Advanced Materials Interfaces最新文献_第8页

Photocatalytic Performance Enhancement Using External Magnetic Fields - A Review 外磁场增强光催化性能的研究进展

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-08-04 DOI: 10.1002/admi.202500493

Pengsheng Liu, Xiaoan Mao

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Ceramics Surface Design by Laser Texturing: A Review on Structures and Functionalities 激光变形陶瓷表面设计：结构与功能研究进展

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-08-01 DOI: 10.1002/admi.202500302

Edna Silva, Augusto Lopes, Georgina Miranda

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Strain Relief and Domain Architecture in Epitaxial NiO Films on La2/3Sr1/3MnO3/SrTiO3 for Spin-Transport Engineering La2/3Sr1/3MnO3/SrTiO3外延NiO薄膜的应变应变与畴结构

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-08-01 DOI: 10.1002/admi.202500452

Shoulong Chen, Carlos Frontera, Meritxell Toda-Casaban, Alberto Pomar, Lluis Balcells, Zorica Konstantinovic, Cesar Magén, Benjamin Martinez, Narcis Mestres

{"title":"Strain Relief and Domain Architecture in Epitaxial NiO Films on La2/3Sr1/3MnO3/SrTiO3 for Spin-Transport Engineering","authors":"Shoulong Chen, Carlos Frontera, Meritxell Toda-Casaban, Alberto Pomar, Lluis Balcells, Zorica Konstantinovic, Cesar Magén, Benjamin Martinez, Narcis Mestres","doi":"10.1002/admi.202500452","DOIUrl":"10.1002/admi.202500452","url":null,"abstract":"This study reports on the epitaxial growth and structural characterization of ultrathin NiO-films deposited by magnetron sputtering on La2/3Sr1/3MnO3 (LSMO) films grown on SrTiO3 (STO) substrates with (001)- and (111)-orientations. X-ray diffraction and atomic-force microscopy show that all NiO layers are single-phase, face-centered pseudo-cubic, atomically smooth, root-main-square (RMS) surface roughness <0.15 nm, and form abrupt interfaces with LSMO. High-resolution reciprocal-space maps reveal that the films are largely relaxed, but exhibit a slight compressive distortion, yielding unit-cell volumes larger than bulk NiO. Despite a nominal ≈7% lattice mismatch, aberration-corrected scanning transmission electron microscopy uncovers an array of misfit dislocations at the NiO/LSMO interface that help to accommodate strain allowing epitaxial growth of NiO layers. On (001)-oriented samples, the four antiferromagnetic T-domains are oblique to the sample plane, while on the (111) case, one lies in-plane. This in-plane domain shows greater spacing between ferromagnetic (111) planes due to unit cell distortion. This structural domain splitting can influence magnetic order and spin transmission efficiency, highlighting crystallographic orientation as a key factor in designing high-performance spintronic devices.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 16","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500452","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144894118","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Region-Selective Growth of Cu2O Shell on Gold Nanoprisms Cu2O壳在金纳米片上的区域选择性生长

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-07-31 DOI: 10.1002/admi.202500512

Ziyoda Ganieva, Dávid Kovács, Zoltán Osváth, Dániel Zámbó, András Deák

{"title":"Region-Selective Growth of Cu2O Shell on Gold Nanoprisms","authors":"Ziyoda Ganieva, Dávid Kovács, Zoltán Osváth, Dániel Zámbó, András Deák","doi":"10.1002/admi.202500512","DOIUrl":"10.1002/admi.202500512","url":null,"abstract":"Structural control in metal/semiconductor multicomponent nanoparticles can lead to advanced functional properties, as optoelectronic processes and accessibility (e.g., by charge carriers or molecules) of the different components can be simultaneously tailored. In this study, the impact of surface-adsorbed molecules (5-amino-2-mercaptobenzimidazole - AMBI) on the wet-chemical deposition of cuprous oxide (Cu2O) shells on gold nanoprisms is investigated. It is shown that the otherwise excellent compatibility between gold and Cu2O, and hence the shell deposition, is profoundly influenced by the presence of AMBI. The time evolution of the optical and structural properties during the shell growth indicates that the inherent Volmer-Weber characteristic of the Cu2O deposition process gets greatly amplified by the surface adsorption of AMBI. Measurements performed on individual nanoparticles show that this originates in the inhomogeneous, multi-patch coverage of the particle surface. Under optimized synthetic conditions, the tips of the nanoprisms are effectively protected from Cu2O overgrowth and are left bare.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 16","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500512","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144894162","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Design of Highly Efficient Nanomembranes Toward Direct Air Capture. Essential Role of Nanolayer Interface 用于直接空气捕获的高效纳米膜的设计。纳米层界面的重要作用

