Water, Air, & Soil Pollution最新文献

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Impact of Alternating Reactor Functions on Aerobic Granular Sludge: Treatment Efficiency of Brewery Wastewater and Microbial Community 交替反应器功能对好氧颗粒污泥的影响:啤酒废水处理效率及微生物群落
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-23 DOI: 10.1007/s11270-025-08148-y
Shuo Yang, Dongxu Lu, Shaogen Liu, Yunkun Wang, Hongkui He, Jintong Ma, Liming Qin
{"title":"Impact of Alternating Reactor Functions on Aerobic Granular Sludge: Treatment Efficiency of Brewery Wastewater and Microbial Community","authors":"Shuo Yang,&nbsp;Dongxu Lu,&nbsp;Shaogen Liu,&nbsp;Yunkun Wang,&nbsp;Hongkui He,&nbsp;Jintong Ma,&nbsp;Liming Qin","doi":"10.1007/s11270-025-08148-y","DOIUrl":"10.1007/s11270-025-08148-y","url":null,"abstract":"<div><p>Brewery wastewater typically contains abundant refractory organic substances, that pose challenges, such as poor stability and low pollutant removal efficiency, when treated with conventional aerobic granular sludge (AGS). Hydrolytic acidification (HA) is an effective pretreatment approach that enhances the biological properties of wastewater. However, prolonged HA may lead to the disintegration of the AGS, thereby affecting its treatment efficacy. To address this issue, we propose an operational mode with alternating reactor functions, integrating HA with an SBR and alternately switching the functions of HA and SBR to maintain the stability of AGS and improve wastewater treatment efficiency. The experimental findings revealed that after the acclimation stage, the removal efficiencies of chemical oxygen demand, total nitrogen, NH4<sup>+</sup>-N, and PO<sub>4</sub><sup>3+</sup>-P in the experimental group reached 84.95%, 77.05%, 98.96%, and 79.38%, respectively, which were notably superior to those in the control group, which were 76.7%, 70.6%, 97.73%, and 78.61%, respectively. The results of the microbial community analysis suggest that the alternating operational mode facilitates the enrichment of functional microbial communities associated with pollutant removal, further augmenting the pollutant removal capacity. Our results offer a novel perspective for the application of AGS in the treatment of brewery wastewater and demonstrate that the alternating reactor function mode can effectively enhance treatment efficiency. Future research could further optimize the operating conditions and explore the application potential of the alternating operation of HA and SBR in the treatment of diverse types of wastewater.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 8","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144117619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and Characterization of a New Clay Based Magnetic Composite Muscovite/Fe2O3/FTS for Efficient Removal of Toxic Metal Ions 新型粘土基白云母/Fe2O3/FTS磁性复合材料的合成与表征
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-23 DOI: 10.1007/s11270-025-08127-3
Charifa Chahrazed Hanagria, Boumediene Haddou, Abdelkader Debab, Ibrahim Ameri, Sabah Ansar, Kavita Sharma, Asmaa Benettayeb
{"title":"Synthesis and Characterization of a New Clay Based Magnetic Composite Muscovite/Fe2O3/FTS for Efficient Removal of Toxic Metal Ions","authors":"Charifa Chahrazed Hanagria,&nbsp;Boumediene Haddou,&nbsp;Abdelkader Debab,&nbsp;Ibrahim Ameri,&nbsp;Sabah Ansar,&nbsp;Kavita Sharma,&nbsp;Asmaa Benettayeb","doi":"10.1007/s11270-025-08127-3","DOIUrl":"10.1007/s11270-025-08127-3","url":null,"abstract":"<div><p>In this study, we developed a magnetic composite using Muscovite which was functionalized with Fe<sub>2</sub>O<sub>3</sub> and sodium folate (FTS: C<sub>19</sub>H<sub>18</sub>N<sub>7</sub>NaO<sub>6</sub>) to remove Sm(III), Co(II), and Ni(II) metal ions from wastewater. Various characterization techniques, including X-ray diffraction, vibrating