Chemical Society Reviews最新文献_第10页

Liquid–liquid and gas–liquid dispersions in electrochemistry: concepts, applications and perspectives† 电化学中的液-液和气-液分散体：概念、应用和前景。

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2024-11-04 DOI: 10.1039/D3CS00535F

Kang Wang, Yucheng Wang and Marc Pera-Titus

{"title":"Liquid–liquid and gas–liquid dispersions in electrochemistry: concepts, applications and perspectives†","authors":"Kang Wang, Yucheng Wang and Marc Pera-Titus","doi":"10.1039/D3CS00535F","DOIUrl":"10.1039/D3CS00535F","url":null,"abstract":"Electrochemistry plays a pivotal role in a vast number of domains spanning from sensing and manufacturing to energy storage, environmental conservation, and healthcare. Electrochemical applications encompassing gaseous or organic substrates encounter shortcomings ascribed to high mass transfer/internal resistances and low solubility in aqueous electrolytes, resulting in high overpotentials. In practice, strong acids and expensive organic electrolytes are required to promote charge transfer in electrochemical cells, resulting in a high carbon footprint. Liquid–liquid (L–L) and gas–liquid (G–L) dispersions involve the dispersion of a nano/micro gas or liquid into a continuous liquid phase such as micelles, (macro)emulsions, microemulsions, and microfoams stabilised by surface-active agents such as surfactants and colloidal particles. These dispersions hold promise in addressing the drawbacks of electrochemical reactions by fostering the interfacial surface area between immiscible reagents and mass transfer of electroactive organic and gas reactants and products from/to the bulk to/from the electrode surface. This tutorial review provides a taxonomy of liquid–liquid and gas–liquid dispersions for applications in electrochemistry, with emphasis on their assets and challenges in industrially relevant reactions for fine chemistry and depollution.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 24","pages":" 11701-11724"},"PeriodicalIF":40.4,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11562458/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142566393","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Boron enabled bioconjugation chemistries 支持硼的生物共轭化学物质

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2024-10-30 DOI: 10.1039/D4CS00750F

Mengmeng Zheng, Lingchao Kong and Jianmin Gao

{"title":"Boron enabled bioconjugation chemistries","authors":"Mengmeng Zheng, Lingchao Kong and Jianmin Gao","doi":"10.1039/D4CS00750F","DOIUrl":"10.1039/D4CS00750F","url":null,"abstract":"Novel bioconjugation reactions have been heavily pursued for the past two decades. A myriad of conjugation reactions have been developed for labeling molecules of interest in their native context as well as for constructing multifunctional molecular entities or stimuli-responsive materials. A growing cluster of bioconjugation reactions were realized by tapping into the unique properties of boron. As a rare element in human biology, boronic acids and esters exhibit remarkable biocompatibility. A number of organoboron reagents have been evaluated for bioconjugation, targeting the reactivity of either native biomolecules or those incorporating bioorthogonal functional groups. Owing to the dynamic nature of B–O and B–N bond formation, a significant portion of the boron-enabled bioconjugations exhibit rapid reversibility and accordingly have found applications in the development of reversible covalent inhibitors. On the other hand, stable bioconjugations have been developed that display fast kinetics and significantly expand the repertoire of bioorthogonal chemistry. This contribution presents a summary and comparative analysis of the recently developed boron-mediated bioconjugations. Importantly, this article seeks to provide an in-depth discussion of the thermodynamic and kinetic profiles of these boron-enabled bioconjugations, which reveals structure–reactivity relationships and provides guidelines for bioapplications.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 24","pages":" 11888-11907"},"PeriodicalIF":40.4,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/cs/d4cs00750f?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142542157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A comprehensive review of covalent organic frameworks (COFs) and their derivatives in environmental pollution control† 共价有机框架（COF）及其衍生物在环境污染控制中的应用综述

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2024-10-30 DOI: 10.1039/D4CS00521J

Shengbo Ge, Kexin Wei, Wanxi Peng, Runzhou Huang, Esther Akinlabi, Hongyan Xia, Muhammad Wakil Shahzad, Xuehua Zhang, Ben Bin Xu and Jianchun Jiang

