ACS Sustainable Chemistry & Engineering最新文献_第10页

Regulating the Zn/Electrolyte Interface by Natural Proline Additive for Durable Zinc-Ion Batteries 用天然脯氨酸添加剂调节耐用锌离子电池的锌/电解质界面

IF 7.1 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2025-05-13 DOI: 10.1021/acssuschemeng.5c0011110.1021/acssuschemeng.5c00111

Xiaorui Wang, Xilin Wang, Pengyang Lei, Bin Wang and Jianli Cheng*,

{"title":"Regulating the Zn/Electrolyte Interface by Natural Proline Additive for Durable Zinc-Ion Batteries","authors":"Xiaorui Wang, Xilin Wang, Pengyang Lei, Bin Wang and Jianli Cheng*, ","doi":"10.1021/acssuschemeng.5c0011110.1021/acssuschemeng.5c00111","DOIUrl":"https://doi.org/10.1021/acssuschemeng.5c00111https://doi.org/10.1021/acssuschemeng.5c00111","url":null,"abstract":"Aqueous zinc-ion batteries (AZIBs) have garnered significant attention as promising alternatives to traditional lithium-ion batteries in sustainable energy storage systems. However, their further development is hindered by critical challenges, such as severe dendrite growth and side reactions. Meanwhile, the performance improvement of AZIBs using common single-function electrolyte additives is limited. In this study, a natural proline with dual functionality is introduced to regulate the electrochemical properties of the interface, guide uniform deposition of Zn, regulate the solvation structure of Zn2+, and induce exposure of the Zn (002) surface. After testing, the modified Zn symmetric cell exhibits exceptional durability of more than 1700 h at 4.0 mA h cm–2/1.0 mA cm–2 and over 200 h at 50 mA cm–2/10 mA h cm–2. Furthermore, the Zn//MnO2 full cell, which has a proline-containing electrolyte, demonstrates high specific capacity (294.3 mA h g–1 at 0.3 A g–1) and outstanding cycle stability with a high-capacity retention of 60% after 2000 cycles, much better than that of ZIBs with the pristine ZnSO4 electrolyte. Zn//MnO2 pouch cell (3.8 × 1.3 cm) also exhibits excellent cycling stability with a retention of 53.6% after 1000 cycles at a current density of 3 A g–1. This research provides a multipurpose electrolyte additive that serves as an effective reference for advancing the capability of AZIBs.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"13 20","pages":"7395–7405 7395–7405"},"PeriodicalIF":7.1,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144133840","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Bioinspired Flavylium Surfactants for Hydrophobic Agglomeration of Fine Kaolinite Particles 用于高岭石微粒疏水团聚的生物启发黄烷表面活性剂

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2025-05-13 DOI: 10.1021/acssuschemeng.5c00698

W. Samadhi Fernando, Peter W. McDonald, Negin Amini, George V. Franks, San H. Thang, Chris Ritchie

{"title":"Bioinspired Flavylium Surfactants for Hydrophobic Agglomeration of Fine Kaolinite Particles","authors":"W. Samadhi Fernando, Peter W. McDonald, Negin Amini, George V. Franks, San H. Thang, Chris Ritchie","doi":"10.1021/acssuschemeng.5c00698","DOIUrl":"https://doi.org/10.1021/acssuschemeng.5c00698","url":null,"abstract":"With increasing environmental concerns and the drawbacks associated with the synthetic materials currently used in industry, there is a growing demand for more eco-friendly and efficient alternatives in mineral processing applications. To help address this, three bioinspired surfactants (M8Flav, M12Flav, and D8Flav) were synthesized by modifying the core structure of flavylium, a plant-based pigment, by installing secondary and tertiary alkyl amines. Hydrophobic agglomeration of fine kaolinite (D4,3: 10 μm) particles facilitated through the application of these bioinspired surfactants was examined. Spectroscopic, microscopic, and XRD (X-ray diffraction) analyses were performed to interrogate the association of flavylium with kaolinite including the elucidation of potential interactions and mechanisms for the changes in macroscopic properties of the kaolinite aggregates. The surface hydrophobicity of kaolinite was evaluated using the Washburn capillary rise method, with enhanced hydrophobicity observed after treatment with the surfactants. Real-time in situ aggregate size measurements under a controlled shear rate were conducted using an image-derived particle size measuring technique to systematically evaluate the impact of surfactant dosage and alkyl chain configuration on aggregate size and stability. Turbidity reduction of the supernatants and gravitational sedimentation under quiescent conditions of surfactant-treated kaolinite slurries were also examined. These findings reveal the applicability of flavylium-based surfactants, positioning them as valuable tools for improving techniques in clay separation and dewatering processes.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"3 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143940299","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Regioselective N-2 Alkylation of Tetrazoles with Phenacyl Halides under Mechanochemical Conditions and Its Application to a Solid-State Synthesis of the Antiepileptic Drug Cenobamate 机械化学条件下四唑与Phenacyl卤化物的区域选择性N-2烷基化及其在抗癫痫药物Cenobamate固态合成中的应用

