Huiyu Xiong, Xiaoxin Feng, Lei Gao, Liping Xiang, Dong Xie, Caiting Li, Weizhi Peng, Zhixiu Huang, Xuan Liu
{"title":"Outstanding Formaldehyde Abatement Performance and Preferable Resistance to SO2 and H2O over CrOx-CeOx Facilitated Hierarchical Porous Biochars Catalysts","authors":"Huiyu Xiong, Xiaoxin Feng, Lei Gao, Liping Xiang, Dong Xie, Caiting Li, Weizhi Peng, Zhixiu Huang, Xuan Liu","doi":"10.1007/s11270-025-07922-2","DOIUrl":"10.1007/s11270-025-07922-2","url":null,"abstract":"<div><p>A suite of CrCe oxides facilitated hierarchical porous biochars from walnut husks and rice straws (XCr<sub>y</sub>Ce<sub>1-y</sub>/WSAC) were readily synthesized for formaldehyde (HCHO) abatement. BET, XRD, XPS, SEM, H<sub>2</sub>-TPR, TG-DTG, and in situ DRIFTS were adopted to disclose their physicochemical properties and the elimination mechanism of HCHO. 18%Cr<sub>0.5</sub>Ce<sub>0.5</sub>/WSAC exhibited splendid HCHO abatement efficiency (99.2%) at 280 °C. The effects of O<sub>2</sub>, SO<sub>2</sub>, H<sub>2</sub>O for HCHO abatement over 18%Cr<sub>0.5</sub>Ce<sub>0.5</sub>/WSAC were trialed, and the strangulation influences of SO<sub>2</sub> counteracted the furtherance effect of O<sub>2</sub> to some extent, which was relieved by the facilitation of H<sub>2</sub>O. CrO<sub>x</sub>-CeO<sub>x</sub> co-facilitated WSAC presented better performance than Cr or Ce oxide separately facilitated WSACs, which was associated with the redox cycle of Cr<sup>6+</sup> + Ce<sup>3+</sup><b> ↔ </b>Cr<sup>3+</sup> + Ce<sup>4+</sup>, resulting in higher redox capability, better dispersion of active ingredient, more oxygen vacancies and superior active oxygen mobility. Furthermore, the hierarchical porous support accelerated the diffusion and mass transfer of reactants and intermediates. Noteworthily, the effects of CrO<sub>x</sub>-CeO<sub>x</sub> and the hierarchical porous structure of the support on the tolerance to SO<sub>2</sub> and H<sub>2</sub>O were deeply and systematically investigated. Ultimately, 18%Cr<sub>0.5</sub>Ce<sub>0.5</sub>/WSAC emerged desirable prospects in practical applications thanks to splendid catalytic performance and satisfactory resistance to SO<sub>2</sub> and H<sub>2</sub>O.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 5","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740660","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Enhanced Adsorption of Methylene Blue Using Aminotrimethylphosphonate-Grafted Hydroxyapatite Derived from Moroccan Natural Phosphate: A Sustainable Approach for Wastewater Treatment","authors":"Sarah Saoiabi, Souhayla Latifi, Sanaâ Saoiabi","doi":"10.1007/s11270-025-07925-z","DOIUrl":"10.1007/s11270-025-07925-z","url":null,"abstract":"<div><p>This study explores the enhancement of methylene blue (MB) adsorption from aqueous solutions using hydroxyapatite (HAp) grafted with aminotrimethylphosphonate (AMP). Leveraging Morocco's natural phosphate resources, HAp was synthesized and modified with varying concentrations of AMP (5%, 10%, 15%, and 20%) to evaluate its adsorption performance. Dynamic Light Scattering (DLS) analysis indicated a reduction in particle size with increasing AMP content, which improved the dispersion and stability of the HAp particles. Zeta potential measurements revealed that AMP grafting reduced the negative surface charge, particularly in acidic conditions, favoring the adsorption of the cationic MB molecules. X-ray diffraction (XRD) patterns showed increased crystallinity in the AMP-grafted composites, which provided a more stable adsorbent structure. Infrared spectroscopy (FTIR) confirmed successful AMP incorporation, leading to changes in the vibrational modes of key functional groups. The equilibrium adsorption capacity (qe) of the composites increased with AMP content, with the HAp + 20% AMP composite achieving the highest qe of approximately 0.0854 mg/g, demonstrating the effectiveness of AMP grafting in enhancing the adsorption properties of HAp. These findings suggest that AMP-grafted HAp composites are highly efficient adsorbents for methylene blue removal, offering a sustainable solution for wastewater treatment.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 5","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pradeep Kumkar, Chandani R. Verma, Martin Lexa, Sachin M. Gosavi, Sanjay S. Kharat, Lukáš Kalous
