Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques最新文献_第2页

Tribomechanical Properties of TiSiCN Coatings Obtained by Anodic Evaporation of Titanium and Decomposition of Hexamethyldisilazane in a Discharge in a System with a Self-Heating Hollow Cathode 在带自加热空心阴极的系统中通过钛的阳极蒸发和六甲基二硅氮烷的放电分解获得的 TiSiCN 涂层的摩擦力学性能

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Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Pub Date : 2024-12-18 DOI: 10.1134/S102745102470112X

A. I. Menshakov, Yu. A. Bryuhanova

{"title":"Tribomechanical Properties of TiSiCN Coatings Obtained by Anodic Evaporation of Titanium and Decomposition of Hexamethyldisilazane in a Discharge in a System with a Self-Heating Hollow Cathode","authors":"A. I. Menshakov, Yu. A. Bryuhanova","doi":"10.1134/S102745102470112X","DOIUrl":"10.1134/S102745102470112X","url":null,"abstract":"Using the method of reactive anodic evaporation of titanium in an arc discharge in a system with a self-heating hollow cathode in a gas mixture Ar + C2H2 + N2 with the addition of hexamethyldisilazane (HMDS) vapors, dense homogeneous TiSiCN nanocomposite coatings with a thickness of up to 15 µm, a hardness of up to 43 GPa, and a wear coefficient of 2.8 × 10–14 m2/N were obtained. It has been shown that by changing the pressure, composition, and activation degree of the vapor–gas mixture, it is possible to change the microstructure and properties of the obtained coatings within a wide range. An increase in the fluxes of C2H2, N2, and HMDS, as well as the discharge current leads to an increase in the coating deposition rate. However, coatings with the optimal microhardness and wear resistance were obtained at a low discharge current of 10 A, a relatively low content of C2H2 (1 cm3/min) and HMDS (0.3 g/h), exceeding of which leads to a decrease in the hardness of the films and deterioration of their quality, which can be explained by excessive ionic exposure and nonoptimal chemical and phase composition of coatings. The chemical and phase compositions of the obtained coatings were studied. The coating structure is a nanocomposite consisting of TiCN nanocrystallites dissolved in an amorphous SiCN matrix.","PeriodicalId":671,"journal":{"name":"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques","volume":"18 5","pages":"1265 - 1270"},"PeriodicalIF":0.5,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142844871","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Formation of a Protective Layer Based on Chromium Boride on the Surface of Kh12MF Steel Using Electron-Beam Treatment 利用电子束处理在 Kh12MF 钢表面形成基于硼化铬的保护层

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Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Pub Date : 2024-12-18 DOI: 10.1134/S1027451024701118

A. S. Milonov, U. L. Mishigdorzhiyn, A. P. Semenov, S. A. Lysykh

{"title":"Formation of a Protective Layer Based on Chromium Boride on the Surface of Kh12MF Steel Using Electron-Beam Treatment","authors":"A. S. Milonov, U. L. Mishigdorzhiyn, A. P. Semenov, S. A. Lysykh","doi":"10.1134/S1027451024701118","DOIUrl":"10.1134/S1027451024701118","url":null,"abstract":"The preparation of coating layers containing the borides Cr2B, Cr2B3, and FeB on Kh12MF steel using the electron-beam treatment of reacting coatings made of Cr2O3, amorphous boron, and carbon is considered. The influence of the treatment time on the structure, composition, and microhardness of the layers is investigated. The maximum microhardness of the layers is ~18.5 GPa. The studies allow one to conclude that electron-beam treatment can be used to strengthen cutting and other tools, which experience high temperature heating during operation, without a significant reduction in performance. It is known that, along with high hardness and wear resistance, boride layers also have a significant disadvantage: increased brittleness. The studies carried out show that the use of electronic heating allows a reduction in brittleness and increase in plasticity of the alloys. The layers after electron-beam boriding have a heterogeneous structure combining hard (brittle) and more plastic structural components.","PeriodicalId":671,"journal":{"name":"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques","volume":"18 5","pages":"1260 - 1264"},"PeriodicalIF":0.5,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142844872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Escalation of NiO/ZnO Nanocomposites Acts as an Electrode in Super Capacitor Applications 氧化镍/氧化锌纳米复合材料的升级在超级电容器应用中用作电极