sample magnetometry (VSM), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and zeta-sizer devices, were employed to analyze the magnetic composite Muscovite/Fe<sub>2</sub>O<sub>3</sub>/FTS. After conducting an optimization study of the adsorption operating conditions, we found that the optimum pH for the adsorption of all metals was 6. Isotherm calculations indicated that the langmuir and sips model provided the best fit (with R<sup>2</sup> ≥ 0.9) for the adsorption of all metal ions. According to the langmuir model, at a pH of 6.0, SD of 1 g L<sup>−1</sup>, in an adsorbate concentration range of 30 to 300 mg/L, the adsorption capacities of Sm(III), Co(II), and Ni(II) were found to be 40 mg.g<sup>−1</sup>, 151.4 mg.g<sup>−1</sup>, and 154 mg.g<sup>−1</sup>, respectively. It was noted that pseudo 2nd order (PSORE) model was the best fit for the kinetics of adsorption of these three metal ions on the composite with an the average relative errors (ARE) of less than 13% and with a q<sub>max,exp</sub> close to q<sub>theoretical</sub>. Negative values of ∆G° were obtained at all three temperatures (298, 303, and 313 K), indicated the spontaneity and feasibility of the adsorption processes for Sm(III) and Ni(II) on the magnetic composite. We observed that spontaneity decreased as the temperature increased. We found that nitric acid (HNO<sub>3</sub>, 0.5 M) was the most effective eluent, and Muscovite/Fe<sub>2</sub>O<sub>3</sub>/FTS composite could be reused up to 6 consecutive cycles.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 8","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144117673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Groundwater Hydrogeochemistry, Regional Vulnerability and Trace Metal Enrichments Around Indus Basin Agricultural Fields of SE Punjab, India 印度旁遮普邦东南部印度河流域农田地下水水文地球化学、区域脆弱性及微量金属富集
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-23 DOI: 10.1007/s11270-025-08126-4
Susanta Paikaray, Parul Singh, Shefali Chander, Alankrit Bhardwaj, Athiyarath Krishnan Sudheer, Sanjeev Kumar
{"title":"Groundwater Hydrogeochemistry, Regional Vulnerability and Trace Metal Enrichments Around Indus Basin Agricultural Fields of SE Punjab, India","authors":"Susanta Paikaray,&nbsp;Parul Singh,&nbsp;Shefali Chander,&nbsp;Alankrit Bhardwaj,&nbsp;Athiyarath Krishnan Sudheer,&nbsp;Sanjeev Kumar","doi":"10.1007/s11270-025-08126-4","DOIUrl":"10.1007/s11270-025-08126-4","url":null,"abstract":"<div><p>Aquifer-groundwater interaction plays an important role in controlling subsurface hydrogeochemistry along semi-arid regions because of limited rainfall and overexploitation of groundwater for domestic and irrigation use. Geochemical processes, nature of aquifer mineralogy, irrigation and domestic usability of groundwater, and pollution vulnerability along Indo-Gangetic Quaternary alluvial plain of Fatehgarh Sahib, SE Punjab, India was studied. The groundwater is slightly alkaline (pH 7.4–8.3) with total dissolved solids of 520–1060 mg L<sup>−1</sup>, hardness of 164–314 mg L<sup>−1</sup> CaCO<sub>3</sub> and salinity of 400–800 mg L<sup>−1</sup> where the central region contains little greater contents. Groundwater is of NaHCO<sub>3</sub> and CaHCO<sub>3</sub> water type and Na<sup>+</sup> and HCO<sub>3</sub><sup>−</sup> constitute the abundant cations and anions, respectively. Silicate rock weathering and evaporation processes have majorly controlled the regional hydrogeochemistry, while cation exchange has dominated the ion exchange process. Other than water hardness (&gt; 160 mg L<sup>−1</sup> CaCO<sub>3</sub>), K<sup>+</sup> (&gt; 5.8 mg L<sup>−1</sup>) and HCO<sub>3</sub><sup>−</sup> (&gt; 360 mg L<sup>−1</sup>), no threats for drinking purpose is found from physical properties and chemical composition of groundwater. However, combined