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Cover Feature: Carbon Dioxide and Epoxide Copolymerization Processes: Advances in Catalyst Design Over Decades (ChemCatChem 20/2025) 封面特色:二氧化碳和环氧化物共聚工艺:几十年来催化剂设计的进展(ChemCatChem 20/2025)
IF 3.9 3区 化学
ChemCatChem Pub Date : 2025-10-19 DOI: 10.1002/cctc.70378
Ishtiyaq Ahmad Wani, Mohsin Hassan, Gulzar A. Bhat
{"title":"Cover Feature: Carbon Dioxide and Epoxide Copolymerization Processes: Advances in Catalyst Design Over Decades (ChemCatChem 20/2025)","authors":"Ishtiyaq Ahmad Wani,&nbsp;Mohsin Hassan,&nbsp;Gulzar A. Bhat","doi":"10.1002/cctc.70378","DOIUrl":"https://doi.org/10.1002/cctc.70378","url":null,"abstract":"<p><b>The Cover Feature</b> portrays catalyst function in CO<sub>2</sub>/epoxide copolymerization. An open lock signifies catalyst accessibility, whereas a closed lock at the activation barrier symbolizes catalytic engagement. The radiant flash conveys the energy driving the process, with the stainless-steel reactor in the backdrop highlighting the experimental setting. At the core, the reaction mechanism captures product formation and catalyst regeneration, emphasizing the elegance of sustainable polymer synthesis. More information can be found in the Review by G. A. Bhat and co-workers (DOI: 10.1002/cctc.202500959).\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 20","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.70378","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145317722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Front Cover: Molecular Hybrid Catalysts in Ni/Photoredox C–N Coupling: Comparison of “in Batch” and “in Flow” Irradiation Techniques (ChemCatChem 20/2025) 封面:Ni/光氧化还原C-N偶联中的分子杂化催化剂:“分批”和“流动”辐照技术的比较(ChemCatChem 20/2025)
IF 3.9 3区 化学
ChemCatChem Pub Date : 2025-10-19 DOI: 10.1002/cctc.70377
Violetta A. Ionova, Dr. Elizaveta V. Ermakova, Kirill S. Zazerin, Dr. Anton S. Abel, Dr. Vladislav M. Korshunov, Dr. Ilya V. Taydakov, Dr. Vitaly A. Roznyatovsky, Dr. Alexei D. Averin, Prof. Irina P. Beletskaya
{"title":"Front Cover: Molecular Hybrid Catalysts in Ni/Photoredox C–N Coupling: Comparison of “in Batch” and “in Flow” Irradiation Techniques (ChemCatChem 20/2025)","authors":"Violetta A. Ionova,&nbsp;Dr. Elizaveta V. Ermakova,&nbsp;Kirill S. Zazerin,&nbsp;Dr. Anton S. Abel,&nbsp;Dr. Vladislav M. Korshunov,&nbsp;Dr. Ilya V. Taydakov,&nbsp;Dr. Vitaly A. Roznyatovsky,&nbsp;Dr. Alexei D. Averin,&nbsp;Prof. Irina P. Beletskaya","doi":"10.1002/cctc.70377","DOIUrl":"https://doi.org/10.1002/cctc.70377","url":null,"abstract":"<p><b>The Front Cover</b> illustrates the different efficiency of two photocatalysts in the Ni/photoredox amination of arylhalides. Photocatalysts are depicted as cats with different characters. When irradiated “in flow”, the more active, classical iridium photocatalyst produces nickel nanoparticles (NiNPs) and nickel black, which leads to deactivation of the catalytic system. The less active, hybrid ruthenium photocatalyst provides an optimal rate of nickel reduction; as a result, the catalytic system is more effective. More information can be found in the Research Article by V. A. Ionova, A. S. Abel, I. P. Beletskaya and co-workers (DOI: 10.1002/cctc.202500964).\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 20","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.70377","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145317684","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cover Feature: Trends in Oxygen Evolution Reaction Activity and Limiting Steps for Different Active Sites on Co3O4(001) (ChemCatChem 19/2025) 封面专题:Co3O4上不同活性位点的析氧反应活性趋势和限制步骤(001)(ChemCatChem 19/2025)
IF 3.9 3区 化学
ChemCatChem Pub Date : 2025-10-07 DOI: 10.1002/cctc.70354
Kapil Dhaka, Stephane Kenmoe, Achim Füngerlings, Rossitza Pentcheva, Kristina Tschulik, Kai S. Exner
{"title":"Cover Feature: Trends in Oxygen Evolution Reaction Activity and Limiting Steps for Different Active Sites on Co3O4(001) (ChemCatChem 19/2025)","authors":"Kapil Dhaka,&nbsp;Stephane Kenmoe,&nbsp;Achim Füngerlings,&nbsp;Rossitza Pentcheva,&nbsp;Kristina Tschulik,&nbsp;Kai S. Exner","doi":"10.1002/cctc.70354","DOIUrl":"https://doi.org/10.1002/cctc.70354","url":null,"abstract":"<p><b>The Cover Feature</b> shows Co<sub>3</sub>O<sub>4</sub>(001) for the oxygen evolution reaction. The lower part shows an OH-terminated crystallographic slab. Three zoom windows identify a tetrahedral site (Termination A), an octahedral site (Termination B), and a pseudo-octahedral motif on Termination B. Connectors map each inset to its surface location. The water in the background places the material in its operating environment. More information can be found in the Research Article by K. S. Exner and co-workers (DOI: 10.1002/cctc.202500992).\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 19","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.70354","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145237272","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Front Cover: Non-Noyori-Type Ruthenium-POP Pincer Catalysts in Ethanol Upgrading (ChemCatChem 19/2025) 封面:非noyori型钌- pop钳形催化剂在乙醇升级(ChemCatChem 19/2025)
