Cagatay Han Aldemir, Ahmet Faruk Yazici, Nehir Ergezer, Taha Can Korkmaz, Evren Mutlugun, Yusuf Kelestemur
{"title":"Zinc Chalcogenide Based Shell Layers for Colloidal Quantum Wells","authors":"Cagatay Han Aldemir, Ahmet Faruk Yazici, Nehir Ergezer, Taha Can Korkmaz, Evren Mutlugun, Yusuf Kelestemur","doi":"10.1002/admi.202500120","DOIUrl":"https://doi.org/10.1002/admi.202500120","url":null,"abstract":"<p>Colloidal quantum wells, also known as colloidal nanoplatelets (NPLs), have emerged as a promising class of materials for light-emitting devices (LEDs). However, the most widely studied core/shell NPLs, which rely on cadmium-based shell layers, face challenges due to toxicity concerns and improper charge confinement. To address these limitations, a new synthetic approach is presented that enables the controlled growth of zinc chalcogenide-based shell layers on NPLs. The synthesized CdSe/ZnSe core/shell NPLs exhibit emission between 615 and 630 nm, with a moderate photoluminescence quantum yield (PL-QY) of 40–50%. It is also demonstrated that the lateral dimensions of the CdSe core NPLs significantly affect the optical properties of the core/shell heterostructures, with smaller lateral dimensions resulting in narrower emission linewidths as low as 20 nm. Further passivation of these core/shell NPLs with an additional ZnS shell layer significantly increases the PL-QY up to 80–90%. Finally, the device performance of these two core/shell NPLs is investigated by fabricating solution-processed LEDs. With LEDs incorporating CdSe/ZnSe/ZnS core/multi-shell NPLs as the active light-emitting layer, an external quantum efficiency (EQE) of 3.82% and a maximum brightness of 6477 cd m<sup>−</sup><sup>2</sup> is obtained. These findings underscore the significant potential of zinc chalcogenide-based shell layers in advancing colloidal NPLs toward high-performance light-emitting devices.</p>","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 12","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500120","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144514935","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Buddhika S. A. Gedara, Peter S. Rice, Prescott E. Evans, Daniel Baranowski, Marcus A. Sharp, Tom Autrey, Bojana Ginovska, Zdenek Dohnálek, Zbynek Novotny
{"title":"Thermodynamic Stability and Site-Specific Distribution of Graphitic and Pyridinic Nitrogen in Graphene Moiré on Ru(0001)","authors":"Buddhika S. A. Gedara, Peter S. Rice, Prescott E. Evans, Daniel Baranowski, Marcus A. Sharp, Tom Autrey, Bojana Ginovska, Zdenek Dohnálek, Zbynek Novotny","doi":"10.1002/admi.202500142","DOIUrl":"https://doi.org/10.1002/admi.202500142","url":null,"abstract":"<p>Graphene-like materials are of interest for large-scale hydrogen storage applications due to their lightweight, durable, and scalable properties. Nitrogen-doping minimizes kinetic limitations in diffusion and recombination on surfaces, however, the role of graphitic nitrogen (GN) and pyridinic nitrogen (PN) is not well understood. Nitrogen-doped graphene is synthesized on Ru(0001) using chemical vapor deposition (CVD) of pyridine and ion irradiation. Scanning tunneling microscopy (STM), x-ray photoelectron spectroscopy (XPS), and density functional theory (DFT) are used to identify the structure, location, and thermodynamic stability of nitrogen species within the graphene moiré. CVD of pyridine results in a low nitrogen concentration (<0.1at%), while the post-growth nitrogen ion irradiation allows us to increase the concentration further. The concentration of GN and PN is controlled by varying the ion dose and annealing temperature. Comparison of measured and simulated STM images of GN and PN yield an excellent agreement, allowing us to confidently establish that GN is preferentially located near the center of the Atop region, while PN is located in the valley region of the graphene moiré. This report explicitly confirms the site assignments and provides a foundation for the site synthesis and analysis of structural and electronic properties that drive the reactivity of N-doped graphene.</p>","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 13","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500142","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144647753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Leo James, Christopher Vega-Sánchez, Priya Mehta, Xuehua Zhang, Chiara Neto