parameter weighted arithmetic water quality indices (WQI) suggest poor to very poor quality for drinking use (WQI- 133–325). A mixed irrigation suitability is inferred from agricultural indices where residual sodium carbonate (RSC- 0.9–5.2) and Kelley’s ratio (KR- 0.5–1.4) suggests &gt; 50% of the studied groundwater is unsuitable for irrigation use, while percent sodium (Na%- 31–57) and sodium absorption ratio (SAR- 2.0–3.8) suggests their permissible limits with no sodium hazard concerns. Upto 2.0 mg L<sup>−1</sup> F<sup>−</sup> was measured where &gt; 40% samples exceeds the desirable limit (1.0 mg L<sup>−1</sup>) and SW region groundwater is relatively enriched in F<sup>−</sup> irrespective of their depth. Both geogenic and fertilizer origin of F<sup>−</sup> is proposed with no sharp distinction of predominance of any. Uranium and As contents exceed the permissible limit in 43% (&gt; 30 µg L<sup>−1</sup>) and 21% (&gt; 10 µg L<sup>−1</sup>) of the studied groundwater, while Se, Cu, Cr, Co, Mo, Ni, Zn, Th are within their permissible limits with heavy metal pollution indices of 16–167. The central and SW region groundwater which is the regional groundwater flow direction is more deteriorated in terms of drinking and irrigation use and trace metal and F<sup>−</sup> enrichment compared to eastern and NE region.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 8","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144117618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring the Visible Light Photocatalytic Efficiency of Sol–Gel Derived Zinc Ferrite: A Comparative Analysis of Nanoparticles and Thin Films 溶胶-凝胶法制备铁酸锌的可见光催化效率:纳米粒子与薄膜的对比分析
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-23 DOI: 10.1007/s11270-025-08133-5
Samir Briche, Mustapha Boutamart, Otman Abida, Khalid Nouneh, Lekbira El Mersly, El Mountassir El Mouchtari, Salah Rafqah
{"title":"Exploring the Visible Light Photocatalytic Efficiency of Sol–Gel Derived Zinc Ferrite: A Comparative Analysis of Nanoparticles and Thin Films","authors":"Samir Briche,&nbsp;Mustapha Boutamart,&nbsp;Otman Abida,&nbsp;Khalid Nouneh,&nbsp;Lekbira El Mersly,&nbsp;El Mountassir El Mouchtari,&nbsp;Salah Rafqah","doi":"10.1007/s11270-025-08133-5","DOIUrl":"10.1007/s11270-025-08133-5","url":null,"abstract":"<div><p>This study is regarding the novel synthesis of zinc ferrite (ZnFe<sub>2</sub>O<sub>4</sub>) thin films and nanoparticles by a sol–gel transition. In this study, we performed hydrolysis/polycondensation reactions on a mixture of zinc and iron alkoxides. To gather information about surface morphology, chemical composition, optical properties, and crystal structure, we applied UV–VIS, FTIR, XRD, BET, TGA–DSC, AFM, and TEM. We also studied how well the ZnFe<sub>2</sub>O<sub>4</sub> nanoparticles and thin films would degrade Orange G, a model pollutant, through visible light exposure and photocatalytic activity. The results showed the nanoparticles provided the best photocatalytic activity at 500 °C and thin films at 450 °C. The immobilized photocatalyst still demonstrated activity. However, it did not reach the activity levels exhibited by the nanoparticles. This would be expected due to the larger specific surface area of the nanoparticles.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 8","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144117667","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of MXenes, nZVI and Acacia-wood Biochar Treatments on Bioavailability Pb and Fractions in Calcareous-polluted Soils MXenes、nZVI和相思木生物炭处理对钙质污染土壤生物有效性、Pb及其组分的影响
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-23 DOI: 10.1007/s11270-025-08146-0
Ghulam Murtaza, Najmaldin Ezaldin Hassan, Muhammad Usman, Gang Deng, Zeeshan Ahmed, Javed Iqbal, Mohamed S. Elshikh, Humaira Rizwana, Rashid Iqbal
