Journal of Materials Science: Materials in Electronics最新文献

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Tuning the multiferroic properties of spinel nickel ferrite via zinc doping 通过锌掺杂调整尖晶石镍铁酸体的多铁性
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-05-20 DOI: 10.1007/s10854-025-14916-7
O. Rosales-González, A. M. Bolarín-Miró, F. Pedro-García, C. A. Cortes-Escobedo, A. Barba-Pingarrón, F. Sánchez-De Jesús
{"title":"Tuning the multiferroic properties of spinel nickel ferrite via zinc doping","authors":"O. Rosales-González,&nbsp;A. M. Bolarín-Miró,&nbsp;F. Pedro-García,&nbsp;C. A. Cortes-Escobedo,&nbsp;A. Barba-Pingarrón,&nbsp;F. Sánchez-De Jesús","doi":"10.1007/s10854-025-14916-7","DOIUrl":"10.1007/s10854-025-14916-7","url":null,"abstract":"<div><p>This work presents a systematic investigation of the effects of the crystal structure and cation distribution on the multiferroic properties of the zinc-doped ferrite Ni<sub>1-x</sub>Zn<sub>x</sub>Fe<sub>2</sub>O<sub>4</sub> (0 ≤ x ≤ 1, Δx = 0.1) synthesized via high–energy ball milling followed by heat treatment. X-ray diffraction (XRD) analysis confirmed the successful synthesis of cubic spinel ferrite across all the studied compositions, whereas structural changes, such as lattice size, porosity and crystallite size, exhibited compositional dependence. Scanning electron microscopy (SEM) of the pellet surfaces revealed the dependence of the grain size distribution and porosity on the zinc content. Raman spectroscopy analysis allows the determination of the distribution of cations as a function of the Zn content, revealing the change from an inverse to a mixed spinel structure. X-ray photoelectron spectroscopy (XPS) allows the determination of the cations of Ni<sup>2+</sup>, Ni<sup>3+</sup>, Fe<sup>2+</sup> and Fe<sup>3+</sup> distributed in tetrahedral and octahedral sites, resulting in new magnetic and dielectric interactions in the samples. Magnetic hysteresis loops confirmed the ferromagnetic ordering of the synthesized ferrites, with saturation magnetization values ranging from 40 to 76 emu/g for 0 to 0.5 mol of Zn, respectively. The observed increases in relative permittivity and conductivity with increasing zinc content are attributed to the redistribution of Fe<sup>3+</sup> ions within the crystal lattice, which is modulated by the Zn doping level. These findings confirm that bulk zinc-doped nickel ferrites synthesized by high–energy ball milling exhibit improved ferromagnetic and dielectric properties, suggesting potential for expanded technological applications.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 14","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144100379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electromagnetic shielding effectiveness of surface modified porous watermelon rinds biochar nutmeg short fibre reinforced lightweight vinyl ester biocomposite 表面改性多孔西瓜皮生物炭肉豆蔻短纤维增强轻质乙烯基酯生物复合材料的电磁屏蔽效果
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-05-20 DOI: 10.1007/s10854-025-14878-w
K. Kanchana, K. J. Anoop, V. P. Vinod, K. K. Kavitha, Mathur Nadarajan Kathiravan
{"title":"Electromagnetic shielding effectiveness of surface modified porous watermelon rinds biochar nutmeg short fibre reinforced lightweight vinyl ester biocomposite","authors":"K. Kanchana,&nbsp;K. J. Anoop,&nbsp;V. P. Vinod,&nbsp;K. K. Kavitha,&nbsp;Mathur Nadarajan Kathiravan","doi":"10.1007/s10854-025-14878-w","DOIUrl":"10.1007/s10854-025-14878-w","url":null,"abstract":"<div><p>The present research aims to develop an Electromagnetic interference (EMI) shielding which is light weight by natural fiber, and filler reinforced polymer composite. The novelty of this study producing composite using waste biomass by treating the fiber and filler surface modification. As well as analysing the mechanical, dielectric, and EMI shielding efficiency of the composite in accordance to the ASTM (American Society for Testing and Materials) standard. The study founded that composite VNB2, with 2.0 vol.