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-07-31 DOI: 10.1002/admi.202500244

Miho Ariyoshi, Shigenori Fujikawa, Toyoki Kunitake

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Experimental and Theoretical Investigations on Magneto-Electrochemical Oxygen Evolution Reaction of CoFeP Nanorods CoFeP纳米棒磁电化学析氧反应的实验与理论研究

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-07-31 DOI: 10.1002/admi.202500321

Mohammed Arkham Belgami, Afsal S Shajahan, Erdenebayar Baasanjav, Vishwanath Ankalgi, Brahmananda Chakraborty, Sang Mun Jeong, Chandra Sekhar Rout

{"title":"Experimental and Theoretical Investigations on Magneto-Electrochemical Oxygen Evolution Reaction of CoFeP Nanorods","authors":"Mohammed Arkham Belgami, Afsal S Shajahan, Erdenebayar Baasanjav, Vishwanath Ankalgi, Brahmananda Chakraborty, Sang Mun Jeong, Chandra Sekhar Rout","doi":"10.1002/admi.202500321","DOIUrl":"10.1002/admi.202500321","url":null,"abstract":"The pursuit of low-cost, efficient, and durable electrocatalysts for oxygen evolution in alkaline media is vital for water-splitting applications. Herein, the hydrothermal-based synthesis of a multiphase ferromagnetic catalyst CoFeP, comprising FeP, CoP, and Fe2P is reported. Structural analyses confirm the coexistence of phases, and electrochemical studies reveal excellent OER activity. CoFeP exhibits an overpotential of 335 mV at 50 mA cm−2 and a Tafel slope of 116 mV dec−1 without a magnetic field, whereas under the magnetic field of 2000 G, these values lowered to 235 mV and 93 mV dec−1, respectively. The enhancement is attributed to magnetic-field-induced spin polarization, surface reconstruction, and increased ECSA from 70 to 110 mF cm−2, highlighting the potential of magnetic modulation for boosting catalytic performance. Through spin-polarized Density Functional Theory (DFT) simulations, the structural and electronic features of CoFeP, providing theoretical insights into its role in the Oxygen Evolution Reaction (OER) is elucidated. This investigation demonstrates that the application of an external magnetic field significantly reduces the overpotential required for OER as the adsorption of intermediate species becomes stronger due to more charge transfer, aligning with experimental observations. These findings highlight the interplay between magnetic fields and electrocatalytic performance, offering a pathway to enhance energy conversion efficiency.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 17","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500321","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145032304","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

How Real-Time Kinetics Explain the Different Interaction of Cubosomes and Hexosomes Nanoparticles with Lipid Membranes 实时动力学如何解释立方体和六体纳米颗粒与脂质膜的不同相互作用

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-07-31 DOI: 10.1002/admi.202500186

Mario Campana, Silvia Dante, Paola Astolfi, Simone Ranieri, Michela Pisani

{"title":"How Real-Time Kinetics Explain the Different Interaction of Cubosomes and Hexosomes Nanoparticles with Lipid Membranes","authors":"Mario Campana, Silvia Dante, Paola Astolfi, Simone Ranieri, Michela Pisani","doi":"10.1002/admi.202500186","DOIUrl":"10.1002/admi.202500186","url":null,"abstract":"Cubosomes and hexosomes are interesting structures with diverse applications as drug and gene delivery systems, as well as theranostics. Understanding the uptake mechanism of these nanostructures by cell membranes is fundamental to improving and broadening their application. In this study, the kinetics of interaction of monoolein (GMO) cubosomes or dioleoylphosphatidylethanolamine (DOPE) hexosomes with supported lipid bilayers (SLBs) with varying compositions and stiffness, as valuable model membranes, are investigated by neutron reflectivity (NR) coupled with quartz crystal microbalance with dissipation monitoring (QCM-D). Atomic force microscopy (AFM) is also used to analyze SLBs topography after such interaction. Cubosomes rapidly interact with SLBs, resulting in lipid exchange between the two systems, destabilizing the bilayer, and ultimately causing its removal. The inclusion of cholesterol (CHOL) in the SLB confers rigidity, making it more resistant to removal. Completely different results are obtained when hexosomes interact with SLBs: an intrinsic resistance of the bilayers toward these nanoparticles is observed, regardless of CHOL presence, combined with a slight change in SLB composition, suggesting that hexosomes tend to fuse with the SLB. These findings provide new and valuable insights into the potential mechanisms and kinetics of cellular uptake of these systems, enhancing their potential as drug delivery vectors.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 17","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500186","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145032311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A Universal Method for Achieving Ultra-Low Contact Resistances in Organic Electrochemical Transistors 实现有机电化学晶体管超低接触电阻的通用方法