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2025-05-12 DOI: 10.1021/acssuschemeng.4c09608

Kamila Bepirszcz, Anna Maria Mazzetta, Jorge Gómez-Carpintero, Juan Domingo Sánchez, Juan F. González, J. Carlos Menéndez

引用次数: 0

Plasma-Driven Catalytic Conversion of Biogas to Methanol and Acetic Acid and the Role of Water in Tailoring Products 等离子体催化沼气转化为甲醇和乙酸及水在制衣产品中的作用

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2025-05-12 DOI: 10.1021/acssuschemeng.5c01293

Pengxian Ye, Guang Miao, Debjyoti Ray, Zihui Tang, Chunshan Song

{"title":"Plasma-Driven Catalytic Conversion of Biogas to Methanol and Acetic Acid and the Role of Water in Tailoring Products","authors":"Pengxian Ye, Guang Miao, Debjyoti Ray, Zihui Tang, Chunshan Song","doi":"10.1021/acssuschemeng.5c01293","DOIUrl":"https://doi.org/10.1021/acssuschemeng.5c01293","url":null,"abstract":"The conversion of biogas, a widely available renewable source, to the desired liquid products under mild conditions still remains challenging. Integrating nonthermal plasma with catalysts makes it possible to produce acetic acid and methanol directly from biogas consisting mainly of CO2 and CH4. Among various catalysts examined, plasma-reduced Cu/Al2O3 with a flower-like morphology substantially enhances methanol formation. Adding a small amount of water vapor into biogas significantly enhances methanol production under cold plasma. In situ optical emission spectroscopy, probe tests with isotope-labeled D2O and H218O, and plasma desorption analysis provide clear evidence that water not only participates in and promotes the methanol-forming reaction but also facilitates methanol desorption from the catalyst surface under plasma. Increasing the plasma discharge power, however, can dramatically switch the liquid products from methanol-dominated to acetic acid-dominated oxygenates. These novel findings provide a new strategy for the direct conversion of biogas to chemicals and fuels.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"51 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143933210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Multiomics Provides Insights into the Impacts of Microplastics on Heavy Metal(Loid) Accumulation in Lettuce under Simulated Acid Precipitation 模拟酸雨条件下微塑料对生菜重金属（Loid）积累的影响

IF 7.1 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2025-05-12 DOI: 10.1021/acssuschemeng.5c0311410.1021/acssuschemeng.5c03114

Li Chen, Nan Chang, Hongjie Liu, Tao Li, Fengyu Huang*, Yi Zeng, Haoran He, Tianyi Qiu, Yifeng Xu, Lai Peng, Jason C. White and Linchuan Fang*,

{"title":"Multiomics Provides Insights into the Impacts of Microplastics on Heavy Metal(Loid) Accumulation in Lettuce under Simulated Acid Precipitation","authors":"Li Chen, Nan Chang, Hongjie Liu, Tao Li, Fengyu Huang*, Yi Zeng, Haoran He, Tianyi Qiu, Yifeng Xu, Lai Peng, Jason C. White and Linchuan Fang*, ","doi":"10.1021/acssuschemeng.5c0311410.1021/acssuschemeng.5c03114","DOIUrl":"https://doi.org/10.1021/acssuschemeng.5c03114https://doi.org/10.1021/acssuschemeng.5c03114","url":null,"abstract":"Microplastics (MPs) and heavy metal(loid)s (HMs) are widespread agricultural contaminants. Acid precipitation can create acidic conditions, changing migration of these pollutants in soil-crop systems. However, the impacts of MPs on HMs uptake by crops under acid rain conditions and the underlying mechanisms that govern these processes remain unclear. We conducted pot experiments to assess MP-mediated effects on HM accumulation in lettuce (Lactuca sativa L.) under simulated acid rain. We found that high-dose polyethylene (PE) significantly increased shoot Cd accumulation in lettuce by 51.2% and that the presence of acid rain enhanced this effect, as compared to the single PE treatment. In contrast, coexposure to PE and acid rain decreased the As accumulation by 47.6%. This was primarily due to a decrease in soil pH and a change in HMs availability. In the rhizosphere, PE and acid rain positively influenced the relative abundance of Photobacterium that is the main contributor mediating the Cd/As accumulation. Additionally, acid precipitation enhanced MP stress by regulating metabolic pathways and reducing the biosynthesis of several important metabolites, including signal transduction, amino acid, and carbohydrate. Co-analysis of microbiomics and metagenomics showed the functional genes related to the metabolism of biotin, propanoate, and histidine were altered by MPs and acid precipitation, which may cause increases in the abundance of Photobacterium. These findings underscore complex interactions between MPs and acid rain on HMs transport and availability in soil-crop systems, providing important insights for evaluating their risk in farmland.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"13 20","pages":"7667–7681 7667–7681"},"PeriodicalIF":7.1,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144133968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Regioselective N-2 Alkylation of Tetrazoles with Phenacyl Halides under Mechanochemical Conditions and Its Application to a Solid-State Synthesis of the Antiepileptic Drug Cenobamate 机械化学条件下四唑与Phenacyl卤化物的区域选择性N-2烷基化及其在抗癫痫药物Cenobamate固态合成中的应用

