Waste Disposal & Sustainable Energy最新文献

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Evolving dynamics of municipal solid waste management in India: a comprehensive review of status, challenges, opportunities and policy innovations 印度城市固体废物管理的演变动态:对现状、挑战、机遇和政策创新的全面审查
Waste Disposal & Sustainable Energy Pub Date : 2025-04-24 DOI: 10.1007/s42768-024-00220-3
Anitha Rengerla, Parthiban Angamuthu
{"title":"Evolving dynamics of municipal solid waste management in India: a comprehensive review of status, challenges, opportunities and policy innovations","authors":"Anitha Rengerla,&nbsp;Parthiban Angamuthu","doi":"10.1007/s42768-024-00220-3","DOIUrl":"10.1007/s42768-024-00220-3","url":null,"abstract":"<div><p>India’s rapid urbanization, population growth, and industrial expansion have intensified the challenges of solid waste management (SWM), making it a critical issue requiring urgent action. This paper examines the key challenges, trends, and opportunities in SWM, focusing on waste generation patterns, collection, transportation, treatment, and disposal methods in India. The major challenges identified include inefficient waste segregation, poor disposal practices, societal attitudes, and the unorganized informal sector. These problems, compounded by institutional weaknesses, inadequate funding, and slow adoption of technology, worsen the waste management crisis. Proper management of municipal solid waste (MSW) is essential for public health, environmental protection, and the achievement of sustainable development goals. This paper emphasizes the need for alternative waste management techniques, as nearly 90% of MSW is improperly disposed of in open dumps and landfills, posing significant risks to health and the environment. By forecasting future urbanization trends and their impact on waste generation, this paper evaluates effective treatment technologies for MSW in India. This study concludes with actionable recommendations and a unified framework, supported by data and case studies tailored to India’s socio-economic context, and aims at improving SWM practices and promoting long-term sustainability.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":807,"journal":{"name":"Waste Disposal & Sustainable Energy","volume":"7 1","pages":"127 - 150"},"PeriodicalIF":0.0,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143949716","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Leaching of calcium and heavy metals from fly ash by acetic acid and life cycle assessment of the leaching processes 粉煤灰中钙和重金属的醋酸浸出及其生命周期评价
Waste Disposal & Sustainable Energy Pub Date : 2025-04-13 DOI: 10.1007/s42768-025-00222-9
Weichao Kong, Yaqi Peng, Xinglei Zhao, Jiamin Ding, Qionghao Wang, Hengsheng Pan, Xin Xiao, Shengyong Lu
{"title":"Leaching of calcium and heavy metals from fly ash by acetic acid and life cycle assessment of the leaching processes","authors":"Weichao Kong,&nbsp;Yaqi Peng,&nbsp;Xinglei Zhao,&nbsp;Jiamin Ding,&nbsp;Qionghao Wang,&nbsp;Hengsheng Pan,&nbsp;Xin Xiao,&nbsp;Shengyong Lu","doi":"10.1007/s42768-025-00222-9","DOIUrl":"10.1007/s42768-025-00222-9","url":null,"abstract":"<div><p>Municipal solid waste incineration (MSWI) fly ash poses severe environmental risks because of the high potential of fly ash for heavy metal leaching. In this study, the leaching of fly ash by acetic acid was investigated. Key parameters, including time, acetic acid concentration, and fly ash type, were examined for their influence on calcium and heavy metal leaching. The physical and chemical changes in fly ash before and after leaching were analysed via the X-ray fluorescence (XRF), X-ray diffraction (XRD), and heavy metal leaching methods. The results showed that acetic acid effectively leached metals from different types of fly ash, as determined by the risk assessment code (RAC) and risk index (RI), and leaching with 0.25 mol/L acetic acid resulted in the lowest environmental hazard for fly ash. Moreover, adjusting the pH to below 11 during acid treatment, followed by washing with water, substantially reduced heavy metal leaching and increased the potential for safe resource recovery. A life cycle assessment (LCA) using the CML-2001 method revealed that the marine aquatic ecotoxicity potential had the largest environmental impact, accounting for 39.56% of the total index. These findings suggest that acetic acid leaching followed by water washing, improves the potential for repurposing of fly ash as a construction material.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":807,"journal":{"name":"Waste Disposal & Sustainable Energy","volume":"7 1","pages":"115 - 126"},"PeriodicalIF":0.0,"publicationDate":"2025-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143949426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Waste to wealth: silane-modified seaweed biopolymers for sustainable packaging material 废物转化财富:用于可持续包装材料的硅烷改性海藻生物聚合物