IF 3.9 3区 化学
ChemCatChem Pub Date : 2025-10-07 DOI: 10.1002/cctc.70353
Alexander T. Nikol, Rosa Padilla, Martin Nielsen
{"title":"Front Cover: Non-Noyori-Type Ruthenium-POP Pincer Catalysts in Ethanol Upgrading (ChemCatChem 19/2025)","authors":"Alexander T. Nikol,&nbsp;Rosa Padilla,&nbsp;Martin Nielsen","doi":"10.1002/cctc.70353","DOIUrl":"https://doi.org/10.1002/cctc.70353","url":null,"abstract":"<p><b>The Front Cover</b> shows how, like an octopus, the catalyst works with many components simultaneously to reach its target. New RuPOP pincer catalysts upgrade ethanol to butan-1-ol. Adding to the mechanistic understanding of ethanol upgrading, M. Nielsen and co-workers show in their Research Article (DOI: 10.1002/cctc.202500700) that catalysts void of the Noyori unit are fully capable of catalysing the reaction; this contrasts with the common understanding in the community of the role of the catalyst.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 19","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.70353","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145237273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrofunctionalization of Polyunsaturated Hydrocarbons via Palladium(0) π-Lewis Base-Mediated Protonation 钯(0)π-路易斯碱介导的质子化多不饱和烃的加氢功能化
IF 3.9 3区 化学
ChemCatChem Pub Date : 2025-09-30 DOI: 10.1002/cctc.202501167
Meng-Qi Gan, Prof. Dr. Wei Du, Prof. Dr. Ying-Chun Chen
{"title":"Hydrofunctionalization of Polyunsaturated Hydrocarbons via Palladium(0) π-Lewis Base-Mediated Protonation","authors":"Meng-Qi Gan,&nbsp;Prof. Dr. Wei Du,&nbsp;Prof. Dr. Ying-Chun Chen","doi":"10.1002/cctc.202501167","DOIUrl":"https://doi.org/10.1002/cctc.202501167","url":null,"abstract":"<p>Palladium(0)-catalyzed asymmetric hydrofunctionalization of polyunsaturated hydrocarbons offers an atom-economic and highly stereoselective strategy for the synthesis of chiral molecules. Traditionally, these transformations are initiated via well-established mechanisms such as Pd─H insertion or ligand-to-ligand hydrogen transfer (LLHT). More recently, a distinct catalytic mode has emerged, wherein Pd<sup>0</sup> acts as a π-Lewis base catalyst to promote the outer-sphere protonation of diverse polyunsaturated hydrocarbons, such as 1,3-dienes, 1,3-enynes, and allenes, through η<sup>2</sup>-coordination and subsequent π-backdonation, emphasizing its unique mechanistic features and reaction patterns. Importantly, this approach has enabled the construction of a broad array of C─C, C─N, C─O, and C─P bonds with the resultant Pd<sup>II</sup> intermediates, generally in an enantioselective manner, offering efficient synthetic routes to chiral scaffolds and paving new avenues for asymmetric hydrofunctionalization.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 20","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145317643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Essential Logic and Facts Behind the Expansion of the Genetic Code: A Critical Assessment 遗传密码扩展背后的基本逻辑和事实:一个关键的评估
IF 3.9 3区 化学
ChemCatChem Pub Date : 2025-09-27 DOI: 10.1002/cctc.202500809
Huy Tran Le Luu, Dr. Hamid Reza Karbalaei-Heidari, Prof. Dr. Nediljko Budisa
{"title":"Essential Logic and Facts Behind the Expansion of the Genetic Code: A Critical Assessment","authors":"Huy Tran Le Luu,&nbsp;Dr. Hamid Reza Karbalaei-Heidari,&nbsp;Prof. Dr. Nediljko Budisa","doi":"10.1002/cctc.202500809","DOIUrl":"https://doi.org/10.1002/cctc.202500809","url":null,"abstract":"<p>The genetic code, long viewed as a frozen relic of early evolution, is now being systematically reprogrammed. This article examines the chemical, evolutionary, and technological foundations of its expansion, focusing on plasticity, codon architecture, and amino acid selection. The triplet codon structure reflects an evolutionary compromise between metabolic cost and information capacity, while proteins - the essential catalytic