% biochar and 30 vol.% silane-treated nutmeg shell fiber, demonstrates the best mechanical performance, with a tensile strength of 154 MPa, tensile modulus of 5.6 GPa, flexural strength of 221 MPa, flexural modulus of 6.1 GPa, and it is 175%, 229.4%, 151.1%, 177.3%, respectively. However, the impact strength and hardness properties are improved with increase filler content of 4 vol.% of biochar and 30 vol.% silane-treated nutmeg shell fiber on composite VNB3, that is 5.8 J, and 90 shore-d and it is 383.3%and 9.8% increase when compared plain vinyl ester composite V, respectively, suggests that the combination of fiber and biochar provides excellent toughness. Similarly, the dielectric constant of VNB3 reaches 6.62, 5.57, 4.41, and 3.89 at E, F, I, and J, respectively, which it is 97.02%, 104.02%, 99.54%, 131.54%, respectively, due to the formation of conductive networks and improved interfacial polarization. Additionally, the highest EMI shielding effectiveness is observed in VNB3, reaching 8.82, 14.28, 20.16, and 29.82 dB at E, F, I, and J, respectively and it is 299.09% 61.90%, 52.38% 50.22%, respectively, indicating that the increased biochar content enhances charge transport and multiple reflections, optimizing wave attenuation. Owing to such features it could be applied in most of electric and electronic equipment used industries like space craft, communication, navigation, medical, automobile, and information technology, etc.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 14","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144091004","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Crystal growth, thermal and third-order NLO property of a novel 4-aminopyridine cuminaldehyde organic single crystal for photonics and optoelectronic devices 光电子器件用新型4-氨基吡啶孜然醛有机单晶的晶体生长、热学和三阶NLO性质
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-05-19 DOI: 10.1007/s10854-025-14864-2
G. Kanagan, J. Thirupathy, K. Mohanapandian
{"title":"Crystal growth, thermal and third-order NLO property of a novel 4-aminopyridine cuminaldehyde organic single crystal for photonics and optoelectronic devices","authors":"G. Kanagan,&nbsp;J. Thirupathy,&nbsp;K. Mohanapandian","doi":"10.1007/s10854-025-14864-2","DOIUrl":"10.1007/s10854-025-14864-2","url":null,"abstract":"<div><p>An innovative method for growing single crystals of 4-aminopyridine cuminaldehyde (4-AC) has been developed: the slow evaporation solution approach. Several characterizations, including a single crystal X-ray diffraction study, confirmed that the generated crystal had a monoclinic structure and belonged to the centrosymmetric space group P2<sub>1</sub>/c. The generated crystal structure is verified using the powder X-ray diffraction method. The several functional groups in 4-AC crystal were identified using FTIR spectra. The band gap energy values were determined using the Tauc plot and the transmittance was identified using the UV–Vis–NIR optical transmittance analysis. Fluorescence (FL) utilized to identify wavelength of the crystal emissions. To measure the sample's mechanical strength and stability, the Vickers microhardness tester was used. Through TG-DTG experiments, the formed crystal's thermal stability (melting point) has been studied. The structure and chemical characteristics of the produced 4-AC single crystal were determined by a spectroscopic research using <sup>1</sup>H NMR and 13C NMR. The crystal's particle size was determined by a dynamic light scattering (DLS) experiment. To study the third-order NLO response in a 4-AC organic NLO single crystal, the Z-scan measuring method was used. For use in optoelectronic devices and photonic applications, a newly grown single crystal produced using 4-aminopyridine cuminaldehyde is suggested.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 14","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144084812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green synthesis of meso-porous CuFe2O4 nanoparticles through aloe-vera assisted sol–gel auto-combustion method 芦荟辅助溶胶-凝胶自燃烧法绿色合成介孔CuFe2O4纳米颗粒
