Cu2O壳在金纳米片上的区域选择性生长

IF 4.4 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Ziyoda Ganieva, Dávid Kovács, Zoltán Osváth, Dániel Zámbó, András Deák
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引用次数: 0

摘要

金属/半导体多组分纳米颗粒的结构控制可以导致先进的功能特性,因为不同组分的光电过程和可及性(例如,通过载流子或分子)可以同时定制。在本研究中,研究了表面吸附分子(5-氨基-2-巯基苯并咪唑- AMBI)对氧化亚铜(Cu2O)壳在金纳米片上湿化学沉积的影响。结果表明,AMBI的存在深刻地影响了金与Cu2O之间良好的相容性,从而影响了壳沉积。壳生长过程中光学和结构性质的时间演化表明,AMBI的表面吸附极大地放大了Cu2O沉积过程固有的Volmer-Weber特性。对单个纳米颗粒进行的测量表明,这源于颗粒表面的不均匀、多斑块覆盖。在优化的合成条件下,纳米棱镜的尖端被有效地保护,不受Cu2O过度生长的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Region-Selective Growth of Cu2O Shell on Gold Nanoprisms

Region-Selective Growth of Cu2O Shell on Gold Nanoprisms

Region-Selective Growth of Cu2O Shell on Gold Nanoprisms

Region-Selective Growth of Cu2O Shell on Gold Nanoprisms

Region-Selective Growth of Cu2O Shell on Gold Nanoprisms

Structural control in metal/semiconductor multicomponent nanoparticles can lead to advanced functional properties, as optoelectronic processes and accessibility (e.g., by charge carriers or molecules) of the different components can be simultaneously tailored. In this study, the impact of surface-adsorbed molecules (5-amino-2-mercaptobenzimidazole - AMBI) on the wet-chemical deposition of cuprous oxide (Cu2O) shells on gold nanoprisms is investigated. It is shown that the otherwise excellent compatibility between gold and Cu2O, and hence the shell deposition, is profoundly influenced by the presence of AMBI. The time evolution of the optical and structural properties during the shell growth indicates that the inherent Volmer-Weber characteristic of the Cu2O deposition process gets greatly amplified by the surface adsorption of AMBI. Measurements performed on individual nanoparticles show that this originates in the inhomogeneous, multi-patch coverage of the particle surface. Under optimized synthetic conditions, the tips of the nanoprisms are effectively protected from Cu2O overgrowth and are left bare.

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来源期刊
Advanced Materials Interfaces
Advanced Materials Interfaces CHEMISTRY, MULTIDISCIPLINARY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
8.40
自引率
5.60%
发文量
1174
审稿时长
1.3 months
期刊介绍: Advanced Materials Interfaces publishes top-level research on interface technologies and effects. Considering any interface formed between solids, liquids, and gases, the journal ensures an interdisciplinary blend of physics, chemistry, materials science, and life sciences. Advanced Materials Interfaces was launched in 2014 and received an Impact Factor of 4.834 in 2018. The scope of Advanced Materials Interfaces is dedicated to interfaces and surfaces that play an essential role in virtually all materials and devices. Physics, chemistry, materials science and life sciences blend to encourage new, cross-pollinating ideas, which will drive forward our understanding of the processes at the interface. Advanced Materials Interfaces covers all topics in interface-related research: Oil / water separation, Applications of nanostructured materials, 2D materials and heterostructures, Surfaces and interfaces in organic electronic devices, Catalysis and membranes, Self-assembly and nanopatterned surfaces, Composite and coating materials, Biointerfaces for technical and medical applications. Advanced Materials Interfaces provides a forum for topics on surface and interface science with a wide choice of formats: Reviews, Full Papers, and Communications, as well as Progress Reports and Research News.
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