Chemical Society Reviews最新文献_第2页

Practical issues toward high-voltage aqueous rechargeable batteries

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-03-18 DOI: 10.1039/d4cs00779d

Seongjae Ko, Shin-ichi Nishimura, Norio Takenaka, Atsushi Kitada, Atsuo Yamada

引用次数: 0

Synthetic strategies for the incorporation of metallocenes into anti-infective scaffolds

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-03-17 DOI: 10.1039/d4cs01216j

Apollonia Kalamatianou, Corentin Ludwig, Shuai Zhong, Kevin Cariou, Gilles Gasser

引用次数: 0

Decoding recombination dynamics in perovskite solar cells: an in-depth critical review

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-03-17 DOI: 10.1039/d4cs01231c

Ramkrishna Das Adhikari, Mayur Jagdishbhai Patel, Himangshu Baishya, Deepak Yadav, Manab Kalita, Mizanur Alam, Parameswar Krishnan Iyer

{"title":"Decoding recombination dynamics in perovskite solar cells: an in-depth critical review","authors":"Ramkrishna Das Adhikari, Mayur Jagdishbhai Patel, Himangshu Baishya, Deepak Yadav, Manab Kalita, Mizanur Alam, Parameswar Krishnan Iyer","doi":"10.1039/d4cs01231c","DOIUrl":"https://doi.org/10.1039/d4cs01231c","url":null,"abstract":"The remarkable optoelectronic properties of metal halide perovskites (MHPs) have established them as highly promising photovoltaic absorber materials, propelling the rapid advancement of perovskite solar cells (PSCs) that outperform many traditional alternatives in terms of power conversion efficiency (PCE). However, despite their advancements, PSC devices encounter significant non-radiative recombination losses, encompassing trap-assisted (Shockley–Read–Hall) recombination in bulk and interfaces of PSCs, which restricts their open-circuit voltage (VOC) and overall PCE, dragging it below the Shockley–Queisser (SQ) limit. The ongoing debate regarding the role of grain boundary (GB) recombination, whether it primarily manifests as bulk or surface recombination, has spurred extensive research aimed at elucidating these mechanisms. This review provides a critical comprehensive analysis of the thermodynamic correlations related to VOC losses, bridging the gap between the theoretical SQ limit and practical device performance. Subsequently, it delves into recent findings that aim to decipher the multifaced nature and origin of radiative and non-radiative recombination-induced losses within the device stack, assessing their impacts on overall performance. Furthermore, this review emphasizes the application of advanced machine learning techniques to discern dominant recombination mechanisms in PSCs. Finally, it summarizes the notable advanced strategies to mitigate undesirable non-radiative recombination losses, which pave the way to the thermodynamic efficiency limit.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"69 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143640029","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Body fluid diagnostics using activatable optical probes

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-03-14 DOI: 10.1039/d4cs01315h

Jie Zhan, Yanbin Cai, Penghui Cheng, Lei Zheng, Kanyi Pu

{"title":"Body fluid diagnostics using activatable optical probes","authors":"Jie Zhan, Yanbin Cai, Penghui Cheng, Lei Zheng, Kanyi Pu","doi":"10.1039/d4cs01315h","DOIUrl":"https://doi.org/10.1039/d4cs01315h","url":null,"abstract":"In vitro diagnostics often detects biomarkers in body fluids (such as blood, urine, sputum, and cerebrospinal fluids) to identify life-threatening diseases at an early stage, monitor overall health, or provide information to help cure, treat, or prevent diseases. Most clinically used optical in vitro diagnostic tests utilize dye-labeled biomolecules for biomarker recognition and signal readout, which typically involve complex steps and long processing times. Activatable optical probes (AOPs), which spontaneously activate their optical signals only in the presence of disease biomarkers, offer higher signal-to-background ratios and improved detection specificity. They also have the potential to simplify detection procedures by eliminating multiple washing steps. In this review, we summarize recent advances in the use of AOPs for pre-clinical and clinical body fluid diagnostics across various diseases, including cancer, nephro-urological disorders, infectious diseases, and digestive diseases. We begin by discussing the molecular design strategies of AOPs to achieve different optical signal readouts and biomarker specificity. We then highlight their diagnostic applications in various disease models and body fluids. Finally, we address the challenges and future perspectives of AOPs in enhancing body fluid diagnostics and advancing precision medicine.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"8 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143618521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Coacervates as enzymatic microreactors

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-03-14 DOI: 10.1039/d4cs01203h

