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Mathematical Modeling Using Full Factorial Design Applied in the Adsorption of Dye Basic Blue 9 from Synthetic Aqueous Solutions onto Oryza Sativa Husk-Derived Nano-Silica-Smectic Clay Composite
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-12-11 DOI: 10.1007/s11270-024-07676-3
Jean Marie Kepdieu, Gustave Tchanang, Jacques Romain Njimou, Cyprien Joel Ekani, Chantale Njiomou Djangang, Sanda Andrada Maicaneanu, Diego Rosso
{"title":"Mathematical Modeling Using Full Factorial Design Applied in the Adsorption of Dye Basic Blue 9 from Synthetic Aqueous Solutions onto Oryza Sativa Husk-Derived Nano-Silica-Smectic Clay Composite","authors":"Jean Marie Kepdieu,&nbsp;Gustave Tchanang,&nbsp;Jacques Romain Njimou,&nbsp;Cyprien Joel Ekani,&nbsp;Chantale Njiomou Djangang,&nbsp;Sanda Andrada Maicaneanu,&nbsp;Diego Rosso","doi":"10.1007/s11270-024-07676-3","DOIUrl":"10.1007/s11270-024-07676-3","url":null,"abstract":"<div><p>This study focuses on utilizing Oryza sativa husk (rice husk) to produce a nanosilica-doped smectitic clay (Os-Sm) for the adsorption of Basic Blue 9 from aqueous solutions. Response surface methodology was employed to investigate the impact of dye concentration (10—30 mg/L), initial pH (8—11), and contact time (0—100 min). The regression model exhibited a remarkable predictive capability, accounting for over 99% of the targeted response variation within the specified ranges of the factors (R<sup>2</sup> = 99.98%) with a 95% confidence level. The analysis of variance confirmed the significance and accuracy of the mathematical model, with F-values (1539.08 &gt; &gt; 1) and p-values (&lt; 0.05) indicating the statistical significance of almost all factors within the studied ranges. These findings were supported by factorial, surfaces, and contours plots. Furthermore, the pseudo-second-order kinetic and Langmuir models demonstrated excellent fitting to the experimental data, with determination coefficients of 0.976 and 0.965, respectively. At optimal conditions (30 mg/L, pH 11, t &gt; 50 min, and adsorbent dose of 0.5 g/L), approximately 96.33% of the dye was successfully removed. Os-Sm emerges as a promising and efficient alternative for Basic Blue 9 removal in aqueous solutions.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142798322","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel Quaternary Ammonium Functionalized Cellulosic Materials for Nitrate Adsorption from Polluted Waters
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-12-11 DOI: 10.1007/s11270-024-07677-2
Jakub Maculewicz, Aisling D. O’Sullivan, David Barker, Kien Tat Wai, Sumaira Basharat, Ricardo Bello-Mendoza
{"title":"Novel Quaternary Ammonium Functionalized Cellulosic Materials for Nitrate Adsorption from Polluted Waters","authors":"Jakub Maculewicz,&nbsp;Aisling D. O’Sullivan,&nbsp;David Barker,&nbsp;Kien Tat Wai,&nbsp;Sumaira Basharat,&nbsp;Ricardo Bello-Mendoza","doi":"10.1007/s11270-024-07677-2","DOIUrl":"10.1007/s11270-024-07677-2","url":null,"abstract":"<p>This study investigated the ability of waste-derived cellulose materials to remove nitrate from water through adsorption processes. First, a variety of cellulosic waste materials were screened to quantify their adsorptive ability to remove nutrients from water. Due to the low adsorption capacity and frequent leaching of nitrate observed in raw materials, quaternary ammonium functionalization was then employed. Materials were functionalized by adding cationic groups to the biowaste materials to form novel ion exchange adsorbents containing naturally derived biopolymers and/or whole natural fibres with improved nitrate binding capacity. Results revealed that adsorbents originating from high cellulose waste materials can be successfully used to remove nitrate from water. Significant nitrate was removed by functionalized flax and cellulose, of comparable treatment efficiency to a commercial polystyrene-based material used in drinking water filters. Adsorption of nitrate on flax and cellulose based materials was best characterized by the Sips isotherm, reaching maximum sorption capacity of 234.8 and 240.5 mg/g, respectively. This suggests that the interactions between adsorbents and nitrate are more complex than ion exchange alone and can involve other mechanisms, such as dipole/ion force. The kinetics of NO<sub>3</sub><sup>-</sup> adsorption was described well by the pseudo-first order model. The ability to remove nitrate via adsorption from polluted drinking water and freshwaters by re-purposing waste materials aligns strongly with sustainability principles and supports several sustainable development goals (SDGs) including clean water and sanitation.</p>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11270-024-07677-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142798337","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Low-nanosized Broad Spectrum Photocatalyst for Treatment of Pharmaceutical and Industrial Pollutants: New Ce0.97Fe0.03Zn0.04O2 Composition