{"title":"A comprehensive review of covalent organic frameworks (COFs) and their derivatives in environmental pollution control†","authors":"Shengbo Ge, Kexin Wei, Wanxi Peng, Runzhou Huang, Esther Akinlabi, Hongyan Xia, Muhammad Wakil Shahzad, Xuehua Zhang, Ben Bin Xu and Jianchun Jiang","doi":"10.1039/D4CS00521J","DOIUrl":"10.1039/D4CS00521J","url":null,"abstract":"Covalent organic frameworks (COFs) have gained considerable attention due to their design possibilities as the molecular organic building blocks that can stack in an atomically precise spatial arrangement. Since the inception of COFs in 2005, there has been a continuous expansion in the product range of COFs and their derivatives. This expansion has led to the evolution of three-dimensional structures and various synthetic routes, propelling the field towards large-scale preparation of COFs and their derivatives. This review will offer a holistic analysis and comparison of the spatial structure and synthesis techniques of COFs and their derivatives. The conventional methods of COF synthesis (i.e., ultrasonic chemical, microwave, and solvothermal) are discussed alongside the synthesis strategies of new COFs and their derivatives. Furthermore, the applications of COFs and their derived materials are demonstrated in air, water, and soil pollution management such as gas capture, catalytic conversion, adsorption, and pollutant removal. Finally, this review highlights the current challenges and prospects for large-scale preparation and application of new COFs and the derived materials. In line with the United Nations Sustainable Development Goals (SDGs) and the needs of digital-enabled technologies (AI and machine learning), this review will encompass the future technical trends for COFs in environmental pollution control.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 23","pages":" 11259-11302"},"PeriodicalIF":40.4,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/cs/d4cs00521j?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142541209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Harnessing DNA computing and nanopore decoding for practical applications: from informatics to microRNA-targeting diagnostics 利用 DNA 计算和纳米孔解码实现实际应用：从信息学到微 RNA 靶向诊断学

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2024-10-29 DOI: 10.1039/D3CS00396E

Sotaro Takiguchi, Nanami Takeuchi, Vasily Shenshin, Guillaume Gines, Anthony J. Genot, Jeff Nivala, Yannick Rondelez and Ryuji Kawano

{"title":"Harnessing DNA computing and nanopore decoding for practical applications: from informatics to microRNA-targeting diagnostics","authors":"Sotaro Takiguchi, Nanami Takeuchi, Vasily Shenshin, Guillaume Gines, Anthony J. Genot, Jeff Nivala, Yannick Rondelez and Ryuji Kawano","doi":"10.1039/D3CS00396E","DOIUrl":"10.1039/D3CS00396E","url":null,"abstract":"DNA computing represents a subfield of molecular computing with the potential to become a significant area of next-generation computation due to the high programmability inherent in the sequence-dependent molecular behaviour of DNA. Recent studies in DNA computing have extended from mathematical informatics to biomedical applications, with a particular focus on diagnostics that exploit the biocompatibility of DNA molecules. The output of DNA computing devices is encoded in nucleic acid molecules, which must then be decoded into human-recognizable signals for practical applications. Nanopore technology, which utilizes an electrical and label-free decoding approach, provides a unique platform to bridge DNA and electronic computing for practical use. In this tutorial review, we summarise the fundamental knowledge, technologies, and methodologies of DNA computing (logic gates, circuits, neural networks, and non-DNA input circuity). We then focus on nanopore-based decoding, and highlight recent advances in medical diagnostics targeting microRNAs as biomarkers. Finally, we conclude with the potential and challenges for the practical implementation of these techniques. We hope that this tutorial will provide a comprehensive insight and enable the general reader to grasp the fundamental principles and diverse applications of DNA computing and nanopore decoding, and will inspire a wide range of scientists to explore and push the boundaries of these technologies.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 1","pages":" 8-32"},"PeriodicalIF":40.4,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/cs/d3cs00396e?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142541210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Multidimensionally ordered mesoporous intermetallics: Frontier nanoarchitectonics for advanced catalysis† 多维有序介孔金属间化合物：用于先进催化的前沿纳米结构。

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2024-10-29 DOI: 10.1039/D4CS00484A

Hao Lv and Ben Liu

{"title":"Multidimensionally ordered mesoporous intermetallics: Frontier nanoarchitectonics for advanced catalysis†","authors":"Hao Lv and Ben Liu","doi":"10.1039/D4CS00484A","DOIUrl":"10.1039/D4CS00484A","url":null,"abstract":"Ordered intermetallics contribute to a unique class of catalyst materials due to their rich atomic features. Further engineering of ordered intermetallics at a mesoscopic scale is of great importance to expose more active sites and introduce new functions. Recently, multidimensionally ordered mesoporous intermetallic (MOMI) nanoarchitectonics, which subtly integrate atomically ordered intermetallics and mesoscopically ordered mesoporous structures, have held add-in synergies that not only enhance catalytic activity and stability but also optimize catalytic selectivity. In this tutorial review, we have summarized the latest progress in the rational design, targeted synthesis, and catalytic applications of MOMIs, with a special focus on the findings of our group. Three strategies, including concurrent template route, self-template route, and dealloying route, are discussed in detail. Furthermore, physicochemical properties and catalytic performances for several important reactions are also described to highlight the remarkable activity, high stability, and controllable selectivity of MOMI nanoarchitectonics. Finally, we conclude with a summary and explore future perspectives in the field to contribute to wider applications.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 23","pages":" 11321-11333"},"PeriodicalIF":40.4,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142520363","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fundamentals of the recycling of spent lithium-ion batteries 废锂离子电池回收的基本原理

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2024-10-29 DOI: 10.1039/D4CS00362D

Pengwei Li, Shaohua Luo, Yicheng Lin, Jiefeng Xiao, Xiaoning Xia, Xin Liu, Li Wang and Xiangming He