IF 7.1 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2025-05-12 DOI: 10.1021/acssuschemeng.4c0960810.1021/acssuschemeng.4c09608

Kamila Bepirszcz, Anna Maria Mazzetta, Jorge Gómez-Carpintero, Juan Domingo Sánchez, Juan F. González* and J. Carlos Menéndez*,

引用次数: 0

Multiomics Provides Insights into the Impacts of Microplastics on Heavy Metal(Loid) Accumulation in Lettuce under Simulated Acid Precipitation 模拟酸雨条件下微塑料对生菜重金属（Loid）积累的影响

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2025-05-12 DOI: 10.1021/acssuschemeng.5c03114

Li Chen, Nan Chang, Hongjie Liu, Tao Li, Fengyu Huang, Yi Zeng, Haoran He, Tianyi Qiu, Yifeng Xu, Lai Peng, Jason C. White, Linchuan Fang

{"title":"Multiomics Provides Insights into the Impacts of Microplastics on Heavy Metal(Loid) Accumulation in Lettuce under Simulated Acid Precipitation","authors":"Li Chen, Nan Chang, Hongjie Liu, Tao Li, Fengyu Huang, Yi Zeng, Haoran He, Tianyi Qiu, Yifeng Xu, Lai Peng, Jason C. White, Linchuan Fang","doi":"10.1021/acssuschemeng.5c03114","DOIUrl":"https://doi.org/10.1021/acssuschemeng.5c03114","url":null,"abstract":"Microplastics (MPs) and heavy metal(loid)s (HMs) are widespread agricultural contaminants. Acid precipitation can create acidic conditions, changing migration of these pollutants in soil-crop systems. However, the impacts of MPs on HMs uptake by crops under acid rain conditions and the underlying mechanisms that govern these processes remain unclear. We conducted pot experiments to assess MP-mediated effects on HM accumulation in lettuce (Lactuca sativa L.) under simulated acid rain. We found that high-dose polyethylene (PE) significantly increased shoot Cd accumulation in lettuce by 51.2% and that the presence of acid rain enhanced this effect, as compared to the single PE treatment. In contrast, coexposure to PE and acid rain decreased the As accumulation by 47.6%. This was primarily due to a decrease in soil pH and a change in HMs availability. In the rhizosphere, PE and acid rain positively influenced the relative abundance of Photobacterium that is the main contributor mediating the Cd/As accumulation. Additionally, acid precipitation enhanced MP stress by regulating metabolic pathways and reducing the biosynthesis of several important metabolites, including signal transduction, amino acid, and carbohydrate. Co-analysis of microbiomics and metagenomics showed the functional genes related to the metabolism of biotin, propanoate, and histidine were altered by MPs and acid precipitation, which may cause increases in the abundance of Photobacterium. These findings underscore complex interactions between MPs and acid rain on HMs transport and availability in soil-crop systems, providing important insights for evaluating their risk in farmland.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"44 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143933246","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Continuous Fabrication of Strong, Scalable, High-Yield, and Sustainable Materials from Aspen 连续制造强大的，可扩展的，高产的，和可持续的材料从杨木

IF 7.1 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2025-05-12 DOI: 10.1021/acssuschemeng.4c1037710.1021/acssuschemeng.4c10377

Abdolrahim A. Rafi, Staffan K. Nyström, Narbe Shamirza, Pietro Bartocci, Tatjana Karpenja, Cherryleen Garcia-Lindgren, Per Engstrand* and Armando Córdova*,