Waste Disposal & Sustainable Energy Pub Date : 2025-03-31 DOI: 10.1007/s42768-024-00218-x
C. M. Hazwan, C. S. Chang, A. H. Yusoff, N. F. Shoparwe, M. J. K. Mohammad
{"title":"Waste to wealth: silane-modified seaweed biopolymers for sustainable packaging material","authors":"C. M. Hazwan,&nbsp;C. S. Chang,&nbsp;A. H. Yusoff,&nbsp;N. F. Shoparwe,&nbsp;M. J. K. Mohammad","doi":"10.1007/s42768-024-00218-x","DOIUrl":"10.1007/s42768-024-00218-x","url":null,"abstract":"<div><p>In response to the growing environmental threat posed by plastic waste, this study developed hydrophobic biopolymer films from red seaweed (<i>Kappaphycus alvarezii</i>) as a sustainable alternative for packaging. The films were fabricated using a solvent-casting method, followed by surface treatment with triethoxymethylsilane to increase their hydrophobicity. Key metrics, including water solubility (reduced by 37.4%), moisture absorption capacity (decreased by 108.6%), and water vapor permeability (decreased by 65.4%), demonstrated significant improvements over untreated films. Fourier transform infrared (FT-IR) spectroscopy confirmed successful silane integration, whereas mechanical testing revealed increased tensile strength (up to 24.44 MPa) and Young’s modulus (183.41 MPa), with a moderate reduction in elongation at break. These findings indicate that silane-modified seaweed biopolymer films have strong potential as eco-friendly packaging solutions to mitigate plastic waste.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":807,"journal":{"name":"Waste Disposal & Sustainable Energy","volume":"7 1","pages":"99 - 114"},"PeriodicalIF":0.0,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143949572","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic effect of Ce doping and phosphorylation on optimizing the low temperature NH3-SCR activity of the spent V2O5-WO3/TiO2 catalyst Ce掺杂和磷酸化对优化废V2O5-WO3/TiO2催化剂低温NH3-SCR活性的协同效应
Waste Disposal & Sustainable Energy Pub Date : 2025-03-14 DOI: 10.1007/s42768-024-00217-y
Qiulin Wang, Xiongfei Qi, Haonan Wang, Minghui Tang, Shengyong Lu, Dunyu Liu, Jing Jin
{"title":"Synergistic effect of Ce doping and phosphorylation on optimizing the low temperature NH3-SCR activity of the spent V2O5-WO3/TiO2 catalyst","authors":"Qiulin Wang,&nbsp;Xiongfei Qi,&nbsp;Haonan Wang,&nbsp;Minghui Tang,&nbsp;Shengyong Lu,&nbsp;Dunyu Liu,&nbsp;Jing Jin","doi":"10.1007/s42768-024-00217-y","DOIUrl":"10.1007/s42768-024-00217-y","url":null,"abstract":"<div><p>The reactivation and subsequent reuse of exhausted selective catalytic reduction (SCR) catalysts has significant economic and environmental advantages. Water and acid washing along with thermal regeneration are commonly used to eliminate toxic substances from the catalyst surface, while these processes often result in the undesired loss of active components. In this research, an impregnation approach was adopted to replenish the depleted active constituents of the spent V<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> (VW/Ti) catalyst. Experimental investigations were conducted to evaluate the influence of Ce/P doping on both the SCR activity of this rejuvenated catalyst and its resistance to the detrimental effects of SO<sub>2</sub>/H<sub>2</sub>O exposure. The optimal performance is achieved with the Ce/P co-doped VW/Ti catalyst, demonstrating remarkable efficiency in removing nearly 100% of NO<sub><i>x</i></sub> across a broad range of temperatures from 150 to 450 °C. The incorporation of a proper content of Ce serves to increase the VO<sub><i>x</i></sub> surface density from a sub-monolayer state to a monolayer state and fosters the formation of more surface oxygen vacancies. This transformation positively contributes to enhancing both the catalytic activity and the resistance to SO<sub>2</sub>/H<sub>2</sub>O poisoning. Further treatment with H<sub>3</sub>PO<sub>4</sub>, although rendering the catalyst more susceptible to H<sub>2</sub>O, achieves a delicate balance between its surface acidity and redox capabilities. This optimized state not only enhances the catalyst's robustness but also further widens the active temperature window.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":807,"journal":{"name":"Waste Disposal & Sustainable Energy","volume":"7 1","pages":"73 - 84"},"PeriodicalIF":0.0,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s42768-024-00217-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143949446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The effect of CO2 sparging on high-solid acidogenic fermentation of food waste CO2喷淋对食物垃圾高固相产酸发酵的影响