polymers - are built from α-L-amino acids derived from L-alanine. Introducing non-triplet codons or non-α amino acids would demand new metabolic pathways to supply precursors and energy for synthetic life. Current methods for incorporating noncanonical amino acids - stop codon suppression, sense codon reassignment, and quadruplet recoding - are transient and inefficient, consistent with the “ambiguous intermediate” model. Achieving stable expansion requires redesigning tRNA identity sets, improving ribosomal fidelity, rewiring metabolism, and potentially creating new foldamer scaffolds. Orthogonal translation systems and codon box deconstruction have become key tools, while permanent codon reassignment and engineered orthogonal systems mark the likely future. Core technologies include genome-scale codon swapping, directed evolution, cellular compartmentalization, and metabolic integration. Framed by evolutionary models such as Wong's coevolution theory, the WesthoffGrosjean model, and the Alanine World hypothesis, genetic code expansion emerges as a radical extension of life's chemical vocabulary.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 20","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145317698","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Harnessing Selectivity and Reactivity with Noncovalent Interactions in Molecular and Supramolecular Organo-Catalysis: A Computational Perspective 利用分子和超分子有机催化中非共价相互作用的选择性和反应性:计算视角
IF 3.9 3区 化学
ChemCatChem Pub Date : 2025-09-21 DOI: 10.1002/cctc.202501069
Sanat Kumar Mahapatra, Bijoy Ghosh, Dr. Lisa Roy
{"title":"Harnessing Selectivity and Reactivity with Noncovalent Interactions in Molecular and Supramolecular Organo-Catalysis: A Computational Perspective","authors":"Sanat Kumar Mahapatra,&nbsp;Bijoy Ghosh,&nbsp;Dr. Lisa Roy","doi":"10.1002/cctc.202501069","DOIUrl":"https://doi.org/10.1002/cctc.202501069","url":null,"abstract":"<p>Noncovalent interactions (NCIs), such as hydrogen bond, halogen bond, hydrophobic effect, π-stacking, etc., have been integral to biocatalysis, and their application to chemical catalysis has been accelerated over the past two decades. Although the underpinning of these relatively complex interactions is still a challenging foray, advancement in density functional theory and high-level calculations with wave-function-based quantum mechanical approaches have led to reliable interpretations of these weak interactions, with sufficient accuracy, to provide meaningful insights on their physical origins in molecular binding and chemical transformations. Such an in-depth understanding of electronic structure and reactivity offers possibilities for judicious engineering of these complex intra/intermolecular interactions to achieve enzyme-like optimum efficacy. In this study, we therefore focus on applications that demonstrate the advantages of rational manipulation of noncovalent interactions in molecular and supramolecular organocatalytic frameworks, pertaining to chiral catalysis, electron-donor acceptor events in photo-redox catalysis, or transformations within confined spaces of self-assembled capsules and cages. We emphasize on how quantum chemical data analysis provides reasonable indications of catalyst performance. We also highlight the ongoing challenges in computing reaction outcomes and discuss remedial approaches. We believe this overview would provide guiding principles for the successful designing of organo-catalysts using noncovalent weak interactions.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 20","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145317726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Front Cover: Selectivity and Microkinetic Insights on Ethylene Oligomerization over Ni Encapsulated in a Brønsted-less Hollow ZSM-5 Zeolite (ChemCatChem 18/2025) 封面:无br ø nstede中空ZSM-5沸石包封Ni的乙烯寡聚选择性和微动力学见解(ChemCatChem 18/2025)
IF 3.9 3区 化学
ChemCatChem Pub Date : 2025-09-19 DOI: 10.1002/cctc.70316
Omar Abed, Hend Omar Mohammed, Rushana Khairova, Idoia Hita, Vijay Velisoju, Natalia Morlanés, Mark Meijerink, Abdul-Hamid Emwas, Sergio Vernuccio, Pedro Castaño