{"title":"Effect of MXenes, nZVI and Acacia-wood Biochar Treatments on Bioavailability Pb and Fractions in Calcareous-polluted Soils","authors":"Ghulam Murtaza,&nbsp;Najmaldin Ezaldin Hassan,&nbsp;Muhammad Usman,&nbsp;Gang Deng,&nbsp;Zeeshan Ahmed,&nbsp;Javed Iqbal,&nbsp;Mohamed S. Elshikh,&nbsp;Humaira Rizwana,&nbsp;Rashid Iqbal","doi":"10.1007/s11270-025-08146-0","DOIUrl":"10.1007/s11270-025-08146-0","url":null,"abstract":"<div><p>The remediation of contaminated soils with heavy metals is a critical environmental policy in both developing and industrialized countries. The various adsorbents utilization is an effective method for the immobilization of toxic metals in contaminated soils. The present research sought to evaluate lead (Pb) immobilization in contaminated calcareous soil impacted by the application of different amendments such as <i>Acacia</i>-wood biochar MXenes, and nZVI and their interaction during maize growth. The study employed three amendments, biochar MXenes, and nZVI at three concentrations (0, 2.5, and 5%) and various levels of Pb pollution (0, 50, and 100 mg/kg soil). An incubation time of 16 weeks was designated for homogenization of supplements in soil, and maize cultivated following standard procedures. After incubation, various fractions of Pb, such as residual, organic matter-bound, carbonate-bound, exchangeable, and manganese and iron-bound, were determined. Additionally, Pb was assessed using EDTA and DTPA techniques and 1000-grain weight of maize was recorded. The findings indicated that maximum concentration of Pb associated with organic matter was achieved in the 5% <i>Acacia</i>-wood biochar application, reaching 20 mg/kg. Maximum and minimum concentration of Pb extracted was DTPA were recorded in the control sample (95 mg/kg) and 5% biochar treatment (65 mg/kg). Findings indicated that enhancing quantities of biochar and MXenes supplements enhanced weight of 1000 grains of maize across all treatments. Results indicate that biochar and MXenes addition decreased level of Pb extracted using EDTA (129 mg/kg) and DTPA (79 mg/kg). Findings indicated that biochar and MXenes application decreased active Pb and Pb mobility in soil by enhancing carbonate and organic fractions. The biochar and MXenes addition in remediation of soil can improve their efficacy in decreasing the level and active Pb mobility. Biochar offers stable C matrix for more Pb immobilization, whereas MXenes enhance adsorption potential and facilitate ion-exchange ability.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 8","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144117617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Distribution of Microplastic Pollution in Skadar Lake within the National Park of Montenegro 黑山国家公园内斯卡达尔湖的微塑料污染分布
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-22 DOI: 10.1007/s11270-025-08138-0
Neda Bošković, Željko Jaćimović, Oliver Bajt
{"title":"Distribution of Microplastic Pollution in Skadar Lake within the National Park of Montenegro","authors":"Neda Bošković,&nbsp;Željko Jaćimović,&nbsp;Oliver Bajt","doi":"10.1007/s11270-025-08138-0","DOIUrl":"10.1007/s11270-025-08138-0","url":null,"abstract":"<div><p>This study investigates, for the first time, the abundance, composition, distribution, sources, and ecological risks of microplastics (MPs) in the shore sediments of Skadar Lake in Montenegro. MPs were detected in all sediment samples, with their presence varying by sampling site and season. The MP abundances, measured as particles per 100 g of dry sediment, ranged from 9–22, with an average of 15.4 ± 4.3. The identified MP shapes included fibers, fragments, and films, with fibers (41%), sizes 1–3 mm (33.3%), and the color blue (31.9%) being the most dominant. Fourier-transform infrared (FTIR) analysis revealed