Waste Disposal & Sustainable Energy Pub Date : 2025-03-14 DOI: 10.1007/s42768-024-00213-2
Chunmiao Liu, Wenjian Dong, Youli Yang, Wenyan Zhao, Wu Zeng, Yuriy Litti, Chao Liu, Binghua Yan
{"title":"The effect of CO2 sparging on high-solid acidogenic fermentation of food waste","authors":"Chunmiao Liu,&nbsp;Wenjian Dong,&nbsp;Youli Yang,&nbsp;Wenyan Zhao,&nbsp;Wu Zeng,&nbsp;Yuriy Litti,&nbsp;Chao Liu,&nbsp;Binghua Yan","doi":"10.1007/s42768-024-00213-2","DOIUrl":"10.1007/s42768-024-00213-2","url":null,"abstract":"<div><p>Carbon dioxide (CO<sub>2</sub>), a by-product of acidogenic fermentation, also acts as a reactant that affects carboxylic acid metabolism in reactors. However, the effect of headspace CO<sub>2</sub> in an acidogenic leach bed reactor (LBR) is unclear. In this study, high-solid acidogenic fermentation of food waste (FW) in LBRs with different fractions of CO<sub>2</sub> (CK: self-generated headspace, T1: 100% N<sub>2</sub>, T2: 30% CO<sub>2</sub> + 70% N<sub>2</sub>, and T3: 90% CO<sub>2</sub> + 10% N<sub>2</sub>) was performed. CO<sub>2</sub> sparging significantly increased the acidogenic performance of FW, with T3 showing the highest soluble product yield of 0.81 g chemical oxygen demand per 1 g volatile solid removal (gCOD/gVS<sub>removal</sub>). CO<sub>2</sub> sparging prolonged the fermentation of ethanol and lactic acid in T2 and T3 while it hindered the evolution of butyric and caproic acids. The relative abundance of the genus <i>Limosilobacillus</i> was enhanced by CO<sub>2</sub> sparging, reinforcing the ethanol and lactic acid metabolic pathways. However, sparging excessive CO<sub>2</sub> (≥30% CO<sub>2</sub>) inhibited the colonization of the genus <i>Clostridium</i> <i>sensu stricto</i> 12, which suppressed the reverse β pathway with butyric and caproic acids as the metabolites. This work provides valuable insights into the targeted production of carboxylic acids from the acidogenic fermentation of FW via CO<sub>2</sub> regulation.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":807,"journal":{"name":"Waste Disposal & Sustainable Energy","volume":"7 1","pages":"27 - 39"},"PeriodicalIF":0.0,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s42768-024-00213-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143949445","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable management strategies for low-organic matter sludge from a life cycle perspective 从生命周期角度看低有机质污泥的可持续管理策略
Waste Disposal & Sustainable Energy Pub Date : 2025-03-06 DOI: 10.1007/s42768-024-00219-w
Er Li, Xuejun Xiong, Hao Zhou, Binbin Liu, Peng Su, Zexu Chen, Jing Ai, Weijun Zhang
{"title":"Sustainable management strategies for low-organic matter sludge from a life cycle perspective","authors":"Er Li,&nbsp;Xuejun Xiong,&nbsp;Hao Zhou,&nbsp;Binbin Liu,&nbsp;Peng Su,&nbsp;Zexu Chen,&nbsp;Jing Ai,&nbsp;Weijun Zhang","doi":"10.1007/s42768-024-00219-w","DOIUrl":"10.1007/s42768-024-00219-w","url":null,"abstract":"<div><p>Sludge quality is a critical factor influencing the economic and environmental performance of treatment and disposal processes. In many regions, sludge is typically characterized by a low organic matter content. Consequently, the selection of sludge treatment and disposal routes should be tailored to the specific characteristics of sludge in each region, considering its dual attributes of “resource” and “pollution”, and aiming to maximize environmental, economic, and social benefits. Using the current sludge treatment and disposal situation in Wuhan, China, this study conducted a quantitative assessment of carbon emissions, environmental risks, and economic benefits associated with several existing treatment and disposal routes from a life cycle perspective. The results suggest that for sludge characteristics with low organic matter content, co-incineration in coal-fired power plants or cement production processes is the most favorable option. Specifically, when the organic matter content of the sludge falls below approximately 40%, cement production is deemed the preferred process, whereas co-incineration with coal is favored when the organic matter content exceeds 40% but is less than 50%. Owing to the relatively low organic matter and nutrient contents of sludge, optimization of existing anaerobic digestion and aerobic composting processes can be achieved through collaborative treatment with other solid wastes. Moreover, the prevailing carbon trading prices in the Chinese carbon market are relatively low and do not significantly impact the selection of current sludge treatment processes. This study aids in the development of sustainable management strategies for sludge characterized by low resource and pollution attributes in the future.