{"title":"Threatening the Near–Threatened: Microplastics in Jerdon's Catfish (Mystus malabaricus), Endemic to the Global Biodiversity Hotspot, the Western Ghats of India","authors":"Pradeep Kumkar, Chandani R. Verma, Martin Lexa, Sachin M. Gosavi, Sanjay S. Kharat, Lukáš Kalous","doi":"10.1007/s11270-025-07914-2","DOIUrl":"10.1007/s11270-025-07914-2","url":null,"abstract":"<div><p>Microplastic contamination in freshwater fish poses a significant global threat but remains underexplored in biodiversity hotspots like the Western Ghats of India, where rivers exhibit elevated microplastic levels. This study investigates microplastic contamination in the endemic and near-threatened bagrid catfish, <i>Mystus malabaricus</i>, sampled from the Ulhas River, Maharashtra. Microplastics were isolated and analysed for physical attributes (size, shape, colour) using light microscopy and for chemical composition through µ-Raman spectroscopy. Our findings indicate that 50% of the catfish contained microplastics, averaging 2.54 ± 0.41 particles per fish, with five morphotypes identified, predominantly transparent and grey films made of polyethylene (89.3%) and polypropylene (10.7%). The observed characteristics of microplastics reflect a direct relationship to secondary anthropogenic sources, revealing inadequacies in regional waste management infrastructure. This contamination may adversely affect fish development and pose risks to fish consumers and artisanal fisheries. We propose mitigation strategies based on the findings of this and previous studies on the Ulhas River.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 5","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Anna Casari, Loris Tonidandel, Guido Zolezzi, Alberto Bellin, Paolo Negri, Alice Barbero, Roberto Larcher
{"title":"Investigating the Role of Sampler Compartments Employed by POCIS Devices in Pesticides Sampling","authors":"Anna Casari, Loris Tonidandel, Guido Zolezzi, Alberto Bellin, Paolo Negri, Alice Barbero, Roberto Larcher","doi":"10.1007/s11270-025-07901-7","DOIUrl":"10.1007/s11270-025-07901-7","url":null,"abstract":"<div><p>Polar Organic Chemical Integrative Sampler (POCIS) is a passive sampler employed to monitor organic compounds in water (e.g. pesticides, drugs, etc.); in our case consists of a receiving phase, Oasis HLB, enclosed between two polyethersulfone (PES) membranes. In most cases, the analytes were extracted only from the receiving phase but recent works show that some compounds were also adsorbed on the PES membranes. Many aspects on the membrane behaviour are still unknown and this work aims to fill some knowledge gaps exploring the capability of PES membranes to adsorb pesticides. From experiments conducted in a controlled environment, it was seen that more than half of the investigated compounds were adsorbed more effectively by the PES membrane than the Oasis HLB phase. The affinity of these pesticides towards the two sampler compartments, can be explained only partially by the polarity of the compounds. However, a significant adsorption of the most hydrophobic compounds by the PES membrane was noticed, especially for values of LogKow higher than 4. From these experiments, it was possible to calibrate POCIS by comparing the pesticide concentration in water with the amount adsorbed by the two sampler compartments over time, with the estimation of two values of sampling rate for each pesticide (<i>R</i><sub><i>S,HLB</i></sub> and <i>R</i><sub><i>S,PES</i></sub>). It was seen that the combination of the two adsorbent substrates allowed to intercept almost all the studied compounds satisfactorily and this behaviour was also confirmed by a field sampling campaign.