polyethylene and polypropylene as the primary polymers. The pollution load index (PLI) and polymer hazard index (PHI) were used to assess sediment quality. PLI values indicated a low level of MP pollution in the sediments of Skadar Lake, suggesting a minor ecological risk. High PHI values were noted due to the presence of MPs with high-hazard score polymers. This study lays the groundwork for future monitoring and a better understanding of MP pollution, distribution, and potential sources in freshwater ecosystems. Our findings could support the implementation of preventive measures to reduce MP pollution in Skadar Lake, which is part of the National Park of Montenegro.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 8","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144108631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, Characterization, and Effective Adsorption of Naproxen Sodium from Wastewater Using Eco-Friendly Gum Acacia-Grafted-Poly(N,N-Dimethylacrylamide)/CoFe2O4 Hydrogel Nanocomposite 合欢胶接枝聚(N,N-二甲基丙烯酰胺)/CoFe2O4水凝胶纳米复合材料的合成、表征及对萘普生钠的有效吸附
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-22 DOI: 10.1007/s11270-025-08151-3
Pragnesh N. Dave, Sanjay Bamaniya
{"title":"Synthesis, Characterization, and Effective Adsorption of Naproxen Sodium from Wastewater Using Eco-Friendly Gum Acacia-Grafted-Poly(N,N-Dimethylacrylamide)/CoFe2O4 Hydrogel Nanocomposite","authors":"Pragnesh N. Dave,&nbsp;Sanjay Bamaniya","doi":"10.1007/s11270-025-08151-3","DOIUrl":"10.1007/s11270-025-08151-3","url":null,"abstract":"<div><p>Water scarcity and declining water quality, made worse by pharmaceutical waste, pose significant challenges worldwide. There is a high demand to eliminate such contaminants from wastewater. In this study, authors have synthesized a Gum acacia-<i>g</i>-poly (N,N-dimethylacrylamide)/CoFe<sub>2</sub>O<sub>4</sub> nanocomposite hydrogel adsorbent by free radical polymerization technique using N,N-dimethylacrylamide (DMA) monomer, and cobalt ferrite (CF) nanofillers. The structural, morphological, and thermal properties of the synthesized nanocomposite hydrogel were characterized by Fourier-transform infrared spectroscopy (FTIR), powder X-ray diffraction (XRD), scanning electron microscopy (SEM), point zero charge (pH<sub>PZC</sub>)<sub>,</sub> Brunauer–Emmett–Teller (BET) analysis, and thermogravimetric analysis (TGA). XRD analysis revealed a semi crystalline structure with distinct peaks corresponding to CoFe<sub>2</sub>O<sub>4</sub>, indicating increased crystallinity upon adding CF nanoparticles. SEM images showed a porous surface morphology with CF dispersed throughout the hydrogel matrix, leading to an increased BET surface area of 0.7099 m<sup>2</sup> g<sup>−1</sup> compared to the hydrogel without nanofillers. The effectiveness of the GA-<i>g</i>-P(DMA)/CF nanocomposite hydrogel for removing the non-steroidal anti-inflammatory drug (NSAID) naproxen sodium (NS) from aqueous solutions was investigated. Adsorption experiments were conducted under various conditions including solution pH (2 − 11), adsorbent dose (10–100 mg), initial drug concentration (25–200 mg/L), contact time (2–24 h), and temperature (20–60 °C). The maximum adsorption capacity (<i>q</i><sub><i>max</i></sub>) of the hydrogel for NS was determined to be 344.827 mg/g, and the Langmuir isotherm model provided the best fit for the experimental data. The pseudo-second-order kinetic model described the adsorption kinetics well. Electrostatic interactions and hydrogen bonding were identified as the main mechanisms for NS adsorption onto the hydrogel. Furthermore, adsorption − desorption studies demonstrated that the hydrogel could be efficiently recovered and reused for four consecutive runs without significant loss in adsorption performance.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 8","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144108630","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Construction of Zinc Oxide/Nickel Ferric-Layered Double Hydroxide Composite for Efficient Adsorption of Erythromycin: Kinetic and Thermodynamic Investigation 氧化锌/镍铁层状双氢氧化物复合材料高效吸附红霉素的动力学和热力学研究
