Chemical Society Reviews最新文献_第10页

A surface chemistry perspective on SERS: revisiting the basics to push the field forward 表面化学角度的SERS：重温基础知识以推动该领域向前发展。

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-03-26 DOI: 10.1039/D4CS01242A

Chiara Deriu and Laura Fabris

{"title":"A surface chemistry perspective on SERS: revisiting the basics to push the field forward","authors":"Chiara Deriu and Laura Fabris","doi":"10.1039/D4CS01242A","DOIUrl":"10.1039/D4CS01242A","url":null,"abstract":"Surfaces are well known to be complex entities that are extremely difficult to study, and any phenomenon that is related to them is consequently challenging to approach. Moving from the bulk to the nanoscale adds a further layer of complexity to the problem. Because SERS relies on surfaces at the nanoscale, a rigorous understanding of the chemical phenomena that concur in the observation of the SERS signal is still limited or disorganized at best. Specifically, the lack of understanding of the chemical properties of nanoparticle surfaces has direct consequences on the development of SERS-based devices, causing a widespread belief that SERS is an inherently unreliable and fundamentally irreproducible analytical technique. Herein, we discuss old and new literature from SERS and related fields to accompany the reader through a journey that explores the chemical nature and architecture of colloidal plasmonic nanoparticles as the most popular SERS-active surfaces. By examining the chemistry of the surface landscape of the most common SERS colloids and the thermodynamic equilibria that characterize it, we aim to paint a chemically realistic picture of what a SERS analyst deals with on a daily basis. Thus, our goal for this review is to provide a centralized compilation of key, state-of-the-art surface chemistry information that can guide the rational development of analytical protocols and contribute an additional path through which our community can continue to advance SERS as a reliable and robust analytical tool.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 11","pages":" 5224-5247"},"PeriodicalIF":40.4,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11937889/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143707833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Self-healing behavior of superhard covalent bond materials 超硬共价键材料的自愈行为

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-03-24 DOI: 10.1039/D4CS01182A

Keliang Qiu, Xiang Li, Yanhong Li, Yonghai Yue and Lin Guo

引用次数: 0

Insights into the mechanism of 3d transition-metal-catalyzed directed C(sp3)–H bond functionalization reactions 三维过渡金属催化的定向C(sp3)-氢键功能化反应机理研究。

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-03-20 DOI: 10.1039/D4CS00657G

Andrés García-Viada, Juan C. Carretero, Javier Adrio and Nuria Rodríguez

引用次数: 0

Cell-free synthetic biology for natural product biosynthesis and discovery 无细胞合成生物学用于天然产物的生物合成和发现

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-03-19 DOI: 10.1039/D4CS01198H

Andrew J. Rice, Tien T. Sword, Kameshwari Chengan, Douglas A. Mitchell, Nigel J. Mouncey, Simon J. Moore and Constance B. Bailey

{"title":"Cell-free synthetic biology for natural product biosynthesis and discovery","authors":"Andrew J. Rice, Tien T. Sword, Kameshwari Chengan, Douglas A. Mitchell, Nigel J. Mouncey, Simon J. Moore and Constance B. Bailey","doi":"10.1039/D4CS01198H","DOIUrl":"10.1039/D4CS01198H","url":null,"abstract":"Natural products have applications as biopharmaceuticals, agrochemicals, and other high-value chemicals. However, there are challenges in isolating natural products from their native producers (e.g. bacteria, fungi, plants). In many cases, synthetic chemistry or heterologous expression must be used to access these important molecules. The biosynthetic machinery to generate these compounds is found within biosynthetic gene clusters, primarily consisting of the enzymes that biosynthesise a range of natural product classes (including, but not limited to ribosomal and nonribosomal peptides, polyketides, and terpenoids). Cell-free synthetic biology has emerged in recent years as a bottom-up technology applied towards both prototyping pathways and producing molecules. Recently, it has been applied to natural products, both to characterise biosynthetic pathways and produce new metabolites. This review discusses the core biochemistry of cell-free synthetic biology applied to metabolite production and critiques its advantages and disadvantages compared to whole cell and/or chemical production routes. Specifically, we review the advances in cell-free biosynthesis of ribosomal peptides, analyse the rapid prototyping of natural product biosynthetic enzymes and pathways, highlight advances in novel antimicrobial discovery, and discuss the rising use of cell-free technologies in industrial biotechnology and synthetic biology.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 9","pages":" 4314-4352"},"PeriodicalIF":40.4,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/cs/d4cs01198h?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143654147","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Structural codes of organic electrode materials for rechargeable multivalent metal batteries 可充电多价金属电池用有机电极材料结构规范