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 5","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11270-025-07901-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740659","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A Systematic Review on the Application of Bacteria-Based Bioflocculants in Wastewater Treatment: Trends and Future Advances","authors":"Emadeldeen Ahmed Elrasoul, Ee Ling Yong","doi":"10.1007/s11270-025-07902-6","DOIUrl":"10.1007/s11270-025-07902-6","url":null,"abstract":"<div><p>Bioflocculants, a sustainable alternative to conventional metal-based flocculants, are gaining attention in wastewater treatment. Following the PRISMA framework, this paper reviews 60 studies to provide comprehensive insights into bioflocculant production. The bacterial species used, their extraction sources, growth mediums, and the factors influencing bioflocculant flocculating activity were discussed. The findings highlighted that industrial-scale application of bioflocculant requires careful control of external factors and optimal operating parameters, such as pH, carbon or nitrogen sources, and cation addition. The interplay between these factors, along with the bioflocculant source, mixing process, and wastewater strength, determine the large-scale applicability of bioflocculant. The main challenge for researchers is providing cost-effective and optimal production conditions to yield the best flocculating activity. This paper aims to guide future research in overcoming these challenges, thereby advancing the field of bioflocculant production and contributing to sustainable wastewater treatment solutions.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 5","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of Thermally Stable Psyllium Husk/4,4´-Diphenylmethane Diisocyanate-Based Polyurethanes for Effective and Selective Removal of Cationic Dyes","authors":"Kriti, Kiran Kumar, Sunita Ranote, Ghanshyam S. Chauhan, Sandeep Chauhan, Sapna Sharma","doi":"10.1007/s11270-025-07913-3","DOIUrl":"10.1007/s11270-025-07913-3","url":null,"abstract":"<div><p>Dye-laden toxic wastewater generated from textile industries creates a huge problem of toxicity and disposal. Novel research involves biopolymer-based adsorption as the most commonly used remedial method. Herein, a novel psyllium-based polyurethane foam (Psy-PUF) adsorbent was synthesized through polyaddition reaction with 4,4´-Diphenylmethane Diisocyanate (MDI) in the presence of 1,4-diazabicyclo (2.2.2) octane (DABCO 33-LV, as the catalyst), triethanolamine (as the co-catalyst), silicone oil (as a surfactant), and orange peel powder (as a filler) to eliminate dye pollutants. Psy-PUF was characterized using several techniques. The TGA (Thermogravimetric analysis) showed the significant thermal stability of the synthesized Psy-PUF with the final decomposition temperature of 841 °C showing a tremendous increase compared to 601.9 °C for untreated psyllium. Psy-PUF was studied as an adsorbent in binary dye mixtures including cationic and anionic dyes, and the best-adsorbed dyes i.e., malachite green (MG) and crystal violet (CV) were studied. Psy-PUF demonstrated rapid adsorption with 56.38% (MG) and 61.02% (CV) adsorbed only within 20 min, reaching 96.04% and 93.58% for MG and CV, respectively, within 60 min. The adsorption of MG and CV followed pseudo-second-order kinetics with respective R<sup>2</sup> values of 0.98747 and 0.98685. Moreover, the adsorption behavior of Psy-PUF aligned with the Langmuir isotherm, indicating <i>q</i><sub><i>m</i></sub> of 229.35 mg. g<sup>−1</sup> for MG and 223.71 mg. g<sup>−1</sup> for CV. Psy-PUF exhibited remarkable regeneration for up to ten cycles with cumulative adsorption capacities (<i>q</i><sub><i>max</i></sub><i>)</i> of 801.4 mg. g<sup>−1</sup> and 760.3 mg. g<sup>−1</sup> for MG and CV. Thus Psy-PUF is an economically viable, eco-friendly, biodegradable, and recyclable adsorbent, for removing harmful cationic dyes.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 5","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740719","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sai Liu, Wei Song, Xueli Zhang, Xing Chen, Jun Ding, Yu Xia