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Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Pub Date : 2024-12-18 DOI: 10.1134/S1027451024700927

R. Deepa, K. A. Vijayalakshmi

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Surface Modification of Polytetrafluoroethylene by Atmospheric-Pressure Plasma Jets

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Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Pub Date : 2024-12-18 DOI: 10.1134/S1027451024701143

B. B. Baldanov, A. P. Semenov, Ts. V. Ranzhurov

{"title":"Surface Modification of Polytetrafluoroethylene by Atmospheric-Pressure Plasma Jets","authors":"B. B. Baldanov, A. P. Semenov, Ts. V. Ranzhurov","doi":"10.1134/S1027451024701143","DOIUrl":"10.1134/S1027451024701143","url":null,"abstract":"The change of polytetrafluoroethylene surface properties under the influence of nonthermal nonequilibrium plasma generated by plasma jets at atmospheric pressure is shown. The unsteady form of diffuse discharge, a glow discharge, which is superimposed on weak-current spark discharges, is experimentally realized and formed in the gas flow in the form of atmospheric pressure plasma jets. The plasma jet (diameter of the plasma jet is 2.5 cm, length of the jet is 1–2 cm) is oriented perpendicularly to the surface of polytetrafluoroethylene. Water contact angle measurements and electron microscopy are used to determine the surface characteristics of the material. An intensive and homogeneous improvement of the polymer surface wettability is observed on a large area (contact area S ≈ 7 cm2) subjected to plasma treatment during the first seconds of exposure to the plasma jet. The contact angle of the original polytetrafluoroethylene with a drop of water is 102°, while the contact angle θ decreases to 65° when exposed to plasma jets. In the area of plasma jets impact at atmospheric pressure, in contrast to the original surface, there are pronounced inhomogeneous surface formations, and at the interface a sharp change in the wettability of the surface is observed. On the surface of polytetrafluoroethylene sample in the area of plasma jets impact, the percentage of carbon increases, while the percentage of fluorine decreases.","PeriodicalId":671,"journal":{"name":"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques","volume":"18 5","pages":"1271 - 1275"},"PeriodicalIF":0.5,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142844762","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Experimental and Numerical Study of Damage Caused by High-Current Electron Beam to Construction Materials Intended for the First Wall of Powerful Plasma Installations

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Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Pub Date : 2024-12-18 DOI: 10.1134/S1027451024700800

N. P. Bobyr, E. D. Kazakov, M. Yu. Orlov, A. R. Smirnova, A. V. Spitsyn, M. G. Strizhakov, K. A. Sunchugashev, S. I. Tkachenko

{"title":"Experimental and Numerical Study of Damage Caused by High-Current Electron Beam to Construction Materials Intended for the First Wall of Powerful Plasma Installations","authors":"N. P. Bobyr, E. D. Kazakov, M. Yu. Orlov, A. R. Smirnova, A. V. Spitsyn, M. G. Strizhakov, K. A. Sunchugashev, S. I. Tkachenko","doi":"10.1134/S1027451024700800","DOIUrl":"10.1134/S1027451024700800","url":null,"abstract":"An experimental study of the effect of high-current electron beams on crystals made of polycrystalline tungsten and corrosion-resistant ferritic-martensitic steel EK-181 was carried out, as well as a numerical simulation of the process of interaction of the beam with the target, in which the energy of the electron beam was absorbed in the near-surface layers of the samples under study. The experiments were carried out on the Kalmar high-current electron accelerator at an average pulse energy of E ≈ 100 ± 20 J (pulse duration at half maximum 100 ns). During the experiments, samples were irradiated from one to ten times. Numerical modeling was performed using electron spectra calculated on the basis of data (currents and voltages in the diode gap) obtained as a result of electrical measurements. The difference in the nature of destruction of tungsten and steel was demonstrated. It has been shown that tungsten begins to crack after three-pulse exposure with an energy of about 100 J, which correlates well with tests on other types of installations. On steel, minor cracking was observed only after 8–10 pulses of exposure. Numerous traces of droplets of melting and redeposition of the target material were found on the surface of the steel target. For both materials, the specific amount of energy absorbed in the region of interaction of the electron beam with the target was estimated.","PeriodicalId":671,"journal":{"name":"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques","volume":"18 5","pages":"1047 - 1052"},"PeriodicalIF":0.5,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142845052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Structure of Surface Steps in the Deformed Zr62Cu22Fe6Al10 Amorphous Alloy