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-22 DOI: 10.1007/s11270-025-08156-y
Asaad F. Hassan, Attalla F. El-kott, Mohammed A. AlShehri, Fahad M. Aldosari
{"title":"Construction of Zinc Oxide/Nickel Ferric-Layered Double Hydroxide Composite for Efficient Adsorption of Erythromycin: Kinetic and Thermodynamic Investigation","authors":"Asaad F. Hassan,&nbsp;Attalla F. El-kott,&nbsp;Mohammed A. AlShehri,&nbsp;Fahad M. Aldosari","doi":"10.1007/s11270-025-08156-y","DOIUrl":"10.1007/s11270-025-08156-y","url":null,"abstract":"<div><p>Erythromycin, a persistent antibiotic pollutant, poses challenges for wastewater treatment due to its stability and resistance to biodegradation. The current paper was designed to synthesize three solid adsorbents: nickel ferric-layered double hydroxide (NF), zinc oxide nanoparticles (Z), and zinc oxide/nickel ferric-layered double hydroxide composite (ZNF) for the effective removal of erythromycin (Ery). The features of the fabricated solid materials were fully investigated by employing X-ray diffraction analysis (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), attenuated total reflectance Fourier transform infrared (ATR-FTIR), thermogravimetric analysis (TGA), and textural characterization via nitrogen gas adsorption/desorption studies. The obtained results presented that the prepared ZNF has a nano-size (123 nm), surface area of 157.161 m<sup>2</sup>/g with pore radius of 2.67 nm, and rich with different surface chemical function groups. The batch adsorption tests revealed that ZNF achieved the maximum adsorption capacity of 273.51 mg/g at pH 7, 15 °C, 1.7 g/L as adsorbent dosage, and after 6 h of shaking time. The application of various nonlinear isothermal and kinetic models shows good consistency with the Langmuir and pseudo-second-order models. The thermodynamic studies illustrated that the adsorption was endothermic, favorable, and spontaneous. Moreover, all the samples had better reusability and stability after ten adsorption–desorption cycles ZNF loss only 3.1% of its removal efficiency. An interesting and attractive subject of study is the unique structure of ZNF as a pollutant adsorbent with a high adsorption capacity.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 8","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144108632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Helminth Parasites as Bioindicators of Heavy Metal Pollution in the Jhelum River: Insights into Bioaccumulation and Ecological Implications 寄生虫作为Jhelum河重金属污染的生物指示物:生物积累及其生态学意义
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-22 DOI: 10.1007/s11270-025-08107-7
Ishteyaq Majeed Shah, Ibraq Khurshid, Nafee Maqbool, Fayaz Ahmad, Syed Mudasir Ahmad
{"title":"Helminth Parasites as Bioindicators of Heavy Metal Pollution in the Jhelum River: Insights into Bioaccumulation and Ecological Implications","authors":"Ishteyaq Majeed Shah,&nbsp;Ibraq Khurshid,&nbsp;Nafee Maqbool,&nbsp;Fayaz Ahmad,&nbsp;Syed Mudasir Ahmad","doi":"10.1007/s11270-025-08107-7","DOIUrl":"10.1007/s11270-025-08107-7","url":null,"abstract":"<div><p>Biomonitoring using host-parasite dynamics as bioindicators of heavy metal pollution is limited, particularly in Indian riverine systems. This study explored the potential of helminth parasites of fish as bioindicators and accumulators of heavy metals in the Jhelum River, the largest tributary of the Indus River. Samples were collected seasonally over 12 months (June 2022–May 