{"title":"Experimental Study of Gas Microbubbles on Oil-Infused Wrinkled Surfaces","authors":"Leo James, Christopher Vega-Sánchez, Priya Mehta, Xuehua Zhang, Chiara Neto","doi":"10.1002/admi.202500160","DOIUrl":"https://doi.org/10.1002/admi.202500160","url":null,"abstract":"<p>Lubricant-infused surfaces (LIS) have been shown to reduce hydrodynamic drag to a greater extent than theoretically expected, making them attractive candidates for microfluidic applications. The presence of nano- and micro-bubbles has been found to explain this property, but this observation is not widely acknowledged. This work investigated how the volume and distribution of lubricant in wrinkled Teflon LIS affects bubble durability. The lubricant is depleted from LIS by repeated immersion through an air–water interface, as well as by shearing, gravity drainage and spreading. The bubbles are imaged using confocal fluorescence microscopy at different levels of infused lubricant. The lubricant encasing the bubbles on LIS prevented bubbles from shrinking over several hours, compared to uninfused superhydrophobic Teflon wrinkles, in which bubbles more rapidly shrunk in height, typically within 30 min. The size of bubbles is independent of lubricant volume, likely due to lubricant redistribution underwater. These findings point toward the possibility of a short-term stabilization of bubbles on structured surfaces for drag reduction applications through the use of lubricant.</p>","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 12","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500160","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144514933","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Marshall B. Frye, Mengkun Tian, Eoin Moynihan, Ana Sanchez, Lauren M. Garten
{"title":"Interlayer-Mediated Stabilization of Metastable P63cm ScFeO3 on Al2O3","authors":"Marshall B. Frye, Mengkun Tian, Eoin Moynihan, Ana Sanchez, Lauren M. Garten","doi":"10.1002/admi.202500114","DOIUrl":"https://doi.org/10.1002/admi.202500114","url":null,"abstract":"<p>The metastable <i>P</i>6<sub>3</sub><i>cm</i> phase of ScFeO<sub>3</sub> has potential for multiferroic applications not possible in the ground state if stabilization routes can be identified. This work demonstrates that the <i>P</i>6<sub>3</sub><i>cm</i> phase of ScFeO<sub>3</sub> is stabilized on (0001) Al<sub>2</sub>O<sub>3</sub> by the spontaneous formation of two atomic layers of (111) <i>Fm</i><span></span><math>\u0000 <semantics>\u0000 <mover>\u0000 <mn>3</mn>\u0000 <mo>¯</mo>\u0000 </mover>\u0000 <annotation>$bar 3$</annotation>\u0000 </semantics></math><i>m</i> FeO during pulsed laser deposition, as observed via scanning transmission electron microscopy and a shift in the Fe L-edge on approaching the interface. The matching oxygen sublattice and reduced strain of the FeO interlayer enable a ScFeO<sub>3</sub> [11<span></span><math>\u0000 <semantics>\u0000 <mover>\u0000 <mn>2</mn>\u0000 <mo>¯</mo>\u0000 </mover>\u0000 <annotation>$bar 2$</annotation>\u0000 </semantics></math>0] || [<span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mover>\u0000 <mn>1</mn>\u0000 <mo>¯</mo>\u0000 </mover>\u0000 <mover>\u0000 <mn>1</mn>\u0000 <mo>¯</mo>\u0000 </mover>\u0000 </mrow>\u0000 <annotation>$bar 1bar 1$</annotation>\u0000 </semantics></math>2] FeO || Al<sub>2</sub>O<sub>3</sub> [11<span></span><math>\u0000 <semantics>\u0000 <mover>\u0000 <mn>2</mn>\u0000 <mo>¯</mo>\u0000 </mover>\u0000 <annotation>$bar 2$</annotation>\u0000 </semantics></math>0] orientation relationship despite a −17.1% lattice mismatch. Temperature-dependent X-ray diffraction further support interlayer-mediated stabilization, as FeO forms above 850 °C, preceding the formation of the <i>P</i>6<sub>3</sub><i>cm</i> ScFeO<sub>3</sub> phase at 1000 °C. The identification of the FeO interlayer provides insights into the phase stabilization mechanism of <i>P</i>6<sub>3</sub><i>cm</i> ScFeO<sub>3</sub> and presents a strategy for stabilizing other metastable materials that lack epitaxial substrates.</p>","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 12","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500114","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144514797","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Petr Slobodian, Berenika Hausnerova, Pavel Riha, Vladimir Pata, Robert Olejnik, Jiri Matyas