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-03-18 DOI: 10.1039/D4CS01072H

Quanquan Guo, Hao Xu, Xingyuan Chu, Xing Huang, Minghao Yu and Xinliang Feng

{"title":"Structural codes of organic electrode materials for rechargeable multivalent metal batteries","authors":"Quanquan Guo, Hao Xu, Xingyuan Chu, Xing Huang, Minghao Yu and Xinliang Feng","doi":"10.1039/D4CS01072H","DOIUrl":"10.1039/D4CS01072H","url":null,"abstract":"Rechargeable multivalent metal batteries (MMBs) are considered as promising alternatives to Li-ion and Pb-acid batteries for grid-scale energy storage applications due to the multi-electron redox capability of metal anodes. However, the conventional inorganic cathodes used in MMBs face challenges with the sluggish diffusivity and poor storage of charge-dense multivalent cations in their crystal lattice. Organic electrode materials (OEMs), on the other hand, offer several advantages as MMB cathodes, including flexible structural designability, high resource availability, sustainability, and a unique ion-coordination storage mechanism. This review explores the intrinsic connection between the structural features of OEMs and their charge storage performance, aiming to unveil key design principles for organic molecules used in various MMB applications. We begin with an overview of the fundamental aspects of different MMBs (i.e., Zn/Mg/Ca/Al batteries), covering electrolyte selection, metal stripping/plating electrochemistry, and the fundamentals of cathode operation. From a theoretical understanding of redox activities, we summarize the properties of different redox sites and correlate the electrochemical properties of OEMs with various structural factors. This analysis further leads to the introduction of critical design considerations for different types of OEMs. We then critically review a wide range of organic compounds for MMBs, from small organic molecules to redox-active polymers and covalent-organic frameworks, focusing on their structure–property relationships, key electrochemical parameters, and strengths and shortcomings for multivalent ion storage. Finally, we discuss the existing challenges and propose potential solutions for further advancing OEMs in MMBs.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 8","pages":" 4035-4086"},"PeriodicalIF":40.4,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/cs/d4cs01072h?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143640288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Practical issues toward high-voltage aqueous rechargeable batteries 高压水性可充电电池的实际问题

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-03-18 DOI: 10.1039/D4CS00779D

Seongjae Ko, Shin-ichi Nishimura, Norio Takenaka, Atsushi Kitada and Atsuo Yamada

引用次数: 0

Synthetic strategies for the incorporation of metallocenes into anti-infective scaffolds 金属茂烯结合抗感染支架的合成策略

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-03-17 DOI: 10.1039/D4CS01216J

Apollonia Kalamatianou, Corentin Ludwig, Shuai Zhong, Kevin Cariou and Gilles Gasser

引用次数: 0

Decoding recombination dynamics in perovskite solar cells: an in-depth critical review 解码钙钛矿太阳能电池中的重组动力学：一个深入的关键评论

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-03-17 DOI: 10.1039/D4CS01231C

Ramkrishna Das Adhikari, Mayur Jagdishbhai Patel, Himangshu Baishya, Deepak Yadav, Manab Kalita, Mizanur Alam and Parameswar Krishnan Iyer