{"title":"Front Cover: Selectivity and Microkinetic Insights on Ethylene Oligomerization over Ni Encapsulated in a Brønsted-less Hollow ZSM-5 Zeolite (ChemCatChem 18/2025)","authors":"Omar Abed,&nbsp;Hend Omar Mohammed,&nbsp;Rushana Khairova,&nbsp;Idoia Hita,&nbsp;Vijay Velisoju,&nbsp;Natalia Morlanés,&nbsp;Mark Meijerink,&nbsp;Abdul-Hamid Emwas,&nbsp;Sergio Vernuccio,&nbsp;Pedro Castaño","doi":"10.1002/cctc.70316","DOIUrl":"10.1002/cctc.70316","url":null,"abstract":"<p><b>The Front Cover</b> shows the encapsulation of Ni species inside hollow ZSM-5 zeolite cages, emphasizing their role in ethylene oligomerization. The hollow structure isolates Ni<sup>2+</sup> active sites while reducing Brønsted acidity, promoting selective dimerization through the Cossee-Arlman mechanism. This unique catalyst allows us to work in intrinsic conditions and develop a microkinetic model to understand the reaction mechanisms and rates. More information can be found in the Research Article by S. Vernuccio, P. Castano and co-workers (DOI: 10.1002/cctc.202500957).\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 18","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.70316","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145101948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Potential of Cations for Carbon Dioxide Electroreduction 二氧化碳电还原阳离子的电位
IF 3.9 3区 化学
ChemCatChem Pub Date : 2025-09-14 DOI: 10.1002/cctc.202500749
Dr. Federico Dattila, Prof. Núria López
{"title":"The Potential of Cations for Carbon Dioxide Electroreduction","authors":"Dr. Federico Dattila,&nbsp;Prof. Núria López","doi":"10.1002/cctc.202500749","DOIUrl":"https://doi.org/10.1002/cctc.202500749","url":null,"abstract":"<p>The electrochemical reduction of carbon dioxide (<span></span><math></math>) allows both the reduction of anthropogenic greenhouse gas emissions and the storage of intermittent renewable energy. While modeling studies have focused on the catalyst for at least two decades, recently the electrolyte–electrode interface has attracted significant attention, especially metal cations. In this Perspective, we propose simple rules to predict the extent of cation effects on <span></span><math></math> and water reduction depending on the transition metal catalyst, which we later extend to the case of alkali cation-induced surface dissolution. First, we highlight the difficulty of activating <span></span><math></math> and the crucial boost that cations provide for late transition metals. Then we re-interpret state-of-the-art results in terms of a unique descriptor, <i>i.e</i>., cation-induced electrostatic potential. Finally, we suggest a possible qualitative explanation for cation effects in cathodic dissolution and mention strategies to overcome cation-induced salt formation. The final Outlook lists directions that the modeling field should follow, <i>i.e</i>., either simplicity (Computational Cation Electrode) or complexity (Multiscale models), showing the potential of simulations toward the understanding of novel electrochemical processes (<i>i.e</i>., <span></span><math></math> in organic cations).</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 20","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.202500749","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145317032","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Catalytic Depolymerization of Plastics to Valuable Products 塑料催化解聚制有价产品
IF 3.9 3区 化学
ChemCatChem Pub Date : 2025-09-07 DOI: 10.1002/cctc.202500940
Zhao Li, Bing Liu, Teng He, Ping Chen
{"title":"Catalytic Depolymerization of Plastics to Valuable Products","authors":"Zhao Li,&nbsp;Bing Liu,&nbsp;Teng He,&nbsp;Ping Chen","doi":"10.1002/cctc.202500940","DOIUrl":"https://doi.org/10.1002/cctc.202500940","url":null,"abstract":"<p>Plastic products have become integral to every facet of human life. However, the environmental pollution caused by plastic wastes has been an unavoidable problem nowadays. Catalytic depolymerization of plastic waste provides a sustainable and economic alternative to solve the environmental issue. Herein, we summarize different types of catalytic depolymerization based on the compositions and structures of plastics. One catalog is the conversion of plastics into monomers, i.e., polyethylene terephthalate, nylon, and polycarbonate. Then, we focus on the conversion of polyolefins to gaseous and liquid hydrocarbons, value-added products. Selective oxidation of polystyrene and transition to functional polymers are also discussed. Ongoing challenges and opportunities are discussed at the end of this review, in order to offer guidance for the synthesis of valuable products from plastic wastes as new feedstocks.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 20","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145316788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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