Macromolecular Research最新文献

{"title":"Fluorescent nanoparticles using hyaluronic acid-histidine-based manganese dioxide for hydrogen peroxide imaging in inflammatory macrophages","authors":"Ji Yeon Hong,&nbsp;Ji Sun Park,&nbsp;Kyeongsoon Park","doi":"10.1007/s13233-024-00337-8","DOIUrl":"10.1007/s13233-024-00337-8","url":null,"abstract":"<div><p>The presence of excessive hydrogen peroxide (H₂O₂) in the body plays a key role in inflammatory diseases. Among the various methods available, fluorescent nanoparticles have been used to detect H₂O₂ in living cells. Herein, the design of CD44-targetable fluorescent nanoparticles is presented for intracellular H₂O₂ imaging in inflammatory macrophages. Accordingly, CD44-targetable hyaluronic acid-histidine (HA–His) conjugates were sequentially reacted with permanganate and fluorescein (FL) to synthesize HA–His/MnO₂/FL nanoparticles. These prepared HA–His/MnO₂/FL nanoparticles exhibited good dispersibility in water and 10% fetal bovine serum solution. Owing to their rapid responsiveness to H₂O₂, the HA–His/MnO₂/FL nanoparticles showed a good linear relationship with H₂O₂ concentration (0–100 μM). Moreover, the CD44-targetable HA–His/MnO₂/FL nanoparticles were readily internalized in lipopolysaccharide-induced inflammatory macrophages, allowing successful imaging of intracellular H₂O₂ in inflammatory macrophages.</p><h3>Graphical Abstract</h3><p>The HA-His/MnO₂/FL nanoparticles with H₂O₂ responsiveness were readily internalized into activated macrophages, allowing successful intracellular H₂O₂ imaging in inflammatory macrophages\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"33 3","pages":"271 - 276"},"PeriodicalIF":2.8,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143612256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis of sustainable heterocyclic aryl sulfonamide derivatives: computational studies, molecular docking, and antibacterial assessment","authors":"Ajay Kumar,&nbsp;Sheerin Masroor,&nbsp;Savaş Kaya,&nbsp;Konstantin P. Katin,&nbsp;Avni Berisha,&nbsp;Mohammad Ehtisham Khan,&nbsp;Wahid Ali,&nbsp;Syed Kashif Ali,&nbsp;Mohammad S. Alomar,&nbsp;Abdullateef H. Bashiri,&nbsp;Waleed Zakri","doi":"10.1007/s13233-024-00335-w","DOIUrl":"10.1007/s13233-024-00335-w","url":null,"abstract":"<div><p>The treatment of infectious diseases is impacted by the emergence of multidrug-resistant microbiological infections. Due to the long-term usage of antibacterial clinical drugs, microbes develop resistance to clinical drugs. To take advantage of the potential of these families of chemicals, several derivatives of thiophene containing p-toluene sulfonamide (TPS) were prepared using an eco-friendly method with high yields. These synthetic derivatives had a wide range of structural diversity to demonstrate a structure–activity link. In multi-component reaction (MCR), the versatile reactants (1 mmol) react for up to 6–8 h at pH 7.2 ± 0.2 and temperature 70 ± 1 °C. The reaction involved the reusable organic catalyst <span>l</span>-Proline (1 mol%), and the mechanisms through a Knoevenagel condensation pathway, which has the advantage of effectively producing the described thiophene derivatives (TD). Then, further TD reacts with p-toluene sulfonamide (Tosyl-Cl) at 0 °C within 10–12 h to provide the final product TPS. The present investigation provides an inexpensive and eco-friendly method of TPS derivatives. A perusal of the tables indicates that TPS derivatives exhibited promising activity against S. typhimurium as compared to E. coli and S. aureus. The compounds having good activity contained electron-withdrawing as well as electron-donating substituent groups on the benzaldehyde benzene ring of the amino part of the amide.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div><div><p>\u0000Green sustainable development of multi component heterocyclic aryl sulfonamide reaction</p></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"33 3","pages":"331 - 344"},"PeriodicalIF":2.8,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143612062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Rapid synthesis of biocompatible alginates for adsorption of chemical warfare agents","authors":"Jaekyung Bae,&nbsp;Sang Myeon Lee,&nbsp;Min-Kun Kim","doi":"10.1007/s13233-024-00332-z","DOIUrl":"10.1007/s13233-024-00332-z","url":null,"abstract":"<div><p>The demand for lightweight respirators necessitates the development of high-performance composites capable of removing chemical agents. However, most of these materials either pose risks to human health or involve toxic substances in their production. This study investigates the adsorption of cyanogen chloride and sarin onto spherical composites synthesized via a biocompatible and rapid alginate-based method. The incorporation of metal and triethylenediamine, combined with highly