{"title":"Decoding recombination dynamics in perovskite solar cells: an in-depth critical review","authors":"Ramkrishna Das Adhikari, Mayur Jagdishbhai Patel, Himangshu Baishya, Deepak Yadav, Manab Kalita, Mizanur Alam and Parameswar Krishnan Iyer","doi":"10.1039/D4CS01231C","DOIUrl":"10.1039/D4CS01231C","url":null,"abstract":"The remarkable optoelectronic properties of metal halide perovskites (MHPs) have established them as highly promising photovoltaic absorber materials, propelling the rapid advancement of perovskite solar cells (PSCs) that outperform many traditional alternatives in terms of power conversion efficiency (PCE). However, despite their advancements, PSC devices encounter significant non-radiative recombination losses, encompassing trap-assisted (Shockley–Read–Hall) recombination in bulk and interfaces of PSCs, which restricts their open-circuit voltage (VOC) and overall PCE, dragging it below the Shockley–Queisser (SQ) limit. The ongoing debate regarding the role of grain boundary (GB) recombination, whether it primarily manifests as bulk or surface recombination, has spurred extensive research aimed at elucidating these mechanisms. This review provides a critical comprehensive analysis of the thermodynamic correlations related to VOC losses, bridging the gap between the theoretical SQ limit and practical device performance. Subsequently, it delves into recent findings that aim to decipher the multifaced nature and origin of radiative and non-radiative recombination-induced losses within the device stack, assessing their impacts on overall performance. Furthermore, this review emphasizes the application of advanced machine learning techniques to discern dominant recombination mechanisms in PSCs. Finally, it summarizes the notable advanced strategies to mitigate undesirable non-radiative recombination losses, which pave the way to the thermodynamic efficiency limit.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 8","pages":" 3962-4034"},"PeriodicalIF":40.4,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143640029","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Body fluid diagnostics using activatable optical probes 使用可激活的光学探针进行体液诊断

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-03-14 DOI: 10.1039/D4CS01315H

Jie Zhan, Yanbin Cai, Penghui Cheng, Lei Zheng and Kanyi Pu

{"title":"Body fluid diagnostics using activatable optical probes","authors":"Jie Zhan, Yanbin Cai, Penghui Cheng, Lei Zheng and Kanyi Pu","doi":"10.1039/D4CS01315H","DOIUrl":"10.1039/D4CS01315H","url":null,"abstract":" In vitro diagnostics often detects biomarkers in body fluids (such as blood, urine, sputum, and cerebrospinal fluids) to identify life-threatening diseases at an early stage, monitor overall health, or provide information to help cure, treat, or prevent diseases. Most clinically used optical in vitro diagnostic tests utilize dye-labeled biomolecules for biomarker recognition and signal readout, which typically involve complex steps and long processing times. Activatable optical probes (AOPs), which spontaneously activate their optical signals only in the presence of disease biomarkers, offer higher signal-to-background ratios and improved detection specificity. They also have the potential to simplify detection procedures by eliminating multiple washing steps. In this review, we summarize recent advances in the use of AOPs for pre-clinical and clinical body fluid diagnostics across various diseases, including cancer, nephro-urological disorders, infectious diseases, and digestive diseases. We begin by discussing the molecular design strategies of AOPs to achieve different optical signal readouts and biomarker specificity. We then highlight their diagnostic applications in various disease models and body fluids. Finally, we address the challenges and future perspectives of AOPs in enhancing body fluid diagnostics and advancing precision medicine.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 8","pages":" 3906-3929"},"PeriodicalIF":40.4,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/cs/d4cs01315h?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143618521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Coacervates as enzymatic microreactors 凝聚成酶微反应器

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-03-14 DOI: 10.1039/D4CS01203H

Rif Harris, Nofar Berman and Ayala Lampel

{"title":"Coacervates as enzymatic microreactors","authors":"Rif Harris, Nofar Berman and Ayala Lampel","doi":"10.1039/D4CS01203H","DOIUrl":"10.1039/D4CS01203H","url":null,"abstract":"Compartmentalization, a key aspect of biochemical regulation, naturally occurs in cellular organelles, including biomolecular condensates formed through liquid–liquid phase separation (LLPS). Inspired by biological compartments, synthetic coacervates have emerged as versatile microreactors, which can provide customed environments for enzymatic reactions. In this review, we explore recent advances in coacervate-based microreactors, while emphasizing the mechanisms by which coacervates accelerate enzymatic reactions, namely by enhancing substrate and enzyme concentrations, stabilizing intermediates, and providing molecular crowding. We discuss diverse coacervate systems, including those based on synthetic polymers, peptides, and nucleic acids, and describe the selection of enzymatic model systems, as well as strategies for enzyme recruitment and their impact on reaction kinetics. Furthermore, we discuss the challenges in monitoring reactions within coacervates and review the currently available techniques including fluorescence techniques, chromatography, and NMR spectroscopy. Altogether, this review offers a comprehensive perspective on recent progress and challenges in the design of coacervate microreactors, and addresses their potential in biocatalysis, synthetic biology, and nanotechnology.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 9","pages":" 4183-4199"},"PeriodicalIF":40.4,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/cs/d4cs01203h?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143618519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0