Journal of Materials Science: Materials in Electronics最新文献

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Fabrication and Characterization of Piezoelectric Nanogenerator Based on ZnO and PVP for Harvesting Energy System Applications 用于能量采集系统的ZnO和PVP压电纳米发电机的制备与表征
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-04-21 DOI: 10.1007/s10854-025-14783-2
Saba Ejaz, Gul Hassan, Ahmed Shuja
{"title":"Fabrication and Characterization of Piezoelectric Nanogenerator Based on ZnO and PVP for Harvesting Energy System Applications","authors":"Saba Ejaz,&nbsp;Gul Hassan,&nbsp;Ahmed Shuja","doi":"10.1007/s10854-025-14783-2","DOIUrl":"10.1007/s10854-025-14783-2","url":null,"abstract":"<div><p>Self-powered devices are necessary for the growing demand of sustainable energy as well as for portable devices. Numerous techniques and several piezo materials compositions have been investigated for energy harvesting. However, the composition of Zinc Oxide (ZnO) with Polyvinylpyrrolidone (PVP) for Piezoelectric Nanogenerator (PENG) using electrospinning technique has not been investigated for energy harvesting, to-date. In this study, multi solutions of ZnO and PVP were made in Dimethylformamide (DMF), varying the weight of both compositions. The electrospinning technique was used to produce the composite fiber of the solution. The parameters (Voltage, Feed rate, Needle Range, Distance, Time) were optimized. The Taylor cone nano fibers with good form were selected and PENG device have been made. Fabricated Piezoelectric Nanogenerator (PENG) effectively created V<sub>OC</sub> of ~ 40–50 V and I<sub>SC</sub> of 400 nA, which is promising power for wearable electronics, biosensors, light-up LEDs, and low power Internet of Things (IoT) devices. A voltage in this range is quite high for nanoscale energy harvester, showing good material properties, fabrication, and device design.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 12","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143856466","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of uniform submicron metal bump arrays based on undercut sacrificial layer for lift-off process 基于下切牺牲层的均匀亚微米金属碰撞阵列的制备
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-04-21 DOI: 10.1007/s10854-025-14764-5
Zelei Lai, Zhenyou Zou, Jinyu Ye, Yibin Lin, Xiongtu Zhou, Jie Sun, Tailiang Guo, Chaoxing Wu, Qun Yan, Lei Sun, Yongai Zhang
{"title":"Fabrication of uniform submicron metal bump arrays based on undercut sacrificial layer for lift-off process","authors":"Zelei Lai,&nbsp;Zhenyou Zou,&nbsp;Jinyu Ye,&nbsp;Yibin Lin,&nbsp;Xiongtu Zhou,&nbsp;Jie Sun,&nbsp;Tailiang Guo,&nbsp;Chaoxing Wu,&nbsp;Qun Yan,&nbsp;Lei Sun,&nbsp;Yongai Zhang","doi":"10.1007/s10854-025-14764-5","DOIUrl":"10.1007/s10854-025-14764-5","url":null,"abstract":"<div><p>The fabrication of uniform metal bump arrays with submicron-sized diameters is crucial for achieving Micro-LED displays with ultra-high pixel density. This study presents a fabrication strategy that utilizes an undercut sacrificial layer in the lift-off process to achieve fine-pitched metal bump arrays. The influences of sacrificial layer thickness and developing time on the undercut degree, as well as their effects on the morphology and dimensional consistency of bumps, are investigated. It is observed that increasing the developing time leads to a higher degree of undercut, not only facilitating the lift-off of the sacrificial layer but also resulting in an increased base radius of the metal bumps. By optimizing process parameters, we successfully achieved Au bump arrays with a base radius around 0.99 μm, top radius around 0.3 μm, and a pitch size of 1.4 μm, exhibiting height nonuniformity below 5%. This fabrication strategy for uniform metal bump arrays with ultra-high density will greatly contribute to advancing Micro-LED technology towards high definition and high brightness.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 12","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143856464","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research progress on negative temperature coefficient thermistors: review 负温度系数热敏电阻研究进展:综述