porous activated carbon powder, significantly enhances the adsorption capacity of the composite. Rapid synthesis through ion exchange maintains a highly specific surface area. Moreover, the impregnation of metal and triethylenediamine further augments both the physical and chemical adsorption performance of the composite. The properties of the composites were characterized using scanning electron microscopy, energy-dispersive X-ray spectroscopy, and Brunauer–Emmett–Teller analyses. Breakthrough time tests indicated that the impregnated alginate-based composites exhibited superior physical (143%) and chemical (128%) adsorption capabilities compared to military-activated carbon. This study presents a potential biocompatible alginate-based synthesis technique to improve adsorption while enabling easy and rapid adjustment of particle size.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"33 3","pages":"321 - 330"},"PeriodicalIF":2.8,"publicationDate":"2024-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143612311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Surface engineering of zirconia with abaloparatide and nano-hydroxyapatite for synergistic osteogenic activity","authors":"Hong Jae Lee,&nbsp;Yong-Dae Kwon,&nbsp;Sang Cheon Lee","doi":"10.1007/s13233-024-00336-9","DOIUrl":"10.1007/s13233-024-00336-9","url":null,"abstract":"<div><p>We report on the surface engineering of zirconia (ZrO₂) by incorporation of abaloparatide (ABL) on the surface of nano-hydroxyapatite (nHAp)-immobilized zirconia. First, nHAp-immobilized zirconia (nHAp–PDA–ZrO₂) was fabricated by adding nHAp in a polydopamine (PDA)-coating process on zirconia surface. Surface chemistry, morphology, and wettability of nHAp–PDA–ZrO₂ were examined using X-ray photoelectron spectroscopy (XPS), field-emission scanning electron microscopy (FE-SEM), and water contact angle measurement. As a second step, ABL incorporation was performed by the reaction of ABL with PDA layer coated on nHAp–PDA–ZrO₂. A fluorescence microscope visualized that ABL was efficiently bound on the surface of nHAp–PDA–ZrO₂to form ABL/nHAp–PDA–ZrO₂. The synergistic osteogenic effect of ABL and nHAP on alkaline phosphatase (ALP) activity, calcium-mineral deposition, and alizarin red staining were assessed. The combination of ABL and nHAp for surface-engineering approaches may provide an effective approach to develop highly promising bone-regenerative osteogenic implant surfaces.</p><h3>Graphical abstract</h3><p>The surface of zirconia is engineered by incorporation of bone-forming abaloparatide (ABL) and osteoconductive nano-hydroxyapatite (nHAp). This ABL/nHAp-functionalized zirconia surface exhibits synergistic improved osteogenic activity.</p>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"33 3","pages":"277 - 287"},"PeriodicalIF":2.8,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143612304","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis and characterization of hyperbranched thiol hardener and their curing behavior in thiol–epoxy","authors":"Jin Han Song,&nbsp;Seung-Mo Hong,&nbsp;Seok Kyu Park,&nbsp;Hyeok Ki Kwon,&nbsp;Seok-Ho Hwang,&nbsp;Jong-Min Oh,&nbsp;Sang-Mo Koo,&nbsp;Giwon Lee,&nbsp;Chulhwan Park","doi":"10.1007/s13233-024-00334-x","DOIUrl":"10.1007/s13233-024-00334-x","url":null,"abstract":"<div><p>Hyperbranched thiol (Hyperbranched mercaptopropionate, HBMP) was synthesized using a commercially available hydroxyl-terminal hyperbranched oligomer and 3-mercaptopropionic acid applying a low-temperature esterification reaction. The chemical structure and molecular weight analysis of synthesized HBMP were investigated by Fourier transform infrared spectroscopy (FT-IR) and gel permeation chromatography (GPC). The synthesized HBMP was analyzed with curing kinetics, thermal/mechanical properties, and adhesion trait with bisphenol-A-type epoxy resin compared to pentaerythritol tetra-mercaptopropionate (PETMP). The curing kinetics between HBMP and epoxy resin required higher activation energy compared to PETMP case. In addition, it was confirmed that as the content of HBMP increases, the thermal and mechanical properties decrease, but the adhesion property was greatly improved. These results indicate that incorporating hyperbranched thiol in epoxy resin is an efficient method to utilize the material as an adhesive layer.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div><div><p>Synthesis procedure of HBMP reaction with BoltornTM P1000 and 3-MPA.