Rif Harris, Nofar Berman, Ayala Lampel

{"title":"Coacervates as enzymatic microreactors","authors":"Rif Harris, Nofar Berman, Ayala Lampel","doi":"10.1039/d4cs01203h","DOIUrl":"https://doi.org/10.1039/d4cs01203h","url":null,"abstract":"Compartmentalization, a key aspect of biochemical regulation, naturally occurs in cellular organelles, including biomolecular condensates formed through liquid–liquid phase separation (LLPS). Inspired by biological compartments, synthetic coacervates have emerged as versatile microreactors, which can provide customed environments for enzymatic reactions. In this review, we explore recent advances in coacervate-based microreactors, while emphasizing the mechanisms by which coacervates accelerate enzymatic reactions, namely by enhancing substrate and enzyme concentrations, stabilizing intermediates, and providing molecular crowding. We discuss diverse coacervate systems, including those based on synthetic polymers, peptides, and nucleic acids, and describe the selection of enzymatic model systems, as well as strategies for enzyme recruitment and their impact on reaction kinetics. Furthermore, we discuss the challenges in monitoring reactions within coacervates and review the currently available techniques including fluorescence techniques, chromatography, and NMR spectroscopy. Altogether, this review offers a comprehensive perspective on recent progress and challenges in the design of coacervate microreactors, and addresses their potential in biocatalysis, synthetic biology, and nanotechnology.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"22 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143618519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Breaking symmetry for better catalysis: insights into single-atom catalyst design

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-03-13 DOI: 10.1039/d4cs01031k

Pingping Cao, Xueqin Mu, Fanjiao Chen, Shengchen Wang, Yuru Liao, Hui Liu, Yapeng Du, Yuxuan Li, Yudi Peng, Mingzhu Gao, Suli Liu, Dingsheng Wang, Zhihui Dai

{"title":"Breaking symmetry for better catalysis: insights into single-atom catalyst design","authors":"Pingping Cao, Xueqin Mu, Fanjiao Chen, Shengchen Wang, Yuru Liao, Hui Liu, Yapeng Du, Yuxuan Li, Yudi Peng, Mingzhu Gao, Suli Liu, Dingsheng Wang, Zhihui Dai","doi":"10.1039/d4cs01031k","DOIUrl":"https://doi.org/10.1039/d4cs01031k","url":null,"abstract":"Breaking structural symmetry has emerged as a powerful strategy for fine-tuning the electronic structure of catalytic sites, thereby significantly enhancing the electrocatalytic performance of single-atom catalysts (SACs). The inherent symmetric electron density in conventional SACs, such as M–N4 configurations, often leads to suboptimal adsorption and activation of reaction intermediates, limiting their catalytic efficiency. By disrupting this symmetry of SACs, the electronic distribution around the active center can be modulated, thereby improving both the selectivity and adsorption strength for key intermediates. These changes directly impact the reaction pathways, lowering energy barriers, and enhancing catalytic activity. However, achieving precise modulation through SAC symmetry breaking for better catalysis remains challenging. This review focuses on the atomic-level symmetry-breaking strategies of catalysts, including charge breaking, coordination breaking, and geometric breaking, as well as their electrocatalytic applications in electronic structure tuning and active site modulation. Through modifications to the M–N4 framework, three primary configurations are achieved: unsaturated coordination M–Nx(x=1,2,3), non-metallic doping MX–Nx(x=1,2,3), and bimetallic doping M1M2–N4. Advanced characterization techniques combined with density functional theory (DFT) elucidate the impact of these strategies on oxidation, reduction, and bifunctional catalytic reactions. This review highlights the significance of symmetry-breaking structures in catalysis and underscores the need for further research to achieve precise control at the atomic-level.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"4 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143608133","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Bis(trimethylsilyl)phosphide chemistry: a half-century of advances across the periodic table

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-03-12 DOI: 10.1039/d4cs01141d

Jack Baldwin, David P. Mills

引用次数: 0

Metal–organic frameworks (MOFs) toward SO2 detection

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-03-10 DOI: 10.1039/d4cs00997e

Juan L. Obeso, Catalina V. Flores, Ricardo A. Peralta, Margarita Viniegra, N. Martín-Guaregua, Michael T. Huxley, Diego Solis-Ibarra, Ilich A. Ibarra, Christoph Janiak

{"title":"Metal–organic frameworks (MOFs) toward SO2 detection","authors":"Juan L. Obeso, Catalina V. Flores, Ricardo A. Peralta, Margarita Viniegra, N. Martín-Guaregua, Michael T. Huxley, Diego Solis-Ibarra, Ilich A. Ibarra, Christoph Janiak","doi":"10.1039/d4cs00997e","DOIUrl":"https://doi.org/10.1039/d4cs00997e","url":null,"abstract":"Developing technology that can precisely monitor specific air pollutants in diverse settings is essential to control emissions and ensure safe exposure limits are not exceeded. Metal–organic frameworks (MOFs) are crystalline organic–inorganic hybrid materials, which are promising candidates for SO2 detection. Their chemically mutable periodic structure confers outstanding surface area, thermal stability, and a well-defined pore distribution. Moreover, MOFs have exhibited extraordinary performance for SO2 capture. Therefore, research has focused on their possible applications for SO2 sequestration due to the selective and robust chemical and physical interactions of SO2 molecules within MOFs. The variable SO2 affinity presented by MOFs enables the adsorption mechanism and preferential adsorption sites to be resolved. However, for MOF-based SO2 detection, selective SO2 capture at shallow partial pressure (0.01–0.1 bar) is required. Thus, capturing SO2 at low concentration is crucial for SO2 detection, where textural properties of MOFs, mainly the pore-limiting diameter, are essential to achieve selective detection. In this review, we discuss the fundamental aspects of SO2 detection in MOFs, providing a step-by-step methodology for SO2 detection in MOFs. We hope this review can provide valuable background around SO2 detection in MOFs and inspire further research within this new and exciting field.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"13 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143582941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Metal pyrazolate frameworks: crystal engineering access to stable functional materials