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":807,"journal":{"name":"Waste Disposal & Sustainable Energy","volume":"7 1","pages":"85 - 98"},"PeriodicalIF":0.0,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143949552","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Heterogeneous Fenton-like catalysts of tetranitro iron phthalocyanine@Fe3O4@fly ash composites for fast decomposition of environmental contaminants 四硝基铁phthalocyanine@Fe3O4@粉煤灰复合材料快速分解环境污染物的非均相类fenton催化剂
Waste Disposal & Sustainable Energy Pub Date : 2025-03-03 DOI: 10.1007/s42768-024-00214-1
Dapeng Li, Peng Zhang, Yang Jin, Qing Li, Xinyuan Li, Ruirui Chang, Ruoxi Ma, Lin Yan, Suxiang Ge, Juntao Ma
{"title":"Heterogeneous Fenton-like catalysts of tetranitro iron phthalocyanine@Fe3O4@fly ash composites for fast decomposition of environmental contaminants","authors":"Dapeng Li,&nbsp;Peng Zhang,&nbsp;Yang Jin,&nbsp;Qing Li,&nbsp;Xinyuan Li,&nbsp;Ruirui Chang,&nbsp;Ruoxi Ma,&nbsp;Lin Yan,&nbsp;Suxiang Ge,&nbsp;Juntao Ma","doi":"10.1007/s42768-024-00214-1","DOIUrl":"10.1007/s42768-024-00214-1","url":null,"abstract":"<div><p>Using fly ash (FA) solid wastes as economical carriers to construct Fenton-like catalytic composites with additional functions is more practical than the use of a single catalyst. Understanding the structure and properties of catalysts and carriers is vital to improve performance. Tetranitro iron phthalocyanine (TNFePc) is a highly active molecular catalyst, whose immobilization and Fenton-like heterogeneous catalysis remain unclear. In this study, magnetically recyclable composites of TNFePc@Fe<sub>3</sub>O<sub>4</sub>@FA were successfully fabricated. Further, Fe<sub>3</sub>O<sub>4</sub> nanocrystals decorated on FA surfaces could be used as special functional layer for composite recycling and simultaneous in situ TNFePc synthesis. Peroxides of H<sub>2</sub>O<sub>2</sub>, KHSO<sub>5</sub>, and tert-butyl hydrogen could be effectively activated by composites and transformed into highly reactive radicals. Moreover, molecular oxygen could be activated as well. Model pollutants, methylene blue and oxytetracycline, could be synergistically degraded by the radical oxidation of superoxide, hydroxyl, alkoxy, and sulfate radicals and non-radical oxidation of high-valent iron-oxo species of TNPcFe<sup>IV</sup>=O. To the best of our knowledge, this is the first design of FA-based composites with dual function, Fenton-like heterogeneous catalysis and magnetic recyclability, for environmental decontamination.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":807,"journal":{"name":"Waste Disposal & Sustainable Energy","volume":"7 1","pages":"41 - 56"},"PeriodicalIF":0.0,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s42768-024-00214-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143949507","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel sustainable bio-composite for latent heat storage based on pomegranate peels and coconut oil 基于石榴皮和椰子油的新型可持续潜热储存生物复合材料
Waste Disposal & Sustainable Energy Pub Date : 2025-02-25 DOI: 10.1007/s42768-024-00216-z
Najoua Mekaddem, Hanen Nouri, Najet Mouguech, Samia Ben-Ali
{"title":"Novel sustainable bio-composite for latent heat storage based on pomegranate peels and coconut oil","authors":"Najoua Mekaddem,&nbsp;Hanen Nouri,&nbsp;Najet Mouguech,&nbsp;Samia Ben-Ali","doi":"10.1007/s42768-024-00216-z","DOIUrl":"10.1007/s42768-024-00216-z","url":null,"abstract":"<div><p>With rising energy demands and mounting environmental challenges, the push for sustainable energy systems has increased interest in developing advanced energy storage materials. This study aimed to create and evaluate the properties of a novel latent heat storage bio-composite (LHSB) using cost-effective and eco-friendly materials. A bio-based phase-change material (PCM), coconut oil, was added to a bio-support derived from pomegranate peels (PGPs) waste in two forms: raw peels (unwashed and washed) and biochar (physically and physicochemically activated carbon). Pellets of the raw PGPs and activated carbon were fabricated and subsequently impregnated with coconut oil under vacuum conditions. The highest loading capacities were observed to be 60.44% and 