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-05-18 DOI: 10.1007/s10854-025-14930-9
Prabhakar Ningayya Patil, Sarvesh Kumar, Ashwini Anshu, V. M. Jali, B. Sahoo
{"title":"Green synthesis of meso-porous CuFe2O4 nanoparticles through aloe-vera assisted sol–gel auto-combustion method","authors":"Prabhakar Ningayya Patil,&nbsp;Sarvesh Kumar,&nbsp;Ashwini Anshu,&nbsp;V. M. Jali,&nbsp;B. Sahoo","doi":"10.1007/s10854-025-14930-9","DOIUrl":"10.1007/s10854-025-14930-9","url":null,"abstract":"<div><p>An environmentally friendly green technology approach was employed to synthesize CuFe<sub>2</sub>O<sub>4</sub> nanoparticles at a lower temperature using the sol–gel auto-combustion method with natural aloe-vera as a green fuel, followed by annealing of the sample at 400 ºC. The structural, morphological, vibrational, mechanical, optical, surface area and magnetic characterizations were performed using XRD, SEM-EDAX, FTIR-Raman, UV-DRS, BET and VSM techniques. XRD pattern reveals the CuFe<sub>2</sub>O<sub>4</sub> spinel cubic phase (<i>Fd3m-227</i>) with trace amounts of CuO and α-Fe<sub>2</sub>O<sub>3</sub> phases. The estimated crystallite sizes for as-prepared and annealed samples were found to increase. An agglomerated morphology with irregular shape of particles was observed. Raman spectroscopy identified five vibrational modes of the CuFe<sub>2</sub>O<sub>4</sub> phase. FTIR analysis detected tetrahedral and octahedral metal–oxygen modes, providing a deeper understanding of the sample’s mechanical behaviour. The bulk-to-rigidity modulus ratio (<i>B/G</i>) of ~ 1.530 to 1.538, and Cauchy pressure (<i>C</i><sub><i>p</i></sub>) of ~ − 1.98 and − 2.50 GPa for as-prepared and annealed samples confirm the material’s brittle mechanical nature. The optical bandgap (~ 1.60 eV) and Urbach energy (~ 0.369 eV) values were very similar for both as-prepared and annealed samples. The samples exhibit semiconducting behavior with significant defect levels, as confirmed by analysis of Urbach energy. The specific surface area of 107.37 m<sup>2</sup>/g and 74.63 m<sup>2</sup>/g, and pore size between 6.49 nm and 6.98 nm confirmed the mesoporosity of the prepared samples. The magnetic analysis revealed the S-shaped hysteresis curves with soft ferrimagnetic behaviour with a lower magnetic saturation value of ~ 6.8 emu/g, magnetic remanence of ~ 0.48 emu/g, and coercivity ranging from 80 to 97 Gauss. The magnetic saturation decreases while increasing coercive field and magnetic anisotropy as crystallite size increases with an increase in annealing temperature to 400 ºC. The magnetic and optical properties of prepared copper ferrite nanoparticles indicate their green synthesis and their potential for catalysis, magnetic separation, electromagnetic shielding, and biomedical applications.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 14","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144073821","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comprehensive study on fabrication, characterization and performance evaluation of Ag/TiOx/ITO and Au/Ag/TiOx/ITO memristors Ag/TiOx/ITO和Au/Ag/TiOx/ITO忆阻器的制备、表征和性能评价的综合研究
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-05-18 DOI: 10.1007/s10854-025-14894-w
Kubra Saka, Dincer Gokcen, Halil Ibrahim Efkere, Cem Bayram, Suleyman Ozcelik