</p></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"33 3","pages":"367 - 375"},"PeriodicalIF":2.8,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143612303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Water-soluble anionic polymer electrolytes based on polyfluorene as the universal interlayer for organic solar cells","authors":"Rahmatia Fitri Binti Nasrun,&nbsp;Dong Hwan Son,&nbsp;Joo Hyun Kim","doi":"10.1007/s13233-024-00329-8","DOIUrl":"10.1007/s13233-024-00329-8","url":null,"abstract":"<div><p>Conjugated polymers derived from polyfluorene and featuring sulfonate groups in their side chains were synthesized for interlayer in both fullerene and non-fullerene organic solar cells (OSCs). These polymers, specifically denoted as PFS-T-x (x = H, Li), establish an advantageous interfacial dipole through the ionic functionality located at the side chains. Remarkably, the key parameters of organic solar cells, such as <span>({J}_{sc})</span> and <span>(FF,)</span> exhibit improvements as the size of the cation increases. The highest power conversion efficiency (PCE) was achieved using PFS-T-Li as interlayer, reaching up to 9.11% and 16.3% for the device based on fullerene and non-fullerene, respectively. This study can provide a deeper understanding and potential enhancements in the performance of OSCs utilizing polymers as universal interlayers.</p><h3>Graphic abstract</h3><p>\u0000This study explored the impact of different countercations in conjugated polymers used as an interlayer in organic solar cells. It was discovered that the conjugated polyelectrolyte containing lithium countercations produced the highest power conversion efficiency, ascribed to the creation of an advantageous interfacial dipole.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"33 3","pages":"313 - 320"},"PeriodicalIF":2.8,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143612302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhancing the thermal conductivity of epoxy molding compounds by adding SiO2-embedded carbon nanofibers for semiconductor packaging applications","authors":"Yeon-Ryong Chu,&nbsp;Zambaga Otgonbayar,&nbsp;Gyu-Sik Park,&nbsp;Suk Jekal,&nbsp;Ha-Yeong Kim,&nbsp;Jiwon Kim,&nbsp;Yoon-Ho Ra,&nbsp;Seulki Song,&nbsp;Chang-Min Yoon","doi":"10.1007/s13233-024-00317-y","DOIUrl":"10.1007/s13233-024-00317-y","url":null,"abstract":"<div><p>This study presents the synthesis of silica-embedded carbon nanofibers (SiO₂/eCNFs) as additives to enhance the heat dissipation properties of epoxy molding compounds (EMCs) for semiconductor packaging. Three different sized SiO₂ nanoparticles were prepared and added to the precursor solution for polyacrylonitrile (PAN) nanofibers. Through electrospinning and carbonization, SiO₂ nanoparticles-embedded PAN nanofibers were successfully converted to SiO₂/eCNFs. As-fabricated SiO₂/eCNFs were mixed with EMC in different concentrations from 0.1 to 1.0 wt% to investigate the effect of SiO₂/eCNFs on EMC in perspective of thermal and mechanical properties. Under our experimental conditions, the addition of 500SiO₂/eCNFs with 0.4 wt% EMC achieved a 67% enhancement in thermal conductivity and a 43% higher impact strength compared to pristine EMC. The improved thermal and mechanical properties by adding SiO₂/eCNFs additives can be attributed to two factors: one-dimensional carbon and embedded SiO₂ nanoparticles. The presence of one-dimensional carbon successfully enhanced the thermal conductivity owing to its natural graphitic characteristics and dimensional advantages. In addition, the optimal size of the SiO₂ nanoparticles provided more heat dissipation routes while maintaining the packing factor compatibility with the SiO₂ fillers in the EMC. In practical EMC applications for semiconductor chips, infrared (IR) camera observations confirmed a faster increase in the surface temperature with the use of SiO₂/eCNFs-EMC, demonstrating the potential of these new EMC additives as next-generation high-performance semiconductors.</p><h3>Graphical abstract</h3><p>The improvement in the thermal conductivity of the chip molded in epoxy molding compound (EMC) through the addition of SiO₂-embedded carbon nanofibers (SiO₂/eCNFs) is demonstrated. The SiO₂/eCNFs-EMC molded chips exhibited enhanced thermal conductivity, attributed to the formation of heat pathways through the combination of SiO₂ and CNFs.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"33 1","pages":"105 - 116"},"PeriodicalIF":2.8,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142995670","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High biomass content in epoxy vitrimers: a study on bio-based and reprocessable thermosets","authors":"Jonghyeok Jeon,&nbsp;Chungryong Choi","doi":"10.1007/s13233-024-00333-y","DOIUrl":"10.1007/s13233-024-00333-y","url":null,"abstract":"<div><p>This study reports the development of a novel biomass-based epoxy vitrimer using bio-derived monomers and a fully bio-based cross-linking agent. Specifically, di-epoxy, tri-epoxy, and soybean oil (SO)-epoxy monomers were synthesized from renewable sources of 2,5-furandicarboxylic acid (FDCA), protocatechuic acid (PCA), and soybean oil, respectively. A