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-12-11 DOI: 10.1007/s11270-024-07680-7
Nabil Al-Zaqri
{"title":"A Low-nanosized Broad Spectrum Photocatalyst for Treatment of Pharmaceutical and Industrial Pollutants: New Ce0.97Fe0.03Zn0.04O2 Composition","authors":"Nabil Al-Zaqri","doi":"10.1007/s11270-024-07680-7","DOIUrl":"10.1007/s11270-024-07680-7","url":null,"abstract":"<div><p>Nanostructured Fe/Zn codoped CeO<sub>2</sub> photocatalyst revealed high visible light mineralization efficiencies for removal of pharmaceutical ciprofloxacin and industrial reactive yellow 145 dye. Nanocrystalline pure and Fe/Zn codoped CeO<sub>2</sub> (Ce<sub>0.93</sub>Fe<sub>0.03</sub>Zn<sub>0.04</sub>O<sub>2</sub>) powders have been synthesized by a simple coprecipitation manner. The X-ray crystal structure analysis proved the formation of face-centered cubic CeO<sub>2</sub> phase with low nano-crystallite sizes (7–9 nm). The transmission electron microscope (TEM) images of the two samples illustrated that the powders are composed of very small nano-sized particles have approximately spherical view. All particles of both powders have nearly homogenous size and shape. The Kubelka–Munk plot demonstrated that the energy band gap of the synthesized CeO<sub>2</sub> nanopowder was 3.18 eV. The modification of CeO<sub>2</sub> nanopowder by Fe/Zn ions improved the visible light absorption and also reduced its band gap energy to 2.52 eV. Environmentally, 98% and 96% removal efficiencies for reactive yellow 145 dye and medical ciprofloxacin antibiotic were realized by Fe/Zn codoped CeO<sub>2</sub> nanocatalyst. The perfect mineralization, good reusability and high elimination of different concentrations (10–30 ppm) encourages the use of this nanocatalyst for wastewater treatment. The radical trapping tests verified that the superoxide and hydroxyl radicals are the energetic species during the photodegradation reaction of pharmaceutical ciprofloxacin and industrial reactive yellow 145 dye.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142798323","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Application of Magnetically Recoverable Biochar Amended Zirconium Adsorbent Composite for Enhanced As(III, V) Removal from Aqueous Solutions
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-12-10 DOI: 10.1007/s11270-024-07697-y
Imdad Ullah, Shams Ali Baig, Harsa Zaheer, Dilawar Farhan Shams, Hamida Bibi, Waliullah Khan, Xinhua Xu, Muhammad Danish
{"title":"Application of Magnetically Recoverable Biochar Amended Zirconium Adsorbent Composite for Enhanced As(III, V) Removal from Aqueous Solutions","authors":"Imdad Ullah,&nbsp;Shams Ali Baig,&nbsp;Harsa Zaheer,&nbsp;Dilawar Farhan Shams,&nbsp;Hamida Bibi,&nbsp;Waliullah Khan,&nbsp;Xinhua Xu,&nbsp;Muhammad Danish","doi":"10.1007/s11270-024-07697-y","DOIUrl":"10.1007/s11270-024-07697-y","url":null,"abstract":"<p>The occurrence of elevated levels of arsenic in water sources is a global health concern and necessitates implementing sustainable removal technologies. The utilization of biochar composite for treating arsenic contaminated water has been reported as a promising technique in recent years. In the present study, corncob biochar was magnetically modified and amended with zirconium (CCB@Fe<sub>3</sub>O<sub>4</sub>-Zr with Zr to Fe<sub>3</sub>O<sub>4</sub> molar ratio of 1:1, and 1:5) for the purposively removal of As(III) and As(V) from aqueous solutions. Characterization analyses and factors affecting the adsorption, such as adsorbent dose, initial As(III) and As(V) concentration, pH, temperature, contact time, and co-existing anions were investigated. Results demonstrated that the removal of As(III) and As(V) were about 81 and 99%, respectively with the initial concentration of 80 mg/L. Lower solution pH favored As(V) removal and it slightly affected As(III) adsorption in pH range (5.0 to 9.0) due to the presence of neutral As(III) form. Also, increased solution temperature promoted As(V) removal performance demonstrating of an endothermic nature of the adsorption process. Characterization analyses confirmed of the successful magnetization of biochar and zirconium amendment with 7.8 Am<sup>2</sup>/kg saturation magnetization potential and thermally super stable (&gt; 60% residual mass). The weight percentage of Fe and Zr were 12.23 and 7.54% in CCB@Fe<sub>3</sub>O<sub>4</sub>-Zr, which revealed the sufficient agglomeration of the surface modified components on biochar and the post-adsorption tests revealed arsenic adsorption. Findings from the present study suggested that the adsorbent composite could be a precise and promising alternative for enhanced As(III) and As(V) removal from contaminated water.