Journal of Materials Science: Materials in Electronics最新文献

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Exploring the synthesis, characterization, electrical, and magnetic behavior of crystalline Ni1-xZnxFe2O4 nanoparticles 探索晶体 Ni1-xZnxFe2O4 纳米粒子的合成、表征、电学和磁学行为
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-12 DOI: 10.1007/s10854-024-13448-w
Kiran T. Adsure, Sumant B. Jagtap, Shivkumar R. Newaskar, Kiran B. Kore, Adinath M. Funde, Sunil M. Patange, Dattatray J. Late
{"title":"Exploring the synthesis, characterization, electrical, and magnetic behavior of crystalline Ni1-xZnxFe2O4 nanoparticles","authors":"Kiran T. Adsure, Sumant B. Jagtap, Shivkumar R. Newaskar, Kiran B. Kore, Adinath M. Funde, Sunil M. Patange, Dattatray J. Late","doi":"10.1007/s10854-024-13448-w","DOIUrl":"https://doi.org/10.1007/s10854-024-13448-w","url":null,"abstract":"<p>A versatile material family, Ni<sub>1-x</sub>Zn<sub>x</sub>Fe<sub>2</sub>O<sub>4</sub> with x = 0.4 and 0.6, was synthesized via the chemical combustion method. The structural, opto-electrical, and magnetic properties were investigated using various techniques, such as X-ray diffraction (XRD), ultraviolet–visible (UV–Vis) spectroscopy, Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy, scanning electron microscope and energy-dispersive spectroscopy (SEM–EDS), X-ray photoelectron spectroscopy (XPS), and vibrating sample magnetometry (VSM). The XRD validates the cubic spinel-type arrangement within the Fd3m space group and reveals the crystalline sizes for x = 0.4 and 0.6 to be 45 and 39 nm, respectively. Furthermore, for the surface morphology of the sample and elemental stoichiometry, the SEM and EDS were studied. The UV–Vis spectroscopy and FTIR studies reveal the alternation of structure and modifications in the optical band gap of x = 0.4 and 0.6 as 2.0 and 2.18 eV, respectively, resulting from the incorporation of Zn ions. The XPS analysis was carried out to confirm the chemical bonding environment of elements and binding energy. The magnetization behavior at room temperature demonstrated a decrease in the magnetic saturation (Ms) of Ni ferrite with an increase in Zn content. The electrical characteristics indicated semiconductor-like behavior for both samples. Further, the impedance measurement is consistent for double and single semicircular arcs at the chosen temperature. This observation underscores the significant role of grain and grain boundaries influencing magnetic properties. The values of the dielectric constants (ε′) were evaluated within the 20 Hz to 5 MHz frequency range under varying temperatures, demonstrating a pronounced decrease with rising frequency.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210285","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Growth, characterization, spectroscopic examination and computational analysis of optical properties of 3-Carboxypropanaminium DL-tartrate single crystal 酒石酸 3-羧基丙铵单晶的生长、表征、光谱检测和光学特性计算分析
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-12 DOI: 10.1007/s10854-024-13444-0
C. Usha, Ali Raza Ayub, Anthoniammal Panneerselvam, M. Sumithra Devi, R. Jayashree, Tahani Mazyad Almutairi, Gautham Devendrapandi, Ranjith Balu
{"title":"Growth, characterization, spectroscopic examination and computational analysis of optical properties of 3-Carboxypropanaminium DL-tartrate single crystal","authors":"C. Usha, Ali Raza Ayub, Anthoniammal Panneerselvam, M. Sumithra Devi, R. Jayashree, Tahani Mazyad Almutairi, Gautham Devendrapandi, Ranjith Balu","doi":"10.1007/s10854-024-13444-0","DOIUrl":"https://doi.org/10.1007/s10854-024-13444-0","url":null,"abstract":"<p>A slow evaporation solution growth approach was used for synthesizing 3-carboxypropanaminium DL-tartrate (3CPT). Powder X-ray diffraction verified the crystallinity of the material. The crystal’s optical characteristics and transmittance are revealed by the UV–Visible spectroscopic analysis. The crystal’s thermal equilibrium has been investigated using TGA/DTA testing. To study the crystal’s carbon and hydrogen environment, the FT NMR spectra were used. The present compound was investigated using both experimental and theoretical quantum calculations (optimized structure and IR) with the use of DFT theory at the B3LYP functional and 6–311 + + G(d, p) basis set. Molecular orbitals for the HOMO and LUMO states show that the molecule experienced a significant change in charge. The molecule is subjected to ELF and LOL for topological research. The 3CPT has NLO characteristics, according to the hyperpolarizability calculations.