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-04-20 DOI: 10.1007/s10854-025-14727-w
Zhenlin Song, Zengji Chen, Gang Du, Linling Huang, Jia Yin, Jianfeng Cao, Yiping Guo
{"title":"Research progress on negative temperature coefficient thermistors: review","authors":"Zhenlin Song,&nbsp;Zengji Chen,&nbsp;Gang Du,&nbsp;Linling Huang,&nbsp;Jia Yin,&nbsp;Jianfeng Cao,&nbsp;Yiping Guo","doi":"10.1007/s10854-025-14727-w","DOIUrl":"10.1007/s10854-025-14727-w","url":null,"abstract":"<div><p>The global negative temperature coefficient (NTC) thermistor market produces over four billion units annually, with applications spanning industrial manufacturing, aerospace, and household appliances. With the increasing adoption of new energy vehicles and energy storage systems, the demand for reliable temperature control in battery systems has grown significantly. NTC thermistors, renowned for their precision, miniaturization, and rapid response, play a crucial role in maintaining optimal battery temperatures, which contributes to prolonged battery life and enhanced system reliability. Over the past two centuries, various materials have been used to develop NTC thermistors. However, early NTC thermistors often suffered from issues such as a narrow temperature measurement range and poor stability. Therefore, it is necessary to review the effects of different materials, dopants, and manufacturing processes on the electrical properties of NTC thermistors to promote further research and applications. This paper provides a comprehensive review of the characteristics, development history, performance index, and temperature-sensing mechanisms of NTC thermistors. Additionally, it summarizes the current research status and future directions for various types of NTC thermistors.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 11","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143852616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigating the physical and super-capacitive nature of PVA/CeO2 nanocomposite 研究PVA/CeO2纳米复合材料的物理性质和超电容性
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-04-20 DOI: 10.1007/s10854-025-14753-8
Veena Rose Mathew, G. Aryadevi, Geethu Joseph, V. S. Sona, R. Santhosh Kumar, Ginson P. Joseph
{"title":"Investigating the physical and super-capacitive nature of PVA/CeO2 nanocomposite","authors":"Veena Rose Mathew,&nbsp;G. Aryadevi,&nbsp;Geethu Joseph,&nbsp;V. S. Sona,&nbsp;R. Santhosh Kumar,&nbsp;Ginson P. Joseph","doi":"10.1007/s10854-025-14753-8","DOIUrl":"10.1007/s10854-025-14753-8","url":null,"abstract":"<div><p>The PVA/CeO<sub>2</sub> nanocomposite was prepared via the solution casting method. This work highlights the novelty of PVA/CeO<sub>2</sub> nanocomposites in advancing environmentally friendly and high-performance energy storage technologies. The supercapacitor with specific capacitance modified from 3 F/g to 56 F/g is applicable for moderate energy storage devices in day-to-day life. Along with this, we investigated the physio-thermal properties of the same and concluded that its efficacy is proportionate to the dopant inclusion in the matrix PVA.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 11","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143850934","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, characterization, and comprehensive analysis of 2-methylquinolinium picrate: crystal engineering, optical, spectroscopic, thermal stability, and nonlinear optical properties for opto-electronic applications 吡啶-2-甲基喹啉的合成、表征和综合分析:晶体工程、光学、光谱、热稳定性以及光电子应用中的非线性光学特性
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-04-20 DOI: 10.1007/s10854-025-14773-4
S. Nithya, Krishnakumar Muthusamy, Saravanabhavan Munusamy, M. Saravanakumar
{"title":"Synthesis, characterization, and comprehensive analysis of 2-methylquinolinium picrate: crystal engineering, optical, spectroscopic, thermal stability, and nonlinear optical properties for opto-electronic applications","authors":"S. Nithya,&nbsp;Krishnakumar Muthusamy,&nbsp;Saravanabhavan Munusamy,&nbsp;M. Saravanakumar","doi":"10.1007/s10854-025-14773-4","DOIUrl":"10.1007/s10854-025-14773-4","url":null,"abstract":"<div><p>Transparent pale yellow crystals of 2-methylquinolinium picrate (2MQPA) were synthesized from picric acid and 2-methylquinoline using methanol as a solvent. The salt formation occurred through hydrogen bonding between the phenolate group of picric acid and the tertiary nitrogen of 2-methylquinoline. Optical characteristics, including transmittance and photoluminescence, were examined using UV–Vis spectroscopy. Functional groups were identified through Fourier Transform Infrared (FTIR) spectroscopy, while thermal stability and decomposition behavior were analyzed via thermogravimetric-differential thermal analysis (TG–DTA) and differential scanning calorimetry (DSC). The third-order nonlinear optical (NLO) response was investigated using the Z-scan technique. Hirshfeld surface analysis highlighted significant intermolecular interactions, including H–H, C–H, O–H, and N–O contacts. Computational studies optimized the crystal structure, and density functional theory (DFT) calculations confirmed intermolecular charge transfer interactions and N–H⋯O hydrogen bonding, offering detailed insights into the electronic properties of 2MQPA.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 11","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143852615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Flower-like NiMn layered double hydroxide coupled with carbon nanotube arrays on nickel mesh as binder-free electrode for asymmetric supercapacitor 镍网上的花状镍锰层状双氢氧化物与碳纳米管阵列作为不对称超级电容器的无粘结剂电极
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-04-19 DOI: 10.1007/s10854-025-14767-2
Xue Wang, Shuanghui Zeng, Dongjing Liu, Jiao-Jing Shao, Zhao Ding, Jie Zhao
{"title":"Flower-like NiMn layered double hydroxide coupled with carbon nanotube arrays on nickel mesh as binder-free electrode for asymmetric supercapacitor","authors":"Xue Wang,&nbsp;Shuanghui Zeng,&nbsp;Dongjing Liu,&nbsp;Jiao-Jing Shao,&nbsp;Zhao Ding,&nbsp;Jie Zhao","doi":"10.1007/s10854-025-14767-2","DOIUrl":"10.1007/s10854-025-14767-2","url":null,"abstract":"<div><p>Flower-like nickel manganese layered double hydroxide coupled with carbon nanotube arrays in-situ grown on a nickel mesh (NiMn-LDH/CNTs@Ni) has been prepared by a facile hydrothermal method. By increasing the Mn/Ni ratio, the thickness of the LDH nanosheets increased while the spherical structure built up from the interconnected LDH nanosheets degraded. The optimized NiMn-LDH/CNTs@Ni exhibits a three-dimensional flower-like structure with the CNT arrays in-situ grown on nickel mesh by chemical vapor deposition method acting as stems to connect the NiMn-LDH nanoflowers. The prepared NiMn-LDH/CNTs@Ni exhibit high specific capacitance of 1367 F g<sup>−1</sup> at 1 A g<sup>−1</sup>, capacitance retention of 76% at 10 A g<sup>−1</sup> and excellent cycling performance in 3 M KOH aqueous solution. First-principles calculations show that Mn doping improves the electron transport and charge transfer capabilities by narrowing the energy gap and increasing the density of states near the Fermi level, which is conducive to enhancing the charge storage capacity. Asymmetric supercapacitors fabricated with NiMn-LDH/CNTs@Ni and nitrogen-doped carbon nanotubes exhibited energy densities as high as 31.8 W h kg<sup>−1</sup> at a power density of 800 W kg<sup>−1</sup>, demonstrating the potential of the fabricated binder-free electrodes for practical applications. This study demonstrates that modulating the electronic structure and nanostructure by doping hetero metal atoms can effectively improve the charge storage capacity of LDHs.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 11","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143849007","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigating half-metallic Mn2TiSn Heusler alloy for advanced spintronics applications 研究半金属Mn2TiSn Heusler合金在先进自旋电子学中的应用
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-04-19 DOI: 10.1007/s10854-025-14712-3
Rasik Ahmad Parray, Asmat Ara, K. Ravichandran
{"title":"Investigating half-metallic Mn2TiSn Heusler alloy for advanced spintronics applications","authors":"Rasik Ahmad Parray,&nbsp;Asmat Ara,&nbsp;K. Ravichandran","doi":"10.1007/s10854-025-14712-3","DOIUrl":"10.1007/s10854-025-14712-3","url":null,"abstract":"<div><p>Multiferroic composites with high magnetic and electric properties at room temperature are considered the most significant materials due to their potential applications in many electronic devices. Furthermore, ultrafast, eco-friendly, energy-efficient innovative techniques to develop multifunctional materials have attracted abundant importance. In this study, we report on ferromagnetic particulate alloy prepared via a clean, eco-friendly, ultrafast, wet ball milling method followed by annealing at different temperatures. The multiferroic properties of the annealed samples were investigated via different characterizations. X-ray diffraction confirmed the identification of face-centered cubic with L2<sub>1</sub> arrangement. The calculated average crystallite size of prepared Mn<sub>2</sub>TiSn (900 °C/20 h.) Heusler alloy nanoparticles using Scherer’s formula were found to be 37 nm. A high-resolution electron microscope reveals the aggregated morphology with a particle size ranging from 80 to 120 nm. The temperature-dependent electrical resistivity and Seebeck coefficient were measured, suggesting that the alloy behaves like an n-type semiconductor. Such semiconducting behavior may be considered as an indication that Mn<sub>2</sub>TiSn full-Heusler alloy is a spin-gapless semiconductor. Vibrating sample magnetometer measurements suggest that the alloy has soft ferromagnetic properties with low coercivity and high saturation. This result may offer an alternative technique for preparing alloys with improved magnetic and electrical properties. Thus, this work suggests that the material is feasible for spintronic applications.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 11","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143850936","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
N/o-co-doped porous carbon supercapacitor electrode material from sunflower discs via potassium citrate green activation strategy 利用柠檬酸钾绿色活化策略制备的N/o共掺杂多孔碳超级电容器电极材料
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-04-19 DOI: 10.1007/s10854-025-14736-9
Gang Liu, Aoyang Zhang, Shams Forruque Ahmed, Weiwu Ma
{"title":"N/o-co-doped porous carbon supercapacitor electrode material from sunflower discs via potassium citrate green activation strategy","authors":"Gang Liu,&nbsp;Aoyang Zhang,&nbsp;Shams Forruque Ahmed,&nbsp;Weiwu Ma","doi":"10.1007/s10854-025-14736-9","DOIUrl":"10.1007/s10854-025-14736-9","url":null,"abstract":"<p>In the current study, nitrogen and oxygen (N/O)-co-doped porous carbon for supercapacitors was successfully synthesized from sunflower discs through activation modification with potassium citrate and urea. Material characterization and electrochemical performance testing in three-electrode and two-electrode systems demonstrated that the porous carbon (SDU-900), prepared under activation conditions at 900<span>(^{circ })</span>C exhibited an interconnected pore structure and excellent electrochemical properties. In a three-electrode system (6 M KOH as the electrolyte, current density of 0.5 A/g), SDU-900 demonstrated a high specific capacitance of 294.2 F/g. Moreover, the symmetric device based on SDU-900 exhibits an excellent energy density of 20.05 Wh/kg at a power density of 495 W/kg. After 15,000 galvanostatic charge–discharge (GCD) cycles at 5 A/g, the initial specific capacitance was retained at 93.89%, indicating remarkable cycling stability. Notably, the activation process utilized sunflower discs discarded from agricultural production as precursors, replacing the highly corrosive alkali activators with potassium citrate, a benign salt. This approach provides an environmentally friendly method for synthesizing porous carbon for supercapacitor applications.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 11","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143849008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ag/Bi2WO6-based triboelectric nanogenerators for self-powered ethanol sensor 用于自供电乙醇传感器的Ag/ bi2wo6摩擦电纳米发电机
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-04-19 DOI: 10.1007/s10854-025-14797-w
Xiaoran Gong, Haohao Zhang, Jiachen Ye, Chengjia Din, Tao Chen, Xue Li
{"title":"Ag/Bi2WO6-based triboelectric nanogenerators for self-powered ethanol sensor","authors":"Xiaoran Gong,&nbsp;Haohao Zhang,&nbsp;Jiachen Ye,&nbsp;Chengjia Din,&nbsp;Tao Chen,&nbsp;Xue Li","doi":"10.1007/s10854-025-14797-w","DOIUrl":"10.1007/s10854-025-14797-w","url":null,"abstract":"<div><p>Triboelectric nanogenerators (TENG) as gas sensor is a strategy for detection that does not require power source. This study prepared Ag/Bi<sub>2</sub>WO<sub>6</sub> composite as a triboelectric layer in a TENG device. Incorporating Ag particles improved output performance. Additionally, self-powered gas sensor (SPGS) based on 2% Ag/Bi<sub>2</sub>WO<sub>6</sub> exhibited a response of 27.6% to 100 ppm ethanol with response/recovery times (72.7/81 s). SPGS also have a lower limit of detection (LOD) as 2.7 ppm. The enhanced gas-sensitive performance to the catalytic effect of Ag, which facilitated the adsorption and desorption of ethanol gas molecules. This work demonstrating the potential application of multi-element metal oxides in ethanol detection was demonstrated.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 11","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143850935","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of acidification and spiralization on the microstructure and microwave absorbing properties of carbon nanotubes 酸化和螺旋化对碳纳米管微观结构和微波吸收特性的影响
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-04-19 DOI: 10.1007/s10854-025-14500-z
Xinyang Wang, Shicheng Wei, Bo Wang, Yi Liang, Yujiang Wang, Zhen Liu, Weiyang Fu, Kening Huang, Quan Xu
{"title":"Effect of acidification and spiralization on the microstructure and microwave absorbing properties of carbon nanotubes","authors":"Xinyang Wang,&nbsp;Shicheng Wei,&nbsp;Bo Wang,&nbsp;Yi Liang,&nbsp;Yujiang Wang,&nbsp;Zhen Liu,&nbsp;Weiyang Fu,&nbsp;Kening Huang,&nbsp;Quan Xu","doi":"10.1007/s10854-025-14500-z","DOIUrl":"10.1007/s10854-025-14500-z","url":null,"abstract":"<div><p>In this work, acidified and helical carbon nanotubes were prepared by magnetron sputtering, and their electromagnetic parameters and absorption properties were analyzed. Their mechanism of electromagnetic wave-absorbing attenuation was investigated through the finite element method. The acidification and spiralization treatments reduced the diameter of the carbon nanotubes, introduced a large number of internal defects and oxygen-containing functional groups, reduced the effective conductivity, increased the penetration depth, promoted the dielectric polarization relaxation, and made the dielectric parameters more suitable for electromagnetic wave absorption, resulting in an improvement in the impedance matching characteristics and electromagnetic wave absorption performance. The finite element calculations indicated that carbon nanotubes with a helical structure exhibited a more uniform distribution of the scattering electromagnetic field and a smaller intensity. As the small ratio of length to diameter decreased, the intensity of the scattering field gradually decreased and their distribution became more uniform. Furthermore, the acidified helical carbon nanotubes exhibited excellent absorption properties with a maximum absorption bandwidth of 5.60 GHz at a matching thickness of 1.53 mm, and a minimum reflection loss of − 32.14 dB at 12.60 GHz at a matching thickness of 1.79 mm. Therefore, acidified helical carbon nanotubes showed great potential in the application of microwave absorption.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 11","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143849011","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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