{"title":"Turning Plastic Waste Immiscibility into an Advantage: Efficiency Improvement of PVDF-Based Energy Harvesters Using Post-Consumer Thermoplastics","authors":"Petr Slobodian, Berenika Hausnerova, Pavel Riha, Vladimir Pata, Robert Olejnik, Jiri Matyas","doi":"10.1002/admi.202500070","DOIUrl":"https://doi.org/10.1002/admi.202500070","url":null,"abstract":"<p>The immiscibility of plastic waste, which is often a limiting factor in traditional recycling processes, is considered in this study as a key feature for functional material design. Polyvinylidene fluoride (PVDF), renowned for its exceptional triboelectric and piezoelectric properties, is combined with post-consumer thermoplastic waste from the packaging industry to create a novel, sustainable energy-harvesting solution. Immiscible compounds of wasted high-density polyethylene, polypropylene, polystyrene, and polyethylene terephthalate form physical mixtures of domains of individual polymers within the melt, which enhance mechano-electric conversion when paired with PVDF to achieve a remarkable output voltage of 800 V, with short-circuit current and charge densities reaching 260 µAcm⁻<sup>2</sup> and 710 nCm⁻<sup>2</sup>, respectively, surpassing traditional PVDF-nanoparticle composites. This method not only reduces reliance on costly nanomaterials but also demonstrates the potential of repurposed plastic waste for energy applications. The design of the sensors is examined to distinguish the contribution of piezo- and tribo-electrifications. Examples of low-cost sustainable sensors constructed from PVDF and thermoplastic waste films demonstrate efficient energy conversion and sensitivity to mechanical stimuli and highlight the potential of repurposing immiscible plastic waste not only as a solution to pollution but also as a contributor to green energy technologies.</p>","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 12","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500070","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144514563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Strain Relaxation of Al-Rich α-(AlGa)2O3 and α-Al2O3/Ga2O3 Superlattice on m-Plane Sapphire Substrates by Plasma-Assisted Molecular Beam Epitaxy","authors":"Riena Jinno, Hironori Okumura","doi":"10.1002/admi.202500136","DOIUrl":"https://doi.org/10.1002/admi.202500136","url":null,"abstract":"<p>The strain relaxation of Al-rich α-(Al<i><sub>x</sub></i>Ga<sub>1-</sub><i><sub>x</sub></i>)<sub>2</sub>O<sub>3</sub> single layers with <i>x</i> > 0.6 and an α-Al<sub>2</sub>O<sub>3</sub>/Ga<sub>2</sub>O<sub>3</sub> superlattice structure grown on <i>m</i>-plane sapphire substrates by molecular beam epitaxy is investigated. Symmetrical full-width half maximum values of X-ray diffraction (XRD) omega scans are less than 400 arcsec for pseudomorphically grown α-(AlGa)<sub>2</sub>O<sub>3</sub> single layers, but increase significantly as compressive stresses in the α-(AlGa)<sub>2</sub>O<sub>3</sub> layers are released due to lattice relaxation. Transmission electron microscopy (TEM) for a partially relaxed sample reveals the formation of V-shaped dislocations with screw components on the sample surface, while the initial interface layer exhibits a low dislocation density, as the V-shaped dislocations do not completely extend to the epilayer/substrate interface. The variation in dislocation density in the α-(AlGa)<sub>2</sub>O<sub>3</sub> layer results in two distinct XRD peaks. The TEM observation suggests the most probable relaxation system of <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mrow>\u0000 <mo>{</mo>\u0000 <mrow>\u0000 <mn>01</mn>\u0000 <mover>\u0000 <mn>1</mn>\u0000 <mo>¯</mo>\u0000 </mover>\u0000 <mn>2</mn>\u0000 </mrow>\u0000 <mo>}</mo>\u0000 </mrow>\u0000 <mfrac>\u0000 <mn>1</mn>\u0000 <mn>3</mn>\u0000 </mfrac>\u0000 <mrow>\u0000 <mo>⟨</mo>\u0000 <mrow>\u0000 <mn>0</mn>\u0000 <mover>\u0000 <mn>1</mn>\u0000 <mo>¯</mo>\u0000 </mover>\u0000 <mn>11</mn>\u0000 </mrow>\u0000 <mo>⟩</mo>\u0000 </mrow>\u0000 </mrow>\u0000 <annotation>${ {01bar 12} }frac{1}{3}langle {0bar 111} rangle $</annotation>\u0000 </semantics></math>. Scanning TEM observation for the α-Al<sub>2</sub>O<sub>3</sub>/Ga<sub>2</sub>O<sub>3</sub> superlattice structure reveals that the α-Ga<sub>2</sub>O<sub>3</sub> layers are grown in the Stranski-Krastanov (SK) mode.</p>","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 12","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500136","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144514798","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Vikram Singh, Alban Morel, Danick Gallant, Janine Mauzeroll
{"title":"From Microscale to Road Scale: Bridging the Gaps of Predictive Aluminum Corrosion Using SECM (Adv. Mater. Interfaces 8/2025)","authors":"Vikram Singh, Alban Morel, Danick Gallant, Janine Mauzeroll","doi":"10.1002/admi.202570026","DOIUrl":"https://doi.org/10.1002/admi.202570026","url":null,"abstract":"<p><b>Aluminum Alloy Corrosion Prediction</b></p><p>In article 2400669, Janine Mauzeroll and co-workers explore aluminum alloy (AAxxxx) corrosion prediction using microelectrochemistry instead of long-term road testing (days vs. years). A strong correlation between corrosion propagation for in-service and estimated corrosion emerges implying a huge impact on the progress of automobile and aerospace sectors.