</p>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142798473","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pollution Characteristics and Risk Assessment of Heavy Metals in Rural Road Dust for Preschool Children in Baiyin, a Long-Term Polluted Area of NW China
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-12-10 DOI: 10.1007/s11270-024-07694-1
Huilin Gu, Ziyi Wang, Jinglei Zhang, Shun Chen, Yue Du, Ting Yu, Cong Yuan, Shiwei Ai
{"title":"Pollution Characteristics and Risk Assessment of Heavy Metals in Rural Road Dust for Preschool Children in Baiyin, a Long-Term Polluted Area of NW China","authors":"Huilin Gu,&nbsp;Ziyi Wang,&nbsp;Jinglei Zhang,&nbsp;Shun Chen,&nbsp;Yue Du,&nbsp;Ting Yu,&nbsp;Cong Yuan,&nbsp;Shiwei Ai","doi":"10.1007/s11270-024-07694-1","DOIUrl":"10.1007/s11270-024-07694-1","url":null,"abstract":"<div><p>In this study, the pollution characteristics and risks of heavy metals in road dust from long-term polluted areas were investigated. Fifteen road dust samples were collected from five villages along the Dongdagou Stream in Baiyin, China. All samples were tested for heavy metals using an inductively coupled plasma optical emission spectrometer (ICP-OES). Results showed that the concentrations of Cr, Mn, Ni, Cu, Zn, Cd, Pb, As, and Hg in the samples were 67.59 ± 6.01, 414.10 ± 31.62, 171.75 ± 25.92, 91.36 ± 118.56, 369.92 ± 504.87, 2.94 ± 4.37, 71.27 ± 76.56, 6.37 ± 2.55 and 1.46 ± 2.61 mg/kg, respectively. The Nemerow integrated pollution index (NIPI) showed that Minle (ML), Liangzhuang (LZ), Shuanghe (SH), Minqin (MQ) and Shapogang (SPG) villages were heavily polluted, with Hg being the main pollutant. Risk index (RI) results indicated that all the five villages were at considerable or high ecological risk. Hg was the main contributor to the potential ecological risk, accounting for 75.82%. Health risk assessments indicated that exposure to road dust heavy metals in preschool children occurs mainly by ingestion. The hazard indexes (HI) values of the five villages were above or close to 1.0, indicating the risk potential of non-carcinogens to preschool children. For carcinogens, the total carcinogenic risk did not exceed the acceptable range for preschool children. Overall, strong pollution and considerable/high ecological risk were found in the road dust of the present study area and the pollution might pose a non-carcinogenic risk to preschool children.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142798520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Toxic Effects of Tire Wear Particles on Microcystis aeruginosa
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-12-10 DOI: 10.1007/s11270-024-07684-3
Lu Cui, Zizhen Zhou, Jiaqiang Liu, Qian Ding, Yangyang Yang, Vezhenkova Irina, Xisheng Liu, Weiyi Xia
{"title":"Toxic Effects of Tire Wear Particles on Microcystis aeruginosa","authors":"Lu Cui,&nbsp;Zizhen Zhou,&nbsp;Jiaqiang Liu,&nbsp;Qian Ding,&nbsp;Yangyang Yang,&nbsp;Vezhenkova Irina,&nbsp;Xisheng Liu,&nbsp;Weiyi Xia","doi":"10.1007/s11270-024-07684-3","DOIUrl":"10.1007/s11270-024-07684-3","url":null,"abstract":"<div><p>Tire wear particles (TWP), generated by the friction of vehicle tires against the road surface during driving, accelerating, and braking, are transferred to aquatic ecosystems via rainfall runoff. These particles exhibit toxicological effects on aquatic organisms and have become the focus of research in environment and health. Microalgae, as primary producers in the marine food web, play a crucial role in aquatic ecosystems and are inevitably affected by TWP. However, the toxic mechanisms by which TWP influences microalgae's normal physiological activities remain unclear. Given this, <i>Microcystis aeruginosa</i>, a common species in freshwater ecosystems, was selected as an experimental species in this study to investigate the effects of different concentrations of TWP (5, 25, 50, 100 mg/L) on its growth, chlorophyll a content, photosynthetic activity, extracellular polymer secretion (EPS), and oxidative stress. The results showed that TWP had a concentration-dependent inhibitory effect on the growth, chlorophyll content, and photosynthetic activity of <i>Microcystis aeruginosa</i>, with maximum inhibition rates reaching 89.4%, 98.44% and 92.9%, respectively. TWP stimulated the secretion of the EPS of <i>Microcystis aeruginosa</i>, and the secretion of the EPS increased with the increase of the concentration of TWP. TWP also promoted the polysaccharide-to-protein ratio in the EPS with a rise of 27.3–38.5%. Meanwhile, the three-dimensional fluorescence-area-integral analysis indicated that the ratio of the protein-like component was generally higher than the one of the humic-like component in the EPS of <i>Microcystis aeruginosa</i>. The significant increase in superoxide dismutase (SOD) activity under 50 and 100 mg/L TWP exposure predicted a substantial activation of oxidative stress. In contrast, the significant increase in the malondialdehyde (MDA) content indicated the overproduction of reactive oxygen species (ROS) and may lead to lipid peroxidation damage. These findings will help us better understand the toxic mechanisms by which TWP induces effects in microalgae.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142798253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Review of Iron-Based Catalysts for Persulfate Activation to Remove PFAS in Water: Catalytic Effects of Various Iron Species, Influencing Factors and Reaction Pathways
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-12-10 DOI: 10.1007/s11270-024-07632-1
Mengjie Zhang, YiYi Li, Xia Tian, Liang Dai, Gang Wang, Zhenle Lei, Gui Ma, Qianlin Zuo, Min Li, Mengmeng Zhao, Jun Ren
{"title":"A Review of Iron-Based Catalysts for Persulfate Activation to Remove PFAS in Water: Catalytic Effects of Various Iron Species, Influencing Factors and Reaction Pathways","authors":"Mengjie Zhang,&nbsp;YiYi Li,&nbsp;Xia Tian,&nbsp;Liang Dai,&nbsp;Gang Wang,&nbsp;Zhenle Lei,&nbsp;Gui Ma,&nbsp;Qianlin Zuo,&nbsp;Min Li,&nbsp;Mengmeng Zhao,&nbsp;Jun Ren","doi":"10.1007/s11270-024-07632-1","DOIUrl":"10.1007/s11270-024-07632-1","url":null,"abstract":"<div><p>Numerous studies highlight the potential degradation of per- and polyfluoroalkyl substances (PFAS) through advanced oxidation processes. A recent focus involves an innovative technology utilizing iron-based catalysts activated by persulfate, renowned for its exceptional PFAS removal efficiency. However, existing literature lacks a thorough comparison of various iron species catalyzing persulfate for PFAS oxidation, with limited analysis of key degradation factors. This paper conducts a comprehensive review, analyzing PFAS degradation efficiency, mechanisms, and pathways using persulfate activated by ferrous ions, zero-valent iron/nano zero-valent iron, iron-based multimetallic catalysts, and various supported iron catalysts. The influence of solution pH and Fe<sup>2+</sup> concentration on the degradation process is also explored. The review reveals promising PFAS removal performance, often exceeding 90%, by iron-based materials activated with persulfate. Catalysts enhance performance through synergistic elements, optimized structural design, and diverse carriers. Acidic environments favor persulfate activation for organic pollutant degradation, while appropriate Fe<sup>2+</sup> concentrations enhance removal efficiency, with Fe<sup>3+</sup> regeneration being the rate-determining step. Iron-based catalyst-activated persulfate follows free radical (SO•- 4, ·OH, O<sub>2</sub><sup>−•</sup>) and non-free radical pathways (Fe(IV), <sup>1</sup>O<sub>2</sub>, direct electron transfer). Perfluorooctanesulfonic acid (PFOS) degradation involves desulfurization, forming the intermediate product perfluorooctanoic acid (PFOA), followed by defluorination. The critical step is removing one CF<sub>2</sub> unit in each round, leading to complete mineralization. The paper proposes future research directions for iron-based activated persulfate in water treatment for PFAS.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142798521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Soil Microplastic Extraction Efficiency Depends on the Sample Incubation Time and the Organic Matter Removal Agent Used
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-12-10 DOI: 10.1007/s11270-024-07685-2