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Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Pub Date : 2024-12-18 DOI: 10.1134/S1027451024700964

G. E. Abrosimova, N. A. Volkov, A. S. Aronin

{"title":"Structure of Surface Steps in the Deformed Zr62Cu22Fe6Al10 Amorphous Alloy","authors":"G. E. Abrosimova, N. A. Volkov, A. S. Aronin","doi":"10.1134/S1027451024700964","DOIUrl":"10.1134/S1027451024700964","url":null,"abstract":"The structure of the side surfaces of the bulk Zr62Cu22Fe6Al10 amorphous alloy before and after compressive deformation at room temperature was studied using X-ray diffraction and scanning electron microscopy (SEM) methods. After preparation, the samples of the amorphous alloy had a square cross section of 5 × 5 mm and a length of 40 mm. Examining the side surfaces of the samples allows one to avoid influencing the surface structure of a tool used for deformation. The plastic deformation of amorphous alloys occurs through the formation and propagation of shear bands. During compressive deformation at room temperature, a system of steps was formed on the end surfaces of the sample caused by shear bands coming to the surface. Steps on surfaces have different sizes (thickness and height). It was established that the structure of large steps is complex: they consist of elementary steps 15–30 nm thick. The local deformation was estimated based on the size of the steps. The formation of a small number of nanocrystals during deformation was discovered. The nanocrystals are approximately 10 nm in size. The results obtained open a new direction for research into the structure of deformed amorphous alloys and nanocrystallization processes under the influence of deformation.","PeriodicalId":671,"journal":{"name":"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques","volume":"18 5","pages":"1155 - 1159"},"PeriodicalIF":0.5,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142845106","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Investigation of High-Intensity Implantation of Titanium Ions into Silicon under Conditions of Beam Energy Impact on the Surface 研究在光束能量冲击表面的条件下将钛离子高强度植入硅中的情况

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Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Pub Date : 2024-12-18 DOI: 10.1134/S1027451024701040

A. I. Ivanova, D. O. Vakhrushev, O. S. Korneva, A. V. Gurulev, V. A. Varlachev, D. D. Efimov, A. A. Chernyshev

{"title":"Investigation of High-Intensity Implantation of Titanium Ions into Silicon under Conditions of Beam Energy Impact on the Surface","authors":"A. I. Ivanova, D. O. Vakhrushev, O. S. Korneva, A. V. Gurulev, V. A. Varlachev, D. D. Efimov, A. A. Chernyshev","doi":"10.1134/S1027451024701040","DOIUrl":"10.1134/S1027451024701040","url":null,"abstract":"Methods of modifying surface and near-surface layers of materials and coatings by ion beams can be applied in many fields of science and technology. To practically implement the technologies for the targeted improvement of the performance properties of parts and products for various purposes, it is of great interest to develop the methods of deep ion doping of near-surface layers of semiconductor materials, as well as metals and alloys due to the enhancement of radiation-stimulated diffusion under conditions when the irradiated sample deep layers are not subject to a significant temperature impact. This study concerns features and regularities of implementing the synergy of high-intensity titanium ion implantation at current densities of several hundred mA/cm2 with simultaneous energy impact of a submillisecond ion beam with a power density reaching several tens of kW/cm2 on the surface. This work is the first to show that the synergy of high-intensity ion implantation and the energy impact of a high-power density ion beam, taking titanium implantation into silicon as an example, provides the possibility of increasing the ion doping depth from fractions of μm to 6 μm by increasing the irradiation time from 0.5 to 60 min.","PeriodicalId":671,"journal":{"name":"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques","volume":"18 5","pages":"1216 - 1220"},"PeriodicalIF":0.5,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142845105","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