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 8","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202570026","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143852792","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Borophene-Based Ultrasensitive and Broadband Photodetectors (Adv. Mater. Interfaces 8/2025)","authors":"Yaser Abdi, Alireza Eskandari, Zahra Alavi, Anousha Khamsavi, Mahsa Etminan, Mobina Zahedi, Masoud Taleb, Nahid Talebi","doi":"10.1002/admi.202570023","DOIUrl":"https://doi.org/10.1002/admi.202570023","url":null,"abstract":"<p><b>Borophene-Based Photodetector</b></p><p>In article 2400894, Yaser Abdi, Nahid Talebi, and co-workers present a novel approach to photodetectors by directly growing χ3-phase borophene on single-crystal silicon wafers, forming high-quality Schottky junctions. The resulting detectors exhibit exceptional sensitivity and response times, significantly outperforming traditional photodetectors based on two-dimensional materials. This advancement paves the way for enhanced photodetectors in integrated silicon-based circuits and technologies.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 8","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202570023","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143852801","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Najma Khatoon, Binod Subedi, Ahmad Majed, Shiping Wang, Jibao He, Julie N.L. Albert, Michael Naguib, Douglas B Chrisey
{"title":"Synthesis and Photothermal Processing of Silicon-Based Nanoconfined MXenes (Adv. Mater. Interfaces 8/2025)","authors":"Najma Khatoon, Binod Subedi, Ahmad Majed, Shiping Wang, Jibao He, Julie N.L. Albert, Michael Naguib, Douglas B Chrisey","doi":"10.1002/admi.202570024","DOIUrl":"https://doi.org/10.1002/admi.202570024","url":null,"abstract":"<p><b>Energy Materials</b></p><p>In article 2400447, Najma Khatoon and co-workers report ion exchange intercalation of Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXenes with aminopropyl terminated polydimethylsiloxane (PDMS) and subsequent application of photonic curing to study pyrolysis of intercalated PDMS. This study demonstrates that photonic curing is a promising approach for cost-effective, broadband, and scalable synthesis of customizable layered intercalated materials. These materials with precisely controlled nanostructure can find application as energy materials.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 8","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202570024","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143852723","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tsuyoshi Inaba, Richard J Archer, David A Gregory, Shin-ichiro M Nomura
{"title":"Lipid-Hybrid Multicompartment Membrane Systems for Controlled, Compartmentalized Encapsulant Release","authors":"Tsuyoshi Inaba, Richard J Archer, David A Gregory, Shin-ichiro M Nomura","doi":"10.1002/admi.202400959","DOIUrl":"https://doi.org/10.1002/admi.202400959","url":null,"abstract":"<p>Multicellular structures are a common feature in biological organisms, conferring structural advantages including protection of internal content and spatiotemporal organization through defined spatial arrangements. Here a morphologically analogous lipid-hybrid multi-compartmental (LHMC) material produced within seconds on a milliliter scale by use of lipid and hydrophobic surfactant-rich oils referred to as “lipid-inks” is shown. This method encapsulates aqueous solutions at up to 94% of the total volume, into densely packed micro-compartments (20–200 µm) delineated by a continuous thin hydrophobic membrane. These LHMCs can be encased in hydrogel matrices for structural support and ease of handling. Controlled compartmentalized release of encapsulated content is demonstrated by triggered membrane solubilization from the introduction of hydrophilic surfactants to the external solution at or above their critical micellization concentration (CMC). Environmental ionic strength-dependent release rates are also demonstrated in the case of anionic sodium dodecyl sulfate (SDS). Notably, internal micro-compartments maintain content separation, enabling stable spatial patterning leading to controlled temporal release when directionally exposed to solubilizing agents. This micro-compartmentalized system, with its capacity for spatially and temporally regulated release and environmentally tunable rates, holds potential for advances in programmed delivery and responsive release of multiple bioactive agents in medical applications.</p>","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 11","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202400959","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144244949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}