58.02% for washed PGPs and physicochemically activated carbon, respectively. Fourier transform infrared spectroscopy (FTIR) analysis corroborated the absence of chemical reactions between coconut oil and raw or modified PGPs. Scanning electron microscopy (SEM) micrographs provided visual evidence of successful coconut oil impregnation. Thermal gravimetric analysis (TGA) revealed that the operational temperatures of all synthesized PCM composites were considerably lower than their respective thermal degradation temperature limits. The encapsulation efficiencies were determined to be 47.69%, 61.62%, 43.97%, and 59.45% for unwashed peels, washed peels, physical biochar, and physicochemical biochar, respectively. Differential scanning calorimetry (DSC) analysis indicated that the coconut oil/unwashed peels composite exhibited the highest latent heat of melting and freezing, with values of 52.51 and 56.11 kJ/kg, respectively. These findings collectively demonstrate that the prepared LHSBs possess several desirable properties, including leak-proof nature, environmental friendliness, energy efficiency, and suitability for temperature regulation in diverse energy storage applications.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":807,"journal":{"name":"Waste Disposal & Sustainable Energy","volume":"7 1","pages":"57 - 71"},"PeriodicalIF":0.0,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143949613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bubbling-based method for direct carbon dioxide capture from ambient air using alkaline earth metal halides 利用碱土金属卤化物从环境空气中直接捕获二氧化碳的气泡法
Waste Disposal & Sustainable Energy Pub Date : 2025-02-14 DOI: 10.1007/s42768-024-00215-0
Tasawar Ali Chandio, Andriy Budnyk, Ali Dad Chandio
{"title":"Bubbling-based method for direct carbon dioxide capture from ambient air using alkaline earth metal halides","authors":"Tasawar Ali Chandio,&nbsp;Andriy Budnyk,&nbsp;Ali Dad Chandio","doi":"10.1007/s42768-024-00215-0","DOIUrl":"10.1007/s42768-024-00215-0","url":null,"abstract":"<div><p>The high level of CO<sub>2</sub> in the atmosphere is a major global challenge, with excessive emissions continuing into the foreseeable future. Effective methods for CO<sub>2</sub> capture and utilization are therefore necessary to achieve environmental sustainability. In this study, a novel method to capture CO<sub>2</sub> directly from ambient air is developed based on the bubbling of alkaline earth metal solutions, utilizing a simple do-it-yourself (DIY) device. In the bubbling process, ambient air passes through a diffuser to produce tiny air bubbles in an aqueous solution of alkaline earth metal halides (i.e., MCl<sub>2</sub>, where M=Mg<sup>2+</sup>, Ca<sup>2+</sup>, Sr<sup>2+</sup>, and Ba<sup>2+</sup>) and sodium hydroxide. During this process, dissolved metallic ions interact with CO<sub>2</sub> molecules confined in the tiny air bubbles, forming metal carbonates. The depletion of CO<sub>2</sub> in the air flux was monitored by operando Fourier-transform infrared (FTIR) spectroscopy. The CO<sub>2</sub> capture efficiency was found to be dependent on the type of metal halide, its concentration, and pH level. Specifically, 0.10 mol/L MCl<sub>2</sub> aqueous solutions at pH=11 demonstrated efficiencies ranging from 90% to 52% in the following order: Mg &gt; Ca &gt; Sr &gt; Ba, with MgCl<sub>2</sub> exhibiting superior performance in the studied pH range of 6–11. The formed carbonates were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM)-energy-dispersive spectroscopy (EDS), and FTIR. The high purity of the products enables their subsequent use in other applications, contributing to the sustainability of the proposed approach. In summary, this study compares the dynamics of CO<sub>2</sub> capture by MCl<sub>2</sub> in an alkaline medium and evaluates the efficiency of the process in yields of useful carbonates for various industrial applications.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":807,"journal":{"name":"Waste Disposal & Sustainable Energy","volume":"7 1","pages":"1 - 9"},"PeriodicalIF":0.0,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143949435","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Partial or total replacement of blast furnace slag with palm oil fuel ash in high-volume slag cement: hydration characteristics, compressive strength, and carbonation resistance 用棕榈油燃料灰分部分或全部替代高容量矿渣水泥中的高炉矿渣:水化特性、抗压强度和抗碳化性能
Waste Disposal & Sustainable Energy Pub Date : 2025-01-08 DOI: 10.1007/s42768-024-00212-3
Yukun Chen, Han-Seung Lee, Yang Sun
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