{"title":"Comprehensive study on fabrication, characterization and performance evaluation of Ag/TiOx/ITO and Au/Ag/TiOx/ITO memristors","authors":"Kubra Saka,&nbsp;Dincer Gokcen,&nbsp;Halil Ibrahim Efkere,&nbsp;Cem Bayram,&nbsp;Suleyman Ozcelik","doi":"10.1007/s10854-025-14894-w","DOIUrl":"10.1007/s10854-025-14894-w","url":null,"abstract":"<div><p>The structure of electrodes and active materials in memristors plays a critical role in determining their electrical behavior. This study primarily focuses on Ag/TiOₓ/ITO and Au/Ag/TiOₓ/ITO memristors incorporating titanium oxide (TiOₓ) thin films with varying thicknesses (25, 50, and 100 nm), deposited via RF magnetron sputtering onto ITO-coated glass substrates. Comprehensive surface characterization techniques, including scanning electron microscopy (SEM), electron dispersive X-ray spectroscopy (EDX), atomic force microscopy (AFM), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS), were employed to examine the morphological, structural, and chemical properties of the films. SEM–EDX mapping revealed thickness dependent elemental distributions. AFM analysis showed increased surface roughness (1.69 to 2.15 nm) and grain size (60 to 90 nm) with increasing film thickness. XPS measurements conducted at 8-week intervals provided insights into the oxidation behavior of Ag electrodes and their surface chemistry evolution over time. Raman analysis confirmed the presence of anatase and rutile phases in the titanium oxide thin films, as evidenced by the characteristic peaks observed at 196.83 cm<sup>−1</sup> and 607.43 cm<sup>−1</sup>, respectively. Focused ion beam (FIB) and scanning transmission electron microscopy (STEM)-EDX were also utilized to investigate elemental boundaries between the layers. Bipolar resistive switching behavior, without the need for any electroforming process, was observed in all devices within 7 days of fabrication and remained stable throughout 1000 current–voltage (I–V) cycles. After 8 weeks of storage, further endurance tests were conducted using ± 1.5 V SET and RESET voltages, with HRS and LRS values measured at a read voltage of 0.5 V. Notably, the highest HRS/LRS ratio of 16.07 was achieved in the Ag/TiO<sub>x</sub>/ITO memristor with a 100 nm TiO<sub>x</sub> layer. These findings underscore the critical influence of oxide thickness on resistive switching performance and endurance. Furthermore, the comparative evaluation of Ag and Au-passivated Ag electrodes highlights the significance of electrode configuration in enhancing memristor reliability and long-term operational stability.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 14","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10854-025-14894-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144073730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent development on polymer based light weight electromagnetic interference shielding materials 高分子基轻质电磁干扰屏蔽材料的研究进展
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-05-17 DOI: 10.1007/s10854-025-14836-6
Mohammad Anwar Parvez, Mobasserul Islam, Salma Sultana, Masdud Ali, Rakebul Hossain Molla, Abul Hassan, Rajesh Theravalappil, Mohammad A. Hasnat, Nayan Ranjan Singha, Mostafizur Rahaman
{"title":"Recent development on polymer based light weight electromagnetic interference shielding materials","authors":"Mohammad Anwar Parvez,&nbsp;Mobasserul Islam,&nbsp;Salma Sultana,&nbsp;Masdud Ali,&nbsp;Rakebul Hossain Molla,&nbsp;Abul Hassan,&nbsp;Rajesh Theravalappil,&nbsp;Mohammad A. Hasnat,&nbsp;Nayan Ranjan Singha,&nbsp;Mostafizur Rahaman","doi":"10.1007/s10854-025-14836-6","DOIUrl":"10.1007/s10854-025-14836-6","url":null,"abstract":"<div><p>The rapid advancement of modern electronic technologies has significantly enhanced social production efficiency, but it has also led to an increase in electromagnetic interference (EMI). As a result, electromagnetic shielding materials have gained considerable attention, particularly in the context of lightweight and highly integrated electronic devices. Polymers are widely utilized in EMI shielding applications due to their unique properties, such as light weight, high flexibility, and excellent corrosion resistance. This review focuses on well-studied polymer-based lightweight