Ziyoda Ganieva, Dávid Kovács, Zoltán Osváth, Dániel Zámbó, András Deák
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Region-Selective Growth of Cu2O Shell on Gold Nanoprisms
Structural control in metal/semiconductor multicomponent nanoparticles can lead to advanced functional properties, as optoelectronic processes and accessibility (e.g., by charge carriers or molecules) of the different components can be simultaneously tailored. In this study, the impact of surface-adsorbed molecules (5-amino-2-mercaptobenzimidazole - AMBI) on the wet-chemical deposition of cuprous oxide (Cu2O) shells on gold nanoprisms is investigated. It is shown that the otherwise excellent compatibility between gold and Cu2O, and hence the shell deposition, is profoundly influenced by the presence of AMBI. The time evolution of the optical and structural properties during the shell growth indicates that the inherent Volmer-Weber characteristic of the Cu2O deposition process gets greatly amplified by the surface adsorption of AMBI. Measurements performed on individual nanoparticles show that this originates in the inhomogeneous, multi-patch coverage of the particle surface. Under optimized synthetic conditions, the tips of the nanoprisms are effectively protected from Cu2O overgrowth and are left bare.
期刊介绍:
Advanced Materials Interfaces publishes top-level research on interface technologies and effects. Considering any interface formed between solids, liquids, and gases, the journal ensures an interdisciplinary blend of physics, chemistry, materials science, and life sciences. Advanced Materials Interfaces was launched in 2014 and received an Impact Factor of 4.834 in 2018.
The scope of Advanced Materials Interfaces is dedicated to interfaces and surfaces that play an essential role in virtually all materials and devices. Physics, chemistry, materials science and life sciences blend to encourage new, cross-pollinating ideas, which will drive forward our understanding of the processes at the interface.
Advanced Materials Interfaces covers all topics in interface-related research:
Oil / water separation,
Applications of nanostructured materials,
2D materials and heterostructures,
Surfaces and interfaces in organic electronic devices,
Catalysis and membranes,
Self-assembly and nanopatterned surfaces,
Composite and coating materials,
Biointerfaces for technical and medical applications.
Advanced Materials Interfaces provides a forum for topics on surface and interface science with a wide choice of formats: Reviews, Full Papers, and Communications, as well as Progress Reports and Research News.