{"title":"Fundamentals of the recycling of spent lithium-ion batteries","authors":"Pengwei Li, Shaohua Luo, Yicheng Lin, Jiefeng Xiao, Xiaoning Xia, Xin Liu, Li Wang and Xiangming He","doi":"10.1039/D4CS00362D","DOIUrl":"10.1039/D4CS00362D","url":null,"abstract":"This review discusses the critical role of fundamentals of battery recycling in addressing the challenges posed by the increasing number of spent lithium-ion batteries (LIBs) due to the widespread use of electric vehicles and portable electronics, by providing the theoretical basis and technical support for recycling spent LIBs, including battery classification, ultrasonic flaw detection, pretreatment (e.g., discharging, mechanical crushing, and physical separation), electrolyte recovery, direct regeneration, and theoretical calculations and simulations. Physical chemistry principles are essential for achieving effective separation of different components through methods like screening, magnetic separation, and flotation. Electrolyte recovery involves separation and purification of electrolytes through advanced physical and chemical techniques. Direct regeneration technology restores the structure of electrode materials at the microscopic scale, requiring precise control of the physical state and crystal structure of the material. Physical processes such as phase changes, solubility, and diffusion are fundamental to techniques like solid-state sintering, eutectic-salt treatment, and hydrothermal methods. Theoretical calculations and simulations help predict the behaviour of materials during recycling, guiding process optimization. This review provides insights into understanding and improving the recycling process, emphasizing the central role of physical chemistry principles in addressing environmental and energy issues. It is valuable for promoting innovation in spent LIB recycling processes and is expected to stimulate interest among researchers and manufacturers.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 24","pages":" 11967-12013"},"PeriodicalIF":40.4,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142541211","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Understanding deNOx mechanisms in transition metal exchanged zeolites 了解过渡金属交换沸石的脱硝机制

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2024-10-23 DOI: 10.1039/D3CS00468F

Jamal Abdul Nasir, Andrew M. Beale and C. Richard A. Catlow

引用次数: 0

Ultrasound mechanisms and their effect on solid synthesis and processing: a review 超声机制及其对固体合成和加工的影响：综述

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2024-10-23 DOI: 10.1039/D4CS00148F

Cedric Devos, Ariana Bampouli, Elena Brozzi, Georgios D. Stefanidis, Michiel Dusselier, Tom Van Gerven and Simon Kuhn

引用次数: 0

Progress and challenges in structural, in situ and operando characterization of single-atom catalysts by X-ray based synchrotron radiation techniques 利用基于 X 射线的同步辐射技术对单原子催化剂进行结构、原位和操作表征的进展与挑战

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2024-10-22 DOI: 10.1039/D3CS00967J

Yuhang Liu, Xiaozhi Su, Jie Ding, Jing Zhou, Zhen Liu, Xiangjun Wei, Hong Bin Yang and Bin Liu

{"title":"Progress and challenges in structural, in situ and operando characterization of single-atom catalysts by X-ray based synchrotron radiation techniques","authors":"Yuhang Liu, Xiaozhi Su, Jie Ding, Jing Zhou, Zhen Liu, Xiangjun Wei, Hong Bin Yang and Bin Liu","doi":"10.1039/D3CS00967J","DOIUrl":"10.1039/D3CS00967J","url":null,"abstract":"Single-atom catalysts (SACs) represent the ultimate size limit of nanoscale catalysts, combining the advantages of homogeneous and heterogeneous catalysts. SACs have isolated single-atom active sites that exhibit high atomic utilization efficiency, unique catalytic activity, and selectivity. Over the past few decades, synchrotron radiation techniques have played a crucial role in studying single-atom catalysis by identifying catalyst structures and enabling the understanding of reaction mechanisms. The profound comprehension of spectroscopic techniques and characteristics pertaining to SACs is important for exploring their catalytic activity origins and devising high-performance and stable SACs for industrial applications. In this review, we provide a comprehensive overview of the recent advances in X-ray based synchrotron radiation techniques for structural characterization and in situ/operando observation of SACs under reaction conditions. We emphasize the correlation between spectral fine features and structural characteristics of SACs, along with their analytical limitations. The development of IMST with spatial and temporal resolution is also discussed along with their significance in revealing the structural characteristics and reaction mechanisms of SACs. Additionally, this review explores the study of active center states using spectral fine characteristics combined with theoretical simulations, as well as spectroscopic analysis strategies utilizing machine learning methods to address challenges posed by atomic distribution inhomogeneity in SACs while envisaging potential applications integrating artificial intelligence seamlessly with experiments for real-time monitoring of single-atom catalytic processes.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 24","pages":" 11850-11887"},"PeriodicalIF":40.4,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142452605","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Chemical strategies for antisense antibiotics 反义抗生素的化学策略。

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2024-10-22 DOI: 10.1039/D4CS00238E

Mathijs J. Pals, Alexander Lindberg and Willem A. Velema

引用次数: 0