Radosław Stec, Krzysztof Sitko, Marta Pogrzeba, Szymon Rusinowski, Paulina Janota, Izabela Ratman-Kłosińska, Jacek Krzyżak
{"title":"Soil Microplastic Extraction Efficiency Depends on the Sample Incubation Time and the Organic Matter Removal Agent Used","authors":"Radosław Stec,&nbsp;Krzysztof Sitko,&nbsp;Marta Pogrzeba,&nbsp;Szymon Rusinowski,&nbsp;Paulina Janota,&nbsp;Izabela Ratman-Kłosińska,&nbsp;Jacek Krzyżak","doi":"10.1007/s11270-024-07685-2","DOIUrl":"10.1007/s11270-024-07685-2","url":null,"abstract":"<div><p>Environmental pollution by microplastics is now a global problem, as global plastic production is increasing and at the same time recycling of plastic waste is low. In recent years, a number of methods have been developed to determine the content of microplastics in soil. This study compares the efficiency of microplastic extraction in two-week and three-month incubation samples from three different soils artificially contaminated with different types of microplastics. H<sub>2</sub>O<sub>2</sub> and KOH were used as agents to remove organic matter. The effects of changing the incubation time were significant in soils with a high organic matter content. A longer incubation time resulted in a lower efficiency of microplastic extraction. Compared to the results obtained with the control method after a two-week incubation, the loose sand samples achieved a similar extraction efficiency (86%), the amount of MP recovered in the uncontaminated sandy clay samples was 75%, while the sandy clay soils contaminated with heavy metals was 44%. The samples without organic matter removal showed a significantly better recovery rate of microplastics than the samples treated with H<sub>2</sub>O<sub>2</sub> and KOH.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142798519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Intensified Bioaugmentation as a Strategy to Enhance Bioleaching of Mine Tailings with High Metal Content
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-12-10 DOI: 10.1007/s11270-024-07681-6
Irene Acosta Hernández, Jacinto Alonso-Azcárate, Francisco Jesús Fernández-Morales, Luis Rodríguez, José Villaseñor Camacho
{"title":"Intensified Bioaugmentation as a Strategy to Enhance Bioleaching of Mine Tailings with High Metal Content","authors":"Irene Acosta Hernández,&nbsp;Jacinto Alonso-Azcárate,&nbsp;Francisco Jesús Fernández-Morales,&nbsp;Luis Rodríguez,&nbsp;José Villaseñor Camacho","doi":"10.1007/s11270-024-07681-6","DOIUrl":"10.1007/s11270-024-07681-6","url":null,"abstract":"<div><p>Bioleaching is a technology capable of recovering metals from polluted mine tailings. However, the process is slow and time consuming. This work studies the possible enhancement of the bioleaching rate by using different bioaugmentation strategies, i.e. single and multi-step inoculation. Slurry phase batch experiments were performed using real mine tailings containing high concentrations of Fe, Pb, Zn and Mn, and low concentrations of Cd, Ni, Cr and Cu, and a mixed microbial culture of autochthonous acidophilic bacteria grown from those tailings. The effect of the inoculum concentration added at the beginning of the batch experiments was studied in the experiments with single inoculation, while the effect of different reinoculation frequencies was analysed in the multi-step inoculation tests. The results obtained showed that bioaugmentation has a high potential for enhancing the bioleaching process. For both strategies studied, metal bioleaching rates and final removal yields increased when bioaugmentation was carried out. The best results were obtained under the multi-step approach. Average bioleaching rates were multiplied at best case approximately by 2.8 (Fe), 5.0 (Zn), 7.3 (Cu), 17.0 (Mn) and 1.5 (Pb) while removal yields at best case increased approximately 122% (Fe), 31% (Cu), 9% (Cd), 19% (Zn), 17% (Mn), 33% (Ni) and 66% (Cr), compared to reference test (without bioaugmentation). The multi-step approach was able to compensate the assumed inhibitory effect of the metal dissolution during experiments, thus maintaining the active microbial population and the bioleaching rate for longer periods of time.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142798517","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of Microplastics Migration on Farmland Soil Physical and Chemical Properties Under Leaching Conditions
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-12-09 DOI: 10.1007/s11270-024-07690-5
Yuan-zhou Fu, Jin-yan Yang
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