtaram Danish","doi":"10.1016/j.ccr.2025.216458","DOIUrl":"10.1016/j.ccr.2025.216458","url":null,"abstract":"<div><div>Sensors have emerged as crucial tools in various fields, particularly in environmental monitoring and healthcare diagnostics, driven by increasing global health and environmental concerns. Among the promising materials, metal borides, or MBenes, have gained attention for their tunable electronic properties, large surface area, and chemical stability. MBenes demonstrate exceptional potential in both gas and biosensing applications due to their high conductivity and surface reactivity, making them adept at detecting low concentrations of hazardous gases and selectively interacting with biomolecules. This review discusses recent advances in the synthesis, structural modifications, and functionalization of MBenes, emphasizing their role in enhancing sensor selectivity and sensitivity. It also explores theoretical and experimental insights into their interactions with target analytes while outlining the challenges and opportunities for their integration into practical sensing systems. Key achievements include the development of MBene-based gas sensors capable of detecting ultra-low concentrations of gases such as NO<sub>2</sub>, NO, CO, CO<sub>2</sub>, NH<sub>3</sub>, SO, SO<sub>2</sub>, humidity and various fluorocarbons (e.g., C<sub>4</sub>F<sub>7</sub>N, C<sub>5</sub>F<sub>10</sub>O, CF<sub>4</sub>, C<sub>3</sub>F<sub>6</sub>, COF<sub>2</sub>) with unprecedented sensitivity and fast response times. Additionally, MBene-based biosensors have demonstrated remarkable performance in detecting biomolecules and pathogens, offering significant improvements in detection limits and specificity compared to traditional sensing platforms. This review concludes by outlining future research directions aimed at further enhancing MBene-based sensor performance, exploring new applications, and integrating these materials into practical sensing technologies for environmental monitoring, healthcare diagnostics, and industrial process control.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"529 ","pages":"Article 216458"},"PeriodicalIF":20.3,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142992637","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Structural effects of the Pb2+ 6s2 lone pair activity: Eccentricity Pb2+ 6s2孤对活性的结构效应：偏心率

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-01-22 DOI: 10.1016/j.ccr.2025.216434

Charlene Harriswangler , Antía Freire-García , Saray Argibay-Otero , Aurora Rodríguez-Rodríguez , José M. Rodríguez , David Esteban-Gómez , Ezequiel M. Vázquez-López , Carlos Platas-Iglesias

{"title":"Structural effects of the Pb2+ 6s2 lone pair activity: Eccentricity","authors":"Charlene Harriswangler , Antía Freire-García , Saray Argibay-Otero , Aurora Rodríguez-Rodríguez , José M. Rodríguez , David Esteban-Gómez , Ezequiel M. Vázquez-López , Carlos Platas-Iglesias","doi":"10.1016/j.ccr.2025.216434","DOIUrl":"10.1016/j.ccr.2025.216434","url":null,"abstract":"<div><div>The stereochemical activity of the 6s<sup>2</sup> lone pair has profound consequences on the coordination chemistry of metal ions like Tl<sup>+</sup>, Pb<sup>2+</sup> and Bi<sup>3+</sup>. The coordination chemistry of Pb<sup>2+</sup> is very likely the most extensively investigated among the metal ions with [Xe]4f<sup>14</sup>5d<sup>10</sup>6s<sup>2</sup> electronic configuration, allowing for a detailed analysis of the factors that affect the stereochemical activity of the 6s<sup>2</sup> lone pair. In this review, the X-ray structures of a wide variety of Pb<sup>2+</sup> complexes were analyzed by approximating their coordination environments to a prolate spheroid. The eccentricity (ε) of the spheroid provides a straightforward measure of the stereochemical activity of the Pb<sup>2+</sup> lone pair. Holodirected structures are characterized by a rather spherical distribution of the donor atoms around the metal ion, leading to values of ε < 0.05. The stereochemical activity of the lone pair may result in either moderately hemidirected structures, with ε values in the range 0.05–0.15, or strongly hemidirected structures, when ε > 0.15. Hemidirected structures are favored by low coordination numbers and the presence of negatively charged donor atoms. In this work not only have many representative complexes been analyzed to provide a classification of these systems according to their eccentricity, but also a simple tool is provided for coordination chemists, through which they can easily classify their complexes as holodirected or hemidirected.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"529 ","pages":"Article 216434"},"PeriodicalIF":20.3,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142992636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Construction of chlorine-free electrical double layer for efficient seawater oxidation 用于海水高效氧化的无氯电双层结构