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-07-30 DOI: 10.1002/admi.202500208

Luis-Abraham Lozano-Hernández, Patrice Rannou, Yvan Bonnassieux, Sébastien Sanaur

{"title":"A Universal Method for Achieving Ultra-Low Contact Resistances in Organic Electrochemical Transistors","authors":"Luis-Abraham Lozano-Hernández, Patrice Rannou, Yvan Bonnassieux, Sébastien Sanaur","doi":"10.1002/admi.202500208","DOIUrl":"10.1002/admi.202500208","url":null,"abstract":"Organic ElectroChemical Transistors (OECTs) are intensively studied for enabling their use in organic bioelectronics, neuromorphic systems, and biosensors. Beyond device geometry, reaching optimal operation of organic electronic circuits requires the optimization of the physico-chemical properties of the channel. Toward this end, the effects of a “bulk” doping of the channel material and its influence on the contact resistance (RC) at the interface between a Polymeric Mixed Ionic-Electronic conductors (PMIECs) and the Source (S) and Drain (D) electrodes are presented. An easy-to-implement method to achieve ultra-low contact resistances in OECTs is introduced. By incorporation of LiTFSI, a 4x transconductance improvement is achieved, and a decrease of RC by a factor of ≈2 and ≈40 has been observed for p-type or n-type PMIECs, respectively. It reaches an unprecedented width-normalized contact resistance value as low as 1 Ohm.cm with the p(g2T-T) polymer. The formation of very localized domains in the polymeric matrix in the vicinity of the electrodes, as a result of the reduction of TFSIˉ anions, which modulates the energy barrier at the S/D interface, is suggested here. Furthermore, both p(g2T-T) and p(gNDI-gT2) polymers exhibit low water uptake with minute amounts of LiTFSI. Worth noticing, doped p(g2T-T) preserves its volumetric capacitance and demonstrates an exceptional long-term stability. Finally, a universal strategy to fine-tune OECT performances, drawing prospects for implementing next-generation applications in organic bioelectronics and neuromorphics, is proposed.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 16","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500208","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144894221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Development of a Sensitive Electrochemical Aptasensor for Non-Small Cell Lung Cancer Extracellular Vesicle Detection 非小细胞肺癌细胞外囊泡检测灵敏电化学配体传感器的研制

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-07-30 DOI: 10.1002/admi.202500176

Zarinah M. Amin, Volker Nock, Paula Brooksby, Renee V. Goreham

{"title":"Development of a Sensitive Electrochemical Aptasensor for Non-Small Cell Lung Cancer Extracellular Vesicle Detection","authors":"Zarinah M. Amin, Volker Nock, Paula Brooksby, Renee V. Goreham","doi":"10.1002/admi.202500176","DOIUrl":"10.1002/admi.202500176","url":null,"abstract":"Lung cancer is challenging to diagnose due to late symptom manifestation, necessitating non-invasive, point-of-care detection tools. Extracellular vesicles (EVs), nano-sized particles present in body fluids such as exhaled breath, offer a promising diagnostic route. EVs carry molecular cargo from their parent cells, including cancer-specific protein biomarkers, making them ideal targets for early detection. This study presents an electrochemical aptasensor platform for detecting EVs associated with non-small cell lung cancer. A microfabricated gold chip functionalized with AptTex, a thiol-modified aptamer targeting the CD44 biomarker, is developed. Electrochemical impedance spectroscopy confirms aptamer immobilization, and the platform successfully detectss extracellular vesicles in vitro from non-small cell lung cancer cells with a detection limit of 3.0 × 106 particles/mL and ΔRet = 476 ± 192 Ω. Calibration plots for generic extracellular vesicles demonstrated a detection limit of 7.0 × 106 particles/mL. The platform shows sensitivity, reproducibility, and minimal sample requirements. These findings demonstrate the potential of this aptasensor for future integration into a portable disease breathalyser, enabling non-invasive early detection of lung cancer.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 17","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500176","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145028448","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Polymer Nanogels with Albumin Reporting Interface Created Using RAFT Precipitation Polymerization for Disease Diagnosis and Food Testing (Adv. Mater. Interfaces 14/2025) 利用RAFT沉淀聚合制备具有白蛋白报告界面的聚合物纳米凝胶用于疾病诊断和食品检测。接口14/2025)

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-07-30 DOI: 10.1002/admi.70071

Yukiya Kitayama, Erika Yoshimatsu, Atsushi Harada

引用次数: 0