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of crystallite size of LiCu0.5Fe2-yCeyO4 nanospinel ferrites on opto-dielectric properties LiCu0.5Fe2-yCeyO4 纳米星形铁氧体的晶粒尺寸对光介电性能的影响
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-12 DOI: 10.1007/s10854-024-13461-z
Manal F. Abou Taleb, F. Afzal, Q. Hussain, Mohamed M. Ibrahim, Zeinhom M. El-Bahy, A. U. Rahman
{"title":"Impact of crystallite size of LiCu0.5Fe2-yCeyO4 nanospinel ferrites on opto-dielectric properties","authors":"Manal F. Abou Taleb, F. Afzal, Q. Hussain, Mohamed M. Ibrahim, Zeinhom M. El-Bahy, A. U. Rahman","doi":"10.1007/s10854-024-13461-z","DOIUrl":"https://doi.org/10.1007/s10854-024-13461-z","url":null,"abstract":"<p>This study explores the impact of crystallite size on the opto-dielectric properties of LiCu<sub>0.5</sub>Fe<sub>2-y</sub>Ce<sub>y</sub>O<sub>4</sub> (<i>y</i> = 0.0, 0.01, 0.02, 0.03, 0.04) nanospinel ferrites (NSFs) synthesized via sol–gel auto-combustion. X-ray diffraction (XRD) analysis confirmed the crystalline nature and phase purity, revealing variations in crystallite size within the nanoscale range. Fourier-transform infrared spectroscopy (FTIR) provided insights into chemical bonding, affirming the composition and structure reliability. Morphological characterization via scanning electron microscopy (SEM) and transmission electron microscopy (TEM) revealed the nanostructure, highlighting the influence of crystallite size on particle morphology, shape, and size distribution. Energy-dispersive X-ray spectroscopy (EDX) verified the presence of expected elements, with elemental composition offering spatial distribution insights. Inductively coupled plasma (ICP) analysis quantified elemental concentrations, focusing on Li, Cu, Fe, and Ce. Optical properties, including UV–vis absorption spectra, were measured to assess band gap energies. Dielectric measurements across a range of frequencies provided insights into the pure Li-Cu NSFs and Ce<sup>3+</sup> doped Li-Cu NSFs dielectric response, revealing variations in dielectric constant and loss tangent with changing crystallite size. The findings highlighted the significant role of crystallite size in modulating both energy band gap and dielectric properties, essential for applications in high-frequency, photonics, electronics, and sensor technologies.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142226697","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, crystal growth and characterization on a novel third-order nonlinear optical single crystal: 2-amino-3,5-dibromopyridinium-2-chloro-4-nitrobenzoate 新型三阶非线性光学单晶:2-氨基-3,5-二溴吡啶鎓-2-氯-4-硝基苯甲酸盐的合成、晶体生长与表征
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-12 DOI: 10.1007/s10854-024-13481-9
A. Santha, V. Kannan, T. C. Sabari Girisun, S. Ganesamoorthy, S. Brahadeeswaran
{"title":"Synthesis, crystal growth and characterization on a novel third-order nonlinear optical single crystal: 2-amino-3,5-dibromopyridinium-2-chloro-4-nitrobenzoate","authors":"A. Santha, V. Kannan, T. C. Sabari Girisun, S. Ganesamoorthy, S. Brahadeeswaran","doi":"10.1007/s10854-024-13481-9","DOIUrl":"https://doi.org/10.1007/s10854-024-13481-9","url":null,"abstract":"<p>Novel organic compound with significant third-order nonlinear optical properties, namely, 2-amino-3,5-dibromopyridinium-2-chloro-4-nitrobenzoate (ADBPCN), was successfully synthesized, and optical-quality single crystals are grown at room temperature through the slow evaporation method, employing methanol as a solvent. Single-crystal X-ray diffraction (SCXRD) investigation showed that ADBPCN was crystallized in centrosymmetric space group <span>(Poverline{1})</span>. Phase purity and crystallinity of the grown sample were evaluated by powder X-ray diffraction (PXRD) analysis. The transmittance range, cut-off wavelength and optical band gap of the grown crystal were determined through ultraviolet-visible (UV-Vis) spectral analysis. The optical parameters of the ADBPCN crystal, including refractive index (<i>n</i><sub>o</sub>) and reflectance (<i>R</i>), were also measured. Fourier transform infrared (FTIR) analysis was used to determine vibrational properties and main functional groups. The photoluminescence spectrum showed sharp emission peaks, indicating the violet and blue light emission. Thermogravimetric (TG) and differential thermal analysis (DTA) techniques are used to analyze the thermal characteristics of the ADBPCN crystals. The percentage of hydrogen bonding interactions was evaluated through the Hirshfeld surface fingerprint plot. The third-order nonlinear optical parameters of the ADBPCN compound were analyzed by the Z-scan method using a nanosecond Nd:YAG laser.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210286","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Organometallic hexa-aqua magnesium hydrogen maleate third-order nonlinear optical crystal for NLO and optoelectronic device applications 用于 NLO 和光电器件应用的有机金属六水合马来酸氢镁三阶非线性光学晶体
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-12 DOI: 10.1007/s10854-024-13469-5
Y. K. Pratheesha Mol, S. Vinu, S. Keerthi Gopakumar, S. Sindhusha, R. Sheela Christy, G. Vinitha
{"title":"Organometallic hexa-aqua magnesium hydrogen maleate third-order nonlinear optical crystal for NLO and optoelectronic device applications","authors":"Y. K. Pratheesha Mol, S. Vinu, S. Keerthi Gopakumar, S. Sindhusha, R. Sheela Christy, G. Vinitha","doi":"10.1007/s10854-024-13469-5","DOIUrl":"https://doi.org/10.1007/s10854-024-13469-5","url":null,"abstract":"<p>Hexa-aqua magnesium hydrogen maleate single crystal was generated by slow evaporation method. By using single-crystal X-ray diffraction, the crystal structure of hexa-aqua magnesium hydrogen maleate has been identified. It is a member of the monoclinic system with space group P21/c and the lattice parameter as <i>A</i> = 10.207(5) Å, <i>B</i> = 11.829(5) Å, <i>C</i> = 6.745(3) Å, and volume <i>V</i> = 789.499 Å<sup>3</sup>. FTIR spectroscopy was used to analyze the crystal’s functional groups. Thermogravimetric and differential thermal analyses have been used to examine the thermal stability and melting point of the hexa-aqua magnesium hydrogen maleate single crystal. UV–vis transmittance spectrum was identified in the range of 200–1100 nm. The band gap of an HMHM single crystal (E<sub>g</sub>) has been calculated using extrapolation of the linear component with 4.9 eV. Vickers microhardness experiments were used to examine the crystal’s mechanical stability. The grown material belongs to soft category with ‘<i>n</i>’ value of 2.7. The hyperconjugative interaction was explained using the natural bond orbital (NBO) approach. The HOMO–LUMO plot was used to determine the molecule’s chemical potential, electronegativity, and chemical hardness.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142226698","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrothermally synthesized nanostructured NiTiO3 thick films for H2S and room temperature CO2 gas sensing 用于 H2S 和室温 CO2 气体传感的水热合成纳米结构 NiTiO3 厚膜
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-11 DOI: 10.1007/s10854-024-13429-z
Manoj A. More, Swapnil A. More, Matthew D. Femi, Gotan H. Jain, Sarika D. Shinde, Dnyaneshwari Y. Patil, Dnyaneshwar D. Kajale, Ganesh E. Patil