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-01-21 DOI: 10.1016/j.ccr.2025.216463

Han-Ming Zhang

{"title":"Construction of chlorine-free electrical double layer for efficient seawater oxidation","authors":"Han-Ming Zhang","doi":"10.1016/j.ccr.2025.216463","DOIUrl":"10.1016/j.ccr.2025.216463","url":null,"abstract":"<div><div>Seawater electrolysis is an effective means to solve the problems of transport and consumption of offshore wind electricity. The corrosion reaction and chlorine oxidation reaction caused by the existence of chloride in seawater lead to poor electrochemical performances and low efficiencies for seawater oxidation electrocatalysts. Hence, construction of chlorine-free electrical double layer (EDL) has become one hotspot for efficient seawater oxidation. Based on the theories of interfacial electric field, adsorption selectivity, steric hindrance and electrostatic repulsion, six practical strategies have been well developed to construct the chlorine-free EDL, i.e., high-curvature morphology, hard Lewis acid coating, ploy-homoatomic anion, coordinated common ion, oxyanion, and hard Lewis acid with oxyanion. Great progresses have been made in electrocatalyst stability and reaction selectivity. However, five problems still exist limiting the pullulation of seawater oxidation: (i) the constructed EDL not completely chlorine-free. (ii) too simple condition for EDL simulation, (iii) adverse effects of modification components, (iv) lack of influences of adsorbed oxygen-containing intermediates on electrocatalysts, and (v) ignorance of solvated cations and anions in EDL. Finally, five prospects are proposed to propel the developments of chloride-free EDL and seawater electrolysis: (i) combination of multiple strategies for chlorine-free EDL construction, (ii) investigation of dynamical EDL structures by time-responsive information of electrocatalysts and electrolysis interfaces, (iii) precise control of modification components by subtle electrocatalyst preparation and appropriate electrolyte additive, (iv) encompassing oxygen-containing intermediates, and (v) involvement of solvated cations and anions in the simulated EDL. Besides, the understanding of EDL would be deeper, promoting its wide application in the fields of information, energy conversion and storage.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"529 ","pages":"Article 216463"},"PeriodicalIF":20.3,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142990743","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent mitochondria-immobilized fluorescent probes for high-fidelity bioimaging: From design to application 用于高保真生物成像的线粒体固定化荧光探针：从设计到应用

IF 20.3 1区化学

Coordination Chemistry Reviews Pub Date : 2025-01-21 DOI: 10.1016/j.ccr.2025.216456

Wenshu Meng , Ran Chen , Qingqing Jang , Kaifu Ma , Dongpeng Li , Haibin Xiao , Weijie Chi , Chaoyuan Zeng , Wei Shu

{"title":"Recent mitochondria-immobilized fluorescent probes for high-fidelity bioimaging: From design to application","authors":"Wenshu Meng , Ran Chen , Qingqing Jang , Kaifu Ma , Dongpeng Li , Haibin Xiao , Weijie Chi , Chaoyuan Zeng , Wei Shu","doi":"10.1016/j.ccr.2025.216456","DOIUrl":"10.1016/j.ccr.2025.216456","url":null,"abstract":"<div><div>As a significant organelle, mitochondria play unique and especially essential roles in a variety of cellular activities and metabolism processes. However, the discovery of mitochondria dysfunction is tightly related to many human diseases. Currently, quantities of mitochondria-targetable fluorescent sensors and theranostic agents have been exploited to monitor various biomarkers and disease treatment. Nevertheless, these electrostatic interaction-based vehicles inevitably have a tendency to diffuse away from mitochondrial matrix leading to the inaccurate detection results and unstable localization information. Thus, to enable a precise result with a high-fidelity imaging quality, mitochondria-immobilizable probes are attracting increasing attention due to their mitochondria fixable ability and activatable sensing capability without the influence during mitophagy and depolarization process. In this review, we summarily provided an insight overview into the design strategy of mitochondria-immobilizable probes that have been employed into microenvironment, bioreactive species and enzymes detection and other phototherapy applications. Additionally, we also highlighted the challenges and opportunities of mitochondria-anchored probes in the future. We expected that this review will prompt the development of novel mitochondria-fixable fluorescent probes for better unraveling the important pathological variation and processes in mitochondria as well as other organelles.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"529 ","pages":"Article 216456"},"PeriodicalIF":20.3,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142990747","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0