composites. The fundamental theory of EMI shielding is thoroughly introduced, and current testing methods for evaluating shielding effectiveness are summarized to assist in the development of design principles for effective shielding materials. Additionally, the impact of various carbon materials—classified into zero-dimensional, one-dimensional, two-dimensional, and three-dimensional forms—on shielding performance is discussed, along with their corresponding shielding mechanisms. These advanced lightweight materials with superior EMI shielding properties hold immense potential for applications across diverse sectors, including communications, electronics, aerospace, military, and environmental protection.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 14","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144073641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient photodegradation of methylene blue by CdS-based nanocomposites cds基纳米复合材料对亚甲基蓝的高效光降解
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-05-17 DOI: 10.1007/s10854-025-14854-4
S. Fakhri-Mirzanagh, S. H. R. Shojaei, G. R. Pirgholi-Givi, Y. Azizian-Kalandaragh
{"title":"Efficient photodegradation of methylene blue by CdS-based nanocomposites","authors":"S. Fakhri-Mirzanagh,&nbsp;S. H. R. Shojaei,&nbsp;G. R. Pirgholi-Givi,&nbsp;Y. Azizian-Kalandaragh","doi":"10.1007/s10854-025-14854-4","DOIUrl":"10.1007/s10854-025-14854-4","url":null,"abstract":"<div><p>In this research, CdS-based nanocomposites including Ag<sub>2</sub>S-CdS, MnS-CdS, and ZnS-CdS were synthesized using the low-cost hydrothermal method for photocatalytic applications. The structural, morphological, porosity, and optical properties of these nanocomposites were examined by X-ray diffraction (XRD), Dynamic light scattering (DLS), Field Emission Scanning Electron Microscope (FE-SEM), Transmission electron microscopy (TEM), Brunauer–Emmett–Teller (BET) method, Mott–Schottky, and UV–Visible spectra. Results proved that nanocomposites prepared at the nanoscale are not so pros. Also, DLS results showed the agglomeration of the particles. The UV–visible results indicated that the band gap of CdS (2.51 eV) changes in the range of 2.15–3.22 eV by adding the transition metal and a suitable amount of impurity metal decreases the band gap of CdS-based nanocomposites. FE-SEM and TEM analyses illustrated that the product was synthesized without impurity at the nanoscale. Position of conduction (CB) and valence band (VB) edges measured by Mott–Schottky analysis, which includes the reduction potential O<sub>2</sub>/<sup><b>⋅</b></sup>O<sub>2</sub><sup>−</sup> and oxidation potential of <b>·</b>OH/OH<sup>−</sup>. All in all, ZnS-CdS was the most efficient examined nanocomposite, indicating the best degradation rate of methylene blue (MB) under sunlight due to a small band gap, and appropriate positions of CB and VB.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 14","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144074104","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Inorganic hole injection layers for improving the hole injection of quantum dot light-emitting diodes 用于改善量子点发光二极管空穴注入的无机空穴注入层
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-05-16 DOI: 10.1007/s10854-025-14899-5
Xuan Qu, Jing Jiang, Ting Ding, Meng-Wei Wang, Yin-Man Song, Pei-Li Gao, Zi-Bin Huang, Ming-En Li, Shi-Chen Su, Shuang-Peng Wang
