Navigating the functionalization of unactivated alkenes via visible light photocatalysis

IF 40.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Guang-Mei Cao, Si-Shun Yan, Lei Song, Yuan-Xu Jiang, Tian-Yu Gao, Zhen Chen, Wei Zhang, Jian-Heng Ye, Da-Gang Yu
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引用次数: 0

Abstract

Direct functionalization of unactivated alkenes has emerged as a highly effective strategy for the rapid construction of multi-functional, complex molecular architectures from simple, abundant chemicals. This area of research has garnered increasing attention and continues to be a focus of contemporary chemistry. Recent years have witnessed substantial advancements driven by the discovery of photocatalysis and the expansion of activation strategies, which have led to the discovery of novel transformations and the refinement of established reactions. In this review, we provide a comprehensive overview of the visible-light photocatalytic functionalization of unactivated alkenes, with a particular emphasis on key reactions and mechanistic insights into transformations via hydrofunctionalization, difunctionalization and functionalized alkene retention. Furthermore, we discuss the recent progress, ongoing challenges and emerging opportunities in this significant field, highlighting the synthetic utility and potential for future applications.

Abstract Image

通过可见光催化导航非活化烯烃的功能化
非活化烯烃的直接功能化已成为从简单、丰富的化学物质中快速构建多功能、复杂分子结构的一种非常有效的策略。这一研究领域引起了越来越多的关注,并继续成为当代化学的焦点。近年来,由于光催化的发现和激活策略的扩展,导致了新转化的发现和既定反应的改进,取得了实质性的进展。在这篇综述中,我们提供了非活化烯烃可见光催化功能化的全面概述,特别强调了关键反应和机理的见解转化通过加氢功能化,双功能化和功能化烯烃保留。此外,我们还讨论了这一重要领域的最新进展、面临的挑战和新出现的机遇,强调了其综合效用和未来应用的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Chemical Society Reviews
Chemical Society Reviews 化学-化学综合
CiteScore
80.80
自引率
1.10%
发文量
345
审稿时长
6.0 months
期刊介绍: Chemical Society Reviews is published by: Royal Society of Chemistry. Focus: Review articles on topics of current interest in chemistry; Predecessors: Quarterly Reviews, Chemical Society (1947–1971); Current title: Since 1971; Impact factor: 60.615 (2021); Themed issues: Occasional themed issues on new and emerging areas of research in the chemical sciences
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