{"title":"Continuous Fabrication of Strong, Scalable, High-Yield, and Sustainable Materials from Aspen","authors":"Abdolrahim A. Rafi, Staffan K. Nyström, Narbe Shamirza, Pietro Bartocci, Tatjana Karpenja, Cherryleen Garcia-Lindgren, Per Engstrand* and Armando Córdova*, ","doi":"10.1021/acssuschemeng.4c1037710.1021/acssuschemeng.4c10377","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c10377https://doi.org/10.1021/acssuschemeng.4c10377","url":null,"abstract":"Lightweight materials with high strength are desirable for advanced applications in transportation, sports equipment, construction, automotive, and aerospace. Aspen is fast growing, has low flammability, and is renewable and readily available. In this study, we present a continuous, high-yielding, efficient, scalable, and sustainable approach for the fabrication of strong materials from aspen by synergistic selective chemical modification and continuous hot pressing. FTIR analysis revealed changes in the chemical composition of the wood polymers, including the introduction of anionic groups, while SEM images showed morphological and structural transformations such as smoother surfaces and a more compact wood structure. The proposed strategy achieved up to 258 MPa (530% increase) in tensile strength by combining enhanced ion-bonding and hydrogen-bonding with the alignment of cellulose nanofibrils and the solidification of softened, depolymerized lignin through cross-linking reactions. This work demonstrates the continuous large-scale production of lightweight, strong structural materials under energy-efficient and mild modification conditions, suitable for the green fabrication of next-generation advanced materials from wood.A continuous, scalable, high-yielding, and sustainable method creates strong, lightweight materials from aspen via selective chemical modification and hot pressing.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"13 20","pages":"7342–7351 7342–7351"},"PeriodicalIF":7.1,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acssuschemeng.4c10377","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144133976","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Continuous Fabrication of Strong, Scalable, High-Yield, and Sustainable Materials from Aspen 连续制造强大的，可扩展的，高产的，和可持续的材料从杨木

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2025-05-12 DOI: 10.1021/acssuschemeng.4c10377

Abdolrahim A. Rafi, Staffan K. Nyström, Narbe Shamirza, Pietro Bartocci, Tatjana Karpenja, Cherryleen Garcia-Lindgren, Per Engstrand, Armando Córdova

{"title":"Continuous Fabrication of Strong, Scalable, High-Yield, and Sustainable Materials from Aspen","authors":"Abdolrahim A. Rafi, Staffan K. Nyström, Narbe Shamirza, Pietro Bartocci, Tatjana Karpenja, Cherryleen Garcia-Lindgren, Per Engstrand, Armando Córdova","doi":"10.1021/acssuschemeng.4c10377","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c10377","url":null,"abstract":"Lightweight materials with high strength are desirable for advanced applications in transportation, sports equipment, construction, automotive, and aerospace. Aspen is fast growing, has low flammability, and is renewable and readily available. In this study, we present a continuous, high-yielding, efficient, scalable, and sustainable approach for the fabrication of strong materials from aspen by synergistic selective chemical modification and continuous hot pressing. FTIR analysis revealed changes in the chemical composition of the wood polymers, including the introduction of anionic groups, while SEM images showed morphological and structural transformations such as smoother surfaces and a more compact wood structure. The proposed strategy achieved up to 258 MPa (530% increase) in tensile strength by combining enhanced ion-bonding and hydrogen-bonding with the alignment of cellulose nanofibrils and the solidification of softened, depolymerized lignin through cross-linking reactions. This work demonstrates the continuous large-scale production of lightweight, strong structural materials under energy-efficient and mild modification conditions, suitable for the green fabrication of next-generation advanced materials from wood.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"14 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143940301","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Greenhouse Gas Emissions Associated with Pretreatment Techniques Utilized for Biosugar Production 与生物糖生产预处理技术相关的温室气体排放

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2025-05-12 DOI: 10.1021/acssuschemeng.5c00873

Sweta Balchandani, Ulises R. Gracida-Alvarez, Troy R. Hawkins, Pahola Thathiana Benavides

{"title":"Greenhouse Gas Emissions Associated with Pretreatment Techniques Utilized for Biosugar Production","authors":"Sweta Balchandani, Ulises R. Gracida-Alvarez, Troy R. Hawkins, Pahola Thathiana Benavides","doi":"10.1021/acssuschemeng.5c00873","DOIUrl":"https://doi.org/10.1021/acssuschemeng.5c00873","url":null,"abstract":"Less carbon-intensive production of biosugars from lignocellulosic materials can lead to improved manufacturing of biofuels and bioproducts. In this study, the production of biosugars is analyzed to understand the potential of producing bioproducts from biosugars with a low carbon intensity. Life-cycle assessment is conducted on five lignocellulosic feedstocks along with seven pretreatment techniques to produce biosugars as an important platform intermediate for producing bioproducts. The production of electricity using lignin with and without heat integration was also incorporated. In addition, seven bioproducts are analyzed for the estimation of the GHG emissions budget, which represents the emissions available to convert, separate, and upgrade biosugars into bioproducts within the 70% emissions reduction target. Corn stover-deacetylation and dilute acid pretreatment (CS-DDA) provide the lowest GHG emissions for biosugar (0.03 kg CO2 eq/kg biosugar) and thereby the highest GHG emissions budget for the case of lactic acid production (3.76 kg CO2 eq/kg lactic acid). Natural gas and chemicals are the major contributors to all of the pretreatment techniques under study. The outcomes from this study can benefit the advancement of upcoming biobased processes that meet decarbonization targets.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"32 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143940302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0