{"title":"Inorganic hole injection layers for improving the hole injection of quantum dot light-emitting diodes","authors":"Xuan Qu,&nbsp;Jing Jiang,&nbsp;Ting Ding,&nbsp;Meng-Wei Wang,&nbsp;Yin-Man Song,&nbsp;Pei-Li Gao,&nbsp;Zi-Bin Huang,&nbsp;Ming-En Li,&nbsp;Shi-Chen Su,&nbsp;Shuang-Peng Wang","doi":"10.1007/s10854-025-14899-5","DOIUrl":"10.1007/s10854-025-14899-5","url":null,"abstract":"<div><p>Quantum dot light-emitting diodes (QLEDs) hold great potential for next-generation displays, offering outstanding efficiency and exceptional color purity. Nevertheless, their performance remains constrained by poor hole injection and device instability. In this study, a bilayer structure of NiO/NiO<sub>x</sub>:Mg is proposed for the hole injection layer (HIL) in QLEDs to address these challenges. This bilayer structure enhances the work function, facilitates hole injection, and thereby improves the performance of QLEDs. As a result, the optimized device exhibits nearly twice the current efficiency compared to its NiO-based counterpart, along with an extended T<sub>50</sub> lifetime—approximately eight times longer than that of the NiO-based device. Additionally, Mg doping effectively mitigates photoluminescence quenching in quantum dots, and capacitance–voltage analysis, along with other measurements, confirms the reduction of hole injection barriers. These results suggest that employing bilayer HILs significantly improves QLEDs performance, with possible applications in other optoelectronic devices like perovskite solar cells. </p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 14","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144073855","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Insights into the effect of gadolinium doping on the structural, magnetic, and optical properties of β-Ga2O3 钆掺杂对β-Ga2O3结构、磁性和光学性质的影响
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-05-16 DOI: 10.1007/s10854-025-14891-z
Anju Babu, N. Madhusudhana Rao
{"title":"Insights into the effect of gadolinium doping on the structural, magnetic, and optical properties of β-Ga2O3","authors":"Anju Babu,&nbsp;N. Madhusudhana Rao","doi":"10.1007/s10854-025-14891-z","DOIUrl":"10.1007/s10854-025-14891-z","url":null,"abstract":"<div><p>To examine the effect of gadolinium (Gd) doping on the structural, magnetic, and optical characteristics of β-gallium oxide, Gd-doped β-Ga<sub>2</sub>O<sub>3</sub> powder samples were prepared with Gd concentrations of 0, 1, 3, 5, and 7 M% using a reflux condensation method. Structural analysis via X-ray diffraction (XRD) and Rietveld refinement confirmed the formation of single-phase monoclinic β-Ga<sub>2</sub>O<sub>3</sub> at Gd concentrations of 0, 1, and 3 M%. However, samples doped with 5 and 7 M% Gd exhibited minor phase contributions from cubic Gd<sub>3</sub>Ga<sub>5</sub>O<sub>12</sub> alongside β-Ga<sub>2</sub>O<sub>3</sub> as the major phase. Analysis of the surface morphology revealed that both pure and Gd-doped samples retained an ellipsoidal morphology. Energy-dispersive X-ray spectroscopy (EDX) confirmed the purity of the prepared samples, identifying gallium, oxygen, and gadolinium as the sole elements present. Reflectance studies and Tauc plot analysis indicated a reduction in both reflectance and bandgap with increasing Gd doping. Photoluminescence studies in the UV–Vis region showed emission peaks in the UV, blue, and green regions. Magnetic studies conducted at room temperature demonstrated a transition in β-Ga<sub>2</sub>O<sub>3</sub> from a diamagnetic to an antiferromagnetic state upon Gd doping. The modified magnetic properties, combined with the enhanced optical properties achieved through Gd doping, explore the efficacy of Gd-doped β-Ga₂O₃ as a multifunctional material, paving the way for its use in applications as a bifunctional semiconductor material.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 14","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144073714","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of the effect of single walled carbon nanotube (SWCNT) on semiconducting properties of turmeric dye based Schottky device: a space charge limited conduction approach 单壁碳纳米管(SWCNT)对姜黄染料肖特基器件半导体性能影响的研究:一种空间电荷限制传导方法
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-05-16 DOI: 10.1007/s10854-025-14866-0
Subhra Rakshit, Arnab Kanti Karan, N. B. Manik
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