{"title":"Hydrothermally synthesized nanostructured NiTiO3 thick films for H2S and room temperature CO2 gas sensing","authors":"Manoj A. More, Swapnil A. More, Matthew D. Femi, Gotan H. Jain, Sarika D. Shinde, Dnyaneshwari Y. Patil, Dnyaneshwar D. Kajale, Ganesh E. Patil","doi":"10.1007/s10854-024-13429-z","DOIUrl":"https://doi.org/10.1007/s10854-024-13429-z","url":null,"abstract":"<p>In this work we are presenting the hydrothermal method to synthesize NiTiO<sub>3</sub> perovskite nanoparticles (NPs). The effect of variation in reaction temperature on the structural, optical, electrical and gas sensing properties of NiTiO<sub>3</sub> nanoparticles was investigated. The nanoparticles synthesized at different reaction temperatures were characterized by various characterization methods like XRD, FTIR, UV–Visible Spectroscopy, FESEM, TEM, HRTEM and SAED. The results of UV–Visible analysis revealed that band gap of NiTiO<sub>3</sub> decreased from 2.90 to 2.56 eV on increase in reaction temperature from 140 to 200 °C. The XRD analysis showed that crystallite size decreased in the range of 21 to 12 nm on increase in reaction temperature. The various parameters of the material like dislocation density, microstrain and crystallinity were also calculated from XRD data. The average particle size was estimated by FESEM analysis and found to be decreased on increase in reaction temperature. FTIR analysis confirmed the formation of NiTiO<sub>3</sub>. Study of electrical properties proved the semiconducting behaviour of NiTiO<sub>3</sub>. The detail analysis of NiTiO<sub>3</sub> sensor characteristics in terms of sensitivity, selectivity, response and recovery time was carried out. The study of gas sensing performance of NiTiO<sub>3</sub> revealed that NiTiO<sub>3</sub> synthesized at 140 °C showed maximum sensitivity to CO<sub>2</sub> gas at room temperature, whereas NiTiO<sub>3</sub> synthesized at 200 °C showed maximum sensitivity to H<sub>2</sub>S gas at 250 °C.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210266","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Ni doping on the magnetic and photocatalytic properties of CoFe2O4 nanoparticles 掺杂镍对 CoFe2O4 纳米粒子的磁性和光催化性能的影响
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-11 DOI: 10.1007/s10854-024-13449-9
Ali Raza, Arslan Bashir, Ejaz Muhammad, Tariq Jan
{"title":"Effect of Ni doping on the magnetic and photocatalytic properties of CoFe2O4 nanoparticles","authors":"Ali Raza, Arslan Bashir, Ejaz Muhammad, Tariq Jan","doi":"10.1007/s10854-024-13449-9","DOIUrl":"https://doi.org/10.1007/s10854-024-13449-9","url":null,"abstract":"<p>The current study aimed to access photocatalytic degradation of methylene blue (MB) dye using undoped CoFe<sub>2</sub>O<sub>4</sub>, 2%, 4%, and 6% Ni-doped CoFe<sub>2</sub>O<sub>4</sub> nanoparticles synthesized via chemical co-precipitation method. X-ray diffraction (XRD) was performed for structural analysis which confirmed the spinel cubic structure of the prepared nanoparticles. Scanning electron microscopy (SEM) was performed for surface and morphological study revealing the agglomeration of nanoparticles due to magnetic behavior of CoFe<sub>2</sub>O<sub>4</sub> nanoparticles. UV–visible absorption spectroscopy was performed, and bandgap was calculated using tauc plot, which revealed that bandgap increases with increasing Ni doping concentration in CoFe<sub>2</sub>O<sub>4</sub> nanoparticles. Vibrating-sample magnetometry (VSM) was performed to study the magnetic behavior of synthesized nanoparticles, and it was observed that the saturation magnetization value is higher for 2% Ni-doped CoFe<sub>2</sub>O<sub>4</sub> nanoparticles. Photocatalytic activities for the prepared samples were analyzed for MB as an organic pollutant. 2% Ni-doped sample possessed greater efficiency of 67% in degrading the organic pollutant (MB), whereas pure cobalt ferrite possessed 51.6%, respectively. This superior Photocatalytic performance of 2% Ni-doped cobalt ferrite nanoparticles may be associated with introduction of localized defect states that may lead to trapping of electrons to prevent their recombination and enhanced visible light absorption. These findings imply the potential of Ni-doped CoFe<sub>2</sub>O<sub>4</sub> photocatalysts for the degradation of organic pollutants in wastewater.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142226742","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication and characterization of modulation-doped β-(AlxGa1−x)2O3/Ga2O3 tri-metal FET utilizing ultra-high vacuum deposition based on plasma-assisted molecular beam epitaxy 利用基于等离子体辅助分子束外延的超高真空沉积技术制造调制掺杂的 β-(AlxGa1-x)2O3/Ga2O3 三金属场效应晶体管并确定其特性