{"title":"Understanding the Impact of New Pollutant Perfluorooctanoic Acid On the Enhanced Biological Phosphorus Removal Processes","authors":"Sai Liu, Wei Song, Xueli Zhang, Xing Chen, Jun Ding, Yu Xia","doi":"10.1007/s11270-025-07898-z","DOIUrl":"10.1007/s11270-025-07898-z","url":null,"abstract":"<div><p>Perfluorooctanoic acid (PFOA), an emerging contaminant, is frequently detected in wastewater treatment plants. However, the impact of PFOA on enhanced biological phosphorus removal (EBPR) processes in wastewater treatment and the associated mechanisms remain poorly characterized. To address this knowledge gap, a laboratory-scale sequencing batch reactor (SBR) was operated under mesophilic conditions to systematically evaluate the effects of PFOA on EBPR performance, sludge properties, and microbial metabolic functions. The results demonstrated that low PFOA concentrations (≤ 0.5 mg/L) enhanced the removal of chemical oxygen demand (COD) and nutrients. However, at concentrations exceeding 0.5 mg/L, COD and phosphate removal efficiencies declined markedly, whereas ammonia nitrogen removal was not significantly inhibited. High concentrations of PFOA decreased the metabolic transformation of COD and phosphate during the typical cycle, reduced the synthesis of intracellular polymer polyhydroxyalkanoates (PHA), but stimulated glycogen metabolism. High concentrations of PFOA decreased the specific oxygen uptake rate but increased the release of reactive oxygen species (ROS) and lactate dehydrogenase (LDH), collectively impairing microbial metabolic activity. These findings advance the understanding of PFOA’s environmental fate in wastewater systems and offer novel mechanistic insights into its interference with EBPR performance.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 5","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740723","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abolfazl Jamali, Mohammad Ebrahim Ramazani, Arezoo Nejaei, Omid Rafieyan
{"title":"Monitoring of Pollutants in Surface Water with Laboratory Analysis and Satellite Image Between 2019 and 2024, Kichik Chai River, Iran","authors":"Abolfazl Jamali, Mohammad Ebrahim Ramazani, Arezoo Nejaei, Omid Rafieyan","doi":"10.1007/s11270-025-07808-3","DOIUrl":"10.1007/s11270-025-07808-3","url":null,"abstract":"<div><p>This research, conducted between 2019 and 2024, aims to analyze the changing process in the water quality parameters of the Kichik Chai River. It employs laboratory analysis methods, interprets satellite images using ENVI software, and simulates conditions using the QUAL2Kw model to determine compliance with water quality standards. Three methods, namely the water quality index, Piper, and Scholler, were employed to assess the water quality. The investigation into heavy metal concentrations in the Kichik Chai River revealed an increase in pH, total suspended solids (TSS), and total dissolved solids (TDS), along with a slight decrease in turbidity and biochemical oxygen demand (BOD). In the 2024 satellite images, the highest and lowest errors were recorded at stations 4 and 2, respectively, while in the 2019 satellite images, the highest errors were at stations 2, 1, and 4. Furthermore, an analysis of actual pollutant sources in the Kichik Chai River watershed using taxonomy methods across six sampling stations and examining fifteen effective parameters indicated that the locations of the waste material dump, copper production complex, and mine acid water drainage had pollution potential scores of 0.862, 0.726, and 0.705, respectively.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 5","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Mariculture Sludge Modifies Archaeal Community Diversity, Reduces Archaeal Variability, and Enhances Nitrogen Cycling Capacity in Paddy Soil","authors":"Junchi Pan, Yajing Li, Yuehang Hu, Qiongfen Qiu","doi":"10.1007/s11270-025-07906-2","DOIUrl":"10.1007/s11270-025-07906-2","url":null,"abstract":"<div><p>Given the increasing nitrogen losses in paddy soils associated with rice cultivation, this study employed 16S rRNA amplicon sequencing to investigate the effects of different concentrations of mariculture sludge on archaeal communities and nitrogen-cycling microorganisms. Mariculture sludge can enhance the α diversity of archaeal communities in paddy soil. The relative abundances of numerous