fully bio-based tetra-functional thiol cross-linker was also synthesized from <i>α</i>-lipoic acid. The resulting epoxy resins exhibited high biomass contents (77.10% for di-epoxy, 74.30% for tri-epoxy, and 74.00% for SO-epoxy) demonstrating their sustainability. These resins, which can be cured at relatively low temperatures, exhibited exceptional mechanical properties with tensile strengths of up to 55.76 MPa. Moreover, the resins exhibited stress–relaxation behavior and reprocessing capabilities through the integration of thiol–epoxy reactions and transesterification, marking a significant advancement in the development of sustainable alternatives to conventional petroleum-based thermosets. This study underscores the potential application of these bio-based, reprocessable epoxy vitrimers to the reduction of environmental pollution and greenhouse gas emissions.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"33 3","pages":"345 - 354"},"PeriodicalIF":2.8,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143612106","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Crucial role of polymeric binders in enhancing energy density of supercapacitors","authors":"Juhee Yoon,&nbsp;Jeonghun Lee,&nbsp;Young Soo Yun,&nbsp;Hyo won Kwak,&nbsp;Hyoung-Joon Jin","doi":"10.1007/s13233-024-00327-w","DOIUrl":"10.1007/s13233-024-00327-w","url":null,"abstract":"<div><p>The growing demand for efficient energy storage solutions has driven significant advancements in supercapacitor technology, aimed at overcoming the traditional limitations of low energy density. This article reviews strategies for enhancing the energy density of supercapacitors, focusing on advancements in electrolyte formulations, activated carbon materials, pseudocapacitive materials, and binder technologies. Aqueous, ionic liquid, and organic electrolytes have been optimized to expand voltage windows and improve ionic conductivity, thereby increasing energy storage capacity. The development of high specific surface area carbon materials and the precise tailoring of pore size distributions have been shown to enhance capacitance. Pseudocapacitive materials, including metal oxides and MXenes, have demonstrated the potential for significantly higher energy densities through redox-active mechanisms. Innovations in binder systems, particularly those employing conductive materials like reduced graphene oxide, have further improved electrode performance by enhancing structural integrity and ion transport. A key focus is the role of polymer binders, which are vital for reducing the internal resistance and subsequent heat generation. Research in this area aims to develop binders that minimize resistive losses, improve ion transport efficiency, reduce heat generation and maintain optimal operating temperatures, prevent thermal degradation, and increase energy density. Continuous research into new materials and formulations for polymer binders is essential for advancing supercapacitor technology.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"33 2","pages":"153 - 166"},"PeriodicalIF":2.8,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143489395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Research on Parylene-C application to wearable organic electronics: in the respect of substrate type","authors":"Benliang Hou,&nbsp;Yea Eun Lee,&nbsp;Do Hyeon Kim,&nbsp;Heqing Ye,&nbsp;Hyeok-jin Kwon,&nbsp;Se Hyun Kim","doi":"10.1007/s13233-024-00328-9","DOIUrl":"10.1007/s13233-024-00328-9","url":null,"abstract":"<p>Poly(para-xylylene) polymers, also known as parylene and its derivatives, have attracted attention as functional materials in organic electronics. Among the various parylene derivatives, Parylene-C is a unique material that has gained attention in various industries, including wearable electronic devices. Parylene-C is particularly suitable for coating and protecting electronic components because of its high dielectric strength, biocompatibility, and chemical resistance. Herein, we compare three different substrates for application in wearable organic electronics with Parylene-C with respect to the deposition process. We identified the morphology and electrical properties of Parylene-C with a pristine layer and practical electronic devices (capacitors and transistors). Based on this analysis, we applied integrated logic devices with optimized organic transistors on a Parylene-C substrate. Therefore, we expect that this study will aid in the selection and use of versatile substrate types for the fabrication of organic electronics with Parylene-C materials.</p>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"33 2","pages":"185 - 194"},"PeriodicalIF":2.8,"publicationDate":"2024-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143489346","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}