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-03-07 DOI: 10.1039/d4cs00989d

Xiang-Jing Kong, Guang-Rui Si, Tao He, Jian-Rong Li

{"title":"Metal pyrazolate frameworks: crystal engineering access to stable functional materials","authors":"Xiang-Jing Kong, Guang-Rui Si, Tao He, Jian-Rong Li","doi":"10.1039/d4cs00989d","DOIUrl":"https://doi.org/10.1039/d4cs00989d","url":null,"abstract":"As the focus evolves from structure discovery/characterization (what it is) to property/performance exploration (what it is for), the pursuit of stable functional metal–organic frameworks (MOFs) has been ongoing in terms of both fundamental research and industrial implementation. Under the guidance of crystal engineering principles, a plethora of research has developed pyrazolate MOFs (metal pyrazaolate frameworks, MPFs) featuring strong coordination M–N bonding. This attribution helps them retain their structures and functions under the alkaline conditions required for practical use. Based on poly-topic pyrazolate ligands, various classic MOFs, such as Co(bdp), Fe2(BDP)3, Ni8L6, PCN-601, and BUT-55, to name a few, have revealed fascinating architectures, intriguing properties, and record-breaking performances in applications during the past decade. This review will present the full scope of MPFs to date: (1) the superiority and significance of constructing MPFs through the crystal engineering approach, (2) synthetic strategies adopted in building and/or modifying MPFs, (3) structural features and stability of the MPF community, and (4) potential applications in energy and environmental related fields. The future opportunities of MPFs are also discussed for designing the next-generation of smart materials. Overall, this review attempts to provide insights and guidelines for the customization of pyrazolate-based MOFs for specific purposes, which would also promote the development of stable functional porous materials for addressing societal challenges.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"76 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143570154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Formulation principles and synergistic effects of high-voltage electrolytes

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-03-06 DOI: 10.1039/d4cs00826j

Zewei Wei, Du Yuan, Xuedi Yuan, Yalin Zhang, Jianmin Ma, Suojiang Zhang, Haitao Zhang

{"title":"Formulation principles and synergistic effects of high-voltage electrolytes","authors":"Zewei Wei, Du Yuan, Xuedi Yuan, Yalin Zhang, Jianmin Ma, Suojiang Zhang, Haitao Zhang","doi":"10.1039/d4cs00826j","DOIUrl":"https://doi.org/10.1039/d4cs00826j","url":null,"abstract":"The energy density of lithium-ion batteries (LIBs) is primarily determined by the working potential of devices and the specific capacity of cathode compounds. Carbonate-based electrolytes have received considerable attention due to their significance for advancing current cell-assembly process. However, the commercially available liquid LiPF6 based electrolytes cannot withstand the harsh high-voltage environment and the effects of cathode, due to issues such as the undesired oxidative decomposition of ethylene carbonate (EC), the catalytic influence of dissolved transition metal ions (TMs), and the poor performance of interphases with unstable morphologies and components. Furthermore, the complex working mechanisms of high-voltage electrolytes (HVEs) are not fully understood. This review presents a comprehensive summary of the HVEs, including their physical properties, solvation structures, and interface chemistry. Specifically, chemical environment of high-voltage cathode compounds and failure mechanisms of commercial electrolytes are investigated, followed by a discussion of expected functions of HVEs. Then, screening criteria for single-component electrolytes, considering their oxidation resistance and decomposition mechanism, and screening mechanism of interphase species are explored based on their energy level positions. Next, a cross-scale evolution framework is proposed, from the solvation structure to interphase characteristics, aimed at uncovering the formulation principles and synergistic effects of HVEs. Operational mechanisms are systematically scrutinized, starting from the conventional tuning of solvation structure to the incorporation of multiple components and further to the role of entropy-driven effects, all of which will favor the understanding of formulation principles and synergistic effects. Finally, integration of advanced computational methods and mature experimental techniques is expected to foster the development of novel perspectives and promising electrolyte candidates.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"53 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143561345","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0