2023). Concentrations of five heavy metals (Fe, Zn, Cu, Pb, Cd) were assessed in <i>Schizothorax niger</i> tissues (liver, intestine, muscle) and helminth parasites (<i>Pomphorhynchus kashmirensis</i>, <i>Schyzocotyle acheilognathi</i>, <i>Adenoscolex oreini</i>) using Atomic Absorption Spectroscopy. Statistically significant differences (p &lt; 0.01) were observed for all metals across seasons, sites, tissues, and parasitic fauna (Three-way ANOVA). The bioaccumulation hierarchy was <i>P. kashmirensis</i> &gt; <i>S. acheilognathi</i> &gt; <i>A. oreini</i> &gt; liver &gt; intestine &gt; muscle. Cd and Pb were absent in fish muscle tissue but highly concentrated in parasites, demonstrating their superior bioaccumulation capacity. Higher bioconcentration factor (BCF) for Cd and Pb were noted in parasites. Principal Component Analysis (PCA) and graphical visualizations further confirmed the distinct clustering of parasites due to elevated metal uptake. These findings underscore the ecological and toxicological implications of heavy metal pollution and highlight helminth parasites as effective bioindicators of contamination. This study advances insights into trophic transfer and provides a framework for sustainable monitoring and management strategies to protect aquatic biodiversity and food safety in polluted ecosystems.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 8","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144108629","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancements and Future Perspectives in Biological Nitrogen and Phosphorus Removal Coupled Resource Recovery Processes 生物脱氮除磷耦合资源回收工艺研究进展及展望
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-21 DOI: 10.1007/s11270-025-08132-6
Deyi Jiang, Haoyun Wang, Xuandi Cao, Ruochen Wang, Zheqin Dai, Wuxiang Zhang, Haq Nawaz Abbasi, Bing Li, Xingang Wang, Hongliang Dai
{"title":"Advancements and Future Perspectives in Biological Nitrogen and Phosphorus Removal Coupled Resource Recovery Processes","authors":"Deyi Jiang,&nbsp;Haoyun Wang,&nbsp;Xuandi Cao,&nbsp;Ruochen Wang,&nbsp;Zheqin Dai,&nbsp;Wuxiang Zhang,&nbsp;Haq Nawaz Abbasi,&nbsp;Bing Li,&nbsp;Xingang Wang,&nbsp;Hongliang Dai","doi":"10.1007/s11270-025-08132-6","DOIUrl":"10.1007/s11270-025-08132-6","url":null,"abstract":"<div><p>The growing global population and the expansion of agricultural production have resulted in the excessive use of nitrogen (N) and phosphorus (P), which has become a significant environmental challenge. Consequently, addressing wastewater treatment has become a critical priority for achieving sustainable development. This paper presents an overview of the fundamental principles and typical processes for biological N and P removal, followed by a detailed examination of various methods for recovering N and P resources from wastewater. Furthermore, the necessity, characteristics, and applications of biological N and P removal coupled with resource recovery processes are comprehensively analyzed. These coupled processes are anticipated to evolve continually, enhancing treatment efficiency, enabling the simultaneous removal of multiple pollutants, and improving resource recovery, thus advancing the development of green and sustainable water treatment technologies. In the future, the integration of intelligent informatization control of traditional technology, gradual development of emerging technology will promote the widespread implementation of this technology in wastewater treatment with policy support from the government, fostering resource recycling and contributing to environmental protection.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 8","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144100319","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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