定义、设计和确定超分子框架的结构。

IF 39 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Nicholas G White,C Michael McGuirk
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引用次数: 0

摘要

超分子框架,由非共价相互作用组装的有序多孔网络,是一类广泛的功能材料,具有由用于组装它们的相对弱的相互作用产生的紧急组合特性。然而,该领域的连贯发展受到了大量不同名称和首字母缩略词的挑战,这些名称和缩略词用于非常相似的结构,并且在这些材料的表征过程中遇到了不同程度的严格性。这导致了相当大的混乱,特别是对那些刚进入这个领域的人来说,这可能导致重要的早期工作被忽视和进展停滞。在本教程回顾中,我们简要介绍了该领域,建议为这些材料提供连贯的命名系统,以及严格的表征标准。我们最后讨论了可用于增加获得具有所需结构和性质的超分子框架的机会的设计原则。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Defining, designing and determining the structure of supramolecular frameworks.
Supramolecular frameworks, ordered porous networks assembled by noncovalent interactions, are a broad class of functional materials with emergent combinations of properties arising from the relatively weak interactions used to assemble them. However, the coherent advancement of the field is challenged by the abundance of different names and acronyms used for very similar structures and the varying degrees of rigour met during the characterisation of these materials. This has led to considerable confusion, particularly for those new to the field, which can lead to important early work being overlooked and stagnation of progress. In this Tutorial Review, we provide a brief introduction to the field, suggest a coherent naming system for these materials, and rigorous standards for their characterisation. We finish by discussing design principles that can be used to increase the chances of obtaining supramolecular frameworks with desired structures and properties.
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来源期刊
Chemical Society Reviews
Chemical Society Reviews 化学-化学综合
CiteScore
80.80
自引率
1.10%
发文量
345
审稿时长
6.0 months
期刊介绍: Chemical Society Reviews is published by: Royal Society of Chemistry. Focus: Review articles on topics of current interest in chemistry; Predecessors: Quarterly Reviews, Chemical Society (1947–1971); Current title: Since 1971; Impact factor: 60.615 (2021); Themed issues: Occasional themed issues on new and emerging areas of research in the chemical sciences
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