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-11 DOI: 10.1007/s10854-024-13430-6
V. N. Senthil Kumaran, M. Venkatesh, Azath Mubarakali, Abdulrahman Saad Alqahtani, P. Parthasarathy
{"title":"Fabrication and characterization of modulation-doped β-(AlxGa1−x)2O3/Ga2O3 tri-metal FET utilizing ultra-high vacuum deposition based on plasma-assisted molecular beam epitaxy","authors":"V. N. Senthil Kumaran, M. Venkatesh, Azath Mubarakali, Abdulrahman Saad Alqahtani, P. Parthasarathy","doi":"10.1007/s10854-024-13430-6","DOIUrl":"https://doi.org/10.1007/s10854-024-13430-6","url":null,"abstract":"<p>This study investigates the design of MOD-FETs (modulation-doped field effect transistors) using β-Ga<sub>2</sub>O<sub>3</sub> as the substrate material. The main focus is on understanding the impact of self-heating on the alteration of mobility of electrons profile. This paper introduces a model that takes into account the influence on temperature and doping on the electron mobility in β-Ga<sub>2</sub>O<sub>3</sub>. Furthermore, it offers estimations for the conductivity of heat of β-Ga<sub>2</sub>O<sub>3</sub>, considering the influence of temperature and crystalline orientation. Furthermore, we showcase a practical example of modulation-doped β-(Al<sub>x</sub>Ga<sub>1-x</sub>)<sub>2</sub>O<sub>3</sub>/Ga<sub>2</sub>O<sub>3</sub> using a tri-metal FET where the energy level difference between the conduction bands and the presence of undesired channels in the barrier layer determines the maximum sheet carrier density in this structure. These channels enable the transfer of electrons from both the bottom and upper portions of the β-Ga<sub>2</sub>O<sub>3</sub> quantum well. Using modulation doping, the proposed structure exhibited an ultimate current drain of 250 mA/m, a peak conductivity of 40 ms/m, and a potential of 10.0 V at ambient temperature. The electrical characteristics of the TMG device were evaluated by comparing it to the double-metal gate (DMG) device using the Atlas Silvaco TCAD simulation for analysis of performance. The results indicate that, the suggested device exhibits greater efficiency in terms of conductivity, current gain cut-off frequency, and energy gain cut-off frequency as compared to DMG transistors. The measured electric field in this example is a consequence of using a Tri-Metal Gate architecture (TMG) to regulate the channel. The designed setup achieves peak frequency of 45.5/50.5 gigahertz with a gate length of 0.2 mm. This discovery highlights the potential of using the β-(Al<sub>x</sub>Ga<sub>1−x</sub>)<sub>2</sub>O<sub>3</sub>/Ga<sub>2</sub>O<sub>3</sub> with tri-metal FET architecture as a promising method for high-power radio frequency operations.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210398","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dielectric properties and impedance spectroscopic study of (1−x)[0.90NaNbO3–0.10Bi(Mg0.5Ta0.5)O3]–x(Bi0.5Na0.5)0.7(Sr0.7La0.2)0.3Ti0.9Zr0.1O3 ceramics (1-x)[0.90NaNbO3-0.10Bi(Mg0.5Ta0.5)O3]-x(Bi0.5Na0.5)0.7(Sr0.7La0.2)0.3Ti0.9Zr0.1O3 陶瓷的介电性能和阻抗谱研究
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-11 DOI: 10.1007/s10854-024-13474-8
Qin Gao, Nianshun Zhao, Jiale Wu, Qi Yu, Li Wang, Juan Hu, Sha Lu, Xiaofan Zheng
{"title":"Dielectric properties and impedance spectroscopic study of (1−x)[0.90NaNbO3–0.10Bi(Mg0.5Ta0.5)O3]–x(Bi0.5Na0.5)0.7(Sr0.7La0.2)0.3Ti0.9Zr0.1O3 ceramics","authors":"Qin Gao, Nianshun Zhao, Jiale Wu, Qi Yu, Li Wang, Juan Hu, Sha Lu, Xiaofan Zheng","doi":"10.1007/s10854-024-13474-8","DOIUrl":"https://doi.org/10.1007/s10854-024-13474-8","url":null,"abstract":"<p>The solid-state reaction method was employed to synthesize (1−<i>x</i>)[0.90NaNbO<sub>3</sub>–0.10Bi(Mg<sub>0.5</sub>Ta<sub>0.5</sub>)O<sub>3</sub>]–<i>x</i>(Bi<sub>0.5</sub>Na<sub>0.5</sub>)<sub>0.7</sub>(Sr<sub>0.7</sub>La<sub>0.2</sub>)<sub>0.3</sub>Ti<sub>0.9</sub>Zr<sub>0.1</sub>O<sub>3</sub>, denoted as (1−<i>x</i>)(NN–BMT)–<i>x</i>BNSLTZ (<i>x</i>BNSLTZ). XRD analysis of <i>x</i>BNSLTZ confirmed that all samples possessed a pure perovskite structure. SEM micrographs demonstrated homogeneous grain distribution and minimal porosity. With an increasing concentration of BNSLTZ, there was a gradual reduction in average grain size. Impedance spectroscopy was utilized to investigate the electrical properties of <i>x</i>BNSLTZ across a frequency sweep of 10 Hz–1 MHz and over a temperature range of 420–560 °C. The complex impedance and modulus spectra reveal non-Debye-type dielectric relaxation, indicative of two contributing mechanisms: grain and grain boundary effects on conduction. Electric modulus analysis indicated that the low-frequency relaxation process was temperature independent. The dc conductivity variation with temperature follows the Arrhenius equation. The ac conductivity was found to adhere to Jonscher power law. The <i>E</i><sub><i>a</i></sub> (the relaxation activation energy) and <i>E</i><sub><i>c</i></sub> (conductance activation energy) confirmed the relaxation mechanism of 0.3BNSLTZ is dipolar conduction. The dielectric properties showed a significant dependence on both frequency and temperature. A dielectric anomaly pointed to the presence of a single relaxation behavior. It was observed that an increase in BNSLTZ concentration led to a decrease in the maximum dielectric constant. Optimum performance was obtained with the 0.3BNSLTZ ceramics, which has the smallest average grain size (1.54 μm), considerable resistance value (<i>R</i> ~ 1000 K <span>({Omega }cm)</span>), and moderate dielectric constant (<i>ε</i><sub>r</sub> ~ 600), superior to the pure NN-BMT ceramic. These results demonstrate that the electrical property of the <i>x</i>BNSLTZ ceramics have some potential value in the application of electrical materials.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210396","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Eco-friendly water-induced lithium oxide/polyethyleneimine ethoxylated as a possible gate dielectric of the organic field effect transistor 环保型水诱导氧化锂/聚乙烯亚胺乙氧基化物可作为有机场效应晶体管的栅极电介质
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-11 DOI: 10.1007/s10854-024-13391-w
Ali Bahari
{"title":"Eco-friendly water-induced lithium oxide/polyethyleneimine ethoxylated as a possible gate dielectric of the organic field effect transistor","authors":"Ali Bahari","doi":"10.1007/s10854-024-13391-w","DOIUrl":"https://doi.org/10.1007/s10854-024-13391-w","url":null,"abstract":"<p>It seems impossible to use silicon oxide as a suitable gate dielectric material in metal-oxide-semiconductor field effect transistors. Many researchers have studied various metal oxides, nitrides, composite, and hybrid materials in search of dielectric materials that can replace silicon oxide. Each of these materials has advantages and disadvantages. In the present work, water-induced Lithium oxide (LiO<sub>x</sub>) with the organic PEIE (polyethylene imine ethoxylated) materials has been synthesized and studied. One advantage of the present work is using deionized water for getting (LiO<sub>x</sub>) precursor solution from lithium nitrate without the use of any toxic additives, resulting in a low cost-effective and eco-friendly synthesis. By fabricating three organic field effect transistors (OFETs) with LiO<sub>x</sub>/ PEIE nanocomposite materials with the same weight ratio (1:1), desirable electrical characteristics such as higher carrier mobility (μ) of 47.3 cm<sup>2</sup>V<sup>−1</sup> S<sup>−1</sup> , higher on-off current ratio (Ion/Ioff) of ∼10<sup>5</sup> , minima threshold voltage (V<sub>th</sub>) shift of ∼ 0.6 (±0.2) V, lower subthreshold swing (SS) of 3.12 mV/decade and lower tunneling-, and leakage current density (J) of 2 (nA/cm<sup>2</sup>) could be found which demonstrated eco-friendly water-induced LiO<sub>x</sub>/ PEIE can be used as an alternative gate dielectric for the future of the OFET devices.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210397","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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