archaeal taxa, such as Euryarchaeota and Woesearchaeota, were markedly higher in soils with the application of mariculture sludge than in those without mariculture sludge treatment, and the taxonomical distribution was significantly correlated with salinity, pH, NH<sub>4</sub><sup>+</sup>, PO<sub>4</sub><sup>3−</sup> and TN. In terms of microecology, the application of mariculture sludge to paddy soil influenced the assembly of the archaeal community through deterministic processes; the average variation degree of the archaeal community decreased; and the predicted archaeal functions shifted toward nucleoside and nucleotide synthesis, amino acid synthesis, and carbohydrate synthesis. Mariculture sludge application resulted in a significant increase in the abundance of the <i>mcrA</i> gene (methane production) and decreases in the abundance of the <i>amoA</i>, <i>pmoA</i>, and <i>mmoX</i> genes (methane metabolism). Overall, mariculture sludge application enriched the archaeal community, reduced archaeal community variability and increased the potential for nitrogen cycling and biosynthesis in paddy soils. These results offer insights into the potential of mariculture sludge as an organic amendment for sustainable soil management, although further study is needed to assess its long-term effects on greenhouse gas emissions in paddy soil ecosystems.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 5","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740781","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fatima Batool, Faisal Mahmood, Ans Mahmood, Tanvir Shahzad, Sabir Hussain
{"title":"Treatment of Textile Wastewater using Biogenic and Chemically Synthesized Iron Oxide Nanoparticles (FeO-NPs) and their Impact on Seed Germination of Vigna radiata","authors":"Fatima Batool, Faisal Mahmood, Ans Mahmood, Tanvir Shahzad, Sabir Hussain","doi":"10.1007/s11270-025-07937-9","DOIUrl":"10.1007/s11270-025-07937-9","url":null,"abstract":"<div><p>Water and soil receiving discharges from textile industries can have a high concentration of toxic dyes, heavy metals, and other harmful pollutants. Treating that effluent prior to discharge can enhance water quality for agricultural purposes and improve crop nutrition while lowering environmental and human health risks. This study focused on the synthesis of biogenic iron oxide nanoparticles (FeO(B)-NPs) using <i>Conocarpus erectus</i> leaf extract and comparing their catalytic efficiency with chemically synthesized iron oxide nanoparticles (FeO(C)-NPs). The UV–Vis spectroscopy showed the absorption peaks of FeO(B)-NPs and FeO(C)-NPs at 273 and 356 nm, respectively. The FT-IR analysis confirmed the attachment of various functional groups on the surface of nanomaterials. The SEM images determined the irregular granular and spherical shape of both FeO-NPs. While XRD analysis confirmed the typical cubic-like crystalline nature of particles with an average size of 29 nm and 43 nm for FeO(B)-NPs and FeO(C)-NPs, respectively. Both FeO-NPs were further used for treatment of synthetic and textile wastewater, significantly reducing TDS, color intensity, sulfate, phosphate, COD and Cr-concentration. However, FeO(B)-NPs showed higher effectiveness than FeO(C)-NPs being more efficient at reducing the impact of wastewater by increasing the photosynthetic pigments (Chl a, Chl b, Total Chl, and Carotenoids) and germination parameters (50% Seed Germination, Germination%, MET, EI and CUE) of <i>Vigna radiata</i>. FeO(B)-NPs enhanced the germination by 42% and chlorophyll content by 89%, as compared to FeO(C)-NPs which resulted an increase of 14% and 86%, respectively, under textile effluent stress. The findings of current study suggest that biosynthesized FeO-NPs have the potential to offer a green solution for the treatment of textile wastewater while reducing the harmful impact of wastewater on seed germination of <i>Vigna radiata</i>, thus promoting sustainable plant growth and increasing crop yield.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 5","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740923","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}