On Anomalous Diffusion of Fast Electrons through the Silicon Crystal

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Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Pub Date : 2024-12-18 DOI: 10.1134/S1027451024700873

V. V. Syshchenko, A. I. Tarnovsky, V. I. Dronik

{"title":"On Anomalous Diffusion of Fast Electrons through the Silicon Crystal","authors":"V. V. Syshchenko, A. I. Tarnovsky, V. I. Dronik","doi":"10.1134/S1027451024700873","DOIUrl":"10.1134/S1027451024700873","url":null,"abstract":"Anomalous diffusion is a random process in which the root-mean-square displacement of a particle from the starting point depends nonlinearly on time. The possibility of such behavior for high-energy particles moving through the crystal under conditions close to axial channeling was found earlier. In this case, the rapid displacement of particles in a plane transverse to atomic strings (Lévi flights) is due to the temporary capture of the particles in planar channels. In this work, the anomalous diffusion exponent has been found by numerical simulation for different values of the energy of electron transverse motion in the (100) plane of a silicon crystal. It has been shown that, in the case of electrons with an energy exceeding by 1 eV the height of the saddle point of the potential of a system of atomic chains [100], the results are consistent with those obtained earlier. It has been confirmed that the anomalous nature of diffusion is due to the possibility of short-term capture of particles in planar channels. With increasing transverse energy, this possibility disappears and the diffusion becomes normal (Brownian).","PeriodicalId":671,"journal":{"name":"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques","volume":"18 5","pages":"1094 - 1099"},"PeriodicalIF":0.5,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142844961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Theoretical Study of Electron Exchange under Grazing Scattering on Thin Metal Films

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Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Pub Date : 2024-12-18 DOI: 10.1134/S1027451024701064

I. K. Gainullin

引用次数: 0

Dependence of Silicon Carbide Radiation Resistance on the Irradiation Temperature

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Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Pub Date : 2024-12-18 DOI: 10.1134/S1027451024700824

A. A. Lebedev, V. V. Kozlovski, M. E. Levinshtein, K. S. Davydovskaya, R. A. Kuzmin

{"title":"Dependence of Silicon Carbide Radiation Resistance on the Irradiation Temperature","authors":"A. A. Lebedev, V. V. Kozlovski, M. E. Levinshtein, K. S. Davydovskaya, R. A. Kuzmin","doi":"10.1134/S1027451024700824","DOIUrl":"10.1134/S1027451024700824","url":null,"abstract":"The effect of high-temperature electron and proton irradiation on the characteristics of devices based on SiC has been studied. For the study, industrial 4H-SiC integrated Schottky diodes with an n-type base with a blocking voltage of 600, 1200, and 1700 V manufactured by CREE are used. Irradiation is carried out by electrons with an energy of 0.9 MeV and protons with an energy of 15 MeV. It is found that the radiation resistance of SiC Schottky diodes under high-temperature irradiation significantly exceeds the resistance of diodes under irradiation at room temperature. It is shown that this effect arises due to the annealing of compensating radiation defects under high-temperature irradiation. It is revealed that this effect arises due to the annealing of compensating radiation defects under high-temperature irradiation. The parameters of radiation defects are determined by the method of transient capacitance spectroscopy. Under high-temperature (“hot”) irradiation, the spectrum of radiation-induced defects introduced into SiC differs significantly from the spectrum of defects introduced at room temperature. The radiation resistance of silicon and silicon carbide is compared. The relatively small difference in the rate of carrier removal in SiC and Si upon irradiation at room temperature is due to the fact that in SiC, in contrast to Si, there is practically no annealing of primary radiation defects during irradiation.","PeriodicalId":671,"journal":{"name":"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques","volume":"18 5","pages":"1